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Surface-water quality in the West Branch Susquehanna River basin, Pennsylvania: An appraisal of areal and temporal variability from 1962 to 1982 in hydrologic accounting unit 020502

The West Branch Susquehanna River basin has a drainage area of 6,955 square miles in north-central Pennsylvania and comprises Hydrologic Accounting Unit 020502. A National Stream Quality Accounting Network (NASQAN) waterquality data collection site, maintained by the U.S. Geological Survey, is located on the river near its mouth at Lewisburg, Pennsylvania. Water-quality data are collected at numerous other sites throughout the basin by the Pennsylvania Department of Environmental Resources, Bureau of Water Quality Management. Data collected from the NASQAN site and the sites operated by the Pennsylvania Department of Environmental Resources from 1962 to 1982 were used to evaluate water-quality variability in the basin. The following objectives were addressed: (1) describe the surface-water quality upstream of the NASQAN site on an areal and temporal basis; (2) relate the water-quality variability, on both an areal and temporal basis, to general basin characteristics; and (3) assess the ability of the water-quality data collected at the NASQAN site to represent, on both an areal and temporal basis the water quality for Hydrologic Accounting Unit 020502 upstream from the site. Areally, the water quality varies considerably throughout the basin. Generally, the river was found to have moderately good water quality in the upper reaches, poor water quality in its middle reach, and good water quality near the mouth. Two tributaries, Moshannon Creek (median pH 3.9) and Bald Eagle Creek (median pH 7.8), had the most pronounced effect on the water quality of the river. Temporal trends were found in the concentrations of several of the constituents at most of the stations. Of the constituents analyzed, those which exhibited increasing or decreasing trends most frequently were pH, alkalinity, dissolved sulfate, total ammonia, and total nitrite plus nitrate. The largest trends were in the concentrations of total-recoverable aluminum, manganese, and zinc. Causes of areal variation were attributed to land use and geologic variations throughout the basin. Trends which indicated an improvement in water qualijty are believed to be caused by improvements in the treatment of acid mine drainage and wastewater. Trends which indicated degradation of water quality were generally found in areas where these types of treatment are not yet effective. The NASQAN site at Lewisburg was shown not to represent the water quality of the entire basin, either areally or temporally. It does, however, represent the water quality of the West Branch Susquehanna River at its mouth.

Pennsylvania

Hydrologic conditions and water-quality conditions following underground coal mining in the North Fork of the Right Fork of Miller Creek drainage basin, Carbon and Emery Counties, Utah, 2004-2005

In 2004 and 2005, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, reassessed the hydrologic system in and around the drainage basin of the North Fork of the Right Fork (NFRF) of Miller Creek, in Carbon and Emery Counties, Utah. The reassessment occurred 13 years after cessation of underground coal mining that was performed beneath private land at shallow depths (30 to 880 feet) beneath the NFRF of Miller Creek. This study is a follow-up to a previous USGS study of the effects of underground coal mining on the hydrologic system in the area from 1988 to 1992. The previous study concluded that mining related subsidence had impacted the hydrologic system through the loss of streamflow over reaches of the perennial portion of the stream, and through a significant increase in dissolved solids in the stream. The previous study also reported that no substantial differences in spring-water quality resulted from longwall mining, and that no clear relationship between mining subsidence and spring discharge existed. During the summers of 2004 and 2005, the USGS measured discharge and collected water-quality samples from springs and surface water at various locations in the NFRF of Miller Creek drainage basin, and maintained a streamflow-gaging station in the NFRF of Miller Creek. This study also utilized data collected by Cyprus–Plateau Mining Corporation from 1992 through 2001. Of thirteen monitored springs, five have discharge levels that have not returned to those observed prior to August 1988, which is when longwall coal mining began beneath the NFRF of Miller Creek. Discharge at two of these five springs appears to fluctuate with wet and dry cycles and is currently low due to a drought that occurred from 1999–2004. Discharge at two other of the five springs did not increase with increased precipitation during the mid-1990s, as was observed at other monitored springs. This suggests that flowpaths to these springs may have been altered by land subsidence caused by underground coal mining. Analysis of possible impacts to the fifth spring were inconclusive due to a lack of data collected during the mid-1990s. Discharge at eight other monitored springs in the study area appears to be controlled mainly by climatic fluctuations and was generally near the value measured prior to 1988. Discharge at one of these eight springs is significantly greater than that measured during the longwall mining period. Concentrations of magnesium, calcium, sulfate, and dissolved solids at one undermined spring were elevated in relation to other springs in the study area. Dissolved solids concentration at this spring ranged from 539–709 milligrams per liter. Dissolved-solids concentration for all other springs in the study area ranged from 163 to 360 milligrams per liter and was near the median value measured prior to longwall mining beneath the NFRF of Miller Creek drainage basin. Baseflow measured at a streamflow-gaging station on the NFRF of Miller Creek located downstream of the mined area during the summer of 2004 was near 5 gallons per minute. Baseflow in 2005 increased to 7–8 gallons per minute, due to increased precipitation. This is slightly greater than the range of baseflow measured near the end of the longwall mining period which was approximately 3–5 gallons per minute. Seepage investigations carried out in the summer of 2004 and 2005 along the NFRF of Miller Creek showed a net loss of surface flow along the studied reach. Specific areas within the study reach had streamflow losses prior to longwall mining, however, the study reach as a whole was observed to gain in discharge when measured in 1986–1988, immediately before longwall mining began. The area where the greatest loss in discharge from the NFRF of Miller Creek occurred corresponds to an area where overburden (material overlying a deposit of useful geological materials or bedrock) is between 700 and 210 feet thick. Overburden thickness at the place where the streambed first dried up was approximately 600 feet thick. In 2004, approximately 1,600 ft of the streambed of the NFRF of Miller Creek was dry. Only 300 feet of the streambed was dry during the wetter year of 2005. Prior to longwall mining, no dry reaches were observed, though seepage loss was documented. Average discharge measured at a tributary to the NFRF of Miller Creek has increased from 1.6 gallons per minute measured during longwall mining to 7.2 gallons per minute measured in 2004–2005. During both years of this study, the lower reach of the stream regained flow from this tributary and from seepage gains. Water quality in the lower reach of the NFRF of Miller Creek downstream of the longwall-mined area, showed significantly higher concentrations of magnesium, calcium, sulfate, and strontium, in relation to water in the upper reach of the NFRF of Miller Creek and to the springs sampled in the area. Dissolved-solids concentration measured in the lower reach of the stream in 2004 and 2005 ranged from 1,880 to 2,220 milligrams per liter, while sulfate concentrations ranged from 1,090 to 1,320 mg/L. The maximum contaminant level for drinking water in the state of Utah for dissolved solids and sulfate is 2,000 and 1,000 mg/L respectively. Concentrations of these ions are slightly greater than those measured during and just following mining beneath the NFRF of Miller Creek drainage basin, but are significantly higher than those measured prior to mining. With the exception of strontium, dissolved metals concentrations in the NFRF of Miller Creek were similar to those measured in area springs. pH in the creek and at all spring sites was near neutral. Qualitative observations of the creek bottom suggest that mining-related activities have had little effect on vegetative growth.

