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Soda Creek springs - metamorphic waters in the eastern Alaska Range
The Soda Creek springs are a group of small, cold mineral springs on the southern flank of the eastern Alaska Range. The spring waters contain anomalous concentrations of carbon dioxide, sodium, chlorine, sulfate, boron, and ammonia and are actively precipitating deposits of calcite and aragonite. Sparingly present in these deposits are mixed-layer illite-montmorillonite clays and zeolite minerals. Low-temperature metamorphic reactions in subjacent marine sedimentary rocks of Jurassic and Cretaceous age may have produced the fluids and silicate minerals. With only a few exceptions, cool bicarbonate-rich springs in Alaska are concentrated south of the Denali fault system in south-central Alaska, southeastern Alaska, and along the Kaltag-Tintina fault system. These areas are characterized by active or recently active tectonism, major faults and folds, and an abundance of marine sedimentary rocks.
Sulfur in serpentinized oceanic peridotites: Serpentinization processes and microbial sulfate reduction
The mineralogy, contents, and isotopic compositions of sulfur in oceanic serpentinites reflect variations in temperatures and fluid fluxes. Serpentinization of <1 Ma peridotites at Hess Deep occurred at high temperatures (200°–400°C) and low water/rock ratios. Oxidation of ferrous iron to magnetite maintained low ƒO 2 and produced a reduced, low-sulfur assemblage including NiFe alloy. Small amounts of sulfate reduction by thermophilic microbes occurred as the system cooled, producing low-δ 34 S sulfide (1.5‰ to −23.7‰). In contrast, serpentinization of Iberian Margin peridotites occurred at low temperatures(∼20°–200°C) and high water/rock ratios. Complete serpentinization and consumption of ferrous iron allowed evolution to higher ƒO 2 . Microbial reduction of seawater sulfate resulted in addition of low-δ 34 S sulfide (∼15 to ∼43‰) and formation of higher-sulfur assemblages that include valleriite and pyrite. The high SO 4 /total S ratio of Hess Deep serpentinites (0.89) results in an increase of total sulfur and high δ 34 S of total sulfur (mean ∼8‰). In contrast, Iberian Margin serpentinites gained large amounts of 34 S-poor sulfide (mean total S = 3800 ppm), and the high sulfide/total S ratio (0.61) results in a net decrease in δ 34 S of total sulfur (mean ≈ −5‰). Thus serpentinization is a net sink for seawater sulfur, but the amount fixed and its isotopic composition vary significantly. Serpentinization may result in uptake of 0.4–14 × 10 12 g S yr −1 from the oceans, comparable to isotopic exchange in mafic rocks of seafloor hydrothermal systems and approaching global fluxes of riverine sulfate input and sedimentary sulfide output.
Revised geomagnetic polarity time scale for the interval 0–5 m.y. B.P.
A change in the constants used in K‐Ar dating and a significant increase in new data have made a recompilation and recomputation of data used to define the Late Cenozoic K‐Ar polarity time scale highly desirable at this time. All available data in the range 0–5 m.y. have been recalculated using the refined constants, with 354 data points in this time interval now meeting the minimum criteria for acceptability. Recalculation of the major polarity epoch boundaries has yielded ages of 0.73 m.y. for the Brunhes‐Matuyama, 2.48 m.y. for the Matuyama‐Gauss, and 3.40 m.y. for the Gauss‐Gilbert boundaries. A revised polarity time scale has been constructed based on available K‐Ar data and information obtained from marine magnetic anomalies and deep‐sea sedimentary cores.
Barium in hybrid granitoid rocks of the southern Snake Range, Nevada
In a magmatic environment, barium usually substitutes for potassium in the crystallizing silicates, and the two increase together in rocks late in the differentiation sequence. Results of this study show the opposite trend in an equivalent of a large part (63-76 percent SiO 2 ) of the classic differentiation sequence that resulted mainly from assimilation of chemically distinct host rocks. The barium content of the hybrid granitoid rock appears to be controlled mainly by the barium contents of the various sedimentary rock types assimilated.
Gravity survey of the Mount Toondina impact structure, South Australia
Gravity and seismic reflection data, together with geologic mapping, indicate that the Mount Toondina feature in South Australia is best interpreted as an eroded 4-km-diameter impact structure consisting of a ring structural depression surrounding a pronounced central uplift. Beds at the center of the structure within the central uplift have been raised as much as 200 m from depth and deformed by convergent flow. Seismic reflection data indicate that deformation extends to depths of only ≈800 m; at greater depths the reflectors are nearly flat lying, indicating little or no deformation. Gravity data show residual anomalies of +1.0 mGal coincident with the central uplift and a −0.5 Mgal low associated with the ring structural depression. Modeling of the gravity data indicates that relatively high-density material occurs within the central uplift, whereas the ring depression is filled with low-density material. The deformation at Mount Toondina is typical of a complex impact crater; the 4-km diameter is consistent with the expected threshold size for complex craters formed in weak to moderate strength sedimentary rocks.
Lg and Rg waves on the California regional networks from the December 23, 1985 Nahanni earthquake
We investigate Lg and Rg propagation in California using the central and southern California regional networks. Approximately 550 stations constitute these two short-period networks providing a dense coverage of almost the entire state. The waveforms recorded from the December 23, 1985, Nahanni, Canada, earthquake are used to construct three profiles along the propagation path (almost N-S) and three perpendicular to the propagation path (almost E-W) to look at the nature of propagation of these two types of surface waves. Groups of records from stations in various geological and tectonic provinces in California are also examined in order to establish regional characteristics of the surface waves. We find that the propagation characteristics of Lg differ from those of Rg across California; Lg waves are apparently more sensitive to crustal heterogeneities. The most striking observations are the similarity of coda for both the Lg and the Rg waves within geologic provinces and the marked difference in coda between regions. These differences are seen in the amplitudes, coda duration, shape of the energy envelope, frequency content, and sharpness of the phase initiation. In general, a decrease in the Moho depth near the Pacific Coast is correlated with a decrease in the surface wave amplitude, especially at higher frequencies (0.15–0.2 Hz). Most interesting is the association of the San Andreas fault with abrupt changes in the wave train amplitudes. The surface waves are amplified in the vicinity of the fault zone and then decrease in amplitude after the zone is crossed. In the Coast Ranges, amplitudes are low and waveform coherence is poor. The Rg phase dominates the record in the Sierra Nevada, and both surface waves are amplified by the thick sedimentary sequence of the Great Valley.
Sorted bed forms as self-organized patterns: 2. complex forcing scenarios
We employ a numerical model to study the development of sorted bed forms under a variety of hydrodynamic and sedimentary conditions. Results indicate that increased variability in wave height decreases the growth rate of the features and can potentially give rise to complicated, a priori unpredictable, behavior. This happens because the system responds to a change in wave characteristics by attempting to self-organize into a patterned seabed of different geometry and spacing. The new wavelength might not have enough time to emerge before a new change in wave characteristics occurs, leading to less regular seabed configurations. The new seabed configuration is also highly dependent on the preexisting morphology, which further limits the possibility of predicting future behavior. For the same reasons, variability in the mean current magnitude and direction slows down the growth of features and causes patterns to develop that differ from classical sorted bed forms. Spatial variability in grain size distribution and different types of net sediment aggradation/degradation can also result in the development of sorted bed forms characterized by a less regular shape. Numerical simulations qualitatively agree with observed geometry (spacing and height) of sorted bed forms. Also in agreement with observations is that at shallower depths, sorted bed forms are more likely to be affected by changes in the forcing conditions, which might also explain why, in shallow waters, sorted bed forms are described as ephemeral features. Finally, simulations indicate that the different sorted bed form shapes and patterns observed in the field might not necessarily be related to diverse physical mechanisms. Instead, variations in sorted bed form characteristics may result from variations in local hydrodynamic and/or sedimentary conditions.
