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Assessing the vulnerability of public-supply wells to contamination: Glacial aquifer system in Woodbury, Connecticut

This fact sheet highlights findings from the vulnerability study of a public-supply well in Woodbury, Connecticut. The well typically produces water at the rate of 72 gallons per minute from the glacial aquifer system in the Pomperaug River Basin. Water samples were collected at the public-supply well and at monitoring wells installed in or near the simulated zone of contribution to the supply well. Samples of untreated water from the public-supply wellhead contained several types of undesirable constituents, including 11 volatile organic compounds (VOCs), nitrate, pesticides, uranium, and radon. Most of these constituents were detected at concentrations below drinking-water standards, where such standards exist. Only concentrations of the VOC trichlorethylene exceeded the Maximum Contaminant Level (MCL) of 5 micrograms per liter (ug/L) established by U.S. Environmental Protection Agency for drinking water. Radon concentrations exceeded a proposed-but not finalized-MCL of 300 picocuries per liter (pCi/L). Overall, the study findings point to four main factors that affect the movement and fate of contaminants and the vulnerability of the public-supply well in Woodbury: (1) groundwater age (how long ago water entered, or recharged, the aquifer); (2) the percentage of recharge received through urban areas; (3) the percentage of recharge received through dry wells and their proximity to the public-supply well; and (4) natural geochemical processes occurring within the aquifer system; that is, processes that affect the amounts and distribution of chemical substances in aquifer sediments and groundwater. A computer-model simulation of groundwater flow to the public-supply well was used to estimate the age of water particles entering the well along the length of the well screen. About 90 percent of the simulated flow to the well consists of water that entered the aquifer 9 or fewer years ago. Such young water is vulnerable to contaminants resulting from human activities, as indicated by the solvents, fuel components, road salt, and septic-system leachate that were detected in the glacial aquifer system during the current study. Age-dating combined with chemical modeling suggests that less than 2 percent of water produced by the public-supply well is water from the deep bedrock that is "old" (water that recharged, or entered, the aquifer before 1952). Such a small percentage of old groundwater entering the public-supply well offers little potential for dilution of young waters containing contaminants from human activities. Shallow groundwater that originated as recharge through urban areas generally had higher median concentrations and more detections of volatile organic compounds (VOCs) than did groundwater from the deep glacial deposits or fractured bedrock that originated mainly as recharge through agricultural and undeveloped land. Shallow groundwater was also found to be affected by road salt and septic-system leachate. A chemical mixing model indicates that up to 15 percent of nitrate in water from the supply well is likely from septic-system leachate. The Connecticut Department of Public Health has identified several potential sources of contamination in the commercial area of Woodbury (several light industrial or commercial properties where hazardous materials and petroleum products are used and stored). To reduce stormwater runoff in the commercial area, water from the parking lots and pavement is channeled into dry wells-drains that shunt water directly into the aquifer system, bypassing the soil and unsaturated zones. A computer-model simulation of groundwater flow indicates that approximately 16 percent of the water produced by the public-supply well is derived from runoff captured by these drains. Traveltime for water from the dry wells to the public-supply well ranges from about 1.5 to less than 4 years. Dry wells have the potential to enhance contaminant movement to the supply well, suggesting that stormwater-control methods cannot be considered separately from groundwater quality—they are linked. Water-quality protection in this setting depends on the entire community. If residents and businesses take steps to reduce input of manmade contaminants to groundwater, a positive effect on quality of the supply-well water might begin to be seen in less than 10 years, owing to the short residence time of water in the aquifer.

Connecticut↗

Modeling watershed carbon dynamics as affected by land cover change and soil erosion

Process-based ecosystem carbon cycle models typically incorporate vegetation growth, vegetation mortality, and soil respiration as well as the biotic and environmental drivers that influence these variables. However, few spatially explicit process models can efficiently incorporate the influence of land cover change and carbon lateral movement at regional scales or high spatial resolution. This study uses the Land Use and Carbon Scenario Simulator (LUCAS) to demonstrate the development of a fast ecosystem model that not only considers the basic carbon cycle but also incorporates the impact of land cover change, soil erosion, and soil deposition. As input to the LUCAS modeling framework, we used the integrated biosphere simulator (IBIS) to simulate a non-spatial reference carbon cycling scenario without considering land cover change for the Nisqually River watershed in the northwestern United States. We then used the Land Change Monitoring, Assessment, and Projection (LCMAP) remotely sensed 30-m sequential land cover data to generate annual land change history for the Nisqually River area from 1985 to 2017 and used the Unit Stream Powered Erosion and Deposition model (USPED) to estimate annual soil carbon lateral movement. Finally, we combined the annual carbon outputs from IBIS, the land change history from LCMAP, and the soil erosion and deposition from USPED within the LUCAS simulation framework. Results showed that from 1985 to 2017, along with the dynamic land cover changes, total ecosystem biomass carbon increased from 11.4 to 18.6 TgC, mainly due to forest growth. Total ecosystem soil carbon declined from 31.7 to 29.7 TgC, but the overall loss in soil carbon was not uniform across land cover types. Forestland (forest sector) and grassland lost carbon, while wetland, developed land and agricultural land gained carbon. Forest, grassland, and developed land lost 0.0553 TgC during the study period (1.73 Gg of C per year; 1 Gg = 0.001 Tg) from erosion, while wetland gained 0.0071 TgC (0.22 Gg C per year) from deposition. Agricultural land was neutral in terms of soil erosion.

