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At least 865 records · Page 48Linked to original sources
USGS2013

Application of the Precipitation-Runoff Modeling System (PRMS) in the Apalachicola-Chattahoochee-Flint River Basin in the southeastern United States

A hydrologic model of the Apalachicola–Chattahoochee–Flint River Basin (ACFB) has been developed as part of a U.S. Geological Survey (USGS) National Climate Change and Wildlife Science Center effort to provide integrated science that helps resource managers understand the effect of climate change on a range of ecosystem responses. The hydrologic model was developed as part of the Southeast Regional Assessment Project using the Precipitation Runoff Modeling System (PRMS), a deterministic, distributed-parameter, process-based system that simulates the effects of precipitation, temperature, and land use on basin hydrology. The ACFB PRMS model simulates streamflow throughout the approximately 50,700 square-kilometer basin on a daily time step for the period 1950–99 using gridded climate forcings of air temperature and precipitation, and parameters derived from spatial data layers of altitude, land cover, soils, surficial geology, depression storage (small water bodies), and data from 56 USGS streamgages. Measured streamflow data from 35 of the 56 USGS streamgages were used to calibrate and evaluate simulated basin streamflow; the remaining gage locations were used for model delineation only. The model matched measured daily streamflow at 31 of the 35 calibration gages with Nash-Sutcliffe Model Efficiency Index (NS) greater than 0.6. Streamflow data for some calibration gages were augmented for regulation and water use effects to represent more natural flow volumes. Time-static parameters describing land cover limited the ability of the simulation to match historical runoff in the more developed subbasins. Overall, the PRMS simulation of the ACFB provides a good representation of basin hydrology on annual and monthly time steps. Calibration subbasins were analyzed by separating the 35 subbasins into five classes based on physiography, land use, and stream type (tributary or mainstem). The lowest NS values were rarely below 0.6, whereas the median NS for all five classes was within 0.74 to 0.96 for annual mean streamflow, 0.89 to 0.98 for mean monthly streamflow, and 0.82 to 0.98 for monthly mean streamflow. The median bias for all five classes was within –4.3 to 0.8 percent for annual mean streamflow, –6.3 to 0.5 percent for mean monthly streamflow, and –9.3 to 1.3 percent for monthly mean streamflow. The NS results combined with the percent bias results indicated a good to very good streamflow volume simulation for all subbasins. This simulation of the ACFB provides a foundation for future modeling and interpretive studies. Streamflow and other components of the hydrologic cycle simulated by PRMS can be used to inform other types of simulations; water-temperature, hydrodynamic, and ecosystem-dynamics simulations are three examples. In addition, possible future hydrologic conditions could be studied using this model in combination with land cover projections and downscaled general circulation model results.

Alabama, Florida, Georgia↗
USGS2024

Characteristics of debris-flow-prone watersheds and debris-flow-triggering rainstorms following the Tadpole Fire, New Mexico, USA

Moderate- or high-severity fires promote increases in runoff and erosion, leading to a greater likelihood of extreme geomorphic responses, including debris flows. In the first several years following fire, the majority of debris flows initiate when runoff rapidly entrains sediment on steep slopes. From a hazard perspective, it is important to be able to anticipate when and where watershed responses will be dominated by debris flows rather than flood flows. Rainfall intensity averaged over a 15 min duration, I 15 , in particular, has been identified as a key predictor of debris flow likelihood. Developing effective warning systems and predictive models for post-fire debris flow hazards therefore relies on high-temporal resolution rainfall data at the time debris flows initiate. In this study, we documented the geomorphic response of a series of watersheds following a wildfire in western New Mexico, USA, with an emphasis on constraining debris flow timing within rainstorms to better characterize debris-flow-triggering rainfall intensities. We estimated temporal changes in soil hydraulic properties and ground cover in areas burned at different severities over >2 years to offer explanations for observed differences in spatial and temporal patterns in debris flow activity. We observed 16 debris flows, all of which initiated during the first several months following the fire. The average recurrence interval of the debris-flow-triggering I 15 is 1.3 years, which highlights the susceptibility of recently burned watersheds to runoff-generated debris flows in this region. All but one of the debris flows initiated in watersheds burned primarily at moderate or high soil burn severity. Since soil hydraulic properties appeared to be relatively resilient to burning, we attribute reduced debris flow activity at later times to decreases in the fraction of bare ground. Results provide additional constraints on the rainfall characteristics that promote post-fire debris flow initiation in a region where fire size and severity have been increasing.

New Mexico↗
USGS2019

Human-induced and natural carbon storage in floodplains of the Central Valley of California

Active floodplains can putatively store large amounts of organic carbon (SOC) in subsoils originating from catchment erosion processes with subsequent floodplain deposition. Our study focussed on the assessment of SOC pools associated with alluvial floodplain soils that are affected by human-induced changes in floodplain deposition and in situ SOC mineralisation due to land use change and drainage. We evaluated depth-dependent SOC contents based on 23 soil cores down to 3 m and 10 drillings down to 7 m in a floodplain area of the lower Cosumnes River. An estimate of 266 Mg C ha −1 or about 59% of the entire SOC stored within the 7 m profiles was found in the upper 2 m. Most profiles (n = 25) contained discrete buried A horizons at depths of approximately 0.8 m. These profiles had up to 130% higher SOC stocks. The mean δ 13 C of all deep soil profiles clearly indicated that arable land use has already altered the stable isotopic signature in the first meter of the profile. Radiocarbon dating showed that the 14 C age in the buried horizon was younger than in overlaying soils indicating a substantial sedimentation phase for the overlaying soils. An additional analysis of total mercury contents in the soil profiles indicated that this sedimentation was associated with upstream hydraulic gold mining after the 1850s. In summary, deep alluvial soils in floodplains store large amounts of SOC not yet accounted for in global carbon models. Historic data give evidence that large amounts of sediment were transported into the floodplains of most rivers of the Central Valley and deposited over organically rich topsoil, which promoted the stabilization of SOC, and needs to be considered to improve our understanding of the human-induced interference with C cycling.

California↗
USGS1998

Numerical analysis of seawater circulation in carbonate platforms: I. Geothermal convection

Differences in fluid density between cold ocean water and warm ground water can drive the circulation of seawater through carbonate platforms. The circulating water can be the major source of dissolved constituents for diagenetic reactions such as dolomitization. This study was undertaken to investigate the conditions under which such circulation can occur and to determine which factors control both the flux and the patterns of fluid circulation and temperature distribution, given the expected ranges of those factors in nature. Results indicate that the magnitude and distribution of permeability within a carbonate platform are the most important parameters. Depending on the values of horizontal and vertical permeability, heat transport within a platform can occur by one of three mechanisms: conduction, forced convection, or free convection. Depth-dependent relations for porosity and permeability in carbonate platforms suggest circulation may decrease rapidly with depth. The fluid properties of density and viscosity are controlled primarily by their dependency on temperature. The bulk thermal conductivity of the rocks within the platform affects the conductive regime to some extent, especially if evaporite minerals are present within the section. Platform geometry has only a second-order effect on circulation. The relative position of sealevel can create surface conditions that range from exposed (with a fresh-water lens present) to shallow water (with hypersaline conditions created by evaporation in constricted flow conditions) to submerged or drowned (with free surface water circulation), but these boundary conditions and associated ocean temperature profiles have only a second-order effect on fluid circulation. Deep, convective circulation can be caused by horizon tal temperature gradients and can occur even at depths below the ocean bottom. Temperature data from deep holes in the Florida and Bahama platforms suggest that geothermal circulation is actively occurring today to depths as great as several kilometers.

American Journal of Science↗
USGS1988

Proceedings of a workshop on the development and evaluation of habitat suitability criteria: A compilation of papers and discussions presented at Colorado State University, Fort Collins, Colorado, December 8-12, 1986

The development of reliable habitat suitability criteria is critical to the successful implementation of the Instream Flow Incremental Methodology (IFIM), or any other habitat based evaluation technology. It is also a fascinating topic of research, for several reasons. First, the “science” of habitat quantification is relatively young. Descriptions of habitat use and partitioning can be traced back to Darwin, if not further. Attempts to actually quantify habitat use can be found predominantly during the last two decades, with most of the activity occurring in about the last five years. Second, this work is challenging because we are usually working with fish or some other organism that lives out of sight in an environment that is foreign to humans. Most of the data collection techniques that have been developed for standard fisheries work are unsuited, without modification, for criteria development. These factors make anyone involved in this type of research a pioneer, of sorts. Pioneers often make new and wonderful discoveries, but they also sometimes get lost. In our opinion, however, there is an even more rewarding aspect to criteria development research. It seems that the field of biology has tended to become increasingly clinical over the years. Criteria development demands the unobtrusive observation of organisms in their natural environment, a fact that allows the biological to be a naturalist and still get paid for it. The relative youth and importance of habitat quantification have resulted in rapid advancements in the state of the art. The expansion of methods is vividly demonstrated simply by comparing the two Instream Flow Information Papers written on the subject in 1978 and in 1986. One of the missions of the Aquatic Systems Branch (formerly the Instream Flow Group) is to serve as a clearinghouse for new techniques and methods. In keeping with this role, a workshop was conducted during December 1986 to discuss current and newly evolving methods for developing and evaluating habitat suitability criteria. Participation in this workshop was largely by invitation only. The objective was to obtain insights into problems and possible solutions to criteria development, from the perspective of professionals closely involved with the subject. These proceedings of that workshop are intended to supplement the information contained in Instream Flow Information Paper 21, "Development and Evaluation of Habitat Suitability Criteria for Use in the Instream Flow Incremental Methodology." The workshop was closely arranged in five sessions, roughly following the outline of Information Paper 21. The first session dealt with various aspects of study design and how they can influence the outcome of a study. Session two investigated techniques for developing criteria from professional judgment, and some of the problems encountered when personal or agency prejudice enters the picture. Session three concentrated on field data collection procedures, whereas session four examined methods of converting field data into curves. Field verification studies were discussed in session five. Each presentation in the workshop was followed by a question and answer period of 15 to 30 minutes. These discussions were recorded, transcribed, and appended to the end of each paper in these proceedings. We have attempted to capture the essence of these discussions as accurately as possible, but hope that the reader can appreciate the difficulty in translating a free-ranging discussion (from a barely audible tape) to something that makes sense in print. These question and answer sessions constitute the peer review for each of the papers. This provides the reader with the unique opportunity to review the interactions between authors and reviewers.

Book↗
USGS2011

Source region of a granite batholith: Evidence from lower crustal xenoliths and inherited accessory minerals

Like many granites, the Late Cretaceous intrusives of the eastern Mojave Desert, California, have heretofore provided useful but poorly focused images of their source regions. New studies of lower crustal xenoliths and inherited accessory minerals are sharpening these images. Xenoliths in Tertiary dykes in this region are the residues of an extensive partial melting event. Great diversity in their composition reflects initial heterogeneity (both igneous and sedimentary protoliths) and varying amounts of melt extraction (from <10% to >70%). Mineral assemblages and thermobarometry suggest that the melting event occurred at T ≥ 750°C at a depth of about 40 km. Present-day Sr, Nd, and Pb isotopic ratios indicate a Mojave Proterozoic heritage, but unrealistic model ages demonstrate the late Phanerozoic adjustment of parent/daughter ratios. A link between these xenoliths and the Late Cretaceous granites, though not fully documented, is probable; in any case, they provide invaluable clues concerning a crustal melting event, recording information about nature of source material (heterogeneous, supracrustal-rich), conditions of melting (moderately deep, moderately high T, accompanied by partial dehydration), and melt extraction (highly variable, locally extensive). The Old Woman-Piute granites contain a large fraction of inherited zircon and monazite. A SHRIMP ion probe investigation shows that these zircons record a Proterozoic history similar to that which affected the Mojave region. Zonation patterns in zircons, and to a lesser extent monazites and xenotimes, document multiple phases of igneous, metamorphic, and sedimentary growth and degradation, commonly several in a single grain. Low Y in portions of the cores of inherited zircons and monazites and in monazites and outer portions of zircons from the xenoliths appear to indicate growth in equilibrium with abundant garnet.

California↗
USGS2024

An evaluation of fin ray microchemistry to describe movement of White Sturgeon in the Kootenai River basin: Insights and limitations

Introduction: White Sturgeon Acipenser transmontanus in the Kootenai River basin is listed as endangered in the United States and Canada. Declines have been mainly attributed to poor recruitment exacerbated by the environmental effects of Libby Dam in Montana. Reduced primary production downstream of Libby Dam has been identified as one factor limiting growth of White Sturgeon, thereby limiting natural reproduction through delayed sexual maturity. However, estimating changes in growth over time without knowledge of fish location (i.e., Kootenai River vs. Kootenay Lake) is difficult. The objective of this project was to use microchemistry analysis to describe the movement of White Sturgeon within the Kootenai River basin. Methods: Water samples ( n = 27) and White Sturgeon fin rays ( n = 162) collected in the Kootenai River basin were measured for strontium isotope ( 87 Sr: 86 Sr) ratios using laser ablation multicollector inductively coupled plasma mass spectrometry. All water samples and a subset of fin rays ( n = 8) were also analyzed for trace elements (e.g., Sr, Ba, Mg). Fin ray annuli were measured and tested using knowledge of known age; known locations from physical capture events were assigned to age at capture. Results: Strontium isotope analysis was unable to detect differences in the Kootenai River and Kootenay Lake using water or fin ray samples. The Kootenai River and Kootenay Lake were distinguishable using trace element data from water samples, but not fin rays. The discrepancy with trace elements appears to be associated with the physiology of fin ray growth. Discussion: Although this study did not meet its original objective of describing the movement of White Sturgeon in the Kootenai River basin from fin ray microchemistry, our results provide insight into the potential influence of physiology on microchemistry analysis. In particular, fin ray microchemistry of slow-growing fishes may be possible in freshwater systems with further investigation into the physiological processes associated with growth and the incorporation of elements into calcified structures.

British Columbia, Idaho, Montana↗
USGS2024

Shellfish aquaculture farms as foraging habitat for nearshore fishes and crabs

Objective Oyster reefs across North America have declined precipitously over the past 140 years. In Washington State, Olympia oyster Ostrea lurida reefs historically provided water filtration and nearshore structural habitat for fishes and invertebrates, but this species is now functionally extinct across its historical range. In place of these naturally occurring reefs, shellfish farms consisting mainly of nonnative Pacific oysters Magallana gigas now occupy patches of nearshore habitat across Washington. These farms modify intertidal substrate by adding structural habitat via suspended oyster grow bags, predator exclusion nets, loose oyster beds, and other shellfish grow-out gear. As interest and investment in shellfish aquaculture have expanded both locally and globally, so has interest in how these farms modify intertidal habitat and whether the complex structure created by the shellfish and shellfish growing gear provides ecosystem services that are comparable to those of unfarmed areas, such as mudflats and eelgrass meadows. Methods In this study, we sought to quantify how shellfish farms are used as foraging habitat for several common nearshore species of fish and crabs in Puget Sound, Washington. We used direct observations of species-specific behaviors from underwater video to model how habitat type affected observed foraging rates. Result We obtained a total of 393 crab observations, 431 demersal fish observations, and 1856 pelagic fish observations across all seven farm sites. Several common species of pelagic fish (e.g., surfperch [Embiotocidae]) used aquaculture-growing gear more frequently than unfarmed areas as foraging habitat, but Metacarcinus spp. crabs displayed higher foraging frequency in unfarmed mudflats. Species groups such as sculpins (Cottidae) and small flatfish (Pleuronectidae) clearly used specific aquaculture-growing gear and mudflats in roughly equal proportion. Conclusion Our results indicate that shellfish farms within a larger nearshore habitat mosaic of eelgrass meadows, mudflats, bivalve aquaculture gear, and edge habitat can provide foraging habitat for several species of nearshore fish.

Washington↗
USGS2012

A fine-scale assessment of using barriers to conserve native stream salmonids: a case study in Akokala Creek, Glacier National Park, USA

Biologists are often faced with the difficult decision in managing native salmonids of where and when to install barriers as a conservation action to prevent upstream invasion of nonnative fishes. However, fine-scale approaches to assess long-term persistence of populations within streams and watersheds chosen for isolation management are often lacking. We employed a spatially-explicit approach to evaluate stream habitat conditions, relative abundance, and genetic diversity of native westslope cutthroat trout (Oncorhynchus clarkii lewisi) within the Akokala Creek watershed in Glacier National Park- a population threatened by introgressive hybridization with nonnative rainbow trout (O. mykiss) from nearby sources. The systematic survey of 24 stream reaches showed broad overlap in fish population and suitable habitat characteristics among reaches and no natural barriers to fish migration were found. Analysis of population structure using 16 microsatellite loci showed modest amounts of genetic diversity among reaches, and that fish from Long Bow Creek were the only moderately distinct genetic group. We then used this information to assess the potential impacts of three barrier placement scenarios on long-term population persistence and genetic diversity. The two barrier placement scenarios in headwater areas generally failed to meet general persistence criteria for minimum population size (2,500 individuals, Ne = 500), maintenance of long-term genetic diversity (He), and no population subdivision. Conversely, placing a barrier near the stream mouth and selectively passing non-hybridized, migratory spawners entering Akokala Creek met all persistence criteria and may offer the best option to conserve native trout populations and life history diversity. Systematic, fine-scale stream habitat, fish distribution, and genetic assessments in streams chosen for barrier installation are needed in conjunction with broader scale assessments to understand the potential impacts of using barriers for conservation of native salmonid populations threatened by nonnative fish invasions.

Open Fish Science Journal↗
USGS2020

Nonlinear patterns in mercury bioaccumulation in American alligators are a function of predicted age

Mercury is a widespread, naturally occurring contaminant that biomagnifies in wetlands due to the methylation of this element by sulfate-reducing bacteria. Species that feed at the top trophic level within wetlands are predicted to have higher mercury loads compared to species feeding at lower trophic levels and are therefore often used for mercury biomonitoring. However, mechanisms for mercury bioaccumulation in sentinel species are often poorly understood, due to a lack of long-term studies or an inability to differentiate between confounding variables. We examined mercury bioaccumulation patterns in the whole blood of American alligators ( Alligator mississippiensis ) from a long-term mark-recapture study (1979–2017) in South Carolina, USA. Using a growth model and auxiliary information on predicted age at first capture, we differentiated between age- and size-related variation in mercury bioaccumulation, which are often confounded in alligators due to their determinate growth pattern. Contrary to predictions that the oldest or largest individuals were likely to have the highest mercury concentrations, our best-supported model indicated a peak in mercury concentration at 30–40 years of age, depending on the sex, and lower concentrations in the youngest and oldest animals. To evaluate the robustness of our findings, we re-analyzed data from a previously published study of mercury in alligators sampled at Merritt Island National Wildlife Refuge in Florida. Unlike the South Carolina data, the data from Florida contained minimal auxiliary information regarding age, yet the best supported model similarly indicated a peaked rather than increasing relationship between mercury and body size, a less-precise indicator of age. These findings highlight how long-term monitoring can differentiate between confounding variables (e.g., age and size) to better elucidate complex relationships between contaminant exposure and demographic factors in sentinel species.

Florida, South Carolina↗
USGS2016

Impact of Deepwater Horizon Spill on food supply to deep-sea benthos communities

Deep-sea ecosystems encompass unique and often fragile communities that are sensitive to a variety of anthropogenic and natural impacts. After the 2010 Deepwater Horizon (DWH) oil spill, sampling efforts documented the acute impact of the spill on some deep-sea coral colonies. To investigate the impact of the DWH spill on quality and quantity of biomass delivered to the deep-sea, a suite of geochemical tracers (e.g., stable and radio-isotopes, lipid biomarkers, and compound specific isotopes) was measured from monthly sediment trap samples deployed near a high-density deep-coral site in the Viosca Knoll area of the north-central Gulf of Mexico prior to (Oct-2008 to Sept-2009) and after the spill (Oct-10 to Sept-11). Marine (e.g., autochthonous) sources of organic matter dominated the sediment traps in both years, however after the spill, there was a pronounced reduction in marinesourced OM, including a reduction in marine-sourced sterols and n-alkanes and a concomitant decrease in sediment trap organic carbon and pigment flux. Results from this study indicate a reduction in primary production and carbon export to the deep-sea in 2010-2011, at least 6-18 months after the spill started. Whereas satellite observations indicate an initial increase in phytoplankton biomass, results from this sediment trap study define a reduction in primary production and carbon export to the deep-sea community. In addition, a dilution from a low-14C carbon source (e.g., petrocarbon) was detected in the sediment trap samples after the spill, in conjunction with a change in the petrogenic composition. The data presented here fills a critical gap in our knowledge of biogeochemical processes and sub-acute impacts to the deep-sea that ensued after the 2010 DWH spill.

Gulf of Mexico↗
USGS2012

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗
USGS2006

Application of municipal biosolids to dry-land wheat fields - A monitoring program near Deer Trail, Colorado (USA). A presentation for an international conference: "The Future of Agriculture: Science, Stewardship, and Sustainability", August 7-9, 2006, Sacramento, CA

Since late 1993, Metro Wastewater Reclamation District of Denver (Metro District), a large wastewater treatment plant in Denver, Colorado, has applied Grade I, Class B biosolids to about 52,000 acres of non-irrigated farmland and rangeland near Deer Trail, Colorado. In cooperation with the Metro District in 1993, the U.S. Geological Survey (USGS) began monitoring ground water at part of this site. In 1999, the USGS began a more comprehensive study of the entire site to address stakeholder concerns about the chemical effects of biosolids applications. This more comprehensive monitoring program has recently been extended through 2010. Monitoring components of the more comprehensive study included biosolids collected at the wastewater treatment plant, soil, crops, dust, alluvial and bedrock ground water, and stream bed sediment. Streams at the site are dry most of the year, so samples of stream bed sediment deposited after rain were used to indicate surface-water effects. This presentation will only address biosolids, soil, and crops. More information about these and the other monitoring components are presented in the literature (e.g., Yager and others, 2004a, b, c, d) and at the USGS Web site for the Deer Trail area studies at http://co.water.usgs.gov/projects/CO406/CO406.html. Priority parameters identified by the stakeholders for all monitoring components, included the total concentrations of nine trace elements (arsenic, cadmium, copper, lead, mercury, molybdenum, nickel, selenium, and zinc), plutonium isotopes, and gross alpha and beta activity, regulated by Colorado for biosolids to be used as an agricultural soil amendment. Nitrogen and chromium also were priority parameters for ground water and sediment components. In general, the objective of each component of the study was to determine whether concentrations of priority parameters (1) were higher than regulatory limits, (2) were increasing with time, or (3) were significantly higher in biosolids-applied areas than in a similar farmed area where biosolids were not applied. Where sufficient samples could be collected, statistical methods were used to evaluate effects. Rigorous quality assurance was included in all aspects of the study. The roles of hydrology and geology also were considered in the design, data collection, and interpretation phases of the study. Study results indicate that the chemistry of the biosolids from the Denver plant was consistent during 1999-2005, and total concentrations of regulated trace elements were consistently lower than the regulatory limits. Plutonium isotopes were not detected in the biosolids. Leach tests using deionized water to simulate natural precipitation indicate arsenic, molybdenum, and nickel were the most soluble priority parameters in the biosolids. Study results show no significant difference in concentrations of priority parameters between biosolids-applied soils and unamended soils where no biosolids were applied. However, biosolids were applied only twice during 1999-2003. The next soil sampling is not scheduled until 2010. To date concentrations of most of the priority parameters were not much greater in the biosolids than in natural soil from the sites. Therefore, many more biosolids applications would need to occur before biosolids effects on the soil priority constituents can be quantified. Leach tests using deionized water to simulate precipitation indicate that molybdenum and selenium were the priority parameters that were most soluble in both biosolids-applied soil and natural or unamended soil. Study results do not indicate significant differences in concentrations of priority parameters between crops grown in biosolids-applied areas and crops grown where no biosolids were applied. However, crops were grown only twice during 1999-2003, so only two crop samples could be collected. The wheat-grain elemental data collected during 1999-2003 for both biosolids-applied areas and unamended areas are similar

Open-File Report↗
USGS2008

A national reconnaissance for pharmaceuticals and other organic wastewater contaminants in the United States - II) Untreated drinking water sources

