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At least 829 records · Page 46Linked to original sources

Wide-area debris field and seabed characterization of a deep ocean dump site surveyed by autonomous underwater vehicles

Disposal of industrial and hazardous waste in the deep ocean was a pervasive global practice near coastlines in the 20th century. Uncertainty in the quantity, location, and contents of dumped materials at historical disposal sites underscores ongoing risks to marine ecosystems and human health. This study presents analysis of a 150-km2 wide-area sidescan sonar survey conducted in March 2021 with two autonomous underwater vehicles (AUVs) at an offshore dumpsite in San Pedro Basin, California. Previous camera surveys located 60 barrels and other debris; sediment analysis in the region showed varying concentrations of the insecticidal chemical Dichlorodiphenyl-trichloroethane (DDT), for which an estimated 350-700 metric tons was discarded in the San Pedro Basin between 1947 and 1961. A lack of primary historical documents from Montrose Chemical or California Salvage Company that specify the DDT acid waste disposal method has contributed to the ambiguity surrounding whether the dumping method was via bulk discharge or containerized units. Barrels and debris visually detected during previous surveys by Remotely Operated Vehicles (ROVs) Jason and SuBastian and AUV Sentry served as the basis for ground truth testing and object classification using size and acoustic intensity characteristics. Target detection and classification algorithms were developed using image and signal processing techniques that resulted in the identification of over 74,000 debris targets within the survey region. Statistical, spectral, and machine learning techniques are used to characterize seabed variability and for bottom-type classification. These analytical techniques combined with the survey capabilities of AUVs provide a framework for efficient mapping and characterization of uncharted deep-water disposal sites.

California↗

Ultra-high chlorine in submarine Kı̄lauea glasses: Evidence for direct assimilation of brine by magma

Basaltic glass grains from the submarine south flank of Kı̄lauea, Hawai′i, have Cl concentrations of 0.01–1.68 wt%, the latter being the highest Cl content yet recorded for a Hawaiian glass. The high-Cl glass grains are products of brine assimilation by tholeiite magma. The glasses are grains in a sandstone clast from bedded breccias draping the southwestern margin of Kı̄lauea’s submarine midslope bench. The clast contains two distinct suites of glass grains: abundant degassed tholeiites, perhaps derived from subaerial lavas of Mauna Loa that shattered upon ocean entry, and a smaller population of Kea-type tholeiite ( n =17 analyzed) that erupted subaqueously, based on elevated S (780–1050 ppm), H 2 O (0.42–1.27 wt%), and CO 2 (<30–120 ppm), probably early in Kı̄lauea’s shield-building stage. Ten grains in this group have Cl>1000 ppm, six >5000 ppm, and two grains have >10 000 ppm dissolved Cl. Abundances of H 2 O, Na 2 O, K 2 O, and several trace elements increase regularly with Cl concentration, and we estimate that Cl enrichment was due to up to 13 wt% addition of a brine consisting of 78% H 2 O (wt), 13% Cl, 4.4% Na, 2.6% K, 2.6% Ca, 620 ppm Ba, 360 ppm Sr, 65 ppm Rb, and 7 ppm Pb. The large amounts of brine addition argue against bulk assimilation of low-porosity brine-bearing rock. The brine’s composition is appropriate for a seawater-derived hydrothermal fluid that reacted with basaltic wall rocks at T >100°C, losing Mg and S and gaining K, Ca, Rb, Ba, Sr, and Pb, followed by phase separation near 500°C and ∼50 MPa (5 km below sea level at hydrostatic pressure). Brine was assimilated at or near the depth it formed, as estimated on petrologic grounds, but under lithostatic conditions. The highest extents of assimilation either forced volatile saturation of the magma or enriched already coexisting magmatic vapor in H 2 O. Possible mechanisms for assimilation are: (1) forcible injection of brine into magma during bursting of overpressured pockets heated by new dikes, or (2) intrusion of magma into lenses or sills occupied by trapped brine.

Hawaii↗

Archive of digital chirp subbottom profile data collected during USGS cruise 12BIM03 offshore of the Chandeleur Islands, Louisiana, July 2012

From July 23 - 31, 2012, the U.S. Geological Survey conducted geophysical surveys to investigate the geologic controls on barrier island framework and long-term sediment transport along the oil spill mitigation sand berm constructed at the north end and just offshore of the Chandeleur Islands, La. (figure 1). This effort is part of a broader USGS study, which seeks to better understand barrier island evolution over medium time scales (months to years). This report serves as an archive of unprocessed digital chirp subbottom data, trackline maps, navigation files, Geographic Information System (GIS) files, Field Activity Collection System (FACS) logs, and formal Federal Geographic Data Committee (FGDC) metadata. Gained (showing a relative increase in signal amplitude) digital images of the seismic profiles are also provided. Refer to the Abbreviations page for expansions of acronyms and abbreviations used in this report. The USGS St. Petersburg Coastal and Marine Science Center (SPCMSC) assigns a unique identifier to each cruise or field activity. For example, 12BIM03 tells us the data were collected in 2012 during the third field activity for that project in that calendar year and BIM is a generic code, which represents efforts related to Barrier Island Mapping. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity ID. All chirp systems use a signal of continuously varying frequency; the EdgeTech SB-424 system used during this survey produces high-resolution, shallow-penetration (typically less than 50 milliseconds (ms)) profile images of sub-seafloor stratigraphy. The towfish contains a transducer that transmits and receives acoustic energy and is typically towed 1 - 2 m below the sea surface. As transmitted acoustic energy intersects density boundaries, such as the seafloor or sub-surface sediment layers, energy is reflected back toward the transducer, received, and recorded by a PC-based seismic acquisition system. This process is repeated at regular time intervals (for example, 0.125 seconds (s)) and returned energy is recorded for a specific duration (for example, 50 ms). In this way, a two-dimensional (2-D) vertical image of the shallow geologic structure beneath the ship track is produced. Figure 2 displays the acquisition geometry. Refer to table 1 for a summary of acquisition parameters and table 2 for trackline statistics. The archived trace data are in standard Society of Exploration Geophysicists (SEG) SEG Y rev. 0 format (Barry and others, 1975); the first 3,200 bytes of the card image header are in ASCII format instead of EBCDIC format. The SEG Y files may be downloaded and processed with commercial or public domain software such as Seismic Unix (SU) (Cohen and Stockwell, 2010). See the How To Download SEG Y Data page for download instructions. The web version of this archive does not contain the SEG Y trace files. These files are very large and would require extremely long download times. To obtain the complete DVD archive, contact USGS Information Services at 1-888-ASK-USGS or infoservices@usgs.gov. The printable profiles provided here are GIF images that were processed and gained using SU software and can be viewed from the Profiles page or from links located on the trackline maps; refer to the Software page for links to example SU processing scripts. The SEG Y files are available on the DVD version of this report or on the Web, downloadable via the USGS Coastal and Marine Geoscience Data System (http://cmgds.marine.usgs.gov). The data are also available for viewing using GeoMapApp (http://www.geomapapp.org) and Virtual Ocean (http://www.virtualocean.org) multi-platform open source software. Detailed information about the navigation system used can be found in table 1 and the Field Activity Collection System (FACS) logs. To view the trackline maps and navigation files, and for more information about these items, see the Navigation page.

Louisiana↗

Anthropogenic influence on recent bathymetric change in west-central San Francisco Bay

Two multibeam sonar surveys of west-central San Francisco Bay, California, were conducted in 1997 and 2008. Bathymetric change analysis between the two surveys indicates a loss of 14.1 million cubic meters (-3.1 cm/yr) of sediment during this time period, representing an approximately three-fold acceleration of the rate that was observed from prior depth change analysis from 1947 to 1979 for all of Central Bay, using more spatially coarse National Ocean Service (NOS) soundings. The portions of the overlapping survey areas between 1997 and 2008 designated as aggregate mining lease sites lost sediment at five times the rate of the remainder of west-central San Francisco Bay. Despite covering only 28% of the analysis area, volume change within leasing areas accounted for 9.2 million cubic meters of sediment loss, while the rest of the area lost 4.9 million cubic meters of sediment. The uncertainty of this recent analysis is more tightly constrained due to more stringent controls on vertical and horizontal position via tightly coupled, inertially aided differential Global Positioning Systems (GPS) solutions for survey vessel trajectory that virtually eliminate inaccuracies from traditional tide modeling and vessel motion artifacts. Further, quantification of systematic depth measurement error can now be calculated through comparison of static surfaces (e.g., bedrock) between surveys using seafloor habitat maps based on acoustic backscatter measurements and ground-truthing with grab samples and underwater video. Sediment loss in the entire San Francisco Bay Coastal System during the last half-century, as estimated from a series of bathymetric change studies, is 240 million cubic meters, and most of this is believed to be coarse sediment (i.e., sand and gravel) from Central Bay and the San Francisco Bar, which is likely to limit the sand supply to adjacent, open-coast beaches. This hypothesis is supported by a calibrated numerical model in a related study that indicates that there is a potential net export of sand-sized sediment across the Golden Gate, suggesting that a reduction in the supply of sand-sized sediment within west-central San Francisco Bay will limit transport to the outer coast.