Washington↗

Annual dissolved nitrite plus nitrate and total phosphorous loads for the Susquehanna, St. Lawrence, Mississippi-Atchafalaya, and Columbia River basins, 1968-2004

Annual stream-water loads were calculated near the outlet of four of the larger river basins (Susquehanna, St. Lawrence, Mississippi-Atchafalaya, and Columbia) in the United States for dissolved nitrite plus nitrate (NO2 + NO3) and total phosphorus using LOADEST load estimation software. Loads were estimated for the period 1968-2004; although loads estimated for individual river basins and chemical constituent combinations typically were for shorter time periods due to limitations in data availability. Stream discharge and water-quality data for load estimates were obtained from the U.S. Geological Survey (USGS) with additional stream discharge data for the Mississippi-Atchafalaya River Basin from the U.S. Army Corps of Engineers. The loads were estimated to support national assessments of changes in stream nutrient loads that are periodically conducted by Federal agencies (for example, U.S. Environmental Protection Agency) and other water- and land-resource organizations. Data, methods, and results of load estimates are summarized herein; including World Wide Web links to electronic ASCII text files containing the raw data. The load estimates are compared to dissolved NO2 + NO3 loads for three of the large river basins from 1971 to 1998 that the USGS provided during 2001 to The H. John Heinz III Center for Science, Economics and the Environment (The Heinz Center) for a report The Heinz Center published during 2002. Differences in the load estimates are the result of using the most up-to-date monitoring data since the 2001 analysis, differences in how concentrations less than the reporting limit were handled by the load estimation models, and some errors and exclusions in the 2001 analysis datasets (which resulted in some inaccurate load estimates).

Open-File Report↗

Assessment of interim flow water-quality data of the San Joaquin River restoration program and implications for fishes, California, 2009-11

After more than 50 years of extensive water diversion for urban and agriculture use, a major settlement was reached among the U.S. Departments of the Interior and Commerce, the Natural Resources Defense Council, and the Friant Water Users Authority in an effort to restore the San Joaquin River. The settlement received Federal court approval in October 2006 and established the San Joaquin River Restoration Program, a multi-agency collaboration between State and Federal agencies to restore and maintain fish populations, including Chinook salmon, in the main stem of the river between Friant Dam and the confluence with the Merced River. This is to be done while avoiding or minimizing adverse water supply effects to all of the Friant Division contractors that could result from restoration flows required by the settlement. The settlement stipulates that water- and sediment-quality data be collected to help assess the restoration goals. This report summarizes and evaluates water-quality data collected in the main stem of the San Joaquin River between Friant Dam and the Merced River by the U.S. Bureau of Reclamation for the San Joaquin River Restoration Program during 2009-11. This summary and assessment consider sampling frequency for adequate characterization of variability, sampling locations for sufficient characterization of the San Joaquin River Restoration Program restoration reach, sampling methods for appropriate media (water and sediment), and constituent reporting limits. After reviewing the water- and sediment-quality results for the San Joaquin River Restoration Program, several suggestions were made to the Fisheries Management Work Group, a division of the San Joaquin River Restoration Program that focuses solely on the reintroduction strategies and health of salmon and other native fishes in the river. Water-quality results for lead and total organic carbon exceeded the Surface Water Ambient Monitoring Program Basin Plan Objectives for the San Joaquin Basin, and results for copper exceeded the U.S. Environmental Protection Agency Office of Pesticide Programs' aquatic-life chronic and acute benchmarks for invertebrates. One sediment sample contained detections of pyrethroid pesticides bifenthrin, lambda-cyhalothrin, and total permethrin at concentrations above published chronic toxicity thresholds.

