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USGS2020

Short and long-term movement of mudflows of the Mississippi River Delta Front and their known and potential impacts on oil and gas infrastructure

Mudflows on the Mississippi River Delta Front (MRDF) are recognized hazards to oil and gas infrastructure in the shallow (20 – 300 m water depth) Gulf of Mexico. Preconditioning of the seafloor for failure results from high sedimentation rates coupled with slope over-steepening, under-consolidation, and abundant biogenic gas production. Catastrophic failure of production platforms and pipelines due to seafloor displacement during infrequent large hurricanes such as Camille in 1969 and Ivan in 2004, point to cyclical loading of the seafloor by waves as a primary movement trigger. Due to data limitations, the role of smaller storms and background oceanographic processes in driving seafloor movement have remained largely unconstrained, but are thought to contribute to significant seafloor change. With the aid of new high-resolution multibeam mapping and seismic reflection profiling across sections of the MRDF, several moving features within the deforming delta-front environment are investigated and potential hazards to infrastructure installed and adjacent to the region are discussed. Via repeat mapping surveys of selected areas and records of changing shipwreck locations, we highlight significant seafloor displacement across annual to decadal timescales. For example, individual blocks mapped within mudflow gullies adjacent to Southwest Pass show downslope transport of more than 80 m in a single year, while the S.S. Virginia, a 153 m-long oil tanker sunk in 1942 has been relocated and found to have moved downslope more than 400 m in 14 years, without a major hurricane (> Category 2) passing through the region.

Louisiana↗

USGS2024

Studies of the Reactivity of the Ferrihydrite Surface by Iron Isotopic Exchange and Mössbauer Spectroscopy

Two-line ferrihydrite is an important adsorbent of many toxics in natural and anthropogenic systems; however, the specific structural sites responsible for the high adsorption capacity are not well understood. A combination of chemical and spectroscopic techniques have been employed in this study to gain further insight into the structural nature of sites at the ferrihydrite surface. The kinetics of iron isotopic exchange demonstrated that there are at least two types of iron sites in ferrihydrite. One population of sites, referred to as labile sites, approached iron isotopic equilibrium within 24 hr in 59 Fe-NTA solutions, while the second population of sites, referred to as non-labile , exhibited a much slower rate of isotopic exchange. Adsorbed arsenate reduced the degree of exchange by labile sites, indicating that the anion blocked or greatly inhibited the rate of exchange of these sites. Mössbauer spectra were collected from a variety of samples including 56 Fe-ferrihydrite samples with 57 Fe in labile sites, samples containing 57 Fe throughout the structure, and samples with 57 Fe in non-labile sites. The spectra showed characteristic broad doublets signifying poor structural order. Refined fits of the spectra indicated that labile sites have larger quadrupole splitting, hence more local distortion, than non-labile sites. In all cases, the spectra demonstrated some degree of asymmetry, indicating a distribution of Fe environments in ferrihydrite. Overall spectral findings, combined with recent EXAFS results (Waychunas et al. , 1993), indicate that labile sites likely are more reactive (with respect to iron isotopic exchange) because they have fewer neighboring Fe octahedra and are therefore bound less strongly to the ferrihydrite structure. The labile population of sites probably is composed of end sites of the dioctahedral chain structure of 2-line ferrihydrite, which is a subset of the entire population of surface sites. Mössbauer spectra of samples containing adsorbed arsenate indicated that the anion may slightly decrease the distortion of labile sites and stabilized the structure as a whole by bidentate bonding.

Clays and Clay Minerals↗

USGS1961

The data of lead isotope geology related to problems of Ore Genesis

Searching questions about the origins of ore deposits have been asked for many years. Where do ore fluids originate-within the crust, or deeper? Can specific sources of ore metals be identified? When were ores deposited? How long did mineralization continue? What was the rate and paragenesis of deposition? Which deposits are cogenetic, and what metallogenetic provinces do they define? Isotope analyses of lead from rocks and ores provide a new tool for attacking such problems of ore genesis . About two thousand such analyses now available from more than 20 laboratories have been compiled and studied for this purpose. The data now available suggest partial answers to some questions and serve to define other, new problems , not previously recognized. Their greatest import, however, is to illustrate the potential future significance of lead - isotope studies. Ore - lead , as shown two decades ago, ranges widely in isotopic composition. Recent studies show that traces of lead in ordinary rocks of the earth's crust exhibit apparently similar variations. All these variations are attributable primarily to mixing of old lead with accumulations of new radiogenic lead from decay of radioactive uranium and thorium. Each sample of lead preserves in its isotopic composition a record of its own mixing history: a composite record of the time this lead was in different environments, its past associations with uranium and thorium, and the geochemical processes that moved it from place to place. Integrated study of all these variables will throw light on many difficult problems of ore genesis when adequate techniques are developed. Progress will be slow, however, until more accurate lead - isotope analyses can be made at lower cost and more objective criteria developed for interpreting measured isotopic compositions in terms of geologic history.

Economic Geology↗

USGS2012

Cambrian–Ordovician sedimentary rocks of Alaska

Cambrian-Lower Ordovician carbonate rocks that likely formed as part of the Laurentian continental margin, and may thus have been part of the Cambrian-Ordovician great American carbonate bank, occur in east-central Alaska in the Nation Arch area. These strata accumulated on the southwestern margin (present-day coordinates) of the Yukon stable block, a broad area of early Paleozoic carbonate platform deposition in the northern Yukon Territory, and constitute two successions. The first consