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Characterization of the hydrogeologic framework, groundwater-flow system, geochemistry, and aquifer hydraulic properties of the shallow groundwater system in the Wilcox and Lorraine process areas of the Wilcox Oil Company Superfund site near Bristow, Oklahoma, 2022

The Wilcox Oil Company Superfund site (hereinafter referred to as “the site”) was formerly an oil refinery northeast of Bristow in Creek County, Oklahoma. Historical refinery operations contaminated the soil, surface water, streambed sediments, alluvium, and groundwater with refined and stored products at the site. The Wilcox and Lorraine process areas are where the highest concentrations of volatile organic compounds, semivolatile organic compounds, polycyclic aromatic hydrocarbons, and trace elements (including metals) (collectively hereinafter referred to as “contaminants”) were measured in a local shallow perched groundwater system within the alluvium (hereinafter referred to as the “alluvial aquifer”) at the site during previous site assessments. In order to understand the potential migration of contaminants through the soil and groundwater in these areas, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, investigated aquifer characteristics of the alluvial aquifer in the Wilcox and Lorraine process areas of the site to (1) document hydraulic conductivity and other aquifer characteristics of the alluvial aquifer that govern contaminant fate and transport, (2) describe the geospatial extent and concentration of the contaminants in the alluvial aquifer in the Wilcox and Lorraine process areas, and (3) describe the geochemical controls pertaining to oxidation and reduction governing the fate and transport and the degradation potential of contaminants in the groundwater. Various data were compiled and collected to evaluate the aquifer characteristics at the site including the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer. A total of 20 new (2022) groundwater monitoring wells were installed at the site to collect data used to supplement groundwater-level altitude and groundwater-quality data collected from older, existing groundwater monitoring wells and piezometers. Data compiled and collected for the study were used to evaluate the characteristics of the alluvial aquifer at the site. These aquifer characteristics are defined by the hydrogeologic framework, groundwater-flow system, geochemistry, and hydraulic properties of the aquifer.

Oklahoma

Grammar to graph—An approach for semantic transformation of annotations to triples

Data annotation is the process of labeling data to show the outcome that a related data model should predict. In this study, annotation data were transformed into semantic graph triples, mainly for use with the Resource Description Framework (RDF), a type of entity-relationship-attribute data model for graph databases. The transformation of annotation data to semantic graph triples provides complex linguistic meaning with data handling advantages such as reduced data storage needs, improved logical specification of relations between objects, and reusable classes and properties that support logic and inference. A grammar-based framework in graph form supports user questions and queries. The words defining approximately 334 topographic feature types compiled by the U.S. Geological Survey were tokenized as units of analysis and grouped by part of speech. Their dependency relations were identified for this study using natural language processing libraries. Dependency concepts are used as structured semantic relations among part-of-speech classes. Tokens, units equivalent to words, form instances of classes and were quantified within a tabular output format using PostgreSQL data storage software. Table data were logically aligned as triples following a mapping file and stored with an ontology file using Ontop virtual triplestore software. A grammar ontology schema for the data was synchronized to match queries whose results validated the graph’s structure. The text analysis produced 8 part-of-speech classes of content words for object representations and 4 classes of function words for operational applications. Dependency relations formed 27 ontology properties for topographic subgraph structures. Token occurrences shaped overall ontology salience and formed a lexicon of syntactic terms for subgraph objects and properties. The schema ontology of class and property population shapes formed the lexicon of English terms. SPARQL Protocol and RDF Query Language (SPARQL) was used with the lexicon to conform data to RDF guidelines. This study confirms the hypothesis that although linguistic logic varies from description logic, its approximation applies to ontology design. Property and query use case patterns extracted from the analysis support queries concerning complex topographic relations and patterns normally embedded within text definitions. The method used in this study could be applied to text forms in other domains, such as survey notes.

Scientific Investigations Report

Petrography and mineralogy of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida

Florida is covered by flat-lying sedimentary strata of the Atlantic and Gulf Coastal Plains. These strata have accumulated since Middle Jurassic time. The pre-Middle Jurassic, or basement, rocks that underlie the Coastal Plain in Florida are known only from drill cores and cuttings recovered from a relatively small number of boreholes. This data report presents petrographic observations and the results of X-ray diffraction analyses of basement rocks from 18 boreholes across Florida in support of the identification, discrimination, and correlation of units for a subcrop geologic map of pre-Middle Jurassic rocks composing Florida’s sub-Coastal Plain geology.

Florida

Geophysical constraints on continental rejuvenation in central China: Implications for outward growth of the Tibetan Plateau

Continental rejuvenation results from the tectonic reactivation of crustal structures and lithospheric reworking by mantle flow. Geochemical observations and field mapping have traditionally provided the primary evidence for the secular evolution of crustal composition and tectonic processes during continental rejuvenation. Nonetheless, the impact of continental rejuvenation on the observed present-day strain rate and orogenic-scale lithospheric structure has not been well constrained. The pre-existing E-W–trending Central China Orogenic Belt has been overprinted by the N-S–trending Central Longitudinal Seismic Belt and constitutes the intracontinental West Qinling Syntaxis in central China, where the tectonic setting changes eastward from contraction to extension. Combining updated global positioning system data and high-resolution crustal seismic tomography, we reveal a modern continental rejuvenation process within the West Qinling Syntaxis in central China. The northward extrusion of the Tibetan Plateau's weak lithospheric layer (middle-lower crust and lithospheric mantle) of southwestern China relative to the rigid Sichuan Basin/Ordos Block of the eastern West Qinling Syntaxis results in regional dextral shearing that shapes the Central Longitudinal Seismic Belt and defines the eastern Tibetan Plateau margin. The pre-existing E-W–trending Central China Orogenic Belt has been preserved above the brittle-ductile transition zone, and the northward movement of the deep lithospheric layer drives the deformation of the upper crust in the West Qinling Syntaxis. Our results, along with previous studies, suggest the presence of an intracontinental lithospheric interchange structure in central China. The continental rejuvenation of the West Qinling Syntaxis results from a combination of fault reactivation in the upper crust (Stage I, Eocene–Oligocene) and reworking of the deep lithosphere (Stage II, middle–late Miocene) related to the plateau-wide shift in stress accommodation ultimately driven by the redistribution of mass outward from the central Tibetan Plateau. At present, the transition zone between the high- and low-velocity anomalies along the Central Longitudinal Seismic Belt not only shapes the landscape boundary but controls the size and recurrence interval of earthquakes within the West Qinling Syntaxis in central China.

GSA Bulletin

ShakeAlert®—Communication, education, outreach and technical engagement strategic vision

