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Uranium concentration and distribution in six peridotite inclusions of probable mantle origin

Fission-track activation was used to investigate uranium concentration and distribution in peridotite inclusions in alkali basalt from six localities. Whole-rock uranium concentrations range from 24 to 82 ng/g (1ng= 10 −9 g). Most of the uranium is uniformly distributed in the major silicate phases — olivine, orthopyroxene, and clinopyroxene. Chromian spinels may be classified into two groups on the basis of their uranium content, having either less than 10 ng/g or 100–150 ng/g U. In one sample accessory hydrous phases, phlogopite and hornblende, contain 130 and 300 ng/g U, respectively. The contact between the inclusion and the host basalt is usually quite sharp. Glassy or microcrystalline veinlets found in some samples contain more than 1μg/g(1 μg= 10 −6 g). Very little uranium is associated with microcrystals of apatite. Our results agree with some earlier investigators, who have concluded that suboceanic peridotites contain too little uranium to account for normal oceanic heat flow by conduction alone.

Earth and Planetary Science Letters↗

Rhenium-osmium systematics of calcium-aluminium-rich inclusions in carbonaceous chondrites

The Re-Os isotopic systematics of calcium-aluminium-rich inclusions (CAIs) in chondrites were investigated in order to shed light on the behavior of the Re-Os system in bulk chondrites, and to constrain the timing of chemical fractionation in primitive chondrites. CAIs with relatively unfractionated rare earth element (REE) patterns (groups I, III, V, VI) define a narrow range of 187Re/188Os (0.3764-0.4443) and 187Os/188Os (0.12599-0.12717), and high but variable Re and Os abundances (3209-41,820 ppb Os). In contrast, CAIs that show depletions in highly refractory elements and strongly fractionated REE patterns (group II) also show a much larger range in 187Re/188Os (0.409-0.535) and 187Os/188Os (0.12695-0.13770), and greater than an order of magnitude lower Re and Os abundances than other groups (e.g., 75.7-680.2 ppb Os). Sixteen bulk CAIs and CAI splits plot within analytical uncertainty of a 4558 Ga reference isochron, as is expected for materials of this antiquity. Eight samples, however, plot off the isochron. Several possible reasons for these deviations are discussed. Data for multiple splits of one CAI indicate that the nonisochronous behavior for at least this CAI is the result of Re-Os reequilibration at approximately 1.6 Ga. Thus, the most likely explanation for the deviations of most of the nonisochronous CAIs is late-stage open-system behavior of Re and Os in the asteroidal environment. The 187Os/188Os-Os systematics of CAIs are consistent with previous models that indicate group II CAIs are mixtures of components that lost the bulk of their highly refractory elements in a previous condensation event and a minor second component that provided refractory elements at chondritic relative proportions. The high Re/Os of group II CAIs relative to other CAIs and chondrite bulk rocks may have been caused by variable mobilization of Re and Os during medium- to low-temperature parent body alteration ??4.5 Ga ago. This model is favored over nebular models, which pose several difficulties. The narrow range of 187Os/188Os in group I, III, V, and VI bulk CAIs, and the agreement with 187Os/188Os of whole rock carbonaceous chondrites suggest that on a bulk inclusion scale, secondary alteration only modestly fractionated Re/Os in these CAIs. The average of 187Os/188Os for group I, III, V, and VI CAIs is indistinguishable from average CI chondrites, indicating a modern solar system value for 187Os/188Os of 0.12650, corresponding to a 187Re/188Os of 0.3964. Copyright ?? 2001 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗

Upper crustal structure in Puget Lowland, Washington: Results from the 1998 Seismic Hazards Investigation in Puget Sound

A new three-dimensional (3-D) model shows seismic velocities beneath the Puget Lowland to a depth of 11 km. The model is based on a tomographic inversion of nearly one million first-arrival travel times recorded during the 1998 Seismic Hazards Investigation in Puget Sound (SHIPS), allowing higher-resolution mapping of subsurface structures than previously possible. The model allows us to refine the subsurface geometry of previously proposed faults (e.g., Seattle, Hood Canal, southern Whidbey Island, and Devils Mountain fault zones) as well as to identify structures (Tacoma, Lofall, and Sequim fault zones) that warrant additional study. The largest and most important of these newly identified structures lies along the northern boundary of the Tacoma basin; we informally refer to this structure here as the Tacoma fault zone. Although tomography cannot provide information on the recency of motion on any structure, Holocene earthquake activity on the Tacoma fault zone is suggested by seismicity along it and paleoseismic evidence for abrupt uplift of tidal marsh deposits to its north. The tomography reveals four large, west to northwest trending low-velocity basins (Tacoma, Seattle, Everett, and Port Townsend) separated by regions of higher velocity ridges that are coincident with fault-bounded uplifts of Eocene Crescent Formation basalt and pre-Tertiary basement. The shapes of the basins and uplifts are similar to those observed in gravity data; gravity anomalies calculated from the 3-D tomography model are in close agreement with the observed anomalies. In velocity cross sections the Tacoma and Seattle basins are asymmetric: the basin floor dips gently toward a steep boundary with the adjacent high-velocity uplift, locally with a velocity "overhang" that suggests a basin vergent thrust fault boundary. Crustal fault zones grow from minor folds into much larger structures along strike. Inferred structural relief across the Tacoma fault zone increases by several kilometers westward along the fault zone to Lynch Cove, where we interpret it as a zone of south vergent faulting overthrusting Tacoma basin. In contrast, structural relief along the Seattle fault zone decreases west of Seattle, which we interpret as evidence that the N-S directed compression is being accommodated by slip transfer between the Seattle and Tacoma fault zones. Together, the Tacoma and Seattle fault zones raise the Seattle uplift, one of a series of east-west trending, pop-up structures underlying Puget Lowland from the Black Hills to the San Juan Islands.

Washington↗

Age of tilted reefs, Hawaii

Submerged carbonate reefs are preserved as a series of submarine terraces between Molokai and Hawaii along a 200-km span of the southeastern Hawaiian Ridge. Limestones from two of the terraces have been sampled from submersibles and dated radiometrically at 13 and 120 ka. Recognition that the terraces are tilted permits assignment of about a dozen terraces from 150 to 1300 m depth to eight general reef platforms. These reefs were drowned by the combined effects of island subsidence and sea level rise at the end of successive glacial stages from 13 to 647 ka. The platforms are tilted 5 m/km southeast toward the locus of volcanic loading centered on the island of Hawaii. The end of the active period of volcanic shield building is represented on each nonactive volcano by a submerged change in slope. Dating of this slope change by reference to the dated reefs provides independent evidence that shield building ended at about the same time that the volcano changed from eruption of tholeiitic to alkalic basalt. The variation in depth of the dated tilted reefs along the ridge indicates that the end of subsidence follows the end of shield building by about one half million years. The present northwest margin of major subsidence probably crosses southeast Maui. During the last half million years the rate of southeast migration of the beginning of both subsidence and of tholeiitic volcanism does not appear to have increased. However, the rate of southeast migration of the end of both subsidence and of tholeiitic volcanism has apparently increased. This shortening of the life history of the younger volcanoes implies an increase in eruption rates.

Journal of Geophysical Research Solid Earth↗

The 3D Elevation Program—Supporting Florida's economy

Introduction Florida has the longest coastline of any State in the contiguous United States, and its coastal resources are one of the main drivers of its economic growth. High-quality elevation data are beneficial for use in emergency management, especially for hurricane response, recovery, and mitigation, as well as for coastal zone management, flood risk management, infrastructure planning, agriculture, forestry, and natural resources management. Having regional or statewide elevation data coverage that was collected at about the same time allows for improved results from in-depth modeling and more meaningful analysis to support the State’s Chief Science Officer, Geographic Information Officer, State agencies, water management districts, and local governments that will use these data for decision making. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Florida↗

Runoff-generated debris flows: observations and modeling of surge initiation, magnitude, and frequency

Runoff during intense rainstorms plays a major role in generating debris flows in many alpine areas and burned steeplands. Yet compared to debris flow initiation from shallow landslides, the mechanics by which runoff generates a debris flow are less understood. To better understand debris flow initiation by surface water runoff, we monitored flow stage and rainfall associated with debris flows in the headwaters of two small catchments: a bedrock-dominated alpine basin in central Colorado (0.06 km 2 ) and a recently burned area in southern California (0.01 km 2 ). We also obtained video footage of debris flow initiation and flow dynamics from three cameras at the Colorado site. Stage observations at both sites display distinct patterns in debris flow surge characteristics relative to rainfall intensity (I). We observe small, quasiperiodic surges at low I; large, quasiperiodic surges at intermediate I; and a single large surge followed by small-amplitude fluctuations about a more steady high flow at high I. Video observations of surge formation lead us to the hypothesis that these flow patterns are controlled by upstream variations in channel slope, in which low-gradient sections act as “sediment capacitors,” temporarily storing incoming bed load transported by water flow and periodically releasing the accumulated sediment as a debris flow surge. To explore this hypothesis, we develop a simple one-dimensional morphodynamic model of a sediment capacitor that consists of a system of coupled equations for water flow, bed load transport, slope stability, and mass flow. This model reproduces the essential patterns in surge magnitude and frequency with rainfall intensity observed at the two field sites and provides a new framework for predicting the runoff threshold for debris flow initiation in a burned or alpine setting.

California;Colorado↗

Scarp degraded by linear diffusion: Inverse solution for age

Under the assumption that landforms unaffected by drainage channels are degraded according to the linear diffusion equation, a procedure is developed to invert a scarp profile to find its “diffusion age.” Diffusion age, having dimension [length] 2 , is the product of diffusivity times chronological age. The second moment of scarp slope grows linearly with age. This fact, together with an assumption about initial scarp shape, allows the inverse determination of diffusion age. Age found assuming a vertical initial scarp is termed “apparent age”; any nonvertical initial scarp profile has a nonzero initial apparent age. True diffusion age differs from apparent age by a fraction of scarp offset squared. The inverse procedure applied to synthetic data yields the following rules of thumb. Evidence of initial scarp shape has been lost when apparent age reaches twice its initial value. If a scarp is formed by two events, the inversion gives their offset-weighted-mean age with an error that is a fraction of offset squared. A scarp that appears to have been formed by one event may have been formed by two with an interval between them as large as apparent age. After scarps of two fault traces have diffused to appear as one, the error in inferred age may be as large as half the apparent age. Variation of apparent age along strike would indicate multiple fault traces. The simplicity of scarp profile measurement and this inversion makes profile analysis attractive. If linearity of the flow law, time for a free face to be reduced to the angle of repose, and variation of diffusivity with climate and material could be established, profile analysis would become a reliable dating technique.

Journal of Geophysical Research Solid Earth↗

Normalization of stable isotope data for carbonate minerals: implementation of IUPAC guideline

Carbonate minerals provide a rich source of geochemical information because their δ 13 C and δ 18 O values provide information about surface and subsurface Earth processes. However, a significant problem is that the same δ 18 O value is not reported for the identical carbonate sample when analyzed in different isotope laboratories in spite of the fact that the International Union of Pure and Applied Chemistry (IUPAC) has provided reporting guidelines for two decades. This issue arises because (1) the δ 18 O measurements are performed on CO 2 evolved by reaction of carbonates with phosphoric acid, (2) the acid-liberated CO 2 is isotopically fractionated (enriched in 18 O) because it contains only two-thirds of the oxygen from the solid carbonate, (3) this oxygen isotopic fractionation factor is a function of mineralogy, temperature, concentration of the phosphoric acid, and δ 18 O value of water in the phosphoric acid, (4) researchers may use any one of an assortment of oxygen isotopic fractionation factors that have been published for various minerals at various reaction temperatures, and (5) it sometimes is not clear how one should calculate δ 18 O VPDB values on a scale normalized such that the δ 18 O value of SLAP reference water is −55.5 ‰ relative to VSMOW reference water. To enable researchers worldwide to publish the same δ 18 O value (within experimental uncertainty) for the same carbonate sample, we have re-evaluated reported acid fractionation factors for calcite at 25, 50, and 75 °C and propose a revised relation for the temperature dependence of oxygen isotopic acid fractionation factor, α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite , of 1000ln α CO 2 ( ACID ) -calcite=3.48(10 3 /T)-1.47 1000lnαCO2(ACID)-calcite=3.48(103/T)-1.47 Turn MathJax on where T is temperature in kelvin. At 25 °C, α CO 2 ( ACID ) -calcite=1.01025 αCO2(ACID)-calcite=1.01025 , the most commonly accepted value for this quantity. We propose a normalization protocol in which (1) the internationally distributed carbonate isotopic reference materials NBS 18 and NBS 19 are interspersed among carbonate samples analyzed by treatment with phosphoric acid, (2) the δ 18 O values of the calcite reference materials and the carbonate samples are calculated, respectively, by using the α CO 2 ( ACID ) -calcite αCO2(ACID)-calcite relation above and oxygen-isotope acid fractionation factors appropriate for the sample mineralogy and reaction temperature, (3) the δ 18 O values of solid carbonate samples are determined on the VPDB scale ( δ 18 O VPDB ) with IUPAC-recommended scale expansion such that the δ 18 O of SLAP reference water is −55.5 ‰ relative to VSMOW reference water by normalizing δ 18 O values of carbonate samples with 2014-IUPAC-recommended δ 18 O values of NBS 18 and NBS 19, and (4) δ 18 O values on the VPDB scale are converted to δ 18 O values on the VSMOW-SLAP scale by using IUPAC recommendations. To ease calculations in the protocol, a software application titled “Carbon and Oxygen Isotopic Normalization Tool for Carbonates” is available that relies upon IUPAC-recommended δ 13 C and δ 18 O values of carbonate isotopic reference materials ( http://isotopes.usgs.gov/research/topics/carbonatesnormalizationtool.html ).

Geochimica et Cosmochimica Acta↗

Radarclinometry of the Earth and Venus from space-shuttle and Venera-15 imagery

The project to develop a line-integral approach to 2-dimensional radarclinometry and to bring it to the status of producing topographic maps from real radar images has been concluded. The final developments of the theory itself have involved a trial-and-error resolution of the curvature decision process at each integration step over range as follows: (1) Locally Indeterminate Azimuth-Azimuth Curvature is invoked if the range-directed path of integration is within 1 ??? in angle of the tangent to a local characteristic curve of the partial differential equation of radarclinometry (equivalent to a lapse in the necessity for an auxiliary curvature assumption); (2) Local Cylindricity is invoked if the local image isophote has a radius-of-curvature greater than 50 pixels; (3) Least-Squared Local Sphericity is invoked if the characteristic curve trends at greater than 70 ??? to the range direction (the auxiliary curvature assumption is becoming a sufficiently strong influence as to warrant the overconstraint), and (4) the default hypothesis, which is invoked most often, is the localization through the Euler/Lagrange equation from the calculus of variations of the global principle of minimization of the surface area of the terrain. The development of the set of line integrals into a 2-dimensional topographic surface is not practically achieved by branching the line integral at the range threshold, because the radarclinometry equations are too frequently coupled but weakly to the slope component in the direction of radar-azimuth, and under circumstances for which the powerfully influential auxiliary curvature assumption is too unrealistic. In other words, a line integration in radar-azimuth is far more frequently directed orthogonally to the local characteristic curve than is one carried out over range. Such orthogonality results in stepping the strike under the exclusive control of the curvature assumption. Instead, a quasi-surface-integration step is taken by modeling the dependence on initial strike of the gravitational potential energy of the vertical slab of terrain under the range-profile. The adopted starting strike for the range integral is the one which minimizes the gravitational potential energy. This radarclinometric method, in combination with my recently published method for determining an effective radar back-scattering function from one-dimensional slope statistics and image pixel-signal statistics, was applied to three images. First, to separate theoretical difficulties from experimental impediments, an artificial radar image was generated from a topographic map of the Lake Champlain West quadrangle in the Adirondack Mountains. Except for the regional trend in elevation, to which radarclinometry is insensitive by design, the agreement between the original and derived topography appears good. The morphologies agree and the range of relief is the same to within 4%. As an example of data of the highest quality available from space-borne radar at the present time, a SIR-B image of very rugged terrain in the coastal mountains of Oregon was similarly processed. The result, after filtering to redistribute photoclinometric errors about the two-dimensional spatial spectrum, agrees with ground truth almost as well. As an example of the worst possible data, in terms of signal-to-noise ratio and radar incidence angle (no detraction from the praise due the first high resolution space-borne radar-imaging of Venus intended), a Venera-15 image segment in Sedna Planitia just north-east of Sapho was processed, using Venera altimetry and Pioneer roughness data for slope statistics, in spite of the resolution mis-match. Considerably more trial-and-error filtering was required. The result appears plausible, but an error check is, of course, impossible. ?? 1990 Kluwer Academic Publishers.

Earth, Moon and Planets↗

Revising supraglacial rock avalanche magnitudes and frequencies in Glacier Bay National Park, Alaska

The frequency of large supraglacial landslides (rock avalanches) occurring in glacial environments is thought to be increasing due to feedbacks with climate warming and permafrost degradation. However, it is difficult to (i) test this; (ii) establish cause–effect relationships; and (iii) determine associated lag-times, due to both temporal and spatial biases in detection rates. Here we applied the Google Earth Engine supraglacial debris input detector (GERALDINE) to Glacier Bay National Park & Preserve (GLBA), Alaska. We find that the number of rock avalanches (RAs) has previously been underestimated by 53 %, with a bias in past detections towards large area RAs. In total, GLBA experienced 69 RAs during 1984–2020, with the highest frequency in the last three years. Of these, 58 % were deposited into the accumulation zone and then sequestered into the ice within two years. RA sources clustered spatially at high elevations and around certain peaks and ridges, predominantly at the boundary of modelled permafrost likelihood. They also clustered temporally, occurring mainly between May and September when air temperatures were high enough to initiate rock-permafrost degradation mechanisms. There was a chronic background debris supply from RAs, with at least one RA occurring in all but nine years; however, a debris rich period during 2012–2016 was driven by three large RAs delivering 44 % of all (1984–2020) debris (by area). Comparable investigation of slope-failures in other remote currently glaciated regions is lacking. If RA rates are similar elsewhere, especially the bias towards emplacement onto/into accumulation zones, their contribution to glacial sediment budgets has been globally underestimated.

Alaska↗

Special issue “The 2024 M7.6 Noto Peninsula earthquake and seismic swarm”

The 2024 Mw7.5 (M JMA 7.6) Noto Peninsula earthquake struck the Noto Peninsula, central Japan on January 1, 2024, causing widespread damage. This Mw7.5 mainshock, together with the prolonged seismic swarm that persisted in the northeastern Noto Peninsula since the end of 2020, of which the largest event was the 2023 M JMA 6.5 earthquake, constitutes one of the most significant seismic sequences in Japan in recent decades. The sequence provides a rare opportunity to investigate the complex interplay among swarm activity, fluid migration, fault geometry and distribution, and the preparatory conditions required for a large inland crustal earthquake. Motivated by this scientific context, this special issue brings together studies examining the sequence from diverse disciplinary perspectives, incorporating seismic, geodetic, and tsunami-related observations and modelling.

Noto Peninsula↗

Airborne geophysical surveys of the lower Mississippi Valley demonstrate system-scale mapping of subsurface architecture

The Mississippi Alluvial Plain hosts one of the most prolific shallow aquifer systems in the United States but is experiencing chronic groundwater decline. The Reelfoot rift and New Madrid seismic zone underlie the region and represent an important and poorly understood seismic hazard. Despite its societal and economic importance, the shallow subsurface architecture has not been mapped with the spatial resolution needed for effective management. Here, we present airborne electromagnetic, magnetic, and radiometric observations, measured over more than 43,000 flight-line-kilometers, which collectively provide a system-scale snapshot of the entire region. We develop detailed maps of aquifer connectivity and shallow geologic structure, infer relationships between structure and groundwater age, and identify previously unseen paleochannels and shallow fault structures. This dataset demonstrates how regional-scale airborne geophysics can close a scale gap in Earth observation by providing observational data at suitable scales and resolutions to improve our understanding of subsurface structures.

Mississippi River Valley↗

Comparison of U.S. net import reliance for nonfuel mineral commodities—A 60-year retrospective (1954–1984–2014)

Introduction The economic vitality and national security of the United States depend on the reliable supply of numerous nonfuel mineral commodities. Over the past six decades, many of these commodities have been sourced increasingly from outside the United States. The mix of commodities for which the United States is import dependent has changed as technologies have advanced, as substitute materials have been developed, and as world economies have changed. Although reliance on imports is only one of the many factors that determine supply risk, a clear, long-term trend has emerged from the data compiled and published by the U.S. Geological Survey, National Minerals Information Center (USGS–NMIC), and its predecessor organizations. Because the global distribution of mineral resources and reserves is not uniform, the United States has always been import reliant for some mineral commodities. Essentially, the type of commodities and the countries from which they are sourced determine risk related to import dependence. In light of projections that 2.5 billion to 3 billion people globally could move into the middle class by 2030, the demand for many types of mineral commodities is likely to continue to increase. Recent concerns regarding so-called “critical minerals” have been driven by market dislocations in the rare-earth-element supply chain in 2010 that resulted from a short-term policy decision by the Government of the People’s Republic of China to limit exports. That policy has since been changed as a result of actions by the World Trade Organization, but the events that followed, such as higher prices and intensive efforts to diversify sources of supply, illustrate the underlying issues of supply risk and the influence that disruptions can have on supply. These factors are often used in the classification of a mineral commodity as “critical.” The USGS–NMIC collects, analyzes, and disseminates information on a monthly, quarterly, or annual basis for more than 90 nonfuel mineral commodities from more than 180 countries. These data indicate that from 1954 through 2014 there was (1) a clear increase in the number and type of nonfuel mineral commodities for which the United States was net import reliant, (2) an increase in the percentage of import reliance for individual nonfuel mineral commodities, and (3) a shift in the geographic distribution of the source countries.

Fact Sheet↗

Imperiled mammalian fauna of aquatic ecosystems in the Southeast: A management perspective

Management of imperiled mammals associated with aquatic ecosystems in the southeastern United States ranges from almost no management for some species to intensive, high-profile programs for others. Aquatic mammals are notoriously difficult to census because they are often secretive, trap-wary, relatively rare, or have extensive movement patterns. As a result, conservation efforts aimed at these animals often have been greatly hampered by a general lack of comprehensive population data. Historically, certain high-profile, "flagship" species have been the primary beneficiaries of management efforts. One of the earliest examples involves beaver, Castor canadensis , which had been reduced to a low ebb due to unregulated harvest and were subsequently live-trapped by state game officials in the 1940s and repatriated throughout the southeastern states. The success of this restocking program has exceeded expectations, and today beaver numbers have reached what many consider to be nuisance proportions in most states. Similar restocking stories can be told for muskrats ( Ondatra zibethicus ) and, to a limited extent, for river otters ( Lutra canadensis ). Unfortunately, other imperiled species of lesser economic or recreational value have not been as fortunate. Efforts to conserve these lower-profile species have been minimal or conservation problems so immense that their complete recovery has been unsuccessful. Wilson (1992) suggested that 20 percent of all species on earth may be lost to extinction in the next four decades. If this disaster should occur, it would rival the greatest geological extinction episodes. Certainly, conservationists need to explore new methods for preserving mammalian diversity. In this chapter we will discuss the resource management history of aquatic mammals which are imperiled in the Southeast. In doing so we define an aquatic mammal as any mammal that is directly or indirectly associated with aquatic ecosystems. Imperiled mammals are any mammalian species, subspecies, or population listed as endangered, threatened, or of special concern on any state or federal list, and also includes mammals experiencing long-term population declines or significant range contractions.

Book chapter↗

Geochemical characteristics and K-Ar ages of rare-metal bearing pegmatites from the Birimian of southeastern Ghana

The pegmatite-aplite rocks at Mankwadzi (Ejisimanku Hills) in southeastern Ghana are part of the pegmatite district that extends from Cape Coast to Winneba along the Atlantic coastline. The pegmatites are associated with the Cape Coast granite complex and were intruded during the waning phase of the Eburnian Orogeny (∼2.0 Ga). Three muscovite separates from pegmatite give KAr retention ages of 1909 ± 13 Ma , 1965 ± 13 Ma and 2019 ± 14 Ma. A biotite separate from granite yields a KAr age of 1907 ± 13 Ma. These ages are similar to KAr dates previously reported for the Cape Coast granites, indicating that the granites and pegmatites are coeval and probably genetically linked. The pegmatites are enriched in Li, Be, Nb and Sn and considerably impoverished in Rb, Th, Y and REEs. Microscopic examination of quartz from the pegmatites shows a large number of low salinity fluid inclusions that can be divided into two types: (1) one-phase liquid or gas-filled inclusions; and (2) two-phase liquid-vapour inclusions, with the vapour occupying 2–5% of the volume. The homogenisation temperature of the fluid inclusions clusters between 129 and 144°C. These homogenisation temperatures lead to an inferred entrapment temperature of ∼300°C at a pressure of ∼2.5 kbar, which is estimated for the metamorphism of host hornblende schists. The pegmatite fluid inclusions are interpreted as being secondary to the quartz hosts.

Journal of African Earth Sciences↗

Crustal architecture beneath the southern Midcontinent (USA) and controls on Mesoproterozoic iron-oxide mineralization from 3D geophysical models

Several types of critical mineral-bearing ore deposits in the southern Midcontinent region of the U.S. are hosted in Mesoproterozoic igneous rocks largely concealed beneath Paleozoic cover. Discerning the architecture of igneous intrusions and volcanic centers in the crust is fundamental to understanding the geologic evolution of this vast region and its mineral resources. To advance the understanding of the geologic framework beneath the Southeast Missouri Iron Metallogenic Province, we invert continental-scale magnetic and gravity anomaly data to three-dimensional (3D) physical property models. The regional models image altered and mineralized igneous rocks near the Precambrian basement surface and underlying intrusive complexes that extend down to the Moho. At shallow crustal levels, our models confirm that iron oxide-apatite ± rare earth element (IOA±REE) deposits and iron oxide-copper-gold ± cobalt (IOCG) deposits occur within or near the edges of large low density/low susceptibility early Mesoproterozoic (ca 1.4 Ga) silicic calderas and (ca 1.3 Ga) granitic plutons. Previous isotopic and geochemical studies conclude that the iron deposits and their volcanic host rocks originated from mantle-derived and crustal melts that erupted during regional extension. Extension was associated with thermal event(s) that produced the large-scale silicic magmatism related to the ca 1.45 Ga Eastern Granite Rhyolite Province (EGRP) and the 1.35 Ga Southern Granite Rhyolite Province (SGRP). We postulate that early in the evolution of the EGRP, several trans-crustal magmatic plumbing systems developed that are evident in the 3D models. The Southeast Missouri Metallogenic Province is underlain by one such magmatic system that is expressed as a northwest-trending ~ 50 km-wide by 200 km-long elongate track of high susceptibility at deep crustal levels. The high susceptibility corridor splays upward through the crust to the Precambrian surface where the iron deposits are the epigenetic manifestation of this magmatic event. Our findings confirm that the iron deposits, with no distinct connection at the surface, are connected to one large magmatic system at depth. We propose that other similar susceptibility tracks, which are present along the top of the mantle, mark additional feeder zones that allowed magma to ascend to the main eruptive centers that produced the Granite Rhyolite Provinces. The early Mesoproterozoic extensional tectonic framework established crustal-scale pathways that controlled the distribution of subsequent magmatic activity, including the ca 1.4 Ga calderas and underlying intrusions, ca 1.3 Ga silicic plutons and Phanerozoic alkaline intrusions. If these interpretations are correct, our study has identified large areas that are prospective for critical mineral-bearing ore deposits and, importantly, suggests that the Mesoproterozoic architecture may have influenced subsequent magmatism and hydrothermal activity in the southern Midcontinent of the U.S.

Ore Geology Reviews↗

A laboratory-based spectrometer intercomparison for the measurement of snow spectra

Seasonal snow is an integral component of global hydrological systems, global energy budget and Earth's climate. As an important part of many Earth systems, seasonal snow is also an essential source of water for many human populations and ecosystems around the world. As such, the measurement of seasonal snow and characterization of uncertainty in those measurements is crucial. To elucidate potential uncertainty attributable to commonly used field spectrometers (and to a lesser extent imaging spectrometers) and associated reference panels, this work presents results from an intercalibration experiment conducted synchronously with the NASA 2023 Snow Experiment (SnowEx) Albedo campaign near Fairbanks, Alaska USA. Three sets of experiments were carried out under controlled laboratory conditions to characterize the radiometric and spectral wavelength consistency of the instruments as well as the white reference panels used to calculate reflectance from field measurements. Although there was generally good agreement between the instruments, panels, and the references, there were also some notable differences. One instrument showed an average − 74 % change from the reference for radiance, and multiple instruments exceeded the suggested 0.5 nm threshold for spectral wavelength scale. The Discussion section highlights how some of these findings and their implications could improve future field campaigns and general use/maintenance of these high-precision scientific instruments.

Alaska↗

First observation of the ground-state electron-capture of 40K

Potassium-40 is a widespread, naturally occurring isotope whose radioactivity impacts estimated geological ages spanning billions of years, nuclear structure theory, and subatomic rare-event searches—including those for dark matter and neutrinoless double-beta decay. The decays of this long-lived isotope must be precisely known for its use as a geochronometer, and to account for its presence in low-background experiments. There are several known decay modes for potassium-40, but a predicted electron-capture decay directly to the ground state of argon-40 has never been observed. The existence of this decay mode impacts several fields, while theoretical predictions span an order of magnitude. Here we report on the first, successful observation of this rare decay mode, obtained by the KDK (potassium decay) Collaboration using a novel combination of a low-threshold x-ray detector surrounded by a tonne-scale, high-efficiency γ -ray tagger at Oak Ridge National Laboratory. A blinded analysis reveals a distinctly nonzero ratio of intensities of ground-state electron-captures ( I EC 0 ) over excited-state ones ( I EC ∗ ) of I EC 0 / I EC ∗ = 0.0095 stat ± 0.0022 sys ± 0.0010 (68% CL), with the null hypothesis rejected at 4 σ [Stukel et al. , Phys. Rev. Lett. 131 , 052503 (2023) ]. In terms of branching ratio, this unambiguous signal yields I EC 0 = 0.098 % stat ± 0.023 % sys ± 0.010 % , roughly half of the commonly used prediction. This first observation of a third-forbidden unique electron capture improves our understanding of low-energy backgrounds in dark-matter searches and has implications for nuclear-structure calculations. For example, a shell-model based theoretical estimate for the neutrinoless double-beta decay half-life of calcium-48 is increased by a factor of 7 + 3 − 2 . Our nonzero measurement shifts geochronological ages by up to a percent; implications are illustrated for Earth and solar system chronologies.

Physical Review C↗