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Petrology of the Caribou Mountain Pluton, Klamath Mountains, California

The Caribou Mountain pluton is a small trondhjemitic body that intruded semipelitic schist of the Stuart Fork terrane in late Middle Jurassic to Early Cretaceous time. Its emplacement followed the intrusion of an adjoining body of hornblende quartz diorite called the Middle Fork pluton and the mode of its emplacement was as an asymmetric ballooning diapir (Davis, 1963), as shown by concentric foliation, radial late-stage dikes, foliated enclaves, and folded blocks of schlieren-banded tonalite. Coarse-grained hornblende-bearing trondhjemite is the dominant rock type in the Caribou Mountain pluton, and it is called the ‘main trondhjemite’. It was followed by medium-grained ‘late trondhjemite’ and by late-stage trondhjemitic and granodioritic dikes. All the trondhjemitic rock types are characterized by low alkali contents, high light rare earth elements, low initial 87 Sr/ 86 Sr, and low δ 18 O. However, the late trondhjemite has higher Na 2 O and a higher initial 87 Sr/ 86 Sr value than the main trondhjemite, and the two units cannot be related by fractional crystallization. The late granodioritic dikes are richer in Ba, Rb, Y, and Sc than the late trondhjemite and probably reflect assimilation of Stuart Fork metasedimentary rocks by late-stage trondhjemitic magma. Mafic enclaves in the main trondhjemite contain xenocrysts of quartz and plagioclase derived from the host by magma mixing. The enclaves have K 2 O, Ba, and Rb contents similar to, or higher than those of the host rocks. Their rare earth element (REE) patterns display strong middle REE enrichment caused by accumulation of hornblende, probably as the result of filter pressing. The main trondhjemite cannot be derived from Middle Fork magma because the initial 87 Sr/ 86 Sr of the Middle Fork pluton is lower than that of the trondhjemite. The absence of parental mafic magmas of appropriate composition suggests that the Caribou Mountain trondhjemitic magmas formed by partial melting of an amphibolitic source rock compositionally similar to low-K tholeiite.

California

Petrology of Submarine Lavas from Kilauea's Puna Ridge, Hawaii

We have studied 30 quenched tholeiitic lava flows recovered by 20 dredge hauls and one submersible dive along Puna Ridge, the submarine part of the East Rift Zone of Kilauea Volcano, Hawaii Glass grains from numerous additional flows were recovered in turbidite sands cored in the Hawaiian Trough. These quenched lavas document variable primary magma compositions; olivine and multiphase crystallization and fractionation; degassing; wall-rock stoping and assimilation; mixing in the crustal reservoir and the rift zone; entrainment of olivine xenocrysts from a hot, ductile, olivine cumulate body; and disruption of gabbro wallrocks in the rift zone. Glass grains in turbidite sands contain up to 15⋅0wt% MgO, in contrast to < 7⋅0wt% MgO for the sampled glass rinds on lavas. The most forsteritic olivine phenocryst (F0 90·7 ) is in equilibrium with primary Kilauea liquid containing an average 16⋅5 wt% MgO, but ranging from 13⋅4 to 18⋅4%. Lavas and glass grains have more restricted P 2 O 5 /K 2 O and TiO 2 /K 2 O than glass inclusions in olivine, because more diverse liquids trapped as glass inclusions are mixed and homogenized before eruption. Variable trace element compositions in glass grains and whole rocks indicate that the primary liquids form by partial melting of mantle sources retaining clinopyroxene and garnet. Orthopyroxene xenocrysts formed at moderate pressures provide evidence for a sub-crustal staging zone. Chromite and olivine crystallize in the crustal magma reservoir as the liquid cools from an average 1346°C to ∼1170°C. Low viscosities of the primary liquids (0·4 Pas) facilitate olivine settling, and the crystallized olivine forms an olivine cumulate body at the base of the reservoir. Olivine is deformed as the hot ductile dunite body flows down and away from the summit. This flow drives instability of the Hilina landslide on Kilauea. Dikes intrude the dunite, and magma flowing through the dikes disaggregates and entrains olivine xenocrysts in Puna Ridge magmas. Primary liquids pond at or near the base of Kilauea's crustal reservoir because they are denser than more fractionated liquids that occupy the upper parts of the reservoir. The sulfur and water contents of glass rinds indicate that fractionated liquids near the top of the reservoir degas at low pressure, a process that increases their density and causes them to sink to levels where they mix with resident undegassed, near-primary liquid. The fractionated liquids near the top of the magma reservoir acquire excess Cl, owing to assimilation of hydrothermally altered roofrocks. Magma flowing into the rift zone encounters and mixes with low-temperature, multiphase-fractionated melt. The mixed magmas typically contain rare orthopyroxene, plagioclase as sodic as andesine, olivine as fayalitic as F0 75 and Fe-rich augite derived from the fractionated magma. Magma flowing through dikes also dislodged fragments of gabbroic wallrocks that occur as xenoliths. The interrelations in the Kilauean submarine lavas between host glass and glass inclusion compositions, volatile contents and mineral chemistry reveal an extraordinarily complex sequence of petrogenetic processes and events that are difficult or impossible to determine in subaerial Kilauea lavas because of crystallization, reequilibration and degassing during or after their eruption.

