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Possible Late Middle Ordovician organic carbon isotope excursion: Evidence from Ordovician oils and hydrocarbon source rocks, mid-continent and east-central United States

Oils generated by Middle Ordovician rocks are found throughout the Mid-Continent and east-central regions of the United States. Gas chromatographic characteristics of these oils include a relatively high abundance of n-alkanes with carbon numbers less than 20, a strong predominance of odd-numbered n-alkanes between C 10 and C 20 , and relatively small amounts of branched and cyclic alkanes. Saturated and aromatic hydrocarbon fractions of 43 Ordovician oils from the Anadarko, Ardmore, Forest City, Illinois, Michigan, Salina-Sedgwick, and Williston basins and the Iowa shelf demonstrate a wide range in carbon isotope composition (^dgr 13 C sat = -24.9 ^pmil to -33.9 ^pmil, (^dgr 13 C arom = -24.3 ^pmil to -33.7 ^pmil). Saturated and aromatic hydrocarbons extracted from late Middle Ordovician shales (17 core samples) show ranges in ^dgr 13 C similar to that of the oils. The wide ranges in ^dgr 13 C for oils and rock extracts reflect a major, positive excursion(s) (6-9 per ^pmil) in organic matter ^dgr 13 C in late Middle Ordovician rocks. This excursion has at least a regional significance in that it can be documented in sections 480 mi (770 km) apart in south-central Kansas and eastern Iowa. The distance may be as much as 930 mi (1,500 km) if the carbon isotope variations observed in Michigan basin Ordovician oils and in organic matter from late Middle Ordovician rocks in southwestern Ontario are related to the same carbon isotope excursion. Organic-matter ^dgr 13 C in core samples from south-central Kansas and eastern Iowa is not directly related to variations in quantity or quality of organic matter, or maceral compositi n. The positive excursion in organic matter ^dgr 13 C is a possible result of increased organic matter productivity and/or preservation. The parallel shifts in organic and carbonate ^dgr 13 C in core samples from 1 E. M. Greene well, Washington County, Iowa, imply changes in the isotope composition of the ocean-atmosphere carbon reservoir. Differences in the magnitude of the carbon isotope shifts between organic matter (8.8 ^pmil) and carbonate (4.2 ^pmil) in this core suggest a decrease, either locally or regionally, in available dissolved CO 2 , possibly a result of high organic-matter productivity and/or limited circulation in the late Middle Ordovician seas.

American Association of Petroleum Geologists Bulle

Lateral fluid flow in a compacting sand-shale sequence: South Caspian basin

The South Caspian basin contains both sands and shales that have pore-fluid pressures substantially in excess of hydrostatic fluid pressure. Pore-pressure data from the South Caspian basin demonstrate that large differences in excess hydraulic head exist between sand and shale. The data indicate that sands are acting as drains for overlying and underlying compacting shales and that fluid flows laterally through the sand on a regional scale from the basin interior northward to points of discharge. The major driving force for the fluid movement is shale compaction. We present a first- order mathematical analysis in an effort to test if the permeability of the sands required to support a regional flow system is reasonable. The results of the analysis suggest regional sand permeabilities ranging from 1 to 30 md; a range that seems reasonable. This result supports the thesis that lateral fluid flow is occurring on a regional scale within the South Caspian basin. If vertical conduits for flow exist within the basin, they are sufficiently impermeable and do not provide a major outlet for the regional flow system. The lateral fluid flow within the sands implies that the stratigraphic sequence is divided into horizontal units that are hydraulically isolated from one another, a conclusion that has important implications for oil and gas migration.-Authors

South Caspian basin

Source of anomalous magnetization in an area of hydrocarbon potential: Petrologic evidence from the Jurassic Preuss Sandstone, Wyoming-Idaho thrust belt

The Jurassic Preuss Sandstone, which crops out in the central part of the Wyoming-Idaho thrust belt on trend with a hydrocarbon-producing region to the south, has been previously identified as the source of anomalous magnetization in the area. Elsewhere, anomalous magnetization in sedimentary rocks near hydrocarbon accumulations has been attributed to hydrocarbon-engendered magnetic minerals, but magnetization of the Preuss is controlled by detrital magnetite. Evidence of a detrital origin for magnetite includes (1) concentration of magnetite grains along laminations containing other heavy minerals, (2) the presence of exsolved ilmenite, hematite, and spinel in the magnetite grains, and (3) titanium contents typical of igneous-derived magnetite. That detrital magnetite is responsible for the anomalous magnetization in the Preuss is further indicated by the systematic eastward decrease in magnetite abundance corresponding to a similar eastward decrease in magnetic susceptibility and remanent magnetization of the unit. Petrologic and vitrinite reflectance studies indicate a complex low-temperature (<150°C or 302°F) diagenetic history for the Preuss. Nevertheless, preservation of detrital magnetite, the presence of diagenetically early ferric oxide minerals, and the absence of sulfide minerals all indicate that the Preuss has not experienced sulfidic-reducing conditions common in areas of hydrocarbon seepage. The marine carbon isotopic composition of calcite that cements most Preuss sandstones (^dgr13C values ranging from -2.47 to 1.48^pmil is evidence that carbonate diagenesis also was not influenced by hydrocarbons. The results of this multidisciplinary study of the Preuss underscore the importance of similar studies when evaluating the sources of aeromagnetic anomalies in areas of hydrocarbon potential.

Idaho, Utah, Wyoming

Beyond the petroleum system: GEOHORIZONS

The first joint AAPG/AMGP (Association of Mexican Petroleum Geologists) Hedberg Conference on “Geologic Aspects of Petroleum Systems” was held October 2–6, 1994, in Mexico City, Mexico. This research conference attracted nearly 150 geoscientists from 15 countries; 41 papers and 27 posters were presented. The opposite response occurred when the petroleum-system concept was presented more than 20 yr ago; it was largely overlooked. In the past decade, however, interest in this concept as an exploration tool has been growing rapidly. The research conference addressed the concept itself, its elements and processes, the tools and methods used to identify a petroleum system, and many case studies. We summarize responses by the participants to the following three questions. First, what is gained from using the petroleum-system concept? Second, in what new directions will the petroleum-system concept take us in the future? Third, has anything new come out of this research conference?

American Association of Petroleum Geologists Bulle

Evaporite deposits of Bogota area, Cordillera Oriental, Colombia

Four evaporite-bearing stratigraphic zones are known in Cretaceous strata of the Cordillera Oriental of Colombia north and east of Bogota. The easternmost and oldest zone is probably of Berriasian to Valanginian age. The next oldest is probably late Barremian to early Aptian in age. The third appears to be Aptian. The westernmost and best known sequence in the Sabana de Bogota is Turonian to early Coniacian in age. This youngest sequence contains the thickest salt deposits known in Colombia and is probably the most widespread geographically. Most of the rock salt exposed in the three accessible mines (at Zipaquira, Nemocon, and Upin) has a characteristic lamination of alternating slightly argillaceous and highly argillaceous salt layers of varied but moderate thickness. Black, calcareous claystone, commonly very pyritic, is interbedded conformably with the laminated salt in many places throughout the deposits. Fragments of black claystone derived from the thinner interbeds are ubiquitous in all deposits, both as concordant breccia zones and as isolated clasts. Anhydrite is scarce at Zipaquira and apparently even rarer at Nemocon and Upin. Gypsum is produced at three small deposits in the oldest evaporite zone where it probably was concentrated by leaching of salt initially associated with it. The two intervening evaporite zones are not exposed, but their existence and distribution are indicated by brine springs and locally by "rute," a distinctive black, calcareous mud formed by the leaching of salt beds. Fossils show that the youngest salt-claystone zone, in the Sabana de Bogota, is contemporary with associated hematitic sandstone and siltstone, and with carbonaceous and locally coaly claystone. Although evidence is poor, this same facies relation probably exists within the other three evaporite zones. All salt deposits in this study probably are associated with anticlines, a relation best exemplified by the deposits on the Sabana de Bogota. Within these anticlines the salt deposits appear to be contained stratigraphically in fault-bound crestal, claystone cores that have not been mobilized over great vertical distances. The deposits of this study are not salt domes.

Bogota

Revised age and structural interpretations of Nuka Formation at Nuka Ridge, northwestern Alaska: Geologic notes

New collections of foraminifers and macrofossils from Nuka Ridge, the type area of the enigmatic Nuka Formation, demonstrate that the type Nuka Formation is not a continuous stratigraphic sequence as originally described. Paleontologic evidence indicates the presence of a structurally repeated sequence at Nuka Ridge consisting of Upper Mississippian (Meramec and younger) strata overlain by Permian beds which, in turn, are succeeded by Triassic(?) and Cretaceous rocks. Mississippian calcareous mudstone and limestone units are correlated with the Lisburne Group; microcline-bearing arkose units with Mississippian and Permian macrofossils and microfossils represent the Nuka Formation; units of chert are inferred to be of Permian and Triassic age; and wacke at the top of the sequence resembles unnamed wacke assigned to the Cretaceous elsewhere. These new data and their interpretations indicate that the type section of the Nuka Formation is inadequate. The standard for the Nuka Formation is therefore referred to a newly measured section of the middle arkosic unit of the old section.

Alaska

Preliminary report on geology along Atlantic continental margin of northeastern United States

The U.S. Geological Survey is conducting a geologic and geophysical study of the northeastern United States outer continental shelf and the adjacent slope from Georges Bank to Cape Hatteras. The study also includes the adjacent coastal plain because it is a more accessible extension of the shelf. The total study area is about 324,000 sq km, of which the shelf and slope constitute about 181,000 sq km and the coastal plain constitutes 143,000 sq km. The shelf width ranges from about 30 km at Cape Hatteras to about 195 km off Raritan Bay and on Georges Bank. Analyses of bottom samples make if possible to construct a preliminary geologic map of the shelf and slope to a water depth of 2,000 m. The oldest beds cropping out in the submarine canyons and on the slope are of early Late Cretaceous age. Beds of Early Cretaceous and Jurassic age are present in deep wells onshore and probably are present beneath the shelf in the area of this study. Such beds are reported beneath the Scotian shelf on the northeast where they include limestone, salt, and anhydrite. Preliminary conclusions suggest a considerably thicker Mesozoic sedimentary sequence than has been described previously. The region is large; the sedimentary wedge is thick; structures seem favorable; and the hydrocarbon potential may be considerable.

Atlantic continental margin

Structural framework of United States Atlantic outer continental shelf north of Cape Hatteras

To assess the area’s hydrocarbon potential, regional geologic and geophysical studies are being conducted by the U.S. Geological Survey to determine the structural framework of the United States Atlantic outer continental shelf (AOCS) north of Cape Hatteras. Preliminary interpretations of geophysical data suggest that the buried ridge under the eastern edge of the AOCS in the Baltimore Canyon trough area is deeper and farther west than previously suspected. Although it is not observed under the seaward extension of the Cape Fear arch, this ridge can be traced from the south side of the Baltimore Canyon trough northeastward toward the eastern edge of the Georges Bank trough. In the Baltimore Canyon trough area, the ridge seems to be fault controlled and to form the eastern edge of a Mesozoic depocenter in which approximately 12 km of relatively undisturbed post-Paleozoic sediments accumulated. Below a depth of 6 km, rocks previously considered to be crystalline basement instead may be carbonate and/or evaporite sequences of Jurassic age or older which overlie an even deeper crystalline basement. More than 8 km of sediments are present beneath the continental shelf on Georges Bank. The preliminary regional geophysical studies indicate that thick marine sedimentary sections and geologic structures favorable for the accumulation of petroleum apparently exist under the AOCS off the northeastern part of the United States.

Atlantic outer continental shelf

Stratigraphy of Atlantic coastal margin of United States north of Cape Hatteras: Brief survey

A synthesis of studies of sea-floor outcrops of the sedimentary wedge beneath the northeastern United States continental shelf and slope and a reassessment of coastal plain Mesozoic stratigraphy, particularly of the coastal margin, provide insight for estimating the oil and gas potential and provide geologic control for marine seismic investigations of the Atlantic continental margin. The oldest strata known to crop out on the continental slope are late Campanian in age. The Cretaceous-Tertiary contact along the slope ranges from a water depth of 0.6 to 1.5 km south of Georges Bank to 1.8 km in Hudson Canyon. Few samples are available from Tertiary and Late Cretaceous outcrops along the slope. Sediments of the Potomac Group, chiefly of Early Cretaceous age, constitute a major deltaic sequence in the emerged coastal plain. This thick sequence lies under coastal Virginia, Maryland, Delaware, southeastern New Jersey, and the adjacent continental shelf. Marine sands associated with this deltaic sequence may be present seaward under the outer continental shelf. South of the Norfolk arch, under coastal North Carolina, carbonate rocks interfinger with Lower Cretaceous clastic strata. From all available data, Mesozoic correlations in coastal wells between coastal Virginia and Long Island have been revised. The Upper-Lower Cretaceous boundary is placed at the transition between Albian and Cenomanian floras. Potential hydrocarbon source beds are present along the coast in the subsurface sediments of Cretaceous age. Potential reservoir sandstones are abundant in this sequence.

Atlantic coastal plain

Geologic framework of a transect of the central Brooks Range: Regional relations and an alternative to the Endicott Mountains allochthon

This paper evaluates the geologic framework and tectonic development of the central Brooks Range based on a transect through the range and Arctic foothills. A geologic cross section constructed through the transect is confirmed by comparing the retrodeformed section with the regional distribution of lithofacies in the central Brooks Range. Stratigraphic relations in the retrodeformed section are further explained by comparing them to similar stratigraphic relations in the Ikpikpuk-Umiat basin under the Arctic coastal plain. The structural framework of the central Brooks Range and Arctic foothills consists of fold nappes, thrust faults, and detached folds that sole in decollements and late-stage high-angle faults. In the central Brooks Range, shortening is by north-directed thrust faulting and folding of mostly Paleozoic rocks, and transport of any individual thrust sheet relative to underlying rocks is less than 30 km. In the middle of the range, imbricate blocks of lower Paleozoic basement are exposed in the core of the Doonerak anticline, and thrust sheets of stratigraphically higher Paleozoic rocks that overlie basement are exposed in the limbs of the anticline. In the northeast part of the anticline, the Amawk thrust emplaces Silurian and Upper Devonian rocks on a succession of Lower Mississippian an stratigraphically higher rocks that have been detached from the underlying basement along the Blarney Creek thrust. The Slatepile fault system, a system of high-angle faults in the north limb of the Doonerak anticline, drops the core and part of the north limb of the anticline down, giving the impression that the succession of Lower Mississippian and stratigraphically higher rocks that lie on basement south of the system high-angle faults extends under the Upper Devonian rocks that extensively crop out north of the high-angle faults. In the Arctic foothills, the mostly Paleozoic rocks of the north-central Brooks Range extend under Lower Cretaceous rocks of the North Slope foreland basin, and blind thrusts that sole in the Paleozoic rocks ramp up into the Lower Cretaceous and stratigraph cally higher rocks. Also in the Arctic foothills, a thrust sheet that contains the Arctic foothills assemblage overlies rocks of the north-central Brooks Range and Lower Cretaceous rocks of the North Slope foreland basin. Thrust transport of the Arctic foothills assemblage more than 40 km from south of the Doonerak anticline took place during the Early Cretaceous, but thrusting that deformed rocks of the North Slope foreland basin took place during the early Tertiary, with the vertical uplift of the Doonerak anticline being a late-formed feature. Conclusions based on the retrodeformed cross section contrast significantly with previous work in which the Upper Devonian and stratigraphically higher rocks north of the Doonerak anticline are considered part of the Endicott Mountains allochthon, a regional allochthon that extends the breadth of the Brooks Range. In these models, Upper Devonian and younger rocks in the north-central Brooks Range have been thrust-transported 90 or 200 km from south of the Doonerak anticline, and emplacement of the allochthon could reflect as much as 885 km of tectonic shortening. The Lower Mississippian and stratigraphically higher rocks together with the underlying basement in the northeast part of the anticline are considered to be in a window in the Endicott Mountains allochthon and to extend northward beneath allochthonous Upper Devonian and stratigraphically higher rocks in the north-central Brooks Range. Lithofacies patterns in rocks in the central Brooks Range are consistent with the retrodeformed cross section and imply plausible Upper Devonian and Carboniferous depositional systems. Thick Upper Devonian and Lower Mississippian(?) clastic prisms were deposited in basins north of the Doonerak anticline. Mississippian carbonate rocks that overlie these clastic prisms were deposited in differentially subsiding shelf environments that included rocks in the Doonerak anticline. Restored across the Blarney Creek thrust, the Mississippian shelf carbonate rocks that presently lie north of the Doonerak anticline are those that were deposited on basement in the anticline. A carbonate ramp at the south edge of these shelf deposits extends east-southeast across the central Brooks Range and in th retrodeformed section lies south of the Doonerak anticline where Upper and Middle(?) Devonian shaly rocks thicken to the south. Unrestored, the ramp would extend across the Doonerak anticline. Restored Late Devonian and Carboniferous lithofacies patterns in the central Brooks Range also are plausible from a regional perspective and have implications for exploration of basins under the Arctic coastal plain. The Late Devonian to Early Mississippian(?) basins in the north-central Brooks Range are part of a system of Early(?) Devonian to Early Mississippian(?) clastic basins that extend the length of the Brooks Range and include basins under the Arctic coastal plain. These basins are a template for depositional patterns in overlying rocks. Marine shelves between these basins where Mississippian strata unconformably lie on basement, such as in the northeastern Brooks Range and the Doonerak anticline, have depositional histories that are in contrast to areas that overlie the basi s. The resulting stratigraphic framework, together with the structural framework in the basement rocks that controlled the basins, has had a profound effect on the structural style of the fold belt, the salient effect being folds and thrust faults that are not orthogonal to the direction of structural transport. Stratigraphic relations exposed in the fold belt, especially the distribution of potential source rocks, likely model little-explored basins that underlie the North Slope foreland basin.

