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Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington↗

Environmentalism and natural aggregate mining

Sustaining a developed economy and expanding a developing one require the use of large volumes of natural aggregate. Almost all human activity (commercial, recreational, or leisure) is transacted in or on facilities constructed from natural aggregate. In our urban and suburban worlds, we are almost totally dependent on supplies of water collected behind dams and transported through aqueducts made from concrete. Natural aggregate is essential to the facilities that produce energy—hydroelectric dams and coal-fired powerplants. Ironically, the utility created for mankind by the use of natural aggregate is rarely compared favorably with the environmental impacts of mining it. Instead, the empty quarries and pits are seen as large negative environmental consequences. At the root of this disassociation is the philosophy of environmentalism, which flavors our perceptions of the excavation, processing, and distribution of natural aggregate. The two end-member ideas in this philosophy are ecocentrism and anthropocentrism. Ecocentrism takes the position that the natural world is a organism whose arteries are the rivers—their flow must not be altered. The soil is another vital organ and must not be covered with concrete and asphalt. The motto of the ecocentrist is “man must live more lightly on the land.” The anthropocentrist wants clean water and air and an uncluttered landscape for human use. Mining is allowed and even encouraged, but dust and noise from quarry and pit operations must be minimized. The large volume of truck traffic is viewed as a real menace to human life and should be regulated and isolated. The environmental problems that the producers of natural aggregate (crushed stone and sand and gravel) face today are mostly difficult social and political concerns associated with the large holes dug in the ground and the large volume of heavy truck traffic associated with quarry and pit operations. These concerns have increased in recent years as society's demand for living space has encroached on the sites of production; in other words, the act of production has engendered condemnation. Many other environmental problems that are associated with dust and noise and blasting from quarry and pit operations have been reduced through the efficient use of technology. Recycling concrete in buildings, bridges, and roads and asphaltic pavements will ultimately reduce the demand for virgin natural aggregate. The impact created by the large holes in the ground required for the mining of natural aggregate can be greatly reduced by planning their reclamation before mining begins.

Natural Resources Research↗

Saproxylic beetles' morphological traits and higher trophic guilds indicate boreal forest naturalness

Forests contribute to numerous ecosystem functions and services and contain a large proportion of terrestrial biodiversity, but they are being negatively impaced by anthropogenic activities. Forests that have never been clear-cut and have old growth characteristics, termed “near-natural,” often harbor different and richer species assemblages than managed forests. Alternative management strategies may be able to balance the needs of biodiversity with the demands of forestry, but evaluation efforts are limited by the challenges of measuring biodiversity. Species richness is frequently used as a simple measure of biodiversity, but research indicates that it may not adequately capture community-level changes. Alternatively, trait-based measures of biodiversity may prove to be useful, but research is lacking. In this paper, we use a large dataset that includes 339 obligate saproxylic beetle species collected over a decade in the boreal region throughout southern Norway to: (1) establish if there is a difference in beetle community composition between near-natural and managed forests; and (2) determine which measures of beetle biodiversity best indicate forest naturalness. We arranged the sites in an ordination space and tested for differences in community composition between these forest types. We also tested different measures of biodiversity to determine which were the most predictive of forest naturalness. We found a clear difference in community composition between near-natural and managed forests. Additionally, three measures of biodiversity were most predictive of forest naturalness: proportional abundance of predators, community weighted mean (CWM) of wing length, and CWM of body roundness. The probability that a forest was near-natural increased with the proportional abundance of predators but decreased with CWM wing length and body roundness. Although species richness was higher in near-natural forests, the effect was not significant. Overall, our findings underscore the conservation value of near-natural forests and highlight the potential of several measures of biodiversity for determining forest quality.

