USGS Science⌕ Search

SEARCH · USGS Science

Results for “Earth Surface Processes and Landforms”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,665 records · Page 47Linked to original sources
USGS2024

U.S. Geological Survey Earthquake Hazards Program decadal science strategy, 2024–33

Executive Summary Earthquakes represent one of our Nation’s most significant and costly natural hazards, with estimated annual loses from earthquakes close to $15 billion in 2023. Over the past two centuries, 37 U.S. States have experienced an earthquake exceeding a magnitude of 5, and 50 percent of States have a significant potential for future damaging shaking; these statistics speak to the need for nationwide interest and investment in earthquake hazard characterization and risk reduction. Authorized under the Earthquake Hazards Reduction Authorization Act, the U.S. Geological Survey (USGS) Earthquake Hazards Program (EHP) provides the scientific information, situational awareness, and knowledge necessary to reduce deaths, injuries, and economic losses from earthquakes and earthquake-induced tsunamis, landslides, and soil liquefaction. The EHP supports activities in three focused topical areas: (1) earthquake monitoring, (2) hazard assessment, and (3) applied research, using the results of each—and the coordination among them—to further support risk translation and communication in regions at risk nationwide. For earthquake monitoring, the Advanced National Seismic System (ANSS), a cooperative effort of USGS networks, university partner regional seismic networks, and real-time geodetic networks, collects and analyzes data on earthquakes; issues timely, reliable notifications of their occurrence and impacts; and provides data for earthquake research, hazard, and risk assessment as a foundation for building an earthquake-resilient Nation. The USGS-operated ShakeAlert Earthquake Early Warning system is a recent addition to EHP’s ANSS infrastructure. In the realm of earthquake hazard assessment, the EHP contributes to earthquake risk mitigation strategies by developing the National Seismic Hazard Model and maps, and other related products, that describe the likelihood and potential effects of earthquakes nationwide, especially in the urban areas of highest risk. The EHP also conducts research on the causes, characteristics, and effects of earthquakes and prioritizes work that directly increases the accuracy and precision of earthquake hazards assessments, earthquake forecasts, and earthquake monitoring and situational-awareness products and that supports the Nation’s earthquake mitigation practices. Bridging the EHP’s efforts across research, hazard assessments, and earthquake monitoring is a broad and comprehensive collection of earthquake information products, including the National Seismic Hazard Model, ShakeAlert, and other products describing impact, such as ShakeMap and PAGER (Prompt Assessment of Global Earthquakes for Response), which have been developed and integrated into EHP’s real-time monitoring systems. EHP funds external partners to carry out many important collaborative activities through an active external grants program—one of the largest in the USGS—and through cooperative agreements with other partners such as the university-operated regional seismic networks, funded as part of the ANSS. To continue its support of earthquake hazard characterization and risk reduction, the EHP aims to strengthen its foundational products and practices while positioning itself to respond to the evolving needs of the Nation and follow best practices of the scientific community. This document describes a strategy for the program to ensure it can meet these demands. The foundational priorities outlined in this strategy represent those activities that remain critical to the core functionality of the program and those that can be supported under current fiscal year 2024-level appropriations. Priorities described as aspirational are important for future growth, and to maintain the program’s position as a leading global resource in earthquake science, but would require increases in appropriated funding to be fully realized. Across the program’s portfolio of activities, several major themes have been identified as the most critical activities to advance EHP science over the coming decade. Together, these activities provide the framework necessary to integrate critical hazard characterization and risk reduction activities across the program. They provide the structure for research to advance the understanding of where, when, and why earthquakes occur and how we can use improved knowledge to drive short-term and actionable forecasts of seismic activity. They expand the usefulness of critical earthquake products and advance the sophistication of those products to keep pace with the rapidly evolving needs of an ever-expanding user base while maintaining the position of the USGS as a global leader in earthquake science. Focus on system-level science. Establish an automated earthquake-processing pipeline. Enhance the accuracy and reliability of the ShakeAlert Earthquake Early Warning system and plan for extension to other regions. Implement time-dependent earthquake forecasting. Develop physically realistic models. Expand computational capacity. This science strategy is organized into three primary sections. The first section provides an overview of the EHP and its budget, governance, and program council. Readers familiar with the program may wish to focus on the second section, which describes the core of the science strategy, including priorities across each of the EHP’s major program activities in monitoring, hazard assessment, and targeted research. The third section outlines science priorities that cut across program activities, including those involving collaborations external to the EHP.

American Samoa, Guam, Northern Marianas Islands, U↗
USGS1996

Hydrogeologic investigation and simulation of ground-water flow in the Upper Floridan Aquifer of north-central Florida and southwestern Georgia and delineation of contributing areas for selected city of Tallahassee, Florida, water-supply wells

A 4-year investigation of the Upper Floridan aquifer and ground-water flow system in Leon County, Florida, and surrounding counties of north-central Florida and southwestern Georgia began in 1990. The purpose of the investigation was to describe the ground-water flow system and to delineate the contributing areas to selected City of Tallahassee, Florida, water-supply wells. The investigation was prompted by the detection of low levels of tetrachloroethylene in ground-water samples collected from several of the city's water-supply wells. Hydrologic data and previous studies indicate that; ground-water flow within the Upper Floridan aquifer can be considered steady-state; the Upper Floridan aquifer is a single water-bearing unit; recharge is from precipitation; and that discharge occurs as spring flow, leakage to rivers, leakage to the Gulf of Mexico, and pumpage. Measured transmissivities of the aquifer ranged from 1,300 ft 2 /d (feet squared per day) to 1,300,000 ft2/d. Steady-state ground-water flow in the Upper Floridan aquifer was simulated using a three-dimensional ground- water flow model. Transmissivities ranging from less than 5,000 ft2/d to greater than 11,000,000 ft 2 /d were required to calibrate to observed conditions. Recharge rates used in the model ranged from 18.0 inches per year in areas where the aquifer was unconfined to less than 2 inches per year in broad areas where the aquifer was confined. Contributing areas to five Tallahassee water-supply wells were simulated by particle- tracking techniques. Particles were seeded in model cells containing pumping wells then tracked backwards in time toward recharge areas. The contributing area for each well was simulated twice, once assuming a porosity of 25 percent and once assuming a porosity of 5 percent. A porosity of 25 percent is considered a reasonable average value for the Upper Floridan aquifer; the 5 percent porosity simulated the movement of ground-water through only solution-enhanced bedding plains and fractures. The contributing areas were generally elliptical in shape, reflecting the influence of the sloping potentiometric surface. The contributing areas delineated for a 5 percent porosity were always much larger than those determined using a 25 percent porosity. The lowest average ground-water velocity computed within a contributing area, using a 25 percent porosity, was 1.0 ft/d (foot per day) and the highest velocity was 1.6 ft/d. The lowest average ground-water velocity, determined using a 5 percent porosity, was 2.4 ft/d and the highest was 7.4 ft/d. The contributing areas for each of the five wells was also determined analytically and compared to the model-derived areas. The upgradient width of the simulated contributing areas were larger than the upgradient width of the analytically determined contributing areas for four of the five wells. The model could more accurately delineate contributing areas because of the ability to simulate wells as partially penetrating and by incorporating complex, three-dimensional aquifer characteristics, which the analytical method could not.