Alaska

Role of small oil and gas fields in the United States

With the maturation of oil and gas production operations in a province or country, fields found by new-field wildcats diminish in size. The actual economic size cutoff is a function of such factors as depth, water depth offshore, and accessibility to transportation infrastructure. Because of the constraint of resource availability, price is now the principal force driving drilling activity. The proportion of new-field wildcats to other exploratory wells has fallen in recent years, but success in new-field wildcats has risen to about 20%. However, only very small fields, less than 1 million BOE, are being found in large numbers. The 200 largest companies, based on lease revenues, drill 30% of all wells and 44% of the footage, and they make 83% of drilling expenditures. The 20 largest companies alone find 60% of the large fields and 20% of the small ones. Through 1979, almost 93% of known gas fields and 94.5% of known oil fields were small, yet they contain only 14.5% of the ultimately recoverable gas and 12.5% of the oil. However, small fields are less capital intensive than equivalent-capacity synthetic-fuel plants, they are extremely numerous, and they are relatively easy and inexpensive to find and put on production.

American Association of Petroleum Geologists Bulle

Lacustrine-humate model for primary uranium ore deposits, Grants uranium region, New Mexico

Two generations of uranium ore, primary and redistributed, occur in fluvial sandstones of the Upper Jurassic Morrison Formation in the San Juan basin; the two stages of ore formation can be related to the hydrologic history of the basin. Primary ore formed soon after Morrison deposition, in the Late Jurassic to Early Cretaceous, and a model, the lacustrine-humate model, is offered that views primary mineralization as a diagenetic event related to early pore fluid evolution. The basic premise is that the humate, a pore-filling organic material closely associated with primary ore, originated as humic acids dissolved in pore waters of greenish-gray lacustrine mudstones deposited in the mud-flat facies of the Brushy Basin Member and similar "K" shale beds in the Westwater Can on Member. During compaction associated with early burial, formation water expelled from lacustrine mudstone units carried these humic acids into adjacent sandstone beds where the organics precipitated, forming the humate deposits that concentrated uranium. During the Tertiary, much later in the hydrologic history of the basin, when Jurassic sediments were largely compacted, oxygenated ground water flowed basinward from uplifted basin margins. This invasion of Morrison sandstone beds by oxidizing ground waters redistributed uranium from primary ores along redox boundaries, forming ore deposits that resemble roll-front-type uranium ores.