Ecology and Evolution↗

eZ flow metrics: Using z-scores to estimate deviations from natural flow in the Colorado River below Glen Canyon Dam

River flow patterns are primary drivers of lotic ecosystems, and hundreds of metrics have been developed to quantify flow attributes. Although existing metrics have been a powerful tool in designing environmental flows, they are often developed with specific resources in mind and are rarely directly comparable with each other (i.e., units are often different). Here, we focus on natural flows as the resource of interest and develop z-score metrics that measure the naturalness of regulated flows, incorporating natural means and interannual variation. These “eZ metrics” summarize whole year, subdaily, and functional flow patterns as standard deviations from natural such that their values are directly comparable. We illustrate their utility with a case study from the Colorado River downstream of Glen Canyon Dam in Arizona, USA. We calculated metrics for 1964–2022, spanning greater than 5 decades of changing water policy, hydropower generation, and flow experimentation. We evaluate four options for estimating natural baseline flows. Across metrics, we found that subdaily stage variation deviated the most from baseline. Flows to satisfy regional water policy and power demands altered metrics more than designer flows (which target specific resource outcomes), and years with low water releases were closest to natural. Most of the designer flows have not made flow patterns more natural, due to incorrect seasonal timing, small magnitude, or short duration. By explicitly considering interannual variability and quantifying how regulated flows differ from natural using standard deviations, these metrics can inform management when the goal is to restore a natural flow regime.

Colorado River basin↗

Natural resource assessment: an approach to science based planning in national parks

We conducted a natural resource assessment at two national parks, New River Gorge National River and Shenandoah National Park, to help meet the goals of the Natural Resource Challenge-a program to help strengthen natural resource management at national parks. We met this challenge by synthesizing and interpreting natural resource information for planning purposes and we identified information gaps and natural significance of resources. We identified a variety of natural resources at both parks as being globally and/or nationally significant, including large expanses of unfragmented, mixed-mesophytic forests that qualify for wilderness protection, rare plant communities, diverse assemblages of neotropical migratory birds and salamanders, and outstanding aquatic recreational resources. In addition, these parks function, in part, as ecological reserves for plants in and wildlife. With these significant natural resources in mind, we also developed a suite of natural resource management recommendations in light of increasing threats from within and outside park boundaries. We hope that our approach can provide a blueprint for natural resource conservation at publicly owned lands.

Environmental Management↗

Management and natural regeneration in multiple ponderosa pine forests of the southwestern United States

Management treatments in ponderosa pine forests of the southwestern United States (SWUS) are largely done for wildfire mitigation and restoration to lower tree densities. However, lack of natural ponderosa pine regeneration in undisturbed forests (i.e., no occurrence of stand-replacing events) may require management treatments to promote regeneration. We conducted a field and modeling study in 77 ponderosa pine forests across 7 SWUS locations, with the goal of evaluating management impacts on recent natural regeneration ( ∼ "> ∼ 20 y). We categorized management into 3 broad categories: unmanaged, thinned from above and/or below (thinning), and thinned + "> + understory burned (burning). Although climate suitability declined from 1981-2020, management treatments – especially burning – promoted natural regeneration. High density regeneration, an undesirable outcome, occurred in 21 % "> % of managed sites. In addition to effects on near-surface temperature and soil moisture, management conducive to natural regeneration was associated with the density of competing tree species, understory litter and debris cover, and adult tree cone production. Natural regeneration occurred ∼ "> ∼ 5-10 y following management, underscoring sustained effects of management treatments on tree reproduction success. Our results show that forest management treatments have the potential to promote natural ponderosa pine regeneration in the SWUS, sometimes at undesirable high densities. Study Implications: Natural ponderosa pine regeneration is declining in forests of the southwestern United States (SWUS), and may increasingly be incorporated as a goal of forest management treatments. Across a diverse set of managed and unmanaged SWUS forest sites, we found that contemporary management treatments – especially thinning + "> + prescribed understory burning – supported natural ponderosa pine regeneration over the past two decades, which were climatically unfavorable in much of the region. Our results show that existing forest management treatments have the potential to promote natural ponderosa pine regeneration in the SWUS, but will require assessment and modification through time to remain effective.