California↗

Modeling to Predict Escherichia coli at Presque Isle Beach 2, City of Erie, Erie County, Pennsylvania

The Lake Erie beaches in Pennsylvania are a valuable recreational resource for Erie County. Concentrations of Escherichia coli (E. coli) at monitored beaches in Presque Isle State Park in Erie, Pa., occasionally exceed the single-sample bathing-water standard of 235 colonies per 100 milliliters resulting in potentially unsafe swimming conditions and prompting beach managers to post public advisories or to close beaches to recreation. To supplement the current method for assessing recreational water quality (E. coli concentrations from the previous day), a predictive regression model for E. coli concentrations at Presque Isle Beach 2 was developed from data collected during the 2004 and 2005 recreational seasons. Model output included predicted E. coli concentrations and exceedance probabilities--the probability that E. coli concentrations would exceed the standard. For this study, E. coli concentrations and other water-quality and environmental data were collected during the 2006 recreational season at Presque Isle Beach 2. The data from 2006, an independent year, were used to test (validate) the 2004-2005 predictive regression model and compare the model performance to the current method. Using 2006 data, the 2004-2005 model yielded more correct responses and better predicted exceedances of the standard than the use of E. coli concentrations from the previous day. The differences were not pronounced, however, and more data are needed. For example, the model correctly predicted exceedances of the standard 11 percent of the time (1 out of 9 exceedances that occurred in 2006) whereas using the E. coli concentrations from the previous day did not result in any correctly predicted exceedances. After validation, new models were developed by adding the 2006 data to the 2004-2005 dataset and by analyzing the data in 2- and 3-year combinations. Results showed that excluding the 2004 data (using 2005 and 2006 data only) yielded the best model. Explanatory variables in the 2005-2006 model were log10 turbidity, bird count, and wave height. The 2005-2006 model correctly predicted when the standard would not be exceeded (specificity) with a response of 95.2 percent (178 out of 187 nonexceedances) and correctly predicted when the standard would be exceeded (sensitivity) with a response of 64.3 percent (9 out of 14 exceedances). In all cases, the results from predictive modeling produced higher percentages of correct predictions than using E. coli concentrations from the previous day. Additional data collected each year can be used to test and possibly improve the model. The results of this study will aid beach managers in more rapidly determining when waters are not safe for recreational use and, subsequently, when to close a beach or post an advisory.

Scientific Investigations Report↗

Design of a shallow ground-water network to monitor agricultural chemicals, Lake Wales Ridge, central Florida

Extensive agricultural land use and dynamic hydraulic connections between the land surface and ground-water resources render many of Florida's aquifers vulnerable to chemical contamination. In these areas, there is a need to monitor shallow ground water for agricultural chemicals to evaluate potential migration of the chemicals to the subsurface and to deeper aquifers, and to assess the effects of agricultural practices on ground-water quality. Historically, efforts to monitor water-table aquifers have been minimal compared with monitoring deeper aquifers used for municipal drinking-water supply. The Florida Department of Agriculture and Consumer Services has proposed the establishment of long-term, water-quality networks to monitor shallow ground water in agricultural areas of Florida. These networks will bridge the current information gap between local-scale short-duration field studies, which are required for pesticide licensing, and statewide monitoring of deeper ground-water resources. Laboratory (experimental) and short-term field evaluations of the transport of agricultural chemicals to the subsurface contain some degree of uncertainty due to widespread variations in environmental conditions. The proposed regional-scale shallow ground-water networks will serve as "early warning" networks to avoid contamination of ground-water resources. The objectives of these shallow ground-water networks are to provide information for early detection of pesticides and nitrate in the subsurface, and for evaluating temporal trends in concentrations in relation to changes in land use and agricultural practices. Information on trends is important to the U.S. Environmental Protection Agency, State agencies, and agricultural managers, and is an integral part of Florida's Pesticide Management Plan, which evaluates the effectiveness of implementing "best management practices" to minimize environmental impacts. Lake Wales Ridge in Polk and Highlands Counties has been identified by the Florida Department of Agriculture and Consumer Services as a pilot study area for implementing a regional shallow ground-water network. Information gained from designing the Lake Wales Ridge Network will be used to develop plans as similar networks are considered for other areas of Florida. Lake Wales Ridge is heavily utilized for citrus production, but the well-drained, clean sands underlying the region, coupled with a hydraulic connection with deeper karst formations, render the area extremely vulnerable to the transport and migration of agricultural chemicals within the subsurface. The network design for Lake Wales Ridge was developed on the basis of the objectives of monitoring, factors affecting aquifer vulnerability, probability (statistical) sampling theory, and specifications regarding well construction, sampling, and laboratory analysis. The network will provide estimates of regional pesticide and nitrate concentrations in targeted ground water, monitor for trends over time, and will provide baseline, regional-scale information. The areas targeted for sampling were citrus groves located on soils classified as vulnerable to leaching of agricultural chemicals, and ground water in close proximity to the water table. The duration of monitoring is planned to be long term. Chemicals targeted for monitoring include selected nutrients, trace elements, and pesticides used for citrus management. Standardization of field sampling and laboratory methods, and construction of a computerized data-base repository will be important for long-term utility of the data. The proposed network design consists of existing and newly drilled wells. Existing wells were evaluated as candidates for the network based on location and well-construction specifications for water-quality monitoring. Using probability selection techniques, new well locations were selected in areas that lacked adequate existing wells. Implementation of the network will occur in phases. Quarterly sampling of 13 Phase I wells commenced in April 1999. An additional 11 Phase II wells were added to the network in April 2000. Proposed locations have been identified for 8 Phase III wells. Future topics for study include a regional water-quality analysis, a network design evaluation, and consideration of local-scale studies needed to support regional monitoring efforts. An analysis of historical water-quality data for Lake Wales Ridge, including Phase I wells, is needed for the purpose of examining trends, providing a preliminary description of spatial and short-term variability in water quality, and evaluating the proposed network design for cost effectively meeting program objectives. Local-scale, process-oriented studies are needed to provide important information for evaluating regional water-quality data. Coordination between individuals conducting such local-scale studies and those interpreting regional sampling results will be considered as a component of the network design, and will require coordination between multiple agencies.

