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A land-use and water-quality history of White Rock Lake Reservoir, Dallas, Texas, based on paleolimnological analyses

White Rock Lake reservoir in Dallas, Texas contains a 150-cm sediment record of silty clay that documents land-use changes since its construction in 1912. Pollen analysis corroborates historical evidence that between 1912 and 1950 the watershed was primarily agricultural. Land disturbance by plowing coupled with strong and variable spring precipitation caused large amounts of sediment to enter the lake during this period. Diatoms were not preserved at this time probably because of low productivity compared to diatom dissolution by warm, alkaline water prior to burial in the sediments. After 1956, the watershed became progressively urbanized. Erosion decreased, land stabilized, and pollen of riparian trees increased as the lake water became somewhat less turbid. By 1986 the sediment record indicates that diatom productivity had increased beyond rates of diatom destruction. Neither increased nutrients nor reduced pesticides can account for increased diatom productivity, but grain size studies imply that before 1986 diatoms were light limited by high levels of turbidity. This study documents how reservoirs may relate to land-use practices and how watershed management could extend reservoir life and improve water quality.

Journal of Paleolimnology↗

Contribution of arsenic and uranium in private wells and community water systems to urinary biomarkers in US adults: The Strong Heart Study and the Multi-Ethnic Study of Atherosclerosis

Background Chronic exposure to inorganic arsenic (As) and uranium (U) in the United States (US) occurs from unregulated private wells and federally regulated community water systems (CWSs). The contribution of water to total exposure is assumed to be low when water As and U concentrations are low. Objective We examined the contribution of water As and U to urinary biomarkers in the Strong Heart Family Study (SHFS), a prospective study of American Indian communities, and the Multi-Ethnic Study of Atherosclerosis (MESA), a prospective study of racially/ethnically diverse urban U.S. communities. Methods We assigned residential zip code-level estimates in CWSs (µg/L) and private wells (90th percentile probability of As >10 µg/L) to up to 1485 and 6722 participants with dietary information and urinary biomarkers in the SHFS (2001–2003) and MESA (2000–2002; 2010–2011), respectively. Urine As was estimated as the sum of inorganic and methylated species, and urine U was total uranium. We used linear mixed-effects models to account for participant clustering and removed the effect of dietary sources via regression adjustment. Results The median (interquartile range) urine As was 5.32 (3.29, 8.53) and 6.32 (3.34, 12.48) µg/L for SHFS and MESA, respectively, and urine U was 0.037 (0.014, 0.071) and 0.007 (0.003, 0.018) µg/L. In a meta-analysis across both studies, urine As was 11% (95% CI: 3, 20%) higher and urine U was 35% (5, 73%) higher per twofold higher CWS As and U, respectively. In the SHFS, zip-code level factors such as private well and CWS As contributed 46% of variation in urine As, while in MESA, zip-code level factors, e.g., CWS As and U, contribute 30 and 49% of variation in urine As and U, respectively. Impact statement We found that water from unregulated private wells and regulated CWSs is a major contributor to urinary As and U (an estimated measure of internal dose) in both rural, American Indian populations and urban, racially/ethnically diverse populations nationwide, even at levels below the current regulatory standard. Our findings indicate that additional drinking water interventions, regulations, and policies can have a major impact on reducing total exposures to As and U, which are linked to adverse health effects even at low levels.

Journal of Exposure Science and Environmental Epid↗

Shell thinning and pesticide residues in Texas aquatic bird eggs, 1970

Significant decreases in eggshell thickness were found in 15 of 22 species of aquatic birds in Texas in 1970. Shell thickness reductions of 9 to 15 percent were found in white pelicans (Pelecanus erythrorhynchos), brown pelicans (P .occidentalis), and great blue herons (Ardea herodias). DDT family compounds were found in all eggs, and mean residues ranged from 0.4 ppm in white ibis (Eudocimus albus) to 23.2 ppm in great egrets (Casmerodius albus). GDDT residues were negatively correlated with shell thickness in five species; PCBs were negatively correlated in two. Residues in marine birds were generally lower and more uniform than levels in birds feeding in fresh and brackish water. DDT and dieldrin residues were higher in eggs from colonies near agricultural areas where these insecticides were heavily used; higher PCB residues were consistently associated with urban and industrial areas. Populations of five species have declined and deserve continued study: brown pelican, reddish egret (Dichromanassa rufescens), white-faced ibis (Plegadis chihi), laughing gull (Larus atricilla), and Forster's tern (Sterna forsteri). Population trends of four other species were undetermined and should be followed closely in future years.