Utah

Estimation of volume and mass and of changes in volume and mass of selected chat piles in the Picher mining district, Ottawa County, Oklahoma, 2005-10

From the 1890s through the 1970s the Picher mining district in northeastern Ottawa County, Oklahoma, was the site of mining and processing of lead and zinc ore. When mining ceased in about 1979, as much as 165–300 million tons of mine tailings, locally referred to as “chat,” remained in the Picher mining district. Since 1979, some chat piles have been mined for aggregate materials and have decreased in volume and mass. Currently (2013), the land surface in the Picher mining district is covered by thousands of acres of chat, much of which remains on Indian trust land owned by allottees. The Bureau of Indian Affairs manages these allotted lands and oversees the sale and removal of chat from these properties. To help the Bureau of Indian Affairs better manage the sale and removal of chat, the U.S. Geological Survey, in cooperation with the Bureau of Indian Affairs, estimated the 2005 and 2010 volumes and masses of selected chat piles remaining on allotted lands in the Picher mining district. The U.S. Geological Survey also estimated the changes in volume and mass of these chat piles for the period 2005 through 2010. The 2005 and 2010 chat-pile volume and mass estimates were computed for 34 selected chat piles on 16 properties in the study area. All computations of volume and mass were performed on individual chat piles and on groups of chat piles in the same property. The Sooner property had the greatest estimated volume (4.644 million cubic yards) and mass (5.253 ± 0.473 million tons) of chat in 2010. Five of the selected properties (Sooner, Western, Lawyers, Skelton, and St. Joe) contained estimated chat volumes exceeding 1 million cubic yards and estimated chat masses exceeding 1 million tons in 2010. Four of the selected properties (Lucky Bill Humbah, Ta Mee Heh, Bird Dog, and St. Louis No. 6) contained estimated chat volumes of less than 0.1 million cubic yards and estimated chat masses of less than 0.1 million tons in 2010. The total volume of all selected chat piles was estimated to be 18.073 million cubic yards in 2005 and 16.171 million cubic yards in 2010. The total mass of all selected chat piles was estimated to be 20.445 ± 1.840 million tons in 2005 and 18.294 ± 1.646 million tons in 2010. All of the selected chat piles decreased in volume and mass for the period 2005 through 2010. Chat piles CP022 (Ottawa property) and CP013 (Sooner property) had some within-property chat-pile redistribution, with both chat piles having net decreases in volume and mass for the period 2005 through 2010. The Sooner property and the St. Joe property had the greatest volume (and mass) changes, with 1.266 million cubic yards and 0.217 million cubic yards (1.432 ± 0.129 million tons and 0.246 ± 0.022 million tons) of chat being removed, respectively. The chat removed from the Sooner and St. Joe properties accounts for about 78 percent of the chat removed from all selected chat piles and properties. The total volume and mass removed from all selected chat piles for the period 2005 through 2010 were estimated to be 1.902 million cubic yards and 2.151 ± 0.194 million tons, respectively.

Oklahoma

Geologic map of the Mount Trumbull 30' X 60' quadrangle, Mohave and Coconino Counties, northwestern Arizona

The geologic map of the Mount Trumbull 30' x 60' quadrangle is a cooperative product of the U.S. Geological Survey, the National Park Service, and the Bureau of Land Management that provides geologic map coverage and regional geologic information for visitor services and resource management of Grand Canyon National Park, Lake Mead Recreational Area, and Grand Canyon Parashant National Monument, Arizona. This map is a compilation of previous and new geologic mapping that encompasses the Mount Trumbull 30' x 60' quadrangle of Arizona. This digital database, a compilation of previous and new geologic mapping, contains geologic data used to produce the 100,000-scale Geologic Map of the Mount Trumbull 30' x 60' Quadrangle, Mohave and Coconino Counties, Northwestern Arizona. The geologic features that were mapped as part of this project include: geologic contacts and faults, bedrock and surficial geologic units, structural data, fold axes, karst features, mines, and volcanic features. This map was produced using 1:24,000-scale 1976 infrared aerial photographs followed by extensive field checking. Volcanic rocks were mapped as separate units when identified on aerial photographs as mappable and distinctly separate units associated with one or more pyroclastic cones and flows. Many of the Quaternary alluvial deposits that have similar lithology but different geomorphic characteristics were mapped almost entirely by photogeologic methods. Stratigraphic position and amount of erosional degradation were used to determine relative ages of alluvial deposits having similar lithologies. Each map unit and structure was investigated in detail in the field to ensure accuracy of description. Punch-registered mylar sheets were scanned at the Flagstaff Field Center using an Optronics 5040 raster scanner at a resolution of 50 microns (508 dpi). The scans were output in .rle format, converted to .rlc, and then converted to ARC/INFO grids. A tic file was created in geographic coordinates and projected into the base map projection (Polyconic) using a central meridian of -113.500. The tic file was used to transform the grid into Universal Transverse Mercator projection. The linework was vectorized using gridline. Scanned lines were edited interactively in ArcEdit. Polygons were attributed in ArcEdit and all artifacts and scanning errors visible at 1:100,000 were removed. Point data were digitized onscreen. Due to the discovery of digital and geologic errors on the original files, the ARC/INFO coverages were converted to a personal geodatabase and corrected in ArcMap. The feature classes which define the geologic units, lines and polygons, are topologically related and maintained in the geodatabase by a set of validation rules. The internal database structure and feature attributes were then modified to match other geologic map databases being created for the Grand Canyon region. Faults were edited with the downthrown block, if known, on the 'right side' of the line. The 'right' and 'left' sides of a line are determined from 'starting' at the line's 'from node' and moving to the line's end or 'to node'.

Arizona

Assessment of hydrology, water quality, and trace elements in selected placer-mined creeks in the birch creek watershed near central, Alaska, 2001-05

Executive Summary The U.S. Geological Survey, in cooperation with the Bureau of Land Management, completed an assessment of hydrology, water quality, and trace-element concentrations in streambed sediment of the upper Birch Creek watershed near Central, Alaska. The assessment covered one site on upper Birch Creek and paired sites, upstream and downstream from mined areas, on Frying Pan Creek and Harrison Creek. Stream-discharge and suspended-sediment concentration data collected at other selected mined and unmined sites helped characterize conditions in the upper Birch Creek watershed. The purpose of the project was to provide the Bureau of Land Management with baseline information to evaluate watershed water quality and plan reclamation efforts. Data collection began in September 2001 and ended in September 2005. There were substantial geomorphic disturbances in the stream channel and flood plain along several miles of Harrison Creek. Placer mining has physically altered the natural stream channel morphology and removed streamside vegetation. There has been little or no effort to re-contour waste rock piles. During high-flow events, the abandoned placer-mine areas on Harrison Creek will likely contribute large quantities of sediment downstream unless the mined areas are reclaimed. During 2004 and 2005, no substantial changes in nutrient or major-ion concentrations were detected in water samples collected upstream from mined areas compared with water samples collected downstream from mined areas on Frying Pan Creek and Harrison Creek that could not be attributed to natural variation. This also was true for dissolved oxygen, pH, and specific conductance-a measure of total dissolved solids. Sample sites downstream from mined areas on Harrison Creek and Frying Pan Creek had higher median suspended-sediment concentrations, by a few milligrams per liter, than respective upstream sites. However, it is difficult to attach much importance to the small downstream increase, less than 10 milligrams per liter, in median suspended-sediment concentration for either basin. During low-flow conditions in 2004 and 2005, previously mined areas investigated on Harrison Creek and on Frying Pan Creek did not contribute substantial suspended sediments to sample sites downstream from the mined areas. No substantial mining-related water- or sediment-quality problems were detected at any of the sites investigated in the upper Birch Creek watershed during low-flow conditions. Average annual streamflow and precipitation were near normal in 2002 and 2003. Drought conditions, extreme forest fire impact, and low annual streamflow set apart the 2004 and 2005 summer seasons. Daily mean streamflow for upper Birch Creek varied throughout the period of record-from maximums of about 1,000 cubic feet per second to minimums of about 20 cubic feet per second. Streamflow increased and decreased rapidly in response to rainfall and rapid snowmelt events because the steep slopes, thin soil cover, and permafrost areas in the watershed have little capacity to retain runoff. Median suspended-sediment concentrations for the 115 paired samples from Frying Pan Creek and 101 paired samples from Harrison Creek were less than the 20 milligrams per liter total maximum daily load. The total maximum daily load was set by the U.S. Environmental Protection Agency for the upper Birch Creek basin in 1996. Suspended-sediment paired-sample data were collected using automated samplers in 2004 and 2005, primarily during low-flow conditions. Suspended-sediment concentrations in grab samples from miscellaneous sites ranged from less than 1 milligram per liter during low-flow conditions to 1,386 milligrams per liter during a high-flow event on upper Birch Creek. Streambed-sediment samples were collected at six sites on Harrison Creek, two sites on Frying Pan Creek, and one site on upper Birch Creek. Trace-element concentrations of mercury, lead, and zinc in streambed sedimen

Scientific Investigations Report

Reconnaissance of chemical and biological quality in the Owyhee River from the Oregon State line to the Owyhee Reservoir, Oregon, 2001–02

The Owyhee River drains an extremely rugged and sparsely populated landscape in northern Nevada, southwestern Idaho, and eastern Oregon. Most of the segment between the Oregon State line and Lake Owyhee is part of the National Wild and Scenic Rivers System, and few water-quality data exist for evaluating environmental impacts. As a result, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, assessed this river segment to characterize chemical and biological quality of the river, identify where designated beneficial uses are met and where changes in stream quality occur, and provide data needed to address activities related to environmental impact assessments and Total Maximum Daily Loads. Water-quality issues identified at one or more sites were water temperature, suspended sediment, dissolved oxygen, pH, nutrients, trace elements, fecal bacteria, benthic invertebrate communities, and periphyton communities. Generally, summer water temperatures routinely exceeded Oregon's maximum 7-day average criteria of 17.8 degrees Celsius. The presence of few coldwater taxa in benthic invertebrate communities supports this observation. Suspended-sediment concentrations during summer base flow were less than 10 milligrams per liter (mg/L). Dissolved solids concentrations ranged from 46 to 222 mg/L, were highest during base flow, and tended to increase in a downstream direction. Chemical compositions of water samples indicated that large proportions of upland-derived water extend to the lower reaches of the study area during spring runoff. Dissolved fluoride and arsenic concentrations were highest during base flow and may be a result of geothermal springs discharging to the river. No dissolved selenium was detected. Upstream from the Rome area, spring runoff concentrations of suspended sediment ranged from 0 to 52 mg/L, and all except at the Three Forks site were typically below 20 mg/L. Stream-bottom materials from the North Fork Owyhee River, an area with no mines, were enriched with nine trace elements, which indicates that this basin may be a natural source of these elements. Near Rome, the part of the study area not included in the National Wild and Scenic Rivers System, land-use impacts resulted in elevated populations of Escherichia coli bacteria ( E. coli ) during base flow and elevated concentrations of nitrogen and phosphorus during spring runoff. Sites in this area had the highest numbers of benthic invertebrates; the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa; and the highest Hilsenhoff Biotic Index scores. These results suggest degraded stream quality. Periphyton communities at sites in this area approached nuisance levels and could cause significant dissolved oxygen depletions and pH values that exceed Oregon's recommended criteria. Stream-bottom materials from Jordan Creek were enriched with mercury and manganese, which probably were ultimately caused by past mining in that basin. Below Crooked Creek, elevated suspended sediment concentrations (142 mg/L), phosphorus concentrations (0.23 mg/L), and E. coli populations (370 most probable number per 100 milliliters) during the largest spring runoff event could be the result of inputs at the lower end of Jordan Valley and (or) inputs from Crooked Creek. The New Zealand Mud Snail, a highly competitive gastropod introduced to the Snake River in the 1980s, was collected just downstream from the Crooked Creek confluence.

Idaho;Nevada;Oregon

Geochemical characterization of water, sediment, and biota affected by mercury contamination and acidic drainage from historical gold mining, Greenhorn Creek, Nevada County, California, 1999-2001

In 1999, the U.S. Geological Survey (USGS) initiated studies of mercury and methylmercury occurrence, transformation, and transport in the Bear River and Yuba River watersheds of the northwestern Sierra Nevada. Because these watersheds were affected by large-scale, historical gold extraction using mercury amalgamation beginning in the 1850s, they were selected for a pilot study of mercury transport by the USGS and other cooperating agencies. This report presents data on methylmercury (MeHg) and total mercury (THg) concentrations in water, bed sediment, invertebrates, and frogs collected at 40 stations during 1999-2001 in the Greenhorn Creek drainage, a major tributary to Bear River. Results document several mercury contamination “hot spots” that represent potential targets for ongoing and future remediation efforts at abandoned mine sites in the study area. Water-quality samples were collected one or more times at each of 29 stations. The concentrations of total mercury in 45 unfiltered water samples ranged from 0.80 to 153,000 nanograms per liter (ng/L); the median was 9.6 ng/L. Total mercury concentrations in filtered water (41 samples) ranged from less than 0.3 to 8,000 ng/L; the median was 2.7 ng/L. Concentrations of methylmercury in the unfiltered water (40 samples) ranged from less than 0.04 to 9.1 ng/L; the median was 0.07 ng/L. Methylmercury in filtered water (13 samples) ranged from less than 0.04 to 0.27 ng/L; the median was 0.04 ng/L. Acidic drainage with pH values as low as 3.4 was encountered in some of the mined areas. Elevated concentrations of aluminum, cadmium, copper, iron, manganese, nickel, and zinc were found at several stations, especially in the more acidic water samples. Total mercury concentrations in sediment were determined by laboratory and field methods. Total mercury concentrations (determined by laboratory methods) in ten samples from eight stations ranged from about 0.0044 to 12 µg/g (microgram per gram, equivalent to parts per million). Methylmercury concentrations in these samples ranged from less than 0.00011 to 0.0095 µg/g. A field panning method was used to determine the concentration of liquid elemental mercury in 22 samples from 14 stations. Measured quantities of elemental mercury recovered by panning ranged from a trace amount estimated at 100 milligrams per kilogram (equivalent to parts per million) to 45,000 milligrams per kilogram (equivalent to 4.5 per cent, by weight). In total, 194 invertebrate samples were collected at 31 stations; 78 of the samples were analyzed for concentrations of THg and MeHg and used to calculate MeHg to THg ratios. A total of 69 frog samples were collected at 19 stations, and all were analyzed only for THg. Ranges of MeHg concentrations (µg/g, wet weight) in invertebrate samples and number of samples (n) were 0.0012-0.048 for banana slugs (Arionidae, n = 27), 0.027-0.39 for dobsonflies (Corydalidae, n = 14), 0.029-0.50 for predaceous diving beetles (Dytiscidae, n = 31), 0.026-0.52 for predaceous stoneflies (Perlidae, n = 18), 0.011-1.6 for dragonflies (Odonata, n = 46), and 0.061-0.55 for water striders (Gerridae, n = 56). The ratio of MeHg to THg in invertebrates was greater than 50 percent for 74 of 78 samples. The data from this reconnaissance sampling effort have been used by land-management agencies in selecting abandoned mine sites for remediation. The Forest Service has remediated the Sailor Flat site, and the Bureau of Land Management has initiated plans to remediate the Boston Mine drainage tunnel.

California

Streamflow extents and hydraulic characteristics of Meadow Valley Wash at Stuart Ranch, near Rox, Nevada

The former Stuart Ranch, now managed by the Bureau of Land Management, is transected by Meadow Valley Wash, where 4,600 feet of perennial stream and adjacent riparian vegetation provide critical habitat for several wildlife and aquatic species protected under the Endangered Species Act. The stream has been altered by prior construction of irrigation diversions, gravel mining, and removal of riparian vegetation, resulting in the loss of instream and riparian vegetation and disconnected floodplains. The stream alteration has also resulted in the loss of native species and increased non-native invasive species and changes in ecological cycles. With the goal of improving habitat extent and quality for native threatened and endangered species, the Bureau of Land Management (BLM) is considering establishing perennial streams through braided side channels by constructing beaver dam analogs, excavating side channel connectors, and grading an irrigation reservoir berm on the floodplain. The U.S. Geological Survey (USGS) provided hydraulic modeling to assist the BLM in evaluating how possible restoration modifications could affect the extent of aquatic, riparian, and other habitat types. Three two-dimensional (2-D) hydraulic models were developed to simulate 2021 conditions (when most of the topographic data were collected), minor restoration modifications (one excavated side channel and a beaver dam analog), and major restoration modifications (three excavated side channels, a beaver dam analog, and an excavated and graded area to remove the irrigation reservoir) to determine streamflow-inundation extents and hydraulic characteristics (depth and velocity) for base flow and various flood (50-, 20-, 10-, 4-, 2-, and 1-percent annual exceedance probability [AEP]) scenarios. An average summer base flow of 0.92 cubic feet per second was estimated based on data from a USGS streamgage in the study area. The 50-, 20-, 10-, 4-, 2-, and 1-percent AEP streamflows were estimated based on a flood-frequency analysis of data from the streamgage. The base flow and AEP floods were combined with surveyed topographic data to create a 2-D unsteady hydraulic model. The hydraulic model was used to simulate the base flow and flood-inundation extents and hydraulic characteristics under 2021 conditions and with two possible restoration modification scenarios. Under 2021 conditions, flow remains in a single channel until the most downstream end of the modeled reach, where flow then expands into slower velocity pools. During floods, streamflow begins to enter the side channels at the 50-percent flood, expands into the east floodplain at 20-percent flood, and flows in the irrigation reservoir at 4-percent flood. Compared to 2021 conditions with no terrain modification, base flow under the possible restoration modifications enters and remains in the side channels, thus increasing the likelihood of expanding riparian habitat. Additionally, during floods under the major restoration modifications, streamflow expands into the modified terrain surrounding the irrigation reservoir at 10-percent AEP, as opposed to 4-percent AEP under 2021 conditions. For all modeled streamflow scenarios, streamflow is deepest in the center of the main and side channels, as well as the downstream pooled areas. Streamflow is fastest in the narrow sections of the channels, especially in the upper 1,220 feet of the modeled reach.

Nevada

Geologic Map of the House Rock Valley Area, Coconino County, Northern Arizona

This geologic map is a cooperative effort of the U.S. Geological Survey (USGS), the Bureau of Land Management, the National Park Service, and the U.S. Forest Service to provide a geologic database for resource management officials and visitor information services. This map was produced in response to information needs related to a proposed withdrawal of three segregated land areas near Grand Canyon National Park, Arizona, from new hard rock mining activity. House Rock Valley was designated as the east parcel of the segregated lands near the Grand Canyon. This map was needed to provide connectivity for the geologic framework of the Grand Canyon segregated land areas. This geologic map of the House Rock Valley area encompasses approximately 280 mi2 (85.4 km2) within Coconino County, northern Arizona, and is bounded by longitude 111 degrees 37'30' to 112 degrees 05' W. and latitude 36 degrees 30' to 36 degrees 50' N. The map area is in the eastern part of the Arizona Strip, which lies within the southern Colorado Plateaus geologic province (herein Colorado Plateau). The Arizona Strip is the part of Arizona lying north of the Colorado River. The map is bound on the east by the Colorado River in Marble Canyon within Grand Canyon National Park and Glen Canyon National Recreation Area, on the south and west by the Kaibab National Forest and Grand Canyon National Game Preserve, and on the north by the Vermilion Cliffs Natural Area, the Paria Canyon Vermilion Cliffs Wilderness Area, and the Vermilion Cliffs National Monument. House Rock State Buffalo Ranch also bounds the southern edge of the map area. The Bureau of Land Management Arizona Field Office in St. George, Utah, manages public lands of the Vermilion Cliffs Natural Area, Paria Canyon - Vermilion Cliffs Wilderness and Vermilion Cliffs National Monument. The North Kaibab Ranger District in Fredonia, Arizona, manages U.S. Forest Service land along the west edge of the map area and House Rock State Buffalo Ranch. Other lands include about 13 sections of Arizona State land, about ? of a section of private land along House Rock Wash, and about 1? sections of private land at Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. Landmark features within the map area include the Vermilion Cliffs, Paria Plateau, Marble Canyon, and House Rock Valley. Surface drainage in House Rock Valley is to the east toward the Colorado River in Marble Canyon. Large tributaries of Marble Canyon from north to south include Badger Canyon, Soap Creek, Rider Canyon, North Canyon, Bedrock Canyon, and South Canyon. Elevations range from about 2,875 ft (876 m) at the Colorado River in the southeast corner of the map to approximately 7,355 ft (2,224 m) on the east rim of Paria Plateau along the north-central edge of the map area. Three small settlements are in the map area along U.S. Highway 89A, Cliff Dwellers Lodge, Vermilion Cliffs Lodge, and Marble Canyon, Arizona. The community of Jacob Lake is about 9 mi (14.5 km) west of House Rock Valley on the Kaibab Plateau. Lees Ferry is 5 mi (8 km) north of Marble Canyon and marks the confluence of the Paria and Colorado Rivers and the beginning of Marble Canyon. U.S. Highway 89A provides access to the northern part of the map area. Dirt roads lead south into House Rock Valley from U.S. Highway 89A and are collectively maintained by the Bureau of Land Management, the U.S. National Forest Service, and the Grand Canyon Trust. House Rock Valley is one of the few remaining areas where uniform geologic mapping is needed for connectivity to the regional Grand Canyon geologic framework. This information is useful to Federal and State resource managers who direct environmental and land management programs that encompass such issues as range management, biological studies, flood control, water, and mineral-resource investigations. The geologic information will support future and ongoing geologic investigations and scientific studies

Scientific Investigations Map

Mass loading of selected major and trace elements in Lake Fork Creek near Leadville, Colorado, September-October 2001

A mass-loading study of Lake Fork Creek of the Arkansas River between Sugarloaf Dam and the mouth was completed in September-October 2001 to help ascertain the following: (1) variation of pH and aqueous constituent concentrations (calcium, sulfate, alkalinity, aluminum, cadmium, copper, iron, manganese, lead, and zinc) and their relation to toxicity standards along the study reach; (2) location and magnitude of sources of metal loading to Lake Fork Creek; (3) amount and locations of metal attenuation; (4) the effect of streamside wetlands on metal transport from contributing mine tunnels; and (5) the effect of organic-rich inflow from the Leadville National Fish Hatchery on water quality in Lake Fork Creek. The study was done in cooperation with the Bureau of Land Management, U.S. Department of Agriculture Forest Service, and U.S. Fish and Wildlife Service. Constituent concentrations and pH showed variable patterns over the study reach. Hardness-based acute and chronic toxicity standards were exceeded for some inflows and some constituents. However, stream concentrations did not exceed standards except for zinc starting in the upper parts of the study reach and extending to just downstream from the inflow from the Leadville National Fish Hatchery. Dilution from that inflow lowered stream zinc concentrations to less than acute and chronic toxicity standards. The uppermost 800 meters of the study reach that contained inflow from the Bartlett, Dinero, and Nelson mine tunnels and the Dinero wetland was the greatest source of loading for manganese and zinc. A middle section of the study reach that extended approximately 2 kilometers upstream from the National Fish Hatchery inflow to just downstream from that inflow was the largest source of aluminum, copper, iron, and lead loading. The loading was partially from the National Fish Hatchery inflow but also from unknown sources upstream from that inflow, possibly ground water. The largest sources for calcium and sulfate load to the stream were the parts of the study reach containing inflow from the tribu-taries Halfmoon Creek (calcium) and Willow Creek (sulfate). The Arkansas River and its tributaries upstream from Lake Fork Creek were the source of most of the calcium (70 percent), sulfate (82 percent), manganese (77 percent), lead (78 percent), and zinc (95 percent) loads in the Arkansas River downstream from the Lake Fork confluence. In contrast, Lake Fork Creek was the major source of aluminum (68 percent), copper (65 percent), and iron (87 percent) loads to the Arkansas River downstream from the confluence. Attenuation was not important for calcium, sulfate, or iron. However, other metals loads were reduced up to 81 percent over the study reach (aluminum, 25 percent; copper, 20 percent; manganese, 81 percent; lead, 30 percent; zinc, 72 percent). Metal attenuation in the stream occurred primarily in three locations (1) the irrigation diversion ditch; (2) the beaver pond complex extending from upstream from the Colorado Gulch inflow to just downstream from that inflow; and (3) the stream reach that included the inflow from Willow Creek. The most likely attenuation mechanism is precipitation of metal oxides and hydroxides (primarily manganese), and sorption or coprecipitation of trace elements with the precipitating phase. A mass-balance calculation indicated that the wetland between the Dinero Tunnel and Lake Fork Creek removed iron, had little effect on zinc mass load, and was a source for, or was releasing, aluminum and manganese. In contrast, the wetland that occurred between the Siwatch Tunnel and Lake Fork Creek removed aluminum, iron, manganese, and zinc from the tunnel drainage before it entered the creek. Inflow from the National Fish Hatchery increased dissolved organic carbon concentrations in Lake Fork Creek and slightly changed the composition of the dissolved organic carbon. However, dissolved organic carbon loads increased in the stream reach downs

Colorado

Selenium in the upper Blackfoot River watershed, southeastern Idaho, 2001-12

The upper Blackfoot River in southeastern Idaho receives runoff from 12 large phosphate mines. Waste shales that are removed to access the phosphate ore are highly enriched with selenium, resulting in elevated selenium in runoff from the mine waste dumps. In 2001, in cooperation with the Bureau of Land Management, the U.S. Geological Survey (USGS) began monitoring streamflow, selenium, and other water-quality parameters at a single location near the outlet of the upper Blackfoot River to the Blackfoot Reservoir. Water samples primarily were collected by a flow triggered, automated pump sampler, supplemented by manual point and equal-width integrated manual samples. The approach to monitoring concentrations and streamflow over time at a fixed location is ideal for evaluating temporal trends, but provides no information about the relative source contributions from the mine waste dumps draining into various tributaries. In 2001, the Idaho Department of Environmental Quality (IDEQ) began an annual, mid-May, synoptic survey of selenium concentrations and streamflow at 21 locations along the main stem Blackfoot River and its tributaries. Individually, neither the intensive USGS sampling at the outlet nor the IDEQ annual synoptic sampling provides a comprehensive view of selenium runoff in the Blackfoot River watershed. Together, the efforts are complementary; therefore, in this report, results are presented from both sampling efforts. The USGS collected time-series data from 2001 to 2012 at a fixed location, the Blackfoot River near the outlet of the reservoir, near Henry, Idaho (USGS streamgage 13063000). Dissolved selenium concentrations from 450 filtered samples collected at this site ranged from 0.5 to 11.4 micrograms per liter (μg/L). The State of Idaho chronic aquatic life criterion concentration of 5 μg/L was exceeded in 31 percent of the samples, with most exceedances occurring during May of each year. No exceedances of the selenium criterion were recorded in months other than April, May, or June. Concentrations of selenium in unfiltered and filtered samples were similar, and concentrations from samples collected by depth and width integrated methods were similar to those collected by grab (point) samples, indicating that the grab samples adequately represent selenium concentrations across the entire river cross section. In speciation analyses made during 2003 and 2004, the median percentage of total selenium as selenate was 81 percent, ranging from 17 to 98 percent, and the median percentage of total selenium as selenite was 19 percent, ranging from 2 to 83 percent of the total selenium. During the period of study, selenium concentrations had an upward trend during the lowflow season of August–October. Time trends were not obvious during other seasons. Selenium daily loads varied by more than a factor of 900 during the study period and ranged from 0.03 kilograms per day (kg/d) to more than 24 kg/d. Annual maximum daily loads of selenium varied over nearly a factor of 12, ranging from about 2 to 24 kg/d. For the annual spring synoptic samples collected by the IDEQ along the main stem Blackfoot River and major tributaries, selenium concentrations ranged from less than 2 to 870 μg/L in 176 samples. In most years, the synoptic sampling showed that the majority of the selenium loads passing the USGS streamgage at the outlet of the watershed could be attributed to a single tributary, East Mill Creek, which enters the Blackfoot River through Spring Creek. Selenium loads decreased by about half from East Mill Creek before reaching the Blackfoot River, suggesting that much selenium is at least temporarily removed from the water column by uptake by aquatic vegetation or by losses to sediment. Similar decreases in selenium loads occurred through the main stem Blackfoot River before reaching the outlet in low flow years, but not in high flow years.

Idaho

Hydrogeology and simulation of groundwater flow in the Arbuckle-Simpson aquifer, south-central Oklahoma

The Arbuckle-Simpson aquifer in south-central Oklahoma provides water for public supply, farms, mining, wildlife conservation, recreation, and the scenic beauty of springs, streams, and waterfalls. Proposed development of water supplies from the aquifer led to concerns that large-scale withdrawals of water would cause decreased flow in rivers and springs, which in turn could result in the loss of water supplies, recreational opportunities, and aquatic habitat. The Oklahoma Water Resources Board, in collaboration with the Bureau of Reclamation, the U.S. Geological Survey, Oklahoma State University, and the University of Oklahoma, studied the aquifer to provide the Oklahoma Water Resources Board the scientific information needed to determine the volume of water that could be withdrawn while protecting springs and streams. The U.S. Geological Survey, in coopertion with the Oklahoma Water Resources Board, did a study to describe the hydrogeology and simulation of groundwater flow of the aquifer. The outcrop of the Arbuckle-Simpson aquifer covers an area of about 520 square miles in Carter, Coal, Johnston, Murray, and Pontotoc Counties. Three subdivisions of the aquifer outcrop were designated for this study: the eastern, central, and western Arbuckle-Simpson aquifer. This study emphasized the eastern Arbuckle-Simpson aquifer because it is the largest part of the aquifer by area and volume; most groundwater withdrawals are from the eastern Arbuckle-Simpson aquifer; and the largest (by flow) streams and springs sourced from the aquifer are on the eastern Arbuckle-Simpson aquifer. The aquifer lies in an uplifted area commonly referred to as the Arbuckle Mountains, which is characterized by great thicknesses of mostly carbonate rocks, uplifts, folded structures, and large fault displacements. The Arbuckle-Simpson aquifer is contained in three major rock units of Late Cambrian to Middle Ordovician age: the Timbered Hills, Arbuckle, and Simpson Groups. The aquifer is underlain by low-permeability Cambrian and Proterozoic igneous and metamorphic rocks, and is confined above by younger sedimentary rocks of various ages in areas where the top of the aquifer dips below the surface. The major part of the Arbuckle-Simpson aquifer is the Arbuckle Group, which consists of as much as 6,700 feet of limestone in the western Arbuckle-Simpson aquifer, but which thins to an estimated 3,000 feet of predominantly dolostone in the eastern Arbuckle-Simpson aquifer. Water is obtained from cavities, solution channels, fractures, and intercrystalline porosity in the limestone and dolostone. The overlying Simpson Group, consisting of sandstones, shales, and limestones, is as much as 2,300 feet thick in the western Arbuckle-Simpson aquifer, but generally is less than 1,000 feet thick in the eastern aquifer. Water in the Simpson Group is stored primarily in pore spaces between the sand grains in the sandstones. A digital, three-dimensional geologic framework model was constructed to define the geometric relations of fault blocks and subsurface rock units across complex fault zones of the eastern Arbuckle-Simpson aquifer. Geologic data for the model were obtained from 126 drill holes; stratigraphic contacts and faults defined from a digitized version of the surface geologic map; and fault geometry, stratigraphic thickness, and information compiled from geologic and hydrogeologic reports and maps. Groundwater in the aquifer moves from areas of high head (altitude) to areas of low head along streams and springs. The potentiometric surface in the eastern Arbuckle-Simpson aquifer generally slopes from a topographic high from northwest to the southeast, indicating that regional groundwater flow is predominantly toward the southeast. Freshwater is known to extend beyond the aquifer outcrop near the City of Sulphur, Oklahoma, and Chickasaw National Recreation Area, where groundwater flows west from the outcrop of the eastern Arbuckle-Simpson aquifer and becomes confin

Scientific Investigations Report

The effects of sediment and mercury mobilization in the South Yuba River and Humbug Creek confluence area, Nevada County, California: Concentrations, speciation, and environmental fate – Part 1: Field characterization

Millions of pounds of mercury (Hg) were deposited in the river and stream channels of the Sierra Nevada from placer and hard-rock mining operations in the late 1800s and early 1900s. The resulting contaminated sediments are relatively harmless when buried and isolated from the overlying aquatic environment. The entrained Hg in the sediment constitutes a potential risk to human and ecosystem health should it be reintroduced to the actively cycling portion of the aquatic system, where it can become methylated and subsequently bioaccumulated in the food web. Each year, sediment is mobilized within these fluvial systems during high stormflows, transporting hundreds of tons of Hg-laden sediment downstream. The State of California and resource-management agencies, including the Bureau of Land Management (BLM) and the U.S. Forest Service, are concerned about additional disturbances, such as from suction gold dredging activities, which have the potential to mobilize Hg associated with buried sediment layers elevated in Hg that are otherwise likely to remain buried under normal storm conditions. The BLM initiated a study looking at the feasibility of removing Hg-contaminated sediment at the confluence of the South Yuba River and Humbug Creek in the northern Sierra Nevada of California by using standard suction-dredge technology. Additionally, the California State Water Resources Control Board (SWRCB) supported a comprehensive characterization of the intended dredge site. Together, the BLM and SWRCB supported a comprehensive characterization of Hg contamination at the site and the potential effects of sediment disturbance at locations with historical hydraulic mining debris on downstream environments. The comprehensive study consisted of two primary components: field studies and laboratory experiments. The field component, described in this report, had several study elements: 1) a preliminary, smallscale, in-stream dredge test; 2) comprehensive characterization of grain size distribution, Hg speciation, and mineralogy of bed and suspended sediment; 3) a determination of the past and current sources of sediment in the study area; 4) an assessment of Hg bioaccumulation in the local invertebrate population; and 5) a comparison of potential Hg transport caused by natural storm disturbances with potential Hg mobilization caused by suction dredging as a method of Hg removal at the study site. The laboratory component of the study assessed the potential influence of the disturbance of Hg-contaminated sediment through experiments designed to simulate in-stream transport, deposition, and potential methylation of Hg, described in a companion report (see Marvin-DiPasquale and others, 2011). Results of the field studies indicate that the fine-grained fraction (silt-clay, less than 0.063 millimeters) contains the greatest concentration of Hg in contaminated sediment. Because the fine-grained fraction is the most susceptible to longrange fluvial transport, disturbance of Hg-contaminated sediment is likely to increase the concentration and load of Hg in downstream waters. The preliminary, small-scale dredge test showed an increase in the concentration of fine particles and Hg in the water column caused by the dredge activity, despite relatively low concentrations of fine particles and Hg (about 300 nanograms per gram) at the dredge site. Characterization of sediment from two test pits and other sites in the vicinity of the confluence of the South Yuba River and Humbug Creek revealed a highly variable distribution of fine- and coarse-grained sediment. The highest levels of Hg contamination (up to 11,100 ng/g) were associated with the fine-grained fraction of sediment from the bedrock contact zone of Pit 2, a horizon which also yielded grains of gold and gold-Hg amalgam. A closed-circuit tank experiment with a venturi dredge at the base of Pit 1, in a gravel bar within the South Yuba River, resulted in fine-grained suspended sediment remaining in suspension more than 40 hours following the disturbance simulation. Although the volumetric concentration of Hg declined over time as particles settled out, the concentration of Hg on the suspended particles increased over time as the suspended material became finer grained, because Hg is preferentially adsorbed on to clay-sized particles. Mineralogical and chemical analyses indicated that the buried fine-grained material with the greatest Hg contamination was derived from hydraulic mining debris, which consist primarily of Eocene gravels mined in the Malakoff Diggins, North Bloomfield, and Lake City areas within the South Yuba River watershed. Coarse material and more recently deposited sediment were derived primarily from upstream sources on the South Yuba River. The biota assessment indicated that invertebrate taxa collected from all sites on the South Yuba River in 2007, including lower Humbug Creek, had elevated concentrations of total mercury (THg) and methylmercury (MeHg) compared to a reference site on the Bear River, upstream of mining effects. Differences with the reference site were less pronounced in 2008 when a significant reduction in MeHg concentrations was observed in biota across all taxa from concentrations in 2007. It is possible that the inter-annual variation was related to the fact that suction dredging was active in the South Yuba River in 2007 but not in 2008 when a local moratorium was imposed by the BLM. There were significant variations among taxa for both THg and MeHg concentrations, with the water striders (Gerridae) having the highest concentrations of both THg and MeHg; variation among sites was not as strong as between years or among taxa. These results suggest that additional monitoring would be helpful to investigate the possible linkage between variations in MeHg bioaccumulation and levels of suction dredge activity in areas of historical gold mining. Results from the field studies indicate that disturbance of the finegrained Hg-contaminated sediment would likely lead to enhanced mobilization of Hg to downstream environments; therefore, the use of suction dredging to remove Hg at the South Yuba River and Humbug Creek confluence area would likely result in enhanced Hg transport downstream relative to natural conditions.

California

Mercury at the Oat Hill Extension Mine and James Creek, Napa County, California: Tailings, sediment, water, and biota, 2003-2004

The Oat Hill Extension (OHE) Mine is one of several mercury mines located in the James Creek/Pope Creek watershed that produced mercury from the 1870's until 1944 (U.S. Bureau of Mines, 1965). The OHE Mine developed veins and mineralized fault zones hosted in sandstone that extended eastward from the Oat Hill Mine. Waste material from the Oat Hill Mine was reprocessed at the OHE Mine using gravity separation methods to obtain cinnabar concentrates that were processed in a retort. The U.S. Bureau of Land Management requested that the U.S. Geological Survey measure and characterize mercury and other chemical constituents that are potentially relevant to ecological impairment of biota in tailings, sediment, and water at the OHE Mine and in the tributaries of James Creek that drain the mine area (termed Drainage A and B ) (Figs. 1 and 2). This report summarizes such data obtained from sampling of tailings and sediments at the OHE on October 17, 2003; water, sediment, and biota from James Creek on May 20, 2004; and biota on October 29, 2004. These data are interpreted to provide a preliminary assessment of the potential ecological impact of the mine on the James Creek watershed. The mine tailings are unusual in that they have not been roasted and contain relatively high concentrations of mercury (400 to 1200 ppm) compared to unroasted waste rock at other mines. These tailings have contaminated a tributary to James Creek with mercury primarily by erosion, on the basis of higher concentration of mercury (780 ng/L) measured in unfiltered (total mercury, Hg T ) spring water flowing from the OHE to James Creek compared to 5 to 14 ng/L Hg T measured in James Creek itself. Tailing piles (presumably from past Oat Hill mine dumping) near the USBLM property boundary and upstream of the main OHE mine drainage channel ( Drainage A ; Fig. 2) also likely emit mercury, on the basis of their mercury composition (930 to 1200 ppm). The OHE spring water is likely an appreciable source of sulfate and carbonate to James Creek, because the spring water was enriched in sulfate (130 mg/L) and carbonate (430 mg/L as CaCO 3 ) compared to James Creek water (70 to 100 mg/L SO 4 2- and 110 to 170 mg/L as CaCO 3 ) at the time of sampling. Concentrations of mercury in active channel sediment from James Creek are variable and potentially high, on the basis of chemical analysis (2.5 to 17 _g/g-wet sediment) and easily visible cinnabar grains in panned concentrates. Average (geometric mean) organic mercury (presumably monomethyl mercury (MMHg); §2.3.3) concentrations in several invertebrate taxa collected from the James Creek watershed locations were higher than invertebrates taken from a Northern California location lacking a known point source of mercury. The mean proportion of MMHg to total mercury in James Creek predatory insect samples was 40 percent (1 standard deviation = 30 percent); only 40 percent of all insect samples had a MMHg/Hg T proportion greater than 0.5. The low proportions of MMHg measured in invertebrates in James Creek and the presence of cinnabar in the creek suggest that some invertebrates may have anomolously high Hg concentrations as a result of the injestion or adhesion of extremely fine-grained cinnabar particles. Interpretation of Hg T in frogs and fish as an indicator of mercury reactivity, biouptake, or trophic transfer is limited, pending MMHg measuremens, by the possibility of these whole-body samples having contained cinnabar particles at the time of analysis. To minimize this limitation, the gastrointestinal tracts and external surfaces of all amphibians, where cinnabar most likely resides, were carefully flushed to remove any visible particles. However, extremely fine-grained, invisible, adhesive cinnabar particles likely exist in the amphibians' habitats. Hg T in foothill yellow-legged frogs collected from the James Creek study area, ranging from 0.1 to 0.6 μg/g Hg, was on average twice that of an extensive database compiled from Hg T in frogs studied throughout Northern California. Average concentrations of Hg T in frogs from James Creek were similar upstream (0.18 μg/g) and downstream (0.15 μg/g) of the confluence with Tributary 1 and at the lower Corona Mine adit drainage (0.14 μg/g). Frogs may be susceptible to trophic transfer of MMHg from invertebrates, but further study is required to rule out cinnabar ‘contamination.’ Hg T concentrations in rainbow trout collected from James Creek upstream and downstream of Tributary 1 averaged 0.10 μg/g and 0.13 μg/g, respectively. Compared to invertebrates, trout Hg T was less variable, suggesting that trout were less contaminated with cinnabar. California roach had significantly higher Hg T on average than trout (0.16 vs. 0.12 μg/g), and can be considered moderately contaminated compared to the same species from other sites in Northern California, which average 0.12 μg/g Hg. While limited measurements of mercury in water, sediment, and fish exceed, in some samples, predefined ecologically protective criteria for mine-impacted California systems, they do not clearly demonstrate that the biota residing in James Creek in the vicinity of the OHE are ecologically impaired. The potential for ecological impairment is clearly evident from invertebrate methyl mercury results and may manifest in other biological ecosystem residents that have yet to be studied (e.g., piscivorous birds). Methyl mercury concentrations in flowing water and sediment from James Creek and the tributary that drains the OHE are relatively low, ranging from 0.04 to 0.08 ng/L, although these data should be cautiously interpreted (see §3.2). While the results of this investigation suggest that the OHE contributes inorganic mercury to James Creek, they do not indicate the extent to which the OHE site is ecologically impairing biota relative to other sources of mercury. Improved sampling and analytical methods are recommended for future study.

California

Quantifying the eroded and deposited mass of mercury-contaminated sediment by using terrestrial laser scanning at the confluence of Humbug Creek and the South Yuba River, Nevada County, California, 2011–13

High-resolution, terrestrial laser scanning, also known as ground-based lidar (light detection and ranging), was used to quantify the volume of mercury-contaminated sediment eroded from an outcrop of historical placer-mining debris at the confluence of Humbug Creek and the South Yuba River in the Sierra Nevada foothills, about 17 kilometers northeast of Grass Valley, California, and delivered to a zone below an observed flood stage of the South Yuba River. Substantial quantities of mercury were used and lost to the environment from historical placer gold mining activities on the western slope of the Sierra Nevada, California, and recent studies have documented continued persistence of mercury and methylmercury concentrations in water, sediment, fish, and predatory invertebrates in the Yuba River drainage basin in relation to suspected mercury sources. To identify areas that have high levels of mercury contamination as possible remediation targets in the Yuba River drainage basin and other areas in the Sierra Nevada, the U.S. Geological Survey worked in cooperation with the Bureau of Land Management on this and other detailed studies. Malakoff Diggings, one of the largest hydraulic gold mines in the Sierra Nevada, is 3.5 kilometers north of the study site in the Humbug Creek subbasin. Terrestrial laser scanning was used to produce centimeter-scale, three-dimensional maps of the complex outcrop surface, which was composed of an upper erosional area (cliff and over-steepened slope) and a lower depositional area (colluvial slope). The outcrop could not be mapped non-destructively or in sufficient detail by traditional surveying techniques. The study site, which was approximately 70 meters long, 30 meters wide and 20 meters high, was surveyed four times in 2 years (December 15, 2011; October 25, 2012; January 4, 2013; and November 22, 2013) to determine volumetric differences in the upper erosional and lower depositional areas between surveys. Measured changes in volume for the upper erosional area and lower depositional area were multiplied by the corresponding sediment density so that a mass-balance relationship, between the eroded and deposited sediment during each period, could be used to estimate the amount of mercury-contaminated sediment that was transported to below the base of the colluvial slope, where it could be mobilized by the South Yuba River during a flood having a 5-to-10-year recurrence interval. On December 2, 2012, a flood of this estimated magnitude reached the base of the colluvial slope. Between the first and second surveys (December 15, 2011–October 25, 2012), an estimated mass of 18±9.2 kilograms of sediment was transported from steeper slopes to the gently sloping river bank below the base of the colluvial slope. Between the second and third surveys (October 25, 2012–January 4, 2013), an atmospheric river caused heavy precipitation at the study site during late November and early December 2012. This short-duration, high-intensity rain resulted in a large amount of erosion and deposition at the study site and also caused high streamflow (flood stage) in the South Yuba River. From October 2012 to January 2013, 51±31 kilograms of sediment was transported to below the base of the colluvial slope, that is, below the high-water mark of December 2, 2012. Between the third and fourth surveys (January 4, 2013–November 22, 2013), an additional 10±26 kilograms of sediment was transported to below the base of the colluvial slope. During the 24 months of the study, the total mass of sediment delivered below the base of the colluvial slope and the high-water mark of December 2, 2012, was 79±66 kilograms. In any given year there is a 10–20-percent chance (5-to-10-year recurrence interval) of a flood equal to or greater than that of the December 2, 2012, flood, which could transport mercury-contaminated sediment at the study site into the South Yuba River. Hydraulically modeled estimates of the South Yuba River stage during floods having a 50- and 100-year recurrence interval (2- and 1-percent annual exceedance probability, respectively) indicated that resulting river stages could be 2.2–3.0 meters above the base of the colluvial slope, or 2.2–3.0 meters above the high-water mark of December 2, 2012. Such high river stages would be likely to inundate the lower half of the colluvial slope and mobilize a substantial volume of mercury-contaminated sediment to downstream areas.

California

Assessment of hydrogeologic terrains, well-construction characteristics, groundwater hydraulics, and water-quality and microbial data for determination of surface-water-influenced groundwater supplies in West Virginia

In January 2014, a storage tank leaked, spilling a large quantity of 4-methylcyclohexane methanol into the Elk River in West Virginia and contaminating the water supply for more than 300,000 people. In response, the West Virginia Legislature passed Senate Bill 373, which requires the West Virginia Department of Health and Human Resources (WVDHHR) to assess the susceptibility and vulnerability of public surface-water-influenced groundwater supply sources (SWIGS) and surface-water intakes statewide. In response to this mandate for reassessing SWIGS statewide, the U.S. Geological Survey (USGS), in cooperation with the WVDHHR, Bureau of Public Health, Office of Environmental Health Services, compiled available data and summarized the results of previous groundwater studies to provide the WVDHHR with data that could be used as part of the process for assessing and determining SWIGS. Existing geologic, hydrologic, well-construction, water-quality, and other related data and information from previous U.S. Geological Survey (USGS) hydrogeologic studies and the USGS National Water Information System (NWIS) database, in conjunction with data from the West Virginia Bureau for Public Health (WVBPH) Department of Health and Human Resources (WVDHHR) and the West Virginia Department of Environmental Protection database and files, were collected, compiled, and analyzed to help the WVDHHR to better assess public groundwater supply wells that may meet the definition of a surface-water-influenced- groundwater supply (SWIGS). In this study, measures of intrinsic susceptibility, which are characterized by the physical properties that affect the ease with which water moves through the unsaturated zone and, subsequently, into the saturated zone within an aquifer, showed that karst limestone aquifers are the aquifers most intrinsically susceptible to contamination within the State of West Virginia. Karst limestone aquifers are present within Cambrian- and Ordovician-age formations within West Virginia’s eastern panhandle and in Mississippian-age limestones within the Greenbrier River valley. Solution development within these limestone aquifers allows rapid recharge and flow of groundwater within the aquifer, both of which allow surface contaminants to easily enter the aquifer and travel long distances in a short period of time. Alluvial aquifers bordering the Ohio River in western West Virginia are also potentially highly susceptible to contamination because these alluvial aquifers can receive significant recharge from the adjacent Ohio River. Any potential contaminants that may be present in the river have the potential to enter the aquifer and contaminate wells completed within the sand and gravel alluvial sediments within which the wells are completed. These same alluvial sediments, however, help to retard the movement of bacteria and other potentially pathogenic organisms, such as Cryptosporidia and Giardia lamblia , into the aquifer. As a result, samples from alluvial aquifers bordering the Ohio River and elsewhere within the State do not commonly test positive for indicator bacteria, such as total coliform, fecal coliform, or Escherichia coli ( E. coli ). The alluvial sediments do not, however, provide assimilative capacity with respect to water soluble compounds such as nitrate and certain volatile and semi-volatile organic compounds. Therefore, the Ohio River alluvial aquifers are highly susceptible to organic compounds present in the river or on the land surface near a well. These aquifers are also susceptible to nitrate contamination from fertilizers, pesticides, and manure, which are commonly used on the fertile agricultural soils present on terraces along the Ohio River. Abandoned-coal-mine aquifers, which are typically used as a source of groundwater in southern West Virginia, are moderately susceptible to contamination. The vast network of voids from mine entries provide vast storage for groundwater in abandoned mine aquifers, and fracturing of overburden strata, which is common in areas of past or current mining, can allow rapid infiltration of contaminants to the aquifer. Where streams cross over below-drainage underground coal mines, there is an increased potential for contamination of coal-mine aquifers. As a result, above-drainage underground coal mines, those mines that are present at an elevation above local tributary drainage, are probably less susceptible to contamination than are below-drainage underground coal mines. Public groundwater supplies in abandoned coal mines need to be evaluated on a case-by-case basis to assess the potential for recharge of contaminated surface water to enter below-drainage underground coal-mine aquifers and to assess potential hydraulic conductivity to nearby surface-water bodies, such as lakes, ponds, rivers, or streams. Fractured-rock aquifers compose an additional major type of aquifer within the State of West Virginia. Owing to their low permeability and their typically small groundwater capture areas, fractured-rock aquifers within the State of West Virginia typically have low susceptibility to contamination. However, there are exceptions, and wells completed in fractured-rock aquifers that are in close proximity to streams may be adversely affected by induced recharge from the stream. Where such systems are present, frequent bacterial testing of the source water can be used to ascertain the potential for microbial contamination of the aquifer. Intrinsic susceptibility alone does not fully predict whether or not a well is vulnerable to contamination, only that the hydrogeologic terrain is suitable for rapid transport of pathogenic organisms or chemical compounds to and within the aquifer. However, contaminants may or may not be present in the recharge water to an individual well or well field. Therefore, an assessment of potential contaminant sources, such as nearby gas wells, landfills, underground storage tanks, above ground storage tanks, major transportation corridors, surface or underground coal mines, and flood plains, is needed to assess vulnerability. The assessments need to be conducted on a case-by-case basis or, as has been done in this study, by collecting and compiling the number of potential contaminant sources that may be present in the source-water-protection area for an individual public groundwater supply source. Groundwater public-supply systems in areas of high intrinsic susceptibility and with a large number of potential contaminant sources within the recharge or source-water-protection area of individual wells or well fields are potentially vulnerable to contamination and probably warrant further evaluation as potential SWIGS. However, measures can be taken to educate the local population and initiate safety protocols and protective strategies to appropriately manage contaminant sources to prevent release of contaminants to the aquifer, therefore, reducing vulnerability of these systems to contamination. However, each public groundwater supply source needs to be assessed on an individual basis. Data presented in this report can be used to categorize and prioritize wells and springs that have a high potential for intrinsic susceptibility or vulnerability to contamination.

