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Water-quality assessment of the Cook Inlet Basin, Alaska — Environmental setting

The Cook Inlet Basin in Alaska is one of 59 study units selected for study for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment program. The Cook Inlet Basin study unit encompasses the fresh surface and ground waters in the 39,325 square-mile area that drains to Cook Inlet, but does not include the marine waters of Cook Inlet. This report describes the natural factors (climate, physiography, geology, soils, land cover) and the human factors (population, land use, water use) that affect water quality, which is the first step in designing and conducting a multidisciplinary regional water-quality assessment. The surface- and ground-water hydrology, and the aquatic ecosystems of the Cook Inlet Basin are described. The report provides an overview of existing water-quality conditions and summarizes the results of selected water-quality studies of the basin.

Alaska↗

Status and understanding of groundwater quality in the Santa Clara River Valley, 2007-California GAMA Priority Basin Project

Groundwater quality in the approximately 460-square-mile Santa Clara River Valley study unit was investigated from April through June 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. The Santa Clara River Valley study unit contains eight groundwater basins located in Ventura and Los Angeles Counties and is within the Transverse and Selected Peninsular Ranges hydrogeologic province. The Santa Clara River Valley study unit was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected in 2007 by the USGS from 42 wells on a spatially distributed grid, and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system was defined as that part of the aquifer system corresponding to the perforation intervals of wells listed in the CDPH database for the Santa Clara River Valley study unit. The quality of groundwater in the primary aquifer system may differ from that in shallow or deep water-bearing zones; for example, shallow groundwater may be more vulnerable to surficial contamination. Eleven additional wells were sampled by the USGS to improve understanding of factors affecting water quality.The status assessment of the quality of the groundwater used data from samples analyzed for anthropogenic constituents, such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of untreated groundwater resources in the primary aquifers of the Santa Clara River Valley study unit, not the quality of treated drinking water delivered to consumers. Relative-concentrations (sample concentration divided by health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (greater than 1.0); moderate (greater than 0.1 and less than or equal to 1.0); and low (less than or equal to 0.1). For inorganic constituents, relative-concentrations were classified as high (greater than 1.0); moderate (greater than 0.5 and less than or equal to 1.0); and low (less than or equal to 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the areal percentage of the primary aquifer system with relative-concentrations greater than 1.0. Moderate and low aquifer-scale proportions are defined as the areal percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches, grid-based and spatially weighted, were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the Santa Clara River Valley study unit (within 90 percent confidence intervals). The status assessment showed that inorganic constituents were more prevalent and relative-concentrations were higher than for organic constituents. For inorganic constituents with human-health benchmarks, relative-concentrations (of one or more constituents) were high in 21 percent of the primary aquifer system areally, moderate in 30 percent, and low or not detected in 49 percent. Inorganic constituents with human-health benchmarks with high aquifer-scale proportions were nitrate (15 percent of the primary aquifer system), gross alpha radioactivity (14 percent), vanadium (3.4 percent), boron (3.2 percent), and arsenic (2.3 percent). For inorganic constituents with aesthetic benchmarks, relative-concentrations (of one or more constituents) were high in 54 percent of the primary aquifer system, moderate in 41 percent, and low or not detected in 4 percent. The inorganic constituents with aesthetic benchmarks with high aquifer-scale proportions were total dissolved solids (35 percent), sulfate (22 percent), manganese (38 percent), and iron (22 percent). In contrast, the results of the status assessment for organic constituents with human-health benchmarks showed that relative-concentrations were high in 0 percent (not detected above benchmarks) of the primary aquifer system, moderate in 2.4 percent, and low or not detected in 97 percent. Relative-concentrations of the special interest constituent, perchlorate, were moderate in 12 percent of the primary aquifer system and low or not detected in 88 percent. Relative-concentrations of two VOCs-carbon tetrachloride and trichloroethene (TCE)-were moderate in 2.4 percent of the primary aquifer system. One VOC-chloroform (water disinfection byproduct)-was detected in more than 10 percent of the primary aquifer system but at low relative-concentrations. Of the 88 VOCs and gasoline oxygenates analyzed, 71 were not detected. Pesticides were low or not detected in 100 percent of the primary aquifer system. Of the 118 pesticides and pesticide degradates analyzed, 13 were detected and 5 of those had human-health benchmarks. Two of these five pesticides-simazine and atrazine-were detected in more than 10 percent of the primary aquifer system. The second component of this study, the understanding assessment, was to identify the natural and human factors that affect groundwater quality on the basis of the evaluation of land use, physical characteristics of the wells, and geochemical conditions of the aquifer. Results from these analyses are used to explain the occurrence and distribution of selected constituents in the primary aquifer system of the Santa Clara River Valley study unit. The understanding assessment indicated that water quality varied spatially primarily in relation to depth, groundwater age, reduction-oxidation conditions, pH, and location in the regional groundwater flow system. High and moderate relative-concentrations of nitrate and low relative-concentrations of pesticides were correlated with shallow depths to top-of-perforation, and with high dissolved oxygen. Groundwater of modern and mixed ages had higher nitrate than pre-modern-age groundwater. Decreases in concentrations of total dissolved solids (TDS) and sulfate were correlated with increases in pH. This relationship probably indicates relations of these constituents with increasing depth across most of the Santa Clara River Valley study unit. Previous studies have indicated multiple sources of high concentrations of TDS and sulfate and multiple geochemical processes affecting these constituents in the Santa Clara River Valley study unit. Manganese and iron concentrations were highest in pre-modern-age groundwater at depth and in the downgradient area of the Santa Clara River Valley study unit (closest to the coastline), indicating the prevalence of reducing groundwater conditions in these aquifer zones.

Scientific Investigations Report↗

Flow-Meter and Passive Diffusion Bag Tests and Potential Influences on the Vertical Distribution of Contaminants in Wells at Galena Airport, Galena, Alaska, August to October 2002

Past activities at Galena Airport, a U.S. Air Force Base in Galena, Alaska, have resulted in ground-water contamination by volatile organic compounds. The primary contaminants are petroleum hydrocarbons and chlorinated aliphatic hydrocarbons. The U.S. Geological Survey and Earth Tech, in cooperation with the Air Force Center for Environmental Excellence, conducted investigations at Galena Airport from August to October 2002 using polyethylene diffusion bag samplers and borehole flow-meter testing to examine the vertical distribution of ground-water contamination in selected wells. This investigation was limited to the vicinity of building 1845 and to the area between building 1845 and the Yukon River. In addition, the U.S. Geological Survey was asked to determine whether additional wells are needed to more clearly define the nature and extent of the ground-water contamination at the Air Force Base. Little or no vertical water movement occurred under ambient conditions in the wells tested at Galena Airport, Alaska, in August 2002. All of the ambient vertical flows detected in wells were at rates less than the quantitative limit of the borehole flow meter (0.03 gallons per minute). In wells 06-MW-07 and 10-MW-01, no vertical flow was detected. In wells where ambient flow was detected, the direction of flow was downward. In general, concentrations of volatile organic compounds detected in the low-flow samples from wells at Galena Airport were approximately the same concentrations detected in the closest polyethylene diffusion bag sample for a wide variety of volatile organic compounds. The data indicate that the polyethylene diffusion bag sample results are consistent with the low-flow sample results. Vertical profiling of selected wells using polyethylene diffusion bag samplers at Galena Airport showed that from September 30 to October 1, 2002, little vertical change occurred in volatile organic compound concentrations along the screen length despite the fact that little or no vertical flow was measured in most of the tested wells in August 2002. Two of the wells (10-MW-03 and 06-MW-01) had slightly greater vertical concentration variation for some constituents. In these wells, the contaminant depth probably is lithologically influenced. The close match between concentrations measured in polyethylene diffusion bag and low-flow samples indicates that the bag samples accurately represent the distribution of volatile organic compounds in the wells. It is unclear, however, whether the distribution of volatile organic compounds in the wells, as indicated by the bag samplers, represents contaminant distributions in the aquifer or transient movement within the wells. The probable change in well hydraulics between August and late September to October indicates that the relatively uniform vertical distribution of volatile organic compounds in some of the wells may represent in-well mixing. This uncertainty could be clarified by the installation and sampling of well clusters at various times of the year. Additional insight into the vertical distribution of contamination and flow possibly could be obtained by conducting flow-meter tests and collecting polyethylene diffusion bag samples from selected wells at different times of the year. The westernmost contaminant plume at Million Gallon Hill appears to be surrounded by sufficient monitoring wells to detect changes in the plume extent; however, the installation of additional wells at Galena Airport has the potential to provide additional information on the extent of ground-water contamination in the remaining plumes. The additional information to be gained includes better definition of the vertical and lateral extents of the plumes and better definition of the ground-water flow directions.

