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United States mineral resources

The work on this volume began in January 1972, but in a broader sense its production began many years ago. The chapters were written by geologists most of whom have had many years of experience studying the geology of mineral deposits, and more particularly the commodities about which they have written here. A total of nearly 2,300 man-years of professional experience in the geology of mineral resources is represented by the authors of the volume, and about 30 man-years went directly into its preparation. Each chapter contains not only a synthesis of the state of knowledge of the geology of the commodity, but also an appraisal of the known resources, and an examination of the geologic possibilities for finding additional deposits. In January 1972, responsibility for the preparation of the volume was assigned to us as co-editors, and we were given a tentative list of commodities and authors. We provided each author with a suggested outline of general topics to be covered, and some guidelines as to scope and philosophy of approach, but beyond that we avoided any attempt to fit each chapter into a stereotype. Moreover, the types of commodities range from the major metals and industrial minerals such as copper, silver, and fluorspar, which have been the subject of geologic research for years, to other commodities that are of such varied geologic nature (such as pigments or gemstones) or of such minor present importance (such as scandium or thallium) that they cannot be treated from the same viewpoint as the major minerals. The chapters range, therefore, from comprehensive summary reports to general essays that reflect the individuality of the authors as well as the variation among commodities. Throughout the book the emphasis is on geology, but each chapter contains some summary information on uses, technology, and economics. These summaries are not meant to be exhaustive, however, and additional details are in the 1970 edition of "Mineral Facts and Problems" (Bulletin 650 of the U.S. Bureau of Mines) ; indeed, we regard that book and the present volume as being complementary. In the examination of the geologic possibilities for finding new deposits-in many respects the principal innovative contributions of this volume-we asked the authors to frankly apply the limits of their ingenuity and not only to summarize current theories but also to express their own intuitive ideas, however speculative and unconventional they may seem, that have come from years of study devoted to the origin of mineral deposits. Readers will see that some authors have speculated more courageously than others. In any case, we believe readers will find all the chapters interesting, and many stimulating; and a few we believe can be frankly characterized as intellectually exciting. Most chapters include a section on prospecting techniques, and a summary of geologic or related problems on which the authors believe research might be most fruitful in the continuing efforts to find new resources. An integral part of the book is the bibliographic material cited at the conclusion of each chapter, in lieu of repetition of detailed descriptions already in print. Index and "spot" maps are not included in most chapters because they are available elsewhere, and in many cases with more detail than could possibly be included here. Maps showing the distribution of known deposits of many commodities in the United States are available in the Mineral Resource (MR) map series of the U.S. Geological Survey and in the National Atlas of the United States. The first three chapters deal not with resources of specific commodities but with general information that is pertinent to the study of mineral resources. In the introductory chapter we discuss the purposes of the book, the distinctions between reserves and various categories of resources, and some general conclusions drawn from our view of the book in its entirety. In the second chapter V. E. McKelvey discusses the problems of mineral-resource estimates and public policy. In the third chapter, R. L. Erickson discusses some new points of view on the relation of reserves and resources to the crustal abundance of elements. We acknowledge with thanks the cooperation of our colleagues in all phases of the preparation of this volume. Whatever success the book may attain is due entirely to a total effort. A paragraph of acknowledgment originally submitted as a part of the chapter on "Nuclear fuels" is given here instead because we feel it applied to all chapters: "The writers have drawn freely from published information, not all of which is cited, and from their colleagues, none of whom are given specific credit. The reader should be aware that the paper could not have been written without these sources." We extend specific thanks to Michael Fleischer for preparation of summaries of geochemical information that are included in many chapters.