Muscle scars of late Paleozoic freshwater ostracodes from West Virginia
Different adductor muscle attachment scar patterns of the three ostracode genera Darwinula Brady and Robertson, 1885, Gutschickia Scott, 1944, and Whipplella Holland, 1934, from Pennsylvanian and Permian rocks of 'West Virginia are illustrated for the first time. Gutschickia and Whipplella have been considered as junior synonyms of Carbonita Strand, 1928, and the oldest darwinulid scar pattern previously known was from the Upper Triassic of Germany. The different patterns document the presence of Darwinula in the Pennsylvanian of the United States and indicate that Whipplella and Gutschickia are valid genera. The use of ostracodes in discriminating between Carboniferous and Permian continental sedimentary rocks should be based on restudy of the species in these genera.
Cretaceous planktic foraminiferal biostratigraphy of the Calera Limestone, Northern California, USA
The Calera Limestone is the largest, most stratigraphically extensive limestone unit of oceanic character included in the Franciscan Complex of northern California. The aim of this paper is to place the Calera Limestone at its type locality (Rockaway Beach, Pacifica) in a high-resolution biostratigraphy utilizing planktic foraminifers studied in thin section. A section, about 110 m-thick, was measured from the middle thrust slice exposed by quarrying on the southwest side of Calera Hill at Pacifica Quarry. Lithologically, the section is divided in two units; a lower unit with 73 m of black to dark-grey limestone, black chert and tuff, and an upper unit with 36.8 m of light-grey limestone and medium-grey chert. Two prominent black-shale layers rich in organic carbon occur 11 m below the top of the lower black unit and at the boundary with overlying light-grey unit, yielding a total organic content (TOC) of 4.7% and 1.8% t.w., respectively. The fossiliferous Calera Limestone section measured at Pacifica Quarry, from the lower black shale, contains eleven zones and three subzones that span approximately 26 m.y. from the early Aptian to the late Cenomanian. The zones indentified range from the Globigerinelloides blowi Zone to the Dicarinella algeriana Subzone of the Rotalipora cushmani Zone. Within this biostratigraphic interval, the Ticinella bejaouaensis and Hedbergella planispira Zones at the Aptian/Albian boundary are missing as are the Rotalipora subticinensis Subzone of the Biticinella breggiensis Zone and the overlying Rotalipora ticinensis Zone in the late Albian owing both to low-angle thrust faulting and to unconformities. The abundance and preservation of planktic foraminifers are poor in the lower part and improve only within the upper G. algerianus Zone. The faunal relationship indicate that the lower black shale occurs in the upper part of the G. blowi Zone and correlates with the Selli Event recognized at global scale in the early Aptian. The upper black shale occurs at or near the boundary between the G. ferreolensis and G. algerianus Zone in the late Aptian. This black layer, or Thalmann Event as named here, seems to represent the sedimentary expression, at the scale of Permanente Terrane, of a global perturbation of the carbon cycle.
