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At least 847 records · Page 47Linked to original sources
USGS2015

Carbon exchange between the atmosphere and subtropical forested cypress and pine wetlands

Carbon dioxide exchange between the atmosphere and forested subtropical wetlands is largely unknown. Here we report a first step in characterizing this atmospheric–ecosystem carbon (C) exchange, for cypress strands and pine forests in the Greater Everglades of Florida as measured with eddy covariance methods at three locations (Cypress Swamp, Dwarf Cypress and Pine Upland) for 2 years. Links between water and C cycles are also examined at these three sites, as are methane emission measured only at the Dwarf Cypress site. Each forested wetland showed net C uptake from the atmosphere both monthly and annually, as indicated by the net ecosystem exchange (NEE) of carbon dioxide (CO 2 ). For this study, NEE is the difference between photosynthesis and respiration, with negative values representing uptake from the atmosphere that is retained in the ecosystem or transported laterally via overland flow (unmeasured for this study). Atmospheric C uptake (NEE) was greatest at the Cypress Swampp (−900 to −1000 g C m 2 yr −1 ), moderate at the Pine Upland (−650 to −700 g C m 2 yr −1 ) and least at the Dwarf Cypress (−400 to −450 g C m 2 yr −1 ). Changes in NEE were clearly a function of seasonality in solar insolation, air temperature and flooding, which suppressed heterotrophic soil respiration. We also note that changes in the satellite-derived enhanced vegetation index (EVI) served as a useful surrogate for changes in NEE at these forested wetland sites.

Florida↗
USGS2011

Exploring the sensitivity of soil carbon dynamics to climate change, fire disturbance and permafrost thaw in a black spruce ecosystem

In the boreal region, soil organic carbon (OC) dynamics are strongly governed by the interaction between wildfire and permafrost. Using a combination of field measurements, numerical modeling of soil thermal dynamics, and mass-balance modeling of OC dynamics, we tested the sensitivity of soil OC storage to a suite of individual climate factors (air temperature, soil moisture, and snow depth) and fire severity. We also conducted sensitivity analyses to explore the combined effects of fire-soil moisture interactions and snow seasonality on OC storage. OC losses were calculated as the difference in OC stocks after three fire cycles (~500 yr) following a prescribed step-change in climate and/or fire. Across single-factor scenarios, our findings indicate that warmer air temperatures resulted in the largest relative soil OC losses (~5.3 kg C m −2 ), whereas dry soil conditions alone (in the absence of wildfire) resulted in the smallest carbon losses (~0.1 kg C m −2 ). Increased fire severity resulted in carbon loss of ~3.3 kg C m −2 , whereas changes in snow depth resulted in smaller OC losses (2.1–2.2 kg C m −2 ). Across multiple climate factors, we observed larger OC losses than for single-factor scenarios. For instance, high fire severity regime associated with warmer and drier conditions resulted in OC losses of ~6.1 kg C m −2 , whereas a low fire severity regime associated with warmer and wetter conditions resulted in OC losses of ~5.6 kg C m −2 . A longer snow-free season associated with future warming resulted in OC losses of ~5.4 kg C m −2 . Soil climate was the dominant control on soil OC loss, governing the sensitivity of microbial decomposers to fluctuations in temperature and soil moisture; this control, in turn, is governed by interannual changes in active layer depth. Transitional responses of the active layer depth to fire regimes also contributed to OC losses, primarily by determining the proportion of OC into frozen and unfrozen soil layers.

Biogeosciences↗
USGS2011

Enhanced decomposition offsets enhanced productivity and soil carbon accumulation in coastal wetlands responding to climate change

Coastal wetlands are responsible for about half of all carbon burial in oceans, and their persistence as a valuable ecosystem depends largely on the ability to accumulate organic material at rates equivalent to relative sea level rise. Recent work suggests that elevated CO 2 and temperature warming will increase organic matter productivity and the ability of marshes to survive sea level rise. However, we find in a series of preliminary experiments that organic decomposition rates increase by about 20% per degree of warming. Our measured temperature sensitivity is similar to studies from terrestrial systems, three times as high as the response of salt marsh productivity to temperature warming, and greater than the productivity response associated with elevated CO 2 in C 3 marsh plants. Although the experiments were simple and of short duration, they suggest that enhanced CO 2 and warmer temperatures could actually make marshes less resilient to sea level rise, and tend to promote a release of soil carbon. Simple projections indicate that elevated temperatures will increase rates of sea level rise more than any acceleration in organic matter accumulation, suggesting the possibility of a positive feedback between climate, sea level rise, and carbon emissions in coastal environments.

Virginia↗
USGS2011

Enhanced decomposition offsets enhanced productivity and soil carbon accumulation in coastal wetlands responding to climate change

Coastal wetlands are responsible for about half of all carbon burial in oceans, and their persistence as a valuable ecosystem depends largely on the ability to accumulate organic material at rates equivalent to relative sea level rise. Recent work suggests that 5 elevated CO2 and temperature warming will increase organic matter productivity and the ability of marshes to survive sea level rise. However, we find that organic decomposition rates increase by about 12% per degree of warming. Our measured temperature sensitivity is similar to studies from terrestrial systems, twice as high as the response of salt marsh productivity to temperature warming, and roughly equivalent to the productivity response associated with elevated CO2 10 in C3 marsh plants. Therefore, enhanced CO2 and warmer temperatures may actually make marshes less resilient to sea level rise, and tend to promote a release of soil carbon. Simple projections indicate that elevated temperatures will increase rates of sea level rise more than any acceleration in organic matter accumulation, suggesting the possibility of a positive feedback between 15 climate, sea level rise, and carbon emissions in coastal environment

Biogeosciences Discussions↗
USGS2013

A new data set for estimating organic carbon storage to 3 m depth in soils of the northern circumpolar permafrost region

High-latitude terrestrial ecosystems are key components in the global carbon cycle. The Northern Circumpolar Soil Carbon Database (NCSCD) was developed to quantify stocks of soil organic carbon (SOC) in the northern circumpolar permafrost region (a total area of 18.7 × 10 6 km 2 ). The NCSCD is a geographical information system (GIS) data set that has been constructed using harmonized regional soil classification maps together with pedon data from the northern permafrost region. Previously, the NCSCD has been used to calculate SOC storage to the reference depths 0–30 cm and 0–100 cm (based on 1778 pedons). It has been shown that soils of the northern circumpolar permafrost region also contain significant quantities of SOC in the 100–300 cm depth range, but there has been no circumpolar compilation of pedon data to quantify this deeper SOC pool and there are no spatially distributed estimates of SOC storage below 100 cm depth in this region. Here we describe the synthesis of an updated pedon data set for SOC storage (kg C m -2 ) in deep soils of the northern circumpolar permafrost regions, with separate data sets for the 100–200 cm (524 pedons) and 200–300 cm (356 pedons) depth ranges. These pedons have been grouped into the North American and Eurasian sectors and the mean SOC storage for different soil taxa (subdivided into Gelisols including the sub-orders Histels, Turbels, Orthels, permafrost-free Histosols, and permafrost-free mineral soil orders) has been added to the updated NCSCDv2. The updated version of the data set is freely available online in different file formats and spatial resolutions that enable spatially explicit applications in GIS mapping and terrestrial ecosystem models. While this newly compiled data set adds to our knowledge of SOC in the 100–300 cm depth range, it also reveals that large uncertainties remain. Identified data gaps include spatial coverage of deep (> 100 cm) pedons in many regions as well as the spatial extent of areas with thin soils overlying bedrock and the quantity and distribution of massive ground ice. An open access data-portal for the pedon data set and the GIS-data sets is available online at http://bolin.su.se/data/ncscd/ .

Earth System Science Data↗
USGS1990

Uranium-series dating of secondary carbonates near Yucca Mountain, Nevada. Applications to tectonic, paleoclimatic, and paleohydrologic problems

Near-surface accumulations of secondary carbonates are common in the soils and sediments of the Yucca Mountain area. These carbonates contain small amounts of uranium that allow dating by the uranium-series disequilibrium method. Preliminary results from the Yucca Mountain area indicate that the U-series methods can (1) identify multiple episodes of tectonic fracturing, (2) provide a chronologic framework for paleoclimatically significant eolian deposits, and (3) place constraints on the probable source of waters from which the carbonates precipitated.

