USGS ScienceSearch

SEARCH · USGS Science

Results for “Journal of Analytical and Applied Pyrolysis”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,688 records · Page 50Linked to original sources

A comprehensive geologic framework of the National Crustal Model for seismic hazard studies in the conterminous United States

A three-dimensional (3D) geologic framework has been developed for the conterminous United States (U.S.) as part of the U.S. Geological Survey National Crustal Model to enhance seismic hazard modeling. The geologic framework is created from geologic maps and multiple subsurface geologic unit boundaries including the base of the Miocene, Cenozoic, Phanerozoic, and the Mohorovičić discontinuity. Modifications are made to surficial geologic maps to remove discontinuities across state and country borders. The subsurface distribution of rock type and age is extrapolated from the surface, seeded with subsurface geologic information, and constrained by a map of basement geology. The framework provides the basis for estimates of subsurface seismic velocity and density that is needed to improve estimates of earthquake ground shaking and seismic hazard. The present framework greatly expands and updates a previously published 3D geologic framework of the western part of the U.S. that was itself a first-of-its-kind digital 3D portrayal of the nation.

conterminous United States

Estimation of parental abundance using hierarchical Bayesian modeling with data augmentation

Pedigree-based estimation methods leverage the fact that each offspring in a cohort is genotypically “marked” by its parents and represent a recent and promising toolset for estimating population dynamics. This includes pedigree accumulation estimators that model the “accumulation” of inferred unique parents within a given cohort to estimate parental abundance. Unlike close-kin mark-recapture approaches, which rely on intercohort comparisons, pedigree accumulation modeling can be completed solely using intracohort samples. This is particularly advantageous for semelparous species, where intercohort pairs are impossible and adult life stages can be difficult to sample without affecting their likelihood of successfully reproducing. Previous work has evaluated a range of estimators for such datasets, concluding that the non-parametric Chao estimator provides the most accurate and precise estimates for feasible levels of sampling effort. We used simulated data to evaluate an alternative estimator based on hierarchical modeling and data augmentation in a Bayesian framework. Results indicate that estimates from the hierarchical Bayesian estimator had comparable accuracy and better precision than both the previously tested Chao1 estimator and the improved iChao formulation across a range of sample sizes and sex ratios. Furthermore, the Bayesian estimator was far more robust to simulated errors in pedigree reconstruction, especially the presence of false negatives. Hierarchical Bayesian pedigree accumulation models can also provide additional insight into underlying reproductive ecology through their use of an explicit observation process, allowing for the incorporation or estimation of species- and population-specific reproductive dynamics. More broadly, the parametric nature of these models offers opportunities to efficiently pool information among datasets as well as to propagate uncertainty within more complex models.

Ecology and Evolution

Site response and wave propagation effects in the eastern United States

Fourier amplitude spectra from regional earthquakes in the eastern United States are used in a parametric inversion for source, path, and site effects. Five earthquakes are selected for analysis during the installation of the United States National Seismic Network (US), Earthscope’s USArray Transportable Array (TA), and other temporary arrays to maximize station coverage. A global search algorithm is used to solve for site response from 0.1 to 15 Hz, corner frequency, geometrical spreading ( r - γ ), and frequency dependent anelastic attenuation in the form Q(f) = Q o f α . Tradeoff between moment and geometric spreading is handled by fixing the moment. The tradeoff between corner frequency and Q(f) is solved by selecting the value of corner frequency that minimizes an objective function defined over all stations. Values of site response and attenuation parameters show a strong spatial correlation with the physiographic provinces of the eastern United States. Site response for the Atlantic Coastal Plain is consistent with previous work using spectral ratios relative to a reference site, defined by strong resonance peaks correlated with the thickness of sediments. Site response for the other physiographic provinces is markedly different from the coastal plain, with a lack of distinct resonance peaks and a broad moderate high at frequences from 0.1 to 0.5 Hz consistent with the hard-rock geology of the regions. Like site response, Q(f) has a strong correlation with physiographic province, showing lower values on the coastal plain and higher values inland. Geometric spreading exponent, γ, decreases with increasing hypocenter distance from just above 1 at a few tens of kilometers to 0.9 at 500 km. The limited range in geometric spreading values is attributed to starting the Fourier transform window at the S ‐wave arrival for all distances and averaging over multiple wave types.