Numerous studies have shown that a variety of manufactured and natural organic compounds such as pharmaceuticals, steroids, surfactants, flame retardants, fragrances, plasticizers and other chemicals often associated with wastewaters have been detected in the vicinity of municipal wastewater discharges and livestock agricultural facilities. To provide new data and insights about the environmental presence of some of these chemicals in untreated sources of drinking water in the United States targeted sites were sampled and analyzed for 100 analytes with sub-parts per billion detection capabilities. The sites included 25 ground- and 49 surface-water sources of drinking water serving populations ranging from one family to over 8 million people. Sixty-three of the 100 targeted chemicals were detected in at least one water sample. Interestingly, in spite of the low detection levels 60% of the 36 pharmaceuticals (including prescription drugs and antibiotics) analyzed were not detected in any water sample. The five most frequently detected chemicals targeted in surface water were: cholesterol (59%, natural sterol), metolachlor (53%, herbicide), cotinine (51%, nicotine metabolite), &beta;-sitosterol (37%, natural plant sterol), and 1,7-dimethylxanthine (27%, caffeine metabolite); and in ground water: tetrachloroethylene (24%, solvent), carbamazepine (20%, pharmaceutical), bisphenol-A (20%, plasticizer), 1,7-dimethylxanthine (16%, caffeine metabolite), and tri (2-chloroethyl) phosphate (12%, fire retardant). A median of 4 compounds were detected per site indicating that the targeted chemicals generally occur in mixtures (commonly near detection levels) in the environment and likely originate from a variety of animal and human uses and waste sources. These data will help prioritize and determine the need, if any, for future occurrence, fate and transport, and health-effects research for subsets of these chemicals and their degradates most likely to be found in water resources used for drinking water in the United States.

Science of the Total Environment↗
USGS2011

Using multi-source satellite data for lake level modelling in ungauged basins: A case study for Lake Turkana, East Africa

Managing limited surface water resources is a great challenge in areas where ground-based data are either limited or unavailable. Direct or indirect measurements of surface water resources through remote sensing offer several advantages of monitoring in ungauged basins. A physical based hydrologic technique to monitor lake water levels in ungauged basins using multi-source satellite data such as satellite-based rainfall estimates, modelled runoff, evapotranspiration, a digital elevation model, and other data is presented. This approach is applied to model Lake Turkana water levels from 1998 to 2009. Modelling results showed that the model can reasonably capture all the patterns and seasonal variations of the lake water level fluctuations. A composite lake level product of TOPEX/Poseidon, Jason-1, and ENVISAT satellite altimetry data is used for model calibration (1998-2000) and model validation (2001-2009). Validation results showed that model-based lake levels are in good agreement with observed satellite altimetry data. Compared to satellite altimetry data, the Pearson's correlation coefficient was found to be 0.81 during the validation period. The model efficiency estimated using NSCE is found to be 0.93, 0.55 and 0.66 for calibration, validation and combined periods, respectively. Further, the model-based estimates showed a root mean square error of 0.62 m and mean absolute error of 0.46 m with a positive mean bias error of 0.36 m for the validation period (2001-2009). These error estimates were found to be less than 15 % of the natural variability of the lake, thus giving high confidence on the modelled lake level estimates. The approach presented in this paper can be used to (a) simulate patterns of lake water level variations in data scarce regions, (b) operationally monitor lake water levels in ungauged basins, (c) derive historical lake level information using satellite rainfall and evapotranspiration data, and (d) augment the information provided by the satellite altimetry systems on changes in lake water levels. ?? Author(s) 2011.

Hydrology and Earth System Sciences Discussions↗
USGS2018

Harnessing big data to rethink land heterogeneity in Earth system models

The continual growth in the availability, detail, and wealth of environmental data provides an invaluable asset to improve the characterization of land heterogeneity in Earth system models – a persistent challenge in macroscale models. However, due to the nature of these data (volume and complexity) and computational constraints, these data are underused for global applications. As a proof of concept, this study explores how to effectively and efficiently harness these data in Earth system models over a 1/4° ( ∼ 25 km) grid cell in the western foothills of the Sierra Nevada in central California. First, a novel hierarchical multivariate clustering approach (HMC) is introduced that summarizes the high-dimensional environmental data space into hydrologically interconnected representative clusters (i.e., tiles). These tiles and their associated properties are then used to parameterize the sub-grid heterogeneity of the Geophysical Fluid Dynamics Laboratory (GFDL) LM4-HB land model. To assess how this clustering approach impacts the simulated water, energy, and carbon cycles, model experiments are run using a series of different tile configurations assembled using HMC. The results over the test domain show that (1) the observed similarity over the landscape makes it possible to converge on the macroscale response of the fully distributed model with around 300 sub-grid land model tiles; (2) assembling the sub-grid tile configuration from available environmental data can have a large impact on the macroscale states and fluxes of the water, energy, and carbon cycles; for example, the defined subsurface connections between the tiles lead to a dampening of macroscale extremes; (3) connecting the fine-scale grid to the model tiles via HMC enables circumvention of the classic scale discrepancies between the macroscale and field-scale estimates; this has potentially significant implications for the evaluation and application of Earth system models.

Hydrology and Earth System Sciences↗
USGS2023

A perched culvert and natural obstructions limit fish dispersal in an intermittent prairie stream

Poorly constructed road crossings block upstream movement of fish into stream reaches that provide critical habitat or connect isolated populations. Although removing these barriers is often a conservation priority, quantifying fish passage following removal has not been well studied, particularly in intermittent streams. In this study, we sought to understand how barriers influence the dispersal of fishes in intermittent prairie streams. We used passive integrated transponder tags and antenna stations to quantify fish movement of 3 prairie-stream fishes (Central Stoneroller Campostoma anomalum [Rafinesque, 1820], Southern Redbelly Dace Chrosomus erythrogaster [Rafinesque, 1820], and Creek Chub Semotilis atromaculatus [Mitchill, 1818]) through a road crossing in an intermittent prairie stream for 3 y before and 3 y after removing a perched culvert. We verified that no upstream fish movement occurred through the culvert, despite large aggregations of tagged fish in the intermittent reach below the culvert. In contrast, tagged individuals of all 3 species were detected above the road crossing in each of the 3 y following removal. We also tracked the recovery of these species, plus the Orangethroat Darter Etheostoma spectabile (Agassiz, 1854), following a severe drought in 2018 in 2 spring-fed tributary reaches, 1 without a downstream barrier and 1 with the removed downstream culvert. Surveys of the tributary reaches showed rapid recovery of fish densities following drought in the tributary without a downstream barrier. However, recovery at the site above the removed culvert appeared to be limited by a natural waterfall. Our observations suggest barrier removal allowed access to spawning habitat within the intermittent reach immediately upstream of the site, but other obstacles or shear distance to perennial spring-fed tributary reaches also limited recolonization following severe drought. Increased connectivity between perennial and intermittent reaches in prairie streams likely benefits fishes by increasing their resilience following disturbance and providing habitat during critical life stages.

Kansas↗
USGS2013

Sources and characteristics of organic matter in the Clackamas River, Oregon, related to the formation of disinfection by-products in treated drinking water

This study characterized the amount and quality of organic matter in the Clackamas River, Oregon, to gain an understanding of sources that contribute to the formation of chlorinated and brominated disinfection by-products (DBPs), focusing on regulated DBPs in treated drinking water from two direct-filtration treatment plants that together serve approximately 100,000 customers. The central hypothesis guiding this study was that natural organic matter leaching out of the forested watershed, in-stream growth of benthic algae, and phytoplankton blooms in the reservoirs contribute different and varying proportions of organic carbon to the river. Differences in the amount and composition of carbon derived from each source affects the types and concentrations of DBP precursors entering the treatment plants and, as a result, yield varying DBP concentrations and species in finished water. The two classes of DBPs analyzed in this study-trihalomethanes (THMs) and haloacetic acids (HAAs)-form from precursors within the dissolved and particulate pools of organic matter present in source water. The five principal objectives of the study were to (1) describe the seasonal quantity and character of organic matter in the Clackamas River; (2) relate the amount and composition of organic matter to the formation of DBPs; (3) evaluate sources of DBP precursors in the watershed; (4) assess the use of optical measurements, including in-situ fluorescence, for estimating dissolved organic carbon (DOC) concentrations and DBP formation; and (5) assess the removal of DBP precursors during treatment by conducting treatability "jar-test" experiments at one of the treatment plants. Data collection consisted of (1) monthly sampling of source and finished water at two drinking-water treatment plants; (2) event-based sampling in the mainstem, tributaries, and North Fork Reservoir; and (3) in-situ continuous monitoring of fluorescent dissolved organic matter (FDOM), turbidity, chlorophyll- a , and other constituents to continuously track source-water conditions in near real-time. Treatability tests were conducted during the four event-based surveys to determine the effectiveness of coagulant and powdered activated carbon (PAC) on the removal of DBP precursors. Sample analyses included DOC, total particulate carbon (TPC), total and dissolved nutrients, absorbance and fluorescence spectroscopy, and, for regulated DBPs, concentrations of THMs and HAAs in finished water and laboratory-based THM and HAA formation potentials (THMFP and HAAFP, respectively) for source water and selected locations throughout the watershed. The results of this study may not be typical given the record and near record amounts of precipitation that occurred during spring that produced streamflow much higher than average in 2010-11. Although there were algal blooms, lower concentrations of chlorophyll- a were observed in the water column during the study period compared to historical data. Concentrations of DBPs in finished (treated) water averaged 0.024 milligrams per liter (mg/L) for THMs and 0.022 mg/L for HAAs; maximum values were about 0.040 mg/L for both classes of DBPs. Although DBP concentrations were somewhat higher within the distribution system, none of the samples collected for this study or for the quarterly compliance monitoring by the water utilities exceeded levels permissible under existing U.S. Environmental Protection Agency (USEPA) regulations: 0.080 mg/L for THMs and 0.060 mg/L for HAAs. DOC concentrations were generally low in the Clackamas River, typically about 1.0-1.5 mg/L. Concentrations in the mainstem occasionally increased to nearly 2.5 mg/L during storms; DOC concentrations in tributaries were sometimes much higher (up to 7.8 mg/L). The continuous in-situ FDOM measurements indicated sharp rises in DOC concentrations in the mainstem following rainfall events; concentrations were relatively stable during summer base flow. Even though the first autumn storm mobilized appreciable quantities of carbon, higher concentrations of DBPs in finished water were observed 3-weeks later, after the ground was saturated from additional rainfall. The majority of the DOC in the lower Clackamas River appears to originate from the upper basin, suggesting terrestrial carbon was commonly the dominant source. Lower-basin tributaries typically contained the highest concentrations of DOC and DBP precursors and contributed substantially to the overall loads in the mainstem during storms. During low-flow periods, tributaries were not major sources of DOC or DBP precursors to the Clackamas River. Although the dissolved fraction of organic carbon contributed the majority of DBP precursors, at times the particulate fraction (inorganic sediment and organic particles including detritus and algal material) contributed a substantial fraction of DBP precursors. Considering just the main-stem sites, on average, 10 percent of THMFP and 32 percent of HAAFP were attributed to particulate carbon. This finding suggests water-treatment methods that remove particles prior to chlorination would reduce finished-water DBP concentrations to some degree. Overall, concentrations of THM and HAA precursors were closely linked to DOC concentrations; laboratory DBP formation potentials (DBPFPs) clearly showed that THMFP and HAAFP were greatest in the downstream tributaries that contained elevated carbon concentrations. However, carbon-normalized "specific" formation potentials for THMs and HAAs (STHMFP and SHAAFP, respectively) revealed changes in carbon character over time that affected the two types of DBP classes differently. HAA precursors were elevated in waters containing aromatic-rich soil-derived material arising from forested areas. In contrast, THM precursors were associated with carbon having a lower aromatic content; highest STHMFP occurred in autumn 2011 in the mainstem from North Fork Reservoir downstream to LO DWTP. This pattern suggests the potential for a link between THM precursors and algal-derived carbon. The highest STHMFP value was measured within North Fork Reservoir, indicating reservoir derived carbon may be important for this class of DBPs. Weak correlations between STHMFP and SHAAFP emphasize that precursor sources for these types of DBPs may be different. This highlights not only that different locations within the watershed produce carbon with different reactivity (specific DBPFP), but also that different management approaches for each class of DBP precursors could be required for control. Treatability tests conducted on source water during four basin-wide surveys demonstrated that an average of about 40 percent of DOC can be removed by coagulation. While the decrease in THMFP following coagulation was similar to DOC, the decrease in HAAFP was much greater (approximately 70 percent), indicating coagulation is particularly effective at removing HAA precursors'likely because of the aromatic nature of the carbon associated with HAA precursors. Several findings from this study have direct implications for managing drinking-water resources and for providing useful information that may help improve treatment-plant operations. For example, the use of in-situ fluorometers that measure FDOM provided an excellent proxy for DOC concentration in this system and revealed short-term, rapid changes in DOC concentration during storm events. In addition, the strong correlation between FDOM values measured in-situ and HAA5 concentrations in finished water may permit estimation of continuous HAA concentrations, as was done here. As part of this study, multiple in-situ FDOM sensors were deployed continuously and in real-time to characterize the composition of dissolved organic matter. Although the initial results were promising, additional research and engineering developments will be needed to demonstrate the full utility of these sensors for this purpose. In conclusion, although DBPFPs were strongly correlated to DOC concentration, some DBPs formed from particulate carbon, including terrestrial leaf material and algal material such as planktonic species of blue-green algae and sloughed filaments, stalks, and cells of benthic algae. Different precursor sources in the watershed were evident from the data, suggesting specific actions may be available to address some of these sources. In-situ measurements of FDOM proved to be an excellent proxy for DOC concentration as well as HAA formation during treatment, which suggests further development and refinement of these sensors have the potential to provide real-time information about complex watershed processes to operators at the drinking-water treatment plants. Follow-up studies could examine the relative roles that terrestrial and algal sources have on the DBP precursor pool to better understand how watershed-management activities may be affecting the transport of these compounds to Clackamas River drinking-water intakes. Given the low concentrations of algae in the water column during this study, additional surveys during more typical river conditions could provide a more complete understanding of how algae contribute DBP precursors. Further development of FDOM-sensor technology can improve our understanding of carbon dynamics in the river and how concentrations may be trending over time. This study was conducted in collaboration with Clackamas River Water and the City of Lake Oswego water utilities. Other research partners included Oregon Health and Science University in Hillsboro, Oregon, Alexin Laboratory in Tigard, Oregon, U.S. Geological Survey National Research Program Laboratory in Denver, Colorado, and the U.S. Geological Survey Water Science Centers in Portland, Oregon, and Sacramento, California. This project was supported with funding from Clackamas River Water, City of Lake Oswego, the U.S. Geological Survey, and the Water Research Foundation.

Oregon↗