Natural remediation of arsenic contaminated ground water associated with landfill leachate
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This report presents hydrologic data collected by the U. S. Geological Survey from 1930 to 2001 with emphasis on data collected from 1997 to 2001 as part of a study of ground-water resources in Cedar Valley, Iron County, southwestern Utah (fig. 1). Data collected prior to this study are also presented to show long-term trends. Data were collected during this study in cooperation with the Central Iron County Water Conservancy District; Utah Department of Natural Resources, Division of Water Resources; Utah Department of Environmental Quality, Division of Water Quality; Cedar City; and Enoch City; as part of a study to better understand the ground-water resources of Cedar Valley and to assess possible effects of increased ground-water withdrawal on water quality. Quality of ground water in Cedar Valley is variable and water suppliers need to know if additional water resources can be developed without drawing water of lower quality into public-supply wells. Cedar Valley is in central Iron County at the transitional boundary between the Basin and Range and Colorado Plateau physiographic provinces described by Hunt (1974) and covers about 570 mi2. Additional data from wells west of Cedar Valley and to the south in the vicinity of Kanarraville in the Virgin River drainage (Colorado River Basin) adjacent to the study area are included. Cedar Valley is bounded on the east by the Markagunt Plateau and Red Hills, on the southwest by the Harmony Mountains, on the west by a complex of low hills, and on the north by the Black Mountains. Altitudes in the study area range from about 5,300 ft in Mud Spring Canyon to about 10,400 ft at Blowhard Mountain to the east.
Fresh to slightly saline water is available in most parts of Rusk County, which is located in the Piney Woods region of northeast Texas. The Wilcox aquifer, which underlies the entire county, was the source of most of the ground water withdrawn during 1980. Other units capable of yielding fresh ground water are the Carrizo, Queen City, and Sparta aquifers and the Reklaw Formation. About 5.4 million gallons per day (20,440 cubic meters per day) of ground water was used for all purposes during 1980. Of this amount, about 78 percent was used for public supply, 10 percent for mining, 8 percent for industrial purposes, and 4 percent for rural domestic use. Water levels have declined extensively at the city of Henderson, which used about 38 percent of all ground water consumed in Rusk County. Generally, the ground water is of acceptable quality. Water in some of the near-surface beds and some of the deeper sands in the Wilcox aquifer may have become mineralized because of oilfield operations. Ground-water contamination by oilfield brines at Henderson Oil Field has been documented. Two separate instances of streamflow contamination at Striker Creek and Henderson Oil Field have been documented. Moderate amounts of ground water are available for development. The amount that is available perennially is not known, but it is greater than that being withdrawn. Assuming a hydraulic gradient of about 8 feet per mile (1.5 meters per kilometer), at least 12 million gallons per day (45,420 cubic meters per day) of fresh ground water is being transmitted through the Wilcox and about 3 million gallons per day (11,350 cubic meters per day) through the Carrizo. About 20 million acre-feet (24,660 cubic hectometers) of freshwater is available from storage in the Wilcox and about 4 million acre-feet (4,930 cubic hectometers) from storage in the Carrizo. Additional amounts of slightly saline water are available from the major aquifers. Smaller but undetermined amounts of fresh ground water are available from the Sparta and Queen City aquifers and from the Reklaw Formation. Properly constructed wells in the Wilcox and Carrizo aquifers can be expected to yield more than 500 gallons per minute (32 liters per second) if the wells are properly spaced. Development of additional resources around the city of Henderson and the Mount Enterprise Fault System should be considered cautiously because of the probability of saltwater encroachment. Ground water in other parts of the county is practically undeveloped. Some mineralization of ground water is due to natural causes. Other mineralization of ground water is due to contamination. A program needs to be initiated to determine the extent and cause of mineralization that has taken place in freshwater sands. Water-quality data is needed at Henderson in order to monitor saltwater encroachment.
Gas hydrate is a naturally occurring “ice-like” combination of natural gas and water that has the potential to serve as an immense resource of natural gas from the world’s oceans and polar regions. However, gas-hydrate recovery is both a scientific and a technical challenge and much remains to be learned about the geologic, engineering, and economic factors controlling the ultimate energy resource potential of gas hydrate. The amount of natural gas contained in the world’s gas-hydrate accumulations is enormous, but these estimates are speculative and range over three orders of magnitude from about 2,800 to 8,000,000 trillion cubic meters of gas. By comparison, conventional natural gas accumulations (reserves and undiscovered, technically recoverable resources) for the world are estimated at approximately 440 trillion cubic meters. Gas recovery from gas hydrate is hindered because the gas is in a solid form and because gas hydrate commonly occurs in remote Arctic and deep marine environments. Proposed methods of gas recovery from gas hydrate generally deal with disassociating or “melting” in situ gas hydrate by heating the reservoir beyond the temperature of gas-hydrate formation, or decreasing the reservoir pressure below hydrate equilibrium. The pace of energy-related gas hydrate assessment projects has accelerated over the past several years. The Indian National Gas Hydrate Program Expedition 01 was designed to study the gas-hydrate occurrences off the Indian Peninsula and along the Andaman convergent margin with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. During Indian National Gas Hydrate Program Expedition 01, dedicated gas-hydrate coring, drilling, and downhole logging operations were conducted from 28 April 2006 to 19 August 2006.
Studies of seven landfills in the Indianapolis, Indiana, area indicate that in five of the landfills movement of ground water is from the deep aquifers into the uppermost aquifer. In the other two landfills, movement of ground water is from the shallow aquifers to the deeper aquifers, so that leachate is transported into the deeper aquifers. In all the landfills, the predominant direction of ground-water movement is lateral. Placing solid waste into the landfills has occasionally altered the local, but not the regional, flow patterns. Ground-water mounding at shallow depths beneath two of the landfills has caused flow toward the edges of the two fills. Leachate at these fills is moving downward and outward and has affected water quality at shallow depths. Pumping near two other landfills has reversed the direction of regional ground-water flow, allowing leachate to move toward the pumping wells. Leachate at the three remaining landfills is moving downgradient and is discharging into single streams adjacent to each landfill. (Woodard-USGS)
Water that contains radium-226 radioactivity in excess of the 5.0-picocurie-per-liter limit set in the National Interim Primary Drinking Water Regulations was found in the majority of wells sampled throughout Sarasota County. Highest levels were found areally near the coast or near rivers and vertically in the Tamiami-upper Hawthorn aquifer where semiconsolidated phosphate pebbles occur. Analysis of data suggests that part of the radium-226 in ground water of Sarasota County is dissolved by alpha particle recoil. In slightly mineralized water, radium-226 concentrations are decreased by ion exchange or sorption. In more mineralized water, other ions compete with radium-226 for ion exchange or sorption sites. Dissolution of minerals containing radium-226 by mineralized water probably contributes a significant fraction of the dissolved radium-226. Two types of mineralized water were present in Sarasota County. One type is a marine-like water, presumably associated with saltwater encroachment in coastal areas; the other is a calcium magnesium strontium surfate bicarbonate type. In general, water that contains high radium-226 radioactivities also contains too much water hardness or dissolved solids to be used for public supply without treatment that would also reduce radium-226 radioactivities. (USGS)
NETPATH is an interactive Fortran 77 computer program used to interpret net geochemical mass-balance reactions between an initial and final water along a hydrologic flow path. Alternatively, NETPATH computes the mixing proportions of two to five initial waters and net geochemical reactions that can account for the observed composition of a final water. The program utilizes previously defined chemical and isotopic data for waters from a hydrochemical system. For a set of mineral and (or) gas phases hypothesized to be the reactive phases in the system, NETPATH calculates the mass transfers in every possible combination of the selected phases that accounts for the observed changes in the selected chemical and (or) isotopic compositions observed along the flow path. The calculations are of use in interpreting geochemical reactions, mixing proportions, evaporation and (or) dilution of waters, and mineral mass transfer in the chemical and isotopic evolution of natural and environmental waters. Rayleigh distillation calculations are applied to each mass-balance model that satisfies the constraints to predict carbon, sulfur, nitrogen, and strontium isotopic compositions at the end point, including radiocarbon dating. DB is an interactive Fortran 77 computer program used to enter analytical data into NETPATH, and calculate the distribution of species in aqueous solution. This report describes the types of problems that can be solved, the methods used to solve problems, and the features available in the program to facilitate these solutions. Examples are presented to demonstrate most of the applications and features of NETPATH. The codes DB and NETPATH can be executed in the UNIX or DOS1 environment. This report replaces U.S. Geological Survey Water-Resources Investigations Report 91-4078, by Plummer and others, which described the original release of NETPATH, version 1.0 (dated December, 1991), and documents revisions and enhancements that are included in version 2.0. 1 The use of trade, brand or product names in this report is for identification purposes only and does not constitute endorsement by the U.S. Geological Survey.
