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At least 901 records · Page 50Linked to original sources

Reconnaissance of the water resources of Beaver County, Oklahoma

Ground water is the major source of water supply in Beaver County. Because of the rapidly increasing demand for the limited supply of water for irrigation, additional geologic and hydrologic data are needed for management of ground-water resources. This report presents general information on the availability of ground water, on the chemical quality of water, and on streamflow. The chemical quality of water generally is poorer than that of water elsewhere in the Oklahoma Panhandle, and the ability to obtain good quality water may become increasingly difficult as the water resources are developed. Further studies are needed to determine the annual change in water levels, the rate of water-level decline in heavily pumped areas, the volume of water stored in the ground-water reservoir, and the quantity of water that may be withdrawn safely in a given area.

Oklahoma↗

Hydrology and cycling of nitrogen and phosphorus in Little Bean Marsh: A remnant riparian wetland along the Missouri River in Platte County, Missouri, 1996–97

The lack of concurrent water-quality and hydrologic data on riparian wetlands in the Midwestern United States has resulted in a lack of knowledge about the water-quality functions that these wetlands provide. Therefore, Little Bean Marsh, a remnant riparian wetland along the Missouri River, was investigated in 1996 and 1997 primarily to determine the magnitude and character of selected water-quality benefits that can be produced in such a wetland and to identify critical processes that can be managed in remnant or restored riparian wetlands for amelioration of water quality. Little Bean Marsh averages 69 hectares in size, has a maximum depth of about 1 meter, and the majority of the marsh is covered by macrophytes. In 1997, 41 percent of the water received by Little Bean Marsh was from direct precipitation, 14 percent was from ground-water seepage, 30 percent from watershed runoff, and 15 percent was backflow from Bean Lake. Although, Little Bean Marsh was both a ground-water recharge and discharge area, discharge to the marsh was three times the recharge to ground water. Ground-water levels closely tracked marsh water levels indicating a strong hydraulic connection between ground water and the marsh. Reduced surface runoff and ground-water availability are stabilizing influences on marsh hydrology and probably contribute to the persistence of emergent vegetation. The rapid hydraulic connection between Little Bean Marsh and ground water indicates that the hydrologic regime of most wetlands along the lower Missouri River is largely a function of the altitude of the marsh bottom relative to the altitude of the water table. More water was lost from the marsh through evapotranspiration (59 percent) than all other pathways combined. This is partially because the transpiration process of abundant macrophytes can greatly contribute to the evapotranspiration above that lost from open water surfaces. Surface outflow accounted for 36 percent and ground-water seepage accounted for only 5 percent of the losses. Large residence times allows the marsh to greatly affect water quality before water escapes as ground-water recharge or surface outflow. The shallowness of Little Bean Marsh and ion exclusion during ice formation caused the highest specific conductances of 1,100 to 1,300 microsiemens per centimeter at 25 degrees Celsius to occur during the winter. This concentration of dissolved solutes under ice can make wetlands more vulnerable to toxic contaminants than deeper surface-water bodies. Dissolved oxygen was less than 5 mg/L (milligrams per liter) for 3 to 4 months and near 0 mg/L for about 1 month in summer. Despite depths of less than 1 meter, temperature stratification persisted more than 3 months during the summers of 1996 and 1997, preventing mixing and contributing to periods of anoxia. Shallow depths and extended periods of anoxia in the marsh limit the ability of some organisms to escape high-temperature stress. Turbidity in Little Bean Marsh usually was low for several reasons: sediment loadings from the largely flood-plain drainage were low, emergent vegetation shade out algae and shield the water from wind, and high concentrations of bivalent cations increase flocculation rates of inorganic suspended material. The high concentrations of bivalent cations was largely because of a substantial amount of ground-water seepage into the marsh. Dissolved organic nitrogen was the dominant nitrogen species in Little Bean Marsh. Denitrification and biotic uptake kept more than 62 percent of nitrate (NO3) and 43 percent of ammonium (NH4) concentrations in marsh samples less than a detection limit of 0.005 mg/L. This contrasts with the Missouri River where inorganic NO3 dominates. Consequently, artificial flood-plain drainage that bypasses riparian wetlands likely deliver substantially more biotically available inorganic nitrogen to receiving waters than surface water that has been routed through a remnant wetland. Average total nitrogen concentrations in Little Bean Marsh were substantially less than those at other Missouri River wetlands, roughly one-half the mean concentrations in the Missouri River, but roughly twice the average nitrogen values in reservoirs of the glaciated plains of Missouri. The largest concentrations of nearly all species of nitrogen and phosphorus and the most intense period of hypereutrophy coincided with a phytoplankton bloom and senescence of River Bulrush (Scirpus fluviatilis) and common cattail (Typha latifolia) in September 1997. The rapid leaching of nitrogen that occurs soon after macrophyte senescence combined with a recent destratification of the marsh probably provided nitrogen to the nitrogen-limited open-water areas and triggered a phytoplankton bloom. Despite the rarity of runoff events, surface runoff from the watershed, combined with atmospheric deposition, contributed more than seven times the 530 kg (kilograms) of nitrogen that escaped Little Bean Marsh in surface outflow during 1997. Atmospheric deposition alone was more than 530 kg. Seepage to ground water contained less than 1.5 percent of the nitrogen leaving the marsh in surface outflow. The slow decay rate of Scirpus fluviatilis and reducing conditions in bottom sediments make burial of organic nitrogen a substantial sink of nitrogen. Denitrification experiments indicate that denitrification rates were limited by NO3 in the water column. Consequently, decomposition and nitrification of NH4 and organic nitrogen are the rate limiting steps of nitrogen removal in Little Bean Marsh. The NO3-limited rates of denitrification also indicate that Little Bean Marsh has a large unused capacity for nitrogen removal. These data indicate that the vast extent of riparian marshes along the Missouri and Mississippi Rivers may have had a substantial role in limiting NO3 loads to the Gulf of Mexico before agricultural development of flood plains. Drainage and removal of riparian marshes may be a major cause of the increased NO3 loads to the Gulf of Mexico. Periods of anoxia had much larger effects on phosphorus release than the other variables. The largest concentrations of phosphorus occurred in late summer and corresponded with senescing macrophytes, periods of anoxia, and a large algal bloom in Little Bean Marsh. Low water levels prevented the escape of phosphorus in surface outflow during these periods of highest phosphorus concentrations. Dry weather in late summer is typical and probably makes the correspondence of low water levels, anoxia, and consequent low phosphorus release a common occurrence in marshes along the Missouri River. Little Bean Marsh retained more than 95 percent of the phosphorus it received. The amount of phosphorus in surface inflows to the marsh were more than one order of magnitude greater than that escaping in surface outflows. The long hydraulic residence time of the marsh and large contributions of iron from ground water (that provide many sorption sites for phosphorus) make the marsh an effective sediment and phosphorus trap.