Florida, Georgia↗
USGS2024

Effective site coefficients for the 2024 International Building Code (IBC)

The U.S. National Seismic Hazard Models (NSHMs), developed by the U.S. Geological Survey (USGS), have long been the scientific foundation of seismic design guidelines and have been used to compute design ground motions for construction of new buildings and retrofit of existing buildings in the United States and its territories. The 2018 NSHM is adopted by the 2024 International Building Code (IBC). Prior to the 2018 NSHM update, hazard calculations were required only at one reference site condition defined by V S30 =760 m/s (where V S30 is the time-averaged shear wave velocity from the surface to a depth of 30 m) and three periods (peak ground acceleration, PGA, and pseudo spectral accelerations at periods of 0.2 and 1 s, S s and S 1 ). Site coefficients, F PGA , F a , and F v , were then defined by the Building Seismic Safety Council (BSSC) Provisions Update Committee (PUC) in the site-specific procedures of National Earthquake Hazard Reduction Program (NEHRP) Recommended Seismic Provisions to calculate ground motions for other site classes with different V S30 values at the given periods. The design ground motions at other periods were then estimated using a generic spectral shape that was also defined by the BSSC PUC in NEHRP provisions. In recent years, the engineering community has realized there were deficiencies with the F a and F v site coefficients and the generic spectral shape. To avoid potentially dangerous underestimations of design ground motions for long period structures on soft site conditions in high seismicity regions, the BSSC PUC recommended the use of multi-period response spectra (MPRS) in 2017. As a result, the USGS produced multi-period and multi-V S30 response spectral values in the 2018 NSHM for calculations of design ground motions and the site coefficients F a and F v were eliminated from the 2020 NEHRP Provisions. As these site coefficients were widely used inside and outside of the United States, in this study we back-calculate the “effective” site coefficients F a,eff , and F v,eff by comparing MPRS for various site classes with the MPRS for the reference site condition, and discuss the changes that are observed in the 2024 IBC compared to its previous version in 2021. The effective site coefficients are presented for test site locations and their dependence on various factors including period, ground motion intensity, and regional models are discussed. Ratio maps between the new effective site coefficients and the old ones are then presented for soft site classes and for short and long periods. For soft site classes at short periods, the new effective site coefficients are lower than the old site coefficients for high seismicity regions and higher for low seismicity regions. As it was expected, for soft site classes at long periods and high seismicity regions, the new effective site coefficients are much larger than the old site coefficients without imposing the 50% increase as a penalty that was suggested in the 2021 IBC, whereas they could be much smaller if the 50% increase would have been imposed particularly around New Madrid and Charleston high seismicity regions. For low seismicity regions, the long period effective site coefficients can be smaller or larger by 20% compared to the 2021 IBC coefficients.

Conference Paper↗
USGS2024

Greater sage-grouse habitat of Nevada and northeastern California—Integrating space use, habitat selection, and survival indices to guide areas for habitat management

Executive Summary Greater sage-grouse populations ( Centrocercus urophasianus ; hereafter sage-grouse) are threatened by a suite of disturbances and anthropogenic factors that have contributed to a net loss of sagebrush-dominant shrub cover in recent decades. Declines in sage-grouse populations are largely linked to habitat loss across their range. A key component of conservation and land use planning efforts for sage-grouse involves the continued monitoring and modeling of habitat requirements and suitability across its range. The Bureau of Land Management (BLM) is addressing the management of sage-grouse habitats on BLM-authorized public lands throughout the western United States through a land use planning amendment and associated environmental impact statement (86 FR 66331). More than 25 percent of the range-wide distribution of sage-grouse is within Nevada and northeastern California, and information on sage-grouse distribution and habitat requirements is important to guide appropriate management decisions. Therefore, the BLM has identified the need for updated spatially explicit information on sage-grouse habitat in Nevada and northeastern California to guide the land use planning amendment and associated management decisions. To address this need, researchers with the U.S. Geological Survey, in close cooperation with multiple State and Federal resource agency partners, including BLM, Nevada Department of Wildlife (NDOW) and California Department of Fish and Wildlife (CDFW), sought to map sage-grouse distribution and produce example habitat designations in these states. Herein, we report results of our primary study objective, which was to map sage-grouse habitat and create example habitat management areas, based on more than a decade of location and survival data collected from marked sage-grouse across the study region coupled with lek count survey data managed by the NDOW and the CDFW. We expanded on previously developed methodology to incorporate information on habitat selection and survival during reproductive life stages and specific seasons with updated sage-grouse location and known fate datasets, while also including brood-rearing areas that are understood to be threatened and important for population persistence. We combined predictive habitat map surfaces for each life stage and season with updated information on current occupancy patterns to classify habitat based on its suitability and probability of occupancy. We carried out additional steps to delineate specific example habitat management areas, specifically (1) incorporated corridors connecting key nesting and brood-rearing habitat, (2) corrected outputs for pre-wildfire habitat conditions within areas burned in the last 16 years, and (3) masked out areas of anthropogenic development. Our methodological example of deriving habitat management areas was intended to help inform decisions by BLM and other land managers regarding conservation and management of sage-grouse. Associated data products in the form of habitat maps provide updated, detailed, and comprehensive information about the status of habitats and can be useful to partner agencies in their efforts to designate and rank habitats for this species of high conservation concern in Nevada and California, with full recognition that on-the-ground field data and local sources of information and expertise should be used in conjunction with inferences from these models.