Executive Summary In 2006, the U.S. Geological Survey (USGS) began directly supporting ShakeAlert ® research and in 2012 the ShakeAlert demonstration system began testing ( Given and others, 2018 ). The ShakeAlert earthquake early warning (EEW) system is a partnership between the U.S. Geological Survey (USGS) and the three West Coast States (Washington, Oregon, and California) served by the ShakeAlert System, which is part of the larger Advanced National Seismic System (ANSS). With more than 143 million people exposed to potentially damaging shaking in the United States ( Jaiswal and others, 2015 ), earthquakes are a national hazard. Most of our Nation’s earthquake risk is concentrated in the highly populated areas on the active plate tectonic boundaries on the West Coast of the conterminous United States. ShakeAlert is the first public alert system in the United States to provide rapid mass notification of earthquake detection, potentially offering seconds of warning before strong shaking arrives. A few seconds may not seem like much time, but the information in ShakeAlert Messages can be used to trigger automated actions that can prevent injury or death, reduce immediate damage, and speed recovery from earthquakes. The information product issued by the ShakeAlert system is called a ShakeAlert Message and is one of the information products and tools of the ANSS. The ShakeAlert System includes the USGS component, plus the pathways by which ShakeAlert-powered products and (or) services are delivered to end users. Alerts can be delivered to cell phones or be used to trigger automated systems to protect equipment, facilities, and infrastructure, such as slowing or stopping a train. ShakeAlert-powered automated actions can include fire house doors that can be opened to prevent jamming, heavy equipment (for example, trains, elevators, and cranes) that can be automatically stopped or parked in safe positions, and pipeline valves that can be closed to prevent surges and spills. A few seconds of warning also may be sufficient for people to take protective actions, such as drop, cover, and hold on or modified protective actions for a broad range of populations. Advance training may increase the benefit of a speedy response to an alert. Outreach and education about EEW may raise awareness of the overall earthquake threat and how people can best react when they receive an alert or feel shaking. ShakeAlert communication, education, outreach, and technical engagement (CEO&TE) efforts are highly collaborative and essential for the success of the ShakeAlert System. This strategic vision informs how the vast ShakeAlert CEO&TE Community operates and works together. The CEO&TE Community delineates a strategic framework that is intended to set the path for a long-term, sustainable approach to CEO&TE through three focus areas and five priorities. Focus Areas Technical engagement.— The objective of this focus area is to expand and broaden ShakeAlert technical engagement and implementation. External engagement.— This focus area targets engagement in long-term communication, education, and outreach planning, implementation, and evaluation. Internal engagement.— The purpose of this focus area is to build and sustain a robust infrastructure to optimize collaboration, information sharing, and project planning among the community of stakeholders charged with implementing ShakeAlert CEO&TE. Priorities The enumeration of the five priorities listed below does not suggest priority ranking. Public safety, preparedness, and resilience; Technical implementation and engagement; Consistent messaging and communication; Integration with other Federal and State earthquake hazards products; and Educational resources development and dissemination. This strategic vision is a tangible outcome of collaboration among many stakeholders beginning in July 2016. Since then, the work of the ShakeAlert CEO&TE Community has grown into an international effort. The USGS has developed, tested, and implemented a broad spectrum of communication, education, and outreach tools and resources—all of which recognize that seconds matter when it comes to safety and mitigating harm from earthquake hazards. The CEO&TE social science research effort has provided invaluable insights into the ShakeAlert System’s human interface. USGS-licensed technical partners develop, test, and implement real-world applications using ShakeAlert Messages. The success of ShakeAlert CEO&TE efforts is predicated on robust collaboration across numerous agencies, organizations, and groups. As such, this strategic vision outlines a “partnership model” that delineates roles and responsibilities to ensure alignment with focus areas and priorities. The partnership model includes the CEO&TE lead agency (USGS); its principal partners (State agencies and university partners); its implementation partners (for example, technical partners who build systems to deliver ShakeAlert-powered products and (or) services [focus area one]), earthquake education partners who work to increase public preparedness for seismic events (focus area two); and other organizations that work together to enhance the adoption and effectiveness of the ShakeAlert System. These partners collaborate and convene through a variety of working groups and forums, which are also described in this strategic vision and align with focus area three (internal engagement). The CEO&TE Community collaboratively developed its operating principles and a consensus-based, decision-making strategic framework to guide its collective work. Performance metrics are used to continually measure success. Ultimately, the USGS and ShakeAlert CEO&TE Community are advancing the ShakeAlert System that as of the publication of this strategic vision to “provide earthquake early warning for all” serves more than 50 million people.

Circular

Bascom Laser Diffraction Sedimentology Laboratory, Reston, Virginia

Introduction At the Bascom Laser Diffraction Sedimentology Laboratory, which is located in the Florence Bascom Geoscience Center at U.S. Geological Survey (USGS) headquarters in Reston, Virginia, scientists use physical sedimentology and particle characterization techniques to conduct detailed sediment characterization. Scientists address research problems in collaboration with other USGS science centers, State geological surveys, commercial industry, universities, and other partners. Laboratory capabilities include laser diffractometry for quantitative particle-size analysis, portable x-ray fluorescence (XRF) analysis for determining elemental abundances in rock or sediment samples, petrographic analysis of geologic media, and mechanical sieve analysis. These methods are used to analyze soil and sediment core material from terrestrial, marine, and lacustrine environments, surface sediments from coastal regions, and calcareous materials. Work done by the laboratory supports geologic mapping, resource assessments, land change studies, and geohazard analyses.

Fact Sheet

Final project peport for “Mapping riparian vegetation response to climate change on the San Carlos Apache Reservation and Upper Gila River watershed to inform restoration priorities: 1935 to present – Phase 2: Focus on tamarisk vegetation”

Riparian ecosystems play a critical role in supporting wildlife habitats, maintaining water quality, and sustaining ecological resilience in arid landscapes. In the Upper Gila River level-4 Hydrologic Unit Code (HUC-4; Identification Number – 1504) watershed of Arizona and New Mexico, and across areas of the San Carlos Apache Tribe of the San Carlos Apache Reservation (hereafter, Tribe/Tribal – entity; or Reservation - place), riparian ecosystems have been substantially altered by the widespread expansion of tamarisk ( Tamarix spp.), an invasive and non-native riparian species. Tamarisk has high water use and increased flammability, making it a growing concern as droughts intensify across the southwestern United States (U.S.). Recent research indicates that tamarisk is increasingly stressed under prolonged drought conditions, which can elevate wildfire risk and further degrade riparian habitat. In response, the U.S. Geological Survey (USGS) Western Geographic Science Center, in collaboration with the Tribe, developed remote sensing–based tools to map riparian vegetation composition and monitor vegetation condition over time. These tools enable accurate identification of tamarisk extent, detection of vegetation stress, and comparison with native species such as cottonwood and willow. This information directly supports restoration and management actions, including targeted tamarisk removal, protection of endangered species habitat, and prioritization of areas for native vegetation recovery. The tools also provide insight into how riparian vegetation responds to changing climate and hydrologic conditions, strengthening long-term planning for riparian forest management. Findings from this work demonstrate that riparian vegetation responses vary across river systems, indicating differences in plant composition and hydro-climatic conditions. Tamarisk on both the Gila and San Carlos Rivers generally exhibit greater declines in greenness in response to higher temperature as well as lower precipitation and river flow, while cottonwood ( Populus fremontii ) and willow (Salix spp.) are particularly sensitive to changes in discharge along the San Carlos River and respond more directly to both high and low flows, with more moderate responses to precipitation and temperature. By providing actionable, science-based information, this research supports climate adaptation planning, wildfire risk reduction, and improved riparian ecosystem health, with benefits that extend beyond the Reservation to regional water and wildlife conservation efforts.

Arizona, New Mexico

Estimating aftershock risk for entry into earthquake-damaged buildings

We present a simple method to estimate the risk of experiencing strong shaking from aftershocks during entry into earthquake-damaged buildings. We compute wait times until the probability of strong ground shaking from aftershocks reaches a predefined risk threshold; for example, a 0.4 percent probability of experiencing Modified Mercalli Intensity 7 or greater shaking during the planned building entry. We also develop a relation between aftershock probability and the probability of strong shaking, so that users can reference the U.S. Geological Survey aftershock forecast during an ongoing aftershock sequence to determine if the risk threshold has been met. We apply our method to active continental regions (for example, the Western United States), stable continental regions (for example, the Central and Eastern United States), and subduction zones (for example, Cascadia or Alaska).

Open-File Report

Stratigraphic notes—Volume 2, 2025

This is the second volume in the U.S. Geological Survey (USGS) series of reports on stratigraphy entitled “Stratigraphic Notes,” which consists of short papers that highlight stratigraphic studies, changes in stratigraphic nomenclature, and explanations of stratigraphic names and concepts used on published geologic maps. “Stratigraphic Notes” is a long-term (multiyear), multivolume publication containing articles that address updates or revisions to stratigraphic nomenclature (and whose content ultimately will be incorporated by National Geologic Map Database personnel into Geolex, https://ngmdb.usgs.gov/Geolex/ ). We welcome papers for the “Stratigraphic Notes” series from geoscientists of the USGS, of State Geological Surveys, and from academicians. Papers can be submitted for publication in “Stratigraphic Notes” by contacting the USGS Geologic Names Committee ( gnc@usgs.gov ). As new “Stratigraphic Notes” volumes are published, links to the volumes will be posted at https://doi.org/10.3133/pp1879 .

Professional Paper

Stratigraphic notes—Volume 3, 2026

This is the third volume in the U.S. Geological Survey (USGS) series of reports on stratigraphy entitled “Stratigraphic Notes,” which consists of short papers that highlight stratigraphic studies, changes in stratigraphic nomenclature, and explanations of stratigraphic names and concepts used on published geologic maps. “Stratigraphic Notes” is a long-term (multiyear), multivolume publication containing articles that address updates or revisions to stratigraphic nomenclature (and whose content ultimately will be incorporated by National Geologic Map Database personnel into Geolex, https://ngmdb.usgs.gov/Geolex/ ). We welcome papers for the “Stratigraphic Notes” series from geoscientists of the USGS, of State Geological Surveys, and from academicians. Papers can be submitted for publication in “Stratigraphic Notes” by contacting the USGS Geologic Names Committee ( gnc@usgs.gov ). As new “Stratigraphic Notes” volumes are published, links to the volumes will be posted at https://doi.org/10.3133/pp1879 .