Florida↗

Interaction of a legacy groundwater contaminant plume with the Little Wind River from 2015 through 2017, Riverton Processing site, Wyoming

The Riverton Processing site was a uranium mill 4 kilometers southwest of Riverton, Wyoming, that prepared uranium ore for nuclear reactors and weapons from 1958 to 1963. The U.S. Department of Energy completed surface remediation of the uranium tailings in 1989; however, groundwater below and downgradient from the tailings site and nearby Little Wind River was not remediated. Beginning in 2010, a series of floods along the Little Wind River began to mobilize contaminants in the unsaturated zone, resulting in substantial increases of uranium and other contaminants of concern in monitoring wells completed inside the contaminant plume. In 2011, the U.S. Department of Energy started a series of university and Government agency retrospective and field investigations to understand the processes controlling contaminant increases in the groundwater plume. The goals of the field investigations described in this report were to (1) identify and quantify the contaminant flux and potential associated biological effects from groundwater associated with the legacy plume as it enters a perennial stream reach, and (2) assess chemical exposure and potential effects to biological receptors from the interaction of the contaminant plume and the river. Field investigations along the Little Wind River were completed by the U.S. Geological Survey during 2015–17 in cooperation with the U.S. Department of Energy Office of Legacy Management to characterize: (1) seepage areas and seepage rates; (2) pore-water and bed sediment chemistry and hyporheic exchange and reactive loss; and (3) exposure pathways and biological receptors. All data collected during the study are contained in two U.S. Geological Survey data releases, available at https://doi.org/10.5066/F7BR8QX4 and https://doi.org/10.5066/P9J9VJBR . A variety of tools and methods were used during the field characterizations. Streambed temperature mapping, electrical resistivity tomography, electromagnetic induction, fiber-optic distributed temperature sensing, tube seepage meters, vertical thermal sensor arrays, and an environmental tracer (radon) were used to identify areas of groundwater seepage and associated seepage rates along specific sections of the study reach of the river. Drive points, minipiezometers, diffusive equilibrium in thin-film/diffusive gradients in thin-film probes, bed-sediment samples, and equal discharge increment sampling methods were used to characterize pore-water chemistry, estimate hyporheic exchange and reactive loss of selected chemical constituents, and quantify contaminant loadings entering the study reach. Sampling and analysis of surface sediments, filamentous algae, periphytic algae, and macroinvertebrates were used to characterize biological exposure pathways, metal uptake, and receptors. Areas of focused groundwater discharge identified by the fiber-optic distributed temperature sensing surveys corresponded closely with areas of elevated electrical conductivity identified by the electromagnetic induction survey results in the top 5 meters of sediment. During three monitoring periods in 2016, the mean vertical seepage rate measured with tube seepage meters was 0.45 meter per day, ranging from −0.02 to 1.55 meters per day. Five of the 11 locations where vertical thermal profile data were collected along the study reach during August 2017 indicated mean upwelling values ranging from 0.11 to 0.23 meter per day. Radon data collected from the Little Wind River during June, July, and August 2016 indicated a consistent inflow of groundwater to the central part of the study reach, in the area congruous with the center of the previously mapped groundwater plume discharge zone. During August 2017, the greatest attenuation of uranium from reactive loss in pore-water samples was observed at three locations along the study reach, at depths between 6 and 15 centimeters, and similar trends in molybdenum attenuation were also observed. Bed-sediment concentration profiles collected during 2017 also indicated attenuation of uranium and molybdenum from groundwater during hyporheic mixing of surface water with the legacy plume during groundwater upwelling into the river. Streamflow measurements combined with equal discharge increment water sampling along the study reach indicated an increase in dissolved uranium concentrations in the downstream direction during 2016 and 2017. Net uranium load entering the Little Wind River study reach was about 290 and 435 grams per day during 2016 and 2017, respectively. Biological samples indicated that low levels of uranium and molybdenum exposure were confined to the benthos in the Little Wind River within and immediately downstream from the perimeter of the groundwater plume. Concentrations of molybdenum and uranium in filamentous algae were consistently low at all sites in the study reach with no indication of increased exposure of dissolved bioavailable molybdenum or uranium at sites next to or downstream from the groundwater plume. Comparison of the August 2017 results from electromagnetic induction, tube seepage meters, vertical thermal profiling, and pore-water chemistry surveys were in general agreement in identifying areas with upwelling groundwater conditions along the study reach. However, the electroconductivity values measured with electromagnetic induction in the top 100 centimeters of sediment did not agree with sodium concentrations measured in pore-water samples collected at similar streambed depths. Differences and similarities between multiple methods can result in additional insights into hydrologic and biogeochemical processes that may be occurring along a reach of a river system interacting with shallow groundwater inputs. It may be advantageous to apply a variety of geophysical, geochemical, hydrologic, and biological tools at other Uranium Mill Tailings Remedial Action ( https://www.energy.gov/sites/prod/files/2014/10/f19/UMTRCA.pdf ) sites during the investigation of legacy contaminant plume interactions with surface-water systems.