California, Idaho, Nevada↗
USGS2024

Timing and geometry of the Chemehuevi Formation reveal a late Pleistocene sediment pulse into the Lower Colorado River

The Chemehuevi Formation is a distinctive 50−150-m-thick wedge-shaped Pleistocene sedimentary unit deposited by the Colorado River. It lines the perimeters of the river’s floodplains and bedrock canyons for more than 600 km between the mouth of the Grand Canyon and the delta region in the Gulf of California. The formation is composed of a basal tan to light-yellowish-brown and pale-orange mud-dominated facies overlain and interbedded by a light-yellow-brown sand-dominated facies. The unit is one of two extensively exposed aggradational packages in the Lower Colorado River corridor, in addition to a series of other smaller alluvial terrace deposits. The Chemehuevi Formation appears to represent the response of a fully integrated Colorado River system to a significant perturbation, in contrast to the Bullhead Alluvium, which is likely a unique result of Pliocene river integration. The aggradation of the Chemehuevi Formation in the Lower Colorado River corridor may be similarly due to a unique event in the Colorado River system, or it may instead be a well-preserved sedimentary sequence recording typical behavior of the Colorado River below the Grand Canyon in the late Pleistocene. As such, multiple causal mechanisms have been proposed, but no study to date has conclusively explained the Chemehuevi Formation. To help resolve its timing, duration, and origin, we applied post-infrared infrared stimulated luminescence, carbonate U-Th series, and zircon sensitive high-resolution ion microprobe U-Th series geochronology to determine the ages of key exposures of the unit over a wide spatial area. These new data demonstrate that the Chemehuevi Formation was deposited ca. 110−90 ka. The depositional ages collectively overlap, suggesting that deposition occurred rapidly relative to the resolution of the geochronometers. The new depositional timing coincides with a shift from glacial to interglacial conditions after the marine isotope stage 5-6 transition. This observation is consistent with a climate-induced sediment pulse as a causal mechanism, yet correlations with similar deposits in the Colorado River headwaters or in neighboring catchments appear elusive. Potentially, climate transitions between glacial and interglacial periods induced a sediment pulse from hillslopes of the Colorado River system that resulted in the Chemehuevi Formation. An alternative or additional explanation is that the Chemehuevi Formation represents release of lava dam−impounded sediment in the Grand Canyon. The surface geometry of the Chemehuevi Formation projects upstream to the approximate location of lava dams, and the largest possible lava dam impoundment (the Upper Prospect dam) is comparable in volume to the formation. The lava dam hypothesis appears to be a possible explanation for the Chemehuevi Formation. However, tying deposition to a specific lava dam or series of lava dams remains challenging due to discrepancies in timing and volume. The combined effects of a series of lava dams may have led to the Chemehuevi Formation, as the last Pleistocene lava dam eruption coincides with the onset of deposition. Alternatively, the formation may result from the combined effects of both regional climate transitions and the lava dams that created a transient reservoir to compound a climate transition−driven sediment pulse. The geochronologic data presented here do not allow us to distinguish between the lava dam or climate transition hypotheses but will need to be reconciled with any future proposed depositional model.

Arizona, California, Nevada↗
USGS1999

Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99

The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).

California, Nevada↗
USGS1994

Hydrogeology of the Chickasaw National Recreation Area, Murray County, Oklahoma

The Travertine District (Park) of the Chickasaw National Recreation Area, operated and maintained by the National Park Service, is near the City of Sulphur in south-central Oklahoma. The Park was established in 1902 because of its unique hydrologic setting, which includes Rock Creek, Travertine Creek, numerous mineralized and freshwater springs, and a dense cover of riparian vegetation. Since the turn of the century several flowing artesian wells have been drilled within and adjacent to the Park. Discharge from many of these springs and the numbers of flowing wells have declined substantially during the past 86 years. To determine the cause of these declines, a better understanding of the hydrologic system must be obtained. The U.S. Geological Survey, in cooperation with the National Park Service, has appraised hydrologic information obtained for the Park from several studies conducted during 1902-87. The principal geologic units referred to in this report are the Arbuckle Group and the overlying Simpson Group. These rocks are of Upper Cambrian to Middle Ordovician age and are composed of dolomitic limestone, with some sandstones and shales in the Simpson Group. Surface geologic maps give a general understanding of the regional subsurface geology, but information about the subsurface geology within the Park is poor. The Simpson and Arbuckle aquifers are the principal aquifers in the study area. The two aquifers are not differentiated readily in some parts of the study area because of the similarity of the Simpson and Arbuckle rocks; thus, both water-bearing units are referred to frequently as the Arbuckle-Simpson aquifer. The aquifers are confined under the Park, but are unconfined east and south of the Park. Precipitation on the outcrop area of the Arbuckle aquifer northeast and east of the Park recharges the freshwater springs (Antelope and Buffalo Springs) near the east boundary of the Park. The source of water from mineralized springs located in the central part of the Park, and flowing wells within and north of the Park, is believed to be a mix of waters from rocks of the Arbuckle and Simpson Groups. The source of water from two highly mineralized springs, Bromide and Medicine, that ceased to flow in the early 1970’s is believed to be from the Simpson Group. Water-quality characteristics reflect the sources of ground water in the study area. The highly mineralized springs near the western end of the Park are a sodium chloride type with dissolved solids greater than 4,500 mg/L. The freshwater springs near the eastern end of the Park are a calcium bicarbonate type with total dissolved solids of less than 400 mg/L. Flow from the artesian wells has declined substantially during the past 86 years and the wells are estimated to currently discharge only about 10 percent of the total flow reported in 1939. The depletion is believed to be caused by a gradual lowering of the hydraulic head within the aquifer. The influence on the hydrologic system of local municipal and industrial pumping from the Arbuckle-Simpson aquifer is difficult to discern because the system is much more sensitive to precipitation than to pumpage. Ground-water levels and spring flows in this region respond rapidly to precipitation. The effects of withdrawals from the City of Sulphur and Oklahoma Gas and Electric Company power-plant water-well fields are not discernible at wells and springs. The hydrologic system may be influenced by pumping, particularly during extended dry periods of several years, but the impact of pumping on the system cannot be determined without further investigation.

Oklahoma↗
USGS2000

Water quality of selected springs and public-supply wells, Pine Ridge Indian Reservation, South Dakota, 1992-97

This report presents results of a water-quality study for the Pine Ridge Indian Reservation, South Dakota. The study was a cooperative effort between the U.S. Geological Survey and the Water Resources Department of the Oglala Sioux Tribe. Discharge and water-quality data were collected during 1992-97 for 14 contact springs located in the northwestern part of the Reservation. Data were collected to evaluate potential alternative sources of water supply for the village of Red Shirt, which currently obtains water of marginal quality from a well completed in the Inyan Kara aquifer. During 1995-97, water-quality data also were collected for 44 public-supply wells that serve about one-half of the Reservation's population. Quality-assurance sampling was used to evaluate the precision and accuracy of environmental samples. Ten of the springs sampled contact the White River Group, and four contact the Pierre Shale. Springs contacting the White River Group range from calcium bicarbonate to sodium bicarbonate water types. Two springs contacting the Pierre Shale have water types similar to this; however, sulfate is the dominant anion for the other two springs. In general, springs contacting the White River Group are shown to have better potential as alternative sources of water supply for the village of Red Shirt than springs contacting the Pierre Shale. Nine of the springs with better water quality were sampled repeatedly; however, only minor variability in water quality was identified. Six of these nine springs, of which five contact the White River Group, probably have the best potential for use as water supplies. Discharge from any of these six springs probably would provide adequate water supply for Red Shirt during most periods, based on a limited number of discharge measurements collected. Concentrations of lead exceeded the U.S. Environmental Protection Agency (USEPA) action level of 15 µg/L for three of these six springs. Five of these six springs also had arsenic concentrations that exceeded 10 µg/L, which could be problematic if the current maximum contaminant level (MCL) is lowered. Blending of water from one or more springs with water from the existing Inyan Kara well may be an option to address concerns regarding both quantity and quality of existing and potential sources. All nine springs that were sampled for indicator bacteria had positive detections on one or more occasions during presumptive tests. Although USEPA standards for bacteria apply only to public-water supplies, local residents using spring water for domestic purposes need to be aware of the potential health risks associated with consuming untreated water. One spring contacting the White River Group and two springs contacting the Pierre Shale exceeded 15 pCi/L for gross alpha; these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Nine springs were sampled for selected pesticides and tritium. The pesticides atrazine, carbaryl, and 2,4-D were not detected in any of the samples. The nine springs were analyzed for tritium in order to generally assess the age of the water and to determine if concentrations exceeded the MCL established for gross beta-particle activity. Tritium results indicated two springs are composed primarily of water recharged prior to atmospheric testing of nuclear bombs and two other springs have a relatively large percentage of test-era water. The remaining five springs had tritium values that indicated some percentage of test-era water; however, additional sampling would be needed to determine whether water is predominantly pre- or post-bomb age. Of the 44 public-supply wells sampled, 42 are completed in the Arikaree aquifer, one is completed in an alluvial aquifer, and one is completed in the Inyan Kara aquifer. Water from the alluvial well is a sodium bicarbonate water type, water from Arikaree aquifer ranges from calcium bicarbonate to sodium bicarbonate types, and water from the Inyan Kara well is a calcium sulfate bicarbonate type. Of the 44 wells sampled, 28 (64 percent) tested positive for indicator bacteria in presumptive tests. Because these were single samples that generally were collected upstream from chemical treatment feeders, positive detections do not necessarily constitute exceedances of drinking-water standards. A single sample from an Arikaree well exceeded the MCL for arsenic of 50 µg/L. Arsenic exceeded 10 µg/L for six additional Arikaree wells and for the alluvial well and the Inyan Kara well, which could be problematic if the current MCL is lowered. The alluvial well also exceeded the secondary maximum contaminant level (SMCL) for dissolved solids, which is non-enforceable, and the action level for lead. The Inyan Kara well exceeded the SMCL's for iron and for manganese and the MCL of 5 pCi/L for radium-226 and 228 combined. Several Arikaree wells exceeded SMCL's for either pH, sulfate, dissolved solids, iron, or manganese. One Arikaree well exceeded the MCL of 4.0 mg/L for fluoride and another exceeded the MCL of 10 mg/L for nitrite plus nitrate. Ten Arikaree wells equalled or exceeded 15 pCi/L for gross alpha; however, these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Eight wells, all from the Arikaree aquifer, equalled or exceeded the proposed MCL of 20 µg/L for uranium and 33 wells (75 percent) equalled or exceeded one-half of the proposed MCL. Although this standard has only been proposed, additional information regarding the extent of elevated uranium concentrations in the Arikaree aquifer, and the geochemical processes involved, may be beneficial. It was determined from analyses of uranium isotope data for five wells that the source of elevated uranium concentrations is naturally occurring, rather than anthropogenic.

South Dakota↗
USGS2026

Computation of regional groundwater budgets for the Virginia Coastal Plain aquifer system

