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At least 883 records · Page 49Linked to original sources

Determination of human-health pharmaceuticals in filtered water by chemically modified styrene-divinylbenzene resin-based solid-phase extraction and high-performance liquid chromatography/Mass Spectrometry

In 1999, the Methods Research and Development Program of the U.S. Geological Survey National Water Quality Laboratory began the process of developing a method designed to identify and quantify human-health pharmaceuticals in four filtered water-sample types: reagent water, ground water, surface water minimally affected by human contributions, and surface water that contains a substantial fraction of treated wastewater. Compounds derived from human pharmaceutical and personal-care product use, which enter the environment through wastewater discharge, are a newly emerging area of concern; this method was intended to fulfill the need for a highly sensitive and highly selective means to identify and quantify 14 commonly used human pharmaceuticals in filtered-water samples. The concentrations of 12 pharmaceuticals are reported without qualification; the concentrations of two pharmaceuticals are reported as estimates because long-term reagent-spike sample recoveries fall below acceptance criteria for reporting concentrations without qualification. The method uses a chemically modified styrene-divinylbenzene resin-based solid-phase extraction (SPE) cartridge for analyte isolation and concentration. For analyte detection and quantitation, an instrumental method was developed that used a high-performance liquid chromatography/mass spectrometry (HPLC/MS) system to separate the pharmaceuticals of interest from each other and coextracted material. Immediately following separation, the pharmaceuticals are ionized by electrospray ionization operated in the positive mode, and the positive ions produced are detected, identified, and quantified using a quadrupole mass spectrometer. In this method, 1-liter water samples are first filtered, either in the field or in the laboratory, using a 0.7-micrometer (μm) nominal pore size glass-fiber filter to remove suspended solids. The filtered samples then are passed through cleaned and conditioned SPE cartridges at a rate of about 15 milliliters per minute. Excess water is eliminated from the cartridge sorbent bed by passing air through the cartridges, and the analytes retained on the SPE bed are eluted from the cartridge sequentially, first with methanol, followed by acidified methanol, and combined in collection tubes. This sample extract then is reduced from about 10 milliliters (mL) to about 0.1 mL (or 100 microliters) under a stream of purified nitrogen gas with the collection tubes in a heated (40°C) water bath. The reduced extracts then are fortified with an internal standard solution (when using internal standard quantitation), brought to a final volume of 1 mL with an aqueous ammonium formate buffer solution, and filtered through a 0.2-μm Teflon syringe filter as they are transferred into vials for instrumental analysis. Instrumental analysis by the HPLC/MS procedure permits determination of individual pharmaceutical concentrations from 0.005 to 1.0 microgram per liter, based on the lowest and the highest calibration standards routinely used. The reporting levels for this method are compound dependent, and have been experimentally determined based on the precision of quantitation of compounds from eight fortified organic-free water samples in single-operator experiments. The method detection limits and interim reporting levels for the compounds determined by this method were calculated from recoveries of the pharmaceuticals from reagent-water samples amended at 0.05 microgram per liter, and ranged between 0.0069 and 0.0142 microgram per liter, and 0.015 and 0.10 microgram per liter, respectively. Concentrations for 12 compounds are reported without qualification, and for two compounds are reported as qualified estimates. After initial development, the method was applied to more than 1,800 surface-, ground-, and wastewater samples from 2002 to 2005 and documented in a number of published studies. This research application of the method provided the opportunity to collect a large data set of ambient environmental concentrations and also permitted the collection of an extensive set of reagent blanks and spike quality-control (QC) samples. This multiple-year set of QC samples enabled further evaluation of method performance under multiple operator and multiple instrument conditions typical of routine laboratory operation. These results are an important part of the entire data set contained in this report because they document method performance over an extended time. Because sample matrix can substantially affect method performance, inclusion of environmental matrix-spike samples is required as a routine component of study plan quality control. Method performance has been measured by long-term tracking of observed recoveries from fortified organic-free water samples processed with environmental samples (laboratory reagent spikes), as well as by observed recoveries from multiple fortified environmental water samples. The fortified environmental samples included surface water, wastewater effluent-dominated surface water, and ground water, fortified at two environmentally relevant concentrations and corrected for ambient environmental concentrations. Because the responses of individual pharmaceuticals vary as a function of proton affinity, the ionization efficiency, and thus relative response, of each pharmaceutical, the quality-control surrogate compounds, and the quantitation internal standard can be suppressed or enhanced by the presence of the sample matrix. As a result, several quality-control sample types are required to properly interpret the ambient environmental concentrations of pharmaceuticals in aqueous samples. The quality-control sample types and results include laboratory reagent spikes and laboratory reagent blanks to provide insight into the performance of the method in the absence of a sample matrix, and matrix-spike recovery samples and replicate environmental samples, collected from representative sample matrix types within the aquatic system under study.