Open-File Report↗

Historical Channel Adjustment and Estimates of Selected Hydraulic Values in the Lower Sabine River and Lower Brazos River Basins, Texas and Louisiana

The U.S. Geological Survey, in cooperation with the Texas Water Development Board, evaluated historical channel adjustment and estimated selected hydraulic values at U.S. Geological Survey streamflow-gaging stations in the lower Sabine River Basin in Texas and Louisiana and lower Brazos River Basin in Texas to support geomorphic assessments of the Texas Instream Flow Program. Channel attributes including cross-section geometry, slope, and planform change were evaluated to learn how each river's morphology changed over the years in response to natural and anthropogenic disturbances. Historical and contemporary cross-sectional channel geometries at several gaging stations on each river were compared, planform changes were assessed, and hydraulic values were estimated including mean flow velocity, bed shear stress, Froude numbers, and hydraulic depth. The primary sources of historical channel morphology information were U.S. Geological Survey hard-copy discharge-measurement field notes. Additional analyses were done using computations of selected flow hydraulics, comparisons of historical and contemporary aerial photographs, comparisons of historical and contemporary ground photographs, evaluations of how frequently stage-discharge rating curves were updated, reviews of stage-discharge relations for field measurements, and considerations of bridge and reservoir construction activities. Based on historical cross sections at three gaging stations downstream from Toledo Bend Reservoir, the lower Sabine River is relatively stable, but is subject to substantial temporary scour-and-fill processes during floods. Exceptions to this characterization of relative stability include an episode of channel aggradation at the Sabine River near Bon Wier, Texas, during the 1930s, and about 2 to 3 feet of channel incision at the Sabine River near Burkeville, Texas, since the late 1950s. The Brazos River, at gaging stations downstream from Waco, Texas, has adjusted to a combination of hydrologic, sedimentary, and anthropogenic controls. Since the 1960s, numerous point bars have vertically accreted and vegetation has encroached along the channel margins, which probably promotes channel-bed incision to compensate for a reduction in cross-sectional area. Channel incision was detected at all gaging stations along the Brazos River, and the depth of incision is greatest in the lowermost gaging stations, exemplified by about 5 feet of channel-bed incision between 1993 and 2004 at Richmond, Texas. One notable exception to this pattern of incision was a period of aggradation at U.S. Geological Survey gaging station 08096500 Brazos River at Waco, Texas, during the late 1920s and 1930s, probably associated with upstream dam construction. Lateral channel migration rates along the Brazos River determined from aerial photographs are greatest between Waco and Hempstead, Texas, with numerous bends moving an average of more than 10 feet per year. Migration rates at selected bends downstream from Hempstead were measured as less than 10 feet per year, on average. Two tributaries of the Brazos River, the Little and Navasota Rivers, also were investigated for historical channel adjustment. The Little River near Cameron, Texas (08106500) has incised its channel bed about 12 feet since 1949, and the lower Navasota River shows complex adjustment to bridge construction activities and a channel avulsion.

Scientific Investigations Report↗

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington↗

Network analysis of a regional fishery: Implications for management of natural resources, and recruitment and retention of anglers

Angler groups and water-body types interact to create a complex social-ecological system. Network analysis could inform detailed mechanistic models on, and provide managers better information about, basic patterns of fishing activity. Differences in behavior and reservoir selection among angler groups in a regional fishery, the Salt Valley fishery in southeastern Nebraska, USA, were assessed using a combination of cluster and network analyses. The four angler groups assessed ranged from less active, unskilled anglers (group One) to highly active, very skilled anglers (group Four). Reservoir use patterns and the resulting network communities of these four angler groups differed; the number of reservoir communities for these groups ranged from two to three and appeared to be driven by reservoir location (group One), reservoir size and its associated attributes (groups Two and Four), or an interaction between reservoir size and location (group Three). Network analysis is a useful tool to describe differences in participation among angler groups within a regional fishery, and provides new insights about possible recruitment of anglers. For example, group One anglers fished reservoirs closer to home and had a greater probability of dropping out if local reservoir access were restricted.