Professional Paper

Reduction of red bed sedimentary rocks in connection with energy metal ore formation: A case study from the Sinbad seep, Mesa County, Colorado

The Paradox Basin’s Sinbad seep is a modern analog for ancient bleaching of red bed sediments by introduced alkaline, reducing brines. This bleaching, involving reductive alteration of former red beds, is essential ground preparation that enables the altered rocks to trap Cu, U, and V from later oxidized fluids, forming ore deposits. Study of Sinbad thus offers insights into these metallic mineralization processes in the Paradox and other sedimentary basins. The Sinbad seep occurs where shallow groundwater interacts with organic-rich petroleum source rocks, flows up a fault, and discharges into Salt Creek. Ratios of Na/Cl, Na/Br, and Cl/Br, plus high sulfate concentrations, indicate that the salinity of the seep water originated from dissolution of halite and gypsum during topographically driven flow of meteoric water across a diapir of the Pennsylvanian Paradox Formation, rather than from deep basinal brines. In contact with the organic-rich shales of the Paradox, these SO 4 -rich waters become reduced through bacterial reduction, producing H 2 S. The waters react with red beds of the Permian Cutler Formation, causing pervasive bleaching. The bleaching at Sinbad is characterized by iron-conservative reduction of ferric iron in diagenetic hematite and detrital ilmenite and magnetite to Fe sulfides. The ferrous iron is retained in these sulfides likely as sorbed Fe. Associated alteration includes precipitation of quartz and feldspar overgrowths, partial dissolution of detrital quartz and feldspar caused by pressure solution, formation of clay and authigenic rutile, and precipitation of carbonate and gypsum. The Fe sulfides rapidly degenerate to a mixture of jarosite and iron oxides on weathering at the surface. Among the major-oxide elements and most trace elements, there is no statistical difference between unbleached and bleached samples. The exceptions are uranium and sulfur, which are somewhat greater in bleached samples. Fission track radiography illuminates that uranium is preferentially concentrated in iron oxide cements, iron sorbed into detrital clasts, and finely disseminated iron oxide in illite cement in bleached samples. A leaching experiment suggests that uranium may be more easily available for mobilization from rocks that have undergone bleaching alteration, making them potential U sources. In addition, bleached rocks form effective traps for U, V, and some Cu mineralization.

Colorado

Temporal, spatial, and chemical evolution of Quaternary high-silica rhyolites in the Mineral Mountains, Utah

The Mineral Mountains in southwestern Utah are a structurally controlled core complex at the confluence of the Colorado Plateau and the Basin and Range physiographic provinces. Aside from hosting Utah’s largest batholith, the Mineral Mountains host some of the State’s youngest high-silica rhyolites, which have been linked to a magma source that is presently being utilized as an enhanced geothermal system. The high-silica rhyolites take the form of effusive lavas and domes, and explosive products are rare. Previous K-Ar dating of these Pleistocene rhyolites placed eruptions between about 790 and 500 kilo-annum (ka) with contemporaneous basalts erupting in the valley to the east of the Mineral Mountains. Large uncertainties on these ages obscured the tempo of eruptions and thus hindered attempts to constrain the timescales of the petrogenetic processes that produced the rhyolites. In this study, we build on previous studies conducted in the 1970s and 1980s by using new geochronologic and geochemical data to investigate the temporal and spatial evolution of the youngest phase of volcanism in the Mineral Mountains. We identify two major eruptive periods, from approximately 850 to 750 ka and from approximately 590 to 480 ka. The older phase is characterized by the eruption of several basaltic lavas, two obsidian flows, and a series of coalescing porphyritic rhyolite domes. The younger phase included the eruption of six evolved high-silica rhyolite domes and one pyroclastic deposit, followed by the eruption of trachyandesite in the adjacent valley to the east. Whole-rock geochemical data indicate that the rhyolites can be divided into three chemical groups, with more evolved compositions erupting through time. The youngest rhyolites along the range crest have the lowest total iron and TiO 2 concentrations and the highest incompatible element concentrations, indicative of increasing differentiation with time and elevation. Improved precision on the eruption ages indicates a recurrence interval of approximately 20 thousand years. The eruptive flux for both periods of rhyolitic volcanism is about 0.01 cubic kilometers per thousand years, which is less than the magma resurgence flux rates for syn-caldera and post-caldera eruptions of the Valles Caldera and Yellowstone Caldera volcanic systems. Collectively, these geochemical, geochronological, and volumetric data may facilitate a better understanding of heat flux and the longevity of magmatic sources related to geothermal resources in similar small-volume, silicic systems.

Utah

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas

Streams, springs, and volcanic lakes for volcano monitoring

Introduction Volcanic unrest can trigger appreciable change to surface waters such as streams, springs, and volcanic lakes. Magma degassing produces gases and soluble salts that are absorbed into groundwater that feeds streams and lakes. As magma ascends, the amount of heat and degassing will increase, and so will any related geochemical and thermal signal. Subsurface magma movement can cause pressurization that alters hydrostatic head and may induce groundwater discharge. Fluid-pressure changes have been linked to distal volcano-tectonic earthquakes (White and McCausland, 2016; Coulon and others, 2017) and phreatic eruptions (for example, Yamaoka and others, 2016). Clearly, changes in groundwater and surface waters are both indicators of unrest and clues to how and where magma is rising toward the surface. Where possible, it is prudent to incorporate real-time hydrologic data into multiparameter monitoring of restless volcanoes. Hydrologic dynamics can also be tracked by changes in groundwater levels that are commonly measured in shallow boreholes (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume, on boreholes; Hurwitz and Lowenstern, 2024). Although inferred to be common, relatively few volcano-hydrology anomalies are well documented, and many are essentially anecdotal (Newhall and others, 2001), reflecting the fact that high-resolution time series remain rare. Extreme examples include the 2008 eruption of Nevado del Huila, Colombia, where relatively minor phreatomagmatic eruptions were accompanied by expulsion of as much as 300 million cubic meters of groundwater from fissures high on the volcano (Worni and others, 2011), generating large lahars. Substantial decreases in flow rate from springs about 8 kilometers from the summit of Mayon Volcano, Philippines, have been noted before most eruptions in the 20th century (Newhall and others, 2001). Stream monitoring at Redoubt Volcano in 2009 allowed Werner and others (2012) to recognize that groundwater was unable to absorb (or scrub) the high flux of volcanic gas and that a high CO 2 /SO 2 precursor signal had been evident for 5 months prior to the eruption. A key to better interpreting hydrologic anomalies—or even identifying them—is therefore obtaining adequate baseline data. Most hydrologic monitoring at U.S. volcanoes has been accomplished by intermittent sampling surveys with annual or less frequent sampling (for example, https://hotspringchem.wr.usgs.gov/index.php ). More frequent sampling, however, generally is needed to establish reliable baselines. A recent hydrologic and hydrothermal monitoring experiment at 25 sites and 10 of the 12 level 4 (very high threat) volcanoes in the U.S. portion of the Cascade Range demonstrated that there is sufficient temporal variability in hydrothermal fluxes, even during quiescent periods, that one-time measurements will commonly have limited interpretive value (Crankshaw and others, 2018). Thus, surveys are best augmented with data from streamgages (for example, Evans and others, 2004; Bergfeld and others, 2008). Streamflow (water discharge) data allow measured temperature and specific conductance to be converted to heat and solute mass fluxes, which could be insightful parameters for detecting anomalous activity (McCleskey and others, 2012). At the Yellowstone Caldera, long-term monitoring of river solutes has allowed calculation of the chloride flux, a proxy for heat discharge (Hurwitz and others, 2007; McCleskey and others, 2016) from the subsurface magma. This is readily accomplished because data from streamgages are continuously recorded and archived by the U.S. Geological Survey (USGS) National Water Information System (NWIS) (USGS, 2024). Similar studies on stratovolcanoes or shield volcanoes would be scientifically useful, and yet are logistically challenging, requiring streamgages on numerous radial drainages complemented by either frequent manual sampling or numerous deployments of equipment to measure water temperature and specific conductance as a proxy for water chemistry. Another challenge is that some volcanic areas, especially shield volcanoes, are characterized by near-surface porous rocks and soils, such that surface streams are rare and replaced by distant, dilute large-volume springs with only a trace of any original volcanically sourced water (Manga, 2001; Hurwitz and others, 2021). Volcanic lakes are worthy of special attention for monitoring efforts, as their temperature and composition can provide evidence of increased flux of volatile-rich fluids from below. Quantifying changes in volatile and heat release from magma can be simpler in lakes than for volcanoes with radial drainages and no major lakes. Moreover, volcanic lakes pose a range of hazards themselves, including phreatomagmatic eruptions, debris flows, flank collapse, tsunamis, and toxic gas release (Mastin and Witter, 2000; Delmelle and others, 2015; Manville, 2015; Rouwet and others, 2015)—hazards that have historically been responsible for substantial loss of life at many volcanoes worldwide (Manville, 2015). Catastrophic CO 2 release at Lake Nyos, Cameroon, in 1986 suffocated about 1,750 people and about 3,500 livestock and was probably triggered by a large landslide into the gas-saturated lake (Kling and others, 1987; Evans