Techniques and Methods↗

Final project memorandum: sea-level rise modeling handbook: resource guide for resource managers, engineers, and scientists

Coastal wetlands of the Southeastern United States are undergoing retreat and migration from increasing tidal inundation and saltwater intrusion attributed to climate variability and sea-level rise. Much of the literature describing potential sea-level rise projections and modeling predictions are found in peer-reviewed academic journals or government technical reports largely suited to reading by other Ph.D. scientists who are more familiar or engaged in the climate change debate. Various sea-level rise and coastal wetland models have been developed and applied of different designs and scales of spatial and temporal complexity for predicting habitat and environmental change that have not heretofore been synthesized to aid natural resource managers of their utility and limitations. Training sessions were conducted with Federal land managers with U.S. Fish and Wildlife Service, National Park Service, and NOAA National Estuarine Research Reserves as well as state partners and nongovernmental organizations across the northern Gulf Coast from Florida to Texas to educate and to evaluate user needs and understanding of concepts, data, and modeling tools for projecting sea-level rise and its impact on coastal habitats and wildlife. As a result, this handbook was constructed from these training and feedback sessions with coastal managers and biologists of published decision-support tools and simulation models for sea-level rise and climate change assessments. A simplified tabular context was developed listing the various kinds of decision-support tools and ecological models along with criteria to distinguish the source, scale, and quality of information input and geographic data sets, physical and biological constraints and relationships, datum characteristics of water and land elevation components, utility options for setting sea-level rise and climate change scenarios, and ease or difficulty of storing, displaying, or interpreting model output. The handbook is designed to be a primer to understanding sea-level rise and a practical synthesis of the current state of knowledge and modeling tools as a resource guide for DOl land management needs and facilitating Landscape Conservation Cooperative (LCC) research and conservation initiatives.

Conference Paper↗

Flow modification in the Nation’s streams and rivers

This report summarizes a national assessment of flowing waters conducted by the U.S. Geological Survey’s (USGS) National Water-Quality Assessment (NAWQA) Project and addresses several pressing questions about the modification of natural flows in streams and rivers. The assessment is based on the integration, modeling, and synthesis of monitoring data collected by the USGS and the U.S. Environmental Protection Agency at more than 7,000 streams and rivers across the conterminous United States from 1980 to 2014. Key findings include the following. First, flow in many of the Nation’s streams and rivers is different from what it would be under natural conditions. In particular, low flows are more frequent, are of shorter duration, and vary less from one year to the next than they would naturally. In addition, high flows have been reduced in magnitude, are of shorter duration, are less frequent, and vary less from one year to the next than they would naturally. Other characteristics of natural flows also have been modified. Second, over the last 60 years (1955–2014), climatic trends have caused a change of 50 percent or more in one or more streamflow attributes at two-thirds of climate-sensitive streamgaging sites. However, these climate-induced changes have been less influential on streamflow modification than have land and water-management practices. Third, in every region assessed, streamflow modification was associated with reduced ecological health, as indicated by two biological communities—invertebrates and fish. Biological communities were increasingly likely to be impaired (defined as having lost a statistically significant number of species) in streams with flows most different from natural conditions. Finally, several case studies are presented that illustrate viable management strategies for balancing the water needs of people and ecosystems.

Circular↗

Hydrography of and biogeochemical inputs to Liberty Bay, a small urban embayment in Puget Sound, Washington

This multi-chapter report describes scientific and logistic understanding gained from a 2 year proof-of-concept study in Liberty Bay, a small urban embayment in central Puget Sound, Washington. The introductory chapter describes the regional and local setting, the high-level study goals, the site-specific urban stressors, and the interdisciplinary study approach. Subsequent data chapters describe detailed studies of various components of the Liberty Bay ecosystem: the aquatic environment (Chapter 2), surface and groundwater quantity and quality (Chapter 3), sediment quality (Chapter 4), eelgrass habitat (Chapter 5), carbon and nitrogen sources (Chapter 6), and a statistical model relating herring spawn probability to shoreline attributes (Chapter 7). The final chapter synthesizes knowledge about individual components into a system-wide understanding of how urbanization may affect the Liberty Bay ecosystem. The Liberty Bay study was conducted as part of the U.S. Geological Survey's Coastal Habitats in Puget Sound project, an interdisciplinary collaboration to understand physical and biological processes that affect nearshore ecosystems.

Scientific Investigations Report↗

Preliminary water-use estimates in the United States in 1985

Preliminary 1985 water use estimates are tabulated by State for the Und States, Puerto Rico, the Virgin Islands, and the District of Columbia. Preliminary estimates of water withdrawn from surface water and groundwater sources for offstream water use categories are presented prior to publication of the final estimates in a U.S. Geological Survey Circular to allow for the timely release of the estimates to the general public. (Author 's abstract)

Open-File Report↗

Quantifying components of the hydrologic cycle in Virginia using chemical hydrograph separation and multiple regression analysis

This study by the U.S. Geological Survey, prepared in cooperation with the Virginia Department of Environmental Quality, quantifies the components of the hydrologic cycle across the Commonwealth of Virginia. Long-term, mean fluxes were calculated for precipitation, surface runoff, infiltration, total evapotranspiration (ET), riparian ET, recharge, base flow (or groundwater discharge) and net total outflow. Fluxes of these components were first estimated on a number of real-time-gaged watersheds across Virginia. Specific conductance was used to distinguish and separate surface runoff from base flow. Specific-conductance data were collected every 15 minutes at 75 real-time gages for approximately 18 months between March 2007 and August 2008. Precipitation was estimated for 1971–2000 using PRISM climate data. Precipitation and temperature from the PRISM data were used to develop a regression-based relation to estimate total ET. The proportion of watershed precipitation that becomes surface runoff was related to physiographic province and rock type in a runoff regression equation. Component flux estimates from the watersheds were transferred to flux estimates for counties and independent cities using the ET and runoff regression equations. Only 48 of the 75 watersheds yielded sufficient data, and data from these 48 were used in the final runoff regression equation. The base-flow proportion for the 48 watersheds averaged 72 percent using specific conductance, a value that was substantially higher than the 61 percent average calculated using a graphical-separation technique (the USGS program PART). Final results for the study are presented as component flux estimates for all counties and independent cities in Virginia.

Virginia↗

Estimating monthly, annual, and low 7-day, 10-year streamflows for ungaged rivers in Maine

Regression equations to estimate monthly, annual, and low 7-day, 10-year (7Q10) streamflows were derived for rivers in Maine. The derived regression equations for estimating mean monthly, mean annual, median monthly, median annual, and low 7Q10 streamflows for ungaged rivers in Maine presented in this report supersede those derived in previous studies. Twenty-six U.S. Geological Survey streamflow-gaging stations on unregulated, rural rivers in Maine with 10 years or more of recorded streamflow were used to develop the regression equations. Ordinary least squares (OLS) regression techniques were used to select the explanatory variables (basin and climatic characteristics) that would appear in the final regression equations. OLS regression of all possible subsets was done with 62 explanatory variables for each of 27 response variables. Five explanatory variables were chosen for the final regression equations: drainage basin area, areal fraction of the drainage basin underlain by sand and gravel aquifers, distance from the coast to the drainage basin centroid, mean drainage basin annual precipitation, and mean drainage basin winter precipitation (the sum of mean monthly precipitation for December, January, and February). Generalized least-squares regression techniques were used to derive the final coefficients and measures of uncertainty for the regression equations. The forms of many of the derived regression equations indicate some physical, mechanistic processes. Drainage basin area is the most statistically important explanatory variable and appears in all derived regression equations. Monthly streamflows are related inversely to the distance from the coast to the drainage basin centroid during December, January, February, and March; that is, the closer a river basin is to the coast, the higher monthly streamflows are per unit drainage basin area during the winter. The relation reverses in May when higher streamflows are attributed to basins farther from the coast. These relations are consistent with colder, inland drainage basins storing more water in snowpack during the winter and releasing it in the spring. The monthly streamflows (and low 7Q10) during July, August, September, and October are related positively to areal fraction of the drainage basin underlain by sand and gravel aquifers. In general, sand and gravel aquifers underlying Maine river basins have excellent water-yielding characteristics and can provide water to streams during low-flow conditions in the summer and early fall.