Pesticides Monitoring Journal↗

Evaluation of osprey habitat suitability and interaction with contaminant exposure

Ospreys (Pandion haliaetus) have been the focus of conservation efforts since their dramatic population decline attributed to dichlorodiphenyltrichloroethane and related chemicals in the 1960s. Several recent studies of ospreys nesting in the United States have indicated improved reproduction. However, the density of breeding ospreys varies greatly among locations, with some areas seemingly habitable but not occupied. Because of concerns about pollution in the highly industrialized portions of the Delaware River and Bay, USA, we evaluated contaminant exposure and productivity in ospreys nesting on the Delaware River and Bay in 2002. We characterized habitat in the coastal zone of Delaware, USA, and the area around the river in Pennsylvania, USA, using data we collected as well as extant information provided by state and federal sources. We characterized habitat based on locations of occupied osprey nests in Delaware and Pennsylvania. We evaluated water clarity, water depth, land use and land cover, nest availability, and contaminants in sediment for use in a nest-occupancy model. Our results demonstrated that the presence of occupied nests was associated with water depth, water clarity, distance to an occupied osprey nest, and presence of urban land use, whereas a companion study demonstrated that hatching success was associated with the principal components derived from organochlorine-contaminant concentrations in osprey eggs (total polychlorinated biphenyls, p,p'-dichlorodiphenylethylene, chlordane and metabolites, and heptachlor epoxide). Our study provides guidelines for resource managers and local conservation organizations in management of ospreys and in development of habitat models that are appropriate for other piscivorous and marsh-nesting birds.

Journal of Wildlife Management↗

Pb-Sr isotopic and geochemical constraints on sources and processes of lead contamination in well waters and soil from former fruit orchards, Pennsylvania, USA: A legacy of anthropogenic activities

Isotopic discrimination can be an effective tool in establishing a direct link between sources of Pb contamination and the presence of anomalously high concentrations of Pb in waters, soils, and organisms. Residential wells supplying water containing up to 1600 ppb Pb to houses built on the former Mohr orchards commercial site, near Allentown, PA, were evaluated to discern anthropogenic from geogenic sources. Pb (n = 144) and Sr (n = 40) isotopic data and REE (n = 29) data were determined for waters from residential wells, test wells (drilled for this study), and surface waters from pond and creeks. Local soils, sediments, bedrock, Zn-Pb mineralization and coal were also analyzed (n = 94), together with locally used Pb-As pesticide (n = 5). Waters from residential and test wells show overlapping values of 206 Pb/ 207 Pb, 208 Pb/ 207 Pb and 87 Sr/ 86 Sr. Larger negative Ce anomalies (Ce/Ce*) distinguish residential wells from test wells. Results show that residential and test well waters, sediments from residential water filters in water tanks, and surface waters display broad linear trends in Pb isotope plots. Pb isotope data for soils, bedrock, and pesticides have contrasting ranges and overlapping trends. Contributions of Pb from soils to residential well waters are limited and implicated primarily in wells having shallow water-bearing zones and carrying high sediment contents. Pb isotope data for residential wells, test wells, and surface waters show substantial overlap with Pb data reflecting anthropogenic actions (e.g., burning fossil fuels, industrial and urban processing activities). Limited contributions of Pb from bedrock, soils, and pesticides are evident. High Pb concentrations in the residential waters are likely related to sediment build up in residential water tanks. Redox reactions, triggered by influx of groundwater via wells into the residential water systems and leading to subtle changes in pH, are implicated in precipitation of Fe oxyhydroxides, oxidative scavenging of Ce(IV), and desorption and release of Pb into the residential water systems. The Pb isotope features in the residences and the region are best interpreted as reflecting a legacy of industrial Pb present in underlying aquifers that currently supply the drinking water wells.