California↗

Incorporation of seawater into mid-ocean ridge lava flows during emplacement

Evidence for the interaction between seawater and lava during emplacement on the deep seafloor can be observed in solidified flows at a variety of scales including rapid quenching of their outer crusts and the formation of lava pillars through the body of the flow. Recently, an additional interaction, incorporation of heated seawater (vapor) into the body of a flow, has been proposed. Large voids and vesicles beneath the surface crusts of mid-ocean ridge crest lobate and sheet lava flows and lava drips found within those cavities have been cited as evidence for this interaction. The voids resulting from this interaction contribute to the high porosity of the shallow ocean crust and play an important role in crustal permeability and hydrothermal circulation at mid-ocean ridges, and thus it is important to understand their origin. We analyze lava samples from the fast-spreading East Pacific Rise and intermediate-spreading Galapagos Spreading Center to characterize this process, identify the source of the vapor, and investigate the implications this would have on submarine lava flow dynamics. We find that lava samples that have interacted with a vapor have a zone of increased vesicularity on the underside of the lava crust and a coating of precipitate minerals (i.e., crystal fringe) that are distinct in form and composition from those crystallized from the melt. We use thermochemical modeling to simulate the reaction between the lava and a vapor and find that only with seawater can we reproduce the phase assemblage we observe within the crystal fringes present in the samples. Model results suggest that large-scale contamination of the lava by mass exchange with the vapor is unlikely, but we observe local enrichment of the lava in Cl resulting from the incorporation of a brine phase separated from the seawater. We suggest that high eruption rates are necessary for seawater incorporation to occur, but the mechanism by which seawater enters the flow has yet to be resolved. A persistent vapor phase may be important in inhibiting the collapse of lava flow roofs during natural waxing and waning of lava levels during emplacement allowing lava pathways to be maintained during long lived eruptions. In addition, we illustrate the potential for a persistent vapor layer to increase local flow rates within submarine flows by up to a factor of three, thereby influencing how lava is distributed across the ridge crest. ?? 2006 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗

Mercury contamination and potential health risks to Arctic seabirds and shorebirds

Since the last Arctic Monitoring and Assessment Programme (AMAP) effort to review biological effects of mercury (Hg) on Arctic biota in 2011 and 2018, there has been a considerable number of new Arctic bird studies. This review article provides contemporary Hg exposure and potential health risk for 36 Arctic seabird and shorebird species, representing a larger portion of the Arctic than during previous AMAP assessments now also including parts of the Russian Arctic. To assess risk to birds, we used Hg toxicity benchmarks established for blood and converted to egg, liver, and feather tissues. Several Arctic seabird populations showed Hg concentrations that exceeded toxicity benchmarks, with 50 % of individual birds exceeding the “no adverse health effect” level. In particular, 5 % of all studied birds were considered to be at moderate or higher risk to Hg toxicity. However, most seabirds (95 %) were generally at lower risk to Hg toxicity. The highest Hg contamination was observed in seabirds breeding in the western Atlantic and Pacific Oceans. Most Arctic shorebirds exhibited low Hg concentrations, with approximately 45 % of individuals categorized at no risk, 2.5 % at high risk category, and no individual at severe risk. Although the majority Arctic-breeding seabirds and shorebirds appeared at lower risk to Hg toxicity, recent studies have reported deleterious effects of Hg on some pituitary hormones, genotoxicity, and reproductive performance. Adult survival appeared unaffected by Hg exposure, although long-term banding studies incorporating Hg are still limited. Although Hg contamination across the Arctic is considered low for most bird species, Hg in combination with other stressors, including other contaminants, diseases, parasites, and climate change, may still cause adverse effects. Future investigations on the global impact of Hg on Arctic birds should be conducted within a multi-stressor framework. This information helps to address Article 22 (Effectiveness Evaluation) of the Minamata Convention on Mercury as a global pollutant.

Science of the Total Environment↗

A comparison of Sr-Nd-Pb isotopes in young and old continental lithospheric mantle: Patagonia and eastern China

It is commonly accepted that beneath the continental crust lies a keel of lithospheric mantle, which extends 50–200 kilometres downward to a transition zone into the asthenosphere. The chemical and physical properties of this reservoir are best known through studies of the basalts and xenoliths that provide samples of the subcrustal mantle. Although sharing many characteristics with oceanic island basalts, some continental basalts become increasingly distinct isotopically as crustal age increases, strongly supporting a permanent association between crust and mantle. Consequently, the distinctive trace element and isotope composition of the lithospheric mantle is able to give important clues to its origin and evolution. The mantle under newly‐created crust is typified by a radiogenic isotope variability that emphasizes the materials from which the continental lithosphere is assembled. Old lithospheric mantle, on the other hand, exhibits more evolved isotopic patterns that attest to the existence of long‐lived, chemically complex systems. A comparison of the Pb, Sr and Nd isotopes in alkalic to sub‐alkalic basalt derived from Phanerozoic (Patagonia) and Middle Archaean to Early Proterozoic (eastern China) subcrustal mantle is useful for identifying ‘end‐member’ components of the lithosphere. One component, having an isotopic composition close to PREMA, either continues to evolve virtually unchanged after incorporation into the lithosphere or is, itself, a relatively new addition even to old lithosphere. Another component, beginning with the isotopic composition of BSE, undergoes significant reduction in U/Pb and Sm/Nd (but not Rb/Sr) upon incorporation into the lithosphere and, with time, shows an increasingly retarded evolution of 206 Pb/ 204 Pb and negative ε Nd‐values approaching the isotopic composition of EMI. Five models are discussed that relate the isotopic composition of the continental lithospheric mantle to that of other parts of the terrestrial system, which may be involved in its origin and evolution. The potential locations of the contributing components and the mechanisms and timing of their assembly into lithosphere are considered. Current knowledge, however, does not allow us to distinguish unequivocally among the various scenarios for the creation and evolution of this reservoir.

Australian Journal of Earth Sciences↗

United States Gulf of Mexico waters provide important nursery habitat for Mexico’s green turtle nesting populations

Resolving natal populations for juvenile green turtles is challenging given their potential for extensive dispersal during the oceanic stage and ontogenetic shifts among nursery habitats. Mitochondrial DNA markers have elucidated patterns of connectivity between green turtle nesting populations (rookeries) and juvenile foraging aggregations. However, missing rookery baseline data and haplotype sharing among populations have often impeded inferences, including estimating origins of Gulf of Mexico juveniles. Here, we assessed genetic structure among seven foraging aggregations spanning southern Texas (TX) to southwestern Florida (SWFL), including Port Fourchon, Louisiana (LA); a surface-pelagic aggregation (SP) offshore of Louisiana and Florida; Santa Rosa Island, Florida (SRI); St. Joseph Bay, Florida (SJB); and the Big Bend region, Florida (BB). We estimated source contributions to aggregations with novel genetic data (excluding SP and BB) using a Bayesian many-to-one mixed stock analysis (MSA) approach. Haplotype frequencies for western (TX, LA, SP, SRI) and eastern (SJB, BB, SWFL) aggregations were significantly differentiated. The largest shift in haplotype frequencies between proximal nursery sites occurred between SRI and SJB, separated by only 150 km, highlighting the lack of a geographic yardstick for predicting genetic structure. In contrast to previous MSA results, there was no signal of Florida juveniles at any foraging site. Mexican contributions dominated in all aggregations, with strong connectivity between western Bay of Campeche (Tamaulipas/Veracruz) rookeries and western foraging aggregations. MSA indicated more diverse Mexican origins for eastern aggregations, with larger inputs from the eastern Bay of Campeche (Campeche/Yucatán), Campeche Bank, and Quintana Roo rookeries. These results demonstrate the significance of the Gulf of Mexico coast and offshore waters of the United States as important nursery habitat for green turtles of Mexican origin and highlight the need for international coordination for management of these populations.

Alabama, Florida, Louisiana, Mississippi, Texas↗

Disentangling stationary and dynamic estuarine fish habitat to inform conservation: Species-specific responses to physical habitat and water quality in San Francisco Estuary

Estuaries represent critical aquatic habitat that connects surface water distributed between Earth’s landmasses and oceans. They are dynamic transitional ecosystems, which provide important habitat for fishes and other aquatic organisms. Effective conservation of species inhabiting estuaries requires knowledge of the habitat features that drive their abundance and distribution. We sought to elucidate how stationary (i.e., wetlands, shoals, and channels) and dynamic (i.e., salinity, temperature, turbidity, and chlorophyll concentration) habitat features interact to drive distributions of individual fish species. The Pacific coast of the conterminous United States has over 400 estuaries of various types. The largest (historical surface area) is San Francisco Estuary, California. We conducted extensive field observations of fishes in the central San Francisco Estuary among stationary habitat types (i.e., wetland, shoal, and channel) over a 19-month period encompassing substantial variability in dynamic water quality conditions. Most of the species observed, especially native species of special management interest, were associated with tidal wetland habitat. Few species exhibited associations with water quality conditions driven by seasonal (temperature) or a combination of broad- and fine-scale ecosystem processes (salinity and turbidity). Our study provides (1) an empirical demonstration of how researchers can deal with the complex and dynamic expressions of habitat in estuarine systems to address urgent natural resource problems and (2) a clear demonstration of the urgent need for habitat restoration and its likely outcome in systems such as San Francisco Estuary. Restoration of suitable tidal wetland habitat on the West Coast of the United States is likely to be an effective conservation tool to support estuarine fishes given that over 90% of historical tidal wetland habitat in San Francisco Estuary and 85% of vegetated wetland habitat along the Pacific coast of the United States has been lost due to human modification.

California↗

The surface elevation table and marker horizon technique: A protocol for measuring wetland elevation dynamics, narrative (Version 2.0)

The National Park Service (NPS), in response to the growing evidence and awareness of the effects of climate change on federal lands, determined that monitoring wetland elevation change is a top priority in North Atlantic Coastal parks (Stevens et al. 2010). As a result, the NPS Northeast Coastal and Barrier Network (NCBN) in collaboration with colleagues from the U.S. Geological Survey (USGS) and the National Oceanic and Atmospheric Administration (NOAA) have developed a protocol for monitoring wetland elevation change and other processes important for determining the viability of wetland communities. Although focused on North Atlantic Coastal parks, this document is applicable to all coastal and inland wetland regions. Wetlands exist within a narrow range of elevation that is influenced by local hydrologic conditions. For tidally influenced coastal wetlands, local hydrologic conditions may be changing as sea levels continue to rise. As sea level rises, coastal wetland systems may either a) build elevation to maintain favorable hydrologic conditions for their survival or b) become increasingly inundated beyond their physiological tolerance resulting in an eventual conversion to open water. A better understanding of these processes will help to determine the present and future viability of coastal wetlands managed by the NPS and can help address measures to ensure these communities exist into the future. This protocol provides the reader with instructions and guidelines on designing a monitoring plan or study to: Quantify elevation change in wetlands with the Surface Elevation Table (SET); understand the processes that influence elevation change, including vertical accretion (SET and Marker Horizon methods); survey the wetland surface and SET mark to a common reference datum to allow for comparing sample stations to each other and to local tidal datums; survey the SET mark to monitor its relative stability; and establish water level equipment to characterize the hydrology and tidal datums for a particular wetland site or sites. The protocol is divided into two documents: The narrative (this document) presents an overview of all aspects of monitoring wetland elevation dynamics, and a document of Standard Operating Procedures (SOPs) with detailed instructions on the design, installation, data collection, and data management in support of monitoring changes in wetland elevation.

Science Report↗

Constraints on near-ridge magmatism using 40Ar/39Ar geochronology of enriched MORB from the 8°20' N seamount chain

Our understanding of the spatial-temporal-compositional relationships between off-axis magmatism and mid-ocean ridge spreading centers is limited. Determining the 40 Ar/ 39 Ar ages of mid-ocean ridge basalt (MORB) lavas erupting near mid-ocean ridges (MOR) has been a challenge due to the characteristically low K 2 O contents in incompatible element-depleted normal MORB (NMORB). High-precision 40 Ar/ 39 Ar geochronology is used here to determine ages of young, basaltic lavas erupted along the 8°20' N seamount chain west of the East Pacific Rise (EPR) axis that have a range of incompatible element enrichments (EMORB) suitable for 40 Ar/ 39 Ar geochronology (e.g., K 2 O contents > 0.3 wt%). 40 Ar/ 39 Ar ages were determined in 29 well-characterized basalts sampled using HOV Alvin and dredging. Detailed geochronology and geochemical analyses provide important constraints on the timing, distribution, and origins of lavas that constructed this extensive volcanic lineament relative to magmatism beneath the adjacent EPR axis. Seamount eruption ages are up to ∼1.6 Ma younger than the underlying lithosphere, supporting a model of prolonged off-axis magmatism for at least 2 Myrs at distances as great as ∼90 km from the ridge axis. Increasing geochemical heterogeneity with eruption distance reflects the diminishing effect of sub-ridge melt focusing. The range of geochemically distinct lavas erupted at given distances from the ridge highlights the dynamic nature of the near-ridge magmatic environment over Myr timescales. Linear ridge-like (EPR-parallel) morphotectonic features erupt the youngest and most incompatible element-enriched lavas of the entire seamount chain, indicating there is a recent change in the influence of mantle heterogeneity and off-axis melt metasomatism on the near-ridge lithospheric mantle. Changes in seamount morphologies are attributed to counter-clockwise rotation and southward migration of the nearby Siqueiros transform over the last few million years.

Earth and Planetary Science Letters↗

Mercury bioaccumulation and cortisol interact to influence endocrine and immune biomarkers in a free-ranging marine mammal

Mercury bioaccumulation from deep-ocean prey and the extreme life history strategies of adult female northern elephant seals ( Mirounga angustirostris ) provide a unique system to assess the interactive effects of mercury and stress on animal health by quantifying blood biomarkers in relation to mercury (skeletal muscle and blood mercury) and cortisol concentrations. The thyroid hormone thyroxine (tT4) and the antibody immunoglobulin E (IgE) were associated with mercury and cortisol concentrations interactively, where the magnitude and direction of the association of each biomarker with mercury or cortisol changed depending on the concentration of the other factor. For example, when cortisol concentrations were lowest, tT4 was positively related to muscle mercury, whereas tT4 had a negative relationship with muscle mercury in seals that had the highest cortisol concentrations. Additionally, we observed that two thyroid hormones, triiodothyronine (tT3) and reverse triiodothyronine (rT3), were negatively (tT3) and positively (rT3) associated with mercury concentrations and cortisol in an additive manner. As an example, tT3 concentrations in late breeding seals at the median cortisol concentration decreased by 14% across the range of observed muscle mercury concentrations. We also observed that immunoglobulin M (IgM), the pro-inflammatory cytokine IL-6 (IL-6), and a reproductive hormone, estradiol, were negatively related to muscle mercury concentrations but were not related to cortisol. Specifically, estradiol concentrations in late molting seals decreased by 50% across the range of muscle mercury concentrations. These results indicate important physiological effects of mercury on free-ranging apex marine predators and interactions between mercury bioaccumulation and extrinsic stressors. Deleterious effects on animals’ abilities to maintain homeostasis (thyroid hormones), fight off pathogens and disease (innate and adaptive immune system), and successfully reproduce (endocrine system) can have significant individual- and population-level consequences.

Environmental Science & Technology↗

Carboniferous climate teleconnections archived in coupled bioapatite δ18OPO4 and 87Sr/86Sr records from the epicontinental Donets Basin, Ukraine

Reconstructions of paleo-seawater chemistry are largely inferred from biogenic records of epicontinental seas. Recent studies provide considerable evidence for large-scale spatial and temporal variability in the environmental dynamics of these semi-restricted seas that leads to the decoupling of epicontinental isotopic records from those of the open ocean. We present conodont apatite δ 18 O PO4 and 87 Sr/ 86 Sr records spanning 24 Myr of the late Mississippian through Pennsylvanian derived from the U–Pb calibrated cyclothemic succession of the Donets Basin, eastern Ukraine. On a 2 to 6 Myr-scale, systematic fluctuations in bioapatite δ 18 O PO4 and 87 Sr/ 86 Sr broadly follow major shifts in the Donets onlap–offlap history and inferred regional climate, but are distinct from contemporaneous more open-water δ 18 O PO4 and global seawater Sr isotope trends. A −1 to −6‰ offset in Donets δ 18 O PO4 values from those of more open-water conodonts and greater temporal variability in δ 18 O PO4 and 87 Sr/ 86 Sr records are interpreted to primarily record climatically driven changes in local environmental processes in the Donets sea. Systematic isotopic shifts associated with Myr-scale sea-level fluctuations, however, indicate an extrabasinal driver. We propose a mechanistic link to glacioeustasy through a teleconnection between high-latitude ice changes and atmospheric p CO 2 and regional monsoonal circulation in the Donets region. Inferred large-magnitude changes in Donets seawater salinity and temperature, not archived in the more open-water or global contemporaneous records, indicate a modification of the global climate signal in the epicontinental sea through amplification or dampening of the climate signal by local and regional environmental processes. This finding of global climate change filtered through local processes has implications for the use of conodont δ 18 O PO4 and 87 Sr/ 86 Sr values as proxies of paleo-seawater composition, mean temperature, and glacioeustasy.

Donets Basin↗

Differential preservation in the geologic record of intraoceanic arc sedimentary and tectonic processes

Records of ancient intraoceanic arc activity, now preserved in continental suture zones, are commonly used to reconstruct paleogeography and plate motion, and to understand how continental crust is formed, recycled, and maintained through time. However, interpreting tectonic and sedimentary records from ancient terranes after arc–continent collision is complicated by preferential preservation of evidence for some arc processes and loss of evidence for others. In this synthesis we examine what is lost, and what is preserved, in the translation from modern processes to the ancient record of intraoceanic arcs. Composition of accreted arc terranes differs as a function of arc–continent collision geometry. ‘Forward-facing’ collision can accrete an oceanic arc on to either a passive or an active continental margin, with the arc facing the continent and colliding trench- and forearc-side first. In a ‘backward-facing’ collision, involving two subduction zones with similar polarity, the arc collides backarc-first with an active continental margin. The preservation of evidence for contemporary sedimentary and tectonic arc processes in the geologic record depends greatly on how well the various parts of the arc survive collision and orogeny in each case. Preservation of arc terranes likely is biased towards those that were in a state of tectonic accretion for tens of millions of years before collision, rather than tectonic erosion. The prevalence of tectonic erosion in modern intraoceanic arcs implies that valuable records of arc processes are commonly destroyed even before the arc collides with a continent. Arc systems are most likely to undergo tectonic accretion shortly before forward-facing collision with a continent, and thus most forearc and accretionary-prism material in ancient arc terranes likely is temporally biased toward the final stages of arc activity, when sediment flux to the trench was greatest and tectonic accretion prevailed. Collision geometry and tectonic erosion vs. accretion are important controls on the ultimate survival of material from the trench, forearc, arc massif, intra-arc basins, and backarc basins, and thus on how well an ancient arc terrane preserves evidence for tectonic processes such as subduction of aseismic ridges and seamounts, oblique plate convergence, and arc rifting. Forward-facing collision involves substantial recycling, melting, and fractionation of continent-derived material during and after collision, and so produces melts rich in silica and incompatible trace elements. As a result, forward-facing collision can drive the composition of accreted arc crust toward that of average continental crust.

Earth-Science Reviews↗

Data-limited fishery assessment methods shed light on the exploitation history and population dynamics of Endangered Species Act-listed Yelloweye Rockfish in Puget Sound, Washington

Objective The distinct population segment (DPS) of Yelloweye Rockfish Sebastes ruberrimus inhabiting the Puget Sound/Georgia Basin was listed under the Endangered Species Act (ESA) in 2010, and a formal recovery plan for the DPS was published by National Oceanic and Atmospheric Administration Fisheries in 2017. In this recovery plan, the biological criteria for delisting or downlisting were specified as certain levels of spawning potential ratio (SPR), a commonly used metric of equilibrium stock status for commercially exploited fishes. Although this metric can be estimated from length compositions, the combination of length data with a catch history (which was not previously available for this DPS) improves our understanding of population dynamics over time and allows us to estimate a different measure of stock status, relative (to unfished) spawning stock biomass (SSB), rather than only SPR. Methods To estimate relative SSB and reconstruct the historical dynamics of this DPS, we reconstructed the catch history from fisheries records, collated length data from historical and contemporary hook-and-line surveys, and fitted a data-limited version of a statistical catch-at-age model. Result Despite a high level of uncertainty, we estimated that Yelloweye Rockfish in Puget Sound are above 25% of unfished biomass (a reference point detailed in the recovery criteria) under the assumption of deterministic recruitment, presenting the first direct estimates of Yelloweye Rockfish population status in Puget Sound. Conclusion However, as informed by recent genetic studies, the DPS boundaries of ESA-listed Yelloweye Rockfish extend from South Puget Sound to Queen Charlotte Strait in British Columbia. The Canadian portion of this population is managed separately and is currently estimated to be at 32% of unfished biomass (95% quantiles = 15%–68%). Thus, the disjunction between the biological boundaries of the population and the jurisdictional boundaries between Canada and the United States presents an additional source of uncertainty in assessing recovery that must be addressed to achieve DPS-wide recovery goals.

Washington↗

A northern Cordilleran ocean-continent transect: Sitka Sound, Alaska, to Atlin Lake, British Columbia