Hawaii

Mineral equilibria in the system nepheline-alkali feldspar-plagioclase and their petrological significance

The purpose of this work is a theoretical consideration of equilibrium conditions in the system nepheline - alkali feldspar - plagioclase - alkali chloride aqueous solution based on the thermodynamic treatment of experimental data (Orville, 1963; Iiyama et al., 1963; Debron et al., 1961) for particular systems. The excess thermodynamic functions (Z E , S E , H E , V E ) of solid solutions were calculated for it. These data enable us to derive the diagrams of isotherms for the distribution of sodium components between nepheline and alkali feldspar ; between plagioclase and alkali feldspar ; and among plagioclase , nepheline , and alkali feldspar for the temperature range 400-1000° C. In order to check the calculated diagrams we analysed the minerals from the binary and ternary assemblages of the systems nepheline $ alkali feldspar $ plagioclase from various igneous massifs of nepheline syenites of the world. Temperatures obtained from different geothermometers were found to coincide satisfactorily.

Journal of Petrology

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California

Molybdenite saturation in silicic magmas: Occurrence and petrological implications

We identified molybdenite (MoS 2 ) as an accessory magmatic phase in 13 out of 27 felsic magma systems examined worldwide. The molybdenite occurs as small (< 20 µm) triangular or hexagonal platelets included in quartz phenocrysts. Laser-ablation inductively coupled plasma mass spectrometry analyses of melt inclusions in molybdenite-saturated samples reveal 1–13 ppm Mo in the melt and geochemical signatures that imply a strong link to continental rift basalt–rhyolite associations. In contrast, arc-associated rhyolites are rarely molybdenite-saturated, despite similar Mo concentrations. This systematic dependence on tectonic setting seems to reflect the higher oxidation state of arc magmas compared with within-plate magmas. A thermodynamic model devised to investigate the effects of T , f O 2 and f S 2 on molybdenite solubility reliably predicts measured Mo concentrations in molybdenite-saturated samples if the magmas are assumed to have been saturated also in pyrrhotite. Whereas pyrrhotite microphenocrysts have been observed in some of these samples, they have not been observed from other molybdenite-bearing magmas. Based on the strong influence of f S 2 on molybdenite solubility we calculate that also these latter magmas must have been at (or very close to) pyrrhotite saturation. In this case the Mo concentration of molybdenite-saturated melts can be used to constrain both magmatic f O 2 and f S 2 if temperature is known independently (e.g. by zircon saturation thermometry). Our model thus permits evaluation of magmatic f S 2 , which is an important variable but is difficult to estimate otherwise, particularly in slowly cooled rocks.

Journal of Petrology

Petrologic and experimental evidence for the etching of garnets by organic acids in the upper Jurassic Morrision Formation, northwestern New Mexico

The upper Jurassic Morrison Formation in the southern part of the San Juan Basin contains uniquely etched detrital garnets characterized by smooth, crystallographically controlled faceted surfaces. The etched garnets occur in relatively homogeneous Morrison sandstones in discrete stratigraphic zones that are bounded above and below by sandstones bearing unetched garnets. Diagenetic alterations associated with etched garnets include etched staurolite, skeletal plagioclase, regularly interstratified illite-smectite, iron-rich chlorite, ankerite, albite, diagenetically altered (organic-poor) uranium ore, and extensive secondary porosity. Etching of garnets and partial to complete dissolution of other aluminosilicate minerals were caused by high concentrations of organic acids generated during the maturation of epigenetic organic matter (predominantly type-III kerogen) in the Morrison Formation. The presence of authigenic phases that form near 100 degrees C indicates that temperatures were high enough during diagenesis to cause the thermal degradation of kerogen. The subsequent release of reactive organic acids promoted a variety of water-rock reactions. This hypothesis was corroborated by experiments in which dicarboxylic acid solutions created facets on garnets identical to those developed on naturally etched Morrison garnets. The excellent complexing ability of organic acid anions accounts for the characteristic lack of alteration products on etched surfaces.