Fisheries Research↗

Selected chemical composition of deposited sediments in the flooded areas of New Orleans following Hurricane Katrina

Nearly 4 weeks after Hurricane Katrina passed through St. Bernard Parish, the U.S. Geological Survey's (USGS) Mid-Continent Geographic Science Center and the University of Missouri-Rolla's (UMR) Natural Hazard Mitigation Institute deployed a team of scientists to the region to collect perishable environmental and engineering data. The team collected 149 samples throughout the affected area to chemically characterize the Katrina depositional sediments. Preliminary results of this effort are presented here.

Louisiana↗

Selenium teratogenesis in natural populations of aquatic birds in central California

The frequency and types of malformations are described that were encountered during the spring of 1983 in a natural population of aquatic birds exposed to agricultural drainwater ponds and food items containing high concentrations of selenium in central California. A total of 347 nests of aquatic birds containing 1,681 eggs was selected for study at Kesterson Reservoir located in the Kesterson National Wildlife Refuge (NWR), Merced County, California. Embryos collected during incubation or from eggs that failed to hatch were examined to determine the age at death and presence of malformations. Embryonic death was generally high; approximately 17–60% of the nests of different species contained at least one dead embryo. The incidence of malformed embryos was also high; approximately 22–65% of the nests where at least two embryos were examined contained abnormal embryos. American coots ( Fulica americana ) and black-necked stilts ( Himantopus mexicanus ) experienced the highest incidence of malformed embryos. For all species, the average percentage of eggs containing dead or live abnormal embryos was 16.1 whereas the average percentage containing live abnormal embryos was 10.7. Multiple gross malformations of the eyes, brain, and feet were often present. Brain defects included hydrocephaly and exencephaly. Eye defects included both unilateral and bilateral anophthalmia and microphthalmia. Eye and foot defects with ectrodactyly and swollen joints were the most common in coots. Beak defects also occurred frequently and most often included incomplete development of the lower beak of ducks ( Anas spp.) and stilts. Wing and leg defects were most prevalent in stilts and ducks, with ectromelia and amelia most prevalent in stilts. Other malformations occurring at lower frequencies included enlarged hearts with thin ventricular walls, liver hypopiasia, and gastroschisis. Based upon simultaneous examination of a control population of aquatic birds of the same species and published studies, the incidences of embryonic mortality and deformities were 9–30 times greater than expected. The role of the form of selenium responsible for teratogenesis in laboratory studies is discussed.

California↗

The Ebro margin study, northwestern Mediterranean Sea - an introduction

The Ebro continental margin from the coast to the deep sea off northeastern Spain was selected for a multidisciplinary project because of the abundant Ebro River sediment supply, Pliocene and Quaternary progradation, and margin development in a restricted basin where a variety of controlling factors could be evaluated. The nature of this young passive margin for the last 5 m.y. was investigated with particular emphasis on marine circulation, sediment dynamics, sediment geochemistry, depositional facies, seismic stratigraphy, geotechnical properties, geological hazards and human influences. These studies show the importance of marine circulation, variation in sediment supply, sea-level oscillation and tectonic setting for the understanding of modern and ancient margin depositional processes and growth patterns.

Marine Geology↗

Movement, home range, and site fidelity of bluegills in a Great Plains Lake

Little is known about the distribution, movement, and home ranges of bluegills Lepomis macrochirus in lentic environments. Therefore, the objectives of this study were to evaluate the seasonal and diel differences in movement rates, site fidelity, and home range of bluegills in a shallow, natural Great Plains lake. A total of 78 bluegills (200-273 mm total length) were implanted with radio transmitters in March and May 2000. Of these fish, 10 males and 10 females were randomly selected and located every 2 h during one 24-h period each month from April to September 2000. Bluegill movement peaked during midsummer: however, there was little difference in diel movements, suggesting relatively consistent movement throughout the 24-h period. Home range estimates (which included the 24-h tracking plus an additional six locations from the same fish located once per day for six consecutive days each month) ranged up to 172 ha, probably because only about half of the bluegills exhibited site fidelity during any month sampled. Bluegill movement did not appear to be strongly linked with water temperature, barometric pressure, or wind speed. These results suggest that bluegills move considerable distances and that many roam throughout this 332-ha shallow lake. However, diel patterns were not evident. Sampling bluegills in Great Plains lakes using passive gears (e.g., trap nets) may be most effective during the summer months, when fish are most active. Active sampling (e.g., electrofishing) may be more effective than the use of passive gears in spring and fall, when bluegills are less active.

