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At least 847 records · Page 47Linked to original sources
USGS2006

Anaerobic biotransformation of organoarsenical pesticides monomethylarsonic acid and dimethylarsinic acid

Monomethylarsonic acid (MMAV) and dimethylarsinic acid (DMAV) are extensively utilized as pesticides, introducing large quantities of arsenic into the environment. Once released into the environment, these organoarsenicals are subject to microbial reactions. Aerobic biodegradation of MMAV and DMAV has been evaluated, but little is known about their fate in anaerobic environments. The objective of this study was to evaluate the biotransformation of MMAV and DMAV in anaerobic sludge. Biologically mediated conversion occurred under methanogenic or sulfate-reducing conditions but not in the presence of nitrate. Monomethylarsonous acid (MMAIII) was consistently observed as an important metabolite of MMAV degradation, and it was recovered in molar yields ranging from 5 to 47%. The main biotransformation product identified from DMAV metabolism was MMAV, which was recovered in molar yields ranging from 8 to 65%. The metabolites indicate that reduction and demethylation are important steps in the anaerobic bioconversion of MMAV and DMAV, respectively. ?? 2006 American Chemical Society.

Journal of Agricultural and Food Chemistry↗
USGS2003

CO2 hydrate: Synthesis, composition, structure, dissociation behavior, and a comparison to structure I CH4 hydrate

Structure I (sI) carbon dioxide (CO 2 ) hydrate exhibits markedly different dissociation behavior from sI methane (CH 4 ) hydrate in experiments in which equilibrated samples at 0.1 MPa are heated isobarically at 13 K/h from 210 K through the H 2 O melting point (273.15 K). The CO 2 hydrate samples release only about 3% of their gas content up to temperatures of 240 K, which is 22 K above the hydrate phase boundary. Up to 20% is released by 270 K, and the remaining CO 2 is released at 271.0 plusmn; 0.5 K, where the sample temperature is buffered until hydrate dissociation ceases. This reproducible buffering temperature for the dissociation reaction CO 2 ·nH 2 O = CO 2 (g) + nH 2 O(1 to s) is measurably distinct from the pure H 2 O melting point at 273.15 K, which is reached as gas evolution ceases. In contrast, when si CH 4 hydrate is heated at the same rate at 0.1 MPa, >95% of the gas is released within 25 K of the equilibrium temperature (193 K at 0.1 MPa). In conjunction with the dissociation study, a method for efficient and reproducible synthesis of pure polycrystalline CO 2 hydrate with suitable characteristics for material properties testing was developed, and the material was characterized. CO 2 hydrate was synthesized from CO 2 liquid and H 2 O solid and liquid reactants at pressures between 5 and 25 MPa and temperatures between 250 and 281 K. Scanning electron microscopy (SEM) examination indicates that the samples consist of dense crystalline hydrate and 50-300 μm diameter pores that are lined with euhedral cubic hydrate crystals. Deuterated hydrate samples made by this same procedure were analyzed by neutron diffraction at temperatures between 4 and 215 K; results confirm that complete conversion of water to hydrate has occurred and that the measured unit cell parameter and thermal expansion are consistent with previously reported values. On the basis of measured weight gain after synthesis and gas yields from the dissociation experiments, approximately all cages in the hydrate structure are filled such that n ≈ 5.75.

Journal of Physical Chemistry B↗
USGS1998

Optical-cell evidence for superheated ice under gas-hydrate-forming conditions

We previously reported indirect but compelling evidence that fine-grained H 2 O ice under elevated CH 4 gas pressure can persist to temperatures well above its ordinary melting point while slowly reacting to form methane clathrate hydrate. This phenomenon has now been visually verified by duplicating these experiments in an optical cell while observing the very slow hydrate-forming process as the reactants were warmed from 250 to 290 K at methane pressures of 23 to 30 MPa. Limited hydrate growth occurred rapidly after initial exposure of the methane gas to the ice grains at temperatures well within the ice subsolidus region. No evidence for continued growth of the hydrate phase was observed until samples were warmed above the equilibrium H 2 O melting curve. With continued heating, no bulk melting of the ice grains or free liquid water was detected anywhere within the optical cell until hydrate dissociation conditions were reached (292 K at 30 MPa), even though full conversion of the ice grains to hydrate requires 6−8 h at temperatures approaching 290 K. In a separate experimental sequence, unreacted portions of H 2 O ice grains that had persisted to temperatures above their ordinary melting point were successfully induced to melt, without dissociating the coexisting hydrate in the sample tube, by reducing the pressure overstep of the equilibrium phase boundary and thereby reducing the rate of hydrate growth at the ice−hydrate interface. Results from similar tests using CO 2 as the hydrate-forming species demonstrated that this superheating effect is not unique to the CH 4 −H 2 O system.

Journal of Physical Chemistry B↗
USGS1998

Comparison of streambed sediment and aquatic biota as media for characterizing trace elements and organochlorine compounds in the Willamette Basin, Oregon

During 1992-93, 27 organochlorine compounds (pesticides plus total PCB) and 17 trace elements were analyzed in bed sediment and aquatic biota from 20 stream sites in the Willamette Basin as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Data from each medium were compared to evaluate their relative effectiveness for assessing occurrence (broadly defined as documentation of important concentrations) of these constituents. Except for Cd, Hg, Se, and Ag, trace element concentrations generally were higher in bed sediment than in biota. Conversely, although frequencies of detection for organochlorine compounds in biota were only slightly greater than in bed sediment, actual concentrations in biota (normalized to lipid) were as much as 19 times those in sediment (normalized to organic carbon). Sculpin (Cottus spp.) and Asiatic clams (Corbicula fluminea), found at 14 and 7 sites, respectively, were the most widespread taxa collected during the study. Concentrations of trace elements, particularly As and Cu, were typically greater in Asiatic clams than in sculpin. In contrast, almost half of the organochlorine compounds analyzed were found in sculpin, but only DDT and its degradation products were detected in Asiatic clams; this may be related to the lipid content of sculpin, which was about three times higher than for clams. Thus, the medium of choice for assessing occurrence depends largely on the constituent(s) of interest.

Environmental Monitoring and Assessment↗
USGS1997

Landscape characteristics of disturbed shrubsteppe habitats in southwestern Idaho (USA)

We compared 5 zones in shrubsteppe habitats of southwestern Idaho to determine the effect of differing disturbance combinations on landscapes that once shared historically similar disturbance regimes. The primary consequence of agriculture, wildfires, and extensive fires ignited by the military during training activities was loss of native shrubs from the landscape. Agriculture created large square blocks on the landscape, and the landscape contained fewer small patches and more large shrub patches than non-agricultural areas. In contrast, fires left a more fragmented landscape. Repeated fires did not change the distribution of patch sizes, but decreased the total area of remaining shrublands and increased the distance between remaining shrub patches that provide seed sources. Military training with tracked vehicles was associated with a landscape characterized by small, closely spaced, shrub patches. Our results support the general model hypothesized for conversion of shrublands to annual grasslands by disturbance. Larger shrub patches in our region, historically resistant to fire spread and large-scale fires because of a perennial bunchgrass understory, were more fragmented than small patches. Presence of cheatgrass (Bromus tectorum), an exotic annual, was positively related to landscape patchiness and negatively related to number of shrub cells. Thus, cheatgrass dominance can contribute to further fragmentation and loss of the shrub patch by facilitating spread of subsequent fires, carried by continuous fuels, through the patch. The synergistic processes of fragmentation of shrub patches by disturbance, invasion and subsequent dominance by exotic annuals, and fire are converting shrubsteppe in southwestern Idaho to a new state dominated by exotic annual grasslands and high fire frequencies.

Idaho↗
USGS2002

Statistical characteristics of xenoliths in the Antioch kimberlite pipe, Marshall County, northeastern Kansas

Geometrical characteristics of xenoliths in the Antioch kimberlite pipe have been considered in statistical terms. A method of conversion of 2D intersections to 3D dimensions was used. It has been shown that the Rosin-Rammler distribution of mass leads to the Weibull distribution of sizes, whereas a fractal distribution of sizes can be expressed as the Pareto distribution. Lognormal, Weibull, and Pareto distributions have been tested as model distributions. The Pareto distribution could be the most appropriate model for the distribution of xenoliths. This conclusion is in agreement with the general concept that the xenoliths formed as a result of an underground explosion without additional breakage occurring during magma transport. The final distribution may be shifted from the initial model as a result of processes of redistribution and sorting of xenoliths in liquid-crystalline flows.

Kansas↗
USGS2004

Assessing development pressure in the Chesapeake Bay watershed: An evaluation of two land-use change models

Natural resource lands in the Chesapeake Bay watershed are increasingly susceptible to conversion into developed land uses, particularly as the demand for residential development grows. We assessed development pressure in the Baltimore-Washington, DC region, one of the major urban and suburban centers in the watershed. We explored the utility of two modeling approaches for forecasting future development trends and patterns by comparing results from a cellular automata model, SLEUTH (slope, land use, excluded land, urban extent, transportation), and a supply/demand/allocation model, the Western Futures Model. SLEUTH can be classified as a land-cover change model and produces projections on the basis of historic trends of changes in the extent and patterns of developed land and future land protection scenarios. The Western Futures Model derives forecasts from historic trends in housing units, a U.S. Census variable, and exogenously supplied future population projections. Each approach has strengths and weaknesses, and combining the two has advantages and limitations. ?? 2004 Kluwer Academic Publishers.

Environmental Monitoring and Assessment↗
USGS2004

Relative effect of temperature and pH on diel cycling of dissolved trace elements in Prickly Pear Creek, Montana

Diel (24 hr) cycles in dissolved metal and As concentrations have been documented in many northern Rocky Mountain streams in the U.S.A. The cause(s) of the cycles are unknown, although temperature- and pH-dependent sorption reactions have been cited as likely causes. A light/dark experiment was conducted to isolate temperature and pH as variables affecting diel metal cycles in Prickly Pear Creek, Montana. Light and dark chambers containing sediment and a strand of macrophyte were placed in the stream to simulate instream temperature oscillations. Photosynthesis-induced pH changes were allowed to proceed in the light chambers while photosynthesis was prevented in the dark chambers. Water samples were collected periodically for 22 hr in late July 2001 from all chambers and the stream. In the stream, dissolved Zn concentrations increased by 300% from late afternoon to early morning, while dissolved As concentrations exhibited the opposite pattern, increasing 33% between early morning and late afternoon. Zn and As concentrations in the light chambers showed similar, though less pronounced, diel variations. Conversely, Zn and As concentrations in the dark chambers had no obvious diel variation, indicating that light, or light-induced reactions, caused the variation. Temperature oscillations were nearly identical between light and dark chambers, strongly suggesting that temperature was not controlling the diel variations. As expected, pH was negatively correlated ( P < 0.01) with dissolved Zn concentrations and positively correlated with dissolved As concentrations in both the light and dark chambers. From these experiments, photosynthesis-induced pH changes were determined to be the major cause of the diel dissolved Zn and As cycles in Prickly Pear Creek. Further research is necessary in other streams to verify that this finding is consistent among streams having large differences in trace-element concentrations and mineralogy of channel substrate.

Montana↗
USGS2000

The crustal thickness of Australia

We investigate the crustal structure of the Australian continent using the temporary broadband stations of the Skippy and Kimba projects and permanent broadband stations. We isolate near-receiver information, in the form of crustal P-to-S conversions, using the receiver function technique. Stacked receiver functions are inverted for S velocity structure using a Genetic Algorithm approach to Receiver Function Inversion (GARFI). From the resulting velocity models we are able to determine the Moho depth and to classify the width of the crust-mantle transition for 65 broadband stations. Using these results and 51 independent estimates of crustal thickness from refraction and reflection profiles, we present a new, improved, map of Moho depth for the Australian continent. The thinnest crust (25 km) occurs in the Archean Yilgarn Craton in Western Australia; the thickest crust (61 km) occurs in Proterozoic central Australia. The average crustal thickness is 38.8 km (standard deviation 6.2 km). Interpolation error estimates are made using kriging and fall into the range 2.5–7.0 km. We find generally good agreement between the depth to the seismologically defined Moho and xenolith-derived estimates of crustal thickness beneath northeastern Australia. However, beneath the Lachlan Fold Belt the estimates are not in agreement, and it is possible that the two techniques are mapping differing parts of a broad Moho transition zone. The Archean cratons of Western Australia appear to have remained largely stable since cratonization, reflected in only slight variation of Moho depth. The largely Proterozoic center of Australia shows relatively thicker crust overall as well as major Moho offsets. We see evidence of the margin of the contact between the Precambrian craton and the Tasman Orogen, referred to as the Tasman Line.

Journal of Geophysical Research B: Solid Earth↗
USGS2001

Methyl tert‐butyl ether degradation in the unsaturated zone and the relation between MTBE in the atmosphere and shallow groundwater

Atmospheric methyl tert‐butyl ether (MTBE) concentrations in southern New Jersey generally exceeded concentrations in samples taken from the unsaturated zone. A simple unsaturated zone transport model indicates that MTBE degradation can explain the attenuation with half‐lives from a few months to a couple of years. Tert‐butyl alcohol (TBA), a possible degradation product of MTBE, was detected in unsaturated‐zone samples at concentrations exceeding atmospheric levels at some sites, suggesting the possible conversion of MTBE to TBA. At sites where MTBE was detected in shallow groundwater, the concentration was typically higher than the overlying unsaturated‐zone concentration. This observation is consistent with outgassing from the aquifer and combined with the unsaturated‐zone attenuation suggests some of the MTBE detections in shallow groundwater are nonatmospheric in origin, coming from leaking tanks, road runoff, or other sources. The identification of sources of MTBE in groundwater and attenuation mechanisms through the hydrologic cycle is critical in developing an understanding of the long‐term effect of MTBE releases.

Water Resources Research↗
USGS2002

Changes in population and agricultural land in conterminous United States counties, 1790 to 1997

We have developed a data set of changes in population and agricultural land for the conterminous United States at the county level, resulting in more spatial detail than in previously available compilations. The purpose was to provide data on the timing of land conversion as an input to dynamic models of the carbon cycle, although a wide variety of applications exist for the physical, biological, and social sciences. The spatial data represent the appropriate county boundaries for each census year between 1790 and 1997, and the census attributes are attached to the appropriate spatial region. The resulting time series and maps show the history of population (1790-1990) and the history of agricultural development (1850-1997). The patterns of agricultural development reflect the influences of climate, soil productivity, increases in population size, variations in the general economy, and technological changes in the energy, transportation, and agricultural sectors.

Global Biogeochemical Cycles↗
USGS2006

Analysis of ecosystem controls on soil carbon source-sink relationships in the northwest Great Plains

Our ability to forecast the role of ecosystem processes in mitigating global greenhouse effects relies on understanding the driving forces on terrestrial C dynamics. This study evaluated the controls on soil organic C (SOC) changes from 1973 to 2000 in the northwest Great Plains. SOC source-sink relationships were quantified using the General Ensemble Biogeochemical Modeling System (GEMS) based on 40 randomly located 10 × 10 km 2 sample blocks. These sample blocks were aggregated into cropland, grassland, and forestland groups based on land cover composition within each sample block. Canonical correlation analysis indicated that SOC source-sink relationship from 1973 to 2000 was significantly related to the land cover type while the change rates mainly depended on the baseline SOC level and annual precipitation. Of all selected driving factors, the baseline SOC and nitrogen levels controlled the SOC change rates for the forestland and cropland groups, while annual precipitation determined the C source-sink relationship for the grassland group in which noticeable SOC sink strength was attributed to the conversion from cropped area to grass cover. Canonical correlation analysis also showed that grassland ecosystems are more complicated than others in the ecoregion, which may be difficult to identify on a field scale. Current model simulations need further adjustments to the model input variables for the grass cover-dominated ecosystems in the ecoregion.

Global Biogeochemical Cycles↗
USGS2007

Mars reconnaissance orbiter's high resolution imaging science experiment (HiRISE)

The HiRISE camera features a 0.5 m diameter primary mirror, 12 m effective focal length, and a focal plane system that can acquire images containing up to 28 Gb (gigabits) of data in as little as 6 seconds. HiRISE will provide detailed images (0.25 to 1.3 m/pixel) covering ∼1% of the Martian surface during the 2‐year Primary Science Phase (PSP) beginning November 2006. Most images will include color data covering 20% of the potential field of view. A top priority is to acquire ∼1000 stereo pairs and apply precision geometric corrections to enable topographic measurements to better than 25 cm vertical precision. We expect to return more than 12 Tb of HiRISE data during the 2‐year PSP, and use pixel binning, conversion from 14 to 8 bit values, and a lossless compression system to increase coverage. HiRISE images are acquired via 14 CCD detectors, each with 2 output channels, and with multiple choices for pixel binning and number of Time Delay and Integration lines. HiRISE will support Mars exploration by locating and characterizing past, present, and future landing sites, unsuccessful landing sites, and past and potentially future rover traverses. We will investigate cratering, volcanism, tectonism, hydrology, sedimentary processes, stratigraphy, aeolian processes, mass wasting, landscape evolution, seasonal processes, climate change, spectrophotometry, glacial and periglacial processes, polar geology, and regolith properties. An Internet Web site (HiWeb) will enable anyone in the world to suggest HiRISE targets on Mars and to easily locate, view, and download HiRISE data products.

Journal of Geophysical Research E: Planets↗
USGS2006

Effect of tree line advance on carbon storage in NW Alaska

We investigated the size, distribution, and temporal dynamics of ecosystem carbon (C) pools in an area of recent tree line advance, northwest Alaska. Repeat aerial photographs show forest cover increased ???10% in our study area since 1949. We sampled C pools of four principal ecosystem types, tussock tundra, shrub tundra, woodland, and forest, all located on a 600-800 year old river terrace. Significant differences between ecosystem C pools, both above ground and below ground existed. Tundra sites store >22.2 kg C/m2, shrub tundra sites and woodland sites store 9.7 kg C/m2 and 14.3 kg C/m2, respectively, and forest sites store 14.4 kg C/m2. Landscape variation of total ecosystem C was primarily due to organic soil C and was secondarily due to C stored in trees. Soil C/N profiles of shrub tundra sites and woodland sites showed similarities with forest site soils at surface and tundra site soils at depth. We hypothesize that tundra systems transformed to forest systems in this area under a progression of permafrost degradation and enhanced drainage. On the basis of C pool estimates for the different ecosystem types, conversion of tundra sites to forest may have resulted in a net loss of > 7.8 kg C/m2, since aboveground C gains were more than offset by belowground C losses to decomposition in the tundra sites. Tree line advance therefore might not increase C storage in high-latitude ecosystems and thus might not, as previously suggested, act as a negative feedback to warming. Key to this hypothesis and to its projection to future climate response is the fate of soil carbon upon warming and permafrost drainage. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗
USGS2006

Land use/land cover change effects on temperature trends at U.S. Climate Normals stations

Alterations in land use/land cover (LULC) in areas near meteorological observation stations can influence the measurement of climatological variables such as temperature. Urbanization near climate stations has been the focus of considerable research attention, however conversions between non-urban LULC classes may also have an impact. In this study, trends of minimum, maximum, and average temperature at 366 U.S. Climate Normals stations are analyzed based on changes in LULC defined by the U.S. Land Cover Trends Project. Results indicate relatively few significant temperature trends before periods of greatest LULC change, and these are generally evenly divided between warming and cooling trends. In contrast, after the period of greatest LULC change was observed, 95% of the stations that exhibited significant trends (minimum, maximum, or mean temperature) displayed warming trends. Copyriht 2006 by the American Geophysical Union.

Geophysical Research Letters↗
USGS2009

Carbon cycling under 300 years of land use change: importance of the secondary vegetation sink

We have developed a dynamic land model (LM3V) able to simulate ecosystem dynamics and exchanges of water, energy, and CO 2 between land and atmosphere. LM3V is specifically designed to address the consequences of land use and land management changes including cropland and pasture dynamics, shifting cultivation, logging, fire, and resulting patterns of secondary regrowth. Here we analyze the behavior of LM3V, forced with the output from the Geophysical Fluid Dynamics Laboratory (GFDL) atmospheric model AM2, observed precipitation data, and four historic scenarios of land use change for 1700-2000. Our analysis suggests a net terrestrial carbon source due to land use activities from 1.1 to 1.3 GtC/a during the 1990s, where the range is due to the difference in the historic cropland distribution. This magnitude is substantially smaller than previous estimates from other models, largely due to our estimates of a secondary vegetation sink of 0.35 to 0.6 GtC/a in the 1990s and decelerating agricultural land clearing since the 1960s. For the 1990s, our estimates for the pastures' carbon flux vary from a source of 0.37 to a sink of 0.15 GtC/a, and for the croplands our model shows a carbon source of 0.6 to 0.9 GtC/a. Our process-based model suggests a smaller net deforestation source than earlier bookkeeping models because it accounts for decelerated net conversion of primary forest to agriculture and for stronger secondary vegetation regrowth in tropical regions. The overall uncertainty is likely to be higher than the range reported here because of uncertainty in the biomass recovery under changing ambient conditions, including atmospheric CO 2 concentration, nutrients availability, and climate. Copyright 2009 by the American Geophysical Union.

Global Biogeochemical Cycles↗
USGS2008

Evaluating the effects of historical land cover change on summertime weather and climate in New Jersey: Land cover and surface energy budget changes

The 19th-century agrarian landscape of New Jersey (NJ) and the surrounding region has been extensively transformed to the present-day land cover by urbanization, reforestation, and localized areas of deforestation. This study used a mesoscale atmospheric numerical model to investigate the sensitivity of the warm season climate of NJ to these land cover changes. Reconstructed 1880s-era and present-day land cover data sets were used as surface boundary conditions for a set of simulations performed with the Regional Atmospheric Modeling System (RAMS). Three-member ensembles with historical and present-day land cover were compared to examine the sensitivity of surface air and dew point temperatures, rainfall, and the individual components of the surface energy budget to these land cover changes. Mean temperatures for the present-day landscape were 0.3-0.6??C warmer than for the historical landscape over a considerable portion of NJ and the surrounding region, with daily maximum temperatures at least 1.0??C warmer over some of the highly urbanized locations. Reforested regions, however, were slightly cooler. Dew point temperatures decreased by 0.3-0.6??C, suggesting drier, less humid near-surface air for the present-day landscape. Surface warming was generally associated with repartitioning of net radiation from latent to sensible heat flux, and conversely for cooling. While urbanization was accompanied by strong surface albedo decreases and increases in net shortwave radiation, reforestation and potential changes in forest composition have generally increased albedos and also enhanced landscape heterogeneity. The increased deciduousness of forests may have further reduced net downward longwave radiation. Copyright 2008 by the American Geophysical Union.

New Jersey↗
USGS2007

Sulfur species behavior in soil organic matter during decomposition

Soil organic matter (SOM) is a primary re??servoir of terrestrial sulfur (S), but its role in the global S cycle remains poorly understood. We examine S speciation by X-ray absorption near-edge structure (XANES) spectroscopy to describe S species behavior during SOM decomposition. Sulfur species in SOM were best represented by organic sulfide, sulfoxide, sulfonate, and sulfate. The highest fraction of S in litter was organic sulfide, but as decomposition progressed, relative fractions of sulfonate and sulfate generally increased. Over 6-month laboratory incubations, organic sulfide was most reactive, suggesting that a fraction of this species was associated with a highly labile pool of SOM. During humification, relative concentrations of sulfoxide consistently decreased, demonstrating the importance of sulfoxide as a reactive S phase in soil. Sulfonate fractional abundance increased during humification irrespective of litter type, illustrating its relative stability in soils. The proportion of S species did not differ systematically by litter type, but organic sulfide became less abundant in conifer SOM during decomposition, while sulfate fractional abundance increased. Conversely, deciduous SOM exhibited lesser or nonexistent shifts in organic sulfide and sulfate fractions during decomposition, possibly suggesting that S reactivity in deciduous litter is coupled to rapid C mineralization and independent of S speciation. All trends were consistent in soils across study sites. We conclude that S reactivity is related to spqciation in SOM, particularly in conifer forests, and S species fractions in SOM change, during decomposition. Our data highlight the importance of intermediate valence species (sulfoxide and sulfonate) in the pedochemical cycling of organic bound S. Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