West Virginia

Occurrence and hydrogeochemistry of radiochemical constituents in groundwater of Jefferson County and surrounding areas, southwestern Montana, 2007 through 2010

The U.S. Geological Survey, in cooperation with Jefferson County and the Jefferson Valley Conservation District, sampled groundwater in southwestern Montana to evaluate the occurrence and concentration of naturally-occurring radioactive constituents and to identify geologic settings and environmental conditions in which elevated concentrations occur. A total of 168 samples were collected from 128 wells within Broadwater, Deer Lodge, Jefferson, Lewis and Clark, Madison, Powell, and Silver Bow Counties from 2007 through 2010. Most wells were used for domestic purposes and were primary sources of drinking water for individual households. Water-quality samples were collected from wells completed within six generalized geologic units, and analyzed for constituents including uranium, radon, gross alpha-particle activity, and gross beta-particle activity. Thirty-eight wells with elevated concentrations or activities were sampled a second time to examine variability in water quality throughout time. These water-quality samples were analyzed for an expanded list of radioactive constituents including the following: three isotopes of uranium (uranium-234, uranium-235, and uranium-238), three isotopes of radium (radium-224, radium-226, and radium-228), and polonium-210. Existing U.S. Geological Survey and Montana Bureau of Mines and Geology uranium and radon water-quality data collected as part of other investigations through 2011 from wells within the study area were compiled as part of this investigation. Water-quality data from this study were compared to data collected nationwide by the U.S. Geological Survey through 2011. Radionuclide samples for this study typically were analyzed within a few days after collection, and therefore data for this study may closely represent the concentrations and activities of water being consumed locally from domestic wells. Radioactive constituents were detected in water from every well sampled during this study regardless of location or geologic unit. Nearly 41 percent of sampled wells had at least one radioactive constituent concentration that exceeded U.S. Environmental Protection Agency drinking-water standards or screening levels. Uranium concentrations were higher than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 30 micrograms per liter in samples from 14 percent of the wells. Radon concentrations exceeded a proposed MCL of 4,000 picocuries per liter in 27 percent of the wells. Combined radium (radium-226 and radium-228) exceeded the MCL of 5 picocuries per liter in samples from 10 of 47 wells. About 40 percent (42 of 104 wells) of the wells had gross alpha-particle activities (72-hour count) at or greater than a screening level of 15 pCi/L. Gross beta-particle activity exceeded the U.S. Environmental Protection Agency 50 picocuries per liter screening level in samples from 5 of 104 wells. Maximum radium-224 and polonium-210 activities in study wells were 16.1 and 3.08 picocuries per liter, respectively; these isotopes are constituents of human-health concern, but the U.S. Environmental Protection Agency has not established MCLs for them. Radioactive constituent concentrations or activities exceeded at least one established drinking-water standard, proposed drinking-water standard, or screening level in groundwater samples from five of six generalized geologic units assessed during this study. Radioactive constituent concentrations or activities were variable not only within each geologic unit, but also among wells that were completed in the same geologic unit and in close proximity to one another. Established or proposed drinking-water standards were exceeded most frequently in water from wells completed in the generalized geologic unit that includes rocks of the Boulder batholith and other Tertiary through Cretaceous igneous intrusive rocks (commonly described as granite). Specifically, of the wells completed in the Boulder batholith and related rocks sampled as part of this study, 24 percent exceeded the MCL of 30 micrograms per liter for uranium, 50 percent exceeded the proposed alternative MCL of 4,000 picocuries per liter for radon, and 27 percent exceeded the MCL of 5 micrograms per liter for combined radium-226 and radium-228. Elevated radioactive constituent values were detected in samples representing a large range of field properties and water types. Correlations between radioactive constituents and pH, dissolved oxygen, and most major ions were not statistically significant (p-value > 0.05) or were weakly correlated with Spearman correlation coefficients (rho) ranging from -0.5 to 0.5. Moderate correlations did exist between gross beta-particle activity and potassium (rho = 0.72 to 0.82), likely because one potassium isotope (potassium-40) is a beta-particle emitter. Total dissolved solids and specific conductance also were moderately correlated (rho = 0.62 to 0.71) with gross alpha-particle and gross beta-particle activity, indicating that higher radioactivity values can be associated with higher total dissolved solids. Correlations were evaluated among radioactive constituents. Moderate to strong correlations occurred between gross alpha-particle and beta-particle activities (rho = 0.77 to 0.96) and radium isotopes (rho = 0.78 to 0.92). Correlations between gross alpha-particle activity (72-hour count) and all analyzed radioactive constituents were statistically significant (p-value < 0.05), and therefore, gross alpha-particle activity likely may be used as a screening tool for determining the presence of radionuclides in area waters. In this study, gross alpha-particle activities of 7 picocuries per liter or greater were associated with all radioactive constituents whose concentrations exceeded drinking-water standards or screening levels. Radiochemical results varied temporally in samples from several of the thirty-eight wells sampled at least twice during the study. The time between successive sampling events ranged from about 1 to 10 months for 29 wells to about 3 years for the other 9 wells. Radiochemical constituents that varied by greater than 30 percent between sampling events included uranium (29 percent of the resampled wells), and radon (11 percent of the resampled wells), gross alpha-particle activity (38 percent of the resampled wells), and gross beta-particle activity (15 percent of the resampled wells). Variability in uranium concentrations from two wells was sufficiently large that concentrations were less than the MCL in the first set of samples and greater than the MCL in the second. Sample holding times affect analytical results in this study. Gross alpha-particle and gross beta-particle activities were measured twice, 72 hours and 30 days after sample collection. Gross alpha-particle activity decreased an average of 37 percent between measurements, indicating the presence of short-lived alpha-emitting radionuclides in these samples. Gross beta-particle activity increased an average of 31 percent between measurements, indicating ingrowth of longer-lived beta-emitting radionuclides.

Montana