North American Journal of Fisheries Management↗

Selected water-quality data from Fallen Leaf Lake, El Dorado County, California, June through October 1974

In 1974 the U.S. Geological Survey entered into a cooperative agreement with the California Department of Water Resources to study the limnology of Fallen Leaf Lake and adjacent streams. The lake is in California, near the crest of the Sierra Nevada about 23 miles southwest of Reno, Nevada (fig. 1). The study was undertaken to help develop a better understanding of selected characteristics of a high-altitude dilute-solution lake-stream system and the effect of man on the system. Fallen Leaf Lake and the adjacent streams were chosen for the study because the lake represents an alpine system in a basin that has had limited development for a number of years. Recently, local and state groups have become extremely interested in the effects of man's activities on the condition of the lake. The study was designed to: 1. Provide data on selected physical, chemical, and biological characteristics of Fallen Leaf Lake and adjacent streams, 2. Determine whether the magnitude and changes in magnitude of a number of physical, chemical, and biological variables are affected by natural or cultural processes, 3. Characterize a high-altitude, dilute-solution aquatic ecosystem, 4. Compare and contrast the physical, chemical, and biological characteristics of Fallen Leaf Lake and adjacent streams with other lakes in the area.

California↗

The human factor in mining reclamation

Rapid urbanization of the landscape results in less space available for wildlife habitat, agriculture, and recreation. Mineral resources (especially nonmetallic construction materials) become unrecoverable due to inaccessibility caused by development. This report both describes mine sites with serious problems and draws attention to thoughtful reclamation projects for better future management. It presents information from selected sites in terms of their history, landform, design approach, and visual discernment. Examples from Colorado are included to introduce the broader issue of regions soundly developing mining sites, permitting the best utilization of natural resources, and respecting the landscape.

Circular↗

Delineation of faults, fractures, foliation, and ground-water-flow zones in fractured-rock, on the southern part of Manhattan, New York, through use of advanced borehole-geophysical techniques

Advanced borehole-geophysical techniques were used to assess the geohydrology of crystalline bedrock in 20 boreholes on the southern part of Manhattan Island, N.Y., in preparation for construction of a third water tunnel for New York City. The borehole-logging techniques included natural gamma, single-point resistance, short-normal resistivity, mechanical and acoustic caliper, magnetic susceptibility, borehole-fluid temperature and resistivity, borehole-fluid specific conductance, dissolved oxygen, pH, redox, heatpulse flowmeter (at selected boreholes), borehole deviation, acoustic and optical televiewer, and borehole radar (at selected boreholes). Hydraulic head and specific-capacity test data were collected from 29 boreholes. The boreholes penetrated gneiss, schist, and other crystalline bedrock that has an overall southwest to northwest-dipping foliation. Most of the fractures penetrated are nearly horizontal or have moderate- to high-angle northwest or eastward dip azimuths. Foliation dip within the potential tunnel-construction zone is northwestward and southeastward in the proposed North Water-Tunnel, northwestward to southwestward in the proposed Midtown Water-Tunnel, and northwestward to westward dipping in the proposed South Water-Tunnel. Fracture population dip azimuths are variable. Heat-pulse flowmeter logs obtained under pumping and nonpumping (ambient) conditions, together with other geophysical logs, indicate transmissive fracture zones in each borehole. The 60-megahertz directional borehole-radar logs delineated the location and orientation of several radar reflectors that did not intersect the projection of the borehole. Fracture indexes range from 0.12 to 0.93 fractures per foot of borehole. Analysis of specific-capacity tests from each borehole indicated that transmissivity ranges from 2 to 459 feet squared per day; the highest transmissivity is at the Midtown Water-Tunnel borehole (E35ST-D).

