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At least 91 records · Page 5Linked to original sources
USGS2024

A conceptual site model of contaminant transport pathways from the Bremerton Naval Complex to Sinclair Inlet, Washington, 2011–21

Historical activities on the Bremerton Naval Complex (BNC) in Puget Sound, Washington, have resulted in Sinclair Inlet sediments with elevated concentrations of contaminants, including organic contaminants such as polychlorinated biphenyls and trace elements including mercury. Six U.S. Geological Survey–U.S. Navy datasets have been collected since the last major assessment, in 2013, of soil and groundwater contaminant transport pathways and mercury loading estimates from the BNC to Sinclair Inlet. These include: mercury isotope analysis to support sourcing of mercury in Sinclair Inlet; mercury sampling within the dry dock systems; nearshore thermal surveys to identify potential groundwater discharge locations to Sinclair Inlet; time-series monitoring in nearshore wells to understand the inland extent and dynamics of the tidal mixing zone; tidal studies of mercury in nearshore monitoring wells in an area of contaminated fill material called Site 1; and a spatial survey of trace elements and other parameters in nearshore monitoring wells, pore water, seeps, surface water, and sediment along unwalled shorelines in the western part of the BNC. The results were incorporated into an updated Conceptual Site Model and used to update contaminant load estimates from the terrestrial BNC to Sinclair Inlet. The results from these studies provide data to the U.S. Navy to support prioritization of on-going remediation actions to manage contamination on the BNC that reduce potential impacts to Sinclair Inlet sediment, surface water, and fish and shellfish tissue. Mercury isotope analysis of surface sediments and particulate material indicated that a similar industrial mercury profile is present throughout Puget Sound, including terrestrial and marine BNC samples and in other Sinclair Inlet sediments and persists across regions with low and elevated mercury concentrations. Two sources of mercury at the BNC are Sites 1 and 2 subsurface soils/fill material, with total mercury concentrations in particulates collected from the bottom of monitoring wells drilled in these materials ranging from 18,000 to 44,000 nanograms per gram (as compared to the Washington State Marine Sediment Cleanup Screening Level of 590 nanograms per gram). Contaminants are transported from the terrestrial BNC to Sinclair Inlet via three primary pathways, (1) stormwater outfalls, (2) dry dock discharges, and (3) direct discharge along unwalled shorelines. Previous loading estimates (based on filtered total mercury) ranked stormwater outfalls, particularly outfall PSNS015 in Site 2 soils, as the largest soil and groundwater contaminant transport pathway from the terrestrial BNC to Sinclair Inlet. Updated loading estimates in this report suggest that the dry dock systems may be a larger pathway of mercury from the terrestrial BNC to Sinclair Inlet than previously thought, within the same order of magnitude as the PSNS015 storm-drain system. Trace-element loads via direct shoreline discharge are difficult to estimate due to the large and dynamic tidal mixing zone of groundwater and seawater in the nearshore along unwalled shorelines. However, current best estimated ranges suggest that direct shoreline discharge is one of the three main pathways and may contribute smaller mercury loads than the stormwater and the dry dock systems. Along unwalled shorelines, direct groundwater discharge of terrestrial contaminants may be less important than recirculating seawater in the nearshore mixing zone that can extract contaminants from nearshore subsurface material. Total estimated mercury loads from the terrestrial BNC to Sinclair Inlet range from approximately 40 to 200 grams of filtered total mercury per year and a minimum of 70–350 grams of particulate total mercury per year, for a minimum total of 110–525 grams of whole (filtered plus particulate) total mercury per year. Data gaps are identified that, if filled, would further refine the Conceptual Site Model and contaminant loading estimates from the terrestrial BNC to Sinclair Inlet.