Professional Paper↗

Selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001-12

The upper Blackfoot River in southeastern Idaho receives runoff from 12 large phosphate mines. Waste shales that are removed to access the phosphate ore are highly enriched with selenium, resulting in elevated selenium in runoff from the mine waste dumps. In 2001, in cooperation with the Bureau of Land Management, the U.S. Geological Survey (USGS) began monitoring streamflow, selenium, and other water-quality parameters at a single location near the outlet of the upper Blackfoot River to the Blackfoot Reservoir. Water samples primarily were collected by a flow triggered, automated pump sampler, supplemented by manual point and equal-width integrated manual samples. The approach to monitoring concentrations and streamflow over time at a fixed location is ideal for evaluating temporal trends, but provides no information about the relative source contributions from the mine waste dumps draining into various tributaries. In 2001, the Idaho Department of Environmental Quality (IDEQ) began an annual, mid-May, synoptic survey of selenium concentrations and streamflow at 21 locations along the main stem Blackfoot River and its tributaries. Individually, neither the intensive USGS sampling at the outlet nor the IDEQ annual synoptic sampling provides a comprehensive view of selenium runoff in the Blackfoot River watershed. Together, the efforts are complementary; therefore, in this report, results are presented from both sampling efforts. The USGS collected time-series data from 2001 to 2012 at a fixed location, the Blackfoot River near the outlet of the reservoir, near Henry, Idaho (USGS streamgage 13063000). Dissolved selenium concentrations from 450 filtered samples collected at this site ranged from 0.5 to 11.4 micrograms per liter (μg/L). The State of Idaho chronic aquatic life criterion concentration of 5 μg/L was exceeded in 31 percent of the samples, with most exceedances occurring during May of each year. No exceedances of the selenium criterion were recorded in months other than April, May, or June. Concentrations of selenium in unfiltered and filtered samples were similar, and concentrations from samples collected by depth and width integrated methods were similar to those collected by grab (point) samples, indicating that the grab samples adequately represent selenium concentrations across the entire river cross section. In speciation analyses made during 2003 and 2004, the median percentage of total selenium as selenate was 81 percent, ranging from 17 to 98 percent, and the median percentage of total selenium as selenite was 19 percent, ranging from 2 to 83 percent of the total selenium. During the period of study, selenium concentrations had an upward trend during the lowflow season of August–October. Time trends were not obvious during other seasons. Selenium daily loads varied by more than a factor of 900 during the study period and ranged from 0.03 kilograms per day (kg/d) to more than 24 kg/d. Annual maximum daily loads of selenium varied over nearly a factor of 12, ranging from about 2 to 24 kg/d. For the annual spring synoptic samples collected by the IDEQ along the main stem Blackfoot River and major tributaries, selenium concentrations ranged from less than 2 to 870 μg/L in 176 samples. In most years, the synoptic sampling showed that the majority of the selenium loads passing the USGS streamgage at the outlet of the watershed could be attributed to a single tributary, East Mill Creek, which enters the Blackfoot River through Spring Creek. Selenium loads decreased by about half from East Mill Creek before reaching the Blackfoot River, suggesting that much selenium is at least temporarily removed from the water column by uptake by aquatic vegetation or by losses to sediment. Similar decreases in selenium loads occurred through the main stem Blackfoot River before reaching the outlet in low flow years, but not in high flow years.

Idaho↗

Biogeochemical aspects of uranium mineralization, mining, milling, and remediation

Natural uranium (U) occurs as a mixture of three radioactive isotopes: 238 U, 235 U, and 234 U. Only 235 U is fissionable and makes up about 0.7% of natural U, while 238 U is overwhelmingly the most abundant at greater than 99% of the total mass of U. Prior to the 1940s, U was predominantly used as a coloring agent, and U-bearing ores were mined mainly for their radium (Ra) and/or vanadium (V) content; the bulk of the U was discarded with the tailings (Finch et al., 1972). Once nuclear fission was discovered, the economic importance of U increased greatly. The mining and milling of U-bearing ores is the first step in the nuclear fuel cycle, and the contact of residual waste with natural water is a potential source of contamination of U and associated elements to the environment. Uranium is mined by three basic methods: surface (open pit), underground, and solution mining (in situ leaching or in situ recovery), depending on the deposit grade, size, location, geology and economic considerations (Abdelouas, 2006). Solid wastes at U mill tailings (UMT) sites can include both standard tailings (i.e., leached ore rock residues) and solids generated on site by waste treatment processes. The latter can include sludge or “mud” from neutralization of acidic mine/mill effluents, containing Fe and a range of coprecipitated constituents, or barium sulfate precipitates that selectively remove Ra (e.g., Carvalho et al., 2007). In this chapter, we review the hydrometallurgical processes by which U is extracted from ore, the biogeochemical processes that can affect the fate and transport of U and associated elements in the environment, and possible remediation strategies for site closure and aquifer restoration. This paper represents the fourth in a series of review papers from the U.S. Geological Survey (USGS) on geochemical aspects of UMT management that span more than three decades. The first paper (Landa, 1980) in this series is a primer on the nature of tailings and radionuclide mobilization from them. The second paper (Landa, 1999) includes coverage of research carried out under the U.S. Department of Energy’s Uranium Mill Tailings Remedial Action Program (UMTRA). The third paper (Landa, 2004) reflects the increased focus of researchers on biotic effects in UMT environs. This paper expands the focus to U mining, milling, and remedial actions, and includes extensive coverage of the increasingly important alkaline in situ recovery and groundwater restoration.

Applied Geochemistry↗

Map showing drill-hole depths, lithologic intercepts, and partial isopachs of basin fill in the Winnemucca 1 degree by 2 degrees quadrangle, Nevada

The purpose of this map is to aid in the mineral-resource assessment and exploration of covered host rocks by displaying and interpreting data that can be used to estimate the depth of basin fill in the Winnemucca 1° by 2° quadrangle, Nevada. Publicly available information used in making this map includes water, petroleum, and geothermal well data, gravity data and models, seismic profiles, and geologic and geomorphic reports. Wells logs used for this map of the Winnemucca quadrangle are from the following sources: (1) logs of more than 1,000 water wells reported to the State of Nevada Division of Water Resources, which are on file with them in Reno and at the with U.S. Geological Survey in Carson City, (2) 44 petroleum wells collected by the Nevada Bureau of Mines (Lintz, 1957; Schilling and Garside, 1968; Garside and Schilling, 1977, Garside and others, 1977; 1988), and (3) Two geothermal wells reported in Zoback (1979) and Flynn and others (1982). Data from isostatic residual and Bouguer gravity maps by Wagini (1985) contributed to the interpretation of basin configuration. Gravity models of Dixie Valley (Schaefer, 1982, and Speed, 1976) and Grass Valley (Grannell and Noble, 1977) and seismic profiles of Grass and Pine Valleys (Potter and others, 1987) helped refine basis interpretations in those areas. The geologic base map of Paleozoic and Mesozoic igneous and sedimentary rocks, Tertiary volcanic and sedimentary rocks, and Cenozoic structures was simplified from Stewart and Carlson (1976b).