Wyoming↗

Assessment of Historical Water-Quality Data for National Park Units in the Rocky Mountain Network, Colorado and Montana, through 2004

This report summarizes historical water-quality data for six National Park units that compose the Rocky Mountain Network. The park units in Colorado are Florissant Fossil Beds National Monument, Great Sand Dunes National Park and Preserve, and Rocky Mountain National Park; and in Montana, they are Glacier National Park, Grant-Kohrs Ranch National Historic Site, and Little Bighorn Battlefield National Monument. This study was conducted in cooperation with the Inventory and Monitoring Program of the National Park Service to aid in the design of an effective and efficient water-quality monitoring plan for each park. Data were retrieved from a number of sources for the period of record through 2004 and compiled into a relational database. Descriptions of the environmental setting of each park and an overview of the park's water resources are presented. Statistical summaries of water-quality constituents are presented and compared to aquatic-life and drinking-water standards. Spatial, seasonal, and temporal patterns in constituent concentrations also are described and suggestions for future water-quality monitoring are provided.

Scientific Investigations Report↗

Groundwater quality surrounding Lake Texoma during short-term drought conditions

Water quality data from 55 monitoring wells during drought conditions surrounding Lake Texoma, located on the border of Oklahoma and Texas, was compared to assess the influence of drought on groundwater quality. During the drought month of October, water table levels were three feet (0.9 m) lower compared with several months earlier under predrought climate conditions. Detection frequencies of nitrate (> 0.1 mg/l), orthophosphates (> 0.1 mg/l), chlorides (> MCL), and sulfates (> MCL) all increased during drought. Orthophosphate level was higher during drought. Largest increases in concentration were nitrate under both agriculture lands and in septic tank areas. An increase in ammonium-nitrogen was only detected in the septic tank area. The study showed that stressors such as nitrate and total salts could potentially become a health or environmental problem during drought.

Environmental Pollution↗

Review of FEWS NET biophysical monitoring requirements

The Famine Early Warning System Network (FEWS NET) provides monitoring and early warning support to decision makers responsible for responding to famine and food insecurity. FEWS NET transforms satellite remote sensing data into rainfall and vegetation information that can be used by these decision makers. The National Aeronautics and Space Administration has recently funded activities to enhance remote sensing inputs to FEWS NET. To elicit Earth observation requirements, a professional review questionnaire was disseminated to FEWS NET expert end-users; it focused upon operational requirements to determine additional useful remote sensing data and, subsequently, to assess whether such data would be beneficial as FEWS NET biophysical supplementary inputs. The review was completed by over 40 experts from around the world. Reviewers were asked to evaluate the relative importance of environmental variables and spatio-temporal requirements for Earth science data products, in particular for rainfall and vegetation products. The results showed that spatio-temporal resolution requirements are complex and need to vary according to place, time, and hazard; that high resolution remote sensing products continue to be in demand; and that rainfall and vegetation products are valued as data that provide actionable food security information.

Environmental Research Letters↗

Overview of the National Water-Quality Assessment Program

The Nation's water resources are the basis for life and our economic vitality. These resources support a complex web of human activities and fishery and wildlife needs that depend upon clean water. Demands for good-quality water for drinking, recreation, farming, and industry are rising, and as a result, the American public is concerned about the condition and sustainability of our water resources. The American public is asking: Is it safe to swim in and drink water from our rivers or lakes? Can we eat the fish that come from them? Is our ground water polluted? Is water quality degrading with time, and if so, why? Has all the money we've spent to clean up our waters, done any good? The U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program was designed to provide information that will help answer these questions. NAWQA is designed to assess historical, current, and future water-quality conditions in representative river basins and aquifers nationwide. One of the primary objectives of the program is to describe relations between natural factors, human activities, and water-quality conditions and to define those factors that most affect water quality in different parts of the Nation. The linkage of water quality to environmental processes is of fundamental importance to water-resource managers, planners, and policy makers. It provides a strong and unbiased basis for better decisionmaking by those responsible for making decisions that affect our water resources, including the United States Congress, Federal, State, and local agencies, environmental groups, and industry. Information from the NAWQA Program also will be useful for guiding research, monitoring, and regulatory activities in cost effective ways.