Open-File Report↗

A one-dimensional, steady-state, dissolved-oxygen model and waste-load assimilation study for West Fork Blue River, Washington County, Indiana

The Indiana State Board of Health is developing a water-quality management plan that includes establishing limits for wastewater effluents discharged into Indiana streams. A digital model calibrated to conditions in West Fork Blue River was used to predict alternatives for future waste loadings that would be compatible with Indiana stream water-quality standards defined for two critical hydrologic conditions, summer and winter low flows. Alternative waste loads that would permit instream dissolved-oxygen concentrations of at least 5.0 milligrams per liter for West Fork Blue River in Washington County, Ind., were determined. All point-source waste loads that potentially impact West Fork Blue River are in the town of Salem. The Salem municipal wastewater-treatment facility is the only facility in the modeled reach that has a National Pollution Discharge Elimination System permit to discharge organic waste. In-stream dissolved-oxygen concentration averaged 96.5 percent of saturation at selected sites on West Fork Blue River during two 24-hour summer surveys. This high dissolved-oxygen concentration reflects small carbonaceous and nitrogenous waste loads, adequate dilution of waste by the stream, and natural reaeration. Nonpoint source waste loads accounted for an average of 53.2 percent of the total carbonaceous biochemical-oxygen demand and 90.2 percent of the nitrogenous biochemical-oxygen demand. Waste-load assimilation was studied for both summer and annual 7-day, 10-year low flow. Natural streamflow for these conditions was zero, so no benefit from dilution was provided. The projected reaeration capacity of the stream was not sufficient to maintain at least 5 milligrams per liter dissolved oxygen in the stream with current waste-discharge restrictions. Consequently, during low flows, advanced waste treatment (nitrification-denitrification) or some other form of ammonia removal may be necessary to meet current Indiana stream water-quality standards for ammonia and dissolved oxygen. During winter low flow, ammonia toxicity, rather than dissolved-oxygen concentration, was the limiting water-quality criterion downstream from the Salem wastewater-treatment facility.

Indiana↗

Questa baseline and pre-mining ground-water quality investigation. 20. Water chemistry of the Red River and selected seeps, tributaries, and precipitation, Taos County, New Mexico, 2000-2004

As part of a multi-year project to infer the pre-mining ground-water quality at Molycorp's Questa mine site, surface-water samples of the Red River, some of its tributaries, seeps, and snow samples were collected for analysis of inorganic solutes and of water and sulfate stable isotopes in selected samples. The primary aim of this study was to document diel, storm event, and seasonal variations in water chemistry for the Red River and similar variations in water chemistry for Straight Creek, a natural analog site similar in topography, hydrology, and geology to the mine site for inferring pre-mining water-quality conditions. Red River water samples collected between 2000 and 2004 show that the largest variations in water chemistry occur during late summer rainstorms, often monsoonal in nature. Within hours, discharge of the Red River increased from 8 to 102 cubic feet per second and pH decreased from 7.80 to 4.83. The highest concentrations of metals (iron, aluminum, zinc, manganese) and sulfate also occur during such events. Low-pH and high-solute concentrations during rainstorm runoff are derived primarily from alteration 'scar' areas of naturally high mineralization combined with steep topography that exposes continually altered rock because erosion is too rapid for vegetative growth. The year 2002 was one of the driest on record, and Red River discharge reflected the low seasonal snow pack. No snowmelt peak appeared in the hydrograph record, and a late summer storm produced the highest flow for the year. Snowmelt was closer to normal during 2003 and demonstrated the dilution effect of snowmelt on water chemistry. Two diel sampling events were conducted for the Red River, one during low flow and the other during high flow, at two locations, at the Red River gaging station and just upstream from Molycorp's mill site. No discernible diel trends were observed except for dissolved zinc and manganese at the upstream site during low flow. Straight Creek drainage water was sampled periodically from 2001 to 2004 at the down stream end of surface drainage near the point at which it disappeared into the debris fan. This water has a minimal range in pH (2.7 to 3.2) but a substantial concentration range in many solutes; for example, sulfate concentrations varied from 525 to 2,660 mg/L. Many elements covary with sulfate suggesting that dilution is the primary control of the range in solute concentrations. A transect of water samples higher in the scar area were collected in October of 2003. They had a lower range in pH (2.44 to 3.05) and higher solute concentrations than those collected periodically from lower in the catchment. Water isotopes for the upper transect samples indicated slight evaporation, and in part, may account for the higher solute concentrations. Drainage waters also were collected from Hottentot, Junebug, Hansen, Little Hansen, and Goat Hill Gulch drainages. Most constituents from other scar drainage waters showed ranges of concentration similar to those of the Straight Creek waters. An exception was water collected from Goat Hill Gulch, which has some of the highest concentrations of any surface-water sample collected but also contained waste-rock leachates.

New Mexico↗

Major-ion and selected trace-metal chemistry of the Biscayne Aquifer, Southeast Florida

The major-ion and selected trace-metal chemistry of the Biscayne aquifer was characterized as part of the Florida Ground-Water Quality Monitoring Network Program, a multiagency cooperative effort concerned with delineating baseline water quality for major aquifer systems in the State. The Biscayne aquifer is unconfined and serves as the sole source of drinking water for more than 3 million people in southeast Florida. The Biscayne aquifer consists of highly permeable interbedded limestone and sandstone of Pleistocene and Pliocene age underlying most of Dade and Broward Counties and parts of Palm Beach and Monroe Counties. The high permeability is largely caused by extensive carbonate dissolution. Water sampled from 189 wells tapping the Biscayne aquifer was predominantly a calcium bicarbonate type with some mixed types occurring in coastal areas and near major canals. Major - ion is areally uniform throughout the aquifer. According to nonparametric statistical tests of major ions and dissolved solids, the concentrations of calcium, sodium, bicarbonate, and dissolved solids increased significantly with well depth ( 0.05 significance level ), probably a result of less circulation at depth. Potassium and nitrate concentrations decreased significantly with depth. Although the source of recharge to the aquifer varies seasonally, there was no statistical difference in the concentration of major ions in pared water samples from 27 shallow wells collected during wet and dry seasons. Median concentrations for barium, chromium, copper, lead, and manganese were below maximum or secondary maximum contaminant levels set by the US Environmental Protection Agency. The median iron concentration only slightly exceeded the secondary maximum contaminant level. The concentration of barium was significantly related (0.05 significance level) to calcium and bicarbonate concentration. No distinct areal pattern or vertical distribution of the selected trace metals was evident in water from the Biscayne aquifer. Sources for trace metals found in water from the Biscayne aquifer may include local contamination, well-construction techniques, canal - aquifer interactions, and natural occurrence in area soils and rock.

Florida↗

Geohydrology and simulation of ground-water flow in the aquifer system near Calvert City, Kentucky

The U.S. Geological Survey, in cooperation with the Kentucky Natural Resources and Environmental Protection Cabinet, constructed a two-dimensional, steady-state ground-water-flow model to estimate hydraulic properties, contributing areas to discharge boundaries, and the average linear velocity at selected locations in an aquifer system near Calvert City, Ky. Nonlinear regression was used to estimate values of model parameters and the reliability of the parameter estimates. The regression minimizes the weighted difference between observed and calculated hydraulic heads and rates of flow. The calibrated model generally was better than alternative models considered, and although adding transmissive faults in the bedrock produced a slightly better model, fault transmissivity was not estimated reliably. The average transmissivity of the aquifer was 20,000 feet squared per day. Recharge to two outcrop areas, the McNairy Formation of Cretaceous age and the alluvium of Quaternary age, were 0.00269 feet per day (11.8 inches per year) and 0.000484 feet per day (2.1 inches per year), respectively. Contributing areas to wells at the Calvert City Water Company in 1992 did not include the Calvert City Industrial Complex. Since completing the fieldwork for this study in 1992, the Calvert City Water Company discontinued use of their wells and began withdrawing water from new wells that were located 4.5 miles east-southeast of the previous location; the contributing area moved farther from the industrial complex. The extent of the alluvium contributing water to wells was limited by the overlying lacustrine deposits. The average linear ground-water velocity at the industrial complex ranged from 0.90 feet per day to 4.47 feet per day with a mean of 1.98 feet per day.

Water-Resources Investigations Report↗