USGS Science⌕ Search

SEARCH · USGS Science

Results for “Applied Sciences”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 883 records · Page 49Linked to original sources
USGS2009

Geographic relatedness and predictability of Escherichia coli along a peninsular beach complex of Lake Michigan

To determine more accurately the real-time concentration of fecal indicator bacteria (FIB) in beach water, predictive modeling has been applied in several locations around the Great Lakes to individual or small groups of similar beaches. Using 24 beaches in Door County, Wisconsin, we attempted to expand predictive models to multiple beaches of complex geography. We examined the importance of geographic location and independent variables and the consequential limitations for potential beach or beach group models. An analysis of Escherichia coli populations over 4 yr revealed a geographic gradient to the beaches, with mean E. coli concentrations decreasing with increasing distance from the city of Sturgeon Bay. Beaches grouped strongly by water type (lake, bay, Sturgeon Bay) and proximity to one another, followed by presence of a storm or creek outfall or amount of shoreline enclosure. Predictive models developed for beach groups commonly included wave height and cumulative 48-h rainfall but generally explained little E. coli variation (adj. R 2 = 0.19-0.36). Generally low concentrations of E. coli at the beaches influenced the effectiveness of model results presumably because of low signal-to-noise ratios and the rarity of elevated concentrations. Our results highlight the importance of the sensitivity of regressors and the need for careful methods evaluation. Despite the attractiveness of predictive models as an alternative beach monitoring approach, it is likely that FIB fluctuations at some beaches defy simple prediction approaches. Regional, multi-beach, and individual beach predictive models should be explored alongside other techniques for improving monitoring reliability at Great Lakes beaches. Copyright ?? 2009 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Journal of Environmental Quality↗
USGS2024

Improved efficient physics-based computational modeling of regional wave-driven coastal flooding for reef-lined coastlines

Coastal flooding affects low-lying communities worldwide and is expected to increase with climate change, especially along reef-lined coasts, where wave-driven flooding is particularly prevalent. However, current regional modeling approaches are either insufficient or too computationally expensive to accurately assess risks in these complex environments. This study introduces and validates an improved computationally efficient and physics-based approach to compute dynamic wave-driven regional flooding on reef-lined coasts. We coupled a simplified-physics flood model (SFINCS) with a one-dimensional wave transformation model (XBeach-1D). To assess the performance of the proposed approach, we compared its results with results from a fully resolving two-dimensional wave transformation model (XBeach-2D). We applied this approach for a range of storms and sea-level rise scenarios for two contrasting reef-lined coastal geomorphologies: one low relief area and one high relief area. Our findings reveal that SFINCS coupled with XBeach-1D generates flood extents comparable to those produced by XBeach-2D, with a hit rate of 92%. However, this method tends to underpredict the flood extent of weaker, high-frequency storms and overpredict stronger, low-frequency storms. Across scenarios, our approach overpredicted the mean flood water depth, with a positive bias of 7 cm and root mean square difference of 15 cm. Offering approximately 100 times greater computational efficiency than its two-dimensional XBeach counterpart, this flood modeling technique is recommended for wave-driven flood modeling in scenarios with high computational demands, such as modeling numerous scenarios or undertaking detailed regional-scale modeling.

Journal of Marine Science & Engineering↗
USGS2001

HAZUS 99 estimated annualized earthquake losses for the United States

Recent earthquakes around the world show a pattern of steadily increasing damages and losses. The increases are due primarily to two factors: 1) significant growth in urban areas that are prone to earthquakes; and 2) the vulnerability of the older building stock, even buildings that were constructed within the past twenty years. In the United States, earthquake risk has grown substantially with development, while the earthquake hazard has remained relatively constant. To understand the hazard, we study earthquake characteristics and locales in which they occur. To understand risk, we must include characteristics of the built environment in the locales where earthquakes occur, and we must assess potential damages to the built environment and the people who use it. That is a complex undertaking and one this study intends to advance. It is important to estimate the varying degrees of seismic risk throughout the United States because we need that understanding in order to make informed decisions on mitigation policies, priorities, strategies and funding levels—in both the public and private sectors. We can reduce earthquake losses to older buildings by rehabilitating them, and we can reduce earthquake losses in new buildings by applying seismic codes to their design and construction. However, decisions to spend money on either of those solutions require evidence of risk. In the absence of a nationally accepted criterion and methodology for comparing seismic risk across regions, a consensus on optimal mitigation approaches has been difficult to reach. We are all aware of regions with high hazard and high risk, such as Los Angeles, but there is growing recognition that some regions with low seismic hazard actually have high seismic risk, as is the case in New York City and Boston. This risk results, in part, from concentrations of buildings and infrastructure built without use of seismic codes or provisions. Additionally, mitigation policies and practices in the public and private sectors may not have been adopted because a community’s earthquake risk was not clearly demonstrated, and neither was the value of mitigation measures in reducing that risk. The low hazard/high risk problem exists in a number of areas in the U.S., where the infrequency of damaging earthquakes has been interpreted, wrongly, as lack of risk. While earth scientists work to increase knowledge about the hazard throughout the United States, structural engineers and other professionals work to enumerate the many factors that comprise risk. This study is one result of that endeavor. It is based on loss estimates generated by Hazards U.S. (HAZUS), a Geographic Information System (GIS)- based earthquake loss estimation tool, developed by the Federal Emergency Management Agency (FEMA) in cooperation with the National Institute of Building Sciences (NIBS). The HAZUS tool provides an approach to quantifying future earthquake losses that is national in scope, uniform in application, and comprehensive in its coverage of the built environment.

Report↗
USGS2004

Spatially quantitative seafloor habitat mapping: Example from the northern South Carolina inner continental shelf

Naturally occurring hard bottom areas provide the geological substrate that can support diverse assemblages of sessile benthic organisms, which in turn, attract many reef-dwelling fish species. Alternatively, defining the location and extent of bottom sand bodies is relevant for potential nourishment projects as well as to ensure that transient sediment does not affect reef habitats, particularly in sediment-starved continental margins. Furthermore, defining sediment transport pathways documents the effects these mobile bedforms have on proximal reef habitats. Thematic mapping of these substrates is therefore crucial in safeguarding critical habitats and offshore resources of coastal nations. This study presents the results of a spatially quantitative mapping approach based on classification of sidescan-sonar imagery. By using bottom video for image-to-ground control, digital image textural features for pattern recognition, and an artificial neural network for rapid, quantitative, multivariable decision-making, this approach resulted in recognition rates of hard bottom as high as 87%. The recognition of sand bottom was less successful (31%). This approach was applied to a large (686 km2), high-quality, 2-m resolution sidescan-sonar mosaic of the northern South Carolina inner continental shelf. Results of this analysis indicate that both surficial sand and hard bottoms of variable extent are present over the study area. In total, 59% of the imaged area was covered by hard bottom, while 41% was covered by sand. Qualitative spatial correlation between bottom type and bathymetry appears possible from comparison of our interpretive map and available bathymetry. Hard bottom areas tend to be located on flat, low-lying areas, and sandy bottoms tend to reside on areas of positive relief. Published bio-erosion rates were used to calculate the potential sediment input from the mapped hard bottom areas rendering sediment volumes that may be as high as 0.8 million m3/yr for this portion of the South Carolina coast. ?? 2003 Elsevier Ltd. All rights reserved.

South Carolina↗
USGS2015

Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish

Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin Delta, stocked them with mosquitofish ( Gambusia affinis ), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems.

California↗
USGS2020

Spatiotemporal variation in occurrence and co-occurrence of pesticides, hormones, and other organic contaminants in rivers in the Chesapeake Bay Watershed, United States

Investigating the spatiotemporal dynamics of contaminants in surface water is crucial to better understand how introduced chemicals are interacting with and potentially influencing aquatic organisms and environments. Within the Chesapeake Bay Watershed, USA, there are concerns about the potential role of contaminant exposure on fish health. Evidence suggests that exposure to contaminants in surface water is causing immunosuppression and intersex in freshwater fish species. Despite these concerns, there is a paucity of information regarding the complex dynamics of contaminant occurrence and co-occurrence in surface water across both space and time. To address these concerns, we applied a Bayesian hierarchical joint-contaminant model to describe the occurrence and co-occurrence patterns of 28 contaminants and total estrogenicity across six river sites and over three years. We found that seasonal occurrence patterns varied by contaminant, with the highest occurrence probabilities during the spring and summer months. Additionally, we found that the proportion of agricultural landcover in the immediate catchment, as well as stream discharge, did not have a significant effect on the occurrence probabilities of most compounds. Four pesticides (atrazine, metolachlor, fipronil and simazine) co-occurred across sites after accounting for environmental covariates. These results provide baseline information on the contaminant occurrence patterns of several classes of compounds within the Chesapeake Bay Watershed. Understanding the spatiotemporal dynamics of contaminants in surface water is the first step in investigating the effects of contaminant exposure on fisheries and aquatic environments.

Delaware, Maryland, New York, Pennsylvania, Virgin↗
USGS2003

Density of the continental roots: Compositional and thermal contributions

The origin and evolution of cratonic roots has been debated for many years. Precambrian cratons are underlain by cold lithospheric roots that are chemically depleted. Thermal and petrologic data indicate that Archean roots are colder and more chemically depleted than Proterozoic roots. This observation has led to the hypothesis that the degree of depletion in a lithospheric root depends mostly on its age. Here we test this hypothesis using gravity, thermal, petrologic, and seismic data to quantify differences in the density of cratonic roots globally. In the first step in our analysis we use a global crustal model to remove the crustal contribution to the observed gravity. The result is the mantle gravity anomaly field, which varies over cratonic areas from -100 to +100 mGal. Positive mantle gravity anomalies are observed for cratons in the northern hemisphere: the Baltic shield, East European Platform, and the Siberian Platform. Negative anomalies are observed over cratons in the southern hemisphere: Western Australia, South America, the Indian shield, and Southern Africa. This indicates that there are significant differences in the density of cratonic roots, even for those of similar age. Root density depends on temperature and chemical depletion. In order to separate these effects we apply a lithospheric temperature correction using thermal estimates from a combination of geothermal modeling and global seismic tomography models. Gravity anomalies induced by temperature variations in the uppermost mantle range from -200 to +300 mGal, with the strongest negative anomalies associated with mid-ocean ridges and the strongest positive anomalies associated with cratons. After correcting for thermal effects, we obtain a map of density variations due to lithospheric compositional variations. These maps indicate that the average density decrease due to the chemical depletion within cratonic roots varies from 1.1% to 1.5%, assuming the chemical boundary layer has the same thickness as the thermal boundary layer. The maximal values of the density drop are in the range 1.7-2.5%, and correspond to the Archean portion of each craton. Temperatures within cratonic roots vary strongly, and our analysis indicates that density variations in the roots due to temperature are larger than the variations due to chemical differences.

Earth and Planetary Science Letters↗
USGS2025

Assessing the effect of coral reef restoration location on coastal flood hazard along the San Juan Coastline, Puerto Rico

Coastal resilience has become a pressing global issue due to the growing vulnerability of coastlines to the effects of climate change. Nature-based solutions have emerged as a promising approach to coastal protection to not only enhance coastal resilience, but also restore critical ecosystems. Coral reef restoration has the potential to provide ecosystem services benefits; however, there are still key uncertainties in linking restoration design to reductions in coastal flood hazard under current and future climate conditions. In this study, we applied one-dimensional and two-dimensional numerical coastal engineering models, calibrated and validated using field data, to evaluate the effectiveness of coral restoration scenarios on coastal waves, water levels, and flooding along the coast of San Juan, Puerto Rico, U.S.A. Model results indicate a small reduction in maximum water levels under the proposed restoration scenarios. This underscores the importance of these endeavors, not only for ecological preservation but also for preventing further reef deterioration. Such preservation is essential for mitigating the increased coastal risks anticipated in the future. Results from this study provide information to guide policymakers and coastal managers in making informed decisions on viable restoration project design options. By systematically evaluating how restoration location impacts coastal flood hazards, communities can develop and implement proactive strategies to mitigate flood-related risk. In addition, by restoring coral reefs, communities can contribute to environmental preservation while ensuring sustainable development and protection of coastal environments.

Puerto Rico, San Juan coastline↗
USGS2015

The Penobscot River and environmental contaminants: Assessment of tribal exposure through sustenance lifeways

EPA in collaboration with the Penobscot Indian Nation, U.S. Geological Survey (USGS), Agency for Toxic Substances and Disease Registry (ATSDR), and the U.S. Fish and Wildlife Service (USF&WS) collectively embarked on a four year research study to evaluate the environmental health of the riverine system by targeting specific cultural practices and using traditional science to conduct a preliminary contaminant screening of the flora and fauna of the Penobscot River ecosystem. This study was designed as a preliminary screening to determine if contaminant concentrations in fish, eel, snapping turtle, wood ducks, and plants in Regions of the Penobscot River relevant to where PIN tribal members hunt, fish and gather plants were high enough to be a health concern. This study was not designed to be a statistically validated assessment of contaminant differences among study sites or among species. The traditional methodology for health risk assessment used by the U. S. Environmental Protection Agency (EPA) is based on the use of exposure assumptions (e.g. exposure duration, food ingestion rate, body weight, etc.) that represent the entire American population, either as a central tendency exposure (e.g. average, median) or as a reasonable maximum exposure (e.g. 95% upper confidence limit). Unfortunately, EPA lacked exposure information for assessing health risks for New England regional tribes sustaining a tribal subsistence way of life. As a riverine tribe, the Penobscot culture and traditions are inextricably tied to the Penobscot River watershed. It is through hunting, fishing, trapping, gathering and making baskets, pottery, moccasins, birch-bark canoes and other traditional practices that the Penobscot culture and people are sustained. The Penobscot River receives a variety of pollutant discharges leaving the Penobscot Indian Nation (PIN) questioning the ecological health and water quality of the river and how this may affect the practices that sustain their way of life. The objectives of this Regional Applied Research Effort (RARE) study were to: Develop culturally sensitive methodologies for assessing the potential level of exposure tocontaminants that Penobscot Indian Nation tribal members may have from maintainingtribal sustenance practices. Conduct field surveys and laboratory analysis on targeted flora and fauna for chemicalexposure to dioxins/furans, polychlorinated biphenyls (PCBs), total mercury and methyl-mercury. Assist the Agency for Toxic Substances and Disease Registry (ATSDR) by providing thenecessary data to conduct a Public Health Assessment for the Penobscot Indian Nation. Establish protocols for assessing the level of exposure to PCBs, dioxins/furans and mercuryto PIN tribal members as a consequence of gathering tribal plants for medicinal andnutritional purposes; as well as consuming fish, wood duck, and snapping turtle as a primarysource of nutrition. Survey surface water, drinking water, and sediment from the Penobscot River and IndianIsland to assess the exposure of PIN tribal members to environmental genotoxicants thatcontinue cultural sustenance practices. This research initiative collected and analyzed sediment and biota to determine the level of contaminant exposure to Penobscot tribal members. Natural resource utilization patterns and exposure pathways were identified based on discussions with the Tribal elders. Identification of Tribal exposure factors (exposure pathways and contaminant concentrations) was essential for accurately assessing potential long-term Penobscot Indian Nation tribal members’ exposure. Based on this study, ATSDR’s Public Health Assessment (PHA) concluded that the Penobscot Indian Nation (PIN) tribal members who eat fish and snapping turtle at the ingestion levels suggested in the Wabanaki Traditional Cultural Lifeways Exposure Scenario Report (Wabanaki Exposure Scenario) may be exposed to harmful levels of mercury, dioxins/furans, dioxin-like PCBs, and ot