and others, 1993). Gas-charged springs in Soda Bay within Clear Lake (California) have caused almost a dozen deaths to bathers in the past hundred years (ABC News, 2000). A 2005 example of lake overturn and abundant gas release was documented at Mount Chiginagak in Alaska (Schaefer and others, 2008) but did not result in any human casualties. Although thermally stratified lakes, which promote trapping of exsolved magmatic gas, tend to develop in tropical regions, the phenomenon can also arise where salinity creates meromixis (a condition in which a lake does not mix completely), as occurs in Mono Lake, California (Jellison and Melack, 1993; Jellison and others, 1998). If magma erupts or flows into a lake, the interaction between hot magma and cold water can be explosive (Mastin and others, 2004; Zimanowski and others, 2015) and substantially expand the area affected by the eruption. Another hazard is the breaching of crater rims by landslides triggered by volcanic and (or) seismic activity. Under some circumstances, substantial volumes of water can be displaced, leading to large floods and lahars. Late Holocene lake flooding from Aniakchak Crater in the Alaska Peninsula (Waythomas, 2022) and from Paulina Lake in Newberry Crater, Oregon (Chitwood and Jensen, 2000), caused by the failure of outlet sills, testify to the substantial hazards at lake-filled calderas. Several volcanic systems in the United States host lakes known to receive heat and gas from underlying magma. These lakes vary widely in area, depth, and chemical composition. Lakes are present at level 4 volcanoes, including Crater Lake and Newberry Volcano in Oregon; Yellowstone Caldera in Wyoming; Long Valley Caldera, Clear Lake volcanic field, Medicine Lake, and Salton Buttes in California; and Aniakchak Crater, Mount Katmai, Fisher Caldera, Mount Okmok, and Kaguyak Crater, among others, in Alaska. A water lake was present in Halemaʻumaʻu, the crater of Kīlauea, Hawai‘i (fig. F1), from October 2019 to December 2020. Level 3 volcanoes with lakes include Mono Lake volcanic field (Calif.), Mount Bachelor (Ore.), Ukinrek Maars and Mount Chiginagak (Alaska), and Soda Lake (Nevada). In addition, there are lakes at many levels 1 and 2 volcanoes. In the United States, there are no strongly acidic lakes that receive abundant input of magmatic gas, such as those found at Mount Ruapehu (New Zealand), Ijen and Kelud (Indonesia), and Poás (Costa Rica). Nevertheless, many contain fluids that provide clues to magmatic processes below. Since publication of a previous report on recommended instrumentation for volcano monitoring (Moran and others, 2008), continuous hydrologic monitoring has become increasingly feasible. However, changes in water pressure, temperature, and chemistry remain, in general, poorly studied phenomena at volcanoes (Sparks, 2003; National Academies of Sciences, Engineering, and Medicine, 2017). Recent efforts by the USGS have included the temporary study of Cascade Range volcanoes, which included frequent (15 minute to hourly) temporal sampling of temperature, depth, and conductivity (Crankshaw and others, 2018; Ingebritsen and Evans, 2019). At Yellowstone Caldera, many streamgages have now added thermistors and specific conductance sensors, allowing estimation of time-dependent chloride flux as a proxy for variations in subsurface heat flux (McCleskey and others, 2012, 2016). Efforts to better understand lakes have also accelerated, with bathymetric mapping and sampling carried out at several locations in the United States. Especially thorough work was done at Yellowstone Lake thanks to the Hydrothermal Dynamics of Yellowstone Lake (HD-YLAKE, https://hdylake.org ) project, funded primarily by the National Science Foundation. In addition to geophysical surveys and recovery of cores and other samples, HD-YLAKE investigations included remotely operated vehicle (ROV) investigations of hydrothermal vents on the lake floor (fig. F2). Data collected by the ROV provided a better understanding of the thermal and chemical influx from lake-bottom hydrothermal systems (Sohn and others, 2017). In this chapter, we focus on detecting changes in the chemistry, temperature, discharge, or water levels of streams, springs, and lakes that can be caused by seismicity, volumetric strains, or increases in gas flux associated with ascending magma. There is unavoidable overlap with other chapters of this report. Samples of water and gas can also be obtained in boreholes ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–K, 5 p., https://doi.org/10.3133/sir20245062k. ">chapter K , this volume; Hurwitz and Lowenstern, 2024), both shallow and deep. Gas monitoring ( of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–E, 11 p., https://doi.org/10.3133/sir20245062e.">chapter E , this volume; Lewicki and others, 2024) relies in part on samples from springs and wells, particularly where measurable gas plumes are absent. Water acts as a trigger and lubricant for landslides and sediment-rich floods, and so hydrology has obvious relevance for lahar monitoring, as discussed in of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–H, 6 p., https://doi.org/10.3133/sir20245062h. ">chapter H (this volume; Thelen and others, 2024). Shared situational awareness among scientists engaged in geophysical, gas, and hydrologic monitoring will improve overall understanding of the volcanic hazard.

