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Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Post-glacial stratigraphy and late Holocene record of great Cascadia earthquakes in Ozette Lake, Washington, USA

Ozette Lake is an ~100-m-deep coastal lake located along the outer coast of the Olympic Peninsula (Washington, USA); it is situated above the locked portion of the northern Cascadia megathrust but also relatively isolated from active crustal faults and intraslab earthquakes. Here we present a suite of geophysical and geological evidence for earthquake-triggered mass transport deposits (MTDs) and related turbidite deposition in Ozette Lake since ca. 14 ka. Comprehensive high-resolution bathymetry data, seismic reflection profiles, and sediment cores are used to characterize the post-glacial stratigraphic framework and examine paleoseismic evidence in the lacustrine sediments. Stacked sequences of MTDs along the steep eastern flanks of the lake appear to grade basin-ward from thick, chaotic, blocky masses to thin, parallel-bedded turbidite beds. The discrete turbidite event layers are separated by fine-grained (silt and clay) lake sedimentation. The event layers are observed throughout the lake, but the physical characteristics of the deposits vary considerably depending on proximity to primary depocenters, steep slopes, and subaqueous deltas. A total of 30–34 event deposits are observed in the post-glacial record. Radiometric dating was used to reconstruct a detailed sedimentation history over the last ~5.5 k.y., develop an age model, and estimate the recurrence (365–405 yr) for the most recent 12 event layers. Based on sedimentological characteristics, temporal overlap with other regional paleoseismic chronologies, and recurrence estimates, at least 10 of the dated event layers appear to be sourced from slope failures triggered by intense shaking during megathrust ruptures; the recurrence interval for these 10 events is 440–560 yr. Thus, Ozette Lake contains one of the longest and most robust geological records of repeated shaking along the northern Cascadia subduction zone.

Washington

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

Preliminary bedrock geologic map of the Port Henry quadrangle, Essex County, New York, and Addison County, Vermont

Introduction The bedrock geology of the 7.5-minute Port Henry quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 Ga (giga-annum). In the Port Henry quadrangle, the AMCG metaigneous rocks (Yhg, Ygb, Yanw) intruded older, mostly metasedimentary rocks of the Grenville Complex during the middle to late Shawinigan orogeny (~1,160–1,150 Ma [mega-annum]). All rocks were subsequently metamorphosed to upper amphibolite to granulite facies conditions during the 1,080–1,050 Ma Ottawan orogeny. New mapping reveals four periods of deformation: (1) D1 produced rarely preserved isoclinal folds in the paragneiss and marble and predates AMCG magmatism. (2) Subsequent D2 deformation produced the dominant gneissic fabric preserved in the rock, recumbent folding, and deformed all the Proterozoic units in the map area. Syn- to late-D2 felsic magmatism resulted in the regionally extensive Lyon Mountain Granite Gneiss, which hosts numerous magnetite ore bodies. (3) Mylonitic extensional shear zones and core complex formation marked the beginning of D3 deformation. Protracted D3 deformation resulted in F3 upright folding, dome and basin formation, pegmatite intrusion, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron-ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. (4) D4 created northeast- and northwest-trending local high-grade ductile shear zones and boudinage, northwest-trending regional kilometer (km)-wide ductile shear zones, and crosscutting granitic pegmatite dikes. The development of the late-stage regional shear zones (D4) was likely due to the continuation of extensional doming and uplift from upper amphibolite facies conditions at the end of the Ottawan orogeny. The majority of iron-ore deposits in the Port Henry and adjacent Witherbee quadrangles are in the hanging wall of these extensional shear zones. In the Port Henry quadrangle, the km-wide Cheney Mountain shear zone is the result of D4 deformation. Kilometer-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician carbonate bank on the ancient margin of Laurentia. The approximately 1-km-thick Cambrian to Ordovician stratigraphy records a transition from synrift clastics to passive-margin peritidal carbonate buildups to gradually deeper-water subtidal- to shelf-carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Open-File Report includes a bedrock geologic map; a description of map units; a correlation of map units; and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information.

New York, Vermont

Determining Volcanic Risk in Auckland (DEVORA) Research Programme—A transdisciplinary approach to address the challenge of distributed volcanism in an urban environment

The Determining Volcanic Risk in Auckland (DEVORA) Research Programme was launched in 2008 to address the challenges associated with monogenetic volcanism in an urban setting and to enhance volcanic risk management in Tāmaki Makaurau Auckland in Aotearoa New Zealand. It is a multi-agency, increasingly transdisciplinary (defined here as research that transcends traditional disciplinary boundaries by integrating diverse types of knowledge, perspectives, and methods from academic and non-academic participants to create novel solutions to complex problems), and collaborative research program jointly led by Waipapa Taumata Rau University of Auckland and Earth Sciences New Zealand (ESNZ; formerly GNS Science), with core funding from Natural Hazards Commission Toka Tū Ake (NHC; formerly the Earthquake Commission, EQC) and Te Kaunihera o Tāmaki Makaurau Auckland Council (AC). The primary research focus of DEVORA is to investigate the geologic history, volcanic hazards, and risk posed by the basaltic intraplate Auckland Volcanic Field. Disruption from ash fall and gas from other Aotearoa New Zealand volcanoes is also considered. DEVORA’s work to explore exposure and vulnerability in Tāmaki Makaurau Auckland is also useful for assessing risks from other non-volcanic natural hazards, such as seismic and tsunami hazards. The greater Tāmaki Makaurau Auckland region has an ethnically and socio-economically diverse population of approximately 1.7 million, representing about one-third of the Aotearoa New Zealand population, and hosts critical infrastructure of national significance. The size and nature of the populace, consequential economic base, and important infrastructure within Tāmaki Makaurau Auckland mean that the effects of a volcanic eruption would be felt nationally, including through the disruption of air travel to Aotearoa New Zealand. The hazards from such an eruption could potentially affect hundreds of thousands of people, businesses, and lifelines (critical infrastructure). A considerable challenge for emergency and risk managers is the monogenetic nature of the volcanic field. It is not known where or when the next eruption will occur, how much warning we may get before an eruption, nor how an eruption and its effects might unfold. In this contribution, we highlight the concept and collaborative intent of the DEVORA Programme and show how it has evolved over the 16 years since its inception. We describe how DEVORA has unified more than 100 researchers (including more than 50 graduate students) and numerous stakeholders to address key issues facing Tāmaki Makaurau Auckland and describe how research findings are being implemented into policy and communicated to stakeholder agencies and the public. We also illustrate the broader influence of the DEVORA Programme and provide some learnings that might benefit others embarking on similar integrated projects, especially those focused on distributed volcanism in and near populated areas.

Auckland

Vegetation cover and composition in environments surrounding uranium mines in the Grand Canyon ecosystem, Northern Arizona

Mining uranium from breccia-pipe deposits in the greater Grand Canyon region has occurred since the mid-1900s. However, possible ecosystem contamination with harmful levels of radionuclides may have occurred due to mining activities in the 21st century. In response, a 20-year Federal moratorium on new mining claims in the Grand Canyon watershed was initiated in 2012, to allow time to evaluate the potential effects of uranium exploration and mining on human health, wildlife, and water resources. This moratorium, nor the 2023 designation of the “Baaj Nwaavjo I’tah Kukveni–Ancestral Footprints of the Grand Canyon National Monument,” precludes operation or development of mining claims predating 2012. Vegetation is a core ecosystem component that may be affected by uranium mining (for instance, through uptake and storage of radionuclides from the air or soil) or may act as a vector of exposure to wildlife, livestock, and humans (for instance, via their consumption of contaminated plant tissues). To provide baseline information about the plant communities associated with uranium mines in the Grand Canyon region, the U.S. Geological Survey surveyed an approximately 200-meter-wide buffer surrounding four breccia-pipe deposits, each in a unique stage of mine development, and at one reference area (a livestock water tank) that underwent ground disturbance but contains no mineral deposits. We sectioned the buffer zones into 0.65–4.52 hectare plots, within which we (1) inventoried all plant species, (2) measured percent cover of plant species, plant functional groups, and ground surface types (dark cyanobacteria, lichen, moss, bedrock, rock, embedded litter, duff, plant bases, and bare soil) using line-point intercept, and (3) measured length and frequency of gaps between perennial plant canopies using canopy gap intercept. We found that plant composition at the mines and the reference area differed from one another but were all characteristic of expected regional vegetation patterns. We provide this data summary as potential baseline information for future research and management efforts.

Arizona

Small earthquake moment magnitude and implications for frequency–magnitude scaling of injection induced earthquakes of the Raton Basin

Accurate estimation of earthquake source parameters—such as moment magnitudes, corner frequencies, and stress drops—is essential for improving seismic hazard assessments and understanding earthquake physics. In this study, moment magnitudes ( M W ) are calculated for 31,581 earthquakes associated with wastewater injection in the Raton Basin (located along the border between northern New Mexico and southern Colorado) between 2016 and 2024 using radiative transfer theory to fit coda decay envelopes. Our results show that it is feasible to estimate moment magnitudes down to M W ~1 with coda envelopes from a small local monitoring network. Significant differences were found between M W and local magnitudes ( M L ) for small earthquakes ( M < 3.0). A linear relationship was optimized to convert M L to M W : M W = 0.7 M L + 0.96 and M W = 0.73 M L + 0.99 (for the events reported by the U.S. Geological Survey), which can be applied in future studies of Raton Basin seismicity. We find that b -values calculated employing different methods and using M L are approximately 1.0, while those using M W range from 1.2 to 1.4. A larger estimate of the b -value could influence interpretations of the statistical behavior of earthquakes associated with injection and consequently seismic hazard assessments based on a magnitude–frequency distribution. The potential differences between local versus moment magnitude-based earthquake statistics should be considered in other seismically active regions.

Colorado, New Mexico

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Assessing spatial variability of nutrients, phytoplankton, and related water-quality constituents in the California Sacramento–San Joaquin Delta at the landscape scale—2018 high resolution mapping surveys

Executive Summary This study examined the abundance and distribution of nutrients and phytoplankton in the tidal aquatic environments of the Sacramento–San Joaquin Delta (Delta) and Suisun Bay, comprising three spatial surveys conducted in May, July, and October of 2018 that used continuous underway high frequency sampling and measurements onboard a high-speed boat to characterize spatial variation across the extent of the Delta. The method used involves simultaneously collecting information about the concentration and spatial distribution of all major nutrient forms with analogous information about the major classes of phytoplankton and associated water-quality conditions. The results showed substantial variation across space and time, providing an unprecedented snapshot of the dynamic environmental processes that shape the ways nutrients interact with and affect aquatic habitats in the Delta. The purposes of this study were to improve our understanding of how hydrodynamics, landscape features, and aquatic primary productivity interact to drive nutrient cycling and transport in the Delta and to provide insights into the underlying processes most directly responsible for the conditions at the time of this study, and thus into the range of conditions that may be expected following the wide array of prospective future changes to the Delta. One major anticipated change at the time of this study was the planned upgrade to the Sacramento Regional Wastewater Treatment Plant, but the study also informs our understanding of potential effects from other changes to the Delta, such as those caused by other nutrient-management actions, flow actions, large-scale wetland restoration, drought, flood, levee failure, and changes to water management. Nutrient loading is the primary driver of nutrient concentrations in the Delta, but several other major drivers interact to shape their distribution and effects: geomorphology, hydrodynamics, landscape features, and aquatic productivity. Hydrodynamics affect timescales of transport and dilution of nutrient loads in the Delta. During transit through the system, channel geometry, tidal mixing, and water exports affect hydrodynamics in diverse ways that influence water-residence and transport times, thereby markedly affecting the range of times during which natural internal cycling can alter nutrient concentrations and forms. Channel geometry and location shape tidal energy and river currents into these observed dynamics. Interactions with Delta aquatic landscapes such as herbaceous tidal marsh, submerged aquatic vegetation, and large expanses of intertidal or subtidal sediments (all highly productive landscapes) exert demand on available nutrient supplies but can also simultaneously transform and generate nutrients. Finally, while phytoplankton require nutrients to sustain production and thus are a potential nutrient sink, the amount and form of nutrients also can influence the occurrence of harmful algal blooms (HABs) that adversely affect aquatic organisms as well as affect the occurrence of beneficial algal blooms that result in production of algae that are favorable for imperiled Delta pelagic aquatic food webs. The surveys revealed a complex mosaic of spatial variation, with nutrient concentrations varying from near zero to well above concentrations considered eutrophic; nutrient concentrations were more often related to the extent of hydrologic transport and mixing than to specific geographic locations or to specific landscape features. Similarly, the surveys identified phytoplankton abundance ranging from near detection to the level of large phytoplankton blooms, with large variation in phytoplankton community composition. Although the study occurred during a period of low bloom activity, phytoplankton productivity appeared to be the strongest potential sink for inorganic nutrients in the Delta, indicating that it is a larger control on nutrient concentrations and distribution than previously understood. Cycling and transformation within the water column only appeared to substantially lower total nutrient concentrations at the longest estimated transport timescales. Contrary to expectations, we did not observe substantial nutrient depletion near landscape-scale features such as open-water habitats, submerged aquatic vegetation beds, extensive wetlands, or exposed sediments, indicating that these habitat types did not act as major sinks for nutrients in the Delta during these surveys. These results indicated that nutrient reduction efforts may have the greatest effect on pelagic phytoplankton productivity in the more productive reaches of the Delta and estuary, but these effects are unlikely to be magnified by changes to nutrient loss within the Delta over conceivable changes in flow conditions, Delta water management actions, or large-scale wetland restoration activities. Nevertheless, local processes were shown to cause substantial loss, and thus integrating of nutrient effects with other indicators of aquatic habitat conditions will help inform planning future actions at specific sites. Finally, we note that the primary contribution of this study was intended to be the survey data themselves. Aside from the results highlighted in this report, the surveys are a benchmark against which future environmental change may be evaluated, including changes to nutrient management or water exports, drought, large-scale wetland restoration, and climate change. Further, although we highlight some of the main findings from the surveys in this report, the necessarily limited scope precludes examination of many topics for which these surveys may be highly informative. To facilitate the utility of these data to stakeholders, managers, and researchers, we have released the data online (Bergamaschi and others, 2020) and created an online data exploration portal ( https:​//ca.water​.usgs.gov/​bay-​delta/​2018-​delta-​wide-​mapping-​surveys.html ) where users may query the surveys in a variety of ways to test hypotheses, examine relationships, assess spatial trends, and download data. The data exploration portal is intended to be an immersive experience that allows users to gain greater understanding of the complex interactions that shape Delta aquatic environments. This report is intended as a companion to the portal, allowing the reader to challenge and further explore the highlighted findings. This study was a collaboration between the U.S. Geological Survey and the Delta Regional Monitoring Program, with additional funding provided from U.S. Geological Survey Cooperative Matching Funds Program.

California

The Great Lakes Geologic Mapping Coalition—Working collaboratively to understand the geology of the Great Lakes Region

Introduction The Great Lakes Geologic Mapping Coalition (GLGMC), commonly referred to as the “Coalition,” is a partnership between the U.S. Geological Survey (USGS), the U.S. States of Illinois, Indiana, Michigan, Minnesota, New York, Ohio, Pennsylvania, and Wisconsin and the Canadian province of Ontario. The member States receive funding for geologic mapping work from the USGS National Cooperative Geologic Mapping Program (NCGMP), whereas Ontario participates as a nonfunded partner. The mission of the GLGMC is to produce three-dimensional (3D) geologic maps that depict unconsolidated sediments and near-surface bedrock in the Great Lakes region of North America. Geologic maps are the basis of most earth science investigations and help support resource exploration (energy, minerals, groundwater), natural hazard mitigation, infrastructure development, and land-use planning, all of which can be used to advance economic development and strengthen national security in the Great Lakes region. During the last few million years, the Great Lakes region has experienced repeated glacial advances and retreats, leaving behind extensive sediments, abundant natural resources, and widespread effects on the underlying bedrock geology (Swezey and others, 2022). Linked by shared histories of past glaciations, industrial agriculture, and legacy automotive, coal, steel, and manufacturing industries, the GLGMC member States collaborate to improve the understanding of the 3D distribution of the sediments overlying the region’s bedrock (fig. 1). Developing a comprehensive subsurface 3D framework of this glaciated terrain can provide earth science data to policymakers at all levels. These insights facilitate informed decisions on the exploration, use, and protection of vital resources, such as critical minerals, industrial materials, and aquifers, thereby supporting economic prosperity and the well-being of the citizens of this region. Since its inception in 1998, the Coalition has completed more than 100 geologic mapping projects across the Great Lakes region. Each project aims to deliver geologic maps, 3D datasets, and other information that improves understanding of the geology of the Great Lakes region, with an emphasis on economic and water resources. Key deliverables include 3D geologic maps and models typically portraying sediment thickness, often derived from top-of-bedrock and borehole data. These products are developed through a combination of fieldwork, subsurface modeling, and the collection and analysis of rock and sediment cores. To support Coalition goals, member States collaborate with scientists working on related STATEMAP, EDMAP, and FEDMAP projects. Coalition scientists also engage with Tribal Nations in the Great Lakes region to ensure that Tribal interests pertaining to Coalition work are addressed. Through this collaboration, the Coalition unites the efforts of State, Federal, and Tribal Nation stakeholders to advance geologic data production and enhance understanding of the geologic resources of the Great Lakes region.

Illinois, Indiana, Michigan, Minnesota, New York,

Wind River subbasin restoration: Annual report of U.S. Geological Survey activities January 2024 through December 2024

We sampled juvenile wild Oncorhynchus mykiss (Steelhead Trout) in headwater streams of the Wind River, Washington, to characterize population attributes and investigate life-history metrics, particularly migratory patterns, and early life-stage survival. Additionally, this sampling provides an index of abundance of non-native Brook Trout Salvelinus confluentus . We used passive integrated transponder (PIT) tagging and a series of instream PIT-tag interrogation systems (PTISs) to track juveniles and adults. The Wind River subbasin is considered a wild Steelhead refuge by Washington Department of Fish and Wildlife (WDFW). No hatchery Steelhead Trout have been released in the Wind River subbasin since 1997, and hatchery adults are estimated at less than one percent of spawners in most years. Over 25 years of Steelhead Trout status and trend monitoring and research in the subbasin is contributing to understanding of population response to numerous restoration actions in the subbasin, including removal of Hemlock Dam from Trout Creek in 2009, which had an inadequate adult ladder and contributed to increased water temperatures, to near lethal levels for salmonids. Data from our study, and companion work by WDFW, are contributing to the Columbia Basin Fish and Wildlife Program (2009) Research, Monitoring, and Evaluation (RM&E) Strategy of Fish Population Status Monitoring. Specifically, this work addresses the sub-strategies of 1) Assessing the Status and Trends of Diversity of Natural Origin Fish Populations and Uncertainties Research regarding differing life histories of a wild Steelhead Trout population, 2) Assessing the Status and Trend of Adult Natural Origin Fish Populations, and 3) Monitoring and Evaluating the Effectiveness of Tributary Habitat Actions Relative to Environmental, Physical, or Biological Performance Objectives. During summer and fall 2024, we PIT-tagged 2,075 Steelhead Trout parr (age-0 and age-1), in the Trout Creek and upper Wind River watersheds. Age-0 and age-1 parr were at high abundance due to strong spawner numbers in 2023 and 2024 (Estimate of 932 in 2023; and a moderate number of spawners in 2024 though an estimate is not available at this time; 24-year median = 619; Charlie Cochran, WDFW Fish Biologist, personal commun., 2025). An additional 100 parr (age-0 and age-2 or older) were tagged to provide fish for estimating detection efficiencies at PTISs. Steelhead Trout parr were recaptured and detected through repeat headwater sampling, smolt trapping, instream PTISs and Columbia River mainstem PIT-tag detection. We maintained and upgraded six instream PTISs to detect PIT-tagged Steelhead Trout parr, smolts, and adults, providing data for population assessments, and life-cycle research. Detection data from PIT-tagged adult Steelhead Trout at our four primary PTISs allow assessment of adult escapement to tributary watersheds within the Wind River subbasin. Most adult Steelhead detected were tagged by WDFW at an adult trap in the lower Wind River and some as smolts at screw traps. Adult Steelhead Trout detection efficiency estimates at our primary PTIS in Trout Creek have been greater than 99 percent during eight of the past ten years and have exceeded 97% at our primary PTIS in the Wind River during nine of the past ten years. Adult escapement estimates to tributary watersheds are helping evaluate the efficacy of the 2009 removal of Hemlock Dam from rkm 2.0 of Trout Creek. Detections at the instream PTISs have shown trends of age-0 and age-1 Steelhead Trout parr emigration from natal areas during summer and fall, in addition to the expected movement of parr and smolts in spring. Our data suggest that most fish from a cohort that migrate downstream will do so at age-1 for additional rearing in the subbasin. We have estimated that from 15% to 56% of parr tagged as age-0 fish in headwater areas make downstream migrations at age-1 for additional rearing (median = 29%). We have estimated that from 1% to 27% of Steelhead Trout parr, tagged as age-1 fish, make downstream migrations during fall (median = 3.5%): this is especially pronounced in the upper Wind River portion of the watershed (median 10%). These findings raise questions about parr rearing habitat and whether migrations are density- or habitat-quality driven, and answers to such questions are long-term goals of this study as active and passive habitat restoration occurs. Repeat sampling at sites in the subbasin within and between years has enabled assessment of juvenile Steelhead Trout growth patterns. Growth rates (relative change in weight) of age-0 PIT-tagged parr during summer have been similar across the subbasin, though slightly lower in the Trout Creek watershed (Trout Creek sites, 0.57 - 1.25%/day, Wind River sites = 0.94 – 2.48%/day). Summer growth rates have been lower for age-1 parr in the Trout Creek watershed than the upper Wind River watershed (Trout Creek sites, = 0.03 - 0.14%/day, Wind River sites = 0.05 – 0.19%/day). Yearly relative growth was similar across the subbasin for both age-0 and age-1 tagged parr. During 2024 range of mean daily relative change in weight from the previous year for age-0 tagged fish was: Trout Creek sites = 0.96 – 1.41%/day, Wind River sites = 0.80 – 1.30 %/day; and for age1 tagged fish was: Trout Creek sites = 0.37 - 0.50 %/day, Wind River sites = no age-1 tagged recaptures. Non-native Brook Trout are present in the subbasin, chiefly the Trout Creek watershed. Mean percent-of-catch that is Brook Trout, at four sample sites in Trout Creek, has declined from the period 1998 – 2003 to the period 2011 – 2024 (range of decrease = 19 - 82%). Percent-of-catch (of 64 samples, 52 < 10%; 3 > 20%) and number of Brook Trout at the Trout Creek sites from 2011 through 2024, though variable, have generally declined. Habitat restoration evaluation efforts are critical to ensure efficient use of money and resources but require long-term monitoring of population metrics. Detailed viable salmonid population and life-history data, such as that provided by PIT-tagging and instream PTIS networks inform fisheries policy and management and enable assessment of long-term effects of habitat restoration actions such as the removal of Hemlock Dam on Trout Creek and proposed major instream habitat restoration in the upper Wind River.

Washington

Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Complex landslide patterns explained by local intra-unit variability of stratigraphy and structure: Case study in the Tyee Formation, Oregon, USA

Lithology and geologic structure are important controls on landslide susceptibility and are incorporated into many regional landslide hazard models. Typically, metrics for mapped geologic units are used as model input variables and a single set of values for material strength are assumed, regardless of spatial heterogeneities that may exist within a map unit. Here we describe how differences in bedding thickness, grain size, inferred uniaxial compressive strength, and bedding dip control the inherent susceptibility of slopes to deep-seated failure within a single mapped geologic unit - the Tyee Formation of Oregon, USA. The Tyee, which covers over 15,000 km2 and underlies much of the Oregon Coast Range, comprises gently folded alternating beds of sandstone and siltstone deposited as turbidites, forming a 2-km thick Eocene submarine fan which has been uplifted and exhumed through the Cenozoic. Deep-seated landslides are widespread in the Tyee, but form a complex spatial pattern such that landslide density ranges from 0 to 24% of the total landscape area. These slides are often extensive and sufficiently deep to reduce local hillslope gradients, resulting in a strong negative correlation between landslide density and mean local slope. Mean annual precipitation and predicted strong ground motions from Cascadia earthquake scenarios also fail to explain the spatial distribution of deep-seated landslides. Consequently, landslide stability models, which are strongly influenced by landscape slope, pore-water pressure, and seismic acceleration, yield landslide susceptibility maps which are broadly anti-correlated with mapped deep-seated landslide density. Through a multivariable linear regression model, we show that much of the variance in deep-seated landslide density can be explained by variability of intra-unit stratigraphic and structural characteristics, which we measure at 128 sites across two study areas totaling ∼3000 km2. Our results suggest bedding dip is only weakly correlated to landslide density, but strongly influences landslide failure style. Subtle increases in bedding dip, even in the gently folded Tyee Formation, result in a substantially higher likelihood of a landslide being cataclinal, or parallel to bedding. Overall, we find a slight majority of landslides fail within these cataclinal slopes, and that these landslides tend to be larger than non-cataclinal landslides. We also show that the lithological and structural properties that influence landslide susceptibility are distinct for these two populations of landslides. Our results demonstrate how localized, intra-unit, geologic variability can exert strong control on landslide susceptibility and failure style. This suggests that in some locations, landslide hazard models could be significantly improved by incorporating detailed, spatially variable, geologic properties rather than relying solely on generalized geologic map units.

Oregon

Hypothetical CO2 leakage into, and hydrological plume management within, an underground source of drinking water at a proposed CO2 storage facility, Kemper County, Mississippi, USA

A large Geologic Carbon Sequestration (GCS) hub has been proposed in Kemper County, Mississippi. The target injection interval consists of numerous Cretaceous-aged deep saline aquifers overlain by a competent and extensive regional sealing layer. Above the seal, the deepest Underground Source of Drinking Water (USDW) at the site is the Eutaw aquifer of the Eutaw Group and McShan Formation, undifferentiated. To assess potential risks of leakage from the deep sequestration reservoir, a model of a portion of the Cretaceous Eutaw Group was constructed in this study. Simulations tested various permeabilities, hypothetical leakage rates, and plume mitigation strategies utilizing existing wells. Results suggest that, under the influence of regional groundwater flow fields, leaking CO 2 would effectively bypass the existing wells, and to influence this migration would require very large water extraction rates. Therefore, to ensure plume detection, monitoring for leakage at the injection wells themselves is very important.

Mississippi

Analyzing spatial distributions and alignments of pitted cone features in Utopia Planitia on Mars

Martian geomorphology and surface features provide links to understanding past geologic processes such as fluid movement, local and regional tectonics, and feature formation mechanisms. Pitted cones are common features in the northern plains basins of Mars. They have been proposed to have formed from upwelling volatile-rich fluids, such as magma or water-sediment slurries. In this study, we map the spatial distributions of pitted cone features across the Utopia Planitia (UP) basin. Using the Average Nearest Neighbor technique, we find that pitted cone features appear to be clustered across the basin, occurring in a narrow band around the circumferential rim of UP. Additionally, we find that pitted cone features also appear to be aligned in chains that are sub-parallel with the basin margin. Parallel bands of cones generally follow elevation contours of the UP basin, which suggests elevation or a correlated factor plays a major role in pitted cone and cone chain formation. We propose that pitted cones and cone chains may be related to vertical fractures formed around the UP basin rim from subsidence of infilling basin material.

Icarus

Constraining large magnitude event source and path effects using ground motion simulations

The purpose of this study is to use ground motion simulations to investigate ways in which source and path effects for large magnitude events can be represented in non-ergodic GMMs. While we initially developed computation techniques using CyberShake simulations, the range of magnitudes and source-site combinations is not adequate to replicate what is observed empirically. We therefore designed a new ground motion simulation study, which includes earthquakes with a large range of magnitudes distributed uniformly on a fault plane, and sites covering a large range of rupture distances and azimuths. After running a large suite of simulations (M4-M7), we then develop a non-ergodic GMM with the simulation data. We find that the within-site residuals are dominated by the radiation pattern, rupture directivity, and slip patterns. Next, we modify an existing rupture directivity model to fit and remove the observed radiation pattern and rupture directivity from the residuals. We also minimize the contributions of slip patterns by averaging the within-site residuals among multiple source realizations. Finally, after removing the source effects from the within-site residuals, we compare the path effects computed with different magnitude groups using two approaches. The first approach only considers the small events that have the same shortest path to a site with the large events, while the second approach considers all small events on the fault plane. The results indicate that the path effects of large events cannot be satisfactorily approximated with that of small events using either approach.

Conference Paper

Neutron scattering reveals fractionation of natural gas mixtures in unconventional petroleum reservoir pores: Perspectives on energy resource recovery and storage

In unconventional petroleum reservoirs hydrocarbon fluids are hosted by both mineral and organic matter pores. These pores can have diameters that range from microns to less than a single nanometer and, for unconventional reservoirs, there is evidence that small pores ( <20 nm diameter) may constitute a large proportion of the available space. Understanding subsurface volumes and how fluids behave in them can be helpful for predicting hydrocarbon production and storage in the subsurface. One area with knowledge gaps regarding hydrocarbon behavior in small pores is the possibility for mixtures to fractionate (i.e., unmix) based on pore size or pore type. Mixture fractionation as a function of pore size could impact recovery of hydrocarbons, drive compositional shifts during production, and limit fluid storage within candidate reservoirs. To investigate natural gas fractionation in small geologic pores, we applied total neutron scattering to probe methane-ethane mixtures at reservoir pressures (up to ≈30 MPa) and temperature (60°C) within a sample from the Upper Cretaceous Niobrara Formation. Neutron scattering data reveal only minor fractionation occurs between methane and ethane in 20-nm diameter sample mesopores. Increased fractionation is observed for sample micropores, with up to 72% (±1% at 1-sigma) methane found in 2 nm diameter pores following injection of a 50%-50% methane-ethane mixture. These data provide rarely available direct experimental observations of hydrocarbon mixture behavior under nanoconfinement in a sample from an important unconventional petroleum reservoir. Our results are discussed in the context of evaluating hydrocarbon resources in unconventional reservoir meso- and micropores, reconciling observed gas composition changes during production, and more broadly, understanding subsurface pore volumes within an energy storage framework.

Fuel

Induced earthquakes are generally not tidally triggered in Oklahoma and Kansas

Human-induced earthquakes occur along critically stressed faults as injected wastewater simultaneously heightens fluid pressure and pushes faults to failure. We investigate the possibility that small stresses imposed by Earth tides could trigger earthquakes in the induced seismicity region of Oklahoma and Kansas from 2011 to 2018. We decluster a catalog consisting of ∼110,000 earthquakes using three methods (Reasenberg, nearest-neighbor distance, and phase-bin). We find no significant tidal earthquake triggering using Schuster's p -value test for the declustered catalogs as a whole. We search for localized triggering using discretized space-time cells and find ∼0–6% of cells have significant tidal triggering which is close to what is randomly expected (5%) and indicates there is an insignificant amount of tidal triggering for the full study region. One area that has significant p -values across multiple time windows, ∼2014–2016 is ∼15 km from a region of large wastewater injection volume. It is possible that localized tidal triggering occurs for this time and area because faults remain critically stressed and are particularly susceptible to slip under the small stress load from the semidiurnal tide. Possible explanations for the lack of tidal triggering in our broader study are that the pre-seismic stressing rate in the earthquake nucleation area is faster than the tidal stressing rate (∼3 kPa/day), faults are not close enough to critically stressed to be affected by tidal forcing, and that nucleation occurs over longer periods than the tides considered in this study (∼1, ∼14 days). Fluid injection could be the source of a higher pre-seismic stress rate.

Kansas, Oklahoma