Missouri↗

Evaluation of ground-water flow and hydrologic budget for Lake Five-O, a seepage lake in northwestern Florida

Temporal and spatial distributions of ground-water inflow to, and leakage from Lake Five-O, a softwater, seepage lake in northwestern Florida, were evaluated using hydrologic data and simulation models of the shallow ground-water system adjacent to the lake. The simulation models indicate that ground-water inflow to the lake and leakage from the lake to the ground-water system are the dominant components in the total inflow (precipitation plus ground-water inflow) and total outflow (evaporation plus leakage) budgets of Lake Five-O. Simlulated ground-water inflow and leakage were approximately 4 and 5 times larger than precipitation inputs and evaporative losses, respectively, during calendar years 1989-90. Exchanges of water between Lake Five-O and the ground-water system were consistently larger than atmospheric-lake exchanges. A consistent pattern of shallow ground-water inflow and deep leakage was also evident throughout the study period. The mean time of travel from ground-water that discharges at Lake Five-O (time from recharge at the water table to discharge at the lake) was estimated to be within a range of 3 to 6 years. Flow-path evaluations indicated that the intermediate confining unit probably has a negligible influence on the geochemistry of ground-water inflow to Lake Five-O. The hydrologic budgets and flow-path evaluations provide critical information for developing geochemical budgets for Lake Five-O and for improving the understanding of the relative importance of various processes that regulate the acid-neutralizing capacity of softwater seepage lakes in Florida.