Forest Science↗

Sources and chemical stability of soil organic carbon in natural and created coastal marshes of Louisiana

Coastal marshes are globally important for sequestering carbon, yet sea-level rise and anthropogenic stressors can reduce their capacity as carbon sinks. Marsh restoration can offset a portion of carbon loss through the degradation of natural marshes, but potential differences in the sources and stability of soil organic carbon (SOC) between created and natural marshes may affect their function as a long-term carbon sink. Here, we examine the sources and chemical stability of SOC in natural and created marshes across the Gulf coast of Louisiana, USA. Marshes were examined along an estuarine salinity gradient in a former interdistributary basin of the Mississippi River Delta and in six created marshes across a 32-year chronosequence and a natural reference marsh ( n = 6) in the Chenier Plain. Carbon source was assessed using δ 13 C analysis and chemical stability was determined through an acid hydrolysis digestion that removed labile carbon (LC). Soil δ 13 C values suggested that the local vegetation dominated SOC in all natural marshes although brackish marshes had a mix of sources and degradation of SOC. Recalcitrant carbon (RC) was 72.2 ± 0.5 % of SOC across fresh, brackish and saline marshes. The depth-averaged RC accumulation rate was almost three times greater than LC accumulation rate, yet both contributed significantly to accretion and long-term SOC accumulation (124–132 g m −2 y −1 in natural marshes). RC and SOC accumulation rate increased with mineral sediment accumulation rate. For the created marshes, SOC became increasingly recalcitrant due to an increase in in-situ plant inputs, but accumulation rates were lower than the natural marshes. Overall, this study illustrates that natural marshes have a large stock of RC from the vegetation while dredge sediment created marshes have no plant-derived carbon initially, which accumulates slowly thereafter. Restoration practices may be improved by preserving and augmenting these deteriorating but carbon-rich natural marshes.

Louisiana↗

Effect of river sediment on phosphorus chemistry of similarly aged natural and created wetlands in the Atchafalaya Delta, Louisiana, USA

The goal of wetland creation is to produce an artificial wetland that functions as a natural wetland. Studies comparing created wetlands to similarly aged natural wetlands provide important information about creation techniques and their improvement so as to attain that goal. We hypothesized that differences in sediment phosphorus accretion, deposition, and chemistry between created and natural wetlands in the Atchafalaya Delta, Louisiana, USA were a function of creation technique and natural river processes. Sediment deposition was determined with feldspar marker horizons located in created and natural wetlands belonging to three age classes (<3, 5-10, and 15-20 yr old). Phosphorus fractions were measured in these deposited sediments and in suspended and bedload sediment from the Atchafalaya River. Bedload sediment had significantly lower iron- and aluminum-bound, reductant-soluble, and total phosphorus than suspended sediment due to its high sand percentage. This result indicates that wetlands artificially created in the Atchafalaya Delta using bedload sediment will initially differ from natural wetlands of the same age. Even so, similarities between the mudflat stratum of the <1- to 3-yr-old created wetland and the mudflat stratum of the 15- to 20-yr-old natural wetland support the contention that created wetlands in the Atchafalaya Delta can develop natural characteristics through the deposition of river suspended sediment. Differences between three created wetland strata, the 15- to 20-yr-old willow stratum and the < 1- to 3-yr-old willow and mixed marsh strata, and their natural counterparts were linked to design elements of the created wetlands that prevented the direct deposition of the river's suspended sediment. ?? ASA, CSSA, SSSA.

Journal of Environmental Quality↗

Comparison of aliphatic hydrocarbons, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, polybrominated diphenylethers, and organochlorine pesticides in Pacific sanddab (Citharichthys sordidus) from offshore oil platforms and natural reefs along the California coast

Recently, the relative exposure of Pacific sanddab ( Citharichthys sordidus ) to polycyclic aromatic hydrocarbons (PAHs) at oil-production platforms was reported, indicating negligible exposure to PAHs and no discernible differences between exposures at platforms and nearby natural areas sites. In this report, the potential for chronic PAH exposure in fish is reported, by measurement of recalcitrant, higher molecular weight PAHs in tissues of fish previously investigated for PAH metabolites in bile. A total of 34 PAHs (20 PAHs, 11 alkylated PAHs, and 3 polycyclic aromatic thiophenes) were targeted. In addition, legacy contaminants—polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs),—and current contaminants, polybrominated diphenylethers (PBDEs) linked to endocrine disruption, were measured by gas chromatography with electron-capture or mass spectrometric detection, to form a more complete picture of the contaminant-related status of fishes at oil production platforms in the Southern California Bight. No hydrocarbon profiles or unresolved complex hydrocarbon background were found in fish from platforms and from natural areas, and concentrations of aliphatics were low less than 100 nanograms per gram (ng/g) per component]. Total-PAH concentrations in fish ranged from 15 to 37 ng/g at natural areas and from 8.7 to 22 ng/g at platforms. Profiles of PAHs were similar at all natural and platform sites, consisting mainly of naphthalene and methylnaphthalenes, phenanthrene, fluoranthene, and pyrene. Total-PCB concentrations (excluding non-ortho-chloro-substituted congeners) in fish were low, ranging from 7 to 22 ng/g at natural areas and from 10 to 35 ng/g at platforms. About 50 percent of the total-PCBs at all sites consisted of 11 congeners: 153 > 138/163/164 > 110 > 118 > 15 > 99 > 187 > 149 > 180. Most OCPs, except dichlorodiphenyltrichloroethane (DDT)-related compounds, were not detectable or were at concentrations of less than 1 ng/g in fish. p,p′ -dichlorodiphenyltrichloroethane ( p,p′ -DDE) ranged from 5.6 to 33 ng/g at natural areas and from 17 to 76 ng/g at platforms, and comprised greater than 90 percent of the total-DDT concentrations at all sites. The only detectable PBDE congeners were PBDE-47 and PBDE-100, the total concentrations of which ranged from 0.4 to 1.8 ng/g at natural areas and from 0.5 to 3.0 ng/g at platforms. Total-PAH, -PCB, and -DDT concentrations were compared with other Southern California Bight studies involving shoreline mussel, ( Mytilus Species, Kimbrough and others, 2008) and near shore sampling (Pacific sanddab, Schiff and Allen, 2000). At corresponding sites, only total-PCB concentrations agreed well with results from this study; total-DDT concentrations were generally much lower than concentrations documented in previous studies for samples collected nearer to shore by sewage treatment outfalls or 14 years earlier or closer in time to when DDT production was halted (1970). Natural areas and platforms in the Bight do not appear to be affected by harbor or urban pollution. Platforms were no more polluted than the nearby natural areas, with these locations exhibiting only low concentrations of PAHs, PCBs, DDTs, and other contaminants.

California↗

Landscape consequences of natural gas extraction in Bedford, Blair, Cambria, Centre, Clearfield, Clinton, Columbia, Huntingdon, and Luzerne counties, Pennsylvania, 2004-2010

Increased demands for cleaner burning energy, coupled with the relatively recent technological advances in accessing unconventional hydrocarbon-rich geologic formations, have led to an intense effort to find and extract natural gas from various underground sources around the country. One of these sources, the Marcellus Shale, located in the Allegheny Plateau, is currently undergoing extensive drilling and production. The technology used to extract gas in the Marcellus Shale is known as hydraulic fracturing and has garnered much attention because of its use of large amounts of fresh water, its use of proprietary fluids for the hydraulic-fracturing process, its potential to release contaminants into the environment, and its potential effect on water resources. Nonetheless, development of natural gas extraction wells in the Marcellus Shale is only part of the overall natural gas story in this area of Pennsylvania. Conventional natural gas wells, which sometimes use the same technique, are commonly located in the same general area as the Marcellus Shale and are frequently developed in clusters across the landscape. The combined effects of these two natural gas extraction methods create potentially serious patterns of disturbance on the landscape. This document quantifies the landscape changes and consequences of natural gas extraction for Bedford, Blair, Cambria, Centre, Clearfield, Clinton, Columbia, Huntingdon, and Luzerne Counties in Pennsylvania between 2004 and 2010. Patterns of landscape disturbance related to natural gas extraction activities were collected and digitized using National Agriculture Imagery Program (NAIP) imagery for 2004, 2005/2006, 2008, and 2010. The disturbance patterns were then used to measure changes in land cover and land use using the National Land Cover Database (NLCD) of 2001. A series of landscape metrics is also used to quantify these changes and is included in this publication. In this region, natural gas development disturbed approximately 943 hectares of land in which forest sustained three times the amount of disturbance as agricultural land. One-quarter of that total disturbance was from Marcellus natural gas development.

