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At least 883 records · Page 49Linked to original sources

Radon-222 concentrations in ground water and soil gas on Indian reservations in Wisconsin

The weighted average radon-222 concentration of indoor air in homes located on Wisconsin Indian Reservations is 5.8 picocuries per liter, which exceeds the U.S. Environmental Protection Agency action limit of 4 picocuries per liter. Ground water is the principle source of drinking water on Wisconsin Indian Reservations and generally accounts for about 5 percent of the total indoor air radon-222 concentrations found in homes. To determine the distribution of radon-222, ground water from 29 private and community Wisconsin Indian Reservation wells and soil gas at a depth of about 3 feet below land surface adjacent to the wells were sampled. Sites with wells were distributed among the 11 Wisconsin Indian Reservations so that each Reservation contained at least 2 sites. The remaining seven sites were divided among the Reservation by acreage held by each tribe. Ground-water samples were collected using a syringe technique after the wells had been purged sufficiently to reach chemical stability. Samples were then sent by overnight mail to the U.S. Geological Survey, National Water Quality Lab for analysis by liquid scintillation counting. Soil gas was collected in Lucas cells, using a small-diameter soil probe and peristaltic pump. The cells were then analyzed by Lucas cell alpha scintillation counting with a portable radon detector. The highest radon-222 concentrations in ground water and soil gas are from sites with wells finished in the crystalline bedrock aquifer. Radon-222 concentrations in 29 ground-water samples collected from the sand and gravel and sedimentary and crystalline bedrock aquifers range from 260 to 22,000 picocuries per liter with a median concentration of 560 picocuries per liter. Only 2 of the 29 ground-water samples have radon-222 concentrations less than the U.S. Environmental Protection Agency proposed standard of 300 picocuries per liter. The highest radon-222 concentrations were found in ground water from wells in Shawano, Menominee, Forest, and Marathon counties. Radon-222 concentrations in soil gas range from 130 to 7,810 picocuries per liter with a median concentration of 560 picocuries per liter. For sites with wells finished in the sand and gravel aquifer, the coefficient of determination (R2) of the regression of concentration of radon-222 in ground water as a function of well depth is 0.003 and the significance level is 0.32, which indicates that there is not a statistically significant relation between radon-222 concentrations in ground water and well depth. The coefficient of determination of the regression of radon-222 in ground water and soil gas is 0.19 and the root mean square error of the regression line is 271 picocuries per liter. Even though the significance level (0.036) indicates a statistical relation, the root mean square error of the regression is so large that the regression equation would not give reliable predictions. Because of an inadequate number of samples, similar statistical analyses could not be performed for sites with wells finished in the crystalline and sedimentary bedrock aquifers.

Wisconsin↗

Element concentrations in bed sediment of the Yellowstone River basin, Montana, North Dakota, and Wyoming — A retrospective analysis

Chemical data for bed sediment were analyzed as part of the U.S. Geological Survey National Water-Quality Assessment Program investigation of the Yellowstone River Basin in parts of Montana, North Dakota, and Wyoming. The primary data set consisted of about 13,000 samples collected during 1974-79 for the National Uranium Resource Evaluation program. Data were available for 50 elements, although not all samples were analyzed for all elements. Element concentrations varied spatially and were associated with geologic settings or ecoregions. Factor analysis indicated three groups of associated elements: factor 1 elements were strongly correlated with basaltic rocks, factor 2 elements were strongly correlated with granitic rocks, and factor 3 elements were strongly correlated with carbonate rocks. Scores for factor 1 were highest for bed-sediment samples associated with volcanic rocks of Tertiary and Cretaceous age in the Absaroka volcanic field and crystalline rocks of Precambrian age in the Beartooth Mountains. Scores for factor 2 were highest for samples associated with volcanic rocks of Quaternary age on the Yellowstone Plateau, crystalline rocks of Precambrian age, and sedimentary rocks of Tertiary age in the Wyoming Basin ecoregion. Scores for factor 3 were highest in samples associated with sedimentary rocks of Paleozoic age and volcanic rocks of Cretaceous and Tertiary age. Descriptive statistics are presented to serve as a baseline for element concentrations in bed sediment associated with eight geologic settings or ecoregions in the study unit. Some of the concentrations of chromium, copper, lead, nickel, and zinc in bed-sediment samples from areas of crystalline rocks in the Beartooth Mountains and other formations in the western part of the study unit exceeded sediment-quality assessment values associated with toxic effects to aquatic life.

Idaho, Montana, North Dakota, South Dakota, Wyomin↗

Chemical quality of surface waters in Pennsylvania

Pennsylvania has an abundant supply of surface water of good quality. The average rainfall over the 45,300 square miles in the State is about 42 inches per year. Of this amount, about 50 percent appears in the streams as runoff. The combined mean annual runoff of the Delaware, Ohio, and Susquehanna Rivers, at their farthest downstream measuring points in the State, is in excess of 81,000 cubic feet per second. Variations in the chemical quality of the surface waters in Pennsylvania are caused by areal differences in geology, urban and industrial development, mining, quarrying, land use, and runoff. Waters having the least dissolved solids are found in the glaciated northeastern and northwestern parts of the State; waters having higher values of hardness are found in the limestone terranes in the southeastern and south-central parts. In the anthracite coal fields in the northeast and in the bituminous coal fields in the southwest, many streams receive acid mine drainage, which lowers the alkalinity and increases the sulfate content of the waters. The chemical quality of surface waters in Pennsylvania is discussed in general terms. Introductory sections of the report cover the main causative factors which influence chemical quality.

Water Supply Paper↗

Reconnaissance geologic map of part of the San Isidro Quadrangle, Baja California Sur, Mexico

The reconnaissance geology of part of the San Isidro 1:250,000-scale quadrangle of Baja California Sur, Mexico, was mapped in 1982, 1983, and 1984 to determine the age and stratigraphic relations of Tertiary sedimentary and volcanic rocks that comprise the bulk of the Sierra de la Giganta (southern Peninsular Ranges) and Pacific coastal plain. Focus was placed on determining the distribution and age of plateau-capping basalts, and on mapping the eastern limits of Paleogene marine strata and the western limits of the nonmarine Comondu Formation. The area was also examined for outcrops of pre-Tertiary crystalline rocks, however, none were found. Mapping was done on aerial photographs and transferred, where possible, to 1:50,000-scale topographic base maps. Areas with roads were field checked; however, in the northeast part of the map area, lack of roads prevented field checks. Previous geologic surveys of parts of the map area were made by horseback in the early 1920's; reports were published by Darton (1921), Heim (1922), and Beal (1948). Subsurface data from petroleum exploration and a geologic map were incorporated in a regional study by Mina (1957). The first radiometric ages of rocks from the map area were published by Gastil and others (1979). Recently determined radiometric ages and chemical analysis of volcanic rocks were reported by Hausback (1984) and by Sawlan and Smith (1984). Our study incorporates geologic mapping with age control based on new radiometric ages as well as paleontology, Flows and tuffs were dated by the K-Ar method. Fossil ages are based on diatom and mollusk assemblages.

Baja California Sur↗

A model for the assessment of aquifer contamination potential based on regional geologic framework

The texture and three-dimensional framework of geologic materials should be considered in assessments of groundwater's vulnerability to contamination because geology controls the movement of contaminants and groundwater and influences groundwater quality. Contaminants are introduced into, transmitted through, and stored by geologic materials. We present a model that identifies aquifers and ranks sequences of geologic materials by their relative potential for transmitting water and contaminants from land surface. With this basis, the model can be used to assess the potential for contamination of aquifers by surface activities such as landfitling of wastes or application of agricultural chemicals. A regional map of aquifer contamination potential can be generated from the model; it retains the geologic map information intact and available for reinterpretation or other uses. The model was developed using broad, regional map information and is intended to be a general tool for assessing the regional vulnerability of aquifers to contamination. It is not intended for local, site-specific use, but for prioritizing local areas where contamination potential and/or land-use history warrant more detailed assessment or monitoring. Because it provides a regional view of contamination potential, regional patterns or trends of map units should be evaluated, rather than using the map information literally to assess local areas. Methods of applying this model and contamination potential map to groundwater protection and management are currently being studied; research includes an attempt to statistically validate the model with water-quality data, and to identify natural groupings of the ranked contamination potential map units. ?? 1992 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences↗

Environmental setting of Maple Creek watershed, Nebraska

The Maple Creek watershed covers a 955-square-kilometer area in eastern Nebraska, which is a region dominated by agricultural land use. The Maple Creek watershed is one of seven areas currently included in a nationwide study of the sources, transport, and fate of water and chemicals in agricultural watersheds. This study, known as the topical study of 'Agricultural Chemicals: Sources, Transport, and Fate' is part of the National Water-Quality Assessment Program being conducted by the U.S. Geological Survey. The Program is designed to describe water-quality conditions and trends based on representative surface- and ground-water resources across the Nation. The objective of the Agricultural Chemicals topical study is to investigate the sources, transport, and fate of selected agricultural chemicals in a variety of agriculturally diverse environmental settings. The Maple Creek watershed was selected for the Agricultural Chemicals topical study because its watershed represents the agricultural setting that characterizes eastern Nebraska. This report describes the environmental setting of the Maple Creek watershed in the context of how agricultural practices, including agricultural chemical applications and irrigation methods, interface with natural settings and hydrologic processes. A description of the environmental setting of a subwatershed within the drainage area of Maple Creek is included to improve the understanding of the variability of hydrologic and chemical cycles at two different scales.

Scientific Investigations Report↗

Statistical compilation of NAPAP chemical erosion observations

In the mid 1980s, the National Acid Precipitation Assessment Program (NAPAP), in cooperation with the National Park Service (NPS) and the U.S. Geological Survey (USGS), initiated a Materials Research Program (MRP) that included a series of field and laboratory studies with the broad objective of providing scientific information on acid rain effects on calcareous building stone. Among the several effects investigated, the chemical dissolution of limestone and marble by rainfall was given particular attention because of the pervasive appearance of erosion effects on cultural materials situated outdoors. In order to track the chemical erosion of stone objects in the field and in the laboratory, the Ca 2+ ion concentration was monitored in the runoff solution from a variety of test objects located both outdoors and under more controlled conditions in the laboratory. This report provides a graphical and statistical overview of the Ca 2+ chemistry in the runoff solutions from (1) five urban and rural sites (DC, NY, NJ, NC, and OH) established by the MRP for materials studies over the period 1984 to 1989, (2) subevent study at the New York MRP site, (3) in situ study of limestone and marble monuments at Gettysburg, (4) laboratory experiments on calcite dissolution conducted by Baedecker, (5) laboratory simulations by Schmiermund, and (6) laboratory investigation of the surface reactivity of calcareous stone conducted by Fries and Mossotti. The graphical representations provided a means for identifying erroneous data that can randomly appear in a database when field operations are semi-automated; a purged database suitable for the evaluation of quantitative models of stone erosion is appended to this report. An analysis of the sources of statistical variability in the data revealed that the rate of stone erosion is weakly dependent on the type of calcareous stone, the ambient temperature, and the H + concentration delivered in the incident rain. The analysis also showed that the rate of stone erosion is strongly dependent on the rain-delivery conditions and on the surface morphology and orientation.

Open-File Report↗

Variations in the chemical character of the Susquehanna River at Harrisburg, Pennsylvania

The chemical quality of the Susquehanna River at Harrisburg is influenced by three major factors: streamflow, anthracite and bituminous coal-mine drainage, and geology. Water samples collected at Harrisburg near the west bank of the Susquehanna River and those of western tributaries that drain limestone terranes are similar in chemical quality. The water is alkaline and contains calcium, magnesium, and bicarbonate-ion concentrations typical of water drained from limestone. The chemical quality of water samples collected in the center of the river resembles the quality of the West Branch Susquehanna River, which has a dissolved-solids content of about 200 parts per million, and a sulfate-ion concentration that generally exceeds the bicarbonate-ion concentration. Samples collected near the east or Harrisburg bank show the effect of anthracite coalmine drainage from the river's eastern tributaries. The pH of these samples ranges from 5.7 to 7.5, and sulfate is the predominate ion. The dissolved-solids content of the river at the Harrisburg cross-section stations is inversely proportional to the streamflow. During periods of low riverflow, the dissolved-solids content approaches a maximum; during periods of high flow, the content is low. The chemical composition of the river at the Harrisburg cross section indicates that water from the principal tributaries above Harrisburg does not mix sufficiently to lose its chemical-quality identity before reaching Harrisburg irrespective of the long distance involved, the many islands and bridge piers, and the rough streambed. This lack of lateral mixing is probably due to the small depth-width ratio and the extreme width of the river.

Water Supply Paper↗

Reconnaissance of chemical and biological quality in the Owyhee River from the Oregon State line to the Owyhee Reservoir, Oregon, 2001–02

The Owyhee River drains an extremely rugged and sparsely populated landscape in northern Nevada, southwestern Idaho, and eastern Oregon. Most of the segment between the Oregon State line and Lake Owyhee is part of the National Wild and Scenic Rivers System, and few water-quality data exist for evaluating environmental impacts. As a result, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, assessed this river segment to characterize chemical and biological quality of the river, identify where designated beneficial uses are met and where changes in stream quality occur, and provide data needed to address activities related to environmental impact assessments and Total Maximum Daily Loads. Water-quality issues identified at one or more sites were water temperature, suspended sediment, dissolved oxygen, pH, nutrients, trace elements, fecal bacteria, benthic invertebrate communities, and periphyton communities. Generally, summer water temperatures routinely exceeded Oregon's maximum 7-day average criteria of 17.8 degrees Celsius. The presence of few coldwater taxa in benthic invertebrate communities supports this observation. Suspended-sediment concentrations during summer base flow were less than 10 milligrams per liter (mg/L). Dissolved solids concentrations ranged from 46 to 222 mg/L, were highest during base flow, and tended to increase in a downstream direction. Chemical compositions of water samples indicated that large proportions of upland-derived water extend to the lower reaches of the study area during spring runoff. Dissolved fluoride and arsenic concentrations were highest during base flow and may be a result of geothermal springs discharging to the river. No dissolved selenium was detected. Upstream from the Rome area, spring runoff concentrations of suspended sediment ranged from 0 to 52 mg/L, and all except at the Three Forks site were typically below 20 mg/L. Stream-bottom materials from the North Fork Owyhee River, an area with no mines, were enriched with nine trace elements, which indicates that this basin may be a natural source of these elements. Near Rome, the part of the study area not included in the National Wild and Scenic Rivers System, land-use impacts resulted in elevated populations of Escherichia coli bacteria ( E. coli ) during base flow and elevated concentrations of nitrogen and phosphorus during spring runoff. Sites in this area had the highest numbers of benthic invertebrates; the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa; and the highest Hilsenhoff Biotic Index scores. These results suggest degraded stream quality. Periphyton communities at sites in this area approached nuisance levels and could cause significant dissolved oxygen depletions and pH values that exceed Oregon's recommended criteria. Stream-bottom materials from Jordan Creek were enriched with mercury and manganese, which probably were ultimately caused by past mining in that basin. Below Crooked Creek, elevated suspended sediment concentrations (142 mg/L), phosphorus concentrations (0.23 mg/L), and E. coli populations (370 most probable number per 100 milliliters) during the largest spring runoff event could be the result of inputs at the lower end of Jordan Valley and (or) inputs from Crooked Creek. The New Zealand Mud Snail, a highly competitive gastropod introduced to the Snake River in the 1980s, was collected just downstream from the Crooked Creek confluence.

Idaho;Nevada;Oregon↗

Distribution of fish, benthic invertebrate, and algal communities in relation to physical and chemical conditions, Yakima River basin, Washington, 1990

Biological investigations were conducted in the Yakima River Basin, Washington, in conjunction with a pilot study for the U.S. Geological Survey's National Water-Quality Assessment Program. Ecological surveys were conducted at 25 sites in 1990 to (1) assess water-quality conditions based on fish, benthic invertebrate, and algal communities; (2) determine the hydrologic, habitat, and chemical factors that affect the distributions of these organisms; and (3) relate physical and chemical conditions to water quality. Results of these investigations showed that land uses and other associated human activities influenced the biological characteristics of streams and rivers and overall water-quality conditions. Fish communities of headwater streams in the Cascades and Eastern Cascades ecoregions of the Yakima River Basin were primarily composed of salmonids and sculpins, with cyprinids dominating in the rest of the basin. The most common of the 33 fish taxa collected were speckled dace, rainbow trout, and Paiute sculpin. The highest number of taxa (193) was found among the inverte- brates. Insects, particularly sensitive forms such as mayflies, stoneflies, and caddisflies (EPT--Ephemeroptera, Plecoptera, and Trichoptera fauna), formed the majority of the invertebrate communities of the Cascades and Eastern Cascades ecoregions. Diatoms dominated algal communities throughout the basin; 134 algal taxa were found on submerged rocks, but other stream microhabitats were not sampled as part of the study. Sensitive red algae and diatoms were predominant in the Cascades and Eastern Cascades ecoregions, whereas the abundance of eutrophic diatoms and green algae was large in the Columbia Basin ecoregion of the Yakima River Basin. Ordination of physical, chemical, and biological site characteristics indicated that elevation was the dominant factor accounting for the distribution of biota in the Yakima River Basin; agricultural intensity and stream size were of secondary importance. Ordination identified three site groups and three community types. Site groups consisted of (1) small streams of the Cascades and Eastern Cascades ecoregions, (2) small streams of the Columbia Basin ecoregions, and (3) large rivers of the Cascades and Columbia Basin ecoregions. The small streams of the Columbia Basin could be further subdivided into two groups--one where agricultural intensity was low and one where agricultural intensity was moderate to high. Dividing the basin into these three groups removed much of the influence of elevation and facilitated the analysis of land-use effects. Community types identified by ordination were (1) high elevation, cold-water communities associated with low agricultural intensity; (2) lower elevation, warm-water communities associated with low agricultural intensity, and (3) lower elevation, warm-water communities associated with moderate to high agricultural intensity. Multimetric community condition indices indicated that sites in the Cascades and Eastern Cascades site group were largely unimpaired. In contrast, all but two sites in the Columbia Basin site group were impaired, some severely. Agriculture (nutrients and pesticides) was the primary factor responsible for this impairment, and all impaired sites were characterized by multiple indicators of impairment. Three sites (Granger Drain, Moxee Drain, and Spring Creek) had high levels of impairment. Sites in the large-river site group were moderately to severely impaired downstream from the city of Yakima. High levels of impairment at large-river sites corresponded with high levels of pesticides in fish tissues and the occurrence of external anomalies.

Washington↗

Transport of agricultural chemicals in surface flow, tileflow, and streamflow of Walnut Creek Watershed near Ames, Iowa, April 1991-September 1993

The U.S. Geological Survey, in cooperation with the National Soil Tilth Laboratory of the U.S. Department of Agriculture, Agricultural Research Service, conducted a study as part of the multi-scale, inter-agency Management Systems Evaluation Area (MSEA) program to evaluate the effects of agricultural management (farming) systems on water quality. Data on surface flow, tileflow, and streamflow in the Walnut Creek watershed just south of Ames, Iowa, were collected during April 1991-September 1993 at five sites with drainage areas ranging from 366 to 5,130 hectares. Precipitation, flow discharge, and concentration, loads, and yields of nitrate as nitrogen, atrazine, and metolachlor were analyzed to relate the transport of agricultural chemicals to major water-flow processes and to examine flow and transport differences among three subwatersheds. Antecedent conditions and basin-characteristic differences had significant effects on the flow response from the subwatersheds. Monthly streamflow-to-precipitation ratios were greater than 1.0, as a result of snowmelt, and negative when streamflow was lost to the ground-water system in the downstream subwatershed. Dry antecedent conditions resulted in ratios less than 0.3 (July 1992), whereas wet antecedent conditions resulted in ratios from 0.7 to almost 1.0 (July 1993) during months with similar large rainfall amounts. Most of the streamflow from the upland subwatersheds came from tileflow. Surface flow (surface runoff, interflow, and return flow) was highly variable and intermittent, usually lasting for only a few days after a storm, although it could be the dominant source of flow when stormflow was large. Tileflow was less variable and much more persistent, ceasing only after prolonged dry periods. Large quantities of nitrate as nitrogen were transported in Walnut Creek, with concentrations often greater than the Maximum Contaminant Level of 10 milligrams per liter established by the U.S. Environmental Protection Agency for finished drinking water. In the upland subwatersheds, ground-water flow from the tiles appears to have been the primary means of transport to the streams. Concentrations in tileflow and streamflow generally were 4 to 16 milligrams per liter, with the lower concentrations often the result of dilution by surface runoff. Loss ratios, chemical yields expressed as a percentage of average application rates of nitrate as nitrogen for October 1992-September 1993, were about 10 percent for surface flow and more than 100 percent for tileflow from the 366-hectare basin and were more than 200 percent for streamflow from the downstream subwatershed. Concentrations of atrazine and metolachlor in streamflow, typically, were less than the Maximum Contaminant Level of 3.0 micrograms per liter, but were as high as 59 and 80 micrograms per liter, respectively, during stormflow. Concentrations as high as 170 micrograms per liter occurred in tileflow, but these were related to surface flow through surface inlets. The transport of herbicides was extremely variable, with most of the loads occurring during stormflow. Atrazine appeared more susceptible to transport losses to streamflow than did metolachlor. Loss ratios for streamflow from the subwatersheds for April-September periods were 0.3 to 20 percent for atrazine and 0.1 to 2.9 percent for metolachlor. Chemical loss ratios indicated differences in the transport characteristics of the three subwatersheds. The downstream subwatershed, which has steeper terrain, a more-developed natural drainage system, and fewer tiles than the two upland subwatersheds, had the largest loss rates for all three chemicals 206 percent for nitrate as nitrogen (October 1992-September 1993) and 20 percent for atrazine and 2.9 percent for metolachlor (April-September 1993). For May-July 1993, when most of the herbicides were transported, the downstream subwatershed also had the largest cumulative unit discharge and the largest streamflow-to-precipitation ratios.

Iowa↗

Data on water wells, Naval Air Missile Test Center Area, Point Mugu, California

The entire water supply for the U. S. Naval Air Missile Test Center at Point Mugu, Calif., is pumped from wells located .within 2 miles of the Pacific Ocean. A large irrigation development inland from the Test Center has created a landward hydraulic gradient beneath the Test Center, causing sea-water encroachment into the water-yielding deposits. The encroaching sea water has not yet reached the Test Center well field; however, the encroachment poses a serious threat to the Test Center supply. To evaluate the adequacy of the water supply for the Naval Air Missile Test Center under these conditions and to suggest additional sources for future development, the U. S. Geological Survey has canvassed all wells and collected all available hydrologic dataat the Test Center and in the immediate vicinity. The data tabulated in this report include measurements of water levels in wells, well logs, and chemical analyses for all wells south of Hueneme Road collected through February 1959. This study was made by the Geological Survey, U. S. Department of the Interior, under the general supervision of H. L. Wilson, Jr., district engineer for California, and under the immediate supervision of Fred Kunkel, geologist in charge of the Long Beach subdistrict office.

California↗

Chemical data for bottom sediment in Mountain Creek Lake, Dallas, Texas, 1999-2000

Mountain Creek Lake is a reservoir adjacent to the Naval Weapons Industrial Reserve Plant and the former Naval Air Station in Dallas, Texas. The U.S. Geological Survey began studies of water, sediment, and biota in the reservoir in 1994 after a Resource Conservation and Recovery Act Facility Investigation detected concentrations of organic chemicals on both facilities. Additional reservoir bottom sediment samples were collected during December 1999–January 2000 at the request of the Southern Division Naval Facilities Engineering Command to further define the occurrence and distribution of selected constituents and to supplement available data. The U.S. Geological Survey National Water Quality Laboratory analyzed bottom-sediment samples from 16 box cores and 5 gravity cores for major and trace elements, organochlorine pesticides, polychlorinated biphenyls, polycyclic aromatic hydrocarbons, grain size, and cesium-137.

Texas↗

Responses of physical, chemical, and biological indicators of water quality to a gradient of agricultural land use in the Yakima River Basin, Washington

The condition of 25 stream sites in the Yakima River Basin, Washington, were assessed by the U.S. Geological Survey's National Water-Quality Assessment Program. Multimetric condition indices were developed and used to rank sites on the basis of physical, chemical, and biological characteristics. These indices showed that sites in the Cascades and Eastern Cascades ecoregions were largely unimpaired. In contrast, all but two sites in the Columbia Basin ecoregion were impaired, some severely. Agriculture (nutrients and pesticides) was the primary factor associated with impairment and all impaired sites were characterized by multiple indicators of impairment. All indices of biological condition (fish, invertebrates, and algae) declined as agricultural intensity increased. The response exhibited by invertebrates and algae suggested a threshold response with conditions declining precipitously at relatively low levels of agricultural intensity and little response at moderate to high levels of agricultural intensity. This pattern of response suggests that the success of mitigation will vary depending upon where on the response curve the mitigation is undertaken. Because the form of the community condition response is critical to effective water-quality management, the National Water-Quality Assessment Program is conducting studies to examine the response of biota to gradients of land-use intensity and the relevance of these responses to water-quality management. These land-use gradient pilot studies will be conducted in several urban areas starting in 1999.

Environmental Monitoring and Assessment↗

The U.S. Geological Survey's water resources program in New York

The U.S. Geological Survey performs hydrologic investigations throughout the United States to appraise the Nation's water resources. The Geological Survey began its water-resources investigations in New York in 1895. To meet the objectives of assessing New York's water resources, the Geological Survey (1) monitors the quantity and quality of surface and ground water, (2) conducts investigations of the occurrence, availability, and chemical quality of water in specific areas of the State, (3) develops methods and techniques of data-collection and interpretation, (4) provides scientific guidance to the research community, to Federal, State, and local governments, and to the public, and (5) disseminates data and results of research through reports, maps, news releases, conferences, and workshops. Many of the joint hydrologic investigations are performed by the Geological Survey in cooperation with State, county, and nonprofit organizations. The data collection network in New York includes nearly 200 gaging stations and 250 observation wells; chemical quality of water is measured at 260 sites. Data collected at these sites are published annually and are filed in the WATSTORE computer system. Some of the interpretive studies performed by the Geological Survey in New York include (1) determining the suitability of ground-water reservoirs for public-water supply in urban areas, (2) assessing geohydrologic impacts of leachate from hazardous waste sites on stream and ground-water quality, (3) evaluating the effects of precipitation quality and basin characteristics on streams and lakes, and (4) developing digital models of the hydrology of aquifers to simulate ground-water flow and the interaction between ground water and streams.

Open-File Report↗

Radiochemical monitoring of water after the Cannikin event, Amchitka Island, Alaska, August 1974 and chemical monitoring from July 1972 to June 1974

Radiochemical data from the Arnchitka Island study area were obtained from water samples collected by the U.S. Geological Survey during August 1974. Tritium determinations were made on 18 samples, and gross alpha and gross beta/ gamma determinations were made on 12 samples. No appreciable differences were found between the data obtained during August 1974 and the data obtained before the Cannikin event. Chemical analyses were made on 4 samples collected in 1971, on 15 samples in 1972, on 11 samples in 1973, and 7 samples in 1974. Comparison of these analyses to analyses of samples collected before the Cannikin event indicates no changes outside of the seasonal range normally found at the sampling locations.

Alaska↗

Descriptions and chemical analyses for selected wells in the Central Sacramento Valley, California

The Sacramento Valley occupies the northern one-third of the Great Central Valley of California. The study area of this report includes about 1,200 square miles (3,100 square kilometres) adjacent to the Sacramento River from Knights Landing to Los Molinos, in parts of Yolo, Sutter, Colusa, Glenn, Butte, and Tehama Counties. Between April and August 1975, 559 wells were selectively canvassed, and during September and October 1975, water samples were collected for chemical analysis from 209 of the 559 wells canvassed. Field determinations of alkalinity, conductance, pH, and temperature were made on the site at the time of sampling. The samples were then field prepared for shipmment and analysis for individual constituents at the Geological Survey Central Laboratory, Salt Lake City, Utah. Descriptive data for water wells are listed in table 1, chemical data in tables 2 and 3, and the location of these wells is shown on maps 1-33.

California↗

Temporal trends in water-quality constituent concentrations and annual loads of chemical constituents in Michigan watersheds, 1998–2013

In 1998, the Michigan Department of Environmental Quality and the U.S. Geological Survey began the Water Chemistry Monitoring Program for select streams in the State of Michigan. Objectives of this program were to provide assistance with (1) statewide water-quality assessments, (2) the National Pollutant Discharge Elimination System permitting process, and (3) water-resource management decisions. As part of this program, water-quality data collected from 1998 to 2013 were analyzed to identify potential trends for select constituents that were sampled. Sixteen water-quality constituents were analyzed at 32 stations throughout Michigan. Trend analysis on the various water-quality data was done using either the uncensored Seasonal Kendall test or through Tobit regression. In total, 79 trends were detected in the constituents analyzed for 32 river stations sampled for the study period—53 downward trends and 26 upward trends were detected. The most prevalent trend detected throughout the State was for ammonia, with 11 downward trends and 1 upward trend estimated. In addition to trends, constituent loads were estimated for 31 stations from 2002 to 2013 for stations that were sampled 12 times per year. Loads were computed using the Autobeale load computation program, which used the Beale ratio estimator approach to estimate an annual load. Constituent loads were the largest in large watershed streams with the highest annual flows such as the Saginaw and Grand Rivers. Likewise, constituent loads were the smallest in smaller tributaries that were sampled as part of this program such as the Boardman and Thunder Bay Rivers.

Michigan↗