Journal of Sedimentary Petrology

Petrology of gabbroic xenoliths in 1960 Kilauea basalt: crystalline remnants of prior (1955) magmatism

The 1960 Kapoho lavas of Kilauea's east rift zone contain 1-10 cm xenoliths of olivine gabbro, olivine gabbro-norite, and gabbro norite. Textures are poikilitic (ol+sp+cpx in pl) and intergranular (cpx+pl??ol??opx). Poikilitic xenoliths, which we interpret as cumulates, have the most primitive mineral compositions, Fo82.5, cpx Mg# 86.5, and An80.5. Many granular xenoliths (ol and noritic gabbro) contain abundant vesicular glass that gives them intersertal, hyaloophitic, and overall 'open' textures to suggest that they represent 'mush' and 'crust' of a magma crystallization environment. Their phase compositions are more evolved (Fo80-70, cpx Mg# 82-75, and An73-63) than those of the poikilitic xenoliths. Associated glass is basaltic, but evolved (MgO 5 wt%; TiO2 3.7-5.8 wt%). The gabbroic xenolith mineral compositions fit existing fractional crystallization models that relate the origins of various Kilauea lavas to one another. FeO/MgO crystal-liquid partitioning is consistent with the poikilitic ol-gabbro assemblage forming as a crystallization product from Kilauea summit magma with ???8 wt% MgO that was parental to evolved lavas on the east rift zone. For example, least squares calculations link summit magmas to early 1955 rift-zone lavas (???5 wt% MgO) through ???28-34% crystallization of the ol+sp+cpx+pl that comprise the poikilitic ol-gabbros. The other ol-gabbro assemblages and the olivine gabbro-norite assemblages crystallized from evolved liquids, such as represented by the early 1955 and late 1955 lavas (???6.5 wt% MgO) of the east rift zone. The eruption of 1960 Kapoho magmas, then, scoured the rift-zone reservoir system to entrain portions of cumulate and solidification zones that had coated reservoir margins during crystallization of prior east rift-zone magmas. ?? 1994 Springer-Verlag.

Bulletin of Volcanology

Petrology of lavas from episodes 2-47 of the Puu Oo eruption of Kilauea Volcano, Hawaii: Evaluation of magmatic processes

The Puu Oo eruption of Kilauea Volcano in Hawaii is one of its largest and most compositionally varied historical eruptions. The mineral and whole-rock compositions of the Puu Oo lavas indicate that there were three compositionally distinct magmas involved in the eruption. Two of these magmas were differentiated (<6.8 wt% MgO) and were apparently stored in the rift zone prior to the eruption. A third, more mafic magma (9-10 wt% MgO) was probably intruded as a dike from Kilauea's summit reservoir just before the start of the eruption. Its intrusion forced the other two magmas to mix, forming a hybrid that erupted during the first three eruptive episodes from a fissure system of vents. A new hybrid was erupted during episode 3 from the vent where Puu Oo later formed. The composition of the lava erupted from this vent became progressively more mafic over the next 21 months, although significant compositional variation occurred within some eruptive episodes. The intra-episode compositional variation was probably due to crystal fractionation in the shallow (0.0-2.9 km), dike-shaped (i.e. high surface area/volume ratio) and open-topped Puu Oo magma reservoir. The long-term compositional variation was controlled largely by mixing the early hybrid with the later, more mafic magma. The percentage of mafic magma in the erupted lava increased progressively to 100% by episode 30 (about two years after the eruption started). Three separate magma reservoirs were involved in the Puu Oo eruption. The two deeper reservoirs (3-4 km) recharged the shallow (0.4-2.9 km) Puu Oo reservoir. Recharge of the shallow reservoir occurred rapidly during an eruption indicating that these reservoirs were well connected. The connection with the early hybrid magma body was cut off before episode 30. Subsequently, only mafic magma from the summit reservoir has recharged the Puu Oo reservoir. ?? 1992 Springer-Verlag.