Conference Paper↗
USGS1997

A hydrous Ca-bearing magnesium carbonate from playa lake sediments, Salines Lake, Spain

Sediments of playa Lake Salines, SE, Spain, contain a carbonate mineral characterized by X-ray diffraction peaks very similar to, but systematically shifted from those of pure magnesite. Analyses (SEM, IR and Raman spectroscopy, DTA, TGA, and ICP) indicate the mineral is a hydrous Ca-bearing magnesium carbonate with the chemical formula (Mg0.92,Ca0.08)CO3??3H2O. Thermal characteristics of the mineral are similar to those of other known hydrated magnesium carbonates. X-ray and electron diffraction data suggests a monoclinic system (P21/n space group) with unit-cell parameters of a = 6.063(6), b = 10.668(5), and c = 6.014(4) A?? and ?? = 107.28??.

American Mineralogist↗
USGS1998

Hydrologic influence on methane and carbon dioxide dynamics at two north-central Minnesota lakes

Annual emissions of (CH4 + CO2) to the atmosphere were proportional to net hydrologic inputs of C, mostly by groundwater, at two lakes in the Shingobee River watershed in north-central Minnesota. Williams Lake (WL), a closed basin lake near the top of the watershed, had a hydraulic residence time of 2-4 yr and groundwater exchange of about +2 mol dissolved inorganic carbon (DIC) and -0.1 mol dissolved organic carbon (DOC) m-2 lake area yr-1. The Shingobee River flows through Shingobee Lake (SL) that had a hydraulic residence of 0.3-0.4 yr and received net groundwater plus surface-water inputs of +5.3 to +7.3 mol DIC and fewer than +1.3 mol (DOC + particulate organic carbon) m-2 yr-1. Approximately 60-80% of net annual C input to SL was from groundwater. Lake storage of CH4 and CO2 was greatest in late winter, with maximum emissions to the atmosphere immediately following ice melt. The lakes emitted CH4 continuously during open water, having annual losses of -1.6 mol CH4 m-2 yr-1 at WL and -1.9 mol CH4 m-2 yr-1 at SL. Although the WL epilimnion was CO2 depleted throughout summer, net annual CO2 exchange with the atmosphere was near zero because springtime emission offset summertime uptake. CO2 supersaturation resulted in emission of -8.0 mol CO2 m-2 yr-1 at SL.

Limnology and Oceanography↗
USGS2004

Characterization of single-walled carbon nanotubes for environmental implications

Adsorption capacities of N2 and various organic vapors (methyl-ethyl ketone (MEK), toluene, and cyclohexane) on select electric-arc and HiPco produced single walled carbon nanotubes (SWNT) were measured at 77 and 298 K, respectively. The amount of N2 adsorbed on a SWNT sample depended on the sample purity, methodology, and on the sample age. Adsorption capacities of organic vapors (100-1000 ppm vol) on SWNT in humid conditions were much higher than those for microporous activated carbons. These results established a foundation for additional studies related to potential environmental applications of SWNT. The MEK adsorption capacities of samples EA95 and CVD80 and mesoporous tire-derived activated carbon in humid conditions were lower than in dry conditions. This is an abstract of a paper presented at the AIChE Annual Meeting (Austin, TX 11/7-12/2004).

Conference Paper↗
USGS2007

Preliminary identification of ground-water nitrate sources using nitrogen and carbon stable isotopes, Kansas