Computation of detailed groundwater flow budgets for subdivisions of Virginia’s Coastal Plain aquifer system has enabled quantification and more thorough understanding of groundwater flow within this important water resource. A zone budget analysis conducted on previously published groundwater models of the Virginia Coastal Plain and Virginia Eastern Shore shows that groundwater conditions vary substantially throughout the Coastal Plain aquifer system due to local variations in hydrogeology and historical and ongoing variations in groundwater use and management. Decades of substantial groundwater withdrawal from the Coastal Plain aquifer system have fundamentally altered groundwater flow from pre-development conditions. Rates of sustainable withdrawal are limited because the downward groundwater flow rate into confined aquifers supplying groundwater is a relatively small portion of the total groundwater water budget for the aquifer system. Analyses of groundwater budgets from the Virginia Coastal Plain model show that groundwater flow is generally outward from the surficial aquifer to rivers and coastal water bodies and downward through a series of underlying aquifers and confining units to the Potomac aquifer, which is the deepest aquifer and the source of most groundwater withdrawals. Downward flow into the Potomac aquifer currently is estimated to be only 7 percent of total net precipitation-derived net recharge at the land surface but makes up about 66 percent of inflow to the aquifer in Virginia, with much of the remaining inflow occurring laterally from areas outside of defined groundwater budget regions in Virginia. For several decades prior to 2010, high rates of withdrawal from the Potomac aquifer resulted in substantial decline in groundwater storage in the aquifer and in most overlying aquifers and confining units. From 2010 to 2025, rates of withdrawal substantially lower than the historical maximum have resulted in small net increases in groundwater storage in the confined aquifer system for most regions of the Virginia Coastal Plain. Nevertheless, for the same period, groundwater storage for the entire model domain continues to incrementally decline, indicating that storage recovery in Virginia is offset by a continued decrease in storage in areas beneath the Chesapeake Bay or in adjacent areas of Maryland and North Carolina. Withdrawals from the Potomac aquifer have induced substantial downward flow which is a large part of groundwater budgets for confined aquifers such as the Potomac. Downward groundwater flow continues under current conditions, but because vertical flow rates are a function of the difference between water pressure in the upper surficial systems and lower confined units, those rates are lower than those in earlier decades as the confined water levels partially recover from larger groundwater withdrawals in the past. Geographically, groundwater flow is generally inward from perimeter regions of the Virginia Coastal Plain toward central regions with the largest withdrawal rates. Estimated groundwater inflow from coastal regions could be contributing to saltwater intrusion, though that was not measured directly in this study. Analyses of groundwater budgets from the Virginia Eastern Shore peninsula, a geographic region of the Virginia Coastal Plain, show that groundwater flow for that isolated aquifer system is generally outward from the surficial aquifer to coastal water bodies and downward into the confined Yorktown-Eastover aquifer system, which is the source of most withdrawals. Downward groundwater flow into the confined Yorktown-Eastover aquifer system is estimated to be less than 2 percent of total recharge and less than 9 percent of net recharge at the water table but makes up over 93 percent of all inflow to the confined aquifer system. Decades of substantial but relatively consistent groundwater withdrawals have induced greater downward flow rates into the confined aquifer system but also have resulted in loss of groundwater from storage. Currently, estimated storage loss accounts for slightly under 7 percent of withdrawals from the confined aquifer system. The current withdrawal rate from the confined Yorktown-Eastover system is near the highest reported rate for the Eastern Shore, which means that the storage depletion is expected to continue, even though groundwater levels appear to be relatively stable. Estimated groundwater flow rates upward from the confining unit underlying the Yorktown-Eastover system and small rates of inflow from coastal water bodies underscore ongoing concerns about up-coning and lateral intrusion of salty groundwater.

EarthArXiv↗
USGS2023

Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington↗
USGS2000

Regional evaluation of evapotranspiration in the Everglades

Nine sites in the Florida Everglades were selected and instrumented for collection of data necessary for evapotranspiration-determination using the Bowen-ratio energy-budget method. The sites were selected to represent the sawgrass or cattail marshes, wet prairie, and open-water areas that constitute most of the natural Everglades system. At each site, measurements necessary for evapotranspiration (ET) calculation and modeling were automatically made and stored on-site at 15- or 30-minute intervals. Data collected included air temperature and humidity at two heights, wind speed and direction, incoming solar radiation, net solar radiation, water level and temperature, soil moisture content, soil temperature, soil heat flux, and rainfall. Data summarized in this report were collected from January 1996 through December 1997, and the development of site-specific and regional models of ET for this period is described. Latent heat flux is the energy flux density equivalent of the ET rate. Modified Priestley-Taylor models of latent heat flux as a function of selected independent variables were developed at each site. These models were used to fill in periods of missing latent heat flux measurement, and to develop regional models of the entire Everglades region. The regional models may be used to estimate ET in wet prairie, sawgrass or cattail marsh, and open-water portions of the natural Everglades system. The models are not applicable to forested areas or to the brackish areas adjacent to Florida Bay. Two types of regional models were developed. One type of model uses measurements of available energy at a site, together with incoming solar energy and water depth, to estimate hourly ET. This available-energy model requires site data for net radiation, water heat storage, and soil heat flux, as well as data for incoming solar radiation and water depth. The other type of model requires only incoming solar energy, air temperature, and water depth data to provide estimates of hourly ET. The second model thus uses data that are more readily available than the data required for the available-energy model. Computed ET mean annual totals for all nine sites for the 1996-97 period ranged from 42.4 inches per year at a site where the water level is below land surface for several months each year to 57.4 inches per year at an open-water site with no emergent vegetation. Although the density of photosynthetically-active plant leaves has been shown to relate directly to ET in some studies, it does not appear to relate directly to ET in the Everglades, based on comparison of annual ET data with leaf-area index, defined as the Normalized Difference Vegetation Index (NDVI), data from satellite imagery. NDVI and ET appear to be inversely related in the Everglades. The greatest ET rates occurred at open-water sites where the NDVI data indicated the lowest leaf-area index. Among the remaining vegetated sites, there is no clear relation between ET and NDVI, though the highest ET rate corresponded to the lowest NDVI and one of the lowest ET rates corresponded to the highest NDVI value. The variation in ET follows a seasonal pattern, with lowest monthly ET totals occurring in December through February, and highest ET occurring in May through August. The greatest range in monthly ET among all nine sites for the 2-year period occurred at site 3: from 1.81 inches in December 1997 to 6.84 inches in July 1996. A study to compare the Bowen-ratio/energy balance method of ET measurement with the eddy-correlation method was done at one site from June 22, 1998, through September 28, 1998. This comparison indicated that both methods gave comparable values of the Bowen ratio, but there was a considerable difference in available energy measured by the two methods. The mean of all 30-minute measured turbulent heat fluxes from the eddy-correlation apparatus for June 22 through September 29, 1998, was 137.4 watts per square meter, and the mean of the corresponding measured energy was 163.6 watts per square meter, or about 20 percent greater. The disagreement in mean energy fluxes measured by the two methods is problematical and is not fully understood. Although the difference seems to be related to friction velocity, and is practically non-existent at values of friction velocity greater than 0.3 meter per second, the "correctness" of either method cannot be determined with the data available.

