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Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii

High-resolution transboundary vegetation community maps of the Sonoran and Mojave Desert ecoregion to support critical landscape conservation planning and habitat management needs

We produced a 30-m resolution binational land cover map of Bird Conservation Region 33 (BCR 33) for the U.S. North American Bird Conservation Initiative. The region covers large portions of the Sonoran and Mojave Deserts. The map can support the U.S. Fish and Wildlife Service (FWS) Migratory Bird Program’s recovery planning efforts and constitutes the first known binational land cover dataset spanning sections of the United States–Mexico border and using a consistent classification system for both countries. The mapped region includes 152 distinct land cover classes, covering a total area of 38,421,453 ha (148,345 mi 2 ), of which 13,148,345 ha (52,706 mi 2 ) are located in Mexico and 24,770,640 ha (95,639 mi 2 ) in the United States. We primarily used Landsat 8 (OLI) imagery, supplemented by limited ground surveys from two field campaigns, drone-based aerial data, and existing vegetation classification frameworks from both countries. The classification applied a data-fusion approach integrating 30-m Landsat 8 imagery, decadal phenology metrics from vegetation indices, and a random forest model trained mainly with datasets from a comprehensive national mapping project from the U.S. Geological Survey (USGS) GAP Analysis Project (GAP) and federal wildland fire agencies’ Landscape Fire and Resource Management Planning Tools (LANDFIRE) (GAP/LANDFIRE) [United States side] and the National Institute of Statistics and Geography (INEGI) [Mexico side] as well as land cover maps and opportunistic open-access and field observations. Mapping of the full BCR 33 region was carried out in two phases: 1) Phase I, the prototype map, covered a smaller portion of the transboundary area and identified 31 land cover classes, and 2) Phase II, the full BCR 33 map (refer to Figure 1), which resulted in 152 land cover classes. Using a Random Forest classifier, we achieved an overall prediction accuracy of 92% for the Phase I map and 87% for the Phase II full region map. This slight decrease can be attributed to working on a larger, more complex area with a greater number of land cover classes. No formal validation was conducted, aside from using a subset of the collected field observations and training data to assess model performance during and after training. The training sites were further verified using Google Earth (Google, 2026) imagery. Two undergraduate students who worked for over a year visually inspected imagery and open access public images to confirm each training site during model training using in-house developed, online, visual tools. A portion of this field training data was reserved for model validation, and the corresponding results are to be presented in later sections. The project developed an end-to-end, medium- and fine-resolution remote sensing–based data fusion mapping approach. This effort produced a map (Nagler et al., 2025) and the online tools to support a dynamic, live, online map for visualizing the transboundary vegetation communities in BCR 33. The toolset is currently hosted by the University of Arizona (UofA) Vegetation Index and Phenology (VIP) Lab to support FWS partners (https://vip.arizona.edu/viplab_data_explorer?LCM_BCR33). The online map is designed to allow rapid updates using new training, validation, or correction data, making it dynamic and maintainable. The approach we took established a framework for rapid updating and correction of land cover maps, as the model can be quickly retrained with new field observations, updated training data, or other sources. This enables dynamic mapping and change detection of the region’s vegetation. This framework is an advance in data fusion and crowdsourced mapping of complex, vulnerable regions, providing support to regional stakeholders and the wider user community. This transboundary map can inform the protection, conservation, and restoration of vegetation, habitat, and ecosystems, particularly for threatened and endangered species across the two nations using consistent and harmonized binational mapping systems. Beyond supporting land management decisions and stakeholders in the transboundary desert ecoregions, this BCR 33 mapping effort establishes a foundation for future rapid, low-cost, cross-border land cover mapping that can benefit and advance ecosystem management.

Arizona, Baja California, California, Nevada, Sina

The 3D National Topography Model Call for Action—Part 2: The Next Generation 3D Elevation Program

The three-dimensional (3D) National Topography Model initiative to integrate elevation and hydrography data includes the next generation of hydrography data from the 3D Hydrography Program and the next generation of elevation data from the 3D Elevation Program (3DEP). The first-ever collection of light detection and ranging (lidar) data for the nation (IfSAR for Alaska) provides a critical baseline reference, and the addition of multiple repeat elevation mapping projects as part of the next generation of 3DEP would substantially expand analysis capabilities. As the U.S. Geological Survey (USGS) is closing in on our goal of complete coverage with 3DEP data available or in progress for 98.3 percent of the Nation at the end of fiscal year 2024, the USGS is already transitioning to the next generation of 3DEP. Based on the 3D Nation Study results and input from a broad range of stakeholders, the USGS National Geospatial Program has finalized a new design for 3DEP that provides increased lidar quality levels and refresh rates. The new program is designed with more flexibility to meet changing user needs and take advantage of improvements in mapping technologies. The program will aim to expand the level of interagency coordination for topobathymetric lidar acquisition for inland rivers. The next generation of 3DEP will also aim to emphasize research, including advancing program design, products, and services and engaging and leveraging the evolving 3D industry. Research goals also include becoming more flexible in meeting user needs and taking advantage of evolving remote-sensing technologies. The program also plans to move from focusing on producing standard products to producing a concept of a 3D Nation Ecosystem with a variety of inputs, products, and services.

Circular

Design and function of the Autonomous Benthic Imaging and Surveying System (ABISS) for remote sensing of lake and seabed environments

Lake and seabed environments are home to fisheries and other biota that are important to ecosystems and economies, yet these environments and the species that use them are difficult to accurately assess and monitor. Traditional benthic survey techniques, like bottom trawling used by the U.S. Geological Survey, are limited by substrate constraints, poor spatial resolution and precision, and operational depth limits, hindering accurate assessment of benthic species and habitats. In response to these limitations, the U.S. Geological Survey developed the Autonomous Benthic Imaging and Surveying System, a camera system integrated into underwater vehicles, to capture high-resolution images of the lakebed. The system uses color and stereo cameras to collect imagery, which can be analyzed using computational methods to detect organisms and (or) characterize habitat features, such as geologic substrate types. The system has been integrated into autonomous underwater vehicles and into an underwater housing used by self-contained underwater breathing apparatus (SCUBA) divers. Although the engineering of the system was motivated by the need for data collection in the Great Lakes, it has potential to collect high quality data in any aqueous setting with sufficient water clarity and safe operating conditions. The Autonomous Benthic Imaging and Surveying System can operate across diverse depths and light conditions to map and quantify ecological patterns that were difficult or impossible to assess using traditional methods. The Autonomous Benthic Imaging and Surveying System offers the potential for accurate and precise monitoring and assessment of native benthic biota, invasive species, and habitat, potentially providing natural resource managers with improved information to support decision making about benthic resource management.

Great Lakes

The 3D Elevation Program—Supporting Rhode Island’s economy

Introduction High-resolution elevation data are critical to applications of landscape modeling and planning, both of which have a significant effect on Rhode Island’s economy. In these and other enterprises, program managers, while aiming to strike a balance between accuracy and cost, strive to obtain the best available elevation data to help them address a range of issues. Programs focused on climate change, environmental management, transportation design and asset management, aviation navigation and safety, riverine ecosystem management, wildlife habitat characterization and management, shellfish aquaculture, and the management and mapping of forests, parks and recreation areas, soils, wetlands, and impervious surfaces are also among the critical applications that meet the State’s management needs and depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Rhode Island. The status of available and in-progress 3DEP baseline lidar data in Rhode Island is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $178,560 in new benefits annually to the State. The top 10 Rhode Island business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Rhode Island

High-resolution magnetic survey using an unoccupied aerial vehicle to constrain buried lava flow geometry, volume, and eruptive history of Little Cones, Crater Flat, Nevada

Magnetic surveys are an important tool used to augment geologic mapping in distributed volcanic fields. Using magnetic anomalies, it is possible to model the geometry of shallowly buried volcanic features, such as conduits, sills, and lava flows. This subsurface mapping is important for understanding eruption dynamics and emplacement of lava flows, and it sometimes reveals buried volcanoes no longer visible at the surface. These data are critical to better interpret the numbers, styles, and magnitudes of eruptions in distributed volcanic fields and their associated volcanic hazards. New advances in unoccupied aerial vehicles (UAVs) offer an attractive middle range of resolution and aerial coverage between ground-based magnetic surveys and aeromagnetic surveys. Here, we present the results of a UAV fluxgate magnetic survey of the Little Cones, Nevada, scoria cones, which have been the target of previous ground and aeromagnetic surveys. The magnetic anomalies at Little Cones are of interest because the surrounding alluvium conceals lava flows that erupted from Little Cones, making it very difficult to understand the volume and morphology of lava flows from geologic mapping alone. Nonlinear inversion of UAV-collected magnetic data were used to model the thickness and morphology of buried Little Cones’ lava flows with higher precision than achieved previously. The sequence of events and calculated flow characteristics are then interpreted. The total volume of Little Cones, including concealed lava flows, is approximately 0.016 cubic kilometer, and the initial sheet flow erupted in less than 24 hours. The findings presented herein demonstrate that UAV-based magnetic surveys are a reliable method of data collection and an efficient alternative to other survey methods, facilitating development of a three-dimensional perspective of distributed volcanic fields.

Nevada

The 1912 Ms 7.2 earthquake in the Denali region of central Alaska

The 2002 M w 7.9 earthquake in central Alaska ruptured 340 km on three faults—Susitna Glacier thrust fault, Denali fault, Totschunda fault—crossing both the Richardson Highway and the Alaska Pipeline. Its occurrence prompted renewed interest in historical large earthquakes that possibly originated on the Denali fault. One of these earthquakes was a M s 7.2 event on July 7, 1912, which we revisit with two approaches: (1) probabilistic relocation of the epicenter using globally recorded arrival times, and (2) compilation and reassessment of shaking intensity reports to estimate a macroseismic epicenter. Our preferred instrumental epicenter is west of the Parks Highway and in agreement with the maximum‐reported shaking, which was from the Parker–Browne expedition of Denali. We also relocated a M s 6.4 aftershock, whose epicenter is 11 km from the mainshock. Candidate faults for the 1912 earthquake include the Denali fault, the McLeod Creek thrust fault, and the Kantishna Hills thrust fault. Future analysis of active faults, paleoseismic results, 1912 instrumental data, and 1912 felt reports may help in interpreting the fault and mechanism of the 1912 earthquake.

Alaska

Overview of the Cenozoic geology of the northern Harrat Rahat volcanic field, Kingdom of Saudi Arabia

The Harrat Rahat volcanic field, located in the west-central part of the Kingdom of Saudi Arabia, is one of the larger Cenozoic harrats among the more than 17 harrats situated upon the Arabia Plate. The map plate contained herein shows, at a scale of 1:100,000, the mapped volcanic geology of northern Harrat Rahat, which consists of the northernmost one-fifth of Harrat Rahat. Northern Harrat Rahat has an area of about 3,340 square kilometers (km 2 ), of which 2,567 km 2 is covered by Harrat Rahat volcanic rocks and deposits, and it encompasses more than 900 exposed vents (that is, craters, cryptodomes, maars, and scoria cones), 289 of which are isolated by younger volcanic deposits and have not been correlated with the 234 volcanic rock units distinguished by geologic mapping. Northern Harrat Rahat is of special interest owing to its proximity to the city of Al Madinah al Munawwarah, which sits within, and is continuing to expand southward over, the north end of the volcanic field. Al Madinah is home to an expanding population, currently at more than 2 million residents, together with the intermittent addition of approximately 3 million pilgrims during Hajj and Umrah (religious visitations). The center of Al Madinah is less than 8 km from lava flows of the only confirmed historically documented eruption, which occurred in 1256 C.E. (654 A.H.). Earlier prehistoric lava flows also encroached into the area of the present-day city limits, as demonstrated by volcanic rocks exposed widely throughout the city in roadcuts, parks, and excavations for new buildings, although no evidence has been found of any other than the 1256 C.E. lava having reached that area during times of human habitation. Geologic mapping was undertaken by the U.S. Geological Survey in collaboration with the Saudi Geological Survey. The features of primary interest within the map area are scoria cones, lava flows, lava domes, craters, and pyroclastic deposits from the Quaternary, which have compositions of basalt, hawaiite, mugearite, benmoreite, and trachyte. The geologic mapping was published by Downs and others (2019) on a single sheet at 1:75,000 scale and two detailed sheets at 1:25,000 scale, accompanied by detailed explanations of the geology. This report presents the geology on a single sheet at 1:100,000 scale and provides condensed geologic explanations for the convenience of readers of this volume. Some minor errors of nomenclature and lava source regions that do not change fundamental interpretations have been corrected herein.

Professional Paper

Resurvey of the Marble Canyon and Bridge Canyon dam sites in Grand Canyon National Park—Changes in sediment storage and evidence supporting the occurrence of bedrock incision through the mid-20th century

The Bureau of Reclamation developed an extensive plan for a network of dams, water tunnels, and hydropower plants in and around Grand Canyon, Arizona, in the 1940s through 1960s. The two largest of these planned dams were the Marble Canyon and Bridge Canyon Dams on the Colorado River. Though these dams were ultimately never built, Reclamation conducted extensive topographic, bathymetric, and subsurface exploration work at the sites proposed for these dams in the 1940s and 1950s. Resurveys of these dam sites were conducted between 1998 and 2021 to determine the changes in sediment storage at these dam sites caused by the upstream construction and operation of Glen Canyon Dam and by the recession of Lake Mead, the reservoir impounded by Hoover Dam. The resurveys of the Marble Canyon dam sites indicate that the post-1950s changes in sediment storage at these dam sites are broadly consistent with flux-based estimates of voluminous sand erosion from Marble Canyon since the 1963 closure of Glen Canyon Dam. These resurveys also suggest that the pre-dam longitudinal variation in sediment thickness over bedrock played a key role in determining the locations of the sand erosion induced by Glen Canyon Dam; more sand eroded from locations where more sand was present in the 1950s. The resurvey of the Bridge Canyon dam sites indicates that the Colorado River’s incision of the Lake Mead delta is regulated both by bed-sediment grain size and downstream hydraulic controls. Finally, analyses of bed-sediment thickness and sedimentological data at the dam sites, and observations of bed scour and gravel transport, suggest that sufficient bedrock was exposed to allow bedrock incision during commonly recurring pre-dam snowmelt floods that entrained small boulders into transport.

Arizona

The 3D Elevation Program—Supporting the economy of Massachusetts

Introduction Massachusetts extends from the mountains of the Appalachian system in the west of the State to the sandy beaches and rocky shorelines of the Atlantic coast in the east. Inland topographic data support a wide range of important activities, including geologic mapping, transportation planning, forest and wildlife management, quantifying ecological services, water supply protection, commonwealth-wide infrastructure planning, local site planning, and flood-plain management. Nearshore bathymetry can be used to support coastal portions of the Commonwealth by addressing the combined threats of ocean warming, strong storm surge, and rising sea levels. The maintenance and (or) expansion of Massachusetts ports (for instance, Boston, New Bedford) and Cape Cod sediment management depends upon the accurate mapping of bathymetry and the frequent influx of sediment and redeposition. Critical applications that address the broad range of requirements depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Massachusetts. The status of available and in-progress 3DEP baseline lidar data in Massachusetts is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.23 million in new benefits annually to Massachusetts. The top 10 Massachusetts business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Massachusetts

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States

Constraining landslide frequency across the United States to inform county-level risk reduction

Informative landslide hazard estimates are needed to support landslide mitigation strategies to reduce landslide risk across the United States. Whereas existing national-scale landslide susceptibility products assess where landslides are likely to occur, they do not address how often , which is a critical element of landslide hazard and risk assessments. In particular, the U.S. Federal Emergency Management Agency's National Risk Index (NRI) requires landslide frequency estimates to inform expected annual loss estimates. We present county-level landslide frequency (landslides per area per year) estimates for the 50 US states. We applied Bayesian negative binomial regression to estimate both the expected (average) reported landslide frequency and full distribution of annual landslide counts for each county. We compared a suite of models that used combinations of landslide-susceptible area, probability of potentially triggering earthquakes, frequency of potentially triggering precipitation, and ecological region as predictors. We trained our models with landslide inventory data from counties with the most comprehensive records available nationwide and used zero-inflated negative binomial distributions as an incompleteness model to correct for temporal reporting gaps. We selected a preferred frequency model to inform the NRI based on information criteria and physically plausible parameter estimates. The model showed that average annual reported landslide frequencies vary by 5 orders of magnitude across US counties, ranging from 0.002 (0.00015–0.05) landslides 1000 km −2 yr −1 in Kusilvak Census Area, Alaska, to 29 (19–46) landslides 1000 km −2 yr −1 in Lake County, California, reflecting the country's strong variations in landslide susceptibility, earthquake probability, and other factors for which ecological region serves as a proxy. Counties with estimated frequencies in the top 20 % of all counties are predominately along the West Coast of the continental United States, in mountainous regions of the Pacific Northwest and Intermountain West, in locally steep or earthquake-prone regions of the Midwest and Southeast, along the Appalachians, in southern and southeastern Alaska, and on some Hawaiian islands. By examining the number of landslides predicted in 99th percentile years for each county, we identified that 26 % of US counties likely have potential for widespread landsliding with more than 10 landslides 1000 km −2 yr −1 , even when such large events have not been reported in the training data for that county. Overall, our results better represent the range of possible landslide frequencies and spatial variations than previous national-scale estimates reported in the NRI, and our approach can inform other risk-reduction and loss-mitigation efforts across the United States and globally.

Natural Hazards and Earth System Sciences

Cambrian and Ordovician stratigraphy, conodont biostratigraphy, and microfacies analysis to support 1:24,000-scale geologic mapping of the southern Lake Champlain valley, New York and Vermont

Introduction Geologic mapping in the southern Lake Champlain valley of New York and Vermont (fig. 1) has required evaluation of stratigraphic nomenclature used since the early 1900s. The paleogeography of the Cambrian and Ordovician adjacent to the Adirondack Highlands, the high-relief mountains of Proterozoic igneous and metamorphic rocks of northern New York, has impacted the lithostratigraphic succession, facies changes, and several hiatuses that occur within the package of clastic and carbonate rocks that demonstrates overall deepening consistent from the southern to northern Appalachians. The stratigraphic nomenclature used for the geologic mapping of the Cambrian and Ordovician strata of the study area is derived from evaluation of names put forth by previous workers from areas of northern New York and western Vermont. Descriptions of type localities or type sections and other criteria set forth by the North American Stratigraphic Code (North American Commission on Stratigraphic Nomenclature [NACSN], 2021) were consulted. The North American Stratigraphic Code states that lithostratigraphic units, such as the fundamental unit, the formation, be defined by lithic character and be mappable (NACSN, 2021, Article 24). However, some early workers (Walcott, 1912; Kay, 1937; Fisher and Hanson, 1951; Oxley and Kay, 1959) have defined stratigraphic units based on fossil content, which may or may not be facies dependent, and hence may not be mappable as lithostratigraphic units. Although preservation of older names takes priority in stratigraphic nomenclature (NACSN, 2021, Article 7), some do not have adequately defined stratotypes or are located a distance away with different lithologies than that in the study area. Biostratigraphy can be a helpful tool for understanding correlations and facies changes. Herein, conodont biostratigraphy is utilized to date and correlate separate lithologic units. Further, microfacies analyses of units through inspection of petrographic thin sections provide paleogeographic information that helps in understanding the genesis of geologic units.

New York, Vermont

Coastal barrier resilience and resistance: Analysis and metrics for characterizing coastal state

Barrier islands are shaped by a variety of short- and long-term environmental processes such as storms and relative sea-level rise. These islands, found along the estuarine-marine interface, provide ecosystem services including storm surge and wave attenuation, erosion protection to inland marshes, habitat for fish and wildlife, and recreation. Natural resource managers require actionable information on how barrier island resilience and resistance changes over time to understand how an island’s current state relates to past conditions and to inform restoration prioritization and implementation. The U.S. Geological Survey and The Water Institute collaborated on a study to develop indicators of resilience and resistance for barrier islands in Louisiana. Here, resilience captures island persistence on yearly to decadal time scales, and resistance captures persistence on event time scales of days to weeks. The indicators fall in two categories: Tier 1 Screening Metrics, that can be readily calculated from available data, are easily interpretable as an evaluation of barrier condition, and provide a high-level snapshot of overall barrier resilience and resistance; and Tier 2 Analysis Metrics, which are detailed metrics that required specialized analysis and interpretation and are more applicable to answering specific questions managers may have about barrier state. The research team derived Tier 1 resilience indicators from subaerial land and vegetation cover calculated from publicly available maps and products based on satellite imagery. By benchmarking the total land and vegetation extent against their respective historical maxima, this metric provides a snapshot of an island’s current state in the context of its long-term trajectory. The research team developed Tier 1 resistance indicators based on subaerial island configuration and water level recurrence as a proxy for evaluating island resistance to storms, which are the primary driver of short-term change. These Tier 1 metrics can be analyzed over time to provide a high-level assessment of how an island’s resistance decreases because of elevation loss or sea-level rise or increases due to restoration or natural recovery. The research team developed Tier 2 resilience and resistance indicators and associated analyses to provide detailed information for specific time periods or applications (e.g., wildlife management). These metrics include habitat coverage from high-resolution maps, which show composition changes over time to capture the evolving resilience of specific habitat types; high tide flooding analysis, which evaluate island area relative to specified flooding thresholds to characterize resistance in the short-term or, if analyzed over time, indicate changes in resilience; and hypsometric curve analysis, which allows managers to evaluate island area changes above their own elevation benchmarks of interest and similarly characterize resistance in the short-term or indicate changes in resilience if assessed over time. The research team calculated Tier 1 metrics of the barrier islands and headlands along the coast of Louisiana for the period of 1984 through 2021 and Tier 2 metrics for select times during that period depending on data available and quality. The results were captured in a report card for each barrier, which also includes an overview of the metrics and their interpretation; a restoration and storm history; and Tier 1 and Tier 2 metric analysis, including benchmarking against coastwide and regional values as well as to an island’s pre-restoration trajectory. These report cards provide a readily digestible synthesis of barrier condition and trajectory that coastal managers can use to support restoration prioritization and other decisions.

Louisiana

The 3D National Topography Model Call for Action—Part 1. The 3D Hydrography Program

The U.S. Geological Survey is initiating the 3D Hydrography Program (3DHP), the first systematic remapping of the Nation’s surface waters since the original 1:24,000-scale topographic mapping program was active from 1947 to 1992. Building on decades of experience maintaining the National Hydrography Dataset (NHD), the Watershed Boundary Dataset (WBD), and the NHDPlus High Resolution (NHDPlus HR), the 3DHP will completely refresh the Nation’s hydrography data and improve discovery and sharing of water-related data. The design of the 3DHP is based on the results of a study that estimated that the fully implemented program would have the potential to provide more than $1 billion in benefits to Federal, State, Tribal, Territorial, and local governments and to private and nonprofit organizations every year, in addition to myriad societal benefits. The 3DHP would directly support better decision making regarding water resources by providing more accurate, complete, and integrated information than is currently available. The 3DHP datasets will include a three-dimensional (3D) hydrography network generated from and integrated with elevation data from the 3D Elevation Program (3DEP) to better represent stream gradients and channel conditions, along with waterbodies, hydrologic units, hydrologically enhanced elevation and other surfaces, and more consistent and accurate attributes. The 3DHP datasets will inherit key attributes of the NHD, WBD, and NHDPlus HR, and they also will include new attributes and links to other data such as the U.S. Fish and Wildlife Service National Wetlands Inventory, groundwater data, and engineered hydrologic systems such as stormwater networks. The 3DHP will be designed to provide a set of open and interoperable web-based tools, maps, and data catalogs, creating a robust system for users to reference their information about water; the system elements are collectively referred to as the “infostructure.” The 3DHP and the infostructure can provide a foundational geospatial underpinning for the Internet of Water, a community-based effort to modernize tools and technologies to share water data. As proposed, the 3DHP would begin providing products and services to the public in 2024.

Circular

Methodology for inclusion of produced and stored carbon dioxide in the U.S. Geological Survey Federal lands greenhouse gas inventory

The U.S. Geological Survey (USGS) has developed two new carbon dioxide (CO2) emissions and sequestration accounting methods for use in future reports. The first method is a Federal lease-produced CO2 emissions calculation for an update of the report, “Federal Lands Greenhouse Gas Emissions and Sequestration in the United States.” The methodology to incorporate Federal lease CO2 production emissions into the updated report relies on CO2 sales royalty data from the Office of Natural Resources Revenue (ONRR). The end usage points for the gas include enhanced oil recovery with CO2 (CO2-EOR), food and beverage, and chemical production. CO2-EOR is the main end point for natural CO2 production in the United States; it accounted for 94% of usage in 2022 [1]. Federal lands emissions from this sector are estimated at 460 metric tons of CO2 in 2022, a very small amount relative to most other Federal lands emissions sector estimates. The second new method, planned for a separate report, is a calculation of the geologic storage of CO2 on Federal lands. The second method estimates the CO2 stored under Federal surface lands and documents Federal climate change mitigation efforts. Currently, there is no storage of CO2 at an industrial level on Federal lands, however multiple proposals and projects are planned. This method was developed on non-Federal lands datasets in an effort to prepare for when these activities on Federal lands will require accounting. National estimates for CO2 geologic storage using this method, but without a Federal lands filtering step, totaled 8.0 million metric tons (Mt) in 2022. The two methods described here are new benchmark methods in a collection of accounting procedures to document the current state of greenhouse gas emissions and their storage on Federal lands. These benchmarks can then be used to measure any subsequent changes in emissions from or carbon storage beneath Federal lands. While the magnitude of the values is currently non-existent to small, emissions mitigation goals established by decision makers indicate that these values will grow, and their documentation will take on greater value and use.

continental United States