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Influence of an igneous intrusion on the inorganic geochemistry of a bituminous coal from Pitkin County, Colorado

Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions of the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resources potential for coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.Although the effects of igneous dikes on the organic matter in coal have been observed at many localities there is virtually no information on the effects of the intrusions on the inorganic constituents in the coal. Such a study may help to elucidate the behavior of trace elements during in situ gasification of coal and may provide insights into the resource potential of coal and coke affected by the intrusion. To determine the effects of an igneous intrusion on the inorganic chemistry of a coal we used a series of 11 samples of coal and natural coke that had been collected at intervals from 3 to 106 cm from a dike that intruded the bituminous Dutch Creek coal in Pitkin, CO. The samples were chemically analyzed for 66 elements. SEM-EDX and X-ray diffraction analysis were performed on selected samples. Volatile elements such as F, Cl, Hg, and Se are not depleted in the samples (coke and coal) nearest the dike that were exposed to the highest temperatures. Their presence in these samples is likely due to secondary enrichment following volatilization of the elements inherent in the coal. Equilibration with ground water may account for the uniform distribution of Na, B, and Cl. High concentrations of Ca, Mg, Fe, Mn, Sr, and CO2 in the coke region are attributed to the reaction of CO and CO2 generated during the coking of the coal with fluids from the intrusion, resulting in the precipitation of carbonates. Similarly, precipitation of sulfide minerals in the coke zone may account for the relatively high concentrations of Ag, Hg, Cu, Zn, and Fe. Most elements are concentrated at the juncture of the fluidized coke and the thermally metamorphosed coal. Many of the elements enriched in this region (for example, Ga, Ge, Mo, Rb, U, La, Ce, Al, K, and Si) may have been adsorbed on either the clays or the organic matter or on both.

International Journal of Coal Geology↗

Channel Change in 2007 at Selected Sites on the Marias River, Montana, Following a 2006 High-Flow Release from Tiber Dam

In June 2006, an opportunistic high-flow release was made from Tiber Dam on the Marias River in Montana to investigate possible alternatives for partially restoring the river's natural flow pattern and variability. At two sites along the river, we measured channel geometry in 2006 before and after the high-flow release to evaluate channel change and alteration of physical habitat. Here we provide data from a resurvey of those sites, conducted in August 2007.

Data Series↗

Bathymetric contour maps, surface area and capacity tables, and bathymetric change maps for selected water-supply lakes in north-central and west-central Missouri, 2020

Bathymetric data were collected at 10 water-supply lakes in north-central and west-central Missouri by the U.S. Geological Survey (USGS) in cooperation with the Missouri Department of Natural Resources and in collaboration with various local agencies, as part of a multiyear effort to establish or update the surface area and capacity tables for the surveyed lakes. The lakes were surveyed in June and July 2020. Seven of the lakes had been surveyed by the USGS between 2002 and 2007, and the recent surveys were compared to the earlier surveys to document changes in the bathymetric surface and capacity of the lake and produce a bathymetric change map. Bathymetric data were collected using a high-resolution multibeam mapping system mounted on a boat. Supplemental depth data at two of the lakes were collected in shallow areas with an acoustic Doppler current profiler on a remote-controlled boat. Data points from the various sources were exported at a gridded data resolution appropriate to each lake, either 0.82 foot or 1.64 feet. Data outside the multibeam survey extent and greater than the surveyed water-surface elevation generally were obtained from data collected using aerial light detection and ranging (lidar) point cloud data, except at Holden City Lake. A linear enforcement technique was used to add points to the dataset in areas of sparse data (the upper ends of coves where the water was shallow or aquatic vegetation precluded data acquisition) based on surrounding multibeam and upland data values. The various point datasets were used to produce a three-dimensional triangulated irregular network surface of lake-bottom elevations for each lake. A surface area and capacity table was produced from the three-dimensional surface for each lake showing surface area and capacity at specified lake water-surface elevations. Various quality-assurance tests were conducted to ensure quality data were collected with the multibeam, including beam angle checks and patch tests. Additional quality-assurance tests were conducted on the gridded bathymetric data from the survey, the bathymetric surface created from the gridded data, and the contours created from the bathymetric survey. If data from a previous bathymetric survey existed at a given lake, a bathymetric change map was generated from the elevation difference between the previous survey and the 2020 bathymetric survey data points. After reconciling any vertical datum disagreement between the previous survey and the 2020 survey, coincident points between the surveys were identified, and a bathymetric change map was generated using the coincident point data. A decrease in capacity was observed at nearly all the lakes for which a previous survey existed, and the mean bathymetric change between the surveys was positive at all the lakes. The decrease in capacity at the primary spillway elevation ranged from –0.4 percent at Edwin A Pape Lake to 9.4 percent at upper Higginsville Reservoir. The mean bathymetric change ranged from 0.03 foot at Garden City New Lake to 1.75 feet at Harrisonville City Lake, which corresponds to a time-averaged mean bathymetric change ranging from 0.002 foot per year at Garden City New Lake to 0.132 foot per year at Harrisonville City Lake. The computed volumetric sedimentation rate generally ranged from 0.04 to 4.91 acre-feet per year at Garden City New Lake and Holden City Lake, respectively; however, Harrisonville City Lake had a substantially larger volumetric sedimentation rate of 42.7 acre-feet per year, corresponding to the substantial mean bathymetric change of 1.75 feet and combined with the relatively shorter interval between surveys. Harrisonville City Lake also had the second-largest decrease in capacity at the spillway elevation of 5.9 percent. As with the 2019 surveys, some changes observed in the bathymetric change maps likely result from the difference in data collection equipment and techniques between the surveys. Certain apparent erosional features around the perimeter of certain lakes may be the result of wave action or compaction of sediments exposed to air during low-water years, or may indicate an unidentified but systemic error in the older singlebeam echosounder survey data.

Missouri↗

Hydrogeology, chemical characteristics, and water sources and pathways in the zone of contribution of a public-supply well in San Antonio, Texas

In 2001, the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey initiated a series of studies on the transport of anthropogenic and natural contaminants (TANC) to public-supply wells (PSWs). The main goal of the TANC project was to better understand the source, transport, and receptor factors that control contaminant movement to PSWs in representative aquifers of the United States. Regional- and local-scale study areas were selected from within existing NAWQA study units, including the south-central Texas Edwards aquifer. The local-scale TANC study area, nested within the regional-scale NAWQA study area, is representative of the regional Edwards aquifer. The PSW selected for study is within a well field of six production wells. Although a single PSW was initially selected, because of constraints of well-field operation, samples were collected from different wells within the well field for different components of the study. Data collected from all of the well-field wells were considered comparable because of similar well construction, hydrogeology, and geochemistry. An additional 38 PSWs (mostly completed in the confined part of the aquifer) were sampled throughout the regional aquifer to characterize water quality. Two monitoring well clusters, with wells completed at different depths, were installed to the east and west of the well field (the Zarzamora and Timberhill monitoring well clusters, respectively). One of the monitoring wells was completed in the overburden to evaluate potential hydrologic connectivity with the Edwards aquifer. Geophysical and flowmeter logs were collected from one of the well-field PSWs to determine zones of contribution to the wellbore. These contributing zones, associated with different hydrogeologic units, were used to select monitoring well completion depths and groundwater sample collection depths for depth-dependent sampling. Depth-dependent samples were collected from the PSW from three different depths and under three different pumping conditions. Additionally, selected monitoring wells and one of the well-field PSWs were sampled several times in response to a rainfall and recharge event to assess short-term (event-scale) temporal variations in water quality. For comparison purposes, groundwater samples were categorized as being from regional aquifer PSWs, from the well field (wellhead samples), from the monitoring wells (excluding the overburden well), from the overburden well, from the PSW depth-dependent sampling, and from temporal sampling. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating tracers to characterize geochemical conditions in the aquifer and provide understanding of the mechanisms of mobilization and movement of selected constituents from source areas to a PSW. Sources, tracers, and conditions used to assess water quality and processes affecting the PSW and the aquifer system included (1) carbonate host rock composition; (2) physicochemical constituents; (3) major and trace element concentrations; (4) saturation indices with respect to minerals in aquifer rocks; (5) elemental ratios, such as magnesium to calcium ratios, that are indicative of water-rock interaction processes; (6) oxidation-reduction conditions; (7) nutrient concentrations, in particular nitrate concentrations; (8) the isotopic composition of nitrate, which can point to specific nitrate sources; (9) strontium isotopes; (10) stable isotopes of hydrogen and oxygen; (11) organic contaminant concentrations, including pesticides and volatile organic compounds; (12) age tracers, apparent-age distribution, and dissolved gas data used in age interpretations; (13) depth-dependent water chemistry collected from the PSW under different pumping conditions to assess zones of contribution; and (14) temporal variability in groundwater composition from the PSW and selected monitoring wells in response to an aquifer recharge event. Geochemical results indicate that the well-field and monitoring well samples were largely representative of groundwater in the regional confined aquifer. Constituents of concern in the Edwards aquifer for the long-term sustainability of the groundwater resource include the nutrient nitrate and anthropogenic organic contaminants. Nitrate concentrations (as nitrogen) for regional aquifer PSWs had a median value of 1.9 milligrams per liter, which is similar to previously reported values for the regional aquifer. Nitrate-isotope compositions for groundwater samples collected from the well-field PSWs and monitoring wells had a narrow range, with values indicative of natural soil organic values. A comparison with historical nitrate-isotope values, however, suggests that a component of nitrate in groundwater from biogenic sources might have increased over the last 30 years. Several organic contaminants (the pesticide atrazine, its degradate deethylatrazine, trichloromethane (chloroform; a drinking-water disinfection byproduct), and the solvent tetrachloroethene (PCE)) were widely distributed throughout the regional aquifer and in the local-scale TANC study area at low concentrations (less than 1 microgram per liter). Higher concentrations of PCE were detected in samples from the well-field PSWs and Zarzamora monitoring wells relative to the regional aquifer PSWs. The urban environment is a likely source of contaminants to the aquifer, and these results indicate that one or more local urban sources might be supplying PCE to the Zarzamora monitoring wells and the well-field wells. Samples from the well field also had high concentrations of chloroform relative to the monitoring wells and regional aquifer PSWs. For samples from the regional aquifer PSWs, the most frequently detected organic contaminants generally decreased in concentration with increasing well depth. Deeper wells might intercept longer regional flow paths with higher fractions of older water or water recharged in rural recharge areas in the western part of the aquifer that have been less affected by anthropogenic contaminants. A scenario of hypothetical contaminant loading was evaluated by using results from groundwater-flow-model particle tracking to assess the response of the aquifer to potential contamination. Results indicate that the aquifer responds quickly (less than 1 year to several years) to contaminant loading; however, it takes a relatively long time (decades) for concentrations to reach peak values. The aquifer also responds quickly (less than 1 year to several years) to the removal of contaminant loading; however, it also takes a relatively long time (decades) to reach near background concentrations. Interpretation of geochemical age tracers in this well-mixed karst system was complicated by contamination of a majority of measured tracers and complexities of extensive mixing. Age-tracer results generally indicated that groundwater samples were composed of young, recently recharged water with piston-flow model ages ranging from less than 1 to 41 years, with a median of 17 years. Although a piston-flow model is typically not valid for karst aquifers, the model ages provide a basis for comparing relative ages of different samples and a reference point for more complex hydrogeologic models for apparent-age interpretations. Young groundwater ages are consistent with particle-tracking results from hydrogeologic modeling for the local-scale TANC study area. Age-tracer results compared poorly with other geochemical indicators of groundwater residence time and anthropogenic effects on water quality, indicating that hydrogeologic conceptual models used in groundwater age interpretations might not adequately account for mixing in this karst system. Groundwater samples collected from the well field under a variety of pumping conditions were relatively homogeneous and well mixed for numerous geochemical constituents (with the notable exception of age tracers). Groundwater contributions to the PSW were dominated by well-mixed, relatively homogeneous groundwater, typical of the regional confined aquifer. Zones of preferential flow were determined for the PSW, but groundwater samples from different stratigraphic units were not geochemically distinct. Variations in chemical constituents in response to a rainfall and aquifer recharge event occurred but were relatively minor in the PSW and monitoring wells. This observation is consistent with the hypothesis that the response to individual recharge events in the confined aquifer, unless intersecting conduit flow paths, might be attenuated by mixing processes along regional flow paths. Results of this study are consistent with the existing conceptual understanding of aquifer processes in this karst system and are useful for water-resource development and management practices.

Texas↗

Geological and technological assessment of artificial reef sites, Louisiana outer continental shelf

This paper describes the general procedures used to select sites for obsolete oil and gas platforms as artificial reefs on the Louisiana outer continental shelf (OCS). The methods employed incorporate six basic steps designed to resolve multiple-use conflicts that might otherwise arise with daily industry and commercial fishery operations, and to identify and assess both geological and technological constraints that could affect placement of the structures. These steps include: (1) exclusion mapping; (2) establishment of artificial reef planning areas; (3) database compilation; (4) assessment and interpretation of database; (5) mapping of geological and man-made features within each proposed reef site; and (6) site selection. Nautical charts, bathymetric maps, and offshore oil and gas maps were used for exclusion mapping, and to select nine regional planning areas. Pipeline maps were acquired from federal agencies and private industry to determine their general locations within each planning area, and to establish exclusion fairways along each pipeline route. Approximately 1600 line kilometers of high-resolution geophysical data collected by federal agencies and private industry was acquired for the nine planning areas. These data were interpreted to determine the nature and extent of near-surface geologic features that could affect placement of the structures. Seismic reflection patterns were also characterized to evaluate near-bottom sedimentation processes in the vicinity of each reef site. Geotechnical borings were used to determine the lithological and physical properties of the sediment, and for correlation with the geophysical data. Since 1987, five sites containing 10 obsolete production platforms have been selected on the Louisiana OCS using these procedures. Industry participants have realized a total savings of approximately US $1 500 000 in salvaging costs by converting these structures into artificial reefs. ?? 1993.

Ocean and Coastal Management↗

Landscape conditions predisposing grizzly bears to conflicts on private agricultural lands in the western USA

We used multiple logistic regression to model how different landscape conditions contributed to the probability of human-grizzly bear conflicts on private agricultural ranch lands. We used locations of livestock pastures, traditional livestock carcass disposal areas (boneyards), beehives, and wetland-riparian associated vegetation to model the locations of 178 reported human-grizzly bear conflicts along the Rocky Mountain East Front, Montana, USA during 1986-2001. We surveyed 61 livestock producers in the upper Teton watershed of north-central Montana, to collect spatial and temporal data on livestock pastures, boneyards, and beehives for the same period, accounting for changes in livestock and boneyard management and beehive location and protection, for each season. We used 2032 random points to represent the null hypothesis of random location relative to potential explanatory landscape features, and used Akaike's Information Criteria (AIC/AICC) and Hosmer-Lemeshow goodness-of-fit statistics for model selection. We used a resulting "best" model to map contours of predicted probabilities of conflict, and used this map for verification with an independent dataset of conflicts to provide additional insights regarding the nature of conflicts. The presence of riparian vegetation and distances to spring, summer, and fall sheep or cattle pastures, calving and sheep lambing areas, unmanaged boneyards, and fenced and unfenced beehives were all associated with the likelihood of human-grizzly bear conflicts. Our model suggests that collections of attractants concentrated in high quality bear habitat largely explain broad patterns of human-grizzly bear conflicts on private agricultural land in our study area. ?? 2005 Elsevier Ltd. All rights reserved.

Biological Conservation↗

The Cadiz margin study off Spain: An introduction

The Cadiz continental margin of the northeastern Gulf of Cadiz off Spain was selected for a multidisciplinary project because of the interplay of complex tectonic history between the Iberian and African plates, sediment supply from multiple sources, and unique Mediterranean Gateway inflow and outflow currents. The nature of this complex margin, particularly during the last 5 million years, was investigated with emphasis on tectonic history, stratigraphic sequences, marine circulation, contourite depositional facies, geotechnical properties, geologic hazards, and human influences such as dispersal of river contaminants. This study provides an integrated view of the tectonic, sediment supply and oceanographic factors that control depositional processes and growth patterns of the Cadiz and similar modem and ancient continental margins.

Marine Geology↗

A nonlethal microsampling technique to monitor the effects of mercury on wild bird eggs

Methylmercury is the predominant chemical form of mercury reported in the eggs of wild birds, and the embryo is the most sensitive life stage to methylmercury toxicity. Protective guidelines have been based mainly on captive-breeding studies with chickens (Gallus gallus), mallards (Anas platyrhynchos), and ring-necked pheasants (Phasianus colchicus) or on field studies where whole eggs were collected and analyzed and the effects of the mercury were measured based on the reproductive success of the remaining eggs. However, both of these methods have limitations. As an alternative, we developed a technique that involves extracting a small sample of albumen from a live egg, sealing the egg, returning the egg to its nest to be naturally incubated by the parents, and then relating the hatching success of this microsampled egg to its mercury concentration. After first developing this technique in the laboratory using chicken and mallard eggs, we selected the laughing gull (Larus atricilla) and black-necked stilt (Himantopus mexicanus) as test subjects in the field. We found that 92% of the microsampled laughing gull eggs met our reproductive endpoint of survival to the beginning of hatching compared to 100% for the paired control eggs within the same nests. Microsampled black-necked stilt eggs exhibited 100% hatching success compared to 93% for the paired control eggs. Our results indicate that microsampling is an effective tool for nonlethally sampling mercury concentrations in eggs and, as such, can be used for monitoring sensitive species, as well as for improving studies that examine the effects of mercury on avian reproduction.

Environmental Toxicology and Chemistry↗

The materials flow of mercury in the economies of the United States and the world

Although natural sources of mercury exist in the environment, measured data and modeling results indicate that the amount of mercury released into the biosphere has increased since the beginning of the industrial age. Mercury is naturally distributed in the air, water, and soil in minute amounts, and can be mobile within and between these media. Because of these properties and the subsequent impacts on human health, mercury was selected for an initial materials flow study, focusing on the United States in 1990. This study was initiated to provide a current domestic and international analysis. As part of an increased emphasis on materials flow, this report researched changes and identified the associated trends in mercury flows; it also updates statistics through 1996. In addition to domestic flows, the report includes an international section, because all primary mercury-producing mines are currently foreign, 86 percent of the mercury cell sector of the worldwide chlor-alkali industry is outside the United States, there is a large international mercury trade (1,395 t 1 in 1996), and environmental regulations are not uniform or similarly enforced from country to country. Environmental concerns have brought about numerous regulations that have dramatically decreased both the use and the production of mercury since the late 1980?s. Our study indicates that this trend is likely to continue into the future, as the world eliminates the large mercury inventories that have been stockpiled to support prior industrial processes and products.

Circular↗

Water-quality, stream-habitat, and biological data for Highland and Marchand Bayous, Galveston County, Texas, 2006-07

The U.S. Geological Survey, in cooperation with the Houston-Galveston Area Council and the Texas Commission on Environmental Quality, collected water-quality, stream-habitat, and biological data from five sites on Highland and Marchand Bayous in Galveston County, Texas, during 2006–07. Water-quality data-collection surveys consisted of synoptic 24-hour continuous measurements of water temperature, pH, specific conductance, and dissolved oxygen and periodically collected samples analyzed for several properties and constituents of interest. Bacteria samples were collected monthly at 10 sites on Highland and Marchand Bayous during the study. Stream-habitat data were collected at five sites three times during the study, July–August 2006, March 2007, and July–August 2007. At each site, a representative stream reach was selected. Within this reach, five evenly spaced stream transects were determined. At each transect, stream (wetted channel width, water depth, bottom material, instream cover) and riparian (bank slope and erosion potential, width of natural vegetation, type of vegetation, percentage tree canopy) attributes were measured. Benthic macroinvertebrate and fish data were collected from the same five sites identified for habitat evaluation. Three assessments were done to account for seasonal differences in biotic distribution. Stream-habitat and aquatic biota (benthic macroinvertebrates and fish) were assessed at each site three times during the study to evaluate aquatic life use. A total of 5,126 macroinvertebrate individuals were identified at all sites. During the study, 34 species of fish representing 28 families were collected from all the sites.

Data Series↗

EAARL coastal topography — Northern Gulf of Mexico, 2007: Bare earth

These remotely sensed, geographically referenced elevation measurements of Lidar -derived bare earth ( BE ) topography were produced as a collaborative effort between the U.S. Geological Survey ( USGS ), Florida Integrated Science Center ( FISC ), St. Petersburg, FL ; the National Park Service ( NPS ), Gulf Coast Network, Lafayette, LA ; and the National Aeronautics and Space Administration ( NASA ), Wallops Flight Facility, VA . The purpose of this project is to provide highly detailed and accurate datasets of select barrier islands and peninsular regions of Louisiana, Mississippi, Alabama, and Florida, acquired on June 27-30, 2007. The datasets are made available for use as a management tool to research scientists and natural resource managers. An innovative airborne Lidar instrument originally developed at the NASA Wallops Flight Facility, and known as the Experimental Advanced Airborne Research Lidar ( EAARL ), was used during data acquisition. The EAARL system is a raster-scanning, waveform-resolving, green-wavelength (532-nanometer) Lidar designed to map near-shore bathymetry, topography, and vegetation structure simultaneously. The EAARL sensor suite includes the raster-scanning, water-penetrating full-waveform adaptive Lidar , a down-looking red-green-blue ( RGB ) digital camera, a high-resolution multi-spectral color infrared ( CIR ) camera, two precision dual-frequency kinematic carrier-phase GPS receivers, and an integrated miniature digital inertial measurement unit which provide for submeter georeferencing of each laser sample. The nominal EAARL platform is a twin-engine Cessna 310 aircraft, but the instrument may be deployed on a range of light aircraft. A single pilot, a Lidar operator, and a data analyst constitute the crew for most survey operations. This sensor has the potential to make significant contributions in measuring sub-aerial and submarine coastal topography within cross-environmental surveys. Elevation measurements were collected over the survey area using the EAARL system and the resulting data were then processed using the Airborne Lidar Processing System ( ALPS ), a custom-built processing system developed in a NASA - USGS collaboration. ALPS supports the exploration and processing of Lidar data in an interactive or batch mode. Modules for presurvey flight line definition, flight path plotting, Lidar raster and waveform investigation, and digital camera image playback have been developed. Processing algorithms have been developed to extract the range to the first and last significant return within each waveform. ALPS is used routinely to create maps that represent submerged or sub-aerial topography. Specialized filtering algorithms have been implemented to determine the 'bare earth' under vegetation from a point cloud of last return elevations.

northern Gulf of Mexico↗

The 3D Elevation Program—Supporting Ohio's economy

Introduction High-quality elevation data are proving to be a resource of great economic value in dealing with many important issues in Ohio. Current and accurate high-resolution elevation data support flood risk management, water quantity and quality assessment, precision farming, conservation planning, impervious-surface modeling, forest and other natural resources management, abandoned mine and geologic hazard assessment, karst mapping, and siting of wellhead pads for horizontal drilling. These data also support coastal zone management, traffic safety and preliminary engineering site-selection studies for transportation infrastructure, solar potential and other renewable energy planning, aviation safety, and identification of features of interest or concern such as archaeological sites and orphan oil and gas wells. Critical applications that meet the State’s management needs depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features.

Ohio↗

Conservation Effects Assessment Project-Wetlands assessment in California's Central Valley and Upper Klamath River Basin

Executive Summary-Ecosystem Services Derived from Wetlands Reserve Program Conservation Practices in California's Central Valley and Oregon's Upper Klamath River Basin. The Wetlands Reserve Program (WRP) is one of several programs implemented by the U.S. Department of Agriculture (USDA). Since the WRP's inception in 1990, it has resulted in the restoration of approximately 29,000 hectares in California's Central Valley (CCV) and roughly 12,300 hectares in Oregon's Upper Klamath River Basin (UKRB). Both the CCV and UKRB are agricultural dominated landscapes that have experienced extensive wetland losses and hydrological alteration. Restored habitats in the CCV and UKRB are thought to provide a variety of ecosystem services, but little is known about the actual benefits afforded. The U.S. Geological Survey (USGS) California Cooperative Fish and Wildlife Unit in collaboration with the USDA Natural Resources Conservation Service surveyed 70 WRP sites and 12 National Wildlife Refuge sites in the CCV, and 11 sites in the UKRB to estimate ecosystem services provided. In the CCV, sites were selected along three primary gradients; (1) restoration age, (2) management intensity, and (3) latitude (climate). Sites in the UKRB were assessed along restoration age and management intensity gradients where possible. The management intensity gradient included information about the type and frequency of conservation practices applied at each site, which was then ranked into three categories that differentiated sites primarily along a hydrological gradient. Information collected was used to estimate the following ecosystem services: Soil and vegetation nutrient content, soil loss reduction, floodwater storage as well as avian, amphibian, fish, and pollinator use and habitat availability. Prior to this study, very little was known about WRP habitat morphology in the CCV and UKRB. Therefore in this study, we described these habitats and related them to ecosystem services provided. Our results indicate that although WRP in the CCV and UKRB provide a number of benefits, there may be management mediated trade-offs among ecosystem services. In this report, we considered ecosystem services at the site-specific scale; however, future work will extend to include effects of WRP relative to surrounding cropland.

California↗

Ground-Water Quality of the Northern High Plains Aquifer, 1997, 2002-04

An assessment of ground-water quality in the northern High Plains aquifer was completed during 1997 and 2002-04. Ground-water samples were collected at 192 low-capacity, primarily domestic wells in four major hydrogeologic units of the northern High Plains aquifer-Ogallala Formation, Eastern Nebraska, Sand Hills, and Platte River Valley. Each well was sampled once, and water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, pesticides and pesticide degradates, dissolved solids, major ions, trace elements, dissolved organic carbon (DOC), radon, and volatile organic compounds (VOCs). Tritium and microbiology were analyzed at selected sites. The results of this assessment were used to determine the current water-quality conditions in this subregion of the High Plains aquifer and to relate ground-water quality to natural and human factors affecting water quality. Water-quality analyses indicated that water samples rarely exceeded established U.S. Environmental Protection Agency public drinking-water standards for those constituents sampled; 13 of the constituents measured or analyzed exceeded their respective standards in at least one sample. The constituents that most often failed to meet drinking-water standards were dissolved solids (13 percent of samples exceeded the U.S. Environmental Protection Agency Secondary Drinking-Water Regulation) and arsenic (8 percent of samples exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level). Nitrate, uranium, iron, and manganese concentrations were larger than drinking-water standards in 6 percent of the samples. Ground-water chemistry varied among hydrogeologic units. Wells sampled in the Platte River Valley and Eastern Nebraska units exceeded water-quality standards more often than the Ogallala Formation and Sand Hills units. Thirty-one percent of the samples collected in the Platte River Valley unit had nitrate concentrations greater than the standard, 22 percent exceeded the manganese standard, 19 percent exceeded the sulfate standard, 26 percent exceeded the uranium standard, and 38 percent exceeded the dissolved-solids standard. In addition, 78 percent of samples had at least one detectable pesticide and 22 percent of samples had at least one detectable VOC. In the Eastern Nebraska unit, 30 percent of the samples collected had dissolved-solids concentrations larger than the standard, 23 percent exceeded the iron standard, 13 percent exceeded the manganese standard, 10 percent exceeded the arsenic standard, 7 percent exceeded the sulfate standard, 7 percent exceeded the uranium standard, and 7 percent exceeded the selenium standard. No samples exceeded the nitrate standard. Thirty percent of samples had at least one detectable pesticide compound and 10 percent of samples had at least one detectable VOC. In contrast, the Sand Hills and Ogallala Formation units had fewer detections of anthropogenic compounds and drinking-water exceedances. In the Sand Hills unit, 15 percent of the samples exceeded the arsenic standard, 4 percent exceeded the nitrate standard, 4 percent exceeded the uranium standard, 4 percent exceeded the iron standard, and 4 percent exceeded the dissolved-solids standard. Fifteen percent of samples had at least one pesticide compound detected and 4 percent had at least one VOC detected. In the Ogallala Formation unit, 6 percent of water samples exceeded the arsenic standard, 4 percent exceeded the dissolved-solids standard, 3 percent exceeded the nitrate standard, 2 percent exceeded the manganese standard, 1 percent exceeded the iron standard, 1 percent exceeded the sulfate standard, and 1 percent exceeded the uranium standard. Eight percent of samples collected in the Ogallala Formation unit had at least one pesticide detected and 6 percent had at least one VOC detected. Differences in ground-water chemistry among the hydrogeologic units were attributed to variable depth to water, depth of the well screen below the water table, reduction-oxidation conditions, ground-water residence time, interactions with surface water, composition of aquifer sediments, extent of cropland, extent of irrigated land, and fertilizer application rates.

Scientific Investigations Report↗

Mechanisms of aquatic species invasions across the South Atlantic Landscape Conservation Cooperative region

Invasive species are a global issue, and the southeastern United States is not immune to the problems they present. Therefore, various analyses using modeling and exploratory statistics were performed on the U.S. Geological Survey Nonindigenous Aquatic Species (NAS) Database with the primary objective of determining the most appropriate use of presence-only data as related to invasive species in the South Atlantic Landscape Conservation Cooperative (SALCC) region. A hierarchical model approach showed that a relatively small amount of high-quality data from planned surveys can be used to leverage the information in presence-only observations, having a broad spatial coverage and high biases of observer detection and in site selection. Because a variety of sampling protocols can be used in planned surveys, this approach to the analysis of presence-only data is widely applicable. An important part of the management of natural landscapes is the preservation of designated protected areas. When the hydrologic connection was considered in this analysis, the number of potential invaders that could spread to each protected area within the SALCC region was greatly increased, with a mean exceeding 30 species and the maximum reaching 57 species. Nearly all protected areas are hydrologically connected to at least 20 nonindigenous aquatic species. To examine possible factors which may contribute to nonindigenous aquatic species richness in the SALCC region, a set of exploratory statistics was employed. The best statistical model that included a combination of three anthropogenic variables (densities of housing, roads, and reservoirs) and two environmental variables (elevation range and longitude) explained approximately 62 percent of the variation in introduced species richness. Highest nonindigenous aquatic species richness occurred in the more upland, mountainous regions, where elevation range favored reservoirs and attracted urban centers. Lastly, patterns seen in a diffusion model may reflect less about the diffusion process of the organism and more about the opportunistic nature of the data collection process. These results of the model are considered exploratory in nature.

Alabama, Florida, Georgia, North Carolina, South C↗

Evaluation of water quality and bulk atmospheric deposition in the Guanella Pass area, Clear Creek and Park Counties, Colorado, water year 1995

A study of water quality and bulk atmospheric deposition in the Guanella Pass area during water year 1995 (October 1994 to September 1995) has provided information to characterize conditions in the South Clear Creek and Geneva Creek Basins about 40 miles west of Denver, Colorado, prior to a possible roadreconstruction project. Analytical results of water samples collected from streams, ground water, and lakes and reservoirs indicate that water in the study area generally contained small concentrations of dissolved solids (low-flow stream sample median, 43 milligrams per liter; ground-water median, 104 milligrams per liter) and suspended sediment (high-flow stream sample median, 115 milligrams per liter). Nutrient, trace-element, and organic-carbon concentrations also were small. Acidic pH and large trace-element concentrations were associated with areas affected by natural acid-sulfate weathering or mining. Increases in particulate nutrients, total recoverable trace elements, and suspended sediment were related to seasonal snowmelt and thunderstorms. Benthic macroinvertebrate and periphyton (algae) samples collected from selected sites in August 1995 indicated large variability in characteristics among sites. Macroinvertebrate density ranged from 6.5 to 1,300 organisms per square meter, and periphyton biovolume ranged from 0.023 to 4,700 x 10 6 cubic microns per square centimeter. The discharge of road runoff from any single drainage feature (ditch or culvert) was small compared to streamflows. Analytical results from samples of road runoff indicated a large range in specific conductance, pH in a neutral range, large values of turbidity, and calcium bicarbonate type water. Sodium or magnesium and chloride, however, were predominant in some samples and were probably related to applications of sodium and magnesium chloride to the roads. Although dissolved nutrients and trace elements were detected in samples of road runoff, particulate forms had the largest concentrations. Suspended-sediment concentrations in road runoff were large, and the sediment was primarily fine grained. Large concentrations of dissolved and total recoverable nutrients, total recoverable trace elements, total organic carbon, and suspended sediment in road runoff could cause increased concentrations in streams, lakes, and reservoirs. Ground-water concentrations of chloride, nitrite plus nitrate, and dissolved iron and manganese·could increase if the large concentrations present in road runoff infiltrate shallow aquifers. Bulk atmospheric deposition was collected at three sites with a paved road surface, five sites with a gravel or dirt surface, and five sites with collectors at least 500 feet away from a road. The median bulk -atmospheric-deposition rate for gravel (or dirt) roads was 106 times the median rate at a reference site (located at least 500 feet away from a road) and 39 times the median rate at a typical paved road site. If a stream, lake, or reservoir is located near the road, bulk-atmospheric- deposition products may settle directly onto open water or be washed in by surface runoff. Because the predominant road-runoff trace-element phase is particulate, potential toxic effects on receiving water may be minimal when compared to aquatic-life standards and regulations in the State of Colorado, which are primarily based on dissolved concentrations. U.S. Environmental Protection Agency primary maximum contaminant levels for drinking water were exceeded for dissolved uranium (proposed) in one ground-water sample.

Colorado↗

Data standardization. The key to effective management

Effective management of the nation's water resources is dependent upon accurate and consistent hydrologic information. Before the emergence of environmental concerns in the 1960's, most hydrologic information was collected by the U.S. Geological Survey and other Federal agencies that used fairly consistent methods and equipment. In the past quarter century, however, increased environmental awareness has resulted in an expansion of hydrologic data collection not only by Federal agencies, but also by state and municipal governments, university investigators, and private consulting firms. The acceptance and use of standard methods of collecting and processing hydrologic data would contribute to cost savings and to greater credibility of flow information vital to responsible assessment and management of the nation's water resources. This paper traces the evolution of the requirements and uses of open-channel flow information in the U.S., and the sequence of efforts to standardize the methods used to obtain this information in the future. The variable nature of naturally flowing rivers results in continually changing hydraulic properties of their channels. Those persons responsible for measurement of water flowing in open channels (streamflow) must use a large amount of judgement in the selection of appropriate equipment and technique to obtain accurate flow information. Standardization of the methods used in the measurement of streamflow is essential to assure consistency of data, but must also allow considerable latitude for individual judgement to meet constantly changing field conditions.

Conference Paper↗

The role of the USFWS geographic information system in coastal decisionmaking

Unprecedented demand on coastal resources in the 1980's has generated a need for valid information and analyses to support wise management of the coastal zone. The National Coastal Ecosystems Team of the U.S. Fish and Wildlife Service recently implemented a geographic information system to enhance its ability to analyze and display environmental information about the coastal zone. Outputs from this system have been presented to the State of Louisiana Senate and House Committees on Natural Resources and to the Congressional House of Representatives Committee on Merchant Marine and Fisheries. The purpose of this paper is to describe the use of the Map Overlay Statistical System for addressing selected coastal issues and to discuss its utility for coastal decisionmaking.

Alabama, Florida, Louisiana, Mississippi, Texas↗