Nevada↗

The U.S. Geological Survey Coal Hydrology Program and the potential of hydrologic models for impact assessments

A requirement of Public Law 95-87, the Surface Mining Control and Reclamation Act of 1977, is the understanding of the hydrology in actual and proposed surface-mined areas. Surface-water data for small specific-sites and for larger areas such as adjacent and general areas are needed also to satisfy the hydrologic requirements of the Act. The Act specifies that surface-water modeling techniques may be used to generate the data and information. The purpose of this report is to describe how this can be achieved for smaller watersheds. This report also characterizes 12 ' state-of-the-art ' strip-mining assessment models that are to be tested with data from two data-intensive studies involving small watersheds in Tennessee and Indiana. Watershed models are best applied to small watersheds with specific-site data. Extending the use of modeling techniques to larger watersheds remains relatively untested, and to date the upper limits for application have not been established. The U.S. Geological Survey is currently collecting regional hydrologic data in the major coal provinces of the United States and this data will be used to help satisfy the ' general-area ' data requirements of the Act. This program is reviewed and described in this report. (USGS)

Open-File Report↗

Geologic and environmental characteristics of porphyry copper deposits with emphasis on potential future development in the Bristol Bay Watershed, Alaska (Appendix H)

This report is prepared in cooperation with the Bristol Bay Watershed Assessment being conducted by the U.S. Environmental Protection Agency. The goal of the assessment is to help understand how future large-scale development in this watershed may affect water quality and the salmon fishery. Mining has been identified as a potential source of future large scale development in the region, especially because of the advanced stage of activity at the Pebble prospect. The goal of this report is to summarize the geologic and environmental characteristics of porphyry copper deposits in general, largely on the basis of literature review. Data reported in the Pebble Project Environmental Baseline Document, released by the Pebble Limited Partnership in 2011, are used to enhance the relevance of this report to the Bristol Bay watershed. The geologic characteristics of mineral deposits are paramount to determining their geochemical signatures in the environment. The geologic characteristics of mineral deposits are reflected in the mineralogy of the mineralization and alteration assemblages; geochemical associations of elements, including the commodities being sought; the grade and tonnage of the deposit; the likely mining and ore-processing methods used; the environmental attributes of the deposit, such as acid-generating and acid-neutralizing potentials of geologic materials; and the susceptibility of the surrounding ecosystem to various stressors related to the deposit and its mining, among other features (Seal and Hammarstrom, 2003). Within the Bristol Bay watershed, or more specifically the Nushagak and Kvichak watersheds, the geologic setting is permissive for the occurrence of several mineral deposit types that are amenable for large-scale development. Of these deposit types, porphyry copper deposits (e.g., Pebble) and intrusion-related gold deposits (e.g., Shotgun) are the most important on the basis of the current maturity of exploration activities by the mining industry. The Pebble deposit sits astride the drainage divide between the Nushagak and Kvichak watersheds, whereas the Humble, Big Chunk, and Shotgun deposits are within the Nushagak watershed. The Humble and Big Chunk prospects are geophysical anomalies that exhibit some characteristics similar to those found at Pebble. Humble was drilled previously in 1958 and 1959 as an iron prospect on the basis of an airborne magnetic anomaly. Humble is approximately 85 miles (137 km) west of Pebble; Big Chunk is approximately 30 miles (48 km) north-northwest of Pebble; and Shotgun is approximately 110 miles (177 km) northwest of Pebble. The H and D Block prospects, west of Pebble, represent additional porphyry copper exploration targets in the watershed.

Alaska↗

Roles of regional structures and country-rock facies in defining mineral belts in central Idaho mineral province with detail for Yellow Pine and Thunder Mountain mining districts