New Mexico

Subsidence, crustal structure, and thermal evolution of Georges Bank basin

A geophysical study of Georges Bank basin defines a deep crustal structure that is interpreted in terms of the basin's tectonic and thermal history. Gravity models along three basin cross sections delineate two zones of crustal thinning at the basement hinge zone and oceanic crustal margins. These two zones bound rift-stage crust (about 25 km thick) which underlies the central portion of the basin. Subsidence analysis of the basin, using data from multichannel seismic reflection lines and two COST wells, suggests a rifting and (uniform) extensional origin. Two-dimensional finite difference modeling of the basin defines a crustal structure that concurs with the gravity and subsidence studies. The resulting isotherms show no major changes in the thermal structure since the ate Jurassic. In some areas of the basin, temperatures sufficient for oil generation are determined from maturation studies of Jurassic sediments. Hydrocarbon generation is questionable, however, because of the probable lack of proper and sufficient kerogen in the Jurassic deposits.

American Association of Petroleum Geologists Bulle

Ordovician, Silurian, and Devonian biostratigraphy of east-central Alaska

A predominantly shale and chert sequence has been mapped from the Canadian border at Latitude 65°00′ N. to the Nation River about 25 miles northwest. It has Ordovician and Silurian graptolites in the lower half, and Middle Devonian corals and Upper Devonian spores in the upper half. The lower half of the sequence consists of about 400 to 900 feet of predominantly dark gray graptolitic shale with lesser amounts of grayish black laminated chert. This unit has been traced by Green and Roddick from the international border southeastward into the Dawson area of the Yukon Territory and northeastward into the Ogilvie and Richardson Mountains where it has been mapped by Jackson & Lenz, Norris, and others as the Road River Formation. In the Tatonduk-Nation Rivers area the Road River Formation rests disconformably on a sequence of Middle and Upper Cambrian limestone that locally may include Lower Ordovician (Tremadoc) beds at its top. The sequence of graptolite faunas from the Road River Formation in Alaska is essentially the same as the graptolite zones established by Elles and Wood in Great Britain. All the standard series of the Ordovician and Silurian are probably represented in the formation with the exception of the Tremadoc and possibly the Arenig and Wenlock. Overlying the Road River Formation is a formation, 200 to 800 feet thick, consisting predominantly of thinly bedded and laminated light gray to black chert and siliceous shale that is here named the McCann Hill Chert. This new formation disconformably overlies the Road River Formation, and its lower boundary is at the base of a distinctive limestone and shale member. The basal limestone and shale member of the McCann Hill Chert contains a remarkably varied fauna including corals, brachiopods, trilobites, conodonts, ostracods, and fish of Eifelian (early Middle Devonian) age. Spores from the upper part of the formation resemble those from the overlying Nation River Formation and indicate a Late Devonian age. The McCann Hill Chert is conformably overlain by the Nation River Formation—a thick succession of inter-bedded graywacke, chert conglomerate, and silty shale of Late Devonian age. In the vicinity of Jones Ridge, only 7 miles north of exposures of the Road River Formation, Upper Cambrian limestone is overlain by a pure limestone section containing Ordovician, Middle Devonian, and perhaps Silurian shelly faunas contemporaneous with the Road River Formation and the thinner basal limestone and shale member of the McCann Hill Chert. The rapid change from graptolitic shale to limestone probably reflects changes in conditions of sedimentation, but could be a result of thrust faulting. The Tatonduk-Nation Rivers area seems to lie in a transitional zone between an early Paleozoic eugeosynclinal belt south of the Yukon River and a contemporaneous miogeosynclinal belt along the Porcupine River. One puzzling feature of the lower Paleozoic sequence in the Tatonduk-Nation Rivers area is its thinness in contrast to the much thicker volcanic and detrital sequence on the south and the considerably thicker carbonate sequence on the north.

Alaska

Empirical relation between carbonate porosity and thermal maturity: An approach to regional porosity prediction

Data indicate that porosity loss in subsurface carbonate rocks can be empirically represented by the power function, ^Thgr = a (TTI) b , where ^Thgr is regional porosity, TTI is Lopatin's time-temperature index of thermal maturity, the exponent, b, equals approximately -0.372, and the multiplier, a, is constant for a given data population but varies by an order of magnitude overall. Implications include the following. 1. The decrease of carbonate porosity by burial diagenesis is a maturation process depending exponentially on temperature and linearly on time. 2. The exponent, b, is essentially independent of the rock matrix, and may reflect rate-limiting processes of diffusive transport. 3. The multiplying coefficient, a, incorporates the net effect on porosity of all depositional and diagenetic parameters. Within constraints, carbonate-porosity prediction appears possible on a regional measurement scale as a function of thermal maturity. Estimation of carbonate porosity at the time of hydrocarbon generation, migration, or trapping also appears possible.

American Association of Petroleum Geologists Bulle

Regional magnetotelluric surveys in hydrocarbon exploration, Parana Basin, Brazil

The magnetotelluric geophysical method has been used effectively as a hydrocarbon exploration tool in the intracratonic Parana basin of South America. The Parana basin has an area of about 1,200,000 km 2 (463,000 mi 2 ), extending over portions of Brazil, Paraguay, Uruguay, Argentina, and Bolivia. The Paleozoic marine sedimentary rocks in the Parana basin are covered by the world's most extensive flood basalt complex, making geophysical exploration extremely difficult, although modern seismic techniques recently applied are achieving good results in some areas. The 1-2 km (3,300-6,600 ft) thick surface basalts and buried diabase sills pose no problem for the magnetotelluric method because the natural electromagnetic fields used as the energy source pass easily through the basalt. Data for the regional study were taken on six profiles with soundings spaced 8 to 15 km (5 to 9 mi) apart. The magnetotelluric sounding data outline a linear uplift known as the Ponta Grossa arch. This major structural feature cuts across the northeast-trending intracratonic basin almost perpendicularly, and is injected with numerous diabase dikes. Although its character is reasonably well known in the shallow, eastern parts of the basin, it is poorly delineated in the deeper parts of the basin where promising natural gas zones have been tested in several wells. In the survey area, MT interpretations show that basalts have aggregate thickness of as much as 2 km (6,600 ft), and basement may be as much as 6 km (20,000 ft) below the surface. Over most of the basin, the basalts are covered by Upper Cretaceous to Holocene continental sediments of a few hundred meters thickness and are underlain by 2 to 4 km (6,600 to 13,100 ft) thick Paleozoic sediments with possible hydrocarbon potential. The Ponta Grossa arch is interpreted to be the failed arm of a triple rift system that formed during the separation of the African and South American continents. Shales of the Devonian Ponta Grossa Formation are important Parana basin source rocks for hydrocarbons, as are several Permian units. Significant electrical contrasts occur between the Permian sediments and older units, so that magnetotelluric measurements can give an indication of the regional thickness of the Permian and younger sediments to aid in interpreting hydrocarbon migration patterns and possible trap areas.

Parana Basin

Seismic and geochemical evidence for shallow gas in sediment on Navarin continental margin, Bering Sea

Marine seismic studies coupled with geochemical investigations demonstrate that hydrocarbon gases are ubiquitous in the near-surface (<= 250 m or 820 ft depth) sediment of the Navarin continental margin in the northern Bering Sea. Three types of acoustic anomalies appear to be related to the presence of gas in the sediment. These anomalies are most prevalent in the northern half of the Navarin basin. Acoustic anomalies attributed to gas hydrates and to diagenetic boundaries are present on seismic records of the lower slope between Navarinsky and Zhemchug Canyons. Hydrocarbon gases, methane through butanes, are common in the surface (<= 5 m or 17 ft depth) sediment of the Navarin continental margin. Methane, the most abundant hydrocarbon gas, is present in amounts ranging from 84,000 to 1 µL/L of wet sediment. These concentrations are two to three orders of magnitude greater than the other hydrocarbon gases. The highest concentrations of methane (greater than 1,000 µL/L) were measured in sediment of Navarinsky Canyon and over the central part of the Navarin basin. The source of methane is mainly biogenic, but the hydrocarbon gas compositions in 17 of 141 cores suggest the presence of thermogenic gas. Most of these 17 cores are from the continental slope at water depths greater than 150 m (490 ft). No direct correlation could be found between acoustic anomalies and gas concentrations in the sediment. This lack of correlation is probably due to the limited penetration of the gravity corer and the spotty distribution of hydrocarbon concentrations.

Alaska