Increasing nitrate-N in ground water is a problem in areas with limited ground-water supplies, such as central Kansas. Nitrate-N concentrations in ground water in the study area in Ellis County range from 0.9 to 26 mg/L. Calculated mean values observed in soil cores are 1.2-15 mg/kg. The ??15N signatures of the ground waters are more enriched (+16.8 to +28.7???) than those of the soils (+8.4 to +1 3.7???), strongly suggesting that nitrate-N sources are not from mineralized and labile nitrogen present in the unsaturated zone. Soil cores were collected near municipal wells to determine if soil nitrogen was a contributing source to the ground water. Increased ??15N of total nitrogen with depth suggests that microbial mineralization processes and possible denitrification or volatilization isotope enrichments have affected the observed ?? 15N signatures in the soil. However, the observed soil-nitrogen values are not of sufficient magnitude to explain the nitrate-N concentrations or associated ??15N values observed in the ground water. Stable carbon isotopes provide some supporting evidence that soils are not a major contributor to the observed nitrate-N concentration in the ground water. ?? 13C values of the dissolved organic carbon (DOC) in soils generally become more enriched with depth while corresponding ground-water ??13C (DOC) values are more depleted than in the overlying soils. Carbon isotope values of the soils are indicative of a C4 plant source that is enriched by microbial processes. The ??13C (DOC) of ground water indicates C3 values that may reflect impacts from animal-waste sources.

Current Research in Earth Sciences↗
USGS2006

Unravelling the structural control of mississippi valley-type deposits and prospects in carbonate sequences of the Western Canada Sedimentary Basin

Re-examination of selected MVT outcrops and cores in the Interior Plains and Rocky Moun-tains of Alberta, corroborated with previous paragenetic, isotopic and structural data, suggests Laramide structural channelling of dolomitizing and mineralizing fluids into strained carbonate rocks. At Pine Point, extensional faults underlying the trends of MVT ore bodies and brittle faults overprinting the Great Slave Lake Shear Zone define apinnate fault geometry and appear to be kinematically linked. Chemical and isotopic characteristics of MVT parental fluids are consistent with seawater and brine convection within fault-confined verticalaquifers, strong water-basement rock interaction, metalleaching from the basement, and focused release of hydrothermal fluids within linear zones of strained carbonate caprocks. Zones of recurrent strain in the basement and a cap of carbonate strata constitute the critical criteria for MVTexploration target selection in the WCSB.

Bulletin of the Geological Survey of Canada↗
USGS2013

Geologic model for the assessment of undiscovered hydrocarbons in Lower to Upper Cretaceous carbonate rocks of the Fredericksburg and Washita groups, U.S. Gulf Coast Region

As part of the assessment of undiscovered oil and gas resources in Jurassic and Cretaceous strata of the U.S. Gulf Coast in 2010, the U.S. Geological Survey assessed carbonate rocks of the Fredericksburg and Washita groups and their equivalent units underlying onshore lands and State waters. One conventional assessment unit extending from south Texas to the Florida panhandle was defined: the Fredericksburg-Buda Carbonate Platform-Reef Gas and Oil assessment unit. Assessed strata range in age from Early Cretaceous Albian to Late Cretaceous Cenomanian. The assessment was based on a geologic model that incorporated the Upper Jurassic–Cretaceous–Tertiary Composite Total Petroleum System of the Gulf of Mexico Basin. The following factors were evaluated to define the assessment unit and estimate undiscovered oil and gas resources: potential source rocks, hydrocarbon migration, reservoir porosity and permeability, traps and seals, structural features, depositional framework, and potential for water washing of hydrocarbons near outcrop areas. Analysis of the production history of discovered reservoirs and well data within the assessment unit was also essential for estimating the numbers and sizes of undiscovered oil and gas reservoirs within the assessment unit. The downdip boundary of the assessment unit was drawn as an arbitrary line 10 miles downdip of the Lower Cretaceous shelf margin, to include potential reef-talus reservoirs, a facies described in the geologic model developed for the assessment. Updip boundaries of the assessment unit were drawn based on the updip extent of assessment unit carbonate reservoir rocks, basin margin fault zones, and (or) the presence of producing wells within the assessed interval. Using the U.S. Geological Survey methodology, mean undiscovered resources of 40 million barrels of oil, 622 billion cubic feet of gas, and 14 million barrels of natural gas liquids were estimated for the assessment unit.