Pennsylvania↗

Landscape consequences of natural gas extraction in Cameron, Clarion, Elk, Forest, Jefferson, McKean, Potter, and Warren Counties, Pennsylvania, 2004-2010

Increased demands for cleaner burning energy, coupled with the relatively recent technological advances in accessing hydrocarbon-rich geologic formations, have led to an intense effort to find and extract unconventional natural gas from various underground sources around the country. One of these sources, the Marcellus Shale, located in the Allegheny Plateau, is currently undergoing extensive drilling and production. The technology used to extract gas in the Marcellus Shale is known as hydraulic fracturing and has garnered much attention because of its use of large amounts of fresh water, its use of proprietary fluids for the hydraulic-fracturing process, its potential to release contaminants into the environment, and its potential effect on water resources. Nonetheless, development of natural gas extraction wells in the Marcellus Shale is only part of the overall natural gas story in this area of Pennsylvania. Conventional natural gas wells, which sometimes use the same technique for extraction, are commonly located in the same general area as the Marcellus Shale and are frequently developed in clusters across the landscape. The combined effects of these two natural gas extraction methods create potentially serious patterns of disturbance on the landscape. This document quantifies the landscape changes and consequences of natural gas extraction for Cameron, Clarion, Elk, Forest, Jefferson, McKean, Potter, and Warren Counties in Pennsylvania between 2004 and 2010. Patterns of landscape disturbance related to natural gas extraction activities were collected and digitized using National Agriculture Imagery Program (NAIP) imagery for 2004, 2005/2006, 2008, and 2010. The disturbance patterns were then used to measure changes in land cover and land use using the National Land Cover Database (NLCD) of 2001. A series of landscape metrics is also used to quantify these changes and is included in this publication. In this region, natural gas and oil development disturbed approximately 5,255 hectares (ha) (conventional, 2,400 ha; Marcellus, 357 ha; and oil, 1,883 ha) of land of which 3,507 ha were forested land and 610 ha were agricultural land. Eighty percent of that total disturbance was from conventional natural gas and oil development.

Pennsylvania↗

A precipitation-runoff model for simulating natural streamflow conditions in the Smith River watershed, Montana, water years 1996-2008

This report documents the construction of a precipitation-runoff model for simulating natural streamflow in the Smith River watershed, Montana. This Precipitation-Runoff Modeling System model, constructed in cooperation with the Meagher County Conservation District, can be used to examine the general hydrologic framework of the Smith River watershed, including quantification of precipitation, evapotranspiration, and streamflow; partitioning of streamflow between surface runoff and subsurface flow; and quantifying contributions to streamflow from several parts of the watershed. The model was constructed by using spatial datasets describing watershed topography, the streams, and the hydrologic characteristics of the basin soils and vegetation. Time-series data (daily total precipitation, and daily minimum and maximum temperature) were input to the model to simulate daily streamflow. The model was calibrated for water years 2002–2007 and evaluated for water years 1996–2001. Though water year 2008 was included in the study period to evaluate water-budget components, calibration and evaluation data were unavailable for that year. During the calibration and evaluation periods, simulated-natural flow values were compared to reconstructed-natural streamflow data. These reconstructed-natural streamflow data were calculated by adding Bureau of Reclamation’s depletions data to the observed streamflows. Reconstructed-natural streamflows represent estimates of streamflows for water years 1996–2007 assuming there was no agricultural water-resources development in the watershed. Additional calibration targets were basin mean monthly solar radiation and potential evapotranspiration. The model estimated the hydrologic processes in the Smith River watershed during the calibration and evaluation periods. Simulated-natural mean annual and mean monthly flows generally were the same or higher than the reconstructed-natural streamflow values during the calibration period, whereas they were lower during the evaluation period. The shape of the annual hydrographs for the simulated-natural daily streamflow values matched the shape of the hydrographs for the reconstructed-natural values for most of the calibration period, but daily streamflow values were underestimated during the evaluation period for water years 1996–1998. The model enabled a detailed evaluation of the components of the water budget within the Smith River watershed during the water year 1996–2008 study period. During this study period, simulated mean annual precipitation across the Smith River watershed was 16 inches, out of which 14 inches evaporated or transpired and 2 inches left the basin as streamflow. Per the precipitation-runoff model simulations, during most of the year, surface runoff rarely (less than 2 percent of the time during water years 2002–2008) makes up more than 10 percent of the total streamflow. Subsurface flow (the combination of interflow and groundwater flow) makes up most of the total streamflow (99 or more percent of total streamflow for 71 percent of the time during water years 2002–2008).