Open-File Report↗

Land-Cover Trends of the Central Basin and Range Ecoregion

The U.S. Geological Survey (USGS) Land Cover Trends research project is focused on understanding the amounts, rates, trends, causes, and implications of contemporary land-use and land-cover (LU/LC) change in the United States. This project is supported by the USGS Geographic Analysis and Monitoring Program in collaboration with the U.S. Environmental Protection Agency (EPA) and the National Aeronautics and Space Administration (NASA). LU/LC change is a pervasive process that modifies landscape characteristics and affects a broad range of socioeconomic, biologic, and hydrologic systems. Understanding the impacts and feedbacks of LU/LC change on environmental systems requires an understanding of the rates, patterns, and driving forces of past, present, and future LU/LC change. The objectives of the Land Cover Trends project are to (1) determine and describe the amount, rates, and trends of contemporary LU/LC change by ecoregion for the period 1973-2000 for the conterminous United States, (2) document the causes, driving forces, and implications of change, and (3) synthesize individual ecoregion results into a national assessment of LU/LC change. The Land Cover Trends research team includes staff from the USGS National Center for Earth Resources Observation and Science (EROS), Rocky Mountain Geographic Science Center, Eastern Geographic Science Center, Mid-Continent Geographic Science Center, and the Western Geographic Science Center. Other partners include researchers at South Dakota State University, University of Southern Mississippi, and State University of New York College of Environmental Science and Forestry. This report presents an assessment of LU/LC change in the Central Basin and Range ecoregion for the period 1973-2000. The Central Basin and Range ecoregion is one of 84 Level-III ecoregions as defined by the Environmental Protection Agency. Ecoregions have served as a spatial framework for environmental resource management and to denote areas that contain a geographically distinct assemblage of biotic and abiotic phenomena including geology, physiography, vegetation, climate, soils, land use, wildlife, and hydrology. The established Land Cover Trends methodology generates estimates of LU/LC change using a probability sampling approach and change-detection analysis of thematic land-cover images derived from Landsat satellite imagery.

Scientific Investigations Report↗

Environmental contaminant hazards to wildlife at National Capital region and Mid-Atlantic National Park Service units

Pollutant data for air, water, soil and biota were compiled from databases and internet sources and by staff interviews at 23 National Park Service (NPS) units in 2005. A metric was derived describing the quality and quantity of data for each park, and in combination with known contaminant threats, the need for ecotoxicological study was identified and ranked. Over half of NP units were near Toxic Release Inventory sites discharging persistent pollutants, and fish consumption advisories were in effect at or near 22 of the units. Pesticide and herbicide use was found to be minimal, with the exception of those units with agricultural leases. Only 70 reports were found that describe terrestrial vertebrate environmental contaminant data at or near the units. Of the >75,000 compounds in commerce, empirical exposure data were limited to merely 58 halogenated compounds, insecticides, rodenticides, metals, and some contemporary compounds. Further ecotoxicological monitoring and research is warranted at several units including Shenandoah National Park, Richmond National Battlefield Park, Chesapeake & Ohio Canal National Historical Park, Valley Forge National Historical Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historical Park. The types of investigations vary according to the wildlife species present and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include inclusion of screening level contaminant risk assessments into the NPS Vital Signs Program, development of protocols for toxicological analysis of seemingly affected wildlife, alternative methods and compounds for pest management, and use of non-toxic fishing tackle by visitors.

Book chapter↗

Fraser River watershed, Colorado — Assessment of available water-quantity and water-quality data through water year 1997