U.S. Gulf Coast↗
USGS1989

Thermal and cementation histories of Permian shelf-edge carbonate rocks in the Nanpanjiang Basin, South China

As of 1984, the Nanpanjiang Basin of South China has had almost no exploration by drilling although oil seeps exist among its margins and producing wells occur in adjacent basins. however, cooperative studies by petroleum geologists and geochemists of the United States and the People's Republic of China (1982-1984) show that calcite-cemented reef and fore-reef carbonate rocks near Ziyun contain bitumen in Upper Permian shelf-edge sediment. the cementation history consists of three episodes: (1)precipitation of syndepositional marine cement (formerly botryoidal aragonnite and fibrous magnesian calcite); (2)precipitation of post-depositional early cement (radiaxial calcite); and (3)precipitation of late burial cement (white calcite spar). Hydrocarbons were introduced into the rocks between cementation episodes 2 and 3. Fluid inclusion analysis of secondary inclusions in the burial cement indicates that the rocks were heated to nearly 200 C after hydrocarbon migration and cementation episode 3. Bitumen remains in the rocks as evidence of the earlier presence of liquid hydrocarbons. During this study, Ordovician through Permian carbonate rocks and Cambrian through Triassic clastic rocks were analyzed for total organic carbon (TOC) vitrinite reflectance (R 0 ), and extractable hydrocarbon (HC) content and composition. Within the basin, TOC values ranged from 0.02% to 3.91%, total HC ranged from 0.004 to 0.11 mg/g, and R 0 values were mostly greater than 2.0%. Previous studies by several groups of scientists in this region have found low TOC values and evidence of overmaturity. Our studies found higher TOC values, but otherwiese confirm the earlier findings. We conclude that portions of the basin have been heated beyond the level of liquid hydrocarbon generation and retention. Although our observations do not favor the occurrence of liquid hydrocarbons in the Paleozoic strata along the western maring of the basin, the possibility of significant gas accumulations in fractured reservoirs or of other hydrocarbon accumulations in the basin cannot be ruled out.

Nanpanjian Basin↗
USGS1974

Isotopic composition of carbon and hydrogen in some Apollo 14 and 15 lunar samples

Isotopic composition of carbon and hydrogen in some Apollo 14 and 15 lunar samples was determined by use of a newly constructed combustion line that yields low blanks for CO 2 and H 2 . The results from combustion of fines and breccia from Apollo 14 lunar samples and of fines, breccia, and basalt from Apollo 15 were compared with data obtained by heating samples in vacuo to over 1,350°C. The two techniques gave similar results. Total carbon in the fines ranged from 51 to 110 p/m with a C 13 of +12 to -8 per mil (parts per thousand) PDB. The breccias contain 22 to 50p/mcarbon with a C 13 of -21 to -25 per mil. The crystalline rock (sample 15555) has a carbon content of about 7 p/m and a C 13 of -28 per mil. The total hydrogen in the fines ranges from 66 to 120 p/m with a (D/H) X 10 -6 of 39 to 90. The breccias contain 8 to 38p/mH 2 with a (D/H) X 10 -6 of 103 to 144. The crystalline rock contains about 2 p/m H 2 with a (D/H) X 10 -6 of about 140. Arguments are presented to show that the contamination by earth materials is not as serious a problem as has been proposed by previous authors.

Journal of Research of the U.S. Geological Survey↗
USGS1977

A combustimetric method for determining the total carbon content of geologic materials

A modified LEGO WR-12 carbon determinator is used in a combustimetric determination of total carbon in geologic materials. A thermal conductivity cell is used as the sensing device. International reference samples are analyzed and compared to results previously published. Three new standards from the Canadian Certified Reference Materials Project were received and analyzed for the total carbon content.

Journal of Research of the U.S. Geological Survey↗
USGS2003

Tidal wetland fluxes of dissolved organic carbon and sediment at Browns Island, California: initial evaluation