Montana↗

Multi-resource analysis: A proof of concept study of natural resource tradeoffs in the Piceance Basin, Colorado, using the net resources assessment (NetRA) decision support tool

Executive Summary The U.S. Geological Survey (USGS) is developing a multi-resource analysis (MRA) line of products to inform land-use decision makers. Specifically, MRA products will integrate scientific information, include considerations for natural resource interrelations, and quantify the effects of resource management decisions in biophysical, economic, and societal terms. As part of the establishment of the MRA, the USGS, in collaboration with the University of New Mexico, has developed the Net Resources Assessment (NetRA) decision support tool. As a proof of concept analysis, the NetRA was applied to the Piceance basin in Colorado in a hypothetical example to illustrate how resource managers could use the NetRA to consider tradeoffs of natural resources among alternative development plans and land cover patterns within a geographic region. The NetRA is a policy-relevant approach to assess the availability of multiple natural resources. It is an analytical toolset that may be used to examine the spatiotemporal relations between development of energy and mineral resources and delivery of biological natural resources. The NetRA operates at multiple map scales and contains a set of integrated, compatible submodels with specific data requirements for natural resource stocks, engineering economics, biophysical, and ecological data for ecosystem services stocks, market prices, regulations, and nonmarket values. The NetRA includes an explicit process to consider the interdependence between development and conservation, which is a crucial consideration in land-management and land-use decisions. The NetRA is used to estimate an expected net resource value (NRV). The NRV is the expected, present value, economic benefit from the extraction of a resource (for example, natural gas) minus the total cost of production, which is the aggregation of the development, production, and social costs. Social costs include private costs plus any external costs. There can be external social benefits associated with natural gas production, such as increased demand for locally produced goods and increased employment in the local area through backward and forward linkages of natural gas production. The NRV is used to compare development outcomes (scenarios) from a range of exploration and development plans for cumulative energy production. The Piceance basin application of the NetRA uses the NRV to assess the tradeoff between continuous natural gas extraction and the effects to the local populations of Odocoileus hemionus (mule deer) and aquatic species and to consumptive water uses for an area the size and resolution of a USGS energy resource assessment unit. In the proof of concept simulation, the 2.9-square-mile-area of USGS oil and gas assessment unit 50200263 (Piceance basin continuous gas unit of the Mesaverde Total Petroleum System) was gridded into 588 cells. From this area, seven clusters with potential for development and three that cannot be developed were identified; the three clusters that cannot be developed were identified as wilderness study areas, areas of critical environmental concern, and national forests. On the basis of these criteria, there are 118 cells unsuitable for development in the oil and gas assessment unit: 84 are in national forests, 23 are areas of critical environmental concern, and 11 are wilderness study areas. The remaining cells in the oil and gas assessment unit can be developed on both private and public lands. Two scenarios were considered that are distinguished as plan 1 and plan 2. Plan 1 keeps the amount of land disturbance unchanged and limits the number of development locations to 140 grid cells for the production period, which constrains the amount of the energy resources available for development; the plan requires the usage of the Bureau of Land Management (BLM) unsuitability criteria. Plan 2 also limits the number of development locations to 140 grid cells for the production period but provides a constant volume of energy production by increasing the density of well pads within the cells. The effects of plan 2 to the NRV when there are five wells per pad and five pads per square mile happen mostly in the first 5 years of development, even though the effects on the population of mule deer continue in later years. This outcome is the result of the upfront development and investment costs and the initial effect to the ecosystem services.