eastern United States

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Mid-Cretaceous porphyritic magmatism in the Beartooth Mountains of the northern Laramide foreland and its connection to Frontier Formation sediment dispersal in Bighorn basin, Montana-Wyoming (USA), and Cordilleran tectonism

Porphyritic intrusions in the southeast Beartooth Mountains and porphyritic cobbles from the Torchlight conglomerate of the Cenomanian Frontier Formation in Bighorn basin (Montana-Wyoming, USA) bear striking resemblance. We utilize geologic mapping, petrography, geochemistry, and geochronology to characterize rocks from both locations and test whether the Beartooth Mountains area was the provenance for Bighorn basin cobbles. Mapping on Line Creek Plateau in the Beartooth Mountains shows three units with porphyritic phenocrysts consisting dominantly of plagioclase, plagioclase + potassium feldspar, and plagioclase + quartz. Petrography shows embayed quartz, opacitic rims, and zoned plagioclase. Geochemistry characterizes the intrusions as trachydacite to trachyte and trace elements exhibit enrichment in light rare earth elements and slight depletion in heavy rare earth elements relative to primitive mantle. Zircon U-Pb dating shows substantial Archean inheritance and ca. 104−92 Ma dates; some samples display multiple mid-Cretaceous date populations. Bighorn basin porphyritic cobbles exhibit similar modal mineralogy, near-identical geochemistry, and Archean inheritance and mid-Cretaceous geochronology. We suggest the porphyritic cobbles were sourced from basement-hosted porphyritic intrusions now exposed in the Beartooth Mountains, given that geochemistry does not agree with coeval volcanic sources along the Frontier Formation depositional fairway (Idaho batholith) or sedimentary-hosted Beartooth Mountains porphyritic sills intruded into Cambrian shale. Stratigraphic evidence does not support kilometer-scale mid-Cretaceous Beartooth Mountains exhumation to expose basement-hosted porphyritic intrusions, and we therefore present a volcanic hypothesis to bring rocks to the surface. This mid-Cretaceous multimillion-year magmatism is unexplained by tectonic models for the north-central Laramide foreland, and thus we further explore the emplacement processes, spatiotemporal significance, and tectonic implications of these rocks.

Montana, Wyoming

Anatectic origin of Mississippian spodumene-bearing pegmatites in western Maine during orogenic plateau collapse

Spodumene pegmatites are an important lithium source, but the processes and tectonic settings in which they form are poorly understood. The Rumford pegmatite district surrounding Plumbago Mountain, western Maine, is host to numerous spodumene pegmatites, including the Plumbago North pegmatite (a world-class spodumene resource). Competing petrogenetic models for these spodumene pegmatites include (1) highly fractionated melts of the Mooselookmeguntic igneous complex and (2) anatexis. We tested these hypotheses by constraining the geologic, magmatic, metamorphic, and tectonic history of the Plumbago Mountain area with detailed geologic mapping and U-(Th)-Pb geochronology. The Silurian Rangeley Formation records initial isoclinal folding prior to, and contact-related metamorphism synchronous with, the intrusion of the 417 ± 4 Ma Plumbago Mountain pluton. Peak amphibolite facies metamorphism and crustal melting occurred during the ca. 410 to 400 Ma Acadian orogeny. Pulsed emplacement of the Mooselookmeguntic igneous complex occurred between ca. 389 and 356 Ma. Cassiterite U-Pb dates of spodumene pegmatites (333–327 Ma) are ≥23 m.y. younger than nearby granitic plutons, strongly arguing against the fractional crystallization model. Metamorphic monazite and xenotime (346–328 Ma) and 330 to 308 Ma 40 Ar/ 39 Ar hornblende dates indicate metamorphism coeval with spodumene pegmatite emplacement, supporting anatectic models. Reheating, anatexis, and spodumene pegmatite emplacement occurred during collapse of the 380 to 330 Ma Acadian orogenic plateau. Lithium enrichment may be linked to one or more stages of partial melting of metasedimentary and plutonic rocks during the formation, tenure, and collapse of the Acadian altiplano and emphasizes the role of anatexis in producing spodumene pegmatites of economic significance.

