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USGS2003

The U.S. Geological Survey streamflow and observation-well network in Massachusetts and Rhode Island

The U.S. Geological Survey began systematic streamflow monitoring in Massachusetts nearly 100 years ago (1904) on the Connecticut River at Montague City. Since that time, hydrologic data collection has evolved into a monitoring network of 103 streamgage stations and 200 ground-water observation wells in Massachusetts and Rhode Island (2000 water year). Data from this network provide critical information for a variety of purposes to Federal, State, and local government agencies, engineering consultants, and the public. The uses of this information have been enhanced by the fact that about 70 percent of the streamgage stations and a small but increasing number of observation wells in Massachusetts and Rhode Island have been equipped with digital collection platforms that transmit data by satellite every 4 hours. Twenty-one of the telemetered streamgage stations are also equipped with precipitation recorders. The near real-time data provided by these stations, along with historical data collected at all stations, are available over the Internet at no charge. The monitoring network operated during the 2000 water year was summarized and evaluated with respect to spatial distribution, the current uses of the data, and the physical characteristics associated with the monitoring sites. This report provides maps that show locations and summary tables for active continuous record streamgage stations, discontinued streamgage stations, and observation wells in each of the 28 major basins identified by the Massachusetts Executive Office of Environmental Affairs and five of the major Rhode Island basins. Metrics of record length, regulation, physiographic region and physical and land-cover characteristics indicate that the streamflow-monitoring network represents a wide range of drainage-area sizes, physiographic regions, and basin characteristics. Most streamgage stations are affected by regulation, which provides information for specific water-management purposes, but diminishes the usefulness of these stations for many types of hydrologic analysis. Only 26 of the 103 active streamgage stations operated by the U.S. Geological Survey in Massachusetts and Rhode Island are unaffected by regulation; of these, 17 are in Massachusetts and 9 are in Rhode Island. The paucity of unregulated stations is particularly evident when the stations are grouped into five drainage-area size classes; the fact that about half of these size classes have no representative unregulated stations underscores the importance of establishing and maintaining stations that are unaffected by regulation. The observation-well network comprises 200 wells; 80 percent of these wells are finished in sand and gravel, 19 percent are finished in till, and 1 percent are finished in bedrock. About 6 percent of the wells are equipped with continuous data recorders, and about half of these are capable of transmitting data in near real time.

Open-File Report↗

USGS1996

U.S. Geological Survey federal-state cooperative water-resources program, fiscal year 1995

The Federal-State Cooperative Program is a major U.S. Geological Survey (USGS) activity for the collection, analysis, and reporting of information on the quantity, quality, and use of the Nation's water resources. The fundamental characteristic of the program is that most of the work is undertaken by the USGS through joint-funding agreements, with State, regional, and local agencies providing at least one-half the funds. The main objectives of the program are (1) to collect, on a systematic basis, data needed for the continuing determi- nation and evaluation of the quantity, quality, and use of the Nation's water resources; and (2) to appraise the availability and the physical, chemical, and biological characteristics of surface and ground water through data analysis and interpretive water-resources investigations and research. During fiscal year (FY) 1995, Cooperative Program activities were underway in offices in every State, Puerto Rico, and several territories in concert with about 1,100 cooperating agencies. In FY 1995, Federal funding of $62.1 million as matched by cooperating agencies, which also provided more than $28.2 million unmatched for a total program of about $152 million. This amounted to nearly 38 percent of the total funds for the USGS's water-resources activities. This report presents examples of FY 1995 investigations, as well as information on hydrologic data collection and water-use activities.