Bulletin of Volcanology

Geology and petrology of Mahukona Volcano, Hawaii

The submarine Mahukona Volcano, west of the island of Hawaii, is located on the Loa loci line between Kahoolawe and Hualalai Volcanoes. The west rift zone ridge of the volcano extends across a drowned coral reef at about-1150 m and a major slope break at about-1340 m, both of which represent former shoreines. The summit of the volcano apparently reached to about 250 m above sea level (now at-1100 m depth) did was surmounted by a roughly circular caldera. A econd rift zone probably extended toward the east or sutheast, but is completely covered by younger lavas from the adjacent subaerial volcanoes. Samples were vecovered from nine dredges and four submersible lives. Using subsidence rates and the compositions of flows which drape the dated shoreline terraces, we infer that the voluminous phase of tholeiitic shield growth ended about 470 ka, but tholeiitic eruptions continued until at least 435 ka. Basalt, transitional between tholeiitic and alkalic basalt, erupted at the end of tholeiitic volcanism, but no postshield-alkalic stage volcanism occurred. The summit of the volcano apparently subcided below sea level between 435 and 365 ka. The tholeiitic lavas recovered are compositionally diverse.

Hawaii

Petrology of Hualalai volcano, Hawaii: Implication for mantle composition

Hualalai is one of five volcanoes whose eruptions built the island of Hawaii. The historic 1800-1801 flows and the analyzed prehistoric flows exposed at the surface are alkalic basalts except for a trachyte cone and flow at Puu Waawaa and a trachyte maar deposit near Waha Pele. The 1800-1801 eruption produced two flows: the upper Kaupulehu flow and the lower Huehue flow. The analyzed lavas of the two 1800-1801 flows are geochemically identical with the exception of a few samples from the toe of the Huehue flow that appear to be derived from a separate magmatic batch. The analyzed prehistoric basalts are nearly identical to the 1800-1801 flows but include some lavas that have undergone considerable shallow crystal fractionation. The least fractionated alkalic basalts from Hualalai are in equilibrium with mantle olivine (Fo87) indicating that the Hawaiian mantle source region is not unusually iron-rich. The 1800-1801 and analyzed prehistoric basalts can be generated by about 5-10% partial fusion of a garnet-bearing source relatively enriched in the light-rare-earths. The mantle underlying the Hawaiian Islands is chemically and mineralogically heterogeneous before and after extraction of the magmas that make up the volcanoes.

Hawaii

Petrology of the 2016–2017 eruption of Bogoslof Island

The 2016–2017 eruption of Bogoslof primarily produced crystal-rich amphibole basalts. The dominant juvenile tephra were highly microlitic with diktytaxitic vesicles, and amphiboles had large reaction rims. Both observations support a magma history of slow ascent and/or shallow stalling prior to eruption. Plagioclase-amphibole-clinopyroxene mineralogy are also suggestive of shallow magma crystallization. Lavas were emplaced as shallow submarine lava domes and cryptodomes that produced 70 relatively short-lived and water-rich explosions over the course of the 9-month long eruption. The explosions ejected older trachyandesite lavas that were likely uplifted by cryptodome emplacement that began in December 2016 and continued for many months. Trachyte pumice, similar in composition to a 1796 lava dome, was entrained in basalts by the end of the eruption. The pumice appears to be a largely crystalline magma that was rejuvenated, entrained in the basalt, and heated to ~1000 ℃. The composition of trachytes require differentiation through stronger amphibole control than the apparent shallow crustal evolution implied for the basalt. This suggests that they are magmas derived from a mid-crustal zone of amphibole crystallization. Nearby arc-front volcanoes that notably lack amphibole have strikingly similar compositional trends. Trace element signatures of the Bogoslof basalts, however, suggest derivation from a mantle source with residual garnet and lower-degree melting than basalts from nearby arc-front volcanoes. The diversity of magmas erupted at Bogoslof thus provides an opportunity not only to probe rare backarc compositions from the Aleutian arc, but also to examine the apparent role of amphibole in generating evolved compositions more broadly in arc environments.