Maine

Estimating the probability of export restrictions to inform mineral criticality

To assess risks associated with advanced technologies’ supply chain disruptions, governmental agencies and others have developed mineral “criticality” assessments, with criticality described using the economic impact and probability of supply chain disruptions. Previous work developed subjective supply risk indicators to approximate this probability, typically combining several factors such as supply diversity and trading partners’ political stability, where indicator weightings can substantially impact results. This work explicitly quantifies export barrier probability using an ensemble of machine learning classifiers, with probability estimates informed by exogenous variables, including prior barrier implementation and global export dominance. Major differences in high-probability countries and commodities are observed across models, but the ensemble method highlights Indonesia, China, Tanzania, and the United States as particularly high risk. The Supplementary Data File provides export barrier probability estimates for each analyzed country-commodity pair, enabling a direct, quantitative, objective contribution to assessing mineral criticality, enhancing risk identification and prioritization for policymakers.

Resources, Conservation, and Recycling

Hydrogeologic investigation, framework, and conceptual flow model of the Antlers aquifer, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statute §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. Every 20 years, the Oklahoma Water Resources Board is required to update the hydrologic investigation on which the maximum annual yield determinations were based. The maximum annual yield allocated per acre of land is used to set the equal-proportionate share pumping rate. The maximum annual yield of 5,913,600 acre-feet per year and equal-proportionate-share of 2.1 acre-feet per acre per year currently (2025) in place for the Antlers aquifer were issued by the Oklahoma Water Resources Board on February 14, 1995. Because more than 20 years have elapsed since the 1995 final order for the Antlers aquifer was issued, the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, completed an in-depth hydrologic study that included a hydrogeologic framework and conceptual groundwater-flow model for the 1980–2022 study period. The results of an analysis of land use, long-term climate patterns, streamflow and base-flow patterns, historical groundwater use, as well as groundwater-level fluctuations across the Antlers aquifer are described. In addition, groundwater quality was analyzed for total dissolved solids concentrations and major ions for the Antlers aquifer. An updated hydrogeologic framework was developed that included refining the aquifer boundary in Oklahoma, the creation of new potentiometric surface and saturated thickness of fresh groundwater maps, one multiple-well aquifer test, slug tests, and an analysis of lithologic logs across the aquifer. A conceptual groundwater flow model and water budget were developed by incorporating estimates of recharge from precipitation, saturated-zone evapotranspiration, streambed seepage, lateral groundwater flows, vertical leakage, and withdrawals from groundwater wells.

Oklahoma, Texas

Leveraging wildfire to augment forest management and amplify forest resilience

Successive catastrophic wildfire seasons in western North America have escalated the urgency around reducing fire risk to communities and ecosystems. In historically frequent-fire forests, fuel buildup as a result of fire exclusion is contributing to increased fire severity. The probability of high-severity fire can be reduced by active forest management that reduces fuels, prompting federal and state agencies to commit significant resources to increase the pace and scale of fuel reduction treatments. However, lower severity areas of wildfires also have the potential to act as “treatments,” and even catastrophic fires with large areas of high severity can still have substantial areas of lower severity fire that may be improving forest conditions locally. We quantified active management and wildfire severity across yellow pine and mixed conifer (YPMC) forests in the Sierra Nevada of California over a 22-year period (2001–2022). We did not detect increases in the area treated through time, but the area of beneficial wildfire (low to moderate severity) increased substantially, exceeding active treatment area in 8 of 22 years. Overall, beneficial wildfire treated ~17% more area than all treatments combined, and roughly four times more area than fire-related treatments alone. We then used disturbance history to evaluate resistance to high-severity wildfire and forest loss across the YPMC range. Of the 2.3 million ha YPMC of forests in 2001, 20% lost mature forests due to high-severity fire by 2022, which is nearly half of all YPMC area burned. Most of the landscape (47%) remains at risk of high-severity fire because it had no restorative disturbances, but 33% of the study area has some level of resistance to high-severity wildfire. In these areas, resistance will need to be enhanced and maintained over time via active management or managed wildfire, but these treatment needs will likely outpace capacity even under optimistic implementation scenarios. Given limited resources for implementing active management and the likelihood of a more fiery future, incorporating beneficial wildfire into landscape-level treatment planning has the potential to amplify the impact of active management treatments.

California, Nevada

Evaluation of water quality in the Langford Valley–Irwin Groundwater Subbasin, Fort Irwin National Training Center, California, 1993–2019

The U.S. Army Fort Irwin National Training Center (NTC), 120 miles northeast of Los Angeles in the Mojave Desert of California, obtains its potable water supply from the Bicycle Valley and Langford Valley groundwater basins; Langford Valley groundwater basin is further subdivided into the Langford Well Lake and Irwin groundwater subbasins. The Irwin groundwater subbasin contains younger, unconsolidated deposits that have a saturated thickness of as much as 200 feet (ft) and a lower aquifer within older unconsolidated deposits as thick as 650 ft. Groundwater recharge under predevelopment conditions (before 1941) occurred primarily from infiltration of intermittent streamflow in small washes that cross the Irwin groundwater subbasin. Since that time, groundwater recharge has increased because of growth of the NTC in recent years and as a result of other processes, including (1) infiltration of treated wastewater into the aquifer through ponds near the NTC wastewater treatment facility (WWTF) and (2) infiltration of imported water and treated wastewater used for landscape irrigation at base housing and athletic fields. Water samples were collected from 17 wells and analyzed for field parameters, chemical constituents, and isotope composition in the Irwin groundwater subbasin between 2014 and 2019. These data were supplemented with water-chemistry data collected during 1993–95 and at other times if available. Between 1993–95 and 2015–19, median dissolved solids and nitrate concentrations in water from wells in the Irwin groundwater subbasin increased from 620 to 1,030 milligrams per liter (mg/L) and from 2.8 to 4.5 mg/L as nitrogen, respectively. After 2014, dissolved solids and nitrate concentrations in water from wells near the NTC WWTF decreased as a result of changes in source water quality attributable to reverse osmosis of treated drinking water delivered within the Irwin groundwater subbasin and to increased levels of treatment at the NTC WWTF. Based on delta oxygen-18 and delta deuterium isotope data, increases in dissolved solids concentrations in water from most wells were consistent with evaporation prior to recharge and mobilization of soluble salts from the unsaturated zone. Arsenic and fluoride concentrations in water from wells decreased between 1993–95 and 2015–19 as the basin filled with treated wastewater, but 2015–19 concentrations generally exceeded the California State Water Resources Control Board maximum contaminant levels of 10 micrograms per liter for arsenic and 2 mg/L for fluoride. Most groundwater in the Irwin groundwater subbasin has unadjusted carbon-14 ages ranging from 18,400 to 12,350 years before present. However, water from well 10E3, located along the wash near the subbasin outflow in the southeastern part of the Irwin groundwater subbasin, contained measurable tritium, which is consistent with infiltration of intermittent streamflow and groundwater recharge from the wash after 1952. Chemical and isotopic data indicate that treated wastewater is present in water from most wells in the upper aquifer that underlies the Irwin groundwater subbasin. Wells were not sampled to adequately determine the extent of treated wastewater and changes in water quality within the lower aquifer that underlies the Irwin groundwater subbasin.

California

Estimating habitat availability for Chinook salmon (Oncorhynchus tshawytscha) and steelhead (O. mykiss) to inform reintroduction planning in the middle Snake River basin, USA

Anadromous fishes have been blocked from the middle Snake River basin since the construction of flood control, irrigation, and hydroelectric projects during the 19 th and 20 th centuries, culminating with the construction of Hells Canyon Dam (river kilometer [rkm] 398) in 1967. Seven large watersheds in the blocked area of the basin are under consideration for Pacific salmon reintroduction. The primary objective of this study was to identify and characterize potential reintroduction sites with high-quality rearing and spawning habitat for Chinook salmon ( Oncorhynchus tshawytscha ) and steelhead ( O. mykiss ) upstream of the Hells Canyon Complex in Idaho, Oregon, and Nevada, USA. We created and tested habitat models to predict rearing presence/absence, rearing abundance, and spawning presence/absence using channel morphology, hydrology, and stream temperature variables obtained from regional peer-reviewed datasets. Habitat models were trained with salmonid presence and abundance records collected in the lower Snake River basin (downstream of Hells Canyon Dam), where anadromous fish can currently access, from 1993 to 2011. Model performance was tested with set-aside data comprised of randomly selected reaches and independent environmental DNA data. An index model was created in the middle Snake River basin for each species by combining results from the habitat models. Modeling covariates differed by species and life stage and included different combinations of August stream temperature, summer flow, channel slope, and quadratic terms for temperature and slope. The habitat models predicted high versus low Chinook salmon and steelhead probability and abundance with 66% to 85% accuracy depending on species and life stage. The index models predicted a total of 2,887 km of Chinook salmon habitat and 2,434 km of steelhead habitat in the blocked area. The three basins in the blocked area with the greatest amount of predicted habitat were the Powder River, South Fork Payette River, and North Fork Payette River for Chinook salmon, and the Powder River, South Fork Boise River, and South Fork Payette River for steelhead. The modeling approach presented here is complementary to other planning efforts for Chinook salmon and steelhead reintroduction in the blocked area of the Snake River basin, and similar approaches may be useful for reintroduction planning in other systems.

Idaho, Nevada, Oregon, Utah, Washington, Wyoming

Preliminary field report of landslide hazards following Hurricane Helene

Executive Summary This report reflects our knowledge regarding the widespread landslide activity associated with Hurricane Helene observed during the U.S. Geological Survey’s (USGS) mission assignment to North Carolina in October 2024. The material in this report was originally prepared for the Federal Emergency Management Agency under mission assignment DR-4827-NC. The data and commentary in this report are reflective of a report provided to the Federal Emergency Management Agency (FEMA) on October 18, 2024, as well as information provided in briefings at the Buncombe County Emergency Operations Center. The report has been modified for public dissemination. This assessment was based on systematic visual examination and mapping of landslide locations from aerial and satellite imagery, visual and photographic observations from low-level helicopter overflights and conversations with local landslide experts from the North Carolina Geological Survey and Appalachian Landslide Consultants PLLC, and more than 50 years of combined landslide hazard professional experience of the mission-assigned field team. No systematic field investigations were done by the USGS. While responding to the event, the USGS did not identify any landslides that posed an immediate major threat to recovery personnel in parts of nine counties in North Carolina (Avery, Buncombe, Henderson, McDowell, Mitchell, Polk, Rutherford, Watauga, and Yancey); however, threats from renewed landslide activity may remain heightened in localized areas for months or even years. Known areas of the most abundant landslide occurrence include Bat Cave, Lake Lure, Chimney Rock, Swannanoa, Black Mountain, Fairview, steep areas in Asheville, and the Blue Ridge Parkway. The USGS shared detailed locations of known landslides with the Emergency Operations Centers. The thousands of landslide scars on hillsides and landslide deposits on flatter ground may present some threat to recovery activities. Soil and rocks will continue to erode from newly exposed landslide scars and may pose a threat to people and infrastructure who are immediately nearby. In general, the steeper and taller the landslide scar, the greater the potential threat. This threat is heightened during periods of rainfall and increases with the duration and intensity of rainstorms. Very heavy rainfall, or repeated rainfall events during short periods, could also initiate new landslides on steep slopes. Excavation of landslide deposits, particularly excavation of those deposits directly adjacent to steep slopes, may also pose a threat to nearby people and equipment. An interagency collaborative mapping effort led by the USGS that informed this assessment identified 1,155 landslide locations by the October 2024 briefings, but that number increased to 2,217 in a final reviewed version of the locations published in January 2025. Locations were mapped from satellite imagery, fixed-wing and helicopter surveys, media and social media, and field reports in the 3 weeks following the passage of the remnants of Hurricane Helene. USGS products outlined in this report are publicly available and include geotagged photographs from aerial reconnaissance, hazard models, an interactive view of mapped landslide locations, and landslide safety and education resources.