Florida↗

Modern accumulation rates and a sediment budget for the Eel shelf: a flood-dominated depositional environment

The northern California continental margin is periodically impacted by geologically significant storms, which have a marked influence on terrigenous sediment supply, flood deposition, and long-term accumulation of fine-grained sediment on the Eel shelf. Accumulation of Eel River muds on the adjacent shelf was investigated using 210Pb and 137Cs geochronologies, in order to understand the fate of sediment discharged by the Eel River and to relate patterns of net sediment accumulation (100-yr time scale) to sediment dynamics. 210Pb data demonstrate that modern accumulation of river mud occurs from the 50-m isobath seaward. Across-shelf accumulation rates decrease from maximum mid-shelf values of 0.6–1.7 g cm2 yr1 to values of 0.2–0.4 g cm2 yr1 at the shelf break, with a spatially weighted mean of 0.5 g cm2 yr1 (0.4 cm=yr) for the entire shelf. 210Pbxs sediment-depth profiles from the region of highest accumulation rate are characterized by subsurface intervals of low and uniform activity, which are produced by flood deposition. In some cores, particular 210Pbxs activity intervals may be associated with major Eel River floods of 1955, 1964, and 1974. It is postulated that, because of the coincidence of high-river-flow events and southerly winds during cyclonic winter storms, net northward transport allows for preferential deposition of fine-grained sediment north of the river mouth. Over the past ¾100 years, fluvial sediment input combined with marine dispersal processes have produced a mid-shelf depocenter, evident by both the spatial distribution of 210Pb accumulation rates and by clay-rich flood layers partially preserved in shelf deposits. A fine-grained sediment budget for the dispersal system, based on hydrological data and 210Pb geochronologies, demonstrates that a maximum of ¾20% (3 ð 109 kg=yr) of the mean annual supply of fluvial mud (14 ð 109 kg=yr) is trapped on the shelf. The results of this study demonstrate that: (1) short-term sedimentation processes associated with floods can influence sediment accumulation on longer time scales; and (2) a major fraction of fine-grained sediment supplied to tectonically active margins by flood-prone mountainous rivers bypasses narrow continental shelves.

Marine Geology↗

Evaluation of the effects of precipitation on ground-water levels from wells in selected alluvial aquifers in Utah and Arizona, 1936-2005

Increased withdrawals from alluvial aquifers of the southwestern United States during the last half-century have intensified the effects of drought on ground-water levels in valleys where withdrawal for irrigation is greatest. Furthermore, during wet periods, reduced withdrawals coupled with increased natural recharge cause rising ground-water levels. In order to manage water resources more effectively, analysis of ground-water levels under the influence of natural and anthropogenic stresses is useful. This report evaluates the effects of precipitation patterns on ground-water levels in areas of Utah and Arizona that have experienced different amounts of ground-water withdrawal. This includes a comparison of water-level records from basins that are hydrogeologically and climatologically similar but have contrasting levels of ground-water development. Hydrologic data, including records of ground-water levels, basin-wide annual ground-water withdrawals, and precipitation were examined from two basins in Utah (Milford and central Sevier) and three in Arizona (Aravaipa Canyon, Willcox, and Douglas). Most water-level records examined in this study from basins experiencing substantial ground-water development (Milford, Douglas, and Willcox) showed strong trends of declining water levels. Other water-level records, generally from the less-developed basins (central Sevier and Aravaipa Canyon) exhibited trends of increasing water levels. These trends are likely the result of accumulating infiltration of unconsumed irrigation water. Water-level records that had significant trends were detrended by subtraction of a low-order polynomial in an attempt to eliminate the variation in the water-level records that resulted from ground-water withdrawal or the application of water for irrigation. After detrending, water-level residuals were correlated with 2- to 10-year moving averages of annual precipitation from representative stations for the individual basins. The water-level residual time series for each well was matched with the 2- to 10-year moving average of annual precipitation with which it was best correlated and the results were compared across basins and hydrologic settings. Analysis of water-level residuals and moving averages of annual precipitation indicate that ground-water levels in the Utah basins respond more slowly to precipitation patterns than those from the Arizona basins. This is attributed to the dominant mechanism of recharge that most directly influences the respective valley aquifers. Substantial recharge in the Utah basins likely originates as infiltrating snowmelt in the mountain block far from the valley aquifer, whereas mountain-front recharge and streambed infiltration of runoff are the dominant recharge mechanisms operating in the Arizona basins. It was determined that the fraction of water-level variation caused by local precipitation patterns becomes more difficult to resolve with increasing effects of ground-water pumping, especially from incomplete records. As the demand for ground water increases in the southwestern United States, long-term records of ground-water levels have the potential to provide valuable information about the precipitation-driven variation in water levels, which has implications to water management related to water availability.