The water-quantity and water-quality data for the Fraser River watershed through water year 1997 were compiled for ground-water and surface-water sites. In order to assess the water-quality data, the data were related to land use/land cover in the watershed. Data from 81 water-quantity and water-quality sites, which consisted of 9 ground-water sites and 72 surface-water sites, were available for analysis. However, the data were limited and frequently contained only one or two water-quality analyses per site. The Fraser River flows about 28 miles from its headwaters at the Continental Divide to the confluence with the Colorado River. Ground-water resources in the watershed are used for residential and municipal drinking-water supplies. Surface water is available for use, but water diversions in the upper parts of the watershed reduce the flow in the river. Land use/land cover in the watershed is predominantly forested land, but increasing urban development has the potential to affect the quantity and quality of the water resources. Analysis of the limited ground-water data in the watershed indicates that changes in the land use/land cover affect the shallow ground-water quality. Water-quality data from eight shallow monitoring wells in the alluvial aquifer show that iron and manganese concentrations exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Radon concentrations from these monitoring wells exceeded the U.S. Environmental Protection Agency proposed maximum contaminant level. The proposed radon contaminant level is currently being revised. The presence of volatile organic compounds at two monitoring wells in the watershed indicates that land use affects the shallow ground water. In addition, bacteria detected in three samples are at concentrations that would be a concern for public health if the water was to be used as a drinking supply. Methylene blue active substances were detected in the ground water at some sites and are a possible indication of contamination from wastewater. Age of the alluvial ground water ranged from 10 to 30 years; therefore, results of land-management practices to improve water quality may not be apparent for many years. Surface-water-quality data for the Fraser River watershed are sparse. The surface-water-quality data show that elevated concentrations of selected constituents generally are related to specific land uses in the watershed. For one sample (about 2 percent; 1 of 53), dissolved manganese concentration exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level. Two samples from two surface-water sites in the watershed exceeded the un-ionized ammonia chronic criterion. Spatial distribution of nutrient species (ammonia, nitrite, nitrate, and total phosphorus) shows that elevated concentrations occur primarily downstream from urban areas. Sites with five or more years of record were analyzed for temporal trends in concentration of nutrient species. Downward trends were identified for ammonia and nitrite for three surface-water sites. For nitrate, no trends were observed at two sites and a downward trend was observed at one site. Total phosphorus showed no trend for the site near the mouth of the Fraser River. Downward trends in the nutrient species may reflect changes in the wastewater-treatment facilities in the watershed. Bacteria sampling completed in the watershed indicates that more bacteria are present in the water near urban settings. The limited ground-water and surface-water data for the Fraser River watershed provide a general assessment of the quantity and quality of these resources. Concentrations of most water-quality constituents generally are less than ground- and surface-water-quality standards, but the presence of bacteria, some volatile organic compounds, methylene blue active substances, and increased nutrients in the water may indicate that land use is affecting the water quality.

Colorado↗

Microbial source tracking (MST) in Chattahoochee River National Recreation Area: Seasonal and precipitation trends in MST marker concentrations, and associations with E. coli levels, pathogenic marker presence, and land use

Escherichia coli levels in recreational waters are often used to predict when fecal-associated pathogen levels are a human health risk. The reach of the Chattahoochee River that flows through the Chattahoochee River National Recreation Area (CRNRA), located in the Atlanta-metropolitan area, is a popular recreation area that frequently exceeds the U.S. Environmental Protection Agency beach action value (BAV) for E. coli . A BacteriALERT program has been implemented to provide real-time E. coli estimates in the reach and notify the public of potentially harmful levels of fecal-associated pathogens as indicated by surrogate models based on real-time turbidity measurements from continuous water quality monitoring stations. However, E. coli does not provide information about the sources of fecal contamination and its accuracy as a human health indicator is questionable when sources of contamination are non-human. The objectives of our study were to investigate, within the Park and surrounding watersheds, seasonal and precipitation-related patterns in microbial source tracking marker concentrations of possible sources (human, dog, and ruminant), assess correlations between source contamination levels and culturable E. coli levels, determine which sources best explained model-based E. coli estimates above the BAV and detection of esp2 (a marker for the esp gene associated with pathogenic strains of Enterococcus faecium and Enterococcus faecalis) , and investigate associations between source contamination levels and land use features. Three BacteriALERT sites on the Chattahoochee River were sampled six times per season in the winter and summer from December 2015 through September 2017, and 11 additional stream sites (synoptic sites) from the CRNRA watershed were sampled once per season. Samples were screened with microbial source tracking (MST) quantitative PCR (qPCR) markers for humans (HF183 Taqman), dogs (DogBact), and ruminants (Rum2Bac), the esp2 qPCR marker, and culturable E. coli. At the BacteriALERT sites, HF183 Taqman concentrations were higher under wet conditions DogBact concentrations were greater in the winter and under wet conditions, and Rum2Bac concentrations were comparatively low throughout the study with no difference across seasons or precipitation conditions. Concentrations of HF183 Taqman, DogBact, and Rum2Bac were positively correlated with culturable E. coli concentrations; however, DogBact had the largest R 2 value among the three markers, and the forward stepwise regression indicated it was the best predictor of culturable E. coli concentrations at the BacteriALERT sites. Recursive partitioning indicated that BAV exceedances of model-based E. coli estimates were best explained by DogBact concentrations ≥3 gene copies per mL (CN/mL). Detections of esp2 at BacteriALERT sites were best explained by DogBact concentrations ≥11 CN/mL, while detections of esp2 at synoptic sites were best explained by HF183 Taqman ≥29 CN/mL. At the synoptic sites, HF183 Taqman levels were associated with wastewater treatment plant density. However, this relationship was driven primarily by a single site, suggesting possible conveyance issues in that catchment. esp2 detections at synoptic sites were positively associated with development within a 2-km radius and negatively associated with development within the catchment, suggesting multiple sources of esp2 in the watershed. DogBact and Rum2Bac were not associated with the land use features included in our analyses. Implications for Park management include: 1) fecal contamination levels were highest during wet conditions and in the off season when fewer visitors are expected to be participating in water-based recreation, 2) dogs are likely contributors to fecal contamination in the CRNRA and may be sources of pathogenic bacteria indicating further investigation of the origins of this contamination may be warranted as would be research to understand the human health risks from exposure to dog fecal contamination, and 3) high levels of the human marker at one site in the CRNRA watershed suggests more extensive monitoring in that catchment may locate the origin of human fecal contamination detected during this study.