Fluorescence spectroscopy of ancient sedimentary organic matter via confocal laser scanning microscopy (CLSM)
Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca ( G. prisca ) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location within individual organic entities and in transects across bedded organic matter. Results from spectral scans of the same field of view in Tasmanites with different laser lines showed progressive red-shift in emission maxima with longer excitation wavelengths. This result indicates steady-state Tasmanites fluorescence emission is an overlapping combination of emission from multiple fluorophore functions. Stokes shift decreased with increasing excitation wavelength, further suggesting the presence of multiple fluorophore functions with different S 1 → S 0 transition energies. This observation also indicates that at longer excitation wavelengths, less absorbed light energy is dissipated via collisional transfer than at shorter excitation wavelengths and may suggest fewer polar functions are preferentially absorbing. Confirming earlier results, emission spectra observed from high fluorescence intensity regions (fold apices) in individual Tasmanites are blue-shifted relative to emission from other locations in the same microfossil. We suggest high intensity emission is from photoselective alignment of polarized excitation with the fluorophore absorption and emission transition moment. The blue shift observed in regions of high intensity emission may be due to relative absence or realignment of polar species, e.g., bridging ether or ester functions, although variations in O abundance could not be confirmed with preliminary time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis. Tasmanites occurring in consolidated sediments are flattened from original spherical morphology and, in optical microscopy, this burial deformation results in generally parallel extinction (strain-influenced) and positive elongation. The deformation also induces fluorescence anisotropy observed as variations in emission wavelength when individual Tasmanites are measured from their long axis parallel to bedding, whereas this effect is absent in bedding-normal view. Transects from G. prisca -rich source layers into adjacent reservoir layers show decrease in fluorescence intensity and spectral red-shift (increase in full-width half-maximum with increasing red portion of the half-width). These results may suggest an increase in fluorescence quenching across the source-to-reservoir transition zone, consistent with an increase in aromaticity following petroleum expulsion and migration. These observations are supported by increasing reflectance values measured across similar micro-scale transects. Our results highlight the applicability of CLSM as a broad and under-utilized approach for the characterization of sedimentary organic matter and are discussed with perspective toward petroleum processes and thermal indices research.
Tectonic evolution of the central Brooks Range mountain front: Evidence from the Atigun Gorge region
Atigun Gorge, at the northern front of the eastern Endicott Mountains, contains well-exposed rocks of the upper part of the Endicott Mountains allochthon and rocks of the structurally higher Picnic Creek or Ipnavik River allochthon. These allochthons contain rocks as young as Early Cretaceous (Valanginian) and are separated by a nearly vertical fault zone that contains exotic blocks of Triassic and Jurassic chert and silicified mudstone. Siliceous rocks of this type are not present in the Endicott Mountains allochthon but are characteristic of the Picnic Creek, Ipnavik River, and some of the other allochthons that structurally overlie the Endicott Mountains allochthon in the central and western Brooks Range. These exotic blocks, therefore indicate that structurally higher rocks of either the Picnic Creek or Ipnavik River allochthon were emplaced during the Early Cretaceous and are preserved along the northern flank of the eastern Endicott Mountains. The deformed thickness of this higher allochthon in the subsurface north of the mountains is unknown but probably exceeds 2 kilometers. Similar relations are mapped east of Atigun Gorge in an area of structural transition from the eastern Endicott Mountains into the northern Philip Smith Mountains, which are formed by the parautochthonous North Slope stratigraphic assemblage. The allochthonous rocks at the mountain front are regionally unconformably overlain by proximal Lower Cretaceous (Albian) foredeep conglomerate at the southern flank of the Colville basin, but at Atigun Gorge, the base of these deposits is interpreted as a possible back thrust at a triangle zone. Conglomerate clasts in the foredeep deposits are dominantly chert, mafic igneous rock, and other lithologies characteristic of the Picnic Creek and Ipnavik River allochthons and scattered clasts from the Endicott Mountains allochthon. The conglomerates show that the chert-rich allochthonous rocks and the Endicott Mountains allochthon were emplaced in the north-central Brooks Range by large-scale crustal shortening (>300 km) between the Valanginian and Albian (∼135 to ∼112 Ma). This orogenic event significantly postdates early stages of Brooks Range orogeny but predates later stages of orogeny documented by stratigraphic and apatite fission-track data. These relations reduce the magnitude of shortening inferred at the triangle zone at the Brooks Range mountain front. The outcrop data suggest that some of the strata preserved at a structurally low level north of the mountain front and visible in the seismic data of the Trans-Alaska Crustal Transect (TACT) may consist of clastic sedimentary rocks of the structurally higher Picnic Creek or Ipnavik River allochthon.