Maine↗
USGS2002

The central arctic caribou herd

From the mid-1970s through the mid-1980s, use of calving and summer habitats by Central Arctic herd caribou ( Rangifer tarandus granti ) declined near petroleum development infrastructure on Alaska's arctic coastal plain (Cameron et al. 1979; Cameron and Whitten 1980, Smith and Cameron 1983. Whitten and Cameron 1983a, 1985: Dau and Cameron 1986). With surface development continuing to expand westward from the Prudhoe Bay petroleum development area (Fig. 4.1), concerns arose that the resultant cumulative losses of habitat would eventually reduce productivity of the caribou herd. Specifically, reduced access of adult females to preferred foraging areas might adversely affect growth and fattening (Elison et al. 1986. Clough et al. 1987), in turn depressing calf production (Dauphiné 1976, Thomas 1982, Reimers 1983, White 1983, Eloranta and Nieminen 1986. Lenvik et al. 1988, Thomas and Kiliaan 1991) and survival (Haukioja and Salovaara 1978, Rognmo et al. 1983, Skogland 1984, Eloranta and Nieminen 1986, Adamczewski et al. 1987). Those concerns, though justified in theory, lacked empirical support. With industrial development in arctic Alaska virtually unprecedented, there was little basis for predicting the extent and duration of habitat loss, much less the secondary short- and long-term effects on the well-being of a particular caribou herd. Furthermore, despite a general acceptance that body condition and fecundity of the females are functionally related for reindeer and caribou, it seemed unlikely that any single model would apply to all subspecies of Rangifer , and perhaps not even within a subspecies in different geographic regions. We therefore lacked a complete understanding of the behavioral responses of arctic caribou to industrial development, the manner in which access to habitats might be affected, and how changes in habitat use might translate into measurable effects on fecundity and herd growth rate. Our study addressed the following objectives: 1) estimate variation in the size and productivity of the Central Arctic herd; 2) estimate changes in the distribution and movements of Central Arctic herd caribou in relation to the oil field development; 3) estimate the relationships between body condition and reproductive performance of female Central Arctic herd caribou, and 4) compare the body condition, reproductive success, and offspring survival of females under disturbance-free conditions (i.e., east of the Sagavanirktok River) with the status of those exposed to petroleum-related development (i.e., west of the Sagavanirktok River).

Alaska, Northwest Territories, Yukon Territory↗
USGS2025

Characterizing the scale of regional landslide triggering from storm hydrometeorology

Rainfall strongly affects landslide triggering; however, understanding how storm characteristics relate to the severity of landslides at the regional scale has thus far remained unclear, despite the societal benefits that would result from defining this relationship. As mapped landslide inventories typically cover a small region relative to a storm system, here we develop a dimensionless index for landslide-inducing rainfall, A * , based on extremes of modeled soil water relative to its local climatology. We calibrate A * using four landslide inventories, comprising over 11 000 individual landslides over four unique storm events, and find that a common threshold can be applied to estimate regional shallow-landslide-triggering potential across diverse climatic regimes in California (USA). We then use the spatial distribution of A * , along with topography, to calculate the landslide potential area (LPA) for nine landslide-inducing storm events over the past 20 years, and we test whether atmospheric metrics describing the strength of landfalling storms, such as integrated water vapor transport, correlate with the magnitude of hazardous landslide-inducing rainfall. We find that although the events with the largest LPA do occur during exceptional atmospheric river (AR) storms, the strength of landfalling atmospheric rivers does not scale neatly with landslide potential area, and even exceptionally strong ARs may yield minimal landslide impacts. Other factors, such as antecedent soil moisture driven by storm frequency and mesoscale precipitation features within storms, are instead more likely to dictate the patterns of landslide-generating rainfall throughout the state.