Washington↗
USGS2007

The relative merits of monitoring and domestic wells for ground water quality investigations

The results of two studies of the effect of agricultural land use on shallow ground water quality indicate that monitoring wells may be a better choice than domestic wells for studies of pesticide occurrence or transport, or for use as early-warning indicators of potential drinking water contamination. Because domestic wells represent the used resource, and because domestic well water may be affected by historical rather than current pesticide and land- use practices, domestic wells would be the best choice for an investigation of drinking water quality. The key difference between the domestic and monitoring wells appears to be that the monitoring wells in this study were installed exclusively to sample the shallowest possible ground water. For these studies, 48 shallow domestic wells and 41 monitoring wells were located randomly within two land-use settings (row crops and orchards) in an irrigated agricultural region of eastern Washington and sampled for 145 pesticides (including nine pesticide degradates) and common water quality indicators. Constructing and sampling monitoring wells required approximately four times the resources (including manpower and materials) as locating and sampling domestic wells. Sample collection and quality assurance procedures and analytical techniques were identical except that a portable submersible pump was required for monitoring wells. In both land-use settings, no significant difference in nitrate concentration was found between well types; however, the average number of pesticides detected per well was significantly higher (p<0.05) in the monitoring wells. A greater variety of pesticides was detected in monitoring wells; many were detected only in monitoring wells. More than 60% of detections of pesticides that were found only in domestic wells were of compounds that are no longer in use. These differences in ground water quality found in this study relate to the depth of the well and are apparently related to the age of ground water in the two types of wells and the greater effects of sorption, degradation, dilution, and dispersion that accompany longer groundwater residence times. The decision to invest resources in monitoring wells should be made in light of the study objective and should consider these differences in results from the two types of wells as well as the relative costs.

Ground Water Monitoring and Remediation↗
USGS2009

Flowpath independent monitoring of reductive dechlorination potential in a fractured rock aquifer

The flowpath dependent approaches that are typically employed to assess biodegradation of chloroethene contaminants in unconsolidated aquifers are problematic in fractured rock settings, due to difficulties defining discrete groundwater flowpaths in such systems. In this study, the variation in the potential for chloroethene biodegradation with depth was evaluated in a fractured rock aquifer using two flowpath independent lines of field evidence: (1) the presence of the three biochemical prerequisites [electron donor(s), chloroethene electron acceptor(s), and chlororespiring microorganism(s)] for efficient chloroethene chlororespiration and (2) the in situ accumulation of chloroethene reductive dechlorination daughter products. The validity of this approach was assessed by comparing field results with the results of [1, 2‐ 14 C] cis ‐DCE microcosm experiments. Microcosms were prepared with depth‐specific core material, which was crushed and emplaced in discrete packer intervals for 1 year to allow colonization by the indigenous microbial community. Packer intervals characterized by significant electron donor concentrations, elevated numbers of chlororespiring microorganisms, and high reductive dechlorination product to parent contaminant ratios correlated well with the production of 14 C‐labeled reductive dechlorination products in the microcosm experiments. These results indicate that, in the absence of information on discrete groundwater flowpaths, a modified approach emphasizing flowpath independent lines of evidence can provide insight into the temporal and spatial variability of contaminant biodegradation in fractured rock systems.

Ground Water Monitoring and Remediation↗
USGS2020

Assessment of water quality and fecal contamination sources at Hook Pond, East Hampton, New York

Summary The U.S. Geological Survey, in cooperation with the Village of East Hampton, New York, conducted a 1-year study from August 2017 to August 2018 to provide data necessary to improve understanding of the sources of nutrients and pathogens to Hook Pond watershed to allow for possible mitigation or reduction of loads. Chronic eutrophication and recent concern over harmful cyanobacteria in Hook Pond are the result of past and present land uses and a changing climate that have prompted the Village of East Hampton and local businesses to study and remediate factors contributing to the persistent loading of nutrients, organic contaminants, and pathogens. This assessment of Hook Pond, Hook Pond Dreen, and shallow groundwater provides the most comprehensive set of water-quality data to date. Interpretations presented in this study and the data on which they are based can be used to support management decisions, inform and contribute to modeling, and serve as a baseline for future assessments. Results from continuous monitoring of water temperature, specific conductance, and elevation at Hook Pond site 10 (Maidstone Club golf cart bridge), as well as ancillary weather and tidal data from nearby stations, were used to help explain seasonal and storm-related concentration variation of nitrogen, phosphorus, wastewater-indicator compounds, and pathogens. Data collected were also compared to existing historical data. Physicochemical constituents measured on a routine basis throughout the pond and along the tributary showed the spatial variability in water temperature, specific conductance, dissolved oxygen, pH, turbidity, and chlorophyll a and phycocyanin fluorescence. A lakebed survey was compiled based on the year-round sampling throughout the pond for future comparisons. Water-quality data from shallow groundwater at points around Hook Pond and adjacent to Hook Pond Dreen were interpreted and quantified to estimate relative contributions and species of nutrients, wastewater-indicator compounds, and microbial source tracking (MST) markers to base flow. To supplement the continuous water-surface elevation data, a single set of discharge measurements was collected under normal (nonstorm) conditions to better understand the relative contributions and dilution of surface waters by contaminated groundwater. The nutrient and physicochemical data from this study can be used in conjunction with current and future models and decision support tools to guide planned and ongoing restoration efforts, such as dredging to reduce sediment accumulation, opening a pathway to the ocean (which would change the salinity and flow dynamics of the pond and adjacent groundwater), and addressing growing concerns over cyanobacterial blooms, while serving as a baseline for measuring changes resulting from sea-level rise, climate change, and changes in nutrient loading. The microbial source tracking and indicator bacteria results can help direct efforts to reduce runoff and direct contributions of fecal contamination from dogs and waterfowl along Hook Pond Dreen. The results can also be used to assess the current state of wastewater infrastructure surrounding and contributing to Hook Pond Dreen, based on detection of human markers throughout the year and with both Bacteroides and coliphage methods.

New York↗
USGS2018

Validation of stable isotope ratio analysis to document the biodegradation and natural attenuation of RDX, ESTCP Project ER-201208

Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) is a common soil contaminant at current and former military facilities, including many training and testing ranges. Because RDX is readily transported through soils to the subsurface, this nitramine explosive now also impacts groundwater and drinking water at numerous locations across the country. A significant issue with RDX contamination on ranges and at other military installations is that it often occurs over expansive areas, where in situ or ex situ treatment technologies are difficult to implement. One potential alternative for military ranges and other facilities is monitored natural attenuation (MNA), in which contaminant degradation by natural processes, including biodegradation, are evaluated. However, one limitation of this approach for RDX is the inability to accurately evaluate whether the nitramine is biodegrading under field conditions, as rates may be relatively slow. One potential technique to overcome this limitation is the use of compound-specific stable isotope analysis (CSIA), where biological contaminant destruction can be documented as changes in the ratio of stable isotopes of specific elements in a molecule; for RDX, ratios of 15 N/ 14 N and 13 C/ 12 C are relevant. The objective of this project is to validate a CSIA method to confirm and constrain rates of aerobic and anaerobic biodegradation of RDX at field sites. This technique can be utilized by DoD to provide critical data to support MNA as a remedy for treating this energetic in groundwater, and confirm the effectiveness of in situ enhanced bioremediation remedies. The stable isotopic composition of NO 3 - and NO 2 - was also measured when these anions co-occurred with RDX to evaluate whether these potential degradation products from RDX could be used to further demonstrate MNA in the field.

Report↗
USGS2009

Paleosols in central Illinois as potential sources of ammonium in groundwater

Glacially buried paleosols of pre-Holocene age were evaluated as potential sources for anomalously large concentrations of ammonium in groundwater in East Central Illinois. Ammonium has been detected at concentrations that are problematic to water treatment facilities (greater than 2.0 mg/L) in this region. Paleosols characterized for this study were of Quaternary age, specifically Robein Silt samples. Paleosol samples displayed significant capacity to both store and release ammonium through experiments measuring processes of sorption, ion exchange, and weathering. Bacteria and fungi within paleosols may significantly facilitate the leaching of ammonium into groundwater by the processes of assimilation and mineralization. Bacterial genetic material (DNA) was successfully extracted from the Robein Silt, purified, and amplified by polymerase chain reaction to produce 16S rRNA terminal restriction fragment length polymorphism (TRFLP) community analyses. The Robein Silt was found to have established diverse and viable bacterial communities. 16S rRNA TRFLP comparisons to well-known bacterial species yielded possible matches with facultative chemolithotrophs, cellulose consumers, nitrate reducers, and actinomycetes. It was concluded that the Robein Silt is both a source and reservoir for groundwater ammonium. Therefore, the occurrence of relatively large concentrations of ammonium in groundwater monitoring data may not necessarily be an indication of only anthropogenic contamination. The results of this study, however, need to be placed in a hydrological context to better understand whether paleosols can be a significant source of ammonium to drinking water supplies. ?? 2009 National Ground Water Association.

Ground Water Monitoring and Remediation↗
USGS2014

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently dipping mudstones. Despite more than 18 years of pump and treat (P&T) remediation, and natural attenuation processes, CVOC concentrations in aqueous samples pumped from these deeper strata remain elevated in isolated intervals. DNAPL was detected in one borehole during coring at a depth of 27 m. In contrast to core samples from the weathered zone, concentrations in core samples from deeper unweathered and unfractured strata are typically below detection. However, high CVOC concentrations were found in isolated samples from fissile black carbon-rich strata and fractured gray laminated strata. Aqueous-phase concentrations were correspondingly high in samples pumped from these strata via short-interval wells or packer-isolated zones in long boreholes. A refined conceptual site model considers that prior to P&T remediation groundwater flow was primarily subhorizontal in the higher-permeability near surface strata, and the bulk of contaminant mass was shallow. CVOCs diffused into these fractured and weathered mudstones. DNAPL and high concentrations of CVOCs migrated slowly down in deeper unweathered strata, primarily along isolated dipping bedding-plane fractures. After P&T began in 1995, using wells open to both shallow and deep strata, downward transport of dissolved CVOCs accelerated. Diffusion of TCE and other CVOCs from deeper fractures penetrated only a few centimeters into the unweathered rock matrix, likely due to sorption of CVOCs on rock organic carbon. Remediation in the deep, unweathered strata may benefit from the relatively limited migration of CVOCs into the rock matrix. Synthesis of rock core sampling from closely spaced boreholes with geophysical logging and hydraulic testing improves understanding of the controls on CVOC delineation and informs remediation design and monitoring.

New Jersey, New York, Pennsylvania↗
USGS2021

Review: “Jacob’s Zoo”— How using Jacob’s method for aquifer testing leads to more intuitive understanding of aquifer characteristics

The interpretation of aquifer responses to pumping tests is an important tool for assessing aquifer geometry and properties, which are critical in the assessment of water resources or in environmental remediation. However, the responses of aquifers, measured by time-drawdown relationships in monitoring wells, are nonunique solutions that are affected by many factors. Jacob’s Zoo is a collection of graphical interpretations that allows students and practitioners to develop an intuitive feel for how natural hydrogeological systems work, and develop a set of skills that provide a better understanding of aquifer properties far beyond interpretation of pumping tests. Jacob’s Zoo, based on the work of Jacob (1950), fosters a deeper understanding, although few practitioners realize the full utility of the method. Jacob CE (1950) Flow of groundwater, In: Rouse H (ed) Engineering Hydraulics, Wiley, New York. P 321–386.

Hydrogeology Journal↗
USGS2014

11.12 - Volatile hydrocarbons and fuel oxygenates

Petroleum hydrocarbons and fuel oxygenates are among the most commonly occurring and widely distributed contaminants in the environment. This chapter presents a summary of the sources, transport, fate, and remediation of volatile fuel hydrocarbons and fuel additives in the environment. Much research has focused on the transport and transformation processes of petroleum hydrocarbons and fuel oxygenates, such as benzene, toluene, ethylbenzene, and xylenes and methyl tert‐butyl ether, in groundwater following release from underground storage tanks. Natural attenuation from biodegradation limits the movement of these contaminants and has received considerable attention as an environmental restoration option. This chapter summarizes approaches to environmental restoration, including those that rely on natural attenuation, and also engineered or enhanced remediation. Researchers are increasingly combining several microbial and molecular-based methods to give a complete picture of biodegradation potential and occurrence at contaminated field sites. New insights into the fate of petroleum hydrocarbons and fuel additives have been gained by recent advances in analytical tools and approaches, including stable isotope fractionation, analysis of metabolic intermediates, and direct microbial evidence. However, development of long-term detailed monitoring programs is required to further develop conceptual models of natural attenuation and increase our understanding of the behavior of contaminant mixtures in the subsurface.

Book chapter↗
USGS2012

Time series geophysical monitoring of permanganate injections and in situ chemical oxidation of PCE, OU1 area, Savage Superfund Site, Milford, NH, USA

In situ chemical oxidation (ISCO) treatment with sodium permanganate, an electrically conductive oxidant, provides a strong electrical signal for tracking of injectate transport using time series geophysical surveys including direct current (DC) resistivity and electromagnetic (EM) methods. Effective remediation is dependent upon placing the oxidant in close contact with the contaminated aquifer. Therefore, monitoring tools that provide enhanced tracking capability of the injectate offer considerable benefit to guide subsequent ISCO injections. Time-series geophysical surveys were performed at a superfund site in New Hampshire, USA over a one-year period to identify temporal changes in the bulk electrical conductivity of a tetrachloroethylene (PCE; also called tetrachloroethene) contaminated, glacially deposited aquifer due to the injection of sodium permanganate. The ISCO treatment involved a series of pulse injections of sodium permanganate from multiple injection wells within a contained area of the aquifer. After the initial injection, the permanganate was allowed to disperse under ambient groundwater velocities. Time series geophysical surveys identified the downward sinking and pooling of the sodium permanganate atop of the underlying till or bedrock surface caused by density-driven flow, and the limited horizontal spread of the sodium permanganate in the shallow parts of the aquifer during this injection period. When coupled with conventional monitoring, the surveys allowed for an assessment of ISCO treatment effectiveness in targeting the PCE plume and helped target areas for subsequent treatment.

New Hampshire↗
USGS2022

Understanding the evolution of groundwater-contaminant plume chemistry emanating from legacy contaminant sources: An example from a long-term crude oil spill

Understanding the evolution of plumes emanating from residual hydrocarbon contaminant sources requires evaluating how changes in source compositions over time cause changes in dissolved plume chemistry as residual sources age. This study investigates such changes at the site of a 1979 crude-oil pipeline spill and is the first comprehensive look at groundwater chemistry associated with a residual hydrocarbon source zones in different stages of aging. The data show a direct relationship between concentrations of benzene and naphthalene in the residual oil and those measured in water samples collected below the oil. Groundwater associated with oil near the spill site had different chemical composition compared with water associated with oil that had spread downgradient from the spill zone, indicating a shift in biodegradation reactions. These results emphasize that source zone processes are spatially and temporally heterogeneous and should be accounted for in natural attenuation studies where residual source zones persist.

Minnesota↗
USGS2010

Geophysical Logs, Specific Capacity, and Water Quality of Four Wells at Rogers Mechanical (former Tate Andale) Property, North Penn Area 6 Superfund Site, Lansdale, Pennsylvania, 2006-07

As part of technical assistance to the U.S. Environmental Protection Agency (USEPA) in the remediation of properties on the North Penn Area 6 Superfund Site in Lansdale, Pa., the U.S. Geological Survey (USGS) in 2006-07 collected data in four monitor wells at the Rogers Mechanical (former Tate Andale) property. During this period, USGS collected and analyzed borehole geophysical and video logs of three new monitor wells (Rogers 4, Rogers 5, and Rogers 6) ranging in depth from 80 to 180 feet, a borehole video log and additional heatpulse-flowmeter measurements (to quantify vertical borehole flow) in one existing 100-foot deep well (Rogers 3S), and water-level data during development of two wells (Rogers 5 and Rogers 6) to determine specific capacity. USGS also summarized results of passive-diffusion bag sampling for volatile organic compounds (VOCs) in the four wells. These data were intended to help understand the groundwater system and the distribution of VOC contaminants in groundwater at the property.

Open-File Report↗
USGS2009

Crude oil at the Bemidji Site: 25 years of monitoring, modeling, and understanding

The fate of hydrocarbons in the subsurface near Bemidji, Minnesota, has been investigated by a multidisciplinary group of scientists for over a quarter century. Research at Bemidji has involved extensive investigations of multiphase flow and transport, volatilization, dissolution, geochemical interactions, microbial populations, and biodegradation with the goal of providing an improved understanding of the natural processes limiting the extent of hydrocarbon contamination. A considerable volume of oil remains in the subsurface today despite 30 years of natural attenuation and 5 years of pump‐and‐skim remediation. Studies at Bemidji were among the first to document the importance of anaerobic biodegradation processes for hydrocarbon removal and remediation by natural attenuation. Spatial variability of hydraulic properties was observed to influence subsurface oil and water flow, vapor diffusion, and the progression of biodegradation. Pore‐scale capillary pressure‐saturation hysteresis and the presence of fine‐grained sediments impeded oil flow, causing entrapment and relatively large residual oil saturations. Hydrocarbon attenuation and plume extent was a function of groundwater flow, compound‐specific volatilization, dissolution and biodegradation rates, and availability of electron acceptors. Simulation of hydrocarbon fate and transport affirmed concepts developed from field observations, and provided estimates of field‐scale reaction rates and hydrocarbon mass balance. Long‐term field studies at Bemidji have illustrated that the fate of hydrocarbons evolves with time, and a snap‐shot study of a hydrocarbon plume may not provide information that is of relevance to the long‐term behavior of the plume during natural attenuation.

Minnesota↗
USGS2010

Changes in groundwater flow and volatile organic compound concentrations at the Fischer and Porter Superfund Site, Warminster Township, Bucks County, Pennsylvania, 1993-2009

The 38-acre Fischer and Porter Company Superfund Site is in Warminster Township, Bucks County, Pa. Historically, as part of the manufacturing process, trichloroethylene (TCE) degreasers were used for parts cleaning. In 1979, the Bucks County Health Department detected TCE and other volatile organic compounds (VOCs) in water from the Fischer and Porter on-site supply wells and nearby public-supply wells. The Fischer and Porter Site was designated as a Superfund Site and placed on the National Priorities List in September 1983. A 1984 Record of Decision for the site required the Fischer and Porter Company to pump and treat groundwater contaminated by VOCs from three on-site wells at a combined rate of 75 gallons per minute to contain groundwater contamination on the property. Additionally, the Record of Decision recognized the need for treatment of the water from two nearby privately owned supply wells operated by the Warminster Heights Home Ownership Association. In 2004, the Warminster Heights Home Ownership Association sold its water distribution system, and both wells were taken out of service. The report describes changes in groundwater levels and contaminant concentrations and migration caused by the shutdown of the Warminster Heights supply wells and presents a delineation of the off-site groundwater-contamination plume. The U.S. Geological Survey (USGS) conducted this study (2006-09) in cooperation with the U.S. Environmental Protection Agency (USEPA). The Fischer and Porter Site and surrounding area are underlain by sedimentary rocks of the Stockton Formation of Late Triassic age. The rocks are chiefly interbedded arkosic sandstone and siltstone. The Stockton aquifer system is comprised of a series of gently dipping lithologic units with different hydraulic properties. A three-dimensional lithostratigraphic model was developed for the site on the basis of rock cores and borehole geophysical logs. The model was simplified by combining individual lithologic units into generalized units representing upward fining sedimentary cycles capped by a siltstone bed. These cycles were labeled units 1 through 8 and are called stratigraphic units in this report. Groundwater in the unweathered zone mainly moves through a network of interconnecting secondary openings--bedding-plane fractures and joints. Groundwater generally is unconfined in the shallower part of the aquifer and confined or semiconfined in the deeper part of the aquifer. The migration of VOCs from the Fischer and Porter Site source area is influenced by geologic and hydrologic controls. The hydrologic controls have changed with time. Stratigraphic units 2 and 3 crop out beneath the former Fischer and Porter plant. VOCs originating at the plant source area entered these stratigraphic units and moved downdip to the northwest. When the wells at and in the vicinity of the site were initially sampled in 1979-80, three public-supply wells (BK-366, BK-367, MG-946) and three industrial-supply wells (BK-368, BK-370, and BK-371) were pumping. Groundwater contaminated with VOCs flowed downdip and then northeast along strike toward well BK-366, downdip toward well BK-368, and downdip and then west along strike toward well MG-946. The long axis of the TCE plume is oriented about N. 18° W. in the direction of dip. In 1979-80, the leading edge of the plume was about 3,500 feet wide. With the cessation of pumping of the supply wells in 2004, the size of the plume has decreased. In 2007-09, the plume was approximately 2,000 feet long and 2,000 feet wide at the leading edge. On the western side of the site, TCE and tetrachloroethylene (PCE) appear to be moving downdip though stratigraphic unit 3. The downdip extent of TCE and PCE migration extended approximately 550 feet off-site to the northwest and 750 feet off-site to the north. TCE concentrations in water samples from wells at the western site boundary increased from 1996 to 2007. On the northern side of the site, TCE and PCE appeared to be moving downward and laterally though stratigraphic units 2, 3, and 4. Groundwater-flow directions shifted to the northwest in the intermediate and deep zones after cessation of pumping of well BK-366 in 2004. The shutdown of the Warminster Heights wells had little effect on the direction of groundwater flow in the shallow zone. In 2007, TCE concentrations measured in water samples from the three remediation wells by the USGS ranged from less than 340 to 3,000 µg/L, and PCE concentrations ranged from less than 8.4 to 51 µg/L. TCE concentrations in water samples from the source-area remediation wells have decreased with time but remain highly variable. From 2001 to 2008, the TCE and PCE concentrations in water samples from wells BK-370 and BK-371 showed a linear decreasing trend. TCE and PCE concentrations in water samples from well BK-1324 showed an exponentially decreasing trend. In 2007, TCE concentrations measured in water samples from shallow wells ranged from less than 0.1 to 14,000 µg/L, and PCE concentrations ranged from less than 0.1 to 340 µg/L. The TCE and PCE plumes followed the hydraulic gradient in the shallow zone. In 2007, TCE concentrations measured in water samples from on-site intermediate-depth monitor wells ranged from less than 0.1 to 500 µg/L, and PCE concentrations ranged from 1.3 to 28 µg/L. The TCE and PCE plumes followed the hydraulic gradient in the intermediate zone and extended off-site to the north and northwest of the source area. Concentrations of TCE in water samples north and west of the source area increased from 1996 to 2007. In 2007, the TCE concentrations measured in water samples from on-site monitor wells in the deep zone ranged from 1.1 to 86 µg/L, and PCE concentrations ranged from less than 0.1 to 8.4 µg/L. The TCE and PCE plumes generally followed the hydraulic gradient in the deep zone and extended off-site to the northwest of the source area. In general, concentrations of TCE in water samples from monitor wells outside the source area increased between 1996 and 2005 and decreased between 2005 and 2007; concentrations were less in 2007 than in 1996.

Pennsylvania↗
USGS2021

Discharge data collection and analysis and implications for surface-water/groundwater interactions in the lower Las Vegas Wash, Clark County, Nevada, 2016–18

The lower Las Vegas Wash represents the terminal surface drainage for the Las Vegas Valley in southern Nevada. In 1997, high concentrations of perchlorate were found in seeps contributing to discharge in this area and traced to an industrial byproduct from manufacturing operations in the mid-1900s at the nearby Basic Magnesium, Incorporated, plant. The discovery prompted a water-resources investigation by the Nevada Department of Environmental Protection (NDEP) to develop an understanding of the nearby groundwater flow system and the dynamics associated with surface-water flow in the Wash. In 2016, the U.S. Geological Survey was tasked with evaluating surface-water discharge in the lower Las Vegas Wash near locations where perchlorate concentrations from the groundwater system had been detected. Results of this study will assist NDEP with identifying areas of groundwater and surface-water interaction and help guide future cleanup and monitoring efforts. Streamflow discharge is evaluated along a 4-mile section of the lower Las Vegas Wash (referred to as the Wash) and used to describe surface-water and groundwater interactions between the Wash channel and bank sediments. Continuous discharge data were collected during a 2-year period (2016–18) at 5 gaging stations along the Wash. Additionally, multiple discrete measurements between gaging stations were collected during 4 synoptic sampling events between 2016 and 2018. A diurnal discharge pattern, controlled by upstream treated wastewater releases, provided high- and low-discharge markers that are used to compute downstream time-lags of peak and minimum flows. Computed time-lags are used to establish travel times between measurement sites, and difference in upstream and time-lagged downstream hydrographs are used to compute increases (gain) or decreases (loss) in discharge between gaging stations or between gaging stations and discrete measurements. Tributary surface-water inflows to the lower Las Vegas Wash from wastewater discharge, remediation efforts, and periodic flooding from rainfall runoff are included in computing differences in discharge. Differences between discharge data from delineated reaches are used to define locations of daily, monthly, and yearly streamflow gains from or losses to adjacent bank sediments. Construction of additional channel-stabilization weirs have occurred since the completion of this study and the associated change to streamflow dynamics may limit study results to the period analyzed; however, methods and processes described in this report can be used in future evaluations.

Nevada↗
USGS2016

Groundwater science relevant to the Great Lakes Water Quality Agreement: A status report

When the Great Lakes Water Quality Agreement (GLWQA) was signed in 1972 by the Governments of Canada and the United States (the “Parties”) (Environment Canada, 2013a), groundwater was not recognized as important to the water quality of the Lakes. At that time, groundwater and surface water were still considered as two separate systems, with almost no appreciation for their interaction. When the GLWQA was revised in 1978 (US Environmental Protection Agency (USEPA), 2012), groundwater contamination, such as that reported at legacy industrial sites such as those at Love Canal near the Niagara River, was squarely in the news. Consequently, the potential impacts of contaminated groundwater from such sites on Great Lakes water quality became a concern (Beck, 1979), and Annex 16 was added to the agreement, to address “pollution from contaminated groundwater” (Francis, 1989). However, no formal process for reporting under this annex was provided. The GLWQA Protocol in 1987 modified Annex 16 and called for progress reports beginning in 1988 (USEPA, 1988). The Protocol in 2012 provided a new Annex 8 to address groundwater more holistically (Environment 2 Canada, 2013b). Annex 8 (Environment Canada, 2013b) commits the Parties to coordinate groundwater science and management actions; as a first step, to “publish a report on the relevant and available groundwater science” by February 2015 (this report); and to “identify priorities for science activities and actions for groundwater management, protection, and remediation…” The broader mandate of Annex 8 is to (1) “identify groundwater impacts on the chemical, physical and biological integrity of the Waters of the Great Lakes;” (2) “analyze contaminants, including nutrients in groundwater, derived from both point and non-point sources impacting the Waters of the Great Lakes;” (3) “assess information gaps and science needs related to groundwater to protect the quality of the Waters of the Great Lakes;” and (4) “analyze other factors, such as climate change, that individually or cumulatively affect groundwater’s impact on the quality of the Waters of the Great Lakes.” A binational Annex 8 Subcommittee was formed to lead efforts to fulfill the mandate of this annex (members listed on p. i of this report). In turn, this subcommittee has recruited a task team to prepare this report (listed as authors of each chapter). This report addresses all of the above four objectives, based on a compilation of the “relevant and available groundwater science.” Specifically, the second objective (to “analyze contaminants”) is addressed by incorporating information obtained in ongoing monitoring and research activities conducted by the Parties, and by various other members of the Great Lakes Executive Committee.

Illinois, Indiana, Michigan, Minnesota, New York, ↗
USGS2025

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter↗
USGS2016

A fractured rock geophysical toolbox method selection tool

Geophysical technologies have the potential to improve site characterization and monitoring in fractured rock, but the appropriate and effective application of geophysics at a particular site strongly depends on project goals (e.g., identifying discrete fractures) and site characteristics (e.g., lithology). No method works at every site or for every goal. New approaches are needed to identify a set of geophysical methods appropriate to specific project goals and site conditions while considering budget constraints. To this end, we present the Excel-based Fractured-Rock Geophysical Toolbox Method Selection Tool (FRGT-MST). We envision the FRGT-MST (1) equipping remediation professionals with a tool to understand what is likely to be realistic and cost-effective when contracting geophysical services, and (2) reducing applications of geophysics with unrealistic objectives or where methods are likely to fail.

Groundwater↗