The 155 km wide, 310 km long Sitka Sound – Atlin Lake continent–ocean transect includes almost all the geologic, geophysical, and geotectonic elements of the Canadian Cordillera. It crosses the Chugach, Wrangellia, Alexander, Stikine, and Cache Creek terranes, the Gravina and Laberge overlap assemblages, intrusive and metamorphic belts, and neotectonic faults that bound major blocks. Linear belts of magnetic highs are associated with Jurassic and Cretaceous granitic belts in Wrangellia and the western and central parts of the Alexander terrane and with the granitic rocks of the Coast plutonic–metamorphic complex (CPMC). The Border Ranges fault may be expressed at depth on either side of the Peril Strait fault. An enigmatic northeast-trending gradient in the CPMC and adjacent rocks separates a regional magnetic low to the northwest from a 300 nT high field to the southeast. The Bouguer gravity field decreases in broad steps from Pacific crust high values to lows at the international boundary, with pronounced gradients at the east edge of Chugach terrane and west edge of of CPMC. It indicates that the crust thickens from about 20 to 40 km from southwest to northeast. Ultramafic bodies in the Chugach, Alexander, and Wrangellia terranes and Gravina assemblage underlie local highs. Most of the accumulated seismic strain is released by large earthquakes on the Fairweather – Queen Charlotte Islands plate-margin fault, but the northern part of the Glacier Bay region, the Denali fault zone, and the Coast Mountains also have significant seismicity. Part of the Glacier Bay region is being uplifted at a high rate. Most of these features are related to the joining of ( i ) Wrangellia to Alexander terrane (Carboniferous), ( ii ) Stikine to Cache Creek terrane (Early Jurassic), ( iii ) Alexander terrane and Gravina assemblage to Stikine (Late Cretaceous), and ( iv ) Chugach to Wrangellia and Alexander terrane (Late Cretaceous or Paleogene).

Alaska, British Columbia↗

Three-dimensional distribution of gas hydrate beneath southern Hydrate Ridge: Constraints from ODP Leg 204

Large uncertainties about the energy resource potential and role in global climate change of gas hydrates result from uncertainty about how much hydrate is contained in marine sediments. During Leg 204 of the Ocean Drilling Program (ODP) to the accretionary complex of the Cascadia subduction zone, we sampled the gas hydrate stability zone (GHSZ) from the seafloor to its base in contrasting geological settings defined by a 3D seismic survey. By integrating results from different methods, including several new techniques developed for Leg 204, we overcome the problem of spatial under-sampling inherent in robust methods traditionally used for estimating the hydrate content of cores and obtain a high-resolution, quantitative estimate of the total amount and spatial variability of gas hydrate in this structural system. We conclude that high gas hydrate content (30-40% of pore space or 20-26% of total volume) is restricted to the upper tens of meters below the seafloor near the summit of the structure, where vigorous fluid venting occurs. Elsewhere, the average gas hydrate content of the sediments in the gas hydrate stability zone is generally <2% of the pore space, although this estimate may increase by a factor of 2 when patchy zones of locally higher gas hydrate content are included in the calculation. These patchy zones are structurally and stratigraphically controlled, contain up to 20% hydrate in the pore space when averaged over zones ???10 m thick, and may occur in up to ???20% of the region imaged by 3D seismic data. This heterogeneous gas hydrate distribution is an important constraint on models of gas hydrate formation in marine sediments and the response of the sediments to tectonic and environmental change. ?? 2004 Published by Elsevier B.V.

Earth and Planetary Science Letters↗

Methane hydrate formation in turbidite sediments of northern Cascadia, IODP Expedition 311

Expedition 311 of the Integrated Ocean Drilling Program (IODP) to northern Cascadia recovered gas-hydrate bearing sediments along a SW-NE transect from the first ridge of the accretionary margin to the eastward limit of gas-hydrate stability. In this study we contrast the gas gas-hydrate distribution from two sites drilled ~ 8??km apart in different tectonic settings. At Site U1325, drilled on a depositional basin with nearly horizontal sedimentary sequences, the gas-hydrate distribution shows a trend of increasing saturation toward the base of gas-hydrate stability, consistent with several model simulations in the literature. Site U1326 was drilled on an uplifted ridge characterized by faulting, which has likely experienced some mass wasting events. Here the gas hydrate does not show a clear depth-distribution trend, the highest gas-hydrate saturation occurs well within the gas-hydrate stability zone at the shallow depth of ~ 49??mbsf. Sediments at both sites are characterized by abundant coarse-grained (sand) layers up to 23??cm in thickness, and are interspaced within fine-grained (clay and silty clay) detrital sediments. The gas-hydrate distribution is punctuated by localized depth intervals of high gas-hydrate saturation, which preferentially occur in the coarse-grained horizons and occupy up to 60% of the pore space at Site U1325 and > 80% at Site U1326. Detailed analyses of contiguous samples of different lithologies show that when enough methane is present, about 90% of the variance in gas-hydrate saturation can be explained by the sand (> 63????m) content of the sediments. The variability in gas-hydrate occupancy of sandy horizons at Site U1326 reflects an insufficient methane supply to the sediment section between 190 and 245??mbsf. ?? 2008 Elsevier B.V.

Earth and Planetary Science Letters↗