Florida↗
USGS2024

Assessment of water levels, nitrate, and arsenic in the Carson Valley Alluvial Aquifer and the development of a data visualization tool for the Carson River Basin, Nevada

Residents of Carson Valley, Douglas County, Nevada, rely on the basin-fill alluvial aquifer underlying the valley for drinking water. Since the 1980s, groundwater levels and water-quality data have been collected to monitor the status of the aquifer system and to assist in planning efforts to address current (2024) and future demand. The U.S. Geological Survey (USGS), in cooperation with Douglas County, Nevada, evaluated trends in water levels, nitrate, and arsenic concentrations from a network of monitoring and domestic wells in Carson Valley. This work also assessed the monitoring well network to determine the suitability of wells for characterizing the occurrence of arsenic in the groundwater. Monitoring of constituents, such as nitrate and arsenic concentrations, is needed to assess changes in contaminant distribution and to evaluate the effect that changing land use and groundwater pumping has on their occurrence and transport. Results of the trend analysis indicate water levels are declining ( p <0.05) in 17 of 26 selected monitoring wells (65 percent). Areas with the largest change in water levels, with more than 20 feet of declines, were within the community areas of Johnson Lane, Ruhenstroth, South Agricultural, East Valley, and Fish Springs. Variations in water levels measured in wells from the Central Agricultural, Minden, Foothill, Alpine County (one well), and Gardnerville Ranchos areas show periods of increase and decrease over time, but they also maintain long-term declining trends ( p <0.05). Increases in nitrate concentrations in groundwater samples collected from 9 out of 14 selected monitoring wells (64 percent) are statistically significant ( p <0.05) within the Ruhenstroth, Gardnerville Ranchos, East Valley, Genoa, and Johnson Lane community areas. Samples collected from a well in Indian Hills/Jacks Valley indicated a decreasing trend in nitrate concentration over time. Nitrate concentrations in samples collected from wells in East Valley, Genoa, Johnson Lane, and Indian Hills/Jack Valley were consistently low (less than 3 milligrams per liter [mg/L]) and stable. Nitrate concentrations from selected wells in Johnson Lane and Garnerville Ranchos exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) of 10 mg/L (as nitrogen) and have trends that are increasing over time. In 2022, a sample collected from Johnson Lane had a concentration (7.3 mg/L) below the MCL with an increasing trend over time. Temporal trend analyses for groundwater arsenic concentrations in Carson Valley could not be done because of a lack of temporal data. However, using available historical data, arsenic concentrations seem to be greater in groundwater from wells located on the eastern and northern areas of the valley than in wells located on the western or southern areas. Groundwater arsenic concentrations exceed 5 micrograms per liter (μg/L) in most samples collected from wells in Johnson Lane, Airport, Central Agricultural, and East Valley areas and in many cases exceed the U.S. Environmental Protection Agency (EPA) MCL of 10 μg/L. Data indicate that groundwater from domestic wells screened at deeper intervals are likely more vulnerable to elevated arsenic concentrations than shallower wells. A groundwater network evaluation for Carson Valley identified potential modifications in the sampling locations and frequency to better understand the effect of groundwater pumping in communities where municipal and domestic demand are greatest, potentially enhancing understanding of contaminant transport in these areas. Potential modifications to the active well network include reducing the frequency of sample collection from existing network wells (6 out of 11) that have consistently shown low and stable nitrate concentrations, adding wells in areas where data are sparse, and increasing the number of wells in areas with elevated groundwater nitrate concentrations. Including the analysis of arsenic in samples from the active groundwater monitoring well network will provide more detail on the temporal and spatial variability of arsenic concentrations. A visualization tool for the Carson River Basin was developed to provide access to discrete and near real-time hydrologic and water-quality data. The Carson River Basin Hydro Mapper (CBH; U.S. Geological Survey, 2023b) shows active and historical discrete water levels measured by the USGS and the State of Nevada Division of Water Resources, discrete groundwater nitrate and arsenic concentration data collected by the USGS, near real-time streamflow, and surface water levels for select waterbodies. The hydrologic data in the CBH provides resource managers, the public, and the scientific community with an easily accessible tool to present and communicate the most up-to-date information available about local and basin-wide water resources.

Nevada↗
USGS2025

Geochemistry of quartz and fluid inclusions associated with gold, tungsten, and antimony in the Stibnite-Yellow Pine district, Idaho