Colorado↗

Methodology for applying monitored natural attenuation to petroleum hydrocarbon-contaminated ground-water systems with examples from South Carolina

Natural attenuation processes such as dispersion, advection, and biogradation serve to decrease concentrations of disssolved contaminants as they are transported in all ground-water systems. However, the efficiency of these natural attenuation processes and the degree to which they help attain remediation goals, varies considerably from site to site. This report provides a methodology for quantifying various natural attenuation mechanisms. This methodology incorporates information on (1) concentrations of contaminants in space and/or time; (2) ambient reduction/oxidation (redox) conditions; (3) rates and directions of ground-water flow; (4) rates of contaminant biodegradation; and (5) demographic considerations, such as the presence of nearby receptor exposure points or property boundaries. This document outlines the hydrologic, geochemical, and biologic data needed to assess the efficiency of natural attenuation, provides a screening tool for making preliminary assessments, and provides examples of how to determine when natural attenuation can be a useful component of site remediation at leaking underground storage tank sites. At a site in the Piedmont Physiographic Province (Laurens, South Carolina), hydrologic and water-chemistry data indicate that the natural attenuation capacity for benzene is approximately 5 percent per foot of flowpath. As a result, benzene concentrations would decrease from about 28,000 micrograms per liter in ground water at the source area to less than 5 micrograms per liter 200 feet downgradient and prior to discharging to a stream. Because of this rapid attenuation, contaminants do not presently impact the stream downgradient of the site. In contrast, at a site in the coastal Plain Physiographic Province (Charleston, South Carolina), hydrologic and water-chemistry data indicate that, even thought the site has a substantial natural attenuation capacity, it may not be sufficient to fully protect a nearby point of ground-water discharge. These two sites illustrate how the efficiency of natural attenuation processes acting on petroleum hydrocarbons can be systematically evaluated using hydrologic, geochemical, and microbiologic methods. These methods, in turn, can be used to assess the role that the natural attenuation of petroleum hydrocarbons can play in achieving overall site remediation.

South Carolina↗

Exploring life history characteristics of naturalized versus stocked chinook

Naturalization of stocked populations can result in divergence of life-history traits from domestic stocks. Lake Michigan supports popular Chinook (Oncorhynchus tshawytscha) Salmon fisheries that have been sustained by stocking since the late 1960s. Natural recruitment of Chinook Salmon in Lake Michigan has increased in the last few decades and currently contributes over 50% of Chinook Salmon recruits. Samples collected as part of a lakewide mass-marking of Lake Michigan Chinook Salmon, starting with the 2006 year class, indicated hatchery fish average 30-mm longer and 130 grams heavier than naturalized fish at age-1. We hypothesized that selective forces differ for naturalized and hatchery populations resulting in divergent life-history characteristics with implications for Chinook Salmon population production and the Lake Michigan fishery. Specific life-history metrics of interest include: age- and size- at maturity, spawning run timing, fecundity, and sex ratio. Objectives: We evaluated life history characteristics between naturally recruited and stocked Chinook Salmon in Lake Michigan to help discern potential changes resulting from naturalization and implications for fisheries. A. Conduct an analysis of historical data to determine if life-history parameters changed through time as the Chinook Salmon population became increasingly naturalized. B. Conduct a two-year field study of naturalized and hatchery stocked Chinook Salmon spawning populations to quantify differences in life-history metrics of adults. C. Determine if reproductive potential differs between naturalized and hatchery stocked Chinook salmon by measuring egg thiamine levels.