Stratigraphic relations of the Bolsa Quartzite, Vekol Mountains, Pinal County, Arizona
A quartzite unit occurring between the rocks of the Precambrian Apache Group and those of the Cambrian Abrigo Formation in the Vekol Mountains, Final County, Ariz., has been called both Troy Quartzite (Precambrian) and Bolsa(?) Quartzite (Cambrian). Regional and local geologic relationships indicate that this intervening unit is definitely the Bolsa Quartzite. The Bolsa ranges in thickness from at least 200 ft at several localities in the Vekol Mountains to 0 ft over a positive area underlain by Precambrian diabase which has intruded the Apache Group. Previous observations that the diabase intruded the quartzite unit (thereby making this quartzite unit the Troy Quartzite) have been reinterpreted; all nonfaulted exposures of the basal contact of the quartzite unit show sedimentary relationships. No evidence was found to suggest that the Troy Quartzite was ever deposited in the Vekol Mountains.
Diffuse flow hydrothermal manganese mineralization along the active Mariana and southern Izu-Bonin arc system, western Pacific
Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 ?? and 7 ?? manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean-8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of Mn mineralization. Factor analyses indicate various mixtures of two dominant components: hydrothermal Mn oxide for the stratabound Mn and detrital aluminosilicate for the Mn-cemented sandstone; and two minor components, hydrothermal Fe oxyhydroxide and biocarbonate/biosilica. Our conceptual model shows that Mn mineralization was produced by hydrothermal convection cells within arc volcanoes and sedimentary prisms that occur along, the flanks and within calderas. The main source of hydrothermal fluid was seawater that penetrated through fractures, faults, and permeable volcanic edifices. The fluids were heated by magma, enriched in metals by leaching of basement rocks and sediments, and mixed with magmatic fluids and gases. Dikes and sills may have been another source of heat that drove small-scale circulation within sedimentary prisms. Copyright 2008 by the American Geophysical Union.
The role of aeolian sediment in the preservation of archaeological sites in the Colorado River corridor, Grand Canyon, Arizona: Final report on research activities, 2003-2006
This report summarizes a three-year study of aeolian sedimentary processes in the Colorado River corridor, Grand Canyon, Arizona, and discusses the relevance of those processes to the preservation of archaeological sites. Findings are based upon detailed sedimentary and geomorphic investigations conducted in three areas of the river corridor, continuous measurements of wind, precipitation, and aeolian sediment transport at six locations for up to 26 months, short-term field study at 35 other sites, examination of historical aerial photographs, and review of data collected and analyzed by previous studies. Detailed results of this study, which involved collaboration with scientists at the Grand Canyon Monitoring and Research Center, National Park Service, Northern Arizona University, the Hopi Tribe, and GeoArch, Inc., have been published previously in topical USGS Open-File Reports (Draut and Rubin, 2005, 2006), a USGS Scientific Investigations Report (Draut and others, 2005), and will be discussed in two forthcoming journal articles. This report serves as an overview of the results and contains new conclusions regarding aeolian sedimentary processes in the Colorado River Ecosystem and their relevance to many archaeological sites.
Bottom currents and sediment transport in Long Island Sound: A modeling study
A high resolution (300-400 m grid spacing), process oriented modeling study was undertaken to elucidate the physical processes affecting the characteristics and distribution of sea-floor sedimentary environments in Long Island Sound. Simulations using idealized forcing and high-resolution bathymetry were performed using a three-dimensional circulation model ECOM (Blumberg and Mellor, 1987) and a stationary shallow water wave model HISWA (Holthuijsen et al., 1989). The relative contributions of tide-, density-, wind- and wave-driven bottom currents are assessed and related to observed characteristics of the sea-floor environments, and simple bedload sediment transport simulations are performed. The fine grid spacing allows features with scales of several kilometers to be resolved. The simulations clearly show physical processes that affect the observed sea-floor characteristics at both regional and local scales. Simulations of near-bottom tidal currents reveal a strong gradient in the funnel-shaped eastern part of the Sound, which parallels an observed gradient in sedimentary environments from erosion or nondeposition, through bedload transport and sediment sorting, to fine-grained deposition. A simulation of estuarine flow driven by the along-axis gradient in salinity shows generally westward bottom currents of 2-4 cm/s that are locally enhanced to 6-8 cm/s along the axial depression of the Sound. Bottom wind-driven currents flow downwind along the shallow margins of the basin, but flow against the wind in the deeper regions. These bottom flows (in opposition to the wind) are strongest in the axial depression and add to the estuarine flow when winds are from the west. The combination of enhanced bottom currents due to both estuarine circulation and the prevailing westerly winds provide an explanation for the relatively coarse sediments found along parts of the axial depression. Climatological simulations of wave-driven bottom currents show that frequent high-energy events occur along the shallow margins of the Sound, explaining the occurrence of relatively coarse sediments in these regions. Bedload sediment transport calculations show that the estuarine circulation coupled with the oscillatory tidal currents result in a net westward transport of sand in much of the eastern Sound. Local departures from this regional westward trend occur around topographic and shoreline irregularities, and there is strong predicted convergence of bedload transport over most of the large, linear sand ridges in the eastern Sound, providing a mechanism which prevents their decay. The strong correlation between the near-bottom current intensity based on the model results and the sediment response, as indicated by the distribution of sedimentary environments, provides a framework for predicting the long-term effects of anthropogenic activities.
The emplacement of ophiolites by collision
Ophiolites, recognized in most of the world's orogenic belts, are generally interpreted to be oceanic crust and upper mantle (lithosphere) fragments that have been incorporated into continental margins at consuming plate boundaries. We suggest that the mechanism for ophiolite emplacement is the same in both the Alpine and Andean-type orogenes. In both geological settings, obduction of oceanic lithosphere onto the continental lithosphere is caused by the convergence of light, buoyant bodies such as oceanic plateaus, continental slivers, island arcs, or old hot spot traces. For example, the Troodos ophiolite complex, previously interpreted by some workers as resulting from continental collision, may have been emplaced by the collision of Cyprus with the Eratosthenes Plateau embedded in the oceanic eastern Mediterranean crust. On the other hand, the Upper Jurassic Coast Range Ophiolites of California, previously interpreted as resulting from typical oceanic subduction, may be the result of a continuous injection of thick nonsubductable packages of light, continentally derived sedimentary rocks, seamounts, and plateaus into the subduction zones. Many other ophiolite complexes may be similarly related to accreted terranes.
K-Ar age of the Similkameen Batholith and Kruger Alkalic Complex, Washington and British Columbia
Twelve K-Ar age determinations from the Similkameen batholith and the contiguous Kruger Alkalic Complex, including seven newly reported here, range from 69.9 m.y. to 177.2 m.y. Ages of coexisting hornblende and biotite show discordancies ranging from about 72 m.y. to 106 m.y., with hornblende consistently showing the greater analytical age. The hornblendes, with one exception, show increasing analytical age with increasing potassium content and approximately fit a 191.0-m.y. 40 Ar (radiogenic )/K isochron. The isochron shows a negative intersection with the 40 Ar (radiogenic) axis, indicating partial argon loss. The large negative deviation from the isochron of one low-potassium sample suggests that the isochron is biased to older ages. If so, the Similkameen and Kruger rocks probably crystallized between roughly 177 m.y. and 191 m.y. ago. The discordancies between hornblende and coexisting biotite are attributed to argon loss during one or possibly more episodes of thermal metamorphism, the most recent of which was probably between about 50 and 70 m.y. ago. This bracket is based on the age of apparently unmetamorphosed sedimentary deposits containing detritus from the Similkameen and Kruger bodies and the analytical age of the youngest biotite.