Deposits in the historic Stibnite-Yellow Pine district in east-central Idaho were mined for Ag, Au, Hg, Sb, and W. Ore is hosted in breccia and fault zones along NE-striking faults that transect the Atlanta lobe of the Late Cretaceous Idaho batholith and metamorphosed Neoproterozoic to lower Paleozoic rocks. Geochronological studies have delineated five superimposed and zoned hydrothermal events in the mining district which range in age from Late Cretaceous to the Eocene. They formed the following consecutive assemblages: (1) vein and disseminated pre-ore milky quartz (± calcite), muscovite, and brassy pyrite with minor molybdenite and base metal sulfides; (2) vein and disseminated quartz, calcite, sericite, auriferous-pyrite, and arsenopyrite; (3) potassium feldspar, quartz, dolomite, and calcite with vein and disseminated scheelite ± pyrite and arsenopyrite; (4) Au-Ag veins that contain adularia; and (5) breccia, vein, and disseminated quartz, calcite, and stibnite with minor Ag sulfosalts and distal zones of cinnabar and realgar at Fern and Hermes mines. In this study, the pressure, temperature, and composition of ore-forming fluids were measured in Au-, W-, and Sb-bearing samples collected from drill core and surface exposures. Using optical petrography, scanning electron microscopy cathodoluminescence (SEM-CL) and electron microprobe cathodoluminescence (EMPA-CL) imaging, as well as electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectrometry trace element analyses, four major overprinting generations of hydrothermal quartz are defined. Fluid inclusion assemblages (FIAs) in each generation of quartz were characterized by microthermometry and laser Raman spectroscopy. Quartz and fluid inclusion paragenesis are as follows: (Qi) altered and overprinted Qi with no coeval FIAs that formed before or during event 1; (Q1) early veins as well as disseminated quartz with dull gray SEM-CL and H 2 O-NaCl-CO 2 FIAs that formed at minimum temperatures and pressures of 281° to 358°C and 1346 to 1789 bar during event 2 (Au); (Q2) vein and disseminated quartz, often euhedral, with H 2 O-NaCl ± CO 2 ± CH 4 FIAs that formed at minimum temperatures and pressures of 183° to 213°C and 72 to 602 bar during event 3 (W); and (Q3) euhedral and disseminated quartz with H 2 O-NaCl FIAs that formed at minimum temperature and pressures of 156° to 161°C and 5 to 6 bar during event 5 (Sb). Stibnite hosts H 2 O-NaCl FIAs trapped at minimum temperatures and pressures of 150° to 189°C and 5 to 12 bar that are similar to those of Q3-hosted FIAs. The quartz paragenetic history in the district follows a progressive temporal path from Tienriched quartz deposited by a relatively deep and higher temperature aqueous-carbonic fluid to a Li, Al, and Sb enriched quartz precipitated from a lower temperature aqueous fluid. Gases in fluid inclusion extracts from ore and gangue minerals were analyzed by mass spectrometry. Noble gas isotope analysis of fluid inclusion extracts revealed three signatures. Pre-ore Qi has R/R A (the isotopic ratio of the sample 3 He/ 4 He to atmospheric 3 He/ 4 He (1.384 × 10 −6 )) values that reflect the composition of the crustal melt-derived Atlanta lobe of the Idaho batholith. Quartz (Q1) and auriferous arsenian pyrite of hydrothermal event 2 have 20 Ne/ 4 He and R/R A values that plot along the air-crust mixing line, and these gases were likely introduced by metamorphic fluids derived from metasedimentary rocks. Stibnite with associated quartz (Q3 ± Q2) have 20 Ne/ 4 He and R/R A values that extend from the air-crust mixing line to the air-mantle mixing line, showing a shift from a crustal signature to an overprinting mantle signature. Late calcite has 20 Ne/ 4 He and R/R A values that extend from air toward the mantle end member, which suggests that magmatic volatiles condensed into meteoric groundwater late in the paragenesis. A mantle volatile source is also supported by high 20 Ne/ 22 Ne ratios. The Stibnite-Yellow Pine district is similar to other Au-W-Sb districts around the world in ore fluid chemistries, with late-stage stibnite being a product of cooling. The fluid pressure-temperature-composition (P-T-X) estimates and the crustal source of He during hydrothermal event 2 gold mineralization are characteristic of orogenic Au deposits, and the observed inclusion reequilibration textures indicate that trapped fluid inclusions were deformed during transitions between the brittle-ductile environment. Scheelite was deposited during event 3 with Q2 quartz and is overgrown by Q3 quartz and stibnite. Our interpretation of the quartz texture, chemistry, and fluid inclusion P-T-X data suggest that Au, W, and Sb mineralization occurred as hydrothermal fluids evolved from H 2 O-NaCl-CO 2 at >300°C and depths of ~4 to 6 km near the ductile to brittle transition to H 2 O-NaCl at ~150°C and epithermal depths as the Idaho batholith was exhumed. Geochronology indicates that from the Late Cretaceous to early Eocene, overprinting hydrothermal events formed deep orogenic Au, intermediate W, and shallow epithermal Au-Ag and Sb. Without comprehensive geochronologic constraints, our fluid inclusion data and textural observations could be interpreted as a single evolving hydrothermal system, as has been done in many other mining districts with similar mineralization.

Idaho↗
USGS2000

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii↗
USGS2026

Treatability study to evaluate bioremediation of trichloroethene at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, 2020–22