Arizona, Utah↗

Use of isotopic data to evaluate recharge and geologic controls on the movement of ground water in Las Posas Valley, Ventura County, California

Injection, storage, and recovery of imported water is planned for aquifers underlying Las Posas Valley. To evaluate sources of ground-water recharge and the age of the water (time since recharge), and to identify barriers to ground-water flow prior to the injection of imported water, samples from wells and surface sources were collected and analyzed for chemical and isotopic composition. The delta oxygen- 18 and delta deuterium composition in almost 50 samples from 32 wells ranged from -6.0 to -7.9 per mil, and -40 to -60 per mil, respectively; and in 13 samples of surface water at 6 sites the composition ranged from -6.2 to -9.4 per mil, and -42 to -71 per mil, respectively. Water from wells in the upper aquifer system near Arroyo Simi and Arroyo Las Posas (different reaches of the same stream) was isotopi cally lighter than water from other wells sampled and was similar in isotopic composition to water in the stream. Water in the stream is a mixture of local water and imported water from northern California that was discharged to the stream as treated municipal wastewater. Water from wells near the stream contained tritium and, therefore, was recharged less than 50 years ago. Water from wells in other parts of the valley was isotopically heavier, did not contain tritium, and, therefore, was recharged more than 50 years ago. Interpreted carbon-14 ages for water from wells along a flow path through the valley ranged from at least 800 to more than 8,000 years before present. There were large differences in the chemistry, isotopic composition, and interpreted age of water from wells between the eastern and western parts of Las Posas Valley. These changes are consistent with geologic and hydrologic data that suggest the presence of a barrier to ground-water flow between east and west Las Posas Valley.

Water-Resources Investigations Report↗

Factors influencing the occurrence of floods in a humid region of diverse terrain

This report describes relations between flood peaks and hydrologic factors in a humid region with limited climatic variation but a diversity of terrain. Statistical multiple-regression techniques have been applied to hydrologic data on New England. Many topographic and climatic factors have been evaluated. and their relations to flood peaks have been examined. Many of the factors that influence flood peaks are interrelated, and part of the investigation consisted of determining the most efficient factor in each of several groups of highly interrelated variables. Drainage area size was found to be the most important factor. Main-channel slope was found to be next in importance, and a simple yet efficient indicator of main-channel slope was developed. The surface area of lakes and ponds was found to be a factor significantly influencing peak discharges. Of several indices tested the intensity of rainfall for a given duration and frequency was found to be most highly related to the magnitude of peaks. The increase in peaks caused by snowmelt and frozen ground was found to be related to an index of winter temperature-the average number of degrees below freezing in January. After the above-mentioned topographic and climatic characteristics had been taken into account, there remained deviations in peak discharges that showed an evident relation to orographic patterns. An orographic factor was mapped as defined by the peak discharges of record. Multiple-regression equations were developed that related, with acceptable accuracy, peak discharges of 1.2-to 300-year recurrence intervals to 6 hydrologic variables; 3 of the variables were topographic, 2 climatic, and 1 orographic. The remaining unexplained variations in flood-peak occurrence are believed attributable to the chance variation in storms.

Water Supply Paper↗

Development of soil radiocarbon profiles in a reactive transport framework

Today, there is a greater appreciation for the importance of the physical protection of carbon (C) through interactions with mineral surfaces, isolation from microbes, and the important role of transport in shaping soil properties and controlling moisture limitations on decomposition. As our paradigm for soil organic carbon (SOC) preservation changes, so too should our representation of the underlying processes in soil models. Reactive transport models (RTMs) provide a framework capable of assessing the interactive influence of soil chemistry and transport processes on the accumulation and turnover of SOC. In this study, we present new developments in the isotopically enabled RTM “CrunchTope,” which is capable of explicitly tracking the three isotopes of carbon ( 12 C, 13 C, and 14 C) and their fractionation between multiple coexisting and interacting solid, liquid and gas phases. This modeling framework opens the door to new applications of depth-resolved RTMs models in application to SOC and deeper subsurface carbon reservoirs. Here, we demonstrate SOC accumulation and radiocarbon aging for long-timescale models of soil development in CrunchTope. Our goal is to assess advantages and limitations of such an approach and to identify the type and complexity of reaction networks that are required to adequately apply this model to SOC dynamics. We assess the behavior of this model relative to a high-resolution dataset of SOC content, stable isotope composition, and radiocarbon ages as well as physical and hydrologic data measured from a chronosequence of soils located near Santa Cruz, California. Starting from a previously published model using a simplified reaction network with a single class of carbon, we sequentially incorporate multiple C reservoirs subject to both reactivity and transport pathways. Our results indicate that multiple SOC pools with different mean ages of C do not inherently emerge as a result of including reactions which are conventionally expected to provide a diversity of transit times, i.e., sorption and complexation of SOC on mineral surfaces. Instead, transit times emerge as a result of the timescales of the reactions represented in the reaction network. For mineral associated C, the RTM framework imposes dynamic equilibrium with the fluid phase dissolved organic C, such that no distinction in radiocarbon ages is achieved between these pools. Aged C can be produced by including a solid-phase C reservoir, with a rate-limited solubilization coefficient. Aging of SOC in this way is more akin to selective preservation than to mineral protection and, while such a mechanism may be at play in many soils, mineral protection is thought to be at least as important. As such, our results indicate that additional parameterization is required to reproduce the heterogeneity of carbon transit times that result from organo-mineral interactions. These efforts show the promise of a modeling approach where the varied transit time of soil C emerges from the dynamic physical and hydrologic properties of the model rather than from the a priori assignment of operationally defined pools.