Carbon and sediment fluxes from tidal wetlands are of increasing concern in the Sacramento-San Joaquin River Delta (Delta), because of drinking water issues and habitat restoration efforts. Certain forms of dissolved organic carbon (DOC) react with disinfecting chemicals used to treat drinking water, to form disinfection byproducts (DBPs), some of which are potential carcinogens. The contribution of DBP precursors by tidal wetlands is unknown. Sediment transport to and from tidal wetlands determines the potential for marsh accretion, thereby affecting habitat formation. Water, carbon, and sediment flux were measured in the main channel of Browns Island, a tidal wetland located at the confluence of Suisun Bay and the Delta. In-situ instrumentation were deployed between May 3 and May 21, 2002. Water flux was measured using acoustic Doppler current profilers and the index-velocity method. DOC concentrations were measured using calibrated ultraviolet absorbance and fluorescence instruments. Suspended-sediment concentrations were measured using a calibrated nephelometric turbidity sensor. Tidally averaged water flux through the channel was dependent on water surface elevations in Suisun Bay. Strong westerly winds resulted in higher water surface elevations in the area east of Browns Island, causing seaward flow, while subsiding winds reversed this effect. Peak ebb flow transported 36% more water than peak flood flow, indicating an ebb-dominant system. DOC concentrations were affected strongly by porewater drainage from the banks of the channel. Peak DOC concentrations were observed during slack after ebb, when the most porewater drained into the channel. Suspended-sediment concentrations were controlled by tidal currents that mobilized sediment from the channel bed, and stronger tides mobilized more sediment than the weaker tides. Sediment was transported mainly to the island during the 2-week monitoring period, though short periods of export occurred during the spring tide. Future deployments will characterize the seasonal variability of these fluxes.

California↗
USGS2001

Sequence stratigraphy of a South Florida carbonate ramp and bounding siliciclastics (late Miocene-Pliocene)

In southern peninsular Florida, a late-early to early-late Pliocene carbonate ramp (Ochopee Limestone Member of the Tamiami Formation) is sandwiched between underlying marine siliciclastics of the late Miocene to early Pliocene Peace River Formation and an overlying late Pliocene unnamed sand. At least three depositional sequences (DS1, DS2, and DS3), of which two contain condensed sections, are recognized in the Peace River Formation; an additional depositional sequence (DS4) is proposed to include the Ochopee Limestone. Established chronologies and new biostratigraphic results indicate that the Tortonian and Zanclean ages bracket the Peace River Formation. Depositional sequence 1 (DS1) prograded across the present-day peninsular portion of the Florida Platform during the Tortonian age and laps out near the southern margin of the peninsula. During the latest Tortonian and Messinian ages, progradation of DS2 overstepped the southern lap out of DS1 and extended at least as far as the Florida Keys. Deposition of DS2 ended, at the latest, near the Miocene-Pliocene boundary. Siliciclastic supply was reduced during early Pliocene deposition of DS3, which is absent in southernmost peninsular Florida. This reduction in supply of siliciclastics was followed by aggradational accumulation of heterozoan temperate carbonate sediments on a widespread carbonate ramp that includes the Ochopee Limestone. The Ochopee Limestone was deposited during eustatic cycle TB3.6 and ended in the late Pliocene with basinward lap out near the southern margin of the Florida peninsula. The Ochopee Limestone ramp was buried with a late Pliocene resumption of southward influx of siliciclastics (unnamed sand and Long Key Formation) that extended south beyond the middle and upper Florida Keys.

Florida↗
USGS1974

Occurrence of dissolved organic carbon in selected ground-water samples in the United States

A study of nonvolatile DOC (dissolved organic carbon) in ground water was conducted to establish base levels of naturally occurring dissolved organic materials. Samples of ground water were obtained at 100 sites in 27 States. Samples were pressure filtered at the time of collection and immediately frozen on dry ice. DOC concentrations were determined by wet oxidation of organic carbon to carbon dioxide which was measured by an infrared analyzer. The DOC concentrations ranged from less than the 0.1 mg/l limit of detection to 15 mg/l. Concentrations of DOC were directly correlated with specific conductance and alkalinity, but did not correlate with pH. The DOC mean concentration was 1.2 mg/l; however, the DOC median value was lower at 0.7 mg/l. Differences in DOC concentration for various types of consolidated rock aquifers were slight; for example, median DOC values for sandstone, limestone, and crystalline rock aquifer types ranged from 0.5 to 0.7 mg/l. No difference was found in the median DOC concentration between shallow (<200 ft; 61 m) and deep (>200 ft) sand and gravel aquifers.

Journal of Research of the U.S. Geological Survey↗