Georgia↗

Greenhouse gas emissions from diverse Arctic Alaskan lakes are dominated by young carbon

Climate-sensitive Arctic lakes have been identified as conduits for ancient permafrost-carbon (C) emissions and as such accelerate warming. However, the environmental factors that control emission pathways and their sources are unclear; this complicates upscaling, forecasting and climate-impact-assessment efforts. Here we show that current whole-lake CH 4 and CO 2 emissions from widespread lakes in Arctic Alaska primarily originate from organic matter fixed within the past 3–4 millennia (modern to 3,300 ± 70 years before the present), and not from Pleistocene permafrost C. Furthermore, almost 100% of the annual diffusive C flux is emitted as CO 2 . Although the lakes mostly processed younger C (89 ± 3% of total C emissions), minor contributions from ancient C sources were two times greater in fine-textured versus coarse-textured Pleistocene sediments, which emphasizes the importance of the underlying geological substrate in current and future emissions. This spatially extensive survey considered the environmental and temporal variability necessary to monitor and forecast the fate of ancient permafrost C as Arctic warming progresses.

Alaska↗

Assessing the feasibility of satellite-based thresholds for hydrologically driven landsliding

Elevated soil moisture and heavy precipitation contribute to landslides worldwide. These environmental variables are now being resolved with satellites at spatiotemporal scales that could offer new perspectives on the development of landslide warning systems. However, the application of these data to hydro-meteorological thresholds (which account for antecedent soil moisture and rainfall) first need to be evaluated with respect to proven, direct measurement-based thresholds that use rain gauges and in situ soil moisture sensors. Here, we compare ground-based hydrologic data to overlapping satellite-based data before, during, and after a recent season of widespread shallow landsliding in the San Francisco Bay Area (California, USA). We then explore how the remotely sensed information could be used to empirically define hypothetical thresholds for shallow landsliding. We find that the ground-based thresholds developed with a single monitoring station show superior performance because the in situ soil saturation data better reflect the gravity-dominated subsurface flow conditions that are characteristic of hillslopes during the rainy season. Although the satellite-based thresholds can identify most of the landslide days, they include a greater number of false alarms due to overestimates of soil moisture between major storm events. To avoid the type of false alarms that are characteristic of our satellite-based thresholds, further post-processing of the near-surface hydrologic response data to better reflect gravity-dominated drainage should be integrated into satellite-based model outputs. Our results encourage further deployment of ground stations in landslide-prone terrain and cautious exploration of satellite-based hydro-meteorological thresholds where in situ networks are nonexistent.

California↗

Effects of lead in nestling black-crowned night-herons (Nycticorax nycticorax) experimentally dosed in the field

Lead is a known environmental toxicant, and poisoning resulting from the ingestion of lead shot has been well-documented in many species of waterfowl. However, much less is known regarding exposure and effects of free environmental lead in species of birds other than waterfowl. In an attempt to evaluate toxicity of lead to herons and to determine the usefulness of feathers as a non-invasive exposure-monitoring tool, black-crowned night-heron nestlings were dosed with lead to determine its distribution among tissues, and its effects on biochemical biomarkers, growth, and survival. Five-day-old heron nestlings (one per nest) at Chincoteague Bay, Virginia were given a single intra-peritoneal injection of dosing vehicle (control; N=7) or one of three lead solutions (as lead nitrate) (10, 50, or 250 mg/kg body weight of nestling; N=7 per dose) chosen to represent levels below, at, and above those found in moderately-polluted environments. All nestlings treated with lead exhibited dose-dependent inhibition of delta-aminolevulinic acid dehydratase (ALAD) activity compared to controls, and nestlings treated with the highest concentration showed a reduced carcass weight compared to controls. Of several measures of oxidative stress that were analyzed, significant differences were found between low- and high-dosed nestlings in hepatic total thiol and protein-bound sulfhydryl concentrations. No differences in survival were detected between dosed nestlings, controls, or uninjected siblings. Lead concentrations in several matrices, including feathers, are being determined to assess distribution among tissues and will also be examined for relationships with measures of effect.

Society of Environmental Toxicology and Chemistry,↗