Pennsylvania↗

A neural network approach for enhancing information extraction from multispectral image data

A back-propagation artificial neural network (ANN) was applied to classify multispectral remote sensing imagery data. The classification procedure included four steps: (i) noisy training that adds minor random variations to the sampling data to make the data more representative and to reduce the training sample size; (ii) iterative or multi-tier classification that reclassifies the unclassified pixels by making a subset of training samples from the original training set, which means the neural model can focus on fewer classes; (iii) spectral channel selection based on neural network weights that can distinguish the relative importance of each channel in the classification process to simplify the ANN model; and (iv) voting rules that adjust the accuracy of classification and produce outputs of different confidence levels. The Purdue Forest, located west of Purdue University, West Lafayette, Indiana, was chosen as the test site. The 1992 Landsat thematic mapper imagery was used as the input data. High-quality airborne photographs of the same Lime period were used for the ground truth. A total of 11 land use and land cover classes were defined, including water, broadleaved forest, coniferous forest, young forest, urban and road, and six types of cropland-grassland. The experiment, indicated that the back-propagation neural network application was satisfactory in distinguishing different land cover types at US Geological Survey levels II-III. The single-tier classification reached an overall accuracy of 85%. and the multi-tier classification an overall accuracy of 95%. For the whole test, region, the final output of this study reached an overall accuracy of 87%. ?? 2005 CASI.

Canadian Journal of Remote Sensing↗

Regional patterns of anthropogenic influences on streams and rivers in the conterminous United States, from the early 1970s to 2012

This paper introduces a dataset containing consistent time-series measurements of anthropogenic activities potentially affecting stream quality across the conterminous United States and summarizes the most noteworthy trends from 61 variables in 16 categories. Data include measures of atmospheric deposition, agricultural production, livestock, urbanization, irrigation, land use, nutrients from fertilizer, dams/reservoirs, and pesticide use, among others. The trend periods range from 10 to 40 years, beginning as early as 1970 and ending in 2012. Detailed summaries are provided for 1992-2012. Key results include: increase of urbanization and ‘exurbanization’, particularly in the South, Southwest, and Mid-Atlantic; increases in crop production and fertilizer use in much of the Midwest; increases in the concentration of livestock, particularly of hogs and pigs; increases in irrigation, dams, and reservoirs in the Lower Mississippi and Lower Missouri watersheds, widespread increase in the use of the pesticide glyphosate; and widespread decrease in atmospheric deposition of sulfate. These results and others provide a framework for evaluating potential causes of water-quality changes over the past four decades.

Journal of Land Use Science↗

Reconnaissance of surface water estrogenicity and the prevalence of intersex in smallmouth bass (Micropterus dolomieu) inhabiting New Jersey

The observation of testicular oocytes in male fishes has been utilized as a biomarker of estrogenic endocrine disruption. A reconnaissance project led in the Northeastern United States (US) during the period of 2008–2010 identified a high prevalence of intersex smallmouth bass on or near US Fish & Wildlife Service National Wildlife Refuges that included the observation of 100% prevalence in smallmouth bass males collected from the Wallkill River, NJ, USA. To better assess the prevalence of intersex smallmouth bass across the state of New Jersey, a tiered reconnaissance approach was initiated during the fall of 2016. Surface water samples were collected from 101 (85 river, 16 lake/reservoir) sites across the state at base-flow conditions for estrogenicity bioassay screening. Detectable estrogenicity was observed at 90% of the sites and 64% were above the US Environmental Protection Agency trigger level of 1 ng/L. Median surface water estrogenicity was 1.8 ng/L and a maximum of 6.9 ng/L E2EqBLYES was observed. Adult smallmouth bass were collected from nine sites, pre-spawn during the spring of 2017. Intersex was identified in fish at all sites, and the composite intersex prevalence was 93.8%. Prevalence across sites ranged from 70.6% to 100%. In addition to intersex, there was detectable plasma vitellogenin in males at all sites. Total estrogenicity in surface water was determined at these fish collection sites, and notable change over time was observed. Correlation analysis indicated significant positive correlations between land use (altered land; urban + agriculture) and surface water estrogenicity. There were no clear associations between land use and organismal metrics of estrogenic endocrine disruption (intersex or vitellogenin). This work establishes a baseline prevalence of intersex in male smallmouth bass in the state of New Jersey at a limited number of locations and identifies a number of waterbodies with estrogenic activity above an effects-based threshold.

New Jersey↗

Linkages between land-use change and groundwater management foster long-term resilience of water supply in California

Study Region We created a 270-m coupled model of land-use and groundwater conditions, LUCAS-W[ater], for California’s Central Coast. This groundwater-dependent region is undergoing a dramatic reorganization of groundwater management under California’s 2014 Sustainable Groundwater Management Act (SGMA). Study Focus Understanding land-use and land-cover change supports long-term sustainable water management. Anthropogenic water demand has depleted groundwater aquifers worldwide, while future water shortages will likely affect land-use change, creating system feedbacks. Our novel participatory approach fused changes in land-use and associated water use from county-scale data to local water agencies’ estimates of total sustainable supply, scaling up local hydro-geologic knowledge from heterogeneous aquifers and diverse management approaches to a regional level. We assessed five stakeholder-driven scenarios with the same historic rates of urban and agricultural land-use change, but different water and land-use management, analyzing how management strategies altered both the spatial pattern of development and subsequent water sustainability from 2001 to 2061. New Hydrological Insights for the Region Transformative strategies using demand-side interventions that coupled water availability to land-use more effectively achieved long-term sustainability than adaptive strategies using supply-side interventions to increase water supplies. Limiting water withdrawals within SGMA regulated basins resulted in leakage of development into unregulated basins, increasing groundwater pumping there. Protecting ecosystems, farmlands, and recharge areas from development reduced leakage into undeveloped basins without negatively affecting water sustainability.

California↗

Using integrated step-selection analyses to map high-risk electrocution areas for a highly mobile species

Knowledge of animal-movement patterns is a crucial component in identifying areas with high potential for human–wildlife conflict and in prioritizing associated management actions. Electrical energy infrastructure is a major source of mortality for animals worldwide, with millions of birds colliding with or being electrocuted by power lines and power-pole infrastructure each year. Movement, habitat use, and the spatial distribution of electrocution risk can vary with age, but studies of younger age classes are often hampered because these groups are difficult to observe and lack well-defined home ranges. To identify movement patterns and high-use areas of bald eagles in Arizona, USA, we analyzed global positioning system (GPS) telemetry data collected from 13 immature bald eagles ( Haliaeetus leucocephalus ) across Arizona between 2017 and 2023. We built multi-scale, integrated step-selection functions that evaluated eagle responses to a suite of environmental covariates. We then used these models to simulate eagle movement and predict habitat use within and surrounding Maricopa County, which contains both the Phoenix Metropolitan Area and the plurality of bald eagle breeding areas in Arizona. We provide a use case for how these simulated movements could be used by resource managers to identify high-risk areas for electrocution. Eagles avoided urban areas and selected steeper slopes, more pronounced ridges, and areas with greater water and wetland land cover. Predicted habitat use by bald eagles was greatest near waterbodies and along ridges and steep slopes, and indicated where power infrastructure may pose greater electrocution risk. We show how integrated step-selection analyses and movement path simulation may be used for subadult animals lacking stable home ranges to predict high-use areas and identify locations with greater potential for negative human–wildlife interactions.

Arizona↗

Response of benthic algae to environmental gradients in an agriculturally dominated landscape

Benthic algal communities were assessed in an agriculturally dominated landscape in the Central Columbia Plateau, Washington, to determine which environmental variables best explained species distributions, and whether algae species optima models were useful in predicting specific water-quality parameters. Land uses in the study area included forest, range, urban, and agriculture. Most of the streams in this region can be characterized as open-channel systems influenced by intensive dryland (nonirrigated) and irrigated agriculture. Algal communities in forested streams were dominated by blue-green algae, with communities in urban and range streams dominated by diatoms. The predominance of either blue-greens or diatoms in agricultural streams varied greatly depending on the specific site. Canonical correspondence analysis (CCA) indicated a strong gradient effect of several key environmental variables on benthic algal community composition. Conductivity and % agriculture were the dominant explanatory variables when all sites ( n = 24) were included in the CCA; water velocity replaced conductivity when the CCA included only agricultural and urban sites. Other significant explanatory variables included dissolved inorganic nitrogen (DIN), orthophosphate (OP), discharge, and precipitation. Regression and calibration models accurately predicted conductivity based on benthic algal communities, with OP having slightly lower predictability. The model for DIN was poor, and therefore may be less useful in this system. Thirty-four algal taxa were identified as potential indicators of conductivity and nutrient conditions, with most indicators being diatoms except for the blue-greens Anabaena sp. and Lyngbya sp.