Michigan↗

Comparison of litter decomposition in a natural versus coal-slurry pond reclaimed as a wetland

Decomposition is a key function in reclaimed wetlands, and changes in its rate have ramifications for organic-matter accumulation, nutrient cycling, and production. The purpose of this study was to compare leaf litter decomposition rates in coal-slurry ponds vs. natural wetlands on natural floodplain wetlands in Illinois, USA. The rate of decomposition was slower in the natural wetland vs. the coal pond (k=0.0043??0.0008 vs. 0.0066??0.0011, respectively); the soil of the natural wetland was more acidic than the coal pond in this study (pH=5.3 vs. 7.9, respectively). Similarly, higher organic matter levels were related to lower pH levels, and organic matter levels were seven-times higher in the natural wetland than in the coal pond. The coal slurry pond was five years old at the time of the study, while the natural oxbow wetland was older (more than 550 years). The coal-slurry pond was originally a floodplain wetland (slough); the downstream end was blocked with a stoplog structure and the oxbow filled with slurry. The pattern of decomposition for all species in the coal pond was the same as in the natural pond; Potomogeton nodosus decomposed more quickly than Phragmites australis, and both of these species decomposed more quickly than either Typha latifolia or Cyperus erythrorhizos (k=0.0121??0.0008, 0.0051??0.0006, 0.0024??0.0001, 0-0024??0.0004, respectively). Depending on how open or closed the system is to outside inputs, decomposition rate regulates other functions such as production, nutrient cycling, organic-layer accumulation in the soil, and the timing and nature of delivery of detritus to the food chain. ?? 2004 John Wiley and Sons, Ltd.

Land Degradation and Development↗

Natural recharge estimation and uncertainty analysis of an adjudicated groundwater basin using a regional-scale flow and subsidence model (Antelope Valley, California, USA)

Groundwater has provided 50&ndash;90 % of the total water supply in Antelope Valley, California (USA). The associated groundwater-level declines have led the Los Angeles County Superior Court of California to recently rule that the Antelope Valley groundwater basin is in overdraft, i.e., annual pumpage exceeds annual recharge. Natural recharge consists primarily of mountain-front recharge and is an important component of the total groundwater budget in Antelope Valley. Therefore, natural recharge plays a major role in the Court&rsquo;s decision. The exact quantity and distribution of natural recharge is uncertain, with total estimates from previous studies ranging from 37 to 200 gigaliters per year (GL/year). In order to better understand the uncertainty associated with natural recharge and to provide a tool for groundwater management, a numerical model of groundwater flow and land subsidence was developed. The transient model was calibrated using PEST with water-level and subsidence data; prior information was incorporated through the use of Tikhonov regularization. The calibrated estimate of natural recharge was 36 GL/year, which is appreciably less than the value used by the court (74 GL/year). The effect of parameter uncertainty on the estimation of natural recharge was addressed using the Null-Space Monte Carlo method. A Pareto trade-off method was also used to portray the reasonableness of larger natural recharge rates. The reasonableness of the 74 GL/year value and the effect of uncertain pumpage rates were also evaluated. The uncertainty analyses indicate that the total natural recharge likely ranges between 34.5 and 54.3 GL/year.

California↗

Catalyzing change: A literature review on the implementation of the Nature Futures Framework

The Nature Futures Framework (NFF), developed under the Intergovernmental Science–Policy Platform on Biodiversity and Ecosystem Services (IPBES), serves as a catalyst for advancing new scenarios and models focused on biodiversity and ecosystem services within the broader research community. In particular, the framework facilitates the development of scenarios and models that can help guide change processes toward desirable futures for nature and people. This paper assesses 31 studies that have engaged with the NFF since its introduction in 2020, aiming to identify which research areas have been addressed, and where development needs remain. The applications exhibit a large diversity in terms of locations, spatial scales, methods, outputs, and stakeholder involvement. The most common use of the framework has been in developing visions and scenarios. Nearly all studies engaged with diverse values of nature through the framework’s fundamental value perspectives: ‘Nature for Society’, ‘Nature for Nature’, and ‘Nature as Culture/One with Nature’. While the framework is generally perceived as useful, challenges remain in integrating the NFF across multiple scales and fully incorporating plural values, particularly in measuring relational aspects and avoiding Western-centric biases. Future research priorities include developing integrated, quantitative studies and exploring transformative pathways to enhance the framework's effectiveness in driving sustainable outcomes. Overall, the growing body of work using the NFF provides a strong foundation for distilling best practices, facilitating large-scale applications, and achieving the framework's objectives.

Sustainability Science↗