Alaska

The petrologic and degassing behavior of sulfur and other magmatic volatiles from the 2018 eruption of Kīlauea, Hawaiʻi: Melt concentrations, magma storage depths, and magma recycling

Kīlauea Volcano’s 2018 lower East Rift Zone (LERZ) eruption produced exceptionally high lava effusion rates and record-setting SO 2 emissions. The eruption involved a diverse range of magmas, including primitive basalts sourced from Kīlauea’s summit reservoirs. We analyzed LERZ matrix glasses, melt inclusions, and host minerals to identify melt volatile contents and magma storage depths. The LERZ glasses and melt inclusions span nearly the entire compositional range previously recognized at Kīlauea. Melt inclusions in Fo 86-89 olivine from the main eruptive vent (fissure 8) underwent 70–170 °C cooling during transport in LERZ carrier melts, causing extensive post-entrapment crystallization and sulfide precipitation. Many of these melt inclusions have low sulfur (400–900 ppm) even after correction for sulfide formation. CO 2 and H 2 O vapor saturation pressures indicate shallow melt inclusion trapping depths (1–5 km), consistent with formation within Kīlauea’s Halemaʻumaʻu and South Caldera reservoirs. Many of these inclusions also have degassed δ 34 S values (− 1.5 to − 0.5‰). Collectively, these results indicate that some primitive melts experienced near-surface degassing before being trapped into melt inclusions. We propose that decades-to-centuries of repeated lava lake activity and lava drain-back during eruptions (e.g., 1959 Kīlauea Iki) recycled substantial volumes of degassed magma into Kīlauea’s shallow reservoir system. Degassing and magma recycling from the 2008–2018 Halemaʻumaʻu lava lake likely reduced the volatile contents of LERZ fissure 8 magmas, resulting in lower fountain heights compared to many prior Kīlauea eruptions. The eruption’s extreme SO 2 emissions were due to high lava effusion rates rather than particularly volatile-rich melts.

Hawaii

Occurrence of chromian, hercynitic spinel ("pleonaste") in Apollo-14 samples and its petrologic implications

Many isolated grains of a reddish pleonaste-type spinel occur in fines and metabreccia samples, particularly 14 319. Electron microprobe analyses (104) of spinels and their associated phases include 58 of pleonaste which show Mg/(Mg + Fe) 0.44–0.62 and Cr/(Cr + Al) 0.017–0.134 (atomic), plus minor amounts of other ions, and differ greatly from almost all previously recorded lunar spinels; almost no spinels of intermediate composition were found. Two types of compositional zoning exist: a diffuse primary one with cores lower in Ti, and a narrow secondary one from reaction with matrix yielding rims higher in Cr, Ti, and Mn. At contacts with breccia matrix there is a narrow corona of almost pure plagioclase (An 80 -An 94 ), free of opaque minerals and pyroxene. Two types of solid inclusions found in the pleonaste are calcic plagioclase, and tiny spherical masses of nickel-rich sulfide. Similar pleonaste occurs in crystalline rock clasts, mainly with plagioclase; one clast (A) consists only of coarse olivine, plagioclase, and pleonaste, with granulated grain boundaries suggestive of deformation. From composition and texture, this clast is one possible candidate for the mafic cumulate counterpart of the “anorthositic” crust. Another clast (B), also made solely of olivine, plagioclase and pleonaste, is itself a breccia. These data suggest a two-stage brecciation process: 1) disruption (probably pre-Imbrian) of a deep-seated pleonaste-bearing source rock like A and reconsolidation to form a breccia without addition of pyroxene, ilmenite or other minerals; and 2) disruption of this breccia to yield breccia clast B which was then incorporated into the Fra Mauro formation.