Journal of the North American Benthological Societ↗

Stream water temperature limits occupancy of salamanders in mid-Atlantic protected areas

Stream ecosystems are particularly sensitive to urbanization, and tolerance of water-quality parameters is likely important to population persistence of stream salamanders. Forecasted climate and landscape changes may lead to significant changes in stream flow, chemical composition, and temperatures in coming decades. Protected areas where landscape alterations are minimized will therefore become increasingly important for salamander populations. We surveyed 29 streams at three national parks in the highly urbanized greater metropolitan area of Washington, DC. We investigated relationships among water-quality variables and occupancy of three species of stream salamanders ( Desmognathus fuscus , Eurycea bislineata , and Pseudotriton ruber ). With the use of a set of site-occupancy models, and accounting for imperfect detection, we found that stream-water temperature limits salamander occupancy. There was substantial uncertainty about the effects of the other water-quality variables, although both specific conductance (SC) and pH were included in competitive models. Our estimates of occupancy suggest that temperature, SC, and pH have some importance in structuring stream salamander distribution.

Maryland, Virginia, West Virginia↗

An analysis of urban development and its environmental impact on the Tampa Bay watershed

Urbanization has transformed natural landscapes into anthropogenic impervious surfaces. Urban land use has become a major driving force for land cover and land use change in the Tampa Bay watershed of west-central Florida. This study investigates urban land use change and its impact on the watershed. The spatial and temporal changes, as well as the development density of urban land use are determined by analyzing the impervious surface distribution using Landsat satellite imagery. Population distribution and density are extracted from the 2000 census data. Non-point source pollution parameters used for measuring water quality are analyzed for the sub-drainage basins of Hillsborough County. The relationships between 2002 urban land use, population distribution and their environmental influences are explored using regression analysis against various non-point source pollutant loadings in these sub-drainage basins. The results suggest that strong associations existed between most pollutant loadings and the extent of impervious surface within each sub-drainage basin in 2002. Population density also exhibits apparent correlations with loading rates of several pollutants. Spatial variations of selected non-point source pollutant loadings are also assessed.

Journal of Environmental Management↗

Regression modeling of particle size distributions in urban stormwater: Advancements through improved sample collection methods

A new sample collection system was developed to improve the representation of sediment entrained in urban storm water by integrating water quality samples from the entire water column. The depth-integrated sampler arm (DISA) was able to mitigate sediment stratification bias in storm water, thereby improving the characterization of suspended-sediment concentration and particle size distribution at three independent study locations. Use of the DISA decreased variability, which improved statistical regression to predict particle size distribution using surrogate environmental parameters, such as precipitation depth and intensity. The performance of this statistical modeling technique was compared to results using traditional fixed-point sampling methods and was found to perform better. When environmental parameters can be used to predict particle size distributions, environmental managers have more options when characterizing concentrations, loads, and particle size distributions in urban runoff.

Wisconsin↗

Effects of stormwater infiltration on quality of groundwater beneath retention and detention basins

Infiltration of storm water through detention and retention basins may increase the risk of groundwater contamination, especially in areas where the soil is sandy and the water table shallow, and contaminants may not have a chance to degrade or sorb onto soil particles before reaching the saturated zone. Groundwater from 16 monitoring wells installed in basins in southern New Jersey was compared to the quality of shallow groundwater from 30 wells in areas of new-urban land use. Basin groundwater contained much lower levels of dissolved oxygen, which affected concentrations of major ions. Patterns of volatile organic compound and pesticide occurrence in basin groundwater reflected the land use in the drainage areas served by the basins, and differed from patterns in background samples, exhibiting a greater occurrence of petroleum hydrocarbons and certain pesticides. Dilution effects and volatilization likely decrease the concentration and detection frequency of certain compounds commonly found in background groundwater. High recharge rates in storm water basins may cause loading factors to be substantial even when constituent concentrations in infiltrating storm water are relatively low.