North Carolina, South Carolina, Tennessee, Virgini

Geochemical evidence for the origin of late Quaternary loess, Seward Peninsula, Alaska

Loess is the most widespread surficial deposit in the state of Alaska. Although loess of last glacial age is common in mid-continental North America, records of last glacial loess in Alaska have been elusive. Here we report a record of last glacial loess on the Seward Peninsula, along with studies of a transect of loess localities also thought to date to the last glacial period. Highly diverse hypotheses on the origin of loess on the Seward Peninsula include local volcanic rocks and mountain ranges to the north and south, as well as offshore deposits. We present particle size and mineralogical and geochemical data that indicate that the most likely sources for loess in this part of eastern Beringia are glaciogenic silt particles of the Kobuk River and Noatak River, both of which drain the Brooks Range to the northeast. Northeasterly paleowinds were therefore responsible for loess on the Seward Peninsula. Such winds probably occurred during late summer or early autumn, when river discharge was at a minimum but temperatures were still above freezing. Northeasterly winds during the last glacial period are in good agreement with a recent paleoclimate model.

Alaska

Coastal barrier resilience and resistance: Analysis and metrics for characterizing coastal state

Barrier islands are shaped by a variety of short- and long-term environmental processes such as storms and relative sea-level rise. These islands, found along the estuarine-marine interface, provide ecosystem services including storm surge and wave attenuation, erosion protection to inland marshes, habitat for fish and wildlife, and recreation. Natural resource managers require actionable information on how barrier island resilience and resistance changes over time to understand how an island’s current state relates to past conditions and to inform restoration prioritization and implementation. The U.S. Geological Survey and The Water Institute collaborated on a study to develop indicators of resilience and resistance for barrier islands in Louisiana. Here, resilience captures island persistence on yearly to decadal time scales, and resistance captures persistence on event time scales of days to weeks. The indicators fall in two categories: Tier 1 Screening Metrics, that can be readily calculated from available data, are easily interpretable as an evaluation of barrier condition, and provide a high-level snapshot of overall barrier resilience and resistance; and Tier 2 Analysis Metrics, which are detailed metrics that required specialized analysis and interpretation and are more applicable to answering specific questions managers may have about barrier state. The research team derived Tier 1 resilience indicators from subaerial land and vegetation cover calculated from publicly available maps and products based on satellite imagery. By benchmarking the total land and vegetation extent against their respective historical maxima, this metric provides a snapshot of an island’s current state in the context of its long-term trajectory. The research team developed Tier 1 resistance indicators based on subaerial island configuration and water level recurrence as a proxy for evaluating island resistance to storms, which are the primary driver of short-term change. These Tier 1 metrics can be analyzed over time to provide a high-level assessment of how an island’s resistance decreases because of elevation loss or sea-level rise or increases due to restoration or natural recovery. The research team developed Tier 2 resilience and resistance indicators and associated analyses to provide detailed information for specific time periods or applications (e.g., wildlife management). These metrics include habitat coverage from high-resolution maps, which show composition changes over time to capture the evolving resilience of specific habitat types; high tide flooding analysis, which evaluate island area relative to specified flooding thresholds to characterize resistance in the short-term or, if analyzed over time, indicate changes in resilience; and hypsometric curve analysis, which allows managers to evaluate island area changes above their own elevation benchmarks of interest and similarly characterize resistance in the short-term or indicate changes in resilience if assessed over time. The research team calculated Tier 1 metrics of the barrier islands and headlands along the coast of Louisiana for the period of 1984 through 2021 and Tier 2 metrics for select times during that period depending on data available and quality. The results were captured in a report card for each barrier, which also includes an overview of the metrics and their interpretation; a restoration and storm history; and Tier 1 and Tier 2 metric analysis, including benchmarking against coastwide and regional values as well as to an island’s pre-restoration trajectory. These report cards provide a readily digestible synthesis of barrier condition and trajectory that coastal managers can use to support restoration prioritization and other decisions.

Louisiana

Climate change and future water availability in the United States

The steady rise in global temperature as a result of human activity is causing changes in Earth’s water cycle. The balance of water stored within and moving between vapor, liquid, and frozen states in the water cycle is shifting, with consequences for water availability that include increases in drought, fire weather, flooding, and heavy precipitation, as well as cryosphere decline and sea-level rise. In this chapter of the U.S. Geological Survey Integrated Water Availability Assessment—2010–20, we provide an overview of climate-change observations and projections from Earth-system model simulations that relate to future water availability, from global and national climate assessments and from the published literature. Effects of climate change on primary water-cycle components are discussed in context of how global-scale hydroclimate drivers influence regional processes within the United States. Understanding the major climate drivers impacting the water cycle is crucial to predicting future changes in water availability and developing adaptation strategies to ensure human and ecosystem water supplies. First, we provide background information on the water cycle, the climate-model ensemble simulations developed to produce projections based on warming scenarios, and attribution and certainty levels. Tipping points, self-reinforcing feedbacks, cascading effects, and compound extremes are introduced. The framework of climatic impact drivers (CIDs) outlined in the Intergovernmental Panel on Climate Change Sixth Assessment Report (IPCC AR6) is used to show primary drivers of physical change to the water cycle and to understand and predict changes in future water availability. Specific climate-change related observations and projections are discussed for water cycle components of precipitation, evapotranspiration, soil moisture, streamflow, lakes and wetlands, ice and snow, and groundwater, as well as their implications for future water availability for humans and ecosystems. The chapter concludes with a synthesis discussion of three examples of complex regional-scale hydroclimate processes that influence water availability for populations in the United States, including (1) mountain and coastal precipitation, (2) aridification and drought, and (3) the influence of forest-cover change on terrestrial water-vapor recycling.

Professional Paper

Geology, mineralogy, and cassiterite geochronology of the Ayawilca Zn-Pb-Ag-In-Sn-Cu deposit, Pasco, Peru

The Ayawilca deposit in Pasco, Peru, represents the most significant recent base-metal discovery in the central Andes and one of the largest undeveloped In resources globally. As of 2018, it hosts an 11.7 Mt indicated resource grading 6.9% Zn, 0.16% Pb, 15 g/t Ag, and 84 g/t In, an additional 45.0 Mt inferred resource grading 5.6% Zn, 0.23% Pb, 17 g/t Ag, and 67 g/t In, and a separate Sn-Cu-Ag inferred resource of 14.5 Mt grading 0.63% Sn, 0.21% Cu, and 18 g/t Ag. Newly obtained U–Pb dates for cassiterite by LA-ICP-MS (22.77 ± 0.41 and 23.05 ± 2.06 Ma) assign the Ayawilca deposit to the Miocene polymetallic belt of central Peru. The polymetallic mineralization occurs as up to 70-m-thick mantos hosted by carbonate rocks of the Late Triassic to Early Jurassic Pucará Group, and subordinately, as steeply dipping veins hosted by rocks of the Pucará Group and overlying Cretaceous sandstones-siltstones of the Goyllarisquizga Group. Relicts of a distal retrograde magnesian skarn and cassiterite (stage pre-A) were identified in the deepest mantos. The volumetrically most important mineralization at Ayawilca comprises a low-sulfidation assemblage (stage A) with quartz, pyrrhotite, arsenopyrite, chalcopyrite, Fe-rich sphalerite, and traces of stannite and herzenbergite. Stage A sphalerite records progressive Fe depletion, from 33 to 10 mol% FeS, which is compatible with the observed transition from low- to a subsequent intermediate-sulfidation stage (B) marked by the crystallization of abundant pyrite and marcasite. Finally, during a later intermediate-sulfidation stage (C) sphalerite (up to 11 mol% FeS), galena, native bismuth, Cu-Pb-Ag sulfosalts, siderite, Mn-Fe carbonates, kaolinite, dickite, and sericite were deposited. This paragenetic evolution shows striking similarities with that at the Cerro de Pasco Cordilleran-type polymetallic deposit, even if at Ayawilca stage C did not reach high-sulfidation conditions. The occurrence of an early retrograde skarn assemblage suggests that the manto bodies at Ayawilca formed at the transition between distal skarn and skarn-free (Cordilleran-type) carbonate-replacement mineralization. Mineral assemblages define a T- f S 2 evolutionary path close to the pyrrhotite-pyrite boundary. Buffering of hydrothermal fluids by underlying Devonian carbonaceous phyllites of the Excelsior Group imposed highly reduced conditions during stage A mineralization (log f O 2 < − 30 atm). The low f O 2 favored efficient Sn mobility during stages pre-A and A, in contrast to other known ore deposits in the polymetallic belt of central Peru, in which the occurrence of Sn minerals is minor. Subsequent cooling, progressive sealing of vein walls, and decreasing buffering potential of the host rocks promoted the shift from low- (stage A) to intermediate-sulfidation (stages B and C) states. LA-ICP-MS analyses reveal significant In contents in Fe-rich sphalerite (up to 1.7 wt%), stannite (up to 1908 ppm), and chalcopyrite (up to 1185 ppm). The highest In content was found in stage A sphalerite that precipitated along with chalcopyrite and stannite, thus pointing to the early, low-sulfidation assemblage as prospective for this high-tech metal in similar mineral systems. Indium was likely incorporated into the sphalerite crystal lattice via Cu + + In 3+ ↔ 2 Zn 2+ and (Sn, Ge) 4+ + (Ga, In) 3+ + (Cu + Ag) + ↔ 4 Zn 2+ coupled substitutions. Indium incorporation mechanisms into the stannite and chalcopyrite crystal lattices remain unclear.

Pasco

Deformation mechanisms in quartz veins and shear zones elucidate the origin of gold mineralization at Pogo, Alaska

Pogo is a quartz vein hosted, ca. 8 Moz gold deposit. Although it has similarities to orogenic and magmatic-hydrothermal deposits, its origin remains enigmatic. Observations from surface exposures, underground workings, and drill core provide new constraints on quartz vein origins with implications for mineralization. Abundant, largely barren metamorphic segregation quartz veins are found throughout interior Alaska and share characteristics with mineralized quartz veins at Pogo. Pogo quartz veins show crystal plastic deformation fabrics consistent with greenschist to amphibolite facies metamorphism and a lack of internal shear. In contrast, gold in Pogo quartz veins occurs in brittle microfaults and fractures with sulphides such as arsenopyrite and pyrrhotite. Major and minor cataclastic shear zones also exist at Pogo. Cataclastic shear zones commonly cut the mineralized quartz veins and porphyroclasts are dominated by quartz with the same plastic deformation fabrics found in the major Pogo quartz veins. The porphyroclasts, and the carbonaceous clay-rich matrix they sit in, also contain gold indicating that the shear zones postdate quartz and earliest gold deposition. These observations suggest that competency contrasts between the quartz veins and their phyllosilicate-rich host rocks controlled transient permeability formed by late, preferential brittle deformation events localizing sulphide ± gold deposition.

Alaska

Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington