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Arc-related porphyry molybdenum deposit model

This report provides a descriptive model for arc-related porphyry molybdenum deposits. Presented within are geological, geochemical, and mineralogical characteristics that differentiate this deposit type from porphyry copper and alkali-feldspar rhyolite-granite porphyry molybdenum deposits. The U.S. Geological Survey's effort to update existing mineral deposit models spurred this research, which is intended to supplement previously published models for this deposit type that help guide mineral-resource and mineral-environmental assessments. Arc-related porphyry molybdenum deposits are a substantial resource for molybdenum metal and may have anomalous concentrations of tungsten. The deposits contain low-grade ore (0.03-0.22 percent molybdenum) as molybdenite, but are large-tonnage, making them amenable to bulk mining open-pit techniques. The mineralizing system usually has fluorine contents of less than 0.1 percent. The cogenetic intrusion is a differentiated calc-alkaline granitoid, typically granodiorite to quartz monzonite in composition, with low rubidium and niobium, and moderate to high strontium concentrations. Metals and hydrothermal fluids are sourced from these intrusions, with an additional meteoric fluid component contributing to peripheral alteration but not adding more metal. The lithology of the surrounding country rocks is not important to the formation of these deposits, but a surrounding carbonate unit may be altered to skarn that contains economic mineralization. The creation of contact-metamorphosed hornfels adjacent to the intrusion is common. Formation of arc-related porphyry molybdenum deposits typically occurs within a continental arc environment related to arc-continent or continent-continent collision and subduction. Few deposits are found in an island arc setting. Most classified arc-related porphyry molybdenum deposits are located in the western cordillera of North America, notably in British Columbia and Alaska. Hydrothermal alteration provides a key component to the identification of a deposit. Alteration usually is zoned from a core of potassic plus/minus silicic alteration outwards through phyllic to propylitic alteration. Argillic alteration may be irregular in shape and will overprint earlier hydrothermal alteration. Exploration should be limited to magmatic arc belts that have been unroofed and eroded to levels of a few kilometers depth. Important geological vectors toward areas of higher grade mineralization include intensity of hydrothermal alteration, veining, and faulting. Anomalous levels of molybdenum, tungsten, copper, lead, or zinc in soils, tills, stream sediments, and drainage waters may indicate the presence of an arc-related porphyry molybdenum deposit. Geophysical exploration techniques have been met with minimal success because of the overall low concentration of associated sulfide and oxide minerals. Geoenvironmental concerns are generally low because of low volumes of sulfide minerals. Most deposits are marginally acid-generating to non-acid-generating with drainage waters being near-neutral pH because of the acid generating potential of pyrite being partially buffered by late-stage calcite-bearing veins. The low ore content results in a waste:ore ratio of nearly 1:1 and large tailings piles from the open-pit method of mining.

Scientific Investigations Report↗

Provenance of Holocene sediment on the Chukchi-Alaskan margin based on combined diffuse spectral reflectance and quantitative X-Ray Diffraction analysis

Sediment clay and silt mineral assemblages provide an excellent means of assessing the provenance of fine-grained Arctic sediment especially when a unique mineral assemblage can be tied to specific source areas. The diffuse spectral reflectance (DSR) first derivative measurements and quantitative X-Ray Diffraction (qXRD) on a high-resolution sediment core from the continental slope north of Alaska constrain the sediment mineralogy. DSR results are augmented by measurements on several adjacent cores and compared to surface sediment samples from the northern Alaskan shelf and slope. Using Principal Component Analysis (PCA), we infer that the three leading DSR modes relate to mixtures of smectite + dolomite, illite + goethite, and chlorite + muscovite. This interpretation is consistent with the down core qXRD results. While the smectite + dolomite, and illite + goethite factors show increased variability down core, the chlorite + muscovite factor had highest positive loadings in the middle Holocene, between ca. 6.0 and 3.6??ka. Because the most likely source of the chlorite + muscovite suite in this vicinity lies in the North Pacific, we argue that the oscillations in chlorite + muscovite values likely reflect an increase in the inflow of Pacific water to the Arctic through the Bering Strait. The time interval of this event is associated in other parts of the globe with a non-linear response of the climate system to the decrease in insolation, which may be related to changes in water exchange between the Pacific and Arctic Ocean. ?? 2009 Elsevier B.V.