The central Idaho metallogenic province hosts numerous mineral deposit types. These include Late Cretaceous precious-polymetallic vein deposits, amagmatic Paleocene–Eocene breccia-hosted gold-tungsten-antimony deposits, and Eocene mercury deposits in metasedimentary roof pendants and in Late Cretaceous granitoids. Hot-springs gold deposits in Eocene volcanic rocks are also included in the central Idaho province. New sensitive high mass-resolution ion microprobe (SHRIMP) uranium-lead (U-Pb) ages for igneous rocks and for detrital zircon analyses of metasedimentary rocks along with geologic mapping clarify the geologic framework of the mineral deposits. This framework includes (1) structural controls for regional distribution of mining districts, (2) progressive structural development of individual districts, (3) regional sedimentary facies and their control of metals associations resulting in regional belts, and (4) influences of the several regional magmatic events. In central Idaho, 15 mining districts form two clusters that are grouped about a 200-kilometer (km) long system of normal faults. The northwestern cluster is in the regional hanging wall west of large, west-side-down faults, and the mineral deposits are located along smaller faults and fractures that cut the regional hanging wall. The southeastern cluster is in the regional hanging wall east of a linked large east-side-down fault and along and controlled by related hanging wall faults. At the southern extent of the regional fault system, the Yellow Pine-Thunder Mountain districts span a nearly 24-km-wide, east-tilted crustal block of normal-fault dominoes, exposing original crustal depths from 5 to 10 km deep on the west in the Late Cretaceous to shallow-surface depths on the east in the Eocene. Ore deposition in the northwestern district cluster was primarily Late Cretaceous and related to Idaho batholith plutons with only a single deposit related to a small Eocene intrusion; in the southeastern cluster, most deposits were initiated in the Late Cretaceous but with varying manifestations of overprinted Eocene mineralization activity. In the Yellow Pine-Thunder Mountain districts at the southern extent of the southern cluster, several mineralizing pulses occurred during hanging-wall collapse, such that (1) early deposits were multiply overprinted and (2) deposit depths, ages, and structural characteristics change progressively eastward. Originally deep-seated western Yellow Pine district deposits are Late Cretaceous viscoplastic mesothermal veins overprinted by Paleocene and Eocene breccia-hosted epithermal deposits. Central Yellow Pine district deposits contain early deeper vein systems but are primarily Paleocene and Eocene breccia-hosted epithermal deposits in Late Cretaceous plutonic rocks and Proterozoic–Paleozoic roof pendant rocks. Eastern district deposits are Eocene hot-springs-related deposits in the roof pendant. Thunder Mountain deposits farthest east are near-surface hot-springs deposits in Eocene volcanic and volcaniclastic rocks that overlie buried Cretaceous igneous and older roof pendant rocks. The mining district clusters are sited across several northwest-striking paleostratigraphic belts that are exposed in roof pendants and are offset by the regional normal fault system. A northeastern belt is Mesoproterozoic strata associated with gold-silver-copper±cobalt deposits. A central belt of Neoproterozoic rocks is not associated with mineral deposits in the central Idaho mineral province. A southwestern belt composed of probable Paleozoic deep-water miogeoclinal slope rocks and late Paleozoic epicratonic basinal rocks is thin and narrowly exposed but associated with gold-silver-antimony-tungsten±mercury deposits. These metasedimentary rocks (and their metal associations) are parts of regional mineral belts in which metal endowments are related to particular sedimentary facies belts and their Cretaceous thrust-fault juxtaposition and where these features have proximity to Late Cretaceous or Eocene igneous rocks. Offset and preservation or erosional stripping of these facies belts, thrust plates, igneous settings, and the associated regional mineral belts were controlled by the sense and magnitude of displacements across the regional normal-fault system.

Idaho↗

The chief oxide-burgin area discoveries, East Tintic district, Utah; A case history

In 1955 exploration for base and precious metals was undertaken by Bear Creek Mining Company immediately north of the Main Tintic district , Utah . During the course of this work Bear Creek became interested in the East Tintic district , primarily as a result of the activities of the U.S. Geological Survey in that area . Data published on the East Tintic district by the Survey and others were studied and map data made available from various mining companies were compiled. Preliminary economic studies were made to determine the present day value of the type of ore body discovered previously in the district . Encouraging results from these investigations led to the selection of specific targets for exploration. Recommendations for a project program were made and approved. Negotiations were successfully concluded in mid-1956 for a unit lease agreement on lands in the East Tintic district owned by the Tintic Standard and Chief Consolidated mining companies and their subsidiaries. Of the targets selected for exploration, the Chief Oxide area seemed to be one of the most prominent. Our preliminary work in the Chief Oxide area corroborated the findings of the U.S. Geological Survey described in Part I of this paper. After careful consideration it was decided to gamble the cost of an exploration shaft in this area for the purpose of providing an underground drilling platform. We also hoped by means of underground workings to establish the existence and nature of the postulated fault. A limited amount of surface drilling was done prior to shaft sinking in order to locate a shaft site and also to obtain additional information of subvolcanic structure and alteration. Underground exploration in the Chief Oxide area was started in January, 1957. The Burgin shaft was sunk to a depth of 1,100 feet and by August, 1959, lateral development on the 1050 level totaled 4,721 feet and underground diamond drilling totaled 15,480 feet. Results of the work done to date are as follows: ( a ) Identification of the sedimentary rock section and an interpretation of the structure in the Burgin mine area . (b) Discovery by penetration of the previously postulated East Tintic thrust fault. (c) Discovery of large zones of manganese oxides and carbonates, which were found to be closely related to silver-lead-zinc mineralization. (d) Discovery of ore-grade lead-zinc mineralization within the footwall rocks of the East Tintic thrust. (e) Discovery of high-grade silver-lead ore within the thrust zone. Insofar as ore localization is concerned the most important structural feature in the Burgin mine area is the East Tintic thrust fault- a fact that opens up new ore potential over a large part of the East Tintic district not previously explored. Although the discoveries to date must be attributed essentially to the application of geology to exploration, the tools of geochemical prospecting and geophysics were also used, and the geochemical work, in particular, was found to be a definite aid in the selection of areas for further exploration.

Utah↗

Bibliography of the Gulf of Mexico coastal plain coal geology

Unlike scientific literature pertaining to most other coal-bearing regions in the conterminous United States, this bibliography on the coal geology of the Gulf Coastal Plain is dominated by work from the late 20th century. Although coals of this region were mined commercially in the late 1800s and early 1900s, they were eclipsed by the production and use of oil and gas in the middle 1920s and were not mined again as a significant fuel source until the 1970s. As a result, the literature consists mainly of a relatively small number of pre-1920 contributions in state and federal reports, followed by a plethora of technical papers, symposia proceedings, field guides, theses, dissertations, and abstracts over the past 40 years. The purpose of this chapter is to record the present work used by U.S. Geological Survey personnel preparing the Gulf Coast Coal Resource Assessment and to furnish an introduction to the larger body of sedimentary, stratigraphic, paleontologic, geochemical, hydrologic, and mining literature that exists in the region. This bibliography is an update of an earlier compilation (Tewalt et al., 1990). Despite its length, it is not exhaustive. Nor is it restricted to papers that focus solely upon coals because an understanding of these coals is rooted in the general geologic literature of the Gulf Coastal Plain.

Louisiana, Texas↗

Peru Mercury Inventory 2006

In 2004, a specific need for data on mercury use in South America was indicated by the United Nations Environmental Programme-Chemicals (UNEP-Chemicals) at a workshop on regional mercury pollution that took place in Buenos Aires, Argentina. Mercury has long been mined and used in South America for artisanal gold mining and imported for chlor-alkali production, dental amalgam, and other uses. The U.S. Geological Survey (USGS) provides information on domestic and international mercury production, trade, prices, sources, and recycling in its annual Minerals Yearbook mercury chapter. Therefore, in response to UNEP-Chemicals, the USGS, in collaboration with the Economic Section of the U.S. Embassy, Lima, has herein compiled data on Peru's exports, imports, and byproduct production of mercury. Peru was selected for this inventory because it has a 2000-year history of mercury production and use, and continues today as an important source of mercury for the global market, as a byproduct from its gold mines. Peru is a regional distributor of imported mercury and user of mercury for artisanal gold mining and chlor-alkali production. Peruvian customs data showed that 22 metric tons (t) of byproduct mercury was exported to the United States in 2006. Transshipped mercury was exported to Brazil (1 t), Colombia (1 t), and Guyana (1 t). Mercury was imported from the United States (54 t), Spain (19 t), and Kyrgyzstan (8 t) in 2006 and was used for artisanal gold mining, chlor-alkali production, dental amalgam, or transshipment to other countries in the region. Site visits and interviews provided information on the use and disposition of mercury for artisanal gold mining and other uses. Peru also imports mercury-containing batteries, electronics and computers, fluorescent lamps, and thermometers. In 2006, Peru imported approximately 1,900 t of a wide variety of fluorescent lamps; however, the mercury contained in these lamps, a minimum of approximately 76 kilograms (kg), and in other products such as batteries and computer electronics is not recycled and may ultimately be released to the environment.

Open-File Report↗

Mercury at the Oat Hill Extension Mine and James Creek, Napa County, California: Tailings, sediment, water, and biota, 2003-2004

The Oat Hill Extension (OHE) Mine is one of several mercury mines located in the James Creek/Pope Creek watershed that produced mercury from the 1870's until 1944 (U.S. Bureau of Mines, 1965). The OHE Mine developed veins and mineralized fault zones hosted in sandstone that extended eastward from the Oat Hill Mine. Waste material from the Oat Hill Mine was reprocessed at the OHE Mine using gravity separation methods to obtain cinnabar concentrates that were processed in a retort. The U.S. Bureau of Land Management requested that the U.S. Geological Survey measure and characterize mercury and other chemical constituents that are potentially relevant to ecological impairment of biota in tailings, sediment, and water at the OHE Mine and in the tributaries of James Creek that drain the mine area (termed Drainage A and B ) (Figs. 1 and 2). This report summarizes such data obtained from sampling of tailings and sediments at the OHE on October 17, 2003; water, sediment, and biota from James Creek on May 20, 2004; and biota on October 29, 2004. These data are interpreted to provide a preliminary assessment of the potential ecological impact of the mine on the James Creek watershed. The mine tailings are unusual in that they have not been roasted and contain relatively high concentrations of mercury (400 to 1200 ppm) compared to unroasted waste rock at other mines. These tailings have contaminated a tributary to James Creek with mercury primarily by erosion, on the basis of higher concentration of mercury (780 ng/L) measured in unfiltered (total mercury, Hg T ) spring water flowing from the OHE to James Creek compared to 5 to 14 ng/L Hg T measured in James Creek itself. Tailing piles (presumably from past Oat Hill mine dumping) near the USBLM property boundary and upstream of the main OHE mine drainage channel ( Drainage A ; Fig. 2) also likely emit mercury, on the basis of their mercury composition (930 to 1200 ppm). The OHE spring water is likely an appreciable source of sulfate and carbonate to James Creek, because the spring water was enriched in sulfate (130 mg/L) and carbonate (430 mg/L as CaCO 3 ) compared to James Creek water (70 to 100 mg/L SO 4 2- and 110 to 170 mg/L as CaCO 3 ) at the time of sampling. Concentrations of mercury in active channel sediment from James Creek are variable and potentially high, on the basis of chemical analysis (2.5 to 17 _g/g-wet sediment) and easily visible cinnabar grains in panned concentrates. Average (geometric mean) organic mercury (presumably monomethyl mercury (MMHg); §2.3.3) concentrations in several invertebrate taxa collected from the James Creek watershed locations were higher than invertebrates taken from a Northern California location lacking a known point source of mercury. The mean proportion of MMHg to total mercury in James Creek predatory insect samples was 40 percent (1 standard deviation = 30 percent); only 40 percent of all insect samples had a MMHg/Hg T proportion greater than 0.5. The low proportions of MMHg measured in invertebrates in James Creek and the presence of cinnabar in the creek suggest that some invertebrates may have anomolously high Hg concentrations as a result of the injestion or adhesion of extremely fine-grained cinnabar particles. Interpretation of Hg T in frogs and fish as an indicator of mercury reactivity, biouptake, or trophic transfer is limited, pending MMHg measuremens, by the possibility of these whole-body samples having contained cinnabar particles at the time of analysis. To minimize this limitation, the gastrointestinal tracts and external surfaces of all amphibians, where cinnabar most likely resides, were carefully flushed to remove any visible particles. However, extremely fine-grained, invisible, adhesive cinnabar particles likely exist in the amphibians' habitats. Hg T in foothill yellow-legged frogs collected from the James Creek study area, ranging from 0.1 to 0.6 μg/g Hg, was on average twice that of an extensive database compiled from Hg T in frogs studied throughout Northern California. Average concentrations of Hg T in frogs from James Creek were similar upstream (0.18 μg/g) and downstream (0.15 μg/g) of the confluence with Tributary 1 and at the lower Corona Mine adit drainage (0.14 μg/g). Frogs may be susceptible to trophic transfer of MMHg from invertebrates, but further study is required to rule out cinnabar ‘contamination.’ Hg T concentrations in rainbow trout collected from James Creek upstream and downstream of Tributary 1 averaged 0.10 μg/g and 0.13 μg/g, respectively. Compared to invertebrates, trout Hg T was less variable, suggesting that trout were less contaminated with cinnabar. California roach had significantly higher Hg T on average than trout (0.16 vs. 0.12 μg/g), and can be considered moderately contaminated compared to the same species from other sites in Northern California, which average 0.12 μg/g Hg. While limited measurements of mercury in water, sediment, and fish exceed, in some samples, predefined ecologically protective criteria for mine-impacted California systems, they do not clearly demonstrate that the biota residing in James Creek in the vicinity of the OHE are ecologically impaired. The potential for ecological impairment is clearly evident from invertebrate methyl mercury results and may manifest in other biological ecosystem residents that have yet to be studied (e.g., piscivorous birds). Methyl mercury concentrations in flowing water and sediment from James Creek and the tributary that drains the OHE are relatively low, ranging from 0.04 to 0.08 ng/L, although these data should be cautiously interpreted (see §3.2). While the results of this investigation suggest that the OHE contributes inorganic mercury to James Creek, they do not indicate the extent to which the OHE site is ecologically impairing biota relative to other sources of mercury. Improved sampling and analytical methods are recommended for future study.

California↗

A test and re-estimation of Taylor's empirical capacity-reserve relationship

In 1977, Taylor proposed a constant elasticity model relating capacity choice in mines to reserves. A test of this model using a very large (n = 1,195) dataset confirms its validity but obtains significantly different estimated values for the model coefficients. Capacity is somewhat inelastic with respect to reserves, with an elasticity of 0.65 estimated for open-pit plus block-cave underground mines and 0.56 for all other underground mines. These new estimates should be useful for capacity determinations as scoping studies and as a starting point for feasibility studies. The results are robust over a wide range of deposit types, deposit sizes, and time, consistent with physical constraints on mine capacity that are largely independent of technology. ?? 2009 International Association for Mathematical Geology.

Natural Resources Research↗

Preliminary report on the Cape Nome gold region, Alaska

The following report is based on a few weeks' examination of the recently discovered Nome gold-mining region, made by us in October, 1899. We collected such topographic and geologic data of this important region as the climatic conditions would permit and our limited time would allow, the trip to Nome being a hurried utilization of a delay while waiting for a steamer for Seattle after the completion of the regular field work in the Yukon Basin.

Alaska↗

Geospatial analysis identifies critical mineral-resource potential in Alaska

Alaska consists of more than 663,000 square miles (1,717,000 square kilometers) of land—more than a sixth of the total area of the United States—and large tracts of it have not been system atically studied or sampled for mineral- resource potential. Many regions of the State are known to have significant mineral-resource potential, and there are currently six operating mines in the State along with numerous active mineral exploration projects. The U.S. Geologi cal Survey and the Alaska Division of Geological & Geophysical Surveys have developed a new geospatial tool that integrates and analyzes publicly available databases of geologic information and estimates the mineral-resource potential for criti cal minerals, which was recently used to evaluate Alaska. The results of the analyses highlight areas that have known mineral deposits and also reveal areas that were not previously considered to be prospective for these deposit types. These results will inform land manage ment decisions by Federal, State, and private landholders, and will also help guide future exploration activities and scientific investigations in Alaska.

Alaska↗

Preliminary report on the Nelson and Radovan copper prospects, Nizina district, Alaska

Renewed copper exploration by Alaska Copper Mines, Incorporated, at the Nelson and Radovan prospects, Nizina district, Alaska, led the Geological Survey in 1951 to map in detail the Nelson fault block, and to re-examine the old workings. In addition, two new prospects were studied. The Nelson fault block is cut by many dominantly strike-slip faults of small displacement, and by bedding faults. Slickensided chalcocite shows post-mineral movement, and chalcocite veinlet in a filled solution cavity indicates that some of the chalcocite is secondary, perhaps very recent. Structural relations indicate two overthrust faults cut the block. The Radovan Greenstone prospect shows massive chalcocite, up to 3 feet wide, in a silicified, epidotized fault zone in the Nikolai greenstone. Ore indicated by surface exposures may amount to 450 tons of chalcocite. The Radovan Low-Contact prospect is on a continuation of the same fault approximately 3 miles southwest of the Greenstone prospect, and 150 feet above the contact of the Nikolai greenstone and the overlying Chitistone limestone. Limonite staining is widespread in bedding planes and small faults near the fault zone; mineralization in the fault zone consists of pyrite, chalcocite, bornite, malachite, realgar, orpiment and stibnite. The sulphides in the fault zone, plus the widespread silicification and epidotization indicate a strong zone of hydrothermal activity which merits extensive prospecting.

Open-File Report↗

Gravity survey in part of the Snake River Plain, Idaho — A preliminary report

During the early summer of 1959, a total of 1,187 gravity stations were occupied on the western part of the Snake River plain in Idaho. An area of 2,000 square miles extending from Glenns Ferry, Idaho, to Caldwell, Idaho, was covered with a station density of one station per two square miles. An additional 1,200 square miles of surrounding area, mainly from Caldwell, Idaho, to the Oregon-Idaho state line, was covered with a density of one station per seven square miles. The mean reproducibility of the observed gravities of these stations was 0.05 milligal, with a maximum discrepancy of 0.2 milligal. Gravity data were reduced to simple Bouguer values using a combined free-air and Bouguer correction of 0.06 milligal per foot. The only anomalies found with closure in excess of 10 milligals are two elongated highs, orientated northwest-southeast, with the northwestern high offset to the northeast by 10 miles. The smaller of these highs extends from Meridian, Idaho, to Nyssa, Oregon, and the larger extends from Swan Falls, Idaho, to Glenns Ferry, Idaho. The maximum value recorded is a simple Bouguer value of -66.5 milligals with respect to the International Ellipsoid. Gradients on the sides of these highs are largest on the northeast sides, reaching six milligals per mile in places. Graticule interpretations of a profile across the southeastern high using a density contrast of 0.3 gm per cubic centimeter indicate an accumulation of lava reaching a thickness of at least 28,000 feet. The Snake River investigation was made for the purpose of searching out, defining, and interpreting gravity anomalies present on the western part of the Snake River lava plain in Idaho. In particular, it was desired to further define gradients associated with the gravity high shown by the regional work of Bonini and Lavin (1957). It was not planned to cover any specific area, but rather to let the observed anomalies determine the course of the field work. The study was undertaken as part of a project on Volcanism and Crustal Deformation, supervised by L. C. Pakiser of the U.S. Geological Survey. Professor Rodgers of the Geophysics Department of the Colorado School of Mines acted as an advisor.

Idaho↗

Water-quality data for two surface coal mines reclaimed with alkaline waste or urban sewage sludge, Clarion County, Pennsylvania, May 1983 through November 1989

Water-quality and other hydrologic data for two surface coal mines in Clarion County, Pa., were collected during 1983-89 as part of studies conducted by the U.S. Geological Survey in cooperation with the Pennsylvania Department of Environmental Resources. Water samples were collected from streams, seeps, monitor wells, and lysimeters on a monthly basis to evaluate changes in water quality resulting from the addition of alkaline waste or urban sewage sludge to the reclaimed mine-spoil surface. The mines are about 3.5 miles apart and were mined for bituminous coal of the upper and lower Clarion seams of the Allegheny Group of Pennsylvanian age. The coal had high sulfur (greater than 2 weight percent) concentrations. Acidic mine drainage is present at both mines. At one mine, about 8 years after mining was completed, large quantities (greater than 400 tons per acre) of alkaline waste consisting of limestone and lime-kiln flue dust were applied on two 2.5-acre plots within the 65-acre mine area. Water-quality data for the alkaline-addition plots and surrounding area were collected for 1 year before and 3 years after application of the alkaline additives (May 1983-July 1987). Data collected for the alkaline-addition study include ground-water level, surface-water discharge rate, temperature, specific conductance, pH, and concentrations of alkalinity, acidity, sulfate, iron (total and ferrous), manganese, aluminum, calcium, and magnesium. At the other mine, about 3.5 years after mining was completed, urban sewage sludge was applied over 60 acres within the 150-acre mine area. Waterquality data for the sludge-addition study were collected for 3.5 years after the application of the sludge (June 1986-December 1989). Data collected for the sludge-addition study include the above constituents plus dissolved oxygen, redox potential (Eh), and concentrations of dissolved solids, phosphorus, nitrogen species, sulfide, chloride, silica, sodium, potassium, cyanide, arsenic, barium, boron, cadmium, chromium, copper, lead, mercury, molybdenum, nickel, selenium, strontium, and zinc. Climatic data, including monthly average temperature and cumulative precipitation, from a nearby weather station for the period January 1983 through December 1989 also are reported.

Open-File Report↗

Geologic map of Kundelan ore deposits and prospects, Zabul Province, Afghanistan; modified from the 1971 original map compilations of K.I. Litvinenko and others

This map and cross sections are redrafted modified versions of the Geological map of the Kundelan ore deposit area, scale 1:10,000 (graphical supplement no. 18) and the Geological map of the Kundelan deposits, scale 1:2,000 (graphical supplement no. 3) both contained in an unpublished Soviet report by Litvinenko and others (1971) (report no. 0540). The unpublished Soviet report was prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan in Kabul during 1971. This redrafted map and cross sections illustrate the geology of the main Kundelan copper-gold skarn deposit, located within the Kundelan copper and gold area of interest (AOI), Zabul Province, Afghanistan. Areas of interest (AOIs) of non-fuel mineral resources within Afghanistan were first described and defined by Peters and others (2007) and later by the work of Peters and others (2011a). The location of the main Kundelan copper-gold skarn deposit (area of this map) and the Kundelan copper and gold AOI is shown on the index map provided on this map sheet. The estimated resources of the Kundelan copper-gold skarn deposit are 21,400 metric tons (t) of copper, 1.6 t of gold, and 133.4 t of molybdenum at an average grade of 1.21 weight percent (wt. %) copper (ranging from 0.66 to 4.03 wt. % copper); 0.9 grams per metric ton (g/t) gold (ranging from 0.3 to 3.1 g/t gold); 0.14 wt. % molybdenum; and as much as 10 g/t silver and 0.03 wt. % bismuth (Peters and others, 2011b). Small past production of gold and base metals is also reported by Douvgal and others (1971) from many prospects within the Kundelan copper and gold AOI. Outside the skarn areas, argillic hydrothermal alteration is present (Abdullah and others, 1977). Most copper and gold prospects in the Kundelan copper and gold AOI are reported to contain commercial-grade ores of copper and (or) gold, and many prospect areas have potential for these commodities to be discovered in commercial volumes. Future initial mine exploration and later development in many of the prospects, and specifically in the Kundelan copper-gold skarn deposit, could result in near-term small- to medium-sized gold mining operations (Peters and others, 2011b). The redrafted map and cross sections reproduce the topology of rock units, contacts, faults, and so forth, of the original Soviet map and cross sections, and they include modifications based on our examination of these documents and our observations made during a brief field visit in August of 2010. We have attempted to translate the original Russian terminology and rock classifications into modern English geologic usage as literally as possible without changing any genetic or process-oriented implications in the original descriptions. We also use the age designations from the original Soviet maps, except for the phase I and II intrusive igneous rocks. Phase I and II igneous rocks are reassigned an Early Cretaceous age (from lower Paleogene) based on a uranium-lead (U-Pb) zircon SHRIMP analysis from quartz diorite, which yielded an age of 104±1 Ma (mega-annum). The information provided in the description of map units is from both the source report by Litvinenko and others (1971) and the original 1:10,000 scale map (graphical supplement no. 18), also from Litvinenko and others (1971). Because of the poor quality of the original map, some map features could not be identified and some features may be misinterpreted. The rock unit colors used on the redrafted maps and cross sections differ from the colors shown on the original Soviet version. Colors were selected according to the color and pattern scheme of the Commission for the Geological Map of the World (CGMW) at http://www.ccgm.org. Elevations on the cross sections are derived from the original Soviet topography and may not match the Global Digital Elevation Model (GDEM) topography used on the redrafted map of this report. Most hydrography derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) has not been included on our redrafted version of the map because of a poor fit with alluvial deposits from the unmodified original Soviet map (graphical supplement no. 18; Litvinenko and others, 1971).

Zabul Province↗