Earth and Planetary Science Letters

Petrology of eucrites, howardites and mesosiderites

The eucrite and howardite calcium-rich achondrites and many mesosiderites are considered as a coherent meteorite assemblage, their silicates consisting essentially of calciumpoor monoclinic and orthorhombic pyroxenes and calcium-rich plagioclase feldspar. The achondrites can be grouped according to their brecciated structure as follows: eucrites—unbrecciated and monomict brecciated achondrites; howardites—polymict brecciated achondrites. Many mesosiderites contain brecciated structures; they are distinguished from the achondrites by their large metallic fraction. The structure and composition of rock fragments in the breccias indicate a complicated sequence of events including magmatic differentiation, brecciation, recrystallization and refragmentation, and ejection from the parent body. Detailed mineralogical and chemical data suggest that the magmatic differentiation proceeded primarily by the separation of pyroxene from an ultrabasic parent material that had a much lower alkali content than ordinary chondrites. Magmatic crystallization took place in environments ranging from extrusive to deep-seated intrusive. Polymict breccias contain fragments with a wide variety of magmatic and recrystallization textures, which suggests that the breccias were formed either in very large or repeated fragmentation events. Monomict breccias contain fragments with a small range of similar magmatic textures, which suggests that these breccias were formed by small or single events. Petrographic evidence suggests that many of the breccias are impact breccias. Either in their original magmatic crystallization sites or in the sites of breccia accumulation, most of these meteorites apparently had a near-surface location prior to ejection from the parent body. Evidence obtained from eucrites, howardites and mesosiderites forms an important part of our understanding of the early evolution of the surface regions of their parent body. Chemical and oxidation conditions were different from those presently found in the Earth's crust and upper mantle, but the necessary conditions may have been present in the early history of the Earth. A lunar origin for eucrites, howardites and mesosiderites is proposed, but an asteroidal origin can not be presently excluded.

Geochimica et Cosmochimica Acta

Petrology of some lithic fragments from Luna 20

Microscopic and electron microprobe studies were made of polished thin sections of part of a 30-mg sample of 250–500 μm lunar soil returned by Luna 20 from a point between Mare Fecunditatis and Mare Crisium. Very fine-grained lithic (crystalline) rock fragments, composing about one fifth of the total sample, have mineralogical compositions equivalent to various types of gabbro, anorthositic gabbro, gabbroic anorthosite and troctolite, with minor basalt. The textures now observed in these fragments are in large part metamorphic. Twentyseven electron microprobe analyses of minerals from these fragments are presented, including olivine, plagioclase, pyroxene, spinel, nickel-iron and a Zr-Ti-REE mineral possibly similar to ‘phase B’ of Lovering and Wark (1971). Analyses of seven melt inclusions and twenty-eight defocused beam analyses of lithic fragments are also given. Some of the fragments contain ‘gas’ inclusions which, along with the fine grain size, are believed to indicate final crystallization under low pressure near surface conditions. The almost complete absence of granophyric material in this sample raises the question of whether or not there are at least two distinct magmas for the plagioclase-rich terrae rocks from which this soil sample was derived in part.

Geochimica et Cosmochimica Acta

Age and petrology of the Tertiary As Sarat volcanic field, southwestern Saudi Arabia

Harrat As Sarat forms the second smallest and southernmost of the basalt fields of western Saudi Arabia and is part of a voluminous Red Sea rift-related continental alkali basalt province. The rocks of the As Sarat were emplaced during the first stage of Red Sea rifting and represent the northernmost extension of the Tertiary Trap Series volcanics that occur mainly in the Yemen Arab Republic and Ethiopia. The field consists of up to 580 m of basalt flows, that are intruded by basaltic plugs, necks, minor dikes, and highly evolved peralkaline trachyte intrusions. K-Ar ages indicate that the As Sarat field formed between 31 and 22 Ma and contains an eruption hiatus of one million years that began about 25 Ma ago. Pre-hiatus flows are primarily hypersthene normative intersertal subalkaline basalt, whereas the majority of post-hiatus flows are nepheline normative alkali basalt and hawaiite with trachytic textures. Normative compositions of the basalts are consistent with their genesis by partial melting at varying depths. Trace element abundances in the basalt indicate that varying degrees of partial melting and fractional crystallization (or crystal accumulation) had major and minor roles, respectively, in development of compositional variation in these rocks. Modeling indicates that the pre-hiatus subalkaline basalts represent 8–10 percent mantle melting at depths of about 70 km and the post-hiatus alkali basalts represent 4–9 percent mantle melting at depths greater than 70 km.

southwestern Saudi Arabia

Organic petrology of epi-impsonite at Page, Oklahoma, U.S.A.

Impsonite (asphaltic pyrobitumen) occurs as fracture-filling veins cutting massive sandstone in the frontal Ouachita Mountains near Page, Oklahoma. The Page impsonite formed from low-temperature alteration of crude oil. Mean maximum bitumen reflectance in oil immersion ( R max "> R max ) of seven samples is 1.41–1.96%. Mean apparent bireflectance of these samples is 0.15–0.54%. The Page deposit classifies at the upper end of epi-impsonite in the generic classification for solid bitumen, based on physical, chemical, and optical characteristics, and as post-oil with unlimited migration in the genetic classification for solid bitumen.

Oklahoma

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology