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At least 847 records · Page 47Linked to original sources

USGS2006

Phase equilibria constraints on the chemical and physical evolution of the campanian ignimbrite

The Campanian Ignimbrite is a > 200 km3 trachyte-phonolite pyroclastic deposit that erupted at 39.3 ?? 0.1 ka within the Campi Flegrei west of Naples, Italy. Here we test the hypothesis that Campanian Ignimbrite magma was derived by isobaric crystal fractionation of a parental basaltic trachyandesitic melt that reacted and came into local equilibrium with small amounts (5-10 wt%) of crustal rock (skarns and foid-syenites) during crystallization. Comparison of observed crystal and magma compositions with results of phase equilibria assimilation-fractionation simulations (MELTS) is generally very good. Oxygen fugacity was approximately buffered along QFM+1 (where QFM is the quartz-fayalite-magnetite buffer) during isobaric fractionation at 0.15 GPa (???6 km depth). The parental melt, reconstructed from melt inclusion and host clinopyroxene compositions, is found to be basaltic trachyandesite liquid (51.1 wt% SiO2, 9.3 wt% MgO, 3 wt% H2O). A significant feature of phase equilibria simulations is the existence of a pseudo-invariant temperature, ???883??C, at which the fraction of melt remaining in the system decreases abruptly from ???0.5 to < 0.1. Crystallization at the pseudo-invariant point leads to abrupt changes in the composition, properties (density, dissolved water content), and physical state (viscosity, volume fraction fluid) of melt and magma. A dramatic decrease in melt viscosity (from 1700 Pa s to ???200 Pa s), coupled with a change in the volume fraction of water in magma (from ??? 0.1 to 0.8) and a dramatic decrease in melt and magma density acted as a destabilizing eruption trigger. Thermal models suggest a timescale of ??? 200 kyr from the beginning of fractionation until eruption, leading to an apparent rate of evolved magma generation of about 10-3 km3/year. In situ crystallization and crystal settling in density-stratified regions, as well as in convectively mixed, less evolved subjacent magma, operate rapidly enough to match this apparent volumetric rate of evolved magma production. ?? Copyright 2007 Oxford University Press.

Journal of Petrology↗

USGS2007

Compositional zoning of the Bishop Tuff

Compositional data for >400 pumice clasts, organized according to eruptive sequence, crystal content, and texture, provide new perspectives on eruption and pre-eruptive evolution of the >600 km 3 of zoned rhyolitic magma ejected as the Bishop Tuff during formation of Long Valley caldera. Proportions and compositions of different pumice types are given for each ignimbrite package and for the intercalated plinian pumice-fall layers that erupted synchronously. Although withdrawal of the zoned magma was less systematic than previously realized, the overall sequence displays trends toward greater proportions of less evolved pumice, more crystals (0·5–24 wt %), and higher FeTi-oxide temperatures (714–818°C). No significant hiatus took place during the 6 day eruption of the Bishop Tuff, nearly all of which issued from an integrated, zoned, unitary reservoir. Shortly before eruption, however, the zoned melt-dominant portion of the chamber was invaded by batches of disparate lower-silica rhyolite magma, poorer in crystals than most of the resident magma but slightly hotter and richer in Ba, Sr, and Ti. Interaction with resident magma at the deepest levels tapped promoted growth of Ti-rich rims on quartz, Ba-rich rims on sanidine, and entrapment of near-rim melt inclusions relatively enriched in Ba and CO 2 . Varied amounts of mingling, even in higher parts of the chamber, led to the dark gray and swirly crystal-poor pumices sparsely present in all ash-flow packages. As shown by FeTi-oxide geothermometry, the zoned rhyolitic chamber was hottest where crystal-richest, rendering any model of solidification fronts at the walls or roof unlikely. The main compositional gradient (75–195 ppm Rb; 0·8–2·2 ppm Ta; 71–154 ppm Zr; 0·40–1·73% FeO*) existed in the melt, prior to crystallization of the phenocryst suite observed, which included zircon as much as 100 kyr older than the eruption. The compositions of crystals, though themselves largely unzoned, generally reflect magma temperature and the bulk compositional gradient, implying both that few crystals settled or were transported far and that the observed crystals contributed little to establishing that gradient. Upward increases in aqueous gas and dissolved water, combined with the adiabatic gradient (for the ∼ 5 km depth range tapped) and the roofward decline in liquidus temperature of the zoned melt, prevented significant crystallization against the roof, consistent with dominance of crystal-poor magma early in the eruption and lack of any roof-rind fragments among the Bishop ejecta, before or after onset of caldera collapse. A model of secular incremental zoning is advanced wherein numerous batches of crystal-poor melt were released from a mush zone (many kilometers thick) that floored the accumulating rhyolitic melt-rich body. Each batch rose to its own appropriate level in the melt-buoyancy gradient, which was self-sustaining against wholesale convective re-homogenization, while the thick mush zone below buffered it against disruption by the deeper (non-rhyolitic) recharge that augmented the mush zone and thermally sustained the whole magma chamber. Crystal–melt fractionation was the dominant zoning process, but it took place not principally in the shallow melt-rich body but mostly in the pluton-scale mush zone before and during batchwise melt extraction.

California↗

USGS2008

The roles of fractional crystallization, magma mixing, crystal mush remobilization and volatile-melt interactions in the genesis of a young basalt-peralkaline rhyolite suite, the greater Olkaria volcanic complex, Kenya Rift valley

The Greater Olkaria Volcanic Complex is a young (???20 ka) multi-centred lava and dome field dominated by the eruption of peralkaline rhyolites. Basaltic and trachytic magmas have been erupted peripherally to the complex and also form, with mugearites and benmoreites, an extensive suite of magmatic inclusions in the rhyolites. The eruptive rocks commonly represent mixed magmas and the magmatic inclusions are themselves two-, three- or four-component mixes. All rock types may carry xenocrysts of alkali feldspar, and less commonly plagioclase, derived from magma mixing and by remobilization of crystal mushes and/or plutonic rocks. Xenoliths in the range gabbro-syenite are common in the lavas and magmatic inclusions, the more salic varieties sometimes containing silicic glass representing partial melts and ranging in composition from anorthite ?? corundum- to acmite-normative. The peralkaline varieties are broadly similar, in major element terms, to the eruptive peralkaline rhyolites. The basalt-trachyte suite formed by a combination of fractional crystallization, magma mixing and resorption of earlier-formed crystals. Matrix glass in metaluminous trachytes has a peralkaline rhyolitic composition, indicating that the eruptive rhyolites may have formed by fractional crystallization of trachyte. Anomalous trace element enrichments (e.g. ??? 2000 ppm Y in a benmoreite) and negative Ce anomalies may have resulted from various Na- and K-enriched fluids evolving from melts of intermediate composition and either being lost from the system or enriched in other parts of the reservoirs. A small group of nepheline-normative, usually peralkaline, magmatic inclusions was formed by fluid transfer between peralkaline rhyolitic and benmoreitic magmas. The plumbing system of the complex consists of several independent reservoirs and conduits, repeatedly recharged by batches of mafic magma, with ubiquitous magma mixing. ?? The Author 2008. Published by Oxford University Press. All rights reserved.

Journal of Petrology↗

USGS2008

Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA

Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge–magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0·5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0·1 and 0·5 mm) that have core An contents of 66–69, and microlites (long axis < 0·1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution–precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma bodies.

Journal of Petrology↗

USGS2009

Magma evolution and ascent at the craters of the moon and neighboring volcanic fields, southern Idaho, USA: Implications for the evolution of polygenetic and monogenetic volcanic fields

The evolution of polygenetic and monogenetic volcanic fields must reflect differences in magma processing during ascent. To assess their evolution we use thermobarometry and geochemistry to evaluate ascent paths for neighboring, nearly coeval volcanic fields in the Snake River Plain, in south-central Idaho, derived from (1) dominantly Holocene polygenetic evolved lavas from the Craters of the Moon lava field (COME) and (2) Quaternary non-evolved, olivine tholeiites (NEOT) from nearby monogenetic volcanic fields. These data show that NEOT have high magmatic temperatures (1205 + or - 27 degrees C) and a narrow temperature range (< 25 degrees C) at any given depth; NEOT parent magmas partially crystallize within the middle crust (14-17 km), but with little time for cooling or assimilation. In contrast, COME magmas partially crystallize at similar depths, but at any given depth exhibit lower temperatures (by ~40 degrees C), and wider temperature ranges (>50 degrees C). Prolonged storage of COME magmas allows them to evolve to higher 87 Sr/ 86 Sr and SiO 2 , and lower MgO and 143 Nd/ 144 Nd. Most importantly, ascent paths control evolution: NEOT often erupt near the axis of the plain where high-flux (Yellowstone-related), pre-Holocene magmatic activity replaces granitic middle crust with basaltic sills, resulting in a net increase in NEOT magma buoyancy. COME flows erupt off-axis, where felsic crustal lithologies sometimes remain intact, providing a barrier to ascent and a source for crustal contamination. A three-stage ascent process explains the entire range of erupted compositions. Stage 1 (40-20 km): picrites are transported to the middle crust, undergoing partial crystallization of olivine + or - clinopyroxene. COME magmas pass through unarmored conduits and assimilate 1% or less of ancient gabbroic crust having high Sr and 87 Sr/ 86 Sr and low SiO 2 . Stage 2 (20-10 km): magmas are stored within the middle crust, and evolve to moderate MgO (10%). NEOT magmas, reaching 10% MgO, are positively buoyant and migrate through the middle crust. COME magmas remain negatively buoyant and so crystallize further and assimilate middle crust. Stage 3 (15-0 km): final ascent and eruption occurs when volatile contents, increased by differentiation, are sufficient (1-2 wt % H 2 O) to provide magma buoyancy through the middle (and upper) crust.

Idaho↗

USGS2010

The role of water in generating the calc-alkaline trend: New volatile data for aleutian magmas and a new tholeiitic index

The origin of tholeiitic (TH) versus calc-alkaline (CA) magmatic trends has long been debated. Part of the problem stems from the lack of a quantitative measure for the way in which a magma evolves. Recognizing that the salient feature in many TH–CA discrimination diagrams is enrichment in Fe during magma evolution, we have developed a quantitative index of Fe enrichment, the Tholeiitic Index (THI): THI = Fe 4 ·0 /Fe 8 ·0 , where Fe 4 ·0 is the average FeO* concentration of samples with 4 ± 1 wt % MgO, and Fe 8 ·0 is the average FeO* at 8 ± 1 wt % MgO. Magmas with THI > 1 have enriched in FeO* during differentiation from basalts to andesites and are tholeiitic; magmas with THI < 1 are calc-alkaline. Most subduction zone volcanism is CA, but to varying extents; the THI expresses the continuum of Fe enrichment observed in magmatic suites in all tectonic settings. To test various controls on the development of CA trends, we present new magmatic water measurements in melt inclusions from eight volcanoes from the Aleutian volcanic arc (Augustine, Emmons, Shishaldin, Akutan, Unalaska, Okmok, Seguam, and Korovin). Least degassed H 2 O contents vary from ∼2 wt % (Shishaldin) to >7 wt % (Augustine), spanning the global range in arc mafic magmas. Within the Aleutian data, H 2 O correlates negatively with THI, from strongly calc-alkaline (Augustine, THI = 0·65) to moderately tholeiitic (Shishaldin, THI = 1·16). The relationship between THI and magmatic water is maintained when data are included from additional arc volcanoes, back-arc basins, ocean islands, and mid-ocean ridge basalts (MORBs), supporting a dominant role of magmatic water in generating CA trends. An effective break between TH and CA trends occurs at ∼2 wt % H 2 O. Both pMELTs calculations and laboratory experiments demonstrate that the observed co-variation of H 2 O and THI in arcs can be generated by the effect of H 2 O on the suppression of plagioclase and the relative enhancement of Fe-oxides on the liquid line of descent. The full THI–H 2 O array requires an increase in fO 2 with H 2 O, from ≤FMQ (where FMQ is the fayalite–magnetite–quartz buffer) in MORB to ∼ΔFMQ +0·5 to +2 in arcs, consistent with inferences from measured Fe and S species in glasses and melt inclusions. A curve fit to the data, H 2 O (wt % ± 1·2) = exp[(1·26 – THI)/0·32], may provide a useful tool for estimating the H 2 O content of magmas that are inaccessible to melt inclusion study.

Journal of Petrology↗

USGS2011

Mineralogy and composition of the oceanic mantle

The mineralogy of the oceanic basalt source region is examined by testing whether a peridotite mineralogy can yield observed whole-rock and olivine compositions from (1) the Hawaiian Islands, our type example of a mantle plume, and (2) the Siqueiros Transform, which provides primitive samples of normal mid-ocean ridge basalt. New olivine compositional data from phase 2 of the Hawaii Scientific Drilling Project (HSDP2) show that higher Ni-in-olivine at the Hawaiian Islands is due to higher temperatures ( T ) of melt generation and processing (by c . 300°C) related to the Hawaiian mantle plume. D Ni is low at high T , so parental Hawaiian basalts are enriched in NiO. When Hawaiian (picritic) parental magmas are transported to shallow depths, olivine precipitation occurs at lower temperatures, where D Ni is high, leading to high Ni-in-olivine. Similarly, variations in Mn and Fe/Mn ratios in olivines are explained by contrasts in the temperatures of magma processing. Using the most mafic rocks to delimit Siqueiros and Hawaiian Co and Ni contents in parental magmas and mantle source compositions also shows that both suites can be derived from natural peridotites, but are inconsistent with partial melting of natural pyroxenites. Whole-rock compositions at Hawaii and Siqueiros are also matched by partial melting experiments conducted on peridotite bulk compositions. Hawaiian whole-rocks have elevated FeO contents compared with Siqueiros, which can be explained if Hawaiian parental magmas are generated from peridotite at 4–5 GPa, in contrast to pressures of slightly greater than 1 GPa for melt generation at Siqueiros; these pressures are consistent with olivine thermometry, as described in an earlier paper. SiO 2 -enriched Koolau compositions are reproduced if high-Fe Hawaiian parental magmas re-equilibrate at 1–1·5 GPa. Peridotite partial melts from experimental studies also reproduce the CaO and Al 2 O 3 contents of Hawaiian (and Siqueiros) whole-rocks. Hawaiian magmas have TiO 2 contents, however, that are enriched compared with melts from natural peridotites and magmas derived from the Siqueiros depleted mantle, and consequently may require an enriched source. TiO 2 is not the only element that is enriched relative to melts of natural peridotites. Moderately incompatible elements, such as Ti, Zr, Hf, Y, and Eu, and compatible elements, such as Yb and Lu, are all enriched at the Hawaiian Islands. Such enrichments can be explained by adding 5–10% mid-ocean ridge basalt (crust) to depleted mantle; when the major element composition of such a mixture is recast into mineral components, the result is a fertile peridotite mineralogy.

Hawai'i↗

USGS2012

The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity

Crystal zoning as well as temperature and pressure estimates from phenocryst phase equilibria are used to constrain the architecture of the intermediate-sized magmatic system (some tens of km 3 ) of Volcán Quizapu, Chile, and to document the textural and compositional effects of magma mixing. In contrast to most arc magma systems, where multiple episodes of open-system behavior obscure the evidence of major magma chamber events (e.g. melt extraction, magma mixing), the Quizapu magma system shows limited petrographic complexity in two large historical eruptions (1846–1847 and 1932) that have contrasting eruptive styles. Quizapu magmas and peripheral mafic magmas exhibit a simple binary mixing relationship. At the mafic end, basaltic andesite to andesite recharge magmas complement the record from peripheral cones and show the same limited range of compositions. The silicic end-member composition is almost identical in both eruptions of Quizapu. The effusive 1846–1847 eruption records significant mixing between the mafic and silicic end-members, resulting in hybridized andesites and mingled dacites. These two compositionally simple eruptions at Volcán Quizapu present a rare opportunity to isolate particular aspects of magma evolution—formation of homogeneous dacite magma and late-stage magma mixing—from other magma chamber processes. Crystal zoning, trace element compositions, and crystal-size distributions provide evidence for spatial separation of the mafic and silicic magmas. Dacite-derived plagioclase phenocrysts (i.e. An 25 – 40 ) show a narrow range in composition and limited zonation, suggesting growth from a compositionally restricted melt. Dacite-derived amphibole phenocrysts show similar restricted compositions and furthermore constrain, together with more mafic amphibole phenocrysts, the architecture of the magmatic system at Volcán Quizapu to be compositionally and thermally zoned, in which an andesitic mush is overlain by a homogeneous dacitic magma that is the source for most of the 1846–1847 and 1932 erupted magmas. Dacite formation is best explained by mineral–melt separation (crystal fractionation) from an andesitic mush, which is inferred to have thermally and compositionally buffered the dacite magma thereby keeping it at relatively low crystallinity (<30 vol. %). The dominant cause of compositional diversity is melt separation. Back-mixing of mush (i.e. crystals with signatures of growth both in the andesitic mush and in the dacite magma) into the overlying dacite magma is rarely observed. Recharge events that increase crystal and magma diversity in the dacite magma are limited to an episode of mafic recharge and mixing just prior to the 1846–1847 eruption, where evidence for magma mixing is present on all scales. Chamber-wide mixing was incomplete (mixing efficiency of ∼0·53–0·85) as flow lobes vary significantly in composition along the proposed mixing array. Estimates of viscosity variations during the course of magma mixing suggest that mixing dynamics and the degree of magma interaction on all scales were established at the beginning of the recharge event.

Volcán Quizapu↗

USGS2012

Lower-crustal xenoliths from Jurassic kimberlite diatremes, upper Michigan (USA): Evidence for Proterozoic orogenesis and plume magmatism in the lower crust of the southern Superior Province

Jurassic kimberlites in the southern Superior Province in northern Michigan contain a variety of possible lower-crustal xenoliths, including mafic garnet granulites, rare garnet-free granulites, amphibolites and eclogites. Whole-rock major-element data for the granulites suggest affinities with tholeiitic basalts. P–T estimates for granulites indicate peak temperatures of 690–730°C and pressures of 9–12 kbar, consistent with seismic estimates of crustal thickness in the region. The granulites can be divided into two groups based on trace-element characteristics. Group 1 granulites have trace-element signatures similar to average Archean lower crust; they are light rare earth element (LREE)-enriched, with high La/Nb ratios and positive Pb anomalies. Most plot to the left of the geochron on a 206 Pb/ €204 Pb vs 207 Pb/ €204 Pb diagram, and there was probably widespread incorporation of Proterozoic to Archean components into the magmatic protoliths of these rocks. Although the age of the Group 1 granulites is not well constrained, their protoliths appear to be have been emplaced during the Mesoproterozoic and to be older than those for Group 2 granulites. Group 2 granulites are also LREE-enriched, but have strong positive Nb and Ta anomalies and low La/Nb ratios, suggesting intraplate magmatic affinities. They have trace-element characteristics similar to those of some Mid-Continent Rift (Keweenawan) basalts. They yield a Sm–Nd whole-rock errorchron age of 1046 ± 140 Ma, similar to that of Mid-Continent Rift plume magmatism. These granulites have unusually radiogenic Pb isotope compositions that plot above the 207 Pb/ €204 Pb vs 206 Pb/ €204 Pb growth curve and to the right of the 4·55 Ga geochron, and closely resemble the Pb isotope array defined by Mid-Continent Rift basalts. These Pb isotope data indicate that ancient continental lower crust is not uniformly depleted in U (and Th) relative to Pb. One granulite xenolith, S69-5, contains quartz, and has a unique peraluminous composition. It has the lowest εNd and εHf values of the suite. Its isotopic compositions indicate that it is significantly older than the other granulites. Broken zircon cores encased by younger overgrowths suggest that this granulite includes a large component of pre-existing sedimentary rocks. Two distinct populations of zircons from S69-5 were dated by sensitive high-resolution ion microprobe. Abundant rounded zircons yield ages of 1104 ± 42 (2σ) Ma, which coincide with the Mid-Continent Rift flood basalt eruptions. Their morphology is similar to those found in lower-crustal rocks that have undergone granulite-facies metamorphism and thus they are considered to represent the age of Group 2 granulites. Also present are less abundant elongate zircon grains that yield a mean age of 1387 ± 32 (2σ) Ma. Their elongate shapes indicate growth from a melt or fluid, possibly associated with 1·3–1·5 Ga anorogenic granite magmatism exposed in the shallow crust to the south in Wisconsin, or related to an initial encroachment of the Keweenawan plume upon the lower crust. Older ages recognized in zircon cores are less well constrained but may be related to tectono-magmatic events in the southern Superior craton. Within the studied suite only S69-5 was recognized as a remnant of the Late Archean lower crust into which the Group 1 and 2 mafic granulite precursor basalts were intruded. Collectively, the data show that the lower crust beneath northern Michigan formed in Archean times and underwent a variety of tectono-magmatic processes throughout the Proterozoic, including orogenesis, partial melting and mafic magmatic underplating in response to upwelling mantle plumes.

Michigan↗

USGS2013

Pre-eruptive magmatic conditions at Augustine Volcano, Alaska, 2006: Evidence from amphibole geochemistry and textures

Variations in the geochemistry and texture of amphibole phenocrysts erupted from Augustine Volcano in 2006 provide new insights into pre- and syn-eruptive magma storage and mixing. Amphiboles are rare but present in all magma compositions (low- to high-silica andesites) from the 3 month long eruption. Unzoned magnesiohornblende in the high- and low-silica andesites exhibit limited compositional variability, relatively high SiO 2 (up to 49·7 wt %), and relatively low Al 2 O 3 (< 11·1 wt %). Intermediate-silica andesites and quenched mafic enclaves contain amphiboles that vary in composition (e.g. SiO 2 40·8–48·9 wt %, Al 2 O 3 6·52–15·2 wt %) and classification (magnesiohornblende–magnesiohastingsite–tschermakite). Compositional variation in amphibole is primarily controlled by temperature-dependent substitutions. Both high- and low-silica andesites represent remnant magmas that were stored in the shallow crust at 4–8 km depth, remaining distinct owing to a complex subsurface plumbing system. Intermediate-silica andesites and quenched mafic inclusions represent pre-eruptive hybrids of resident high- and low-silica andesite magmas and an intruding basalt. Amphiboles in explosive phase high-silica andesites are largely euhedral and unreacted, consistent with the high magma flux rates from depth during this phase (up to 13 800 m 3 s –1 ). Phenocrysts from the other lithologies have reaction rims that range from 1 to >1000 μm in thickness. Reaction rim microlite sizes correlate with reaction rim thicknesses. Reaction rims <50 μm thick contain microlites 1–10 μm in length whereas reaction rims >80 μm thick contain microlites 10–100 μm in length. Differentiating between heating- and decompression-induced amphibole reaction rim formation is problematic because of a lack of experimental constraints. We attempt a new approach to assessing reaction rim formation, based on a kinetic theory of crystal nucleation and growth, in which the differences in reaction rim textures represent different degrees of amphibole disequilibrium. Large crystals and low number densities suggest relatively lower levels of disequilibrium resulting in growth-dominated crystallization. Smaller crystals and larger number densities are indicative of higher nucleation rates and a high driving force.

Alaska↗

USGS2015

Pre-eruptive conditions of the Hideaway Park topaz rhyolite: Insights into metal source and evolution of magma parental to the Henderson porphyry molybdenum deposit, Colorado

The Hideaway Park tuff is the only preserved extrusive volcanic unit related to the Red Mountain intrusive complex, which produced the world-class Henderson porphyry Mo deposit. Located within the Colorado Mineral Belt, USA, Henderson is the second largest Climax-type Mo deposit in the world, and is therefore an excellent location to investigate magmatic processes leading to Climax-type Mo mineralization. We combine an extensive dataset of major element, volatile, and trace element abundances in quartz-hosted melt inclusions and pumice matrix glass with major element geochemistry from phenocrysts to reconstruct the pre-eruptive conditions and the source and evolution of metals within the magma. Melt inclusions are slightly peraluminous topaz rhyolitic in composition and are volatile-charged (≤6 wt % H 2 O, ≤600 ppm CO 2 , &sim;0·3–1·0 wt % F, &sim;2300–3500 ppm Cl) and metal-rich (&sim;7–24 ppm Mo, &sim;4–14 ppm W, &sim;21–52 ppm Pb, &sim;28–2700 ppm Zn, <0·1–29 ppm Cu, &sim;0·3–1·8 ppm Bi, &sim;40–760 ppb Ag, &sim;690–1400 ppm Mn). Melt inclusion and pumice matrix glass chemistry reveal that the Hideaway Park magma evolved by large degrees of fractional crystallization (≤60–70%) during quartz crystallization and melt inclusion entrapment at pressures of ≤300 MPa (≤8 km depth), with little to no crystallization upon shallow ascent and eruption. Filter pressing, crystal settling, magma recharge and mixing of less evolved rhyolite melt, and volatile exsolution were important processes during magma evolution; the low estimated viscosities (&sim;10 5 –10 10  Pa s) of these H 2 O- and F-rich melts probably enhanced these processes. A noteworthy discrepancy between the metal contents in the pumice matrix glass and in the melt inclusions suggests that after quartz crystallization ceased upon shallow magma ascent and eruption, the Hideaway Park magma exsolved an aqueous fluid into which Mo, Bi, Ag, Zn, Mn, Cs, and Y strongly partitioned. Given that the Henderson deposit contains anomalous abundances of not only Mo, but also W, Pb, Zn, Cu, Bi, Ag, and Mn, we suggest that these metals were sourced from similar fluids exsolved from unerupted portions of the same magmatic system. Trace element ratios imply that Mo was sourced deep, from either the lower crust or metasomatized mantle. The origin of sulfur remains unresolved; however, given the extremely low S solubility of rhyolite melts in the shallow crust we favor the possibility that another source of S might supplement or account for that present in the ore deposit, probably the comagmatic, mantle-derived lamprophyres that occur in minor quantities with the voluminous topaz rhyolites in the area. To account for the 437 Mt of MoS 2 (&sim;1·0 × 10 6  t Mo) present in the Henderson ore deposit, a volume of &sim;45 km 3 of Hideaway Park rhyolite magma would have been necessary to supply the Mo (a cylindrical pluton measuring 3·1 km × 6·0 km) along with sparging of &sim;6·8 × 10 5  t of S from &sim;0·05 km 3 of lamprophyre magma. Based on a weighted mean 40 Ar/ 39 Ar age of 27·58 ± 0·24 Ma, similar melt geochemistry, and characteristically F-rich biotite phenocrysts, we conclude that the Hideaway Park tuff was cogenetic with the intrusions at Red Mountain that formed the Henderson deposit.

Colorado↗

USGS2015

Mechanisms and timescales of generating eruptible rhyolitic magmas at Yellowstone caldera from zircon and sanidine geochronology and geochemistry

We constrain the physical nature of the magma reservoir and the mechanisms of rhyolite generation at Yellowstone caldera via detailed characterization of zircon and sanidine crystals hosted in three rhyolites erupted during the (ca. 170 – 70 ka) Central Plateau Member eruptive episode – the most recent post-caldera magmatism at Yellowstone. We present 238U-230Th crystallization ages and trace-element compositions of the interiors and surfaces (i.e., unpolished rims) of individual zircon crystals from each rhyolite. We compare these zircon data to 238U- 230Th crystallization ages of bulk sanidine separates coupled with chemical and isotopic data from single sanidine crystals. Zircon age and trace-element data demonstrate that the magma reservoir that sourced the Central Plateau Member rhyolites was long-lived (150 – 250 kyr) and genetically related to the preceding episode of magmatism, which occurred ca. 256 ka. The interiors of most zircons in each rhyolite were inherited from unerupted material related to older stages of Central Plateau Member magmatism or the preceding late Upper Basin Member magmatism (i.e., are antecrysts). Conversely, most zircon surfaces crystallized near the time of eruption from their host liquids (i.e., are autocrystic). The repeated recycling of zircon interiors from older stages of magmatism demonstrates that sequentially erupted Central Plateau Member rhyolites are genetically related. Sanidine separates from each rhyolite yield 238U-230Th crystallization ages at or near the eruption age of their host magmas, coeval with the coexisting zircon surfaces, but are younger than the coexisting zircon interiors. Chemical and isotopic data from single sanidine crystals demonstrate that the sanidines in each rhyolite are in equilibrium with their host melts, which considered along with their near-eruption crystallization ages suggests that nearly all CPM sanidines are autocrystic. The paucity of antecrystic sanidine crystals relative to antecrystic zircons require a model where eruptible rhyolites are generated by extracting melt and zircons from a long-lived mush of immobile crystal-rich magma. In this process the larger sanidine crystals remain trapped in the locked crystal network. The extracted melts (plus antecrystic zircon) amalgamate into a liquid dominated (i.e., eruptible) magma body that is maintained as a physically distinct entity relative to the bulk of the long-lived crystal mush. Zircon surfaces and sanidines in each rhyolite crystallize after melt extraction/amalgamation and their ages constrain the residence time of eruptible magmas at Yellowstone. Residence times of the large volume rhyolites (~40 – 70 km3) are ≤ 1 kyr (conservatively < 6 kyr), which suggests that large volumes of rhyolite can be generated rapidly by extracting melt from a crystal mush. Because the lifespan of the crystal mush that sourced the Central Plateau Member rhyolites is two orders of magnitude longer than the residence time of eruptible magma bodies within the reservoir, it is apparent that the Yellowstone magma reservoir spends most of its time in a largely-crystalline (i.e., uneruptible) state, similar to the present-day magma reservoir, and that eruptible magma bodies are ephemeral features.

Idaho, Wyoming↗

USGS2017

238U–230Th–226Ra–210Pb–210Po disequilibria constraints on magma generation, ascent, and degassing during the ongoing eruption of Kīlauea

The timescales of magma genesis, ascent, storage and degassing at Kīlauea volcano, Hawai‘i are addressed by measuring 238 U-series radionuclide abundances in lava and tephra erupted between 1982 and 2008. Most analyzed samples represent lavas erupted by steady effusion from Pu‘u ‘Ō‘ō and Kūpahianaha from 1983 to 2008. Also included are samples erupted at the summit in April 1982 and March 2008, along the East Rift Zone at the onset of the ongoing eruption in January 1983, and during vent shifting episodes 54 and 56, at Nāpau crater in January 1997, and Kane Nui O Hamo in June 2007. In general, samples have small (∼4%) excesses of ( 230 Th) over ( 238 U) and ∼3 to ∼17% excesses of ( 226 Ra) over ( 230 Th), consistent with melting of a garnet peridotite source at melting rates between 1 × 10 –3 and 5 × 10 –3 kg m –3 a –1 , and melting region porosity between ∼2 and ∼10%, in agreement with previous studies of the ongoing eruption and historical eruptions. A small subset of samples has near-equilibrium ( 230 Th/ 238 U) values, and thus were generated at higher melting rates. Based on U–Th–Ra disequilibria and Th isotopic data from this and earlier studies, melting processes and sources have been relatively stable over at least the past two centuries or more, including during the ongoing unusually long (>30 years) and voluminous (4 km 3 ) eruption. Lavas recently erupted from the East Rift Zone have average initial ( 210 Pb/ 226 Ra) values of 0·80 ± 0·11 (1σ), which we interpret to be the result of partitioning of 222 Rn into a persistently generated CO 2 -rich gas phase over a minimum of 8 years. This ( 210 Pb) deficit implies an average magma ascent rate of ≤3·7 km a –1 from ∼30 km depth to the surface. Spatter and lava associated with vent-opening episodes erupt with variable ( 210 Pb) deficits ranging from 0·7 to near-equilibrium values in some samples. The samples with near-equilibrium ( 210 Pb/ 226 Ra) are typically more differentiated, suggesting decadal timescales of magma storage in shallow conduits or reservoirs that were not degassing. Lava and spatter samples erupted in the East Rift Zone and at the summit had ( 210 Po) ∼0 at the time of eruption, which results from efficient partitioning of Po into the CO 2 - and SO 2 -rich gas phases during and prior to eruption. Summit ash and Pele’s hair samples from 2008 differ from lava and lapilli samples in that they have elevated initial ( 210 Po), ( 210 Pb/ 226 Ra), and Pb concentrations because of Po condensation on tephra particles, and incorporation of fumarolic Po and Pb into erupted tephra fragments during quenching.

Hawaii↗

USGS2018

Caldera life-cycles of the Yellowstone hotspot track: Death and rebirth of the Heise Caldera

As one of the most geochemically unique drill cores recovered within the Yellowstone–Snake River Plain (YSRP) province, the Sugar City geothermal test well was drilled into intra-caldera rhyolite lavas and tuffs erupted during the middle to late Pliocene and the resurgent basaltic volcanism erupted during the Pleistocene. This sequence parallels the two main stages proposed for YSRP hotspot calderas: i.e. the eruption of several large-volume, ash-flow tuff sheets followed by caldera collapse, then cessation of major rhyolitic activity and gradual subsidence accompanied by filling and eventual burial of the caldera by basalt lava flows. We employ stratigraphic relationships, paleomagnetism, and major, trace element, and Sr–Nd isotope geochemistry to develop models for the origin of the basaltic and rhyolitic magmas within a geographical and temporal context. The basalts are characterized by distinct groupings based on depth and geochemistry and reflect the dominant compositions observed on the surface, e.g. Snake River olivine tholeiite (SROT) and evolved type (e.g. Craters of the Moon). We also observe contaminated basalts that interacted with rhyolite/granite. The basaltic magma formed by shallow partial melting in the plume channel carved into the lithosphere. The older rhyolites preserve the classical characteristics of A-type granites and display major element and trace element concentrations typical for Eastern SRP caldera centres and minimal stratigraphic variation. Multiple lines of evidence document extensive magmatic differentiation and coupled basalt–rhyolite interactions. We find that the most plausible origin for the rhyolites is via partial melting of a hybrid source, comprising Archean crustal components and younger juvenile mafic intrusions. Assimilation of hydrothermally altered material is also required for some eruptive units. The rhyolites did not evolve from residual magma left over from the climactic Kilgore eruption (4·0 Ma), but instead represent discrete magma generation events in the course of a few hundred thousand years between 4·0 to 3·8 Ma. Beginning at approximately 3.3 Ma, basalts were able to erupt through the solidified composite pluton that formed below the caldera. The transition from rhyolite to basalt is tied to the declining flux of basaltic magma as North America moved away from the Yellowstone hotspot core.

Journal of Petrology↗

USGS1991

Intrinsic Nd, Pb, and Sr isotopic heterogeneities exhibited by the Lherz Alpine Peridotite Massif, French Pyrenees

Optically clear, acid-leached Cr-diopside, Al-augite, pargasitic amphibole, and phlogopite from peridotite and ultramafic dikes of the Lherz massif (French Pyrenees) exhibit chemical and isotopic heterogeneities indicative of a complex history. The data cover a wide range on the 143 Nd/ 144 Nd vs. 87 Sr/ 86 Sr covariation diagram, encompassing much of the mantle array and a large area below the array. Pb-isotopic signatures cover a wide range on Pb-Pb correlation diagrams, with several samples falling in the mid-ocean ridge basalt (MORB) field, but with others defining trends towards the enriched mantle II (EM II) and high-mu (HIMU) endmembers of Zindler & Hart (1986). Peridotites display the largest range in isotopic compositions, which formed in response to variable degrees of partial melting and subsequent enrichment during the intrusion of the ultramafic dikes. The ultra-mafic dikes represent at least four generations. Dike isotopic compositions range from ‘depleted’ to ‘enriched’, relative to Bulk Earth, reflecting the average composition of their source regions and subsequent melt-wall rock interactions. No simple isochronous relationships are observed on the 143 Nd/ 144 Nd vs. 147 Sm/ 144 Nd diagram for any lithologic group, demonstrating that the rock assemblages were not created by simple mixing of two homogeneous endmembers. Some ultramafic dikes, which represent low-temperature melt fractions, are enriched in the heavy isotopes of Sr, Nd, and Pb; any magmas derived from partial melting of these dikes are likely to have enriched isotopic signatures, particularly when the degrees of partial melting are only a few per cent.

Pyrenees↗

USGS1978

Factors controlling heavy-mineral variations on the South Texas outer continental shelf, Gulf of Mexico

Heavy-mineral distribution on the outer continental shelf off the southern coast of Texas shows regional variability induced by provenance and local variability reflecting genetic differences in sea-floor sediments. Q-mode factor analysis showed that three suites of heavy minerals are present. The southern ancestral Rio Grande delta sediments contain a distinct opaque-pyroxene-garnet suite, whereas the northern ancestral Brazes-Colorado delta sediments contain a tourmaline-green hornblende suite. An interdelta region contains a heavy mineral suite that is mixed owing to contributions from both ancestral deltas. Analysis of variance, correlation, and regression methods indicate that heavy-mineral variations in each sedimentary province have been significantly influenced by hydraulic fractionation by size, shape, and density, and by a selective chemical decomposition of unstable minerals. These factors have operated at varying degrees on the relict, palimpsest, and modern sediment populations of the sedimentary provinces since the end of Pleistocene time. The differential effects of these processes on the sediments have resulted in local variations that contribute to the total mineralogical variability. A comparison of the heavy mineral suites of the modern and relict Rio Grande delta sediments, which are derived from a common provenance, also shows mineral variations resulting from factors other than provenance.

Texas↗

USGS1978

Estimating pore and cement volumes in thin section

Point count estimates of pore, grain and cement volumes from thin sections are inaccurate, often by more than 100 percent, even though they may be surprisingly precise (reproducibility + or - 3 percent). Errors are produced by: 1) inclusion of submicroscopic pore space within solid volume and 2) edge effects caused by grain curvature within a 30-micron thick thin section. Submicroscopic porosity may be measured by various physical tests or may be visually estimated from scanning electron micrographs. Edge error takes the form of an envelope around grains and increases with decreasing grain size and sorting, increasing grain irregularity and tighter grain packing. Cements are greatly involved in edge error because of their position at grain peripheries and their generally small grain size. Edge error is minimized by methods which reduce the thickness of the sample viewed during point counting. Methods which effectively reduce thickness include use of ultra-thin thin sections or acetate peels, point counting in reflected light, or carefully focusing and counting on the upper surface of the thin section.

Journal of Sedimentary Petrology↗

USGS1979

Inverse grading and hydraulic equivalence in grain-flow deposits

Inversely graded grain-flow deposits are characterized by a hydraulic equivalence that differs from that based on settling velocities or entrainment. Dispersive equivalence, derived from the dispersive pressure hypothesis on how inverse grading develops, was found to agree reasonably well with observed relationships between grain sizes and densities in grain-flow deposits. Furthermore, observed relationships in deposits formed in subaerial and subaqueous environments were found to be independent of fluid density as is required by dispersive equivalence. The results suggest that dispersive pressure controls the development of the inverse grading common to beach foreshore laminations, slip-face foreset strata, the basal parts of some coarse-grained turbidites, and other diverse deposits.

Journal of Sedimentary Petrology↗