Maine↗

A natural resource condition assessment for Sequoia and Kings Canyon National Parks: Appendix 11a: giant sequoias

For natural resource managers in the southern Sierra Nevada, giant sequoia requires very little introduction. It receives great attention as an icon of western forests and as a common namesake with the areas where it occurs. While it is a single component of a very complex system, its attention in this assessment and in general is well deserved. Giant sequoia is one of the few "destination species" that attracts a wide swath of the public by nature of it simply being present. It draws people, who otherwise may not travel, to a natural environment. The result is an expansion of the public’s sense of natural resource stewardship. Because park managers could not achieve their mission without public support, this fostering role of giant sequoia is critical for park natural resources and is important for natural resources in general. Despite its social relevance and physical size, we re-emphasize here that the giant sequoia resource is a relatively small component of the ecosystems of the southern Sierra Nevada. As is the case with all of the resources assessed in the NRCA, we focus on giant sequoia with the understanding that other resources will be considered simultaneously when evaluating management decisions that impact giant sequoia. While we attempt to explicitly address the interaction of giant sequoia with other resources and stressors, we also realize that ultimately managers will integrate much more information than is presented here when making decisions that influence giant sequoia. The autecology and management issues surrounding giant sequoia have been thoroughly reviewed elsewhere (Harvey et al. 1980, Aune 1994, Stephenson 1996). Stephenson (1996), in particular, should be reviewed when considering any management decisions that potentially impact giant sequoia. For those who may not be familiar with giant sequoia ecology, a summary of basic information is provided in a table below. In some parts of this assessment, we reproduce text from Stephenson’s review because it is still relatively current for addressing some of the stressors. Numerous recent studies reported since 1996 have confirmed and expanded the understanding of giant sequoia, especially in areas related to ecophysiology and the effectiveness of restoration treatments. These recent studies are integrated into this assessment. Additionally, much unpublished work has been done that is useful for establishing baselines and evaluating trends. This work is presented in detail in order to expand upon previous work and to inform the final assessments. Instead of providing an introductory description of giant sequoia distribution and the various landowners who manage groves, we refer readers to the more recent descriptions provided by Stephenson (1996) and Willard (2000). Some of the relevant points from these descriptions with respect to giant sequoia within SEKI and Giant Sequoia National Monument (GSNM) include: - Of the native giant sequoia grove area in SEKI and GSNM approximately 38% is within SEKI and 62% is within GSNM. - 35 of the groves that make up the entire population are all or partially managed by SEKI and 33 are managed by GSNM. - As we have done above, reviewers addressing giant sequoia widely recognize its transcendence beyond an ecologically important species to one with considerable added cultural value.

California↗

Analysis of local slopes at the InSight landing site on Mars

To evaluate the topography of the surface within the InSight candidate landing ellipses, we generated Digital Terrain Models (DTMs) at lander scales and those appropriate for entry, descent, and landing simulations, along with orthoimages of both images in each stereopair, and adirectional slope images. These products were used to assess the distribution of slopes for each candidate ellipse and terrain type in the landing site region, paying particular attention to how these slopes impact InSight landing and engineering safety, and results are reported here. Overall, this region has extremely low slopes at 1-meter baseline scales and meets the safety constraints of the InSight lander. The majority of the landing ellipse has a mean slope at 1-meter baselines of 3.2°. In addition, a mosaic of HRSC, CTX, and HiRISE DTMs within the final landing ellipse (ellipse 9) was generated to support entry, descent, and landing simulations and evaluations. Several methods were tested to generate this mosaic and the NASA Ames Stereo Pipeline program dem_mosaic produced the best results. For the HRSC-CTX-HiRISE DTM mosaic, more than 99 % of the mosaic has slopes less than 15°, and the introduction of artificially high slopes along image seams was minimized.

Space Science Reviews↗

An isotope-dilution standard GC/MS/MS method for steroid hormones in water

An isotope-dilution quantification method was developed for 20 natural and synthetic steroid hormones and additional compounds in filtered and unfiltered water. Deuterium- or carbon-13-labeled isotope-dilution standards (IDSs) are added to the water sample, which is passed through an octadecylsilyl solid-phase extraction (SPE) disk. Following extract cleanup using Florisil SPE, method compounds are converted to trimethylsilyl derivatives and analyzed by gas chromatography with tandem mass spectrometry. Validation matrices included reagent water, wastewater-affected surface water, and primary (no biological treatment) and secondary wastewater effluent. Overall method recovery for all analytes in these matrices averaged 100%; with overall relative standard deviation of 28%. Mean recoveries of the 20 individual analytes for spiked reagent-water samples prepared along with field samples analyzed in 2009–2010 ranged from 84–104%, with relative standard deviations of 6–36%. Detection levels estimated using ASTM International’s D6091–07 procedure range from 0.4 to 4 ng/L for 17 analytes. Higher censoring levels of 100 ng/L for bisphenol A and 200 ng/L for cholesterol and 3-beta-coprostanol are used to prevent bias and false positives associated with the presence of these analytes in blanks. Absolute method recoveries of the IDSs provide sample-specific performance information and guide data reporting. Careful selection of labeled compounds for use as IDSs is important because both inexact IDS-analyte matches and deuterium label loss affect an IDS’s ability to emulate analyte performance. Six IDS compounds initially tested and applied in this method exhibited deuterium loss and are not used in the final method.

Book chapter↗

The influence of subcolony-scale nesting habitat on the reproductive success of Adélie penguins

Group-size variation is common in colonially breeding species, including seabirds, whose breeding colonies can vary in size by several orders of magnitude. Seabirds are some of the most threatened marine taxa and understanding the drivers of colony size variation is more important than ever. Reproductive success is an important demographic parameter that can impact colony size, and it varies in association with a number of factors, including nesting habitat quality. Within colonies, seabirds often aggregate into distinct groups or subcolonies that may vary in quality. We used data from two colonies of Adélie penguins 73 km apart on Ross Island, Antarctica, one large and one small to investigate (1) How subcolony habitat characteristics influence reproductive success and (2) How these relationships differ at a small (Cape Royds) and large (Cape Crozier) colony with different terrain characteristics. Subcolonies were characterized using terrain attributes (elevation, slope aspect, slope steepness, wind shelter, flow accumulation), as well group characteristics (area/size, perimeter-to-area ratio, and proximity to nest predators). Reproductive success was higher and less variable at the larger colony while subcolony characteristics explained more of the variance in reproductive success at the small colony. The most important variable influencing subcolony quality at both colonies was perimeter-to-area ratio, likely reflecting the importance of nest predation by south polar skuas along subcolony edges. The small colony contained a higher proportion of edge nests thus higher potential impact from skua nest predation. Stochastic environmental events may facilitate smaller colonies becoming “trapped” by nest predation: a rapid decline in the number of breeding individuals may increase the proportion of edge nests, leading to higher relative nest predation and hindering population recovery. Several terrain covariates were retained in the final models but which variables, the shapes of the relationships, and importance varied between colonies.

Scientific Reports↗

Range-wide population trend analysis for greater sage-grouse (Centrocercus urophasianus)—Updated 1960–2022

Greater sage-grouse ( Centrocercus urophasianus ) are at the center of state and national land-use policies largely because of their unique life-history traits as an ecological indicator for health of sagebrush ecosystems. This updated population trend analysis provides state and federal land and wildlife managers with best-available science to help guide current management and conservation plans aimed at benefitting sage-grouse populations. This analysis relied on previously published population trend modeling methodology from Coates and others (2021, 2022a) and incorporated population lek count data through 2022. Bayesian state-space models estimated 2.9 percent average annual decline in sage-grouse populations across their geographical range, which varied among subpopulations at the largest scale of analysis, termed climate clusters (2.2–4.7). Cumulative declines were 40.9, 65.0, and 79.6 percent range-wide across short (19 years), medium (35 years), and long (55 years) temporal periods, respectively. These results indicate that the most recent nadir for range-wide populations occurred during 2021. However, growth during 2022 was modest, making 2021 a tentative final nadir at this point.

Data Report↗

Geologic maps of the Sacramento-San Joaquin Delta, California

The Sacramento-San Joaquin Delta, the arm of the San Francisco Bay estuary that reaches into the Central Valley of California, differs from typical coastal-plain deltas in three important respects. First, rather than meeting the ocean individually and directly, all major waterways of this delta discharge via a single constricted outlet into a chain of estuarine bays and straits. Second, in the most common vertical sequence of deposits, peat and mud deposited in tidal marshes and swamps (tidal wetlands) directly overlie alluvium or eolian sand, a sequence recording a landward spread of tidal environments rather than the seaward migration of fluvial environments that is typical of coastal-plain deltas (Cosby, 1941, p. 43; Thompson, 1957, p. 12; Shlemon and Begg, 1975, p. 259; Atwater and Belknap, 1980). Finally, intensive human use has led to a peculiar set of conflicts involving rights to water and responsibilities for flood-control levees (Kockelman and other, 1982).

California↗

Geologic setting of the Mountain Pass rare earth deposits, San Bernardino County, California

The Mountain Pass district is in a block of pre-Cambrian metamorphic rocks bounded on the east and south by the alluvium of Ivanpah Valley. This block is separated from Paleozoic and Mesozoic sedimentary and volcanic rocks on the west by the Clark Mountain normal fault, and the northern boundary of the district is a prominent transverse fault. The pre-Cambrian metamorphic complex comprises a great variety of lithologic types including garnetiferous mica gneisses and schists; biotite-garnet-sillimenite gneiss; hornblende gneiss, schist, and amphibolite; biotite gneiss and schist; granitic gneisses and migmatites; pegmatites; and minor amounts of foliated mafic rocks. The rare earth-bearing carbonate rocks are related to potash-rich igneous rocks, of uncertain age, that cut the metamorphic complex. The larger potash-rich intrusive masses, 300 or more feet wide, comprise one granite, two syenite, and four composite shonkinite-syenite bodies. One of the shonkinite-syenite stocks is more than a mile long. Several hundred relatively thin dikes of these potash-rich rocks range in composition, and generally decreasing age, from biotite shonkinite through syenite to granite. A few thin fine-grained shonkinite dikes cut the granite. These potash-rich rocks are cut by east-trending andesitic dikes and by faults. Veins of carbonate rock are most abundant in and near the southwest side of the largest shonkinite-syenite body. Although most veins are less than 6 feet thick, one mass of carbonate rock near the Sulphide Queen min4e is 600 feet in maximum width and 2,400 feet long. About 200 veins have been mapped in the district; their aggregate surface area is probably less than one-tenth that of the large carbonate mass. The carbonate materials, which make up about 60 percent of the veins and the large carbonite body, are chiefly calcite, dolomite, ankerite, and siderite. The other constituents are barite, bastnaesite and perisite, quartz, and variable small quantities of crocidolite, biotite, phlogopite, chlorite, muscovite, apatite, iron oxides, fluorite, monazite, galena, allanite, sphene, pyrite, chalcopyrite, tetrahedrite, malachite, azurite, corussite, wulfenite, aragonite, and thorite. The rare earth oxide content in most of the carbonate rock is less than 13 percent, but in some local concentrations of bastnaesite the content is as high as 40 percent. The origin of the carbonate rocks and related potash-rich igneous rocks is considered in the light of similar associations of carbonate and alkalinic rocks in Sweden, Norway, Russia, South Africa, and the United States. The carbonate rock may have originated (1) as a pre-Cambrian limestone or evaporate sequence in the gneisses; (2) by reaction between magma and the Paleozoic dolomite and limestone overlying the pre-Cambrian complex; (3) by alteration of pre-Cambrian gneisses by emanations from an unknown deep-seated source; or (4) by differentiation of an alkaline magma from shonkinite to syenite to granite, leading to a final carbonate-rich fraction, containing the rare elements, which was emplaced either as a concentrated or a dilute solution. The fourth hypothesis is considered the most plausible.

Open-File Report↗

Measurement of earth pressures by means of the flat jack test

This study deals with the principle and application of a method of measuring the stresses around a rock gallery. The measuring principle consists of cutting a drain in a gallery wall, observing the corresponding stress lessening, then restoring the initial state of stress by means of a Freyssinet flat jack. The application of this method in the Eastern iron-ore mines have given interesting results. In particular, they confirm the validity of the elastic hypothesis in these mines and enable the measurement of the stresses within them ass to be made more accurately than by the usual methods. Finally, by means of improvements, which do not unduly complicate the test performance, complete information on the elastic characteristics of the mineral may be obtained.

Open-File Report↗

High-resolution seismic-reflection image of the Chesapeake Bay impact structure, NASA Langley Research Center, Hampton, Virginia

A 1-kilometer-long (0.62-mile-long) seismic reflection and refraction profile collected at the National Aeronautics and Space Administration (NASA) Langley Research Center, Hampton, Va., provides a detailed image of part of the annular trough of the buried, 35-million-year-old Chesapeake Bay impact structure. This profile passes within 5 meters (m; 16.4 feet (ft)) of a 635.1-m-deep (2,083.8-ft-deep), continuously cored and geophysically logged test hole at the Langley Center (the USGS-NASA Langley corehole). High-resolution seismic reflection images (having a common-depth-point spacing of 2.5 m (8.2 ft)) of the upper 1,000 m (3,281 ft) along the seismic profile were generated by using refraction velocities and corehole sonic velocities to convert from time sections to depth sections. Time-distance, unmigrated depth-distance, and migrated depth-distance images show lateral variations in the geologic units observed in the USGS-NASA Langley corehole. A high-amplitude reflection at 630 to 625 m (2,067 to 2,051 ft) depth on the migrated depth image correlates with the top of weathered granite (the Langley Granite) at 626.3 m (2,054.7 ft) in the Langley core. Additional high-amplitude reflections below that depth likely represent a weathering profile developed in the upper part of the granite. Diffractions on the unmigrated images suggest that the granite contains numerous inhomogeneities that may consist of mineral veins and mineralized faults and fractures, as seen in the granite cores. Above the granite, crater unit A (minimally to moderately disturbed sands and clays of the Cretaceous Potomac Formation) is characterized by semicontinuous, horizontal and moderately inclined reflections that are broken by pervasive, subvertical, small-offset faults. Sediments of the lower beds of crater unit A below 558.1 m (1,831.0 ft) in the core have horizontal bedding and are nearly pristine. Above that depth, the upper beds of crater unit A contain thick fluidized sand intervals and fractured clay-silt beds. The contact between the granite and crater unit A is essentially horizontal on the migrated depth profile and shows minor relief produced by a few steeply dipping faults. Above crater unit A, the lower beds of crater unit B are lithologically similar to the upper beds of crater unit A and display similar impact-generated deformation. In the migrated depth image, crater unit A and the lower beds of crater unit B are combined into one unit. A thin zone (0.3 m (1.0 ft) thick) of injected glauconitic sediment at the base of the lower beds (at 442.5 m (1,451.7 ft) depth) is the only occurrence of exotic material in the lower beds of crater unit B in the core. The upper beds of crater unit B (above 427.7 m (1,403.3 ft) depth) are represented by discontinuous, locally weak, isolated, or inclined reflections on the migrated depth image. In the core, the upper beds of crater unit B are divided into megablocks and megablock zones that consist of fragmented sediments of the Potomac Formation. The megablocks are separated by matrix zones that consist of smaller blocks of sediments of the Potomac Formation suspended in a matrix of native disaggregated sediments of the Potomac Formation and injected, exotic disaggregated, glauconitic Upper Cretaceous and lower Tertiary marine sediments. Angular relationships and offsets of reflections across the high-relief contact between the upper beds of crater unit B and the underlying combined crater unit A and the lower beds of crater unit B suggest that the contact is a dip-slip fault locally. Above a contact with crater unit B at a depth of 269.4 m (884.0 ft), the Exmore beds are represented by strong, continuous and discontinuous, overstepping reflections that suggest division of the Exmore into four laterally discontinuous depositional subunits. Two of these subunits are present near the Langley corehole on the seismic images and are recognized in the core (Gohn and others, this volume, chap. C). In the Langley core, the Exmore beds consist of clasts of Cretaceous and Tertiary preimpact sediments and cataclastic, shocked, pre-Mesozoic igneous rocks suspended in a matrix of calcareous, muddy, quartz-glauconite sand and granules that contains shocked quartz. The dipping, truncated, and disrupted reflections within crater units A and B are interpreted to represent a 550-m-wide (1,805-ft-wide), stratabound collapse structure. This structure does not affect the underlying basement granite or the lower beds of crater unit A, nor does it affect the base of the Exmore beds above crater unit B. The collapse structure is not bounded laterally by major normal faults. Instead, structural displace ments appear to be distributed among abundant short, smalloffset faults and intervals of fluidized sediment. Fluidized sands above 558 m (1,831 ft) depth in crater unit A are interpreted as a low-strength zone that accommodated the widespread, latestage, gravitational collapse of the impact structure. The pro posed Langley collapse structure may be analogous to stratabound grabens in the outer zone of the Silverpit crater (North Sea). The Exmore beds are interpreted as impact-generated, ocean-resurge deposits. The upper contact of the Exmore section is a wavy, semicontinuous reflection that may represent large bedforms produced by resurge currents or returning impact-generated tsunamis, or it may represent the unmodified blocky or hummocky top of the final Exmore debris flow. Typically continuous, nearly horizontal reflections characterize the upper Eocene to Pleistocene postimpact section of dominantly marine sediments.

Virginia↗

Geologic Map of the Estes Park 30' x 60' Quadrangle, North-Central Colorado

The rocks and landforms of the Estes Park 30 x 60 minute quadrangle display an exceptionally complete record of geologic history in the northern Front Range of Colorado. The Proterozoic basement rocks exposed in the core of the range preserve evidence of Paleoproterozoic marine sedimentation, volcanism, and regional soft-sediment deformation, followed by regional folding and gradational metamorphism. The metasedimentary rocks of the Estes Park quadrangle are distinct within northern Colorado for preserving the complete metamorphic zonation from low-grade chlorite-muscovite phyllites, through middle greenschist-grade rocks with sequential aluminous porphyroblasts, to partially melted gneisses that contain high-grade cordierite and garnet in the non-melted residues. Regional and textural evidence shows that the widespread metamorphism was essentially concurrent with intrusion of the Boulder Creek Granodiorite and related magmas and with the peak of deformation in the partially melted high-grade rocks. The metamorphic thermal pulse arrived later following the peak of deformation in the physically higher, cooler, low-grade terrane. Mesoproterozoic time was marked by intrusion of biotite granite in the Longs Peak-St Vrain batholith, a complex, irregular body that occupies nearly half of the core of the Front Range in this quadrangle. The magma was dry and viscous as it invaded the metamorphic rocks and caused wholesale plastic folding of the wall rock structure. Steep metamorphic foliation that resulted from the Paleoproterozoic deformations was bowed upward and re-oriented into flat-lying attitudes as the crystal-rich magma rose buoyantly and spread out in the middle crust. Magma invaded the schists and gneisses along weak foliation planes and produced a characteristic sill-upon-sill intrusive fabric, particularly in the higher parts of the batholith. Broad, open arches and swales that are defined by the flow-aligned feldspar foliation of the granite, as well as by compositional banding in the intruded and included metamorphic rocks, formed late during batholith emplacement due to rising, buoyant magma and sinking, dense wall rocks. The Longs Peak-St Vrain batholith was intruded into crust that was structurally neutral or moderately extending in an east-northeast direction. A broad zone of mylonite, the Moose Mountain shear zone, formed within the batholith during the final stages of consolidation as a result of differential buoyancy between the magma and dense wall rock, not as a result of regional tectonic deformation.

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