Global and Planetary Change↗

Bokan Mountain peralkaline granitic complex, Alexander terrane (southeastern Alaska): evidence for Early Jurassic rifting prior to accretion with North America

The circular Bokan Mountain complex (BMC) on southern Prince of Wales Island, southernmost Alaska, is a Jurassic peralkaline granitic intrusion about 3 km in diameter that crosscuts igneous and metasedimentary rocks of the Alexander terrane. The BMC hosts significant rare metal (rare earth elements, Y, U, Th, Zr, and Nb) mineralization related to the last stage of BMC emplacement. U–Pb (zircon) and 40 Ar/ 39 Ar (amphibole and whole-rock) geochronology indicates the following sequence of intrusive activity: ( i ) a Paleozoic basement composed mainly of 469 ± 4 Ma granitic rocks; ( ii ) intrusion of the BMC at 177 ± 1 Ma followed by rapid cooling through ca. 550 °C at 176 ± 1 Ma that was synchronous with mineralization associated with vertical, WNW-trending pegmatites, felsic dikes, and aegirine–fluorite veins and late-stage, sinistral shear deformation; and ( iii ) intrusion of crosscutting lamprophyre dikes at >150 Ma and again at ca. 105 Ma. The peralkaline nature of the BMC and the WNW trend of associated dikes suggest intrusion during NE–SW rifting that was followed by NE–SW shortening during the waning stages of BMC emplacement. The 177 Ma BMC was synchronous with other magmatic centres in the Alexander terrane, such as (1) the Dora Bay peralkaline stock and (2) the bimodal Moffatt volcanic suite located ∼30 km north and ∼100 km SE of the BMC, respectively. This regional magmatism is interpreted to represent a regional extensional event that precedes deposition of the Late Jurassic – Cretaceous Gravina sequence that oversteps the Wrangellia and Alexander exotic accreted terranes and the Taku and Yukon–Tanana pericratonic terranes of the Canadian–Alaskan Cordillera.

Alaska↗

Evidence for offset of Cretaceous plutons by the Tintina fault in eastern Alaska: Implications for regional metallogeny

Cretaceous magmatism in eastern interior Alaska is voluminous, but temporally and spatially diverse – suggestive of varying sources and drivers. More than 150 new U-Pb zircon and more than 500 geochemical analyses of Cretaceous plutonic units allow for the grouping of distinct plutonic suites. Magmatism was continuous from 120-66 Ma but can be grouped into temporally distinct pulses from ca. 115-100 Ma, 100-90 Ma, and 75-66 Ma. Geochemical diversity occurs during each pulse, further distinguishing multiple suites. Diverse metallogenic epochs are strongly correlated to pluton chemistry. Mineralization is largely absent prior to 108 Ma. From 108-100 Ma, plutonism is coeval with sparse, but notable Au-quartz veins with variable Bi, As, W, and Mo. From 100-90 Ma, intrusion-related mineralization zones from Au-Cu(-Bi) and U-Th in the northwest to central Au- Bi-As-Te(-W), and Mo-W to the southeast. Porphyry style Cu-Mo(-Au) occurrences occur with the latest Cretaceous plutons emplaced from 75-66 Ma . Restoration of ~450 km of dextral movement on the Tintina fault and comparison of metallogenic and geochemical characteristics of Alaska plutons suggest 100-90 Ma plutons may be the continuation of the metallogenically significant Tombstone, Mayo, and Tungsten suites from the Yukon.

Alaska↗

Tracer-based evidence of heterogeneity in subsurface flow and storage within a boreal hillslope

Runoff from boreal hillslopes is often affected by distinct soil boundaries, including the frozen boundary and the organic – mineral boundary (OMB), where highly porous and hydraulically-conductive organic material overlies fine-grained mineral soils. Viewed from the surface, ground cover appears as a patchwork on sub-meter scales, with thick, moss mats interspersed with lichen-covered, silty soils with gravel inclusions. We conducted a decameter-scale subsurface tracer test on a boreal forest hillslope in interior Alaska to quantify locations and mechanisms of transport and storage in these soils, focusing on the OMB. A sodium bromide tracer was added as a slug addition to a pit and sampled at 40 down-gradient wells, screened primarily at the OMB and within a 7 by 12 m well field. We maintained an elevated head in the injection pit for 8.5 h to simulate a storm. Tracer breakthrough velocities ranged from < 0.12 to 0.93 m hr-1, with the highest velocities in lichen-covered soils. After 12 hours and cessation of the elevated head, the tracer coalesced and was only detected in thick mosses at a trough in the OMB. By 24 hours, approximately 17% of the tracer mass could be accounted for. The majority of the mass loss occurred between 4 and 12 hours, while the tracer was in contact with lichen-covered soils, which is consistent with tracer transport into deeper flow paths via preferential flow through discrete gravelly areas. Slow breakthroughs suggest that storage and exchange also occurred in shallow soils, likely related to saturation and drainage in fine-grained mineral soils caused by the elevated hydraulic head. These findings highlight the complex nature of storage and transmission of water and solutes from boreal hillslopes to streams, and are particularly relevant given rapid changes to boreal environments related to climate change, thawing permafrost and increasing fire severity.

Hydrological Processes↗

Tectonic and magmatic controls on the metallogenesis of porphyry deposits in Alaska

Porphyry Cu and Mo deposits and occurrences are found throughout Alaska; they formed episodically during repeated subduction and arc-continent collisions spanning the Silurian to Quaternary. Porphyry systems occur in continental-margin and island arcs, which are broadly grouped into pre-accretionary or post-accretionary arcs. Pre-Mesozoic occurrences formed in continental or island arcs prior to accretion onto the margin of North America, whereas Mesozoic and younger systems formed in arcs that developed after terrane fragments were accreted to the margin of North America. As a result, older porphyry systems are typically in the interior and northern metallogenic belts, whereas the younger porphyry systems are predominantly found in the southern third of the state, closer to the modern continental margin. Alaska porphyry formation peaked in the mid-Cretaceous and continued through the Late Cretaceous to Tertiary, in association with continental-margin arcs extending from the eastern interior, into southwest Alaska and along the Alaska Peninsula and Aleutian Islands. Porphyry system formation is not generally recognized in the Early Cretaceous, Triassic, or early Paleozoic – time periods that coincide with continental collisional events or extension. Relatively few pre-accretionary porphyry systems are documented in more deeply exhumed arc segments due to low preservation potential in areas of rapid or repeated bedrock uplift and associated erosion that occurred during later tectonic events. Significant diversity is observed in porphyry occurrences across the state and even within the same region. Occurrences form in association with arc-related intrusions or intrusive complexes, that range in composition from diorite to syenite, but are commonly monzonitic to granitic. Some porphyry occurrences are associated with alkaline intrusive belts that exhibit a stronger crustal contribution to magmatic sources. Intrusions associated with porphyry formation in Alaska are commonly moderately oxidized, however, a distinct group of porphyry systems are associated with more-reduced magmas. Hydrothermal alteration described at many occurrences exhibits zoning from proximal potassic alteration to typically peripheral and(or) later sericitic alteration, that is flanked by large zones of propylitic alteration. Diversity in alteration is observed where sodic and sodic-calcic alteration is present, commonly in more-enigmatic deposits, such as Island Mountain and Chicken Mountain. Advanced argillic alteration is rare, but present in notable examples, such as the Pebble porphyry Cu(-Au-Mo) deposit. Sulfide mineralization is characterized by pyrite, chalcopyrite, molybdenite, and rare bornite hosted in veinlets, veins and disseminations in wallrocks and causative intrusions. Some porphyry systems contain abundant pyrrhotite and(or) arsenopyrite in the mineral assemblages. Systems that exhibit bornite-bearing assemblages containing abundant molybdenite are commonly arsenic- and gold-poor and tend to be associated with more oxidized arc magmas. In contrast, those systems that are pyrrhotite and(or) arsenopyrite dominant tend to be gold, arsenic, and bismuth bearing, and are commonly associated with more-reduced magmas. Exploration for porphyry occurrences in Alaska has experienced a resurgence and currently constitutes about 20% of exploration dollars in the state. Many systems lack complete descriptions, and coupled with the cost of exploration, remain incompletely explored. Additional understanding of known occurrences combined with a framework geologic understanding of porphyry-bearing metallogenic belts will likely result in new discoveries in the future.

Alaska↗

Synergy between geology and geophysics in graphite mineral resource assessment

Graphite is designated as a critical mineral by the U.S. Government due to its essential role in modern technology and its vulnerability to supply chain disruption. To evaluate domestic graphite resources, the U.S. Geological Survey (USGS) conducted two airborne electromagnetic (AEM) surveys as part of the Earth Mapping Resources Initiative (Earth MRI) over prospective areas in the southern Appalachians of Alabama and the Seward Peninsula of Alaska. These surveys aimed to refine areas of interest by revealing subsurface electrical resistivity patterns indicative of graphite-bearing rocks. The results of the AEM surveys were integrated with existing geological knowledge and supplemented by field observations to assess the likelihood of undiscovered resources in these regions. This multidisciplinary approach combined geophysical techniques with traditional geological methods, enhancing the understanding of graphite potential in areas that may have been previously overlooked. The findings from this initiative are expected to contribute significantly to the ongoing efforts to secure a reliable domestic supply of graphite, thereby reducing import reliance and supporting national interests in mineral resource management.

Conference Paper↗

Geologic Field Notes, Geochemical Analyses, and Field Photographs of Outcrops and Rock Samples from the Big Delta B-1 Quadrangle, East-Central Alaska

The U.S. Geological Survey, in cooperation with the Alaska Department of Natural Resources Division of Mining, Land, and Water, has released a geologic map of the Big Delta B-1 quadrangle of east-central Alaska (Day and others, 2007). This companion report presents the major element oxide and trace element geochemical analyses, including those for gold, silver, and base metals, for representative rock units and for grab samples from quartz veins and mineralized zones within the quadrangle. Also included are field station locations, field notes, structural data, and field photographs based primarily on observations by W.C. Day with additions by J.M. O'Neill and B.M. Gamble, all of the U.S. Geological Survey. The data are provided in both Microsoft Excel spread sheet format and as a Microsoft Access database.

Open-File Report↗

Selected field data collected in 1975, northeastern Craig Quadrangle, southeastern Alaska

This report consists of a computer printout of geologic field data recorded by H.C. Berg from July 2 to July 20, 1975 in the part of the Craig (CR) 1:250,000-scale quadrangle northeast of Clarence Strait (figs. 1 and 2). It contains edited and revised observations on structure, lithology, mineralogy, metamorphism, and mineral occurrences. Areas covered by the observations include southern Etolin and adjacent islands and part of Cleveland Peninsula, including 5 sites in the Ketchikan (KC) quadrangle immediately adjacent to the Craig quadrangle (fig. 2). A preliminary geologic map incorporating the data has been released (Berg and others, 1976). The printout includes the latitude-longitude coordinates of each field station, so that the user can locate the observations within a few metres on larger-scale topographic maps than figure 2. The purpose of this report is to provide an organized file of detailed field observations to supplement and amplify a companion geologic map. The combined reports thus constitute a complete record of available information to serve as wide a range of potential users as possible. The information in this report was transferred from geologic fieldsheets (fig. 3) to computer storage using the method described by Hudson and others (1975). A. Marianne Fujii transcribed the data from the fieldsheets; Betsy Yount and Frances Wahl helped to update the computer file and prepare it for publication; and Bruce Salem wrote the interactive computer program that greatly facilitated entry of the fieldnotes into the computer file.

Alaska↗

Geochemistry and exploration criteria for epithermal cinnabar and stibnite vein deposits in the Kuskokwim River region, southwestern Alaska

Cinnabar- and stibnite-bearing epithermal vein deposits are found throughout the Kuskokwim River region of southwestern Alaska. A geochemical orientation survey was carried out around several of these epithermal lodes to obtain information for planning regional geochemical surveys and to develop procedures which maximize the anomaly: threshold contrast of the deposits. Stream sediment, heavy-mineral concentrate, stream water, and vegetation samples were collected in drainages surrounding the Red Devil, Cinnabar Creek, White Mountain, Rhyolite, and Mountain Top deposits. Three sediment size fractions; nonmagnetic, paramagnetic and magnetic splits of the concentrate samples; stream waters; and the vegetation samples were analyzed for multi-element suites by a number of different chemical procedures. Nonmagnetic, heavy-mineral concentrates were also examined microscopically to identify their mineralogy.

Journal of Geochemical Exploration↗

Contributions to economic geology (short papers and preliminary reports), 1915: Part I. - metals and nonmetals except fuels

This volume is the thirteenth of a series that includes Bulletins 213, 225, 260, 285, 315, 340, 380, 430, 470, 530, 540, and 580, "Contributions to economic geology" for 1902, 1903, 1904, 1905, 1906 (Pt. I), 1907 (Pt. I), 1908 (Pt. I), 1909 (Pt. I), 1910 (P t. I), 1911 (Pt. I) , 1912 (Pt. I), and 1913 (Pt. I), respectively . These bulletins are prepared primarily to insure prompt publication of the economic results of investigations made by the United States Geological Survey. Beginning with the present volume the year included in the title will be the year of publication 1 instead of the year in which the field work reported was done. This volume is therefore dated 1915, and there will be no volume entitled "Contributions to economic geology, 1914." As the subtitle indicates, the papers included are of two classes -(1) short papers giving comparatively detailed description of occurrences that have economic interest but are not of sufficient importance to warrant a more extended description; (2) preliminary reports on economic investigations the results of which are to be published later in more detailed form. These papers are such only as have a direct economic bearing, all topic of purely scientific interest being excluded. Each paper has been issued as an advance chapter as soon as it was ready. Brief abstracts of the publications of the year are given in the annual report of the Director. The complete list of Survey publications affords, by means of finding list of subjects and of authors, further aid in ascertaining the extent of the Survey's work in economic geology. Since 1905 the annual economic bulletin has been printed in two parts, the second part comprising paper on mineral fuels. These volumes for 1906, 1907, 190 , 1909, 1910, 1911, 1912, and 1913 are Bulletins 316, 341, 381, 431, 471, 531, 541, and 581. Bulletin 621 forms Part II of the "Contributions" for 1915. The reports on work in Alaska have been printed in a separate series since 1904, the volume so far issued being Bulletins 259, 284, 314, 345, 379, 442, 480, 520, 542, 592, and 622.

Bulletin↗

Histograms and correlation table for selected elements in samples of the ash of black spruce needles from the Tanacross Quadrangle, Alaska

These histograms and correlation table show the distribution and abundance of, and correlations between, the populations of 21 elements in the ash of black spruce (Picea Mariana B.S.P.) needles collected throughout most of the Tanacross 1:250,000-scale quadrangle. The samples were collected during reconnaissance geochemical studies as part of the U.S. Geological Survey's Alaskan Mineral Resource Assessment Program. Related data for black spruce are presented in other reports (Day, Curtin, and Tripp, 1979 a,b,c) , and background information on the mineral resource assessment of the Tanacross quadrangle is presented in a U.S. Geological Survey Circular (Foster and others, 1976).

Alaska↗

USGS exploration geochemistry studies at the Pebble porphyry Cu-Au-Mo deposit, Alaska— Pdf of presentation

From 2007 through 2010, scientists in the U.S. Geological Survey (USGS) have been conducting exploration-oriented geochemical and geophysical studies in the region surrounding the giant Pebble porphyry Cu-Au-Mo deposit in southwestern Alaska. The Cretaceous Pebble deposit is concealed under tundra, glacial till, and Tertiary cover rocks, and is undisturbed except for numerous exploration drill holes. These USGS studies are part of a nation-wide research project on evaluating and detecting concealed mineral resources. This report focuses on exploration geochemistry and comprises illustrations and associated notes that were presented as a case study in a workshop on this topic. The workshop, organized by L.G. Closs and R. Glanzman, is called 'Geochemistry in Mineral Exploration and Development,' presented by the Society of Economic Geologists at a technical conference entitled 'The Challenge of Finding New Mineral Resources: Global Metallogeny, Integrative Exploration and New Discoveries,' held at Keystone, Colorado, October 2-5, 2010.

Alaska↗

Geology and origin of epigenetic lode gold deposits, Tintina Gold Province, Alaska and Yukon

More than 50 million ounces of lode gold resources have been defined in the previous 15 years throughout accreted terranes of interior Alaska and in adjacent continental margin rocks of Yukon. The major deposits in this so-called Tintina Gold Province formed around 105 to 90 million years ago in east-central Alaska and Yukon, and around 70 million years ago in southwestern Alaska, late in the deformational history of their host rocks. All gold deposits studied to date formed from CO 2 -rich and 18 O-rich crustal fluids, most commonly of low salinity. The older group of ores includes the low-grade intrusion-related gold systems at Fort Knox near Fairbanks and those in Yukon, with fluids exsolved from fractionating melts at depths of 3 to 9 kilometers and forming a zoned sequence of auriferous mineralization styles extending outward to the surrounding metasedimentary country rocks. The causative plutons are products of potassic mafic magmas generated in the subcontinental lithospheric mantle that interacted with overlying lower to middle crust to generate the more felsic ore-related intrusions. In addition, the older ores include spatially associated, high-grade, shear-zonerelated orogenic gold deposits formed at the same depths from upward-migrating metamorphic fluids; the Pogo deposit is a relatively deep-seated example of such. The younger gold ores, restricted to southwestern Alaska, formed in unmetamorphosed sedimentary rocks of the Kuskokwim basin within 1 to 2 kilometers of the surface. Most of these deposits formed via fluid exsolution from shallowly emplaced, highly evolved igneous complexes generated mainly as mantle melts. However, the giant Donlin Creek orogenic gold deposit is a product of either metamorphic devolatilization deep in the basin or of a gold-bearing fluid released from a flysch-melt igneous body.

Alaska, Yukon↗

Results of elemental and stable isotopic measurements, and dietary composition of Arctic grayling (Thymallus arcticus) collected in 2000 and 2001 from the Fortymile River Watershed, Alaska

We report the results of the elemental and stable isotopic analyses, as well as the composition of stomach contents, of Arctic grayling (Thymallus arcticus), an ecologically important resident freshwater sport and subsistence fish in the Fortymile River Mining District of the Interior Highlands Ecoregion in eastern Alaska. These data are presented here as a data compilation with minimal interpretation or discussion. Further analyses of the data will be presented elsewhere. The study area has been mined for placer gold for over a century and is currently experiencing renewed mineral exploration activity. The results for the analysis of 40 inorganic elements are reported for grayling muscle (fillet) tissue, liver tissue, and stomach contents from 34 individuals caught at 11 sites within the watershed. The 11 sites were classified as occurring within the following lithologies: metavolcanic (7 sites), metasedimentary (3 sites), and granitic intrusion (1 site). This information (along with fish tissue stable isotope data) is critical in the assessment of the influence of regional lithology on the fish chemical composition, especially the trace metal content. We report the nitrogen, carbon, and sulfur stable isotope composition of muscle samples. Nitrogen isotopes appear homogeneous (d15N = 7.6 to 9.7 permil) whereas carbon and sulfur isotope compositions of the same samples span a range from d 13C = ?33.1 to ?25.8 permil, and d 34S = ?8.4 to 8.2 permil. Stomach content material was examined for the occurrence and frequency of macroinvertebrate composition and diversity in three individual fish. Results showed a high degree of diversity with 9 to 15 invertebrate taxa; both aquatic and terrestrial forms were represented.

Open-File Report↗

Aqueous geochemical data from the analysis of stream-water samples collected in June and July 2005 — Taylor Mountains 1:250,000 scale quadrangle, Alaska

We report on the chemical analysis of water samples collected from the Taylor Mountains 1:250,000-scale quadrangle. Parameters for which data are reported include pH, conductivity, water temperature, major cation and anion concentrations, trace-element concentrations, and dissolved organic-carbon concentrations. Samples were collected as part of a multiyear U.S. Geological Survey project "Geologic and Mineral Deposit Data for Alaskan Economic Development." Data presented here are from samples collected in June and July of 2005. The data are being released at this time with minimal interpretation. This is the second release of aqueous geochemical data from this project; 2004 aqueous geochemical data were published previously ( Wang and others, 2006 ). The data in this report augment but do not duplicate or supersede the previous data release. Site selection was based on a regional sampling strategy that focused on first- and second-order drainages. Water sample site selection was based on landscape parameters that included physiography, wetland extent, lithological changes, and a cursory field review of mineralogy from pan concentrates. Stream water in the Taylor Mountians quadrangle is dominated by bicarbonate (HCO 3- ), though in a few samples more than 50 percent of the anionic charge can be attributed to sulfate (SO 4 2- ). The major-cation chemistry ranges from Ca 2+ /Mg 2+ dominated to a mix of Ca 2+ /Mg 2+ /Na + +K + . In general, good agreement was found between the major cations and anions in the duplicate samples. Many trace elements in these samples were at or near the analytical method detection limit, but good agreement was found between duplicate samples for elements with detectable concentrations. With the exception of a total mercury concentration of 0.33 ng/L detected in a field blank, field blank major-ion and trace-elements concentrations were below detection.

Alaska↗

Aqueous geochemical data from the analysis of stream-water samples collected in June and July 2006 — Taylor Mountains 1:250,000-scale quadrangle, Alaska

We report on the chemical analysis of water samples collected from the Taylor Mountains 1:250,000-scale quadrangle, Alaska. Parameters for which data are reported include pH, conductivity, water temperature, major cation and anion concentrations, trace-element concentrations, and dissolved organic-carbon concentrations. Samples were collected as part of a multiyear U.S. Geological Survey project entitled ?Geologic and Mineral Deposit Data for Alaskan Economic Development.? Data presented here are from samples collected in June and July 2006. The data are being released at this time with minimal interpretation. This is the third release of aqueous geochemical data from this project; aqueous geochemical data from samples collected in 2004 and 2005 were published previously. The data in this report augment but do not duplicate or supersede the previous data release. Site selection was based on a regional sampling strategy that focused on first- and second-order drainages. Water sample site selection was based on landscape parameters that included physiography, wetland extent, lithological changes, and a cursory field review of mineralogy from pan concentrates. Stream water in the Taylor Mountains quadrangle is dominated by bicarbonate (HCO3-), although in a few samples more than 50 percent of the anionic charge can be attributed to sulfate (SO42-). The major-cation chemistry ranges from Ca2+/Mg2+ dominated to a mix of Ca2+/Mg2+/Na++K+. Generally, good agreement was found between the major cations and anions in the duplicate samples. Many trace elements in these samples were at or near the analytical method detection limit, but good agreement was found between duplicate samples for elements with detectable concentrations. All field blank major-ion and trace-element concentrations were below detection.

Alaska↗

Progressive metamorphism of schists recovered from a deep drill hole near Fairbanks, Alaska

In 1965, a deep test hole drilled near Eielson Air Force Base, Fairbanks district, Alaska, penetrated 9,774 ft (2,979.1 m) into schists of the metamorphic complex of the Yukon-Tanana Upland. Cores recovered from the test hole show that the section is dominated by calc-magnesian rocks with subordinate pelitic schists. Pelitic mineral assemblages define a progressive increase in metamorphic grade with depth, from the garnet to the kyanite isograd. Diopside first appears in the calc-magnesian schists that were cored at a depth of 9,766 ft (2,976.5 m), indicating the onset of the reaction: Tremolite + 3 calcite -f- 2 quartz→5 diopside + 3CO 2 +H 2 O. Ubiquitous staurolite and rare andalusite occur in the kyanite-bearing pelitic schists. Andalusite appears to have crystallized under postkinematic conditions, and the staurolite is apparently of both synkinematic and postkinematic origin. Hornblende and biotite from calc-magnesian schists sampled at depths of 7,142½ ft (2,176.9 m) and 9,766 ft (2,976.5 m) gave 40 K/ 40 Ar ages of 140±8 and 57.3±1.9 m.y., respectively. The hornblende age is believed to represent the age of the latest synkinematic metamorphism, and the biotite age appears to be an anomalously young one related to the outgassing of argon from biotite at greater depth in the section. Recent experimental data on andalusite-kyanite-sillimanite and staurolite equilibria and the stability field of calcite+quartz+tremolite versus diopside in calc-magnesian rocks suggest that the rocks recovered from the 8,218- to 9,770-ft (2,504.7- to 2,977.7-m) interval were synkinematieally recrystallized at crustal depths of 17 to 19 km and at temperatures of 515° to 580°C; the present thermal gradient (31.5°C/km) is similar to that which accompanied metamorphism in Jurassic time.

Alaska↗