Geochimica et Cosmochimica Acta↗

Lithostratigraphy, petrography, biostratigraphy, and strontium-isotope stratigraphy of the surficial aquifer system of western Collier County, Florida

In 1996, seven cores were recovered in western Collier County, southwestern Florida, to acquire subsurface geologic and hydrologic data to support ground-water modeling efforts. This report presents the lithostratigraphy, X-ray diffraction analyses, petrography, biostratigraphy, and strontium-isotope stratigraphy of these cores. The oldest unit encountered in the study cores is an unnamed formation that is late Miocene. At least four depositional sequences are present within this formation. Calculated age of the formation, based on strontium-isotope stratigraphy, ranges from 9.5 to 5.7 Ma (million years ago). An unconformity within this formation that represents a hiatus of at least 2 million years is indicated in the Old Pump Road core. In two cores, Collier-Seminole and Old Pump Road, the uppermost sediments of the unnamed formation are not dated by strontium isotopes, and, based on the fossils present, these sediments could be as young as Pliocene. In another core (Fakahatchee Strand-Ranger Station), the upper part of the unnamed formation is dated by mollusks as Pliocene. The Tamiami Formation overlies the unnamed formation throughout the study area and is represented by the Ochopee Limestone Member. The unit is Pliocene and probably includes the interval of time near the early/late Pliocene boundary. Strontium-isotope analysis indicates an early Pliocene age (calculated ages range from 5.1 to 3.5 Ma), but the margin of error includes the latest Miocene and the late Pliocene. The dinocyst assemblages in the Ochopee typically are not age-diagnostic, but, near the base of the unit in the Collier-Seminole, Jones Grade, and Fakahatchee Strand State Forest cores, they indicate an age of late Miocene or Pliocene. The molluscan assemblages indicate a Pliocene age for the Ochopee, and a distinctive assemblage of Carditimera arata and Chione cortinaria in several of the cores specifically indicates an age near the early/late Pliocene boundary. Undifferentiated sands overlie the Pliocene limestones in two cores in the southern part of the study area. Artificial fill occurs at the top of most of the cores. The hydrologic confining units penetrated by these cores are different in different parts of the study area. To the west, a hard tightly cemented dolostone forms the first major confining unit below the water table. In the eastern part of the study area, confinement is more difficult to determine. A tightly cemented sandstone, much younger than the dolostones to the west and probably not laterally connected to them, forms a slight confining unit in one core. Thick zones of poorly sorted muddy unconsolidated sands form a slight confining unit in other cores; these probably are not correlative to either the sandstone or the dolostones to the west. The age and sedimentologic observations suggest a complex compartmentalization of the surficial aquifer system in southwestern Florida. The calibrations of dinocyst and molluscan occurrences with strontium-isotope stratigraphy allows us to expand and document the reported ranges of many taxa. This report is preliminary and has not been reviewed for conformity with U.S. Geological Survey editorial standards or with the North American Stratigraphic Code. Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Florida↗

Interdecadal changes in the hydrometeorological regime of the Pacific Northwest and in the regional-to-hemispheric climate regimes, and their linkages