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Nutrients, total dissolved solids (TDS), and trace elements affect the suitability of water for human and natural needs. Here, trends in such water-quality constituents are analyzed for 1999–2022 for eight nested monitoring sites in the 24,000 km 2 Fountain Creek watershed in Colorado, USA, by using the weighted regressions on time, discharge, and season (WRTDS) methodology. Fountain Creek shares characteristics with other western U.S. watersheds: (1) an expanding but more water-efficient population, (2) a heavy reliance on imported water, (3) a semiarid climate trending towards warmer and drier conditions, and (4) shifts of water from agricultural to municipal uses. The WRTDS analysis found both upward and downward trends in the concentrations of nutrients that reflected possible shifts in effluent management, instream uptake, and water conservation by a watershed population that grew by about 40%. Selenium, other trace elements, and TDS can pose water-quality challenges downstream and their concentrations were found to have a downwards trend. Those trends could be driven by either a warming and drying of the local climate or decreased agricultural irrigation, as both would reduce recharge and subsequent mobilization from natural geologic sources via groundwater discharge. The patterns illustrate how changes in climate and water use may have affected water quality in Fountain Creek and demonstrate the patterns to look for in other western watersheds.
Our study focuses on the geology, hydrology, and geochemistry of a variety of molybdenum (Mo) porphyry systems. The systems are either high fluorine, granite, Climax-type, systems (e.g. Mount Emmons/ Redwell Mo deposit, Colorado and Questa Mo deposit, New Mexico) or low fluorine granodiorite systems (e.g. Buckingham Stockwork Mo deposit, Battle Mountain, Nevada and Cannivan Gulch Mo deposit, Montana). The water quality of streams, natural springs, mine discharge, and ground water from drill holes were assessed in the region of these deposits. The ultimate goal of our study is to understand the environmental behavior of these Mo porphyry systems in the context of geologic setting, hydrologic regime, and climate.
Ecological conditions in the Greater Everglades have changed due to human activities, including the construction of canals to divert water away from the core of the landscape. Current and planned restoration projects are designed to produce a natural sheetflow of water across the landscape. This restoration of water flow should provide an increase in freshwater needed to restore natural salinities to the fringing estuarine ecosystem. In this report, we describe a Landscape Habitat Suitability Index model designed to evaluate alternative restoration plans for the benefit of a key species, the roseate spoonbill (Platalea ajaja). Model output has shown to be a good indicator of areas capable of supporting spoonbills. Use of this model will allow examination of the potential response of this key species to water management proposed through the Greater Everglades restoration process.
The quality of freshwater at any point on the landscape reflects the combined effects of many processes along water pathways. Human activities on all spatial scales affect both water quality and quantity. Alteration of the landscape and associated vegetation has not only changed the water balance, but typically has altered processes that control water quality. Effects of human activities on a small scale are relevant to an entire drainage basin. Furthermore, local, regional, and global differences in climate and water flow are considerable, causing varying effects of human activities on land and water quality and quantity, depending on location within a watershed, geology, biology, physiographic characteristics, and climate. These natural characteristics also greatly control human activities, which will, in turn, modify (or affect) the natural composition of water. One of the most important issues for effective resource management is recognition of cyclical and cascading effects of human activities on the water quality and quantity along hydrologic pathways. The degradation of water quality in one part of a watershed can have negative effects on users downstream. Everyone lives downstream of the effects of some human activity. An extremely important factor is that substances added to the atmosphere, land, and water generally have relatively long time scales for removal or clean up. The nature of the substance, including its affinity for adhering to soil and its ability to be transformed, affects the mobility and the time scale for removal of the substance. Policy alone will not solve many of the degradation issues, but a combination of policy, education, scientific knowledge, planning, and enforcement of applicable laws can provide mechanisms for slowing the rate of degradation and provide human and environmental protection. Such an integrated approach is needed to effectively manage land and water resources.
The North Platte Natural Resources District (NPNRD) has been actively collecting data and studying groundwater resources because of concerns about the future availability of the highly inter-connected surface-water and groundwater resources. This report, prepared by the U.S. Geological Survey in cooperation with the North Platte Natural Resources District, describes a groundwater-flow model of the North Platte River valley from Bridgeport, Nebraska, extending west to 6 miles into Wyoming. The model was built to improve the understanding of the interaction of surface-water and groundwater resources, and as an optimization tool, the model is able to analyze the effects of water-management options on the simulated stream base flow of the North Platte River. The groundwater system and related sources and sinks of water were simulated using a newton formulation of the U.S. Geological Survey modular three-dimensional groundwater model, referred to as MODFLOW–NWT, which provided an improved ability to solve nonlinear unconfined aquifer simulations with wetting and drying of cells. Using previously published aquifer-base-altitude contours in conjunction with newer test-hole and geophysical data, a new base-of-aquifer altitude map was generated because of the strong effect of the aquifer-base topography on groundwater-flow direction and magnitude. The largest inflow to groundwater is recharge originating from water leaking from canals, which is much larger than recharge originating from infiltration of precipitation. The largest component of groundwater discharge from the study area is to the North Platte River and its tributaries, with smaller amounts of discharge to evapotranspiration and groundwater withdrawals for irrigation. Recharge from infiltration of precipitation was estimated with a daily soil-water-balance model. Annual recharge from canal seepage was estimated using available records from the Bureau of Reclamation and then modified with canal-seepage potentials estimated using geophysical data. Groundwater withdrawals were estimated using land-cover data, precipitation data, and published crop water-use data. For fields irrigated with surface water and groundwater, surface-water deliveries were subtracted from the estimated net irrigation requirement, and groundwater withdrawal was assumed to be equal to any demand unmet by surface water. The groundwater-flow model was calibrated to measured groundwater levels and stream base flows estimated using the base-flow index method. The model was calibrated through automated adjustments using statistical techniques through parameter estimation using the parameter estimation suite of software (PEST). PEST was used to adjust 273 parameters, grouped as hydraulic conductivity of the aquifer, spatial multipliers to recharge, temporal multipliers to recharge, and two specific recharge parameters. Base flow of the North Platte River at Bridgeport, Nebraska, streamgage near the eastern, downstream end of the model was one of the primary calibration targets. Simulated base flow reasonably matched estimated base flow for this streamgage during 1950–2008, with an average difference of 15 percent. Overall, 1950–2008 simulated base flow followed the trend of the estimated base flow reasonably well, in cases with generally increasing or decreasing base flow from the start of the simulation to the end. Simulated base flow also matched estimated base flow reasonably well for most of the North Platte River tributaries with estimated base flow. Average simulated groundwater budgets during 1989–2008 were nearly three times larger for irrigation seasons than for non-irrigation seasons. The calibrated groundwater-flow model was used with the Groundwater-Management Process for the 2005 version of the U.S. Geological Survey modular three-dimensional groundwater model, MODFLOW–2005, to provide a tool for the NPNRD to better understand how water-management decisions could affect stream base flows of the North Platte River at Bridgeport, Nebr., streamgage in a future period from 2008 to 2019 under varying climatic conditions. The simulation-optimization model was constructed to analyze the maximum increase in simulated stream base flow that could be obtained with the minimum amount of reductions in groundwater withdrawals for irrigation. A second analysis extended the first to analyze the simulated base-flow benefit of groundwater withdrawals along with application of intentional recharge, that is, water from canals being released into rangeland areas with sandy soils. With optimized groundwater withdrawals and intentional recharge, the maximum simulated stream base flow was 15–23 cubic feet per second (ft 3 /s) greater than with no management at all, or 10–15 ft 3 /s larger than with managed groundwater withdrawals only. These results indicate not only the amount that simulated stream base flow can be increased by these management options, but also the locations where the management options provide the most or least benefit to the simulated stream base flow. For the analyses in this report, simulated base flow was best optimized by reductions in groundwater withdrawals north of the North Platte River and in the western half of the area. Intentional recharge sites selected by the optimization had a complex distribution but were more likely to be closer to the North Platte River or its tributaries. Future users of the simulation-optimization model will be able to modify the input files as to type, location, and timing of constraints, decision variables of groundwater withdrawals by zone, and other variables to explore other feasible management scenarios that may yield different increases in simulated future base flow of the North Platte River.
The ground water within the 50,000-square-mile area of the layered basalt of the Columbia River Group is a generally uniform bicarbonate water having calcium and sodium in nearly equal amounts as the principal cations. water contains a relatively large amount of silica. The 525 chemical analyses indicate that the prevalent ground water is of two related kinds--a calcium and a sodium water. The sodium water is more common beneath the floors of the main synclinal valleys; the calcium water, elsewhere. In addition to the prevalent type, five special types form a small part of the ground water; four of these are natural and one is artificial. The four natural special types are: (1) calcium sodium chloride waters that rise from underlying sedimentary rocks west of the Cascade Range, (2) mineralized water at or near warm or hot springs, (3) water having unusual ion concentrations, especially of chloride, near sedimentary rocks intercalated at the edges of the basalt, and (4) more mineralized water near one locality of excess carbon dioxide. The one artificial kind of special ground water has resulted from unintentional artificial recharge incidental to irrigation in parts of central Washington. The solids dissolved in the ground water have been picked up on the surface, within the overburden, and from minerals and glasses within the basalt. Evidence for the removal of ions from solution is confined to calcium and magnesium, only small amounts of which are present in some of the sodium-rich water. Minor constituents, such as the heavy metals, alkali metals, and alkali earths, occur in the ground water in trace, or small, amounts. The natural radioactivity of the ground waters is very low. Except for a few of the saline calcium sodium chloride waters and a few occurrences of excessive nitrate, the ground water generally meets the common standards of water good for most ordinary uses, but some of it can be improved by treatment. The water is clear and colorless and has a temperature slightly higher than would be indicated by the accepted 'normal' earth gradient. A small amount of iron is present in some of the water and a slight amount of hydrogen sulfide gas is present in water from most wells. Carbon-14 determinations indicate that the water has been underground for periods ranging from modern times to several tens of thousands of years. Generally, an increase in the age of the water corresponds to depth and with location in the central parts of the main structural basins. The evidence of correlations between chemical characteristics and the age of the water is limited to the excessive nitrate which occurs in young, shallow ground water and to the apparent base-exchange removal of calcium and magnesium that has occurred where the ground water is old.
Background The major issues facing ecosystem restoration and management in south Florida are centered on the availability and distribution of clean, fresh water. Surface water flow modeling studies are an important aspect of the scientific information needs of the ecosystem restoration initiative. Hydrologic models provide much needed predictive capabilities for evaluating options for management of parks, refuges, and lands planned for acquisition, as well as for understanding the impacts of land management practices in surrounding areas. Models must account for the expansive and extremely low relief terrain of south Florida, where surface waters of the natural system are transported by sheet flow from Lake Okeechobee through the Everglades to Florida Bay and the Gulf of Mexico. To model sheet flows, highly accurate elevation data that define the surface topography are required as the most critical input parameter to the Natural Systems Model and other hydrologic models. These data are necessary for calculating water surface slope, depth, velocity, and direction of flow. Hydrologists have stated vertical accuracy requirements of between 3 and 15 centimeters. These accuracy requirements are so stringent, because of the extremely flat terrain, that any standard or other currently available data products would not suffice for this modeling application.
Cache Creek and its tributaries from Clear Lake to Yolo Bypass have been the subject of quality and quantity of water studies by several governmental agencies since the early 1900's. Water-quality data from these studies showed that water in the basin is of good quality for most of the beneficial uses defined by the California State Water Resources Control Board. Concentrations of dissolved constituents are substantially higher in the water in the two largest tributaries than in Cache Creek. Seasonal variations in dissolved constituents are also greater in the tributaries than in Cache Creek. Clear Lake has a major effect on water quality, resulting in little seasonal fluctuation in water quality in Cache Creek. Excessive voron and suspended-sediment concentrations are the greatest water-quality problems, according to existing data. Both of these problems are from natural sources. Water-quality monitoring is presently being conducted monthly at four sites by the California Department of Water Resurces and at several other sites by other agencies. Modifications in current monitoring are proposed to gain further information on diel dissolved-oxygen cycles, pesticides, and biological constituents that may adversely affect beneficial uses. (USGS)
The Massachusetts Sustainable-Yield Estimator is a decision support tool that provides estimates of daily unaltered streamflow, water-use-adjusted streamflow, and water availability for ungaged, user-defined basins in Massachusetts. Daily streamflow at the ungaged site is estimated for unaltered (no water use) and water-use scenarios. The procedure for estimating streamflow was developed previously and has been implemented with minor changes and updated water-use data in version 2.0 of the Massachusetts Sustainable-Yield Estimator. Unaltered streamflow at selected exceedance probabilities is estimated by previously published regression equations. Streamflow is interpolated between the regressed quantiles to produce a continuous flow duration curve. A daily streamflow time series is produced for the ungaged site by relating the estimated flow duration curve at the ungaged site to a flow duration curve at a gaged reference site and then transferring the dates from the reference site to the ungaged site. Minor refinements were made to the previously published methods to estimate unaltered and water-use-adjusted streamflow, including a procedure to enforce the monotonic structure of the regression-based unaltered flow quantiles, improvements to the interpolation method used for computing the estimated flow duration curve, and updates to the methods used to compute time-lagged stream alterations from groundwater pumping or discharges. Additionally, a procedure was developed to estimate prediction intervals for daily and monthly unregulated streamflow time series at an ungaged site. The Massachusetts Sustainable-Yield Estimator computes water-use-adjusted streamflow using water-use data provided by the Massachusetts Department of Environmental Protection. Available water-use data included monthly withdrawal and wastewater discharge volumes from 2010 to 2014 for surface-water and groundwater sources. Water-use-adjusted streamflow represents the potential effect of current water use on natural streamflow in the basin over the range of historical hydrologic conditions. Georeferenced water withdrawal and discharge volumes were incorporated into the Massachusetts StreamStats web application for use in version 2.0 of the Massachusetts Sustainable-Yield Estimator. To compute water-use-adjusted streamflow, mean daily withdrawals and discharges within a user-defined basin are subtracted and added to the unaltered time series, respectively. Surface-water volumes are applied directly to the equation. Time-lagged streamflow alterations from groundwater withdrawal or wastewater discharge sources are estimated by using a response-coefficient method developed from results of previously published, calibrated groundwater models in Massachusetts. The Massachusetts Sustainable-Yield Estimator was updated to version 2.0 to improve software stability and usability. The version 2.0 software application was developed in Microsoft Access with a graphical user interface. All geoprocessing steps, including basin delineation and compilation of basin characteristics and water use within the basin, were completed in the Massachusetts StreamStats web application and exported for use by the Massachusetts Sustainable-Yield Estimator version 2.0.