Scientific Investigations Report

Footprints of past mining in Alaska (USA) derived from high-resolution satellite imagery

Mapping the land area used for mining in the past is essential for guiding the remediation of affected landscapes and assessing the resource potential of related waste products. Despite significant recent progress delineating footprints of active and inactive mining globally, the known inventory of such mine lands remains incomplete. Here, I describe a new map dataset of footprints of land surface disturbance and waste at sites of past mining in Alaska (USA) based on visual interpretation of satellite imagery. This dataset maps 6–14 times the area of previous regional and global mine footprint maps in Alaska and is the first in the region to explicitly delineate mine waste landforms (e.g., tailings piles). The data are publicly available from the U.S. Geological Survey under a “no rights reserved” Creative Commons (CC0) license agreement.

Alaska

Water resources related to breccia pipe uranium mining in the Grand Canyon region

Introduction In the arid Grand Canyon region, water resources are limited to primarily the Colorado River and associated tributaries and to groundwater in the form of seeps and springs. Groundwater resources in the region supply water for human use and support diverse and rich ecosystems in the locations immediately surrounding the seeps and springs. Throughout the region, uranium resources occur and may interact with water resources in both mined and unmined uranium deposits. There is a need to better understand groundwater in the region and the effects from uranium mining in order to better manage the limited water resources in the area. This Fact Sheet summarizes results from U.S. Geological Survey studies that were conducted on this topic from 2012 to 2023.

Arizona

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Hidden system identification: Basin modeling as a tool for examining sedimentary geothermal resource potential

Three-dimensional (3D) geologic and temperature models have been developed for the onshore U.S. Gulf Coast. The results from these models identify areas of moderate- to high-temperature (90°-150°C and >150°C; respectively) geothermal resources at depths <6 km. This modeling study addresses the fundamental challenge of predicting where opportune temperature and lithology coincide. Unlike traditional geothermal systems with surface expressions of hydrothermal circulation (e.g., hot springs, fumaroles, sinter), sedimentary geothermal systems (SGS) are generally hidden. Historically, simplified efforts to predict subsurface temperatures in sedimentary basins have focused on linear temperature extrapolation that does not consider the variable thermal properties of different lithologies or lithologic changes with depth (e.g., compaction, lithification). Therefore, the need to understand basin architecture and predict temperatures in 3D within SGS is paramount to identifying geothermal resources and determining economic feasibility. Basin modeling software has long been used to characterize the subsurface conditions of sedimentary basins, including temperature, in the pursuit of finding hydrocarbons. This tool can also be adapted to evaluate the potential of geothermal resources in a sedimentary basin by predicting the confluence of desirable temperatures and reservoir lithologies. In this work, PetroMod basin modeling software was used to create a regional geologic model of the onshore U.S. Gulf Coast, covering over 500,000 km 2 calibrated to temperature data from wells. Inputs include structural surfaces from commercial databases, lithology information derived from published literature, and corrected bottom-hole temperatures (BHT) from over 6,000 wells. The resulting 3D geologic model can be used to predict temperatures throughout the basin. Maps were exported showing the depth, depositional unit, and reservoir lithology at which temperatures of 90°C and 150°C were reached, revealing over 400,000 km 2 of moderate- to high-temperature resources at depths <6 km. These maps function as a first-order screening tool to identify areas where low-, moderate-, or high-grade resource potential may exist, based on temperature and if optimal reservoir lithologies or depositional units of interest are present. Depending on the success criteria of a project, the same maps can be exported for any isotherm or incorporate other 1407 Gardner and Birdwell subsurface properties. The methodology employed in this work can be applied in any sedimentary basin with available subsurface data. Further calibration incorporating other data, including pressure and porosity, can expand the utility of basin modeling for geothermal evaluations. Basin modeling is a powerful but underutilized tool for identifying prospective geothermal resources in sedimentary basins.

Conference Paper