Selected hydrometeorological (HM) data for the Pacific Northwest, and regional-to-hemispheric atmospheric-circulation data and sea-surface temperature (SST) data for the North Pacific, are examined for three successive interdecadal periods that are subsets of the instrumental record in order to estimate if their characteristics have changed. The HM data included monthly precipitation totals for 50 sites in western Washington and 29 climate divisions of the Pacific Northwest, and streamflow averages for 112 sites in Washington, Oregon, and Idaho. The atmospheric data included the Southern Oscillation Index (SOI), an index of the Pacific/North America (PNA) circulation pattern, measures of the westerly and northerly components of geostrophic flow, and a subset of the Northern Hemisphere 700-millibar geopotential height data; this subset of 162 grid points includes the area between 15 degrees and 75 degrees N, 110 degrees W and 130 degrees E. The SST data are for a 5-degree grid between 20 degrees N and 60 degrees N, 110 degrees W and 130 degrees E. The atmospheric and SST data were examined not only because the HM regime is linked to regional-to-hemispheric climate regimes, but also to estimate the extent of climate shifts displayed by these data. Three subsets of the record were identified as pre-1947 (PRE), 1947-76 (BASE), and post-1976 (POST) water years, based on an analysis of the HM data and previous studies. For each subset, means were calculated for the water year (October-September), the runoff season (March-August), the winter season (October-February), and a baseflow season (August-September). Differences in means and in ratios of the means between the BASE period and the PRE and POST periods were examined for changes. Winter-season mean precipitation during both the PRE and POST periods was smaller than the BASE period, indicating a spatially consistent and distinct change in the HM regime during winter during the PRE and POST periods. For the runoff season, mean precipitation at most sites, in comparison to the BASE period, was smaller during the PRE period and larger during POST period, indicating that different HM regimes occurred during the runoff season for the PRE and POST periods. Water-year mean precipitation was less for both the PRE and POST periods because of decreases in winter-season precipitation; however, the water-year values for the POST period were not as small as those of the PRE period because more precipitation was concentrated in the runoff season. During both the PRE and POST periods, the mean water-year discharge was less than the BASE period for all but 15 of the 112 sites. Fourteen of the 15 sites were in a well-defined region (southern Idaho and southeastern Oregon), and 13 of the 14 had larger means only during the POST period. Winter-season streamflow was less for all but 11 sites during both PRE and POST periods; the largest decreases in the mean, more than 30 percent, were for an area in central Oregon. Except for the sites that had larger mean water-year discharge, runoff-season means also were less than those during the BASE period. Changes in the SOI and PNA index from the BASE period were generally similar to and consistent with those of the majority of the hydrologic data; dissimilarities were in well-defined regions and are attributed to the evolutionary nature of the regime shifts. Negative values of the SOI for the POST period were more persistent than those that have occurred during both the PRE and BASE periods. The changes in the PNA index and the geostrophic flow components during the POST period are consistent with drier and warmer conditions in the Pacific Northwest. The 700-millibar data display trends and differences between the BASE and POST periods; differences in composite anomalies for selected winter months between these periods show a well-defined PNA pattern. For many areas of the North Pacific, the record of SSTs shows a significant long-term trend

Water-Resources Investigations Report↗

Carbon and nitrogen isotopic compositions of particulate organic matter in four large river systems across the United States

Riverine particulate organic matter (POM) samples were collected bi‐weekly to monthly from 40 sites in the Mississippi, Colorado, Rio Grande, and Columbia River Basins (USA) in 1996–97 and analysed for carbon and nitrogen stable isotopic compositions. These isotopic compositions and C : N ratios were used to identify four endmember sources of POM: plankton, fresh terrestrial plant material, aquatic plants, and soil organic material. This large‐scale study also incorporated ancillary chemical and hydrologic data to refine and extend the interpretations of POM sources beyond the source characterizations that could be done solely with isotopic and elemental ratios. The ancillary data were especially useful for differentiating between seasonal changes in POM source materials and the effects of local nutrient sources and in‐stream biogeochemical processes. Average values of δ 13 C and C : N for all four river systems suggested that plankton is the dominant source of POM in these rivers, with higher percentages of plankton downstream of reservoirs. Although the temporal patterns in some rivers are complex, the low δ 13 C and C : N values in spring and summer probably indicate plankton blooms, whereas relatively elevated values in fall and winter are consistent with greater proportions of decaying aquatic vegetation and/or terrestrial material. Seasonal shifts in the δ 13 C of POM when the C : N remains relatively constant probably indicate changes in the relative rates of photosynthesis and respiration. Periodic inputs of plant detritus are suggested by C : N ratios >15, principally on the Columbia and Ohio Rivers. The δ 15 N and δ 13 C also reflect the importance of internal and external sources of dissolved carbon and nitrogen, and the degree of in‐stream processing. Elevated δ 15 N values at some sites probably reflect inputs from sewage and/or animal waste. This information on the spatial and temporal variation in sources of POM in four major river systems should prove useful in future food web and nutrient transport studies.