California↗
USGS2014

Crustal migration of CO2-rich magmatic fluids recorded by tree-ring radiocarbon and seismicity at Mammoth Mountain, CA, USA

Unrest at Mammoth Mountain over the past several decades, manifest by seismicity, ground deformation, diffuse CO 2 emissions, and elevated 3 He/ 4 He ratios in fumarolic gases has been driven by the release of CO 2 -rich fluids from basaltic intrusions in the middle to lower crust. Recent unrest included the occurrence of three lower-crustal (32–19 km depth) seismic swarms beneath Mammoth Mountain in 2006, 2008 and 2009 that were consistently followed by peaks in the occurrence rate of shallow (≤10 km depth) earthquakes. We measured 14 C in the growth rings (1998–2012) of a tree growing in the largest (∼0.3 km 2 ) area of diffuse CO 2 emissions on Mammoth Mountain (the Horseshoe Lake tree kill; HLTK) and applied atmospheric CO 2 concentration source area modeling to confirm that the tree was a reliable integrator of magmatic CO 2 emissions over most of this area. The tree-ring 14 C record implied that magmatic CO 2 emissions from the HLTK were relatively stable from 1998 to 2009, nearly doubled from 2009 to 2011, and then declined by the 2012 growing season. The initial increase in CO 2 emissions was detected during the growing season that immediately followed the largest (February 2010) peak in the occurrence rate of shallow earthquakes. Migration of CO 2 -rich magmatic fluids may have driven observed patterns of elevated deep, then shallow seismicity, while the relationship between pore fluid pressures within a shallow (upper 3 km of crust) fluid reservoir and permeability structure of the reservoir cap rock may have controlled the temporal pattern of surface CO 2 emissions.

California↗
USGS1949

Fourth special report of the Hawaiian Volcano Observatory of the U.S. Geological Survey and the Hawaiian Volcano Research Association: Steam blast volcanic eruptions: A study of Mount Pelée in Martinique as type volcano

The investigation is concerned with the author's expedition to Martinique and St. Vincent in 1902 and comparison of the experience of investigators and sufferers with that of others in so-called "explosive" eruptions. The Hawaiian mechanism is reviewed with special reference to rifts, underground water, intrusion furnace, wedge rupture, and lowering of magma. These features of structure are applied to Martinique, St. Vincent, Kilauea, Tarawera, Sakurajima, Katmai, Taal and Tomboro as a series of steam blasts old and new. The comparison is found to be applicable and the analogy with Hawaii considered as fundamentally magmatic for gas and basaltic slag, brings out the contrast that lies in steam eruptions. For all volcanoes they are believed features of ground water and of collapse. Ground water stimulates lava eruptions. The Pelée disaster at St. Pierre May 8, 1902, followed by a dacite dome with spines, which renewed activity in 1929, is examined for paroxysms of downblast. These are distinguished sharply from the Carib migratory upblasts along valley fissures which are not uncommon elsewhere. The valleys are on rifts recognized as deep fumaroles. The Ghyben-Herzberg laws of ground water are applicable. Geyser rhythm was followed by Pelée, Soufriére of St. Vincent, and Kilauea in their sequence of paroxysms. Structure sections are drawn to scale, and the structural reactions of intrusion, rifts, boiler, gas effervescence, heat, and timing are thus outlined. The bearing of this machinery on volcanism in general, on world ignisepta and on reaction of magma is suggested. It is contended that steamblast is a climax of eruption in the water zone and should be sharply delimited from the rising and intrusion of fundamental earth magma, and from the high pressure water reactions of ocean bottoms. Rising magma is considered an age-long elevatory force along volcanic lines, modified by cyclical yielding. Compared with oceanic volcanism continental irruption in sediments is a separate science in experimental field geophysics. Every locality supramarine or submarine of warm ground and steep thermal gradient is a subject for volcanology, if pulsating ground water is critically, thermally and chemically measured. Authors are referred to herein by names and dates in parentheses, as listed in the appendices.

Martinique↗
USGS2022

Sediment sources and sealed-pavement area drive polycyclic aromatic hydrocarbon and metal occurrence in urban streams

Metals and polycyclic aromatic hydrocarbons (PAHs) are common pollutants in urban streambed sediment, yet their occurrence is highly variable and difficult to predict. To investigate sources of PAHs and metals to streambed sediment, we sampled pavement dust, soil, and streambed sediment in 10 urban watersheds in three regions of the United States and applied a fallout-radionuclide-based sediment-source analysis to quantify the pavement dust contribution to stream sediment (%dust). We also mapped the area of sealcoated pavement in each watershed (%sealed) to investigate the role of coal-tar pavement sealant (CTS) as a PAH source. Median total and carbon-normalized total PAH concentrations were significantly higher in streambed sediment in the Northeast (54.3 mg/kg and 2.71 mg/gOC) and Southeast (5.37 mg/kg and 1.36 mg/gOC), where CTS is commonly used, than in the Northwest (2.11 mg/kg and 0.071 mg/gOC), where CTS is rarely used. Generalized additive models indicated that %sealed and in some cases %dust significantly affected total PAH concentrations in streambed sediments. The %dust was a significant variable for common urban metals: Cu, Pb, and Zn. These findings advance our quantitative understanding of the role of pavement dust as a source and a vector of contaminants to urban streams.

Georgia, New York, North Carolina, Oregon, Virgini↗
USGS2026

Optimizing cryo-focused pyrolysis GC/MS for tracing soil organic matter across diverse ecosystems

The cycling of organic matter in terrestrial soils and sediments is central to a range of biogeochemical processes that regulate nutrient cycling, crop productivity, trace gas emissions, and contaminant transport. Pyrolysis-gas chromatography/mass spectrometry (py-GC/MS) is a powerful tool for characterizing bulk soil organic matter (SOM) at the molecular level. In this study, we used a cryo-focused py-GC/MS system to analyze soil samples from seven diverse ecosystems: vernal pool, prairie pothole, temperate forest, tropical forest, tundra, wildfire-affected boreal forest, and grassland. We addressed a key bottleneck in molecular-level SOM characterization by developing an automated data analysis pipeline to optimize py-GC/MS and complementary evolved gas analysis/mass spectrometry (EGA/MS) methods, incorporating advanced tools for data deconvolution, developing a custom compound class library, and implementing fragmentation spectrum-based molecular networking for the first time. This improved workflow was applied to soil samples from all seven ecosystems, including multiple depths and density fractions. Our findings demonstrate that ecosystem type plays a dominant role in shaping compositional differences in SOM. We also identified trends in the source of SOM compounds (e.g., microbial vs. plant-derived) across soil depth and density fractions, which are critical for understanding persistence and turnover of SOM. Our molecular networking analysis indicated that although many compounds are widespread across ecosystems, others are restricted to specific environments, such as wetlands. This underscores the utility of molecular-level data in elucidating the complexity of SOM composition and the environmental drivers that shape it. Such molecular-level insights can deepen our knowledge of biogeochemical SOM cycles.

Environmental Science and Technology↗
USGS2013

Radiocarbon dating late Quaternary loess deposits using small terrestrial gastropod shells

Constraining the ages and mass accumulation rates of late Quaternary loess deposits is often difficult because of the paucity of organic material typically available for 14 C dating and the inherent limitations of luminescence techniques. Radiocarbon dating of small terrestrial gastropod shells may provide an alternative to these methods as fossil shells are common in loess and contain ∼12% carbon by weight. Terrestrial gastropod assemblages in loess have been used extensively to reconstruct past environmental conditions but have been largely ignored for dating purposes. Here, we present the results of a multi-faceted approach to understanding the potential for using small terrestrial gastropod shells to date loess deposits in North America. First, we compare highly resolved 14 C ages of well-preserved wood and gastropod shells (Succineidae) recovered from a Holocene loess section in Alaska. Radiocarbon ages derived from the shells are nearly identical to wood and plant macrofossil ages throughout the section, which suggests that the shells behaved as closed systems with respect to carbon for at least the last 10 ka (thousands of calibrated 14 C years before present). Second, we apply 14 C dating of gastropod shells to late Pleistocene loess deposits in the Great Plains using stratigraphy and independent chronologies for comparison. The new shell ages require less interpretation than humic acid radiocarbon ages that are commonly used in loess studies, provide additional stratigraphic coverage to previous dating efforts, and are in correct stratigraphic order more often than their luminescence counterparts. Third, we show that Succineidae shells recovered from historic loess in the Matanuska River Valley, Alaska captured the 20th century 14 C bomb spike, which suggests that the shells can be used to date late Holocene and historic-aged loess. Finally, results from Nebraska and western Iowa suggest that, similar to other materials, shell ages approaching ∼40 ka should be viewed with caution as they may reflect trace amounts of contamination. In sum, our results show that small terrestrial gastropod shells, especially from the Succineidae family, provide reliable ages for late Quaternary loess deposits in North America.

Quaternary Science Reviews↗
USGS2020

Combining models of the critical streakline and the cross-sectional distribution of juvenile salmon to predict fish routing at river junctions

Because fish that enter the interior Delta have poorer survival than those emigrating via the Sacramento River, understanding the mechanisms that drive entrainment rates at side channel junctions is critically important for the management of imperiled juvenile salmon. Here, we implement a previously proposed process-based conceptual model to study entrainment rates based on three linked elements: the entrainment zone, critical streakline, and cross-sectional distribution of fish. The critical streakline is the location along a channel cross-section immediately upstream of a junction that forms the spatial divide between parcels of water that enter a side channel or remain in the main channel. The critical streakline therefore divides the main channel into entrainment zones within which fish would likely enter each channel. Combined with information about the cross-sectional distribution of fish upstream of a junction, this conceptual model provides a means to predict fish entrainment into each channel. To apply this conceptual model, we combined statistical models of the critical streakline, the cross-sectional distribution of acoustic tagged juvenile Chinook salmon, and their probability of entrainment into Georgiana Slough. We fit joint beta regression and logistic regression models to acoustic telemetry data gathered in 2011 and 2012 to estimate the cross-sectional distribution of fish upstream of the junction, and to estimate the probability of entrainment for fish on either side of the critical streakline. We show that entrainment rates can be predicted by understanding how the combination of critical streakline position and cross-sectional distribution of fish co-vary as a function of environmental covariates. By integrating over individual positions and entrainment fates to arrive at population-level entrain probability in relation to environmental covariates, our model offers managers a simple but powerful tool to evaluate how alternative actions affect migrating fish.

California↗
USGS2000

Importance of the Mississippi River Basin for investigating agricultural–chemical contamination of the hydrologic cycle

This special issue is devoted to recent and ongoing research relating to the fate and transport of agricultural chemicals in the Mississippi River Basin by the US Geological Survey Toxic Substances Hydrology (Toxics) Program. The Mississippi River Basin drains approximately 3 200 000 km 2 representing 41% of the United States. This is the largest river in the United States and the third largest in the world. The Mississippi River discharges an average of 19 920 m 3 /s of water into the Gulf of Mexico. The river is an extensively used resource, supplying drinking water to 70 cities in the United States. The Mississippi River Basin has undergone dramatic land use and cultural changes over the last 150 years. Approximately 70 million people now live within the basin, representing approximately 27% of the nation's population. This basin has also become one of the most productive agricultural regions in the world in terms of both crops and livestock grown. Approximately 65% of the nation's harvested cropland is grown in this basin, with more than 100 000 metric tons (t) of pesticides and approximately 6 500 000 t of commercial nitrogen fertilizers applied to cropland within the basin annually. The drainage of more than 20 000 000 ha within the basin has been enhanced by means of tile lines and ditches to lower the water table to make the cropland more productive. While removing the water from the soil as intended, this practice also leads to more rapid transport of contaminants to the river, and ultimately the Gulf of Mexico. Furthermore, the extensive chemical use in the Mississippi River Basin has led to the transport of pesticides and nitrate into the region’s streams, aquifers, and atmosphere. An estimated 1 000 000 t of nitrate-N is transported from the Mississippi River Basin into the Gulf of Mexico annually. The peak annual load of herbicides to the Gulf of Mexico has been documented at 1920 t. The fundamental goal of the papers presented in this volume is to provide a scientific basis for decisions necessary to promote sound and efficient agricultural practices and protect the quality of the nation's water resources.

Science of the Total Environment↗