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Geologic and hydrologic features of the San Bernardino area, California; with special reference to underflow across the San Jacinto fault

This is the second in a series of interpretive reports on subsurface outflow from the ground-water basins of San Bernardino County, Calif., prepared by the U.S. Geological Survey in cooperation with the San Bernardino County Flood Control District. One principal purpose of the study was to estimate the ground-water outflow from the Bunker Hill basin to the Rialto-Colton basin across the San Jacinto fault, which, except locally, forms a nearly impermeable boundary between the two basins. In addition, the report deals qualitatively with the geology, the fault barriers that divide the area into several ground-water basins, the physical nature and degree of imperviousness of the barriers, the occurrence and movement of ground water and fluctuations of water level in the basins, and the chemical quality of surface and ground waters in the San Bernardino area. The report includes a geologic map and sections, water-level-contour maps and profiles, and hydrographs of selected well. The Santa Ana River, the principal stream, flows generally westward across the area. Channels of the river and its tributaries overlie a large irregular structural depression filled with alluvial deposits ranging in age from late Tertiary to Recent and forming a valley bounded on the north by the San Gabriel Mountains, on the east by the San Bernardino Mountains, and on the south by an irregular group of hills. Large alluvial fans underlie most of the area, but its landforms also include alluvial benches and terraces near the mountains, stream channels, and elongate hills, ridges, and scarps along the trace of the San Jacinto fault, which strikes northwestward across the valley about in the center of the area. This fault and others divide the area into ground-water basins, which include the Bunker Hill, Rialto-Colton, upper and lower Lytle and Chino basins. The water-bearing deposits include the following units: the younger alluvium. of Recent age, which occupies principally the backfilled channels beneath the Santa Ana River and its tributaries and through which ground water moves from Bunker Hill basin to Rialto-Colton basin; the older alluvium, of Pleistocene age, which is the principal water-bearing unit of the area and yields water to more than a thousand wells; and continental deposits of Tertiary to Quaternary age, which crop out along the southern margin of the area and locally along the San Gabriel Mountains on the north. The younger alluvium attains a maximum thickness of about 125 feet beneath the Santa Ana River south of San Bernardino. Locally in the Bunker Hill basin it is composed of two members, an upper member of relatively impermeable clay and a lower member of highly permeable material in which water is confined by the upper member. The older alluvium locally has a known thickness greater than 700 feet; elsewhere in the San Bernardino Valley it may exceed 1,400 feet. Locally, where ground water is confined in Bunker Hill basin, the older alluvium is divided into three permeable water-bearing zones separated from each other and from the younger alluvium above by less permeable zones. In parts of Chino and Rialto-Colton basins the alluvium consists of a coarse-grained facies along a former course of a major stream that is interfingered with and overlain by relatively fine-grained deposits. The permeability of the younger alluvium in the area beneath the Santa Ana River downstream from the San Jacinto fault was determined from tests to be about 2,700 gallons per day per square foot. The permeability of the coarse water-yielding materials of the older alluvium several miles downstream was estimated from tests to be about the same magnitude. Rocks that yield practically no water include continental rocks of Tertiary age, which are not exposed in the area but are tapped by wells in Rialto-Colton basin, and crystalline and metamorphic rocks of pre-Tertiary age that form the bedrock of the area.

California↗

Ground-water hydrology of the Chad Basin in Bornu and Dikwa Emirates, northeastern Nigeria, with special emphasis on the flow life of the artesian system

Bornu and Dikwa Emirates lie in the Nigerian sector of the Chad Basin, a vast region of interior drainage encompassing about 600,000 square miles of north-central Africa. The report area includes about 25,000 square miles of the basin that lie in Nigeria. Most of the area is a featureless plain that slopes gently northeast and east from the uplands of central Nigeria towards Lake Chad. On its eastern side the lake has one surface outlet which overflows only during exceptionally high stages of the lake. This outlet spills into the channel of Bahr al Ghazal, which in turn drains into the Bod616 depression. Because the lake is shallow, the shoreline fluctuates markedly with high and low stages corresponding to the wet and dry seasons. The semiarid climate of Bornu and Dikwa Emirates is characterized by a long dry season and a short wet season that correspond to seasonal winds. Annual rainfall ranges from 15 inches in the northern part of the area to 32 inches in the southern. The Chad Basin in Dikwa and Bornu Emirates is underlain by interbedded sand and clay, collectively termed the Chad Formation. These alluvial and lactustrine sediments were deposited in or near Lake Chad whet it occupied a much greater area during Pliocene and Pleistocene time. The Chad Formation has a very slight primary dip in the direction of Lake Chad and conforms to the gentle slope of land surface. The known thickness of the formation ranges from a few feet where it overlies bedrock on the periphery of the basin to at least 1,800 feet at Maiduguri; however, its total thickness probably exceeds 2,000 feet in the central part of the basin. Three water-bearing units termed upper, middle, and lower zones occur within the Chad Formation. The upper zone yields water to numerous dug wells throughout the rural areas and also is .the major source of the Maiduguri municipal water .supply. The middle zone yields water from flowing artesian boreholes that have heads ranging from a few feet to 70 feet above land surface throughout a 13,000 square-mile area of the basin in Nigeria. The lower zone also yields water from flowing boreholes ; however, its areal extent has not been proved beyond the environs of Maiduguri. The present investigation is concerned primarily with the middle zone, which is the source of water for some 190 flowing boreholes used as little-watering points in the Nigerian sector of the Chad Basin. The thickness of loads of waterbearing sand in the middle zone ranges from less than 1 foot to 200 feet, and the artesian head ranges from land surface at Maiduguri to 70 feet above land surface at Lake Chad. The depth to the top of the middle zone in the area of flowing boreholes ranges from 500 to 1,250 feet below land surface. The waterbearing properties of the middle zone differ greatly from place to place. Also, the yields of individual flowing boreholes generally range from 50 to 20,000 imperial gallons per hour (gph). On the basis of water availability, the middle zone can be divided as follows : Areas of high-, moderate-, and low-yield artesian aquifer ; areas of low- and moderate-yield subartesian aquifer ; and an area where the yields from boreholes are insignificant or the aquifer is missing. Recommended maximum rates of long-term withdrawal from individual boreholes for the three artesian areas range from 100 to 5,000 gph with boreholes spaced 5 to 10 miles apart. By limiting flows to the recommended maximum rates, the boreholes should continue to flow for at least 30 years. The present average use per borehole (265 gph in 1965) is considerably less than the recommended maximum rates. Recharge to the upper zone occurs in significant but as yet unmeasured quantities, mostly in the vicinity of the major streams. Apparently, however, no significant amount of recharge reaches the middle zone from the Upper zone. Although the middle zone is, in effect, being 'mined' by existing flowing wells, the present (1965) rate of withdrawal i

Water Supply Paper↗

Rare-earth elements

The rare-earth elements (REEs) are 15 elements that range in atomic number from 57 (lanthanum) to 71 (lutetium); they are commonly referred to as the “lanthanides.” Yttrium (atomic number 39) is also commonly regarded as an REE because it shares chemical and physical similarities and has affinities with the lanthanides. Although REEs are not rare in terms of average crustal abundance, the concentrated deposits of REEs are limited in number. Because of their unusual physical and chemical properties, the REEs have diverse defense, energy, industrial, and military technology applications. The glass industry is the leading consumer of REE raw materials, which are used for glass polishing and as additives that provide color and special optical properties to the glass. Lanthanum-based catalysts are used in petroleum refining, and cerium-based catalysts are used in automotive catalytic converters. The use of REEs in magnets is a rapidly increasing application. Neodymium-iron-boron magnets, which are the strongest known type of magnets, are used when space and weight are restrictions. Nickel-metal hydride batteries use anodes made of a lanthanum-based alloys. China, which has led the world production of REEs for decades, accounted for more than 90 percent of global production and supply, on average, during the past decade. Citing a need to retain its limited REE resources to meet domestic requirements as well as concerns about the environmental effects of mining, China began placing restrictions on the supply of REEs in 2010 through the imposition of quotas, licenses, and taxes. As a result, the global rare-earth industry has increased its stockpiling of REEs; explored for deposits outside of China; and promoted new efforts to conserve, recycle, and substitute for REEs. New mine production began at Mount Weld in Western Australia, and numerous other exploration and development projects noted in this chapter are ongoing throughout the world. The REE-bearing minerals are diverse and often complex in composition. At least 245 individual REE-bearing minerals are recognized; they are mainly carbonates, fluorocarbonates, and hydroxylcarbonates (n = 42); oxides (n = 59); silicates (n = 85); and phosphates (n = 26). Many of the world’s significant REE deposits occur in carbonatites, which are carbonate igneous rocks. The REEs also have a strong genetic association with alkaline magmatism. The systematic geologic and chemical processes that explain these observations are not well understood. Economic or potentially economic REE deposits have been found in (a) carbonatites, (b) peralkaline igneous systems, (c) magmatic magnetite-hematite bodies, (d) iron oxide-copper-gold (IOCG) deposits, (e) xenotime-monazite accumulations in mafic gneiss, (f) ion-absorption clay deposits, and (g) monazite-xenotime-bearing placer deposits. Carbonatites have been the world’s main source for the light REEs since the 1960s. Ion-adsorption clay deposits in southern China are the world’s primary source of the heavy REEs. Monazite-bearing placer deposits were important sources of REEs before the mid-1960s and may be again in the future. In recent years, REEs have been produced from large carbonatite bodies mined at the Mountain Pass deposit in California and, in China, at the Bayan Obo deposit in Nei Mongol Autonomous Region, the Maoniuping deposit in Sichuan Province, the Daluxiang deposit in Sichuan Province, and the Weishan deposit in Anhui Province. Alkaline igneous complexes have recently been targeted for exploration because of their enrichments in the heavy REEs. Information relevant to the environmental aspects of REE mining is limited. Little is known about the aquatic toxicity of REEs. The United States lacks drinking water standards for REEs. The concentrations of REEs in environmental media are influenced by their low abundances in crustal rocks and their limited solubility in most groundwaters and surface waters. The scarcity of sulfide minerals, including pyrite, minimizes or eliminates concerns about acid-mine drainage for carbonatite-hosted deposits and alkaline-intrusion-related REE deposits. For now, insights into environmental responses of REE mine wastes must rely on predictive models.

Professional Paper↗

Ground-water resources of the Acu Valley, Rio Grande Norte, Brazil

The Acu Valley is the lower part of the Rio Piranhas valley in the northwestern part of the State of Rio Grande do Norte, Brazil. It begins where the Rio Piranhas leaves the crystalline Precambrian rocks to flow across the outcrop of sedimentary rocks. The area considered in this report extends northward for about 45 kilometers; it is terminated arbitrarily where encroachment by sea water has contaminated the aquifer and imparted a disagreeable saline taste to the water in it. The boundary was not determined in the field, however, for lack of special equipment. Part of the extensive uplands on either side of the valley are included. This makes the total area approximately 2,500 square kilometers. The largest town, Acu, had a population of about 8,000 in 1960. The area is considered to be part of the Drought Polygon of northeast Brazil because the precipitation, although averaging 448 millimeters annually at Acu, varies widely from year to year and often is deficient for many months. The precipitation has been supplemented by use of irrigation wells, but irrigated agriculture is not yet far advanced, and the quantities of water used in irrigation are small. Geologically, the area consists of basement crystalline rocks (Precambrian), a wedge of sedimentary rocks thickening northward (Cretaceous), and alluvial sediments constituting a narrow band in the bottom of the valley (Alluvium and terrace deposits). The crystalline rocks contain water mainly in fractures and, in general, are impermeable. The sedimentary rocks of Cretaceous age comprise two units: a thick but fine-grained sandstone grading upward into siltstone and shale (Acu Sandstone), and limestone and dolomite with an included shale zone (Jandaira Limestone). The sandstone especially and the limestone to a lesser degree are ground-water reservoirs of large capacity. The limestone has been tapped at several places, but the sandstone and its contained water are practically untested and, hence, imperfectly understood. The alluvium of the first terrace is the aquifer supplying most of the ground water being used in the area. Wells in the alluvium yield as much as S0,000 liters per hour. Larger yields probably could be obtained from wells designated to take full advantage of the aquifer. There are in the valley about 300 dug wells which are used for irrigation. Half of these are equipped with pumps and engines. The rest, together with about 500 drive-point wells, are equipped with manual or windmill-driven pumps. In addition to irrigation, the water is used in homes and for cattle. The quantities of water currently used in irrigation are relatively small, both per hectare and in the area as a whole, but .this will probably increase substantially when intensive irrigation becomes a reality. The annual pumpage from the alluvium, nearly constant since 1959, was about 2.5 million cubic meters in 1964, which is only about 90 cubic meters from each hectare-meter of saturated alluvium. This amount would lower the water table about 1 meter in 11 years, if there were no recharge. Actually, no such decline is likely to occur, because the recharge from precipitation alone is estimated to be more than enough to replace the water currently being pumped. Chemical analyses of eight samples show that the ground water in the alluvium is acceptable for most uses. The water in the Acu Sandstone and Jandazra Limestone is more mineralized than that in the alluvium and at some places, at least, is not acceptable for human consumption. The available chemical data on this water, however, are not adequate to judge fully the quality of the water in these formations. It is estimated that about .'22 million cubic meters of water would be needed annually if irrigation were extended to all the bottom land, which totals about 25,000 hectares. This amount is only one-fourth to one-half the estimated recharge from precipitation alone. The present rate of application of water is very low

Water Supply Paper↗

The question of recharge to the deep thermal reservoir underlying the geysers and hot springs of Yellowstone National Park

The extraordinary number, size, and unspoiled beauty of the geysers and hot springs of Yellowstone National Park (the Park) make them a national treasure. The hydrology of these special features and their relation to cold waters of the Yellowstone area are poorly known. In the absence of deep drill holes, such information is available only indirectly from isotope studies. The δD-δ18O values of precipitation and cold surface-water and ground-water samples are close to the global meteoric water line (Craig, 1961). δD values of monthly samples of rain and snow collected from 1978 to 1981 at two stations in the Park show strong seasonal variations, with average values for winter months close to those for cold waters near the collection sites. δD values of more than 300 samples from cold springs, cold streams, and rivers collected during the fall from 1967 to 1992 show consistent north-south and east-west patterns throughout and outside of the Park, although values at a given site vary by as much as 8 ‰ from year to year. These data, along with hot-spring data (Truesdell and others, 1977; Pearson and Truesdell, 1978), show that ascending Yellowstone thermal waters are modified isotopically and chemically by a variety of boiling and mixing processes in shallow reservoirs. Near geyser basins, shallow recharge waters from nearby rhyolite plateaus dilute the ascending deep thermal waters, particularly at basin margins, and mix and boil in reservoirs that commonly are interconnected. Deep recharge appears to derive from a major deep thermal-reservoir fluid that supplies steam and hot water to all geyser basins on the west side of the Park and perhaps in the entire Yellowstone caldera. This water (T ≥350°C; δD = –149±1 ‰) is isotopically lighter than all but the farthest north, highest altitude cold springs and streams and a sinter-producing warm spring (δD = –153 ‰) north of the Park. Derivation of this deep fluid solely from present-day recharge is problematical. The designation of source areas depends on assumptions about the age of the deep water, which in turn depend on assumptions about the nature of the deep thermal system. Modeling, based on published chloride-flux studies of thermal waters, suggests that for a 0.5- to 4-km-deep reservoir the residence time of most of the thermal water could be less than 1,900 years, for a piston-flow model, to more than 10,000 years, for a well-mixed model. For the piston-flow model, the deep system quickly reaches the isotopic composition of the recharge in response to climate change. For this model, stable-isotope data and geologic considerations suggest that the most likely area of recharge for the deep thermal water is in the northwestern part of the Park, in the Gallatin Range, where major north-south faults connect with the caldera. This possible recharge area for the deep thermal water is at least 20 km, and possibly as much as 70 km, from outflow in the thermal areas, indicating the presence of a hydrothermal system as large as those postulated to have operated around large, ancient igneous intrusions. For this model, the volume of isotopically light water infiltrating in the Gallatin Range during our sampling period is too small to balance the present outflow of deep water. This shortfall suggests that some recharge possibly occurred during a cooler time characterized by greater winter precipitation, such as during the Little Ice Age in the 15th century. However, this scenario requires exceptionally fast flow rates of recharge into the deep system. For the well-mixed model, the composition of the deep reservoir changes slowly in response to climate change, and a significant component of the deep thermal water could have recharged during Pleistocene glaciation. The latter interpretation is consistent with the recent discovery of warm waters in wells and springs in southern Idaho that have δD values 10–20 ‰ lower than the winter snow for their present-day high-level recharge. These waters have been interpreted to be Pleistocene in age (Smith and others, 2002). The well-mixed model permits a significant component of recharge water for the deep system to have δD values less negative than –150 ‰ and consequently for the deep system recharge to be closer to the caldera at a number of possible localities in the Park.

Idaho, Montana, Wyoming↗