Hydrological Processes↗

Policy and procedures for the management and archival storage of data collected for hydrologic investigations, U.S. Geological Survey, Indiana District

This report describes the policy and procedures used by the Indiana District of the U.S. Geological Survey, Water Resources Division, to manage and store data collected during hydrologic investigations. It is the policy of the Indiana District that data collected to meet the objectives of projects for hydrologic investigations be documented, organized, and archieved in a manner that (1) facilitates retrieval, evaluation, and use by other District personnel, and (2) enables verifi- cation of data contained in all reports and computer data bases.

Indiana↗

Geomorphic, hydrologic, and erosion data for selected reclaimed hillslopes, the Seneca II mine, Routt County, Colorado, October 1988-July 1990

Geomorphic, hydrologic, and erosion data were collected from five reclaimed hillslopes at the Seneca II mine near Hayden, Colorado. Hillslope surveys were used to determine hillslope lengths, which range from 670 to 1,280 ft, and hillslope gradients, which range from 0.17 to 0.23 ft/ft (17 to 23 percent). Elevations in the study area range from 6,890 to 7,140 feet and hillslope aspect generally is west or south. Mean total vegetation cover ranges from 74 to 91 percent. Total monthly precipitation for December 1988 through May 1990 was computed from daily measurements made with weighing-bucket precipitation gages. Several snowpack measurements were made during 2 winters. Volumetric soil-water content was determined at incremental depths using a neutron probe and in the upper 11.8 in of soil using a time-domain reflectometer. Active and recent soil erosion was indicated by the presence of rills. Rill density (the sum of rill lengths/unit area) was computed at 50-feet intervals along each hillslope study area. Differences in soil-surface elevations between September or October 1989 and June 1990 were determined with an erosion frame and replicate soil-surface surveys at 16 erosion-study plots.

Colorado↗

Are exposure predictions, used for the prioritization of pharmaceuticals in the environment, fit for purpose?

Prioritization methodologies are often used for identifying those pharmaceuticals that pose the greatest risk to the natural environment and to focus laboratory testing or environmental monitoring toward pharmaceuticals of greatest concern. Risk-based prioritization approaches, employing models to derive exposure concentrations, are commonly used, but the reliability of these models is unclear. The present study evaluated the accuracy of exposure models commonly used for pharmaceutical prioritization. Targeted monitoring was conducted for 95 pharmaceuticals in the Rivers Foss and Ouse in the City of York (UK). Predicted environmental concentration (PEC) ranges were estimated based on localized prescription, hydrological data, reported metabolism, and wastewater treatment plant (WWTP) removal rates, and were compared with measured environmental concentrations (MECs). For the River Foss, PECs, obtained using highest metabolism and lowest WWTP removal, were similar to MECs. In contrast, this trend was not observed for the River Ouse, possibly because of pharmaceutical inputs unaccounted for by our modeling. Pharmaceuticals were ranked by risk based on either MECs or PECs. With 2 exceptions (dextromethorphan and diphenhydramine), risk ranking based on both MECs and PECs produced similar results in the River Foss. Overall, these findings indicate that PECs may well be appropriate for prioritization of pharmaceuticals in the environment when robust and local data on the system of interest are available and reflective of most source inputs.

City of York↗

Quantifying and mapping inundation regimes within a large river‐floodplain ecosystem for ecological and management applications

Spatial information on the distribution of ecosystem patterns and processes can be a critical component of designing and implementing effective management programs in river‐floodplain ecosystems. For example, translating how flood pulses detected within a stream gauge record are spatially manifested across a river‐valley bottom can be used to evaluate whether the current distribution of physical conditions has the potential to support priority habitats or if intervention is needed to meet desired goals. The size and complexity of large river‐floodplain systems can make mapping inundation dynamics a challenging task. We used a geospatial model to simulate 40 years (1972–2011) of daily surface‐water inundation depths for 11,331 km 2 of the Upper Mississippi River System floodplain. We identified discrete inundation events at each 4‐m × 4‐m pixel in the model as sequential days of submergence. We then quantified and mapped four aspects of inundation regime – event frequency, duration, magnitude, and timing – for each pixel. The spatial distribution of inundation regime attributes varied within and among multiple levels of river organization, including navigation pools and geomorphic reaches, but only event timing exhibited a strong down‐river trend. Non‐linear relations among inundation attributes and their geospatial distributions likely reflect complex interactions among topographic, hydrologic, and anthropogenic constraints on flooding dynamics. Together, our results reveal spatial gradients in inundation dynamics not captured by hydrologic data alone. Characterizing such diversity in inundation dynamics is important for testing hypotheses about ecological processes, developing models of ecosystem functions, and informing management actions.