Open-File Report↗

USGS1995

U.S. Geological Survey Federal-State Cooperative Water-Resources Program fiscal year 1994

The Federal-State Cooperative Program is a major U.S. Geological Survey (USGS) activity for the collection, analysis, and reporting of information on the quantity, quality, and use of the Nation's water resources. The fundamental characteristic of the program is that most of the work is undertaken by the USGS through joint-funding agreements, with State, regional, and local agencies providing at least one-half the funds. The main objectives of the program are (1) to collect, on a systematic basis, data needed for the continuing determination and evaluation of the quantity, quality, and use of the Nation's water resources; and (2) to appraise the availability and the physical, chemical, and biological characteristics of surface and ground water through data analysis and interpretive water-resources investigations and research. During fiscal year (FY)1994, Cooperative Program activities were underway in offices in every State, Puerto Rico, and several territories in concert with about 1,100 cooperating agencies. In FY 1994, Federal funding of $63.5 million was matched by cooperating agencies, which also provided more than $25 million unmatched for a total program of about $152 million. This amounted to nearly 40 percent of the total funds for the USGS's water-resources activities. This report presents examples of FY 1994 investigations, as well as updated information on hydrologic data collection activities.

Open-File Report↗

USGS2003

Water Resources Data Massachusetts and Rhode Island Water Year 2002

Water resources data for the 2002 water year for Massachusetts and Rhode Island consist of records of stage, discharge, and water quality of streams; contents of lakes and reservoirs, precipitation totals, water levels of ground-water wells, and water-quality of ground water. This report contains discharge records for 98 gaging stations, stage records for 2 gaging stations, stage records for 2 ponds, month-end contents of 5 lakes and reservoirs, precipitation totals at 6 gaging stations, water quality for 27 gaging stations, water levels for 136 observation wells, and ground-water quality for 3 wells. Miscellaneous hydrologic data were collected at various sites that were not a part of the systematic data-collection program; these data are published as miscellaneous discharge measurements, miscellaneous surface-water-quality data, and miscellaneous groundwater- quality data. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating State and Federal agencies in Massachusetts and Rhode Island.

Water Data Report↗

USGS1976

Water resources data for California, water year 1975; Volume 3: Southern Central Valley Basins and The Great Basin from Walker River to Truckee River

Water-resources data for the 1975 water year for California consist of records of streamflow and contents of reservoirs at gaging stations, partial-record stations, and miscellaneous sites; records of water quality including the physical, chemical, and biological characteristics of surface and ground water; and records of water levels in selected observation wells. Records for a few pertinent streamflow and water-quality stations in bordering States are also included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of Lee R. Peterson, district chief; Winchell Smith, assistant district chief for hydrologic data; and Leonard N. Jorgensen, chief of the basic data section. These data represent that part of the National Water Data System collected by the Geological Survey and cooperating local, State, and Federal agencies in California.

California↗

USGS1977

Water resources data for California, water year 1975; Volume 4: Northern Central Valley basins and the Great Basin from Honey Lake basin to Oregon state line

California↗

USGS2011

Spring runoff water-chemistry data from the Standard Mine and Elk Creek, Gunnison County, Colorado, 2010

Water samples were collected approximately every two weeks during the spring of 2010 from the Level 1 portal of the Standard Mine and from two locations on Elk Creek. The objective of the sampling was to: (1) better define the expected range and timing of variations in pH and metal concentrations in Level 1 discharge and Elk Creek during spring runoff; and (2) further evaluate possible mechanisms controlling water quality during spring runoff. Samples were analyzed for major ions, selected trace elements, and stable isotopes of oxygen and hydrogen (oxygen-18 and deuterium). The Level 1 portal sample and one of the Elk Creek samples (EC-CELK1) were collected from the same locations as samples taken in the spring of 2007, allowing comparison between the two different years. Available meteorological and hydrologic data suggest that 2010 was an average water year and 2007 was below average. Field pH and dissolved metal concentrations in Level 1 discharge had the following ranges: pH, 2.90 to 6.23; zinc, 11.2 to 26.5 mg/L; cadmium, 0.084 to 0.158 mg/L; manganese, 3.23 to 10.2 mg/L; lead, 0.0794 to 1.71 mg/L; and copper, 0.0674 to 1.14 mg/L. These ranges were generally similar to those observed in 2007. Metal concentrations near the mouth of Elk Creek (EC-CELK1) were substantially lower than in 2007. Possible explanations include remedial efforts at the Standard Mine site implemented after 2007 and greater dilution due to higher Elk Creek flows in 2010. Temporal patterns in pH and metal concentrations in Level 1 discharge were similar to those observed in 2007, with pH, zinc, cadmium, and manganese concentrations generally decreasing, and lead and copper generally increasing during the snowmelt runoff period. Zinc and cadmium concentrations were inversely correlated with flow and thus apparently dilution-controlled. Lead and copper concentrations were inversely correlated with pH and thus apparently pH-controlled. Zinc, cadmium, and manganese concentrations near the mouth of Elk Creek did not display the pronounced increase observed during high flow in 2007, again perhaps due to remedial activities at the mine site or greater dilution in 2010. Zinc and cadmium loads near the mouth of Elk Creek were generally greater than those at the Level 1 portal for the six sample days in 2010. Whereas metal loads in September 2007 suggested that Level 1 portal discharge was the primary source of metals to the creek, metal loads computed for this study suggest that this may not have been the case in the spring of 2010. d18O values are well correlated with flow, becoming lighter (more negative) during snowmelt in both Level 1 discharge and Elk Creek. Seasonal variations in the chemistry of Level 1 discharge, along with portal flow tracking very closely with creek flow, are consistent with geochemical and environmental tracer data from 2007 that indicate short residence times (<1 year) for groundwater discharging from the Standard Mine.

Colorado↗

USGS1966

Flood of October 8, 1962, on Bachman Branch and Joes Creek at Dallas, Texas

This report presents hydrologic data that enable the user to define areas susceptible to flooding and to evaluate the flood hazard along Bachman Branch and Joes Creek. The data provide a technical basis for making sound decisions concerning the use of flood-plain lands. The report will be useful for preparing building and zoning regulations, locating waste disposal facilities, purchasing unoccupied land, developing recreational areas, and managing surface water in relation to ground-water resources. This is one of the series of reports delineating the flood hazard on streams in the Dallas area.

Texas↗

USGS1983

Highlights of the 1983 Federal-state cooperative water resources program

The U.S. Geological Survey Federal-State Cooperative Water Resources Program in fiscal year 1983 continued to concentrate on investigations of highest priority to the Nation. Hydrologic data collection and interpretive studies were underway in every State, Puerto Rico, and several U.S. territories with focus on such current concerns as ground-water contamination, floods, impacts of toxic wastes, acid precipitation, and stream quality. During the year, this 50-50 matching program was carried out in working partnership with more than 800 State, regional, and local agencies. Joint funding from all sources totaled approximately $92 million. Details of the program are mutually negotiated at the working level by representatives of the Survey and representatives of the cooperating agencies. The pooling of interests results in a balanced effort that directs combined resources to hydrologic investigations having the most significance to both parties. A few of the highlights for FY 1983, and how the program is developed with other agencies are described. (USGS)

Open-File Report↗

USGS1986

ANALYSIS OF THE U. S. GEOLOGICAL SURVEY STREAMGAGING NETWORK.

This paper summarizes the results from the first 3 years of a 5-year cost-effectiveness study of the U. S. Geological Survey streamgaging network. The objective of the study is to define and document the most cost-effective means of furnishing streamflow information. In the first step of this study, data uses were identified for 3,493 continuous-record stations currently being operated in 32 States. In the second step, evaluation of alternative methods of providing streamflow information, flow-routing models, and regression models were developed for estimating daily flows at 251 stations of the 3,493 stations analyzed. In the third step of the analysis, relationships were developed between the accuracy of the streamflow records and the operating budget. The existing streamgaging networks in four Districts were further analyzed to determine the impacts that satellite telemetry would have on the cost effectiveness. Satellite telemetry was not found to be cost effective on the basis of hydrologic-data collection alone, given present cost of equipment and operation.

Conference Paper↗

USGS2013

Groundwater hydrology and estimation of horizontal groundwater flux from the Rio Grande at selected locations in Albuquerque, New Mexico, 2003-9

The Albuquerque, New Mexico, area has two principal sources of water: groundwater from the Santa Fe Group aquifer system and surface water from the San Juan-Chama Diversion Project. From 1960 to 2002, groundwater withdrawals from the Santa Fe Group aquifer system have caused water levels to decline more than 120 feet in some places within the Albuquerque area, resulting in a great deal of interest in quantifying the river-aquifer interaction associated with the Rio Grande. In 2003, the U.S. Geological Survey in cooperation with the Bureau of Reclamation, the Middle Rio Grande Endangered Species Collaborative Program, and the U.S. Army Corps of Engineers began a detailed characterization of the hydrogeology of the Rio Grande riparian corridor in the Albuquerque, New Mexico, area to provide hydrologic data and enhance the understanding of rates of water leakage from the Rio Grande to the alluvial aquifer, groundwater flow through the aquifer, and discharge of water from the aquifer to the riverside drains. A simple conceptual model of flow indicates that the groundwater table gently slopes from the Rio Grande towards riverside drains and the outer boundaries of the inner valley. Water infiltrating from the Rio Grande initially moves vertically below the river, but, as flow spreads farther into the Rio Grande inner valley alluvial aquifer, flow becomes primarily horizontal. The slope of the water-table surface may be strongly controlled by the riverside drains and influenced by other more distal hydrologic boundary conditions, such as groundwater withdrawals by wells. Results from 35 slug tests performed in the Rio Grande inner valley alluvial aquifer during January and February 2009 indicate that hydraulic-conductivity values ranged from 5 feet per day to 160 feet per day with a median hydraulic-conductivity for all transects of 40 feet per day. Median annual horizontal hydraulic gradients in the Rio Grande inner valley alluvial aquifer ranged from 0.011 to 0.002. Groundwater fluxes through the alluvial aquifer calculated by using median slug-test results (qm slug ) and Darcy's law ranged from about 0.1 feet per day to about 0.7 feet per day. Groundwater fluxes calculated by using the Suzuki-Stallman method (qm heat ) ranged from 0.52 feet per day to 0.23 feet per day. Results from the Darcy's law and Suzuki-Stallman flux calculations were compared to discharge measured in riverside drains on both sides of the river north of the Montaño Bridge on February 26, 2009. Flow in the Corrales Riverside Drain increased by 1.4 cubic feet per second from mile 2 to mile 4, about 12 cubic feet per day per linear foot of drain. Flow in the Albuquerque Riverside Drain increased by 15 cubic feet per second between drain miles 0 and 3, about 82 cubic feet per day per linear foot of drain. The flux of water from the river to the aquifer was calculated to be 2.2 cubic feet per day per linear foot of river by using the median qm slug of 0.09 feet per day at Montaño transects west of the river. The total flux was calculated to be 6.0 cubic feet per day per linear foot of river by using the mean(qm heat of 0.24 feet per day for the Montaño transects west of the river. Assuming the Corrales Riverside Drain intercepted all of this flow, the qm slug or qm heat fluxes account for 18 to 50 percent, respectively, of the increase of flow in the drain. The flux of water from the river to the aquifer was calculated to be 15 cubic feet per day per linear foot of river by using the median qm slug of 0.30 feet per day at the Montaño transects east of the river. The flux of water from the river to the aquifer was calculated to be 17 cubic feet per day per linear foot of river by using the mean flux calculated from the Suzuki-Stallman method for the Montaño East transects of 0.34 feet per day. Assuming the Albuquerque Riverside Drain intercepted all this flow, the qm slug or (qm heat fluxes would only account for 18 to 21 percent, respectively, of the increase in flow in the drain. The comparison of these results with those of previous investigations suggests that calculated flux through the Rio Grande inner valley alluvial aquifer is strongly scale dependent and that the thickness of aquifer through which river water flows may be greater than indicated by the vertical temperature profiles.

Albuquerque, New Mexico↗

USGS1982

Digital model of the Bates Creek alluvial aquifer near Casper, Wyoming

A digital model was used to simulate ground-water flow within the Bates Creek alluvial aquifer, southwest of Casper, Wyoming. Hydrologic data collected during 1977 and 1978 were used to develop the flow model under steady-state and transient conditions. Three scenarios for operating the stream-aquifer system were evaluated with the digital model. The scenarios represent no ground-water pumping, pumping by all existing wells , and pumping by all existing and proposed wells. The model simulations used average values of stream discharge, ground-water pumpage and water use as input parameters. A decrease in the quantitity of ground-water discharge to Bates Creek is predicted to occur through 1988 as a result of pumping. The magnitude and timing of the predicted decrease in ground-water discharge may differ from actual ground-water discharge if hydrologic conditions through 1988 vary significantly from the averaged input values used in the simulations. (USGS)

Water-Resources Investigations Report↗

USGS1997

Effect of faulting on ground-water movement in the Death Valley Region, Nevada and California

This study characterizes the hydrogeologic system of the Death Valley region, an area covering approximately 100,000 square kilometers. The study also characterizes the effects of faults on ground-water movement in the Death Valley region by synthesizing crustal stress, fracture mechanics, and structural geologic data. The geologic conditions are typical of the Basin and Range Province; a variety of sedimentary and igneous intrusive and extrusive rocks have been subjected to both compressional and extensional deformation. Faulting and associated fracturing is pervasive and greatly affects ground-water flow patterns. Faults may become preferred conduits or barriers to flow depending on whether they are in relative tension, compression, or shear and other factors such as the degree of dislocations of geologic units caused by faulting, the rock types involved, the fault zone materials, and the depth below the surface. The current crustal stress field was combined with fault orientations to predict potential effects of faults on the regional groundwater flow regime. Numerous examples of faultcontrolled ground-water flow exist within the study area. Hydrologic data provided an independent method for checking some of the assumptions concerning preferential flow paths.

California, Nevada↗

USGS1986

Potential effects of surface coal mining on the hydrology of the Little Bear Creek area, Moorhead coal field, southeastern Montana

The Little Bear Creek area of the Moorhead Coal Field, 27 miles south of Ashland, Montana, contains large reserves of Federally owned coal that have been identified for potential lease sale. A hydrologic study was conducted in the area to describe existing hydrologic system and to assess potential effects of surface mining on local water resources. Hydrologic data collected from private wells, observation wells, test holes and springs indicate that the aquifers are coal and sandstone beds in the upper part of the Tongue River Member, Fort Union Formation (Paleocene age), and sand and gravel layers of valley alluvium (Pleistocene and Holocene age). Surface water is available from ephemeral flow along stretches of the main streams, and from stock ponds throughout the area. Mining the Anderson and Dietz coal beds would destroy one stock well and several stock ponds, would possibly interfere with the flow of one spring, and would lower the potentiometric surface within the coal and sandstone aquifers. The alluvial aquifer beneath Little Bear Creek and Davidson Draw would be removed at the mine site, as would sandstone and coal aquifers above the mine floor. Although mining would alter existing hydrologic systems, alternative water supplies are available. Planned structuring of the spoils and reconstruction of the alluvial aquifers could minimize downstream water-quality degradation. (USGS)

Water-Resources Investigations Report↗

USGS1987

Analysis of the U.S. Geological Survey streamgaging network

This paper summarizes the results from the first 3 years of a 5-year cost-effectiveness study of the U.S. Geological Survey streamgaging network. The objective of the study is to define and document the most cost-effective means of furnishing streamflow information. In the first step of this study, data uses were identified for 3,493 continuous-record stations currently being operated in 32 States. In the second step, evaluation of alternative methods of providing streamflow information, flow-routing models, and regression models were developed for estimating daily flows at 251 stations of the 3,493 stations analyzed. In the third step of the analysis, relationships were developed between the accuracy of the streamflow records and the operating budget. The weighted standard error for all stations, with current operating procedures, was 19.9 percent. By altering field activities, as determined by the analyses, this could be reduced to 17.8 percent. The existing streamgaging networks in four Districts were further analyzed to determine the impacts that satellite telemetry would have on the cost effectiveness. Satellite telemetry was not found to be cost effective on the basis of hydrologic data collection alone, given present cost of equipment and operation.

Water Science and Technology↗

USGS1985

Potential effects of surface coal mining on the hydrology of the Horse Creek area, Sheridan and Moorhead coal fields, southeastern Montana

The Horse Creek area of the Sheridan and Moorhead coal fields, 16 miles east of the Decker Coal Mines near the Tongue River, contains large reserves of Federally owned coal that have been identified for potential lease sale. A hydrologic study was conducted in the area to describe existing hydrologic systems and to assess potential impacts of surface coal mining on local water resources. Hydrologic data collected from private wells, observation wells, test holes, and springs indicate that the aquifers are primarily coal and sandstone beds in the upper part of the Tongue River Member of the Fort Union Formation (Paleocene age) and sand and gravel of valley alluvium (Pleistocene and Holocene age). Surface-water resources are mostly limited to a few stock ponds receiving discharge from springs in the higher ports of the area. Two stock wells, one spring, and three stock ponds receiving discharge from springs supply most of the water used within the Horse Creek basin; the only use is watering of livestock. Mining of the Anderson and Dietz coal beds would destroy one stock well and two ponds receiving discharge from springs, and would lower the potentiometric surface within the coal and sandstone aquifers. Although mining would alter existing hydrologic systems, alternative deeper water supplies are available. (USGS)

Montana↗

USGS1993

Numerical simulation of ground-water flow in the central part of the western San Joaquin Valley, California

The occurrence of selenium in agricultural drain water in the central part of the western San Joaquin Valley, California, has focused concern on strategies for managing shallow, saline ground water. To assess alternatives to agricultural drains, a three-dimensional, finite-difference numerical model of the regional groundwater flow system was developed. This report documents the mathematical approach used to model the flow system, the data base on which the model is based, and the methods used to calibrate the model. The 550-square-mile study area includes parts of the Panoche Creek alluvial fan and parts of the Little Panoche Creek and Cantua Creek alluvial fans. The model simulates transient flow in the semiconfined and confined zones above and below the Corcoran Clay Member of the Tulare Formation of Pleistocene age. The model incorporates areally distributed ground-water recharge, areally and vertically distributed pumping, regional-collector drains in the Wesdands Water District (operative from 1980 to 1985), on-farm drains in parts of the Panoche, Broadview, and Firebaugh Water Districts, and bare-soil evaporation (which occurs if the water table is within 7 feet of land surface). The model also incorporates texture-based estimates of hydraulic conductivity, where texture is defined as the fraction of coarse-grained deposits present in a given subsurface interval. The numerical model was developed using hydrologic data from 1972 to 1988. Most of the parameters incorporated into the model were evaluated independently of the model, including system geometry, the distribution of texture, the altitudes of the water table and potentiometric surface of the confined zone in 1972 (initial condition), the hydraulic conductivity of coarse-grained deposits derived from the Coast Ranges, the hydraulic conductivity of coarse-grained deposits derived from the Sierra Nevada, specific storage, recharge, pumping, and parameters needed to incorporate drains and bare-soil evaporation. Four parameters were calibration variables: the hydraulic conductivity of fine-grained deposits in the semiconfined zone, the hydraulic conductivity of the Corcoran Clay Member, specific yield, and the transmissivity of the confined zone. The model was calibrated in two phases. In the first phase, a steady-state model of the ground-water flow system in 1984 was used to constrain the relation between the hydraulic conductivity of fine-grained deposits in the semiconfined zone and the hydraulic conductivity of the Corcoran Clay Member, thus reducing the number of independent variables from four to three. In the second phase of calibration, the change in altitude of the water table from 1972 to 1984, the change in altitude of the potentiometric surface of the confined zone from 1972 to 1984, and the number of model cells subject to bare-soil evaporation from 1972 to 1988 were used to evaluate the remaining three variables. The calibrated model reproduces the average change in water-table altitude (1972-84) to within 0.4 foot (average measured change 11.5 feet) and the average change in confined zone head (1972- 84) to within 19 feet (average measured change 120 feet). The simulated time-series record of the total number of model cells subject to bare-soil evaporation (each cell is 1 mile square) is within the range of the measured data. The measured values are at a minimum in October and a maximum in July. The October values ranged from 103 in 1972 to 132 in 1984 (the drains were closed in 1985) to 151 in 1988. The July values ranged from 144 in 1973 to 198 in 1984, to 204 in 1988. The simulated values ranged from 103 in 1972 to 161 in 1984, to 208 in 1988.

Water Supply Paper↗

USGS2010

The geochemistry of the Fox Hills-Basal Hell Creek Aquifer in southwestern North Dakota and northwestern South Dakota

The Late Cretaceous Fox Hills Formation and the basal portion of the overlying Hell Creek Formation constitute an important aquifer in the Fort Union coal region. Throughout most of southwestern North Dakota and northwestern South Dakota the aquifer is at depths ranging from 1000 to 2000 ft, except for exposures along the Cedar Creek anticline. Water flows in the aquifer from southwest to northeast, with flow rates of a few feet per year. The recharge and discharge areas of the aquifer are separated by a north-south trending transition zone in which significant changes in water chemistry occur. Dissolved constituents in the recharge area (the western part of the study area) are Na + = 18 mmol/l, Cl − = 0.7 mmol/1, SO 4 2− = 2.7 mmol/1, and HCO 3 − = 13 mmol/l (δ 13 C = −12‰) with p H = 8.5. Ca 2+ , Mg 2+ , and K + are each less than 0.1 mmol/l, dissolved O 2 = 0, and traces of H 2 S and CH 4 are present. Computer modeling and carbon isotope data suggest the following reactions in the recharge area. CO 2 derived from lignitic carbon reacts to dissolve carbonate minerals, with cations then being exchanged for Na + on clay minerals. The high p H in the aquifer is the result of buffering by carbonate-ion exchange equilibria. In the discharge area, p H values have declined to 8.3, Cl − has increased from 0.7 to 5.5 mmol/l, with a parallel increase in Na + SO 4 2− has essentially disappeared, HCO 3 − has increased from 13 to 21 mmol/l (δ 13 C = −9‰), CH 4 has attained concentrations greater than 0.5 mmol/l, and small amounts of He are present. Traces of H 2 S are present, and Ca 2+ , Mg 2+ , and K + concentrations remain low throughout the aquifer: These changes can be accounted for by reactions in the aquifer: (1) sulfate reduction to pyrite with lignitic material as the carbon source and (2) continuous buffering of p H by the carbonate-ion exchange equilibria. Chemical and hydrologic data suggest that the increase in NaCl results from upward movement of small volumes of water into the Fox Hills aquifer from the transition zone eastward. Redox reactions in the aquifer are closely analogous to those observed in pore waters of reducing marine sediments. Reactions approach but do not achieve true thermodynamic equilibrium. Measurements of redox potential suggest a downgradient decrease in redox potential. The measurements are not amenable to quantitative interpretation.

Water Resources Research↗