Executive Summary Chlorinated solvents, including trichloroethene (TCE) and other chlorinated volatile organic compounds (cVOCs), are widespread contaminants that can be treated by bioremediation approaches that enhance anaerobic reductive dechlorination. Reductive dechlorination can be enhanced either through the addition of an electron donor (biostimulation) or the addition of a known dechlorinating culture (bioaugmentation) along with an electron donor. Although bioremediation has been applied at many TCE-contaminated groundwater sites, application in source zones at sites where residual dense nonaqueous phase liquid (DNAPL) is present is more limited. In this study, laboratory and field treatability tests were completed to evaluate the potential application of anaerobic bioremediation for a shallow groundwater plume containing TCE in a perched alluvial aquifer at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, which was on the National Priorities List as the New Brighton/Arden Hills Superfund site until 2019. In addition to the presence of residual DNAPL at the site, temporal variability in groundwater flow directions and input of oxygenated recharge were possible complicating factors for the application of enhanced anaerobic biodegradation in the shallow plume. The Site K plume extends beneath the footprint of Building 103, which was demolished in 2006, and soil excavations to a maximum depth of 6 feet (ft) below ground surface in 2014 were known to leave some deeper contaminated soil in place in the TCE source area. Groundwater treatment at the site, formalized as part of the 1997 Record of Decision, has been in operation since 1986 and consists of an extraction trench at the downgradient edge of the plume to collect groundwater, which is then pumped to an on-site air stripper. Groundwater concentrations in the plume have been relatively stable since treatment began, indicating a continued source of TCE in the aquifer. The desire for a destructive remedy that would enhance the removal of cVOCs in the aquifer at Site K and shorten the remediation timeframe led the U.S. Army to request that the U.S. Geological Survey conduct a groundwater treatability study to assess bioremediation. This report describes the U.S. Geological Survey bioremediation treatability study conducted during 2020–22, including pre-design site characterization to assist in formulating the bioremediation approach, laboratory experiments to support the design of the field pilot test, and implementation and 1-year performance monitoring results for the pilot test. Pre-design site characterization included the collection of soil cores for cVOC analysis and lithologic descriptions and the re-installment of three wells to obtain hydrologic measurements and initial groundwater chemistry. Relatively flat head gradients were measured at the site, and substantial decreases in water-level elevations occurred from spring to summer (May–July 2021). Continuous water-level monitoring indicated a rapid response to precipitation. Groundwater flow velocities were consistently less than 0.5 foot per day, and the pilot bioremediation test was therefore designed with short lateral distances (about 5 ft) between injection and individual monitoring points. Soil analyses confirmed that high volatile organic compound contamination was left in place in the source area. The highest concentrations were near or in clay at the base of the perched aquifer. Concentrations of cVOCs measured in the replaced wells were consistent with historical data and had a maximum TCE concentration of 57,700 micrograms per liter (μg/L), indicative of nearby residual DNAPL based on the general rule of observed concentrations exceeding 1 percent of solubility. The primary TCE daughter product detected was 1,2-cis-dichloroethene (cisDCE), which indicated limited reductive dechlorination in the plume. Groundwater in both the source and downgradient areas was relatively reducing during the pre-design characterization, particularly in the source area where methane concentrations greater than 400 μg/L were measured. Initial laboratory tests conducted using native aquifer microorganisms from the three replacement wells showed that anaerobic TCE biodegradation rates were low when biostimulated with the addition of sodium lactate as an electron donor, also known as a carbon donor, and resulted in the production of only cisDCE. Addition of a known dechlorinating culture, WBC-2, however, resulted in rapid biodegradation and production of ethene, verifying complete reductive dechlorination of TCE. Microcosms constructed with aquifer soil collected from the site were used to evaluate other electron donors besides lactate to support reductive dechlorination by WBC-2, including corn syrup as an alternative fast-release compound and whey, soy-based vegetable oil, and 3-D Microemulsion (Regenesis, San Clemente, California) as slow-release compounds. First-order rate constants for total organic chlorine removal in these WBC-2 amended microcosms were greatest with either lactate or vegetable oil as the donor, ranging between 0.061 and 0.047 per day or corresponding half-lives of 11–15 days. Testing of commercial products in other WBC-2-bioaugmented microcosms led to selection for the field pilot test of an emulsified vegetable oil product that also contained some sodium lactate as a fast-release donor. Delaying the addition of WBC-2 relative to the donor in the microcosms resulted in the most rapid overall biodegradation rates. The selected design for the pilot test utilized three separate test plots, each about 30-ft wide and 60-ft long: plots GS1 and GS2 in the source area of the plume and plot GS3 in the downgradient area of the plume near the excavation trench. Each test plot had one injection well, one monitoring well upgradient from the injection point, and 12 surrounding monitoring wells in a grid to capture variable groundwater flow directions. Donor injections, which included a bromide tracer, were completed in October 2021, immediately following baseline sampling, and the WBC-2 culture was injected about 40 days later, between November 30 and December 2, 2021. Performance monitoring conducted until December 2022 included hydrologic measurements and analyses of cVOCs, redox-sensitive constituents, dissolved organic carbon, bromide, volatile fatty acids, compound-specific carbon isotopes, and microbial communities. The biogeochemical data collected during the pilot tests in the three treatment plots showed that enhanced, complete reductive dechlorination of cVOCs in the groundwater was achieved in the GS1 and GS3 plots. In contrast, evidence of distribution of the injected amendments and subsequent biodegradation was limited in GS2, which was in an area of more heterogeneous soil lithology and low water table elevations. The molar composition of volatile organic compounds in the GS1 and GS3 plots was dominated by ethene in wells that were reached by the injected amendments by the end of the monitoring period. In the GS1 and GS3 plots, similar patterns were observed of cVOC concentrations decreasing to near detection levels, or below, at some wells sampled in July and October 2022, whereas ethene became dominant and indicated sustained complete reductive dechlorination. Baseline cVOC concentrations were more than a factor of 10 higher in the groundwater in the GS1 plot than in GS3, but no apparent inhibition of complete dechlorination occurred. As expected from the initial pre-design site data and the laboratory experiments, enhanced dissolution of residual DNAPL coupled to biodegradation was evident in the GS1 plot, where a marked increase in dichloroethene (DCE) above the initial baseline and upgradient TCE and DCE concentrations occurred. DCE concentrations subsequently declined where DNAPL dissolution was evident, concurrent with production of vinyl chloride and then predominantly ethene. Thus, overall biodegradation rates outpaced the DNAPL dissolution and desorption and DCE production in the source area. This success in complete degradation to predominantly ethene was achieved even in areas where the DCE concentrations reached a maximum of about 30,000 μg/L. Compound specific isotope analysis of carbon in TCE, cisDCE, trans-1,2-dichloroethene, and vinyl chloride was conducted to provide another line of evidence of the occurrence and extent of anaerobic biodegradation. Along a flow path in each plot that was affected by the injected amendments, carbon isotopes in the TCE and daughter cVOCs in the groundwater became isotopically heavier, indicating biodegradation. Enhanced biodegradation rates calculated from the field tests in GS1 and GS3 showed half-lives of 36.9–75.3 days for DCE degradation and 9.48–38.5 days for ethene production. Notably, these ethene production rates calculated from the field tests are consistent with the results of WBC-2-bioaugmented microcosms amended with either lactate or vegetable oil, which had half-lives for total organic chlorine removal that ranged from 11 to 15 days. These rates indicated rapid enhanced biodegradation, which is promising for application of a full-scale bioremediation remedy. Ultimately, however, the mass of residual or sorbed TCE in the aquifer that remains accessible for dissolution and biodegradation would likely control the time required for a full-scale bioremediation effort to achieve performance goals for TCE and cisDCE specified in the Record of Decision for Site K. The field pilot tests showed that the relatively low hydraulic head gradients and temporal changes in groundwater flow directions in the shallow aquifer would add complexity to a full-scale bioremediation effort. The radius of influence (ROI) at GS1 and GS3 (16.3 ft and 12.7 ft, respectively) were close to the design ROI of 15 ft. The estimated ROI at GS2 was about four times the design ROI, but may be less reliable at this location owing to groundwater flow direction. In addition, the low temperatures following WBC-2 injection in late November to early December 2021, in combination with the low hydraulic head gradients, were probably major factors in the delay observed before the onset of enhanced biodegradation following injection of the culture. Additional test injections could be beneficial to optimize the timing of donor and culture injections with the variable temperatures and hydraulic head in the shallow aquifer.

Minnesota↗