New Jersey↗

Regional patterns of pesticide concentrations in surface waters of New York in 1997

The predominant mixtures of pesticides found in New York surface waters consist of five principal components. First, herbicides commonly used on corn (atrazine, metolachlor, alachlor, cyanazine) and a herbicide degradate (deethylatrazine) were positively correlated to a corn-herbicide component, and watersheds with the highest corn-herbicide component scores were those in which large amounts of row crops are grown. Second, two insecticides (diazinon and carbaryl) and one herbicide (prometon) widely used in urban and residential settings were positively correlated to an urban/residential component. Watersheds with the highest urban/residential component scores were those with large amounts of urban and residential land use. A third component was related to two herbicides (EPTC and cyanazine) used on dry beans and corn, the fourth to an herbicide (simazine) and an insecticide (carbaryl) commonly used in orchards and vineyards, and the fifth to an herbicide (DCPA). Results of this study indicate that this approach can be used to: (1) identify common mixtures of pesticides in surface waters, (2) relate these mixtures to land use and pesticide applications, and (3) indicate regions where these mixtures of pesticides are commonly found.

New York↗

Determination of bromine, chlorine and iodine in environmental aqueous samples by epithermal neutron activation analysis and Compton suppression

Halides, particularly Br- and Cl-, have been used as indicators of potential sources of Na+ and Cl- in surface water and groundwater with limited success. Contamination of groundwater and surface water by Na+ and Cl- is a common occurrence in growing urban areas and adversely affects municipal and private water supplies in Illinois and other states, as well as vegetation in environmentally sensitive areas. Neutron activation analysis (NAA) can be effectively used to determine these halogens, but often the elevated concentrations of sodium and chlorine in water samples can give rise to very high detection limits for bromine and iodine due to elevated backgrounds from the activation process. We present a detailed analytical scheme to determine Cl, Br and I in aqueous samples with widely varying Na and Cl concentrations using epithermal NAA in conjunction with Compton suppression. ?? 2006 Akade??miai Kiado??.

Journal of Radioanalytical and Nuclear Chemistry↗

Metal prices in the United States through 2010

This report, which updates and revises the U.S. Geological Survey (USGS) (1999) publication, “Metal Prices in the United States Through 1998,” presents an extended price history for a wide range of metals available in a single document. Such information can be useful for the analysis of mineral commodity issues, as well as for other purposes. The chapter for each mineral commodity includes a graph of annual current and constant dollar prices for 1970 through 2010, where available; a list of significant events that affected prices; a brief discussion of the metal and its history; and one or more tables that list current dollar prices. In some cases, the metal prices presented herein are for some alternative form of an element or, instead of a price, a value, such as the value for an import as appraised by the U.S. Customs Service. Also included are the prices for steel, steel scrap, and iron ore—steel because of its importance to the elements used to alloy with it, and steel scrap and iron ore because of their use in steelmaking. A few minor metals, such as calcium, potassium, sodium, strontium, and thorium, for which price histories were insufficient, were excluded. The annual prices given may be averages for the year, yearend prices, or some other price as appropriate for a particular commodity. Certain trade journals have been the source of much of this price information—American Metal Market, ICIS Chemical Business, Engineering and Mining Journal, Industrial Minerals, Metal Bulletin, Mining Journal, Platts Metals Week, Roskill Information Services Ltd. commodity reports, and Ryan’s Notes. Price information also is available in minerals information publications of the USGS (1880–1925, 1996–present) and the U.S. Bureau of Mines (1926–95), such as Mineral Commodity Summaries, Mineral Facts and Problems, Mineral Industry Surveys, and Minerals Yearbook. In addition to prices themselves, these journals and publications contain information relevant to prices, which has been helpful in the preparation of this publication. Prices in this report have been graphed in 1992 constant dollars to show the effects of inflation as measured by the U.S. Bureau of Labor Statistics Consumer Price Index for All Urban Consumers, a widely used measure of overall inflation in the United States. These prices are not tabulated, but a table of the deflators used is given in an appendix. Constant dollar prices can be used to show how prices that producers receive would have less purchasing power.

Scientific Investigations Report↗