Illinois, Indiana, Iowa, Minnesota, Missouri, Wisc↗

Forensic applications of nitrogen and oxygen isotopes in tracing nitrate sources in urban environments

Ground and surface waters in urban areas are susceptible to nitrate contamination from septic systems, leaking sewer lines, and fertilizer applications. Source identification is a primary step toward a successful remediation plan in affected areas. In this respect, nitrogen and oxygen isotope ratios of nitrate, in conjunction with hydrologic data and water chemistry, have proven valuable in urban studies from Austin, Texas, and Tacoma, Washington. In Austin, stream water was sampled during stremflow and baseflow conditions to assess surface and subsurface sources of nitrate, respectively. In Tacoma, well waters were sampled in adjacent sewered and un-sewered areas to determine if locally high nitrate concentrations were caused by septic systems in the un-sewered areas. In both studies, sewage was identified as a nitrate source and mixing between sewage and other sources of nitrate was apparent. In addition to source identification, combined nitrogen and oxygen isotopes were important in determining the significance of denitrification, which can complicate source assessment by reducing nitrate concentrations and increasing ??15N values. The two studies illustrate the value of nitrogen and oxygen isotopes of nitrate for forensic applications in urban areas. ?? Published by Elsevier Science Ltd. on behalf of AEHS.

Environmental Forensics↗

Analysis and simulation of propagule dispersal and salinity intrusion from storm surge on the movement of a marsh–mangrove ecotone in South Florida

Coastal mangrove–freshwater marsh ecotones of the Everglades represent transitions between marine salt-tolerant halophytic and freshwater salt-intolerant glycophytic communities. It is hypothesized here that a self-reinforcing feedback, termed a “vegetation switch,” between vegetation and soil salinity, helps maintain the sharp mangrove–marsh ecotone. A general theoretical implication of the switch mechanism is that the ecotone will be stable to small disturbances but vulnerable to rapid regime shifts from large disturbances, such as storm surges, which could cause large spatial displacements of the ecotone. We develop a simulation model to describe the vegetation switch mechanism. The model couples vegetation dynamics and hydrologic processes. The key factors in the model are the amount of salt-water intrusion into the freshwater wetland and the passive transport of mangrove (e.g., Rhizophora mangle) viviparous seeds or propagules. Results from the model simulations indicate that a regime shift from freshwater marsh to mangroves is sensitive to the duration of soil salinization through storm surge overwash and to the density of mangrove propagules or seedlings transported into the marsh. We parameterized our model with empirical hydrologic data collected from the period 2000–2010 at one mangrove–marsh ecotone location in southwestern Florida to forecast possible long-term effects of Hurricane Wilma (24 October 2005). The model indicated that the effects of that storm surge were too weak to trigger a regime shift at the sites we studied, 50 km south of the Hurricane Wilma eyewall, but simulations with more severe artificial disturbances were capable of causing substantial regime shifts.

Florida↗

Tracing nitrogen sources and cycling in catchments

This chapter focuses on the uses of isotopes to understand water chemistry.I Isotopic compositions generally cannot be interpreted successfully in the absence of other chemical and hydrologic data. The chapter focusses on uses of isotopes in tracing sources and cycling of nitrogen in the water-component of forested catchment, and on dissolved nitrate in shallow waters, nutrient uptake studies in agricultural areas, large-scale tracer experiments, groundwater contamination studies, food-web investigations, and uses of compound-specific stable isotope techniques. Shallow waters moving along a flowpath through a relatively uniform material and reacting with minerals probably do not achieve equilibrium but gradually approach some steady-state composition. The chapter also discusses the use of isotopic techniques to assess impacts of changes in land-management practices and land use on water quality. The analysis of individual molecular components for isotopic composition has much potential as a method for tracing the source, biogeochemistry, and degradation of organic liquids and gases because different materials have characteristic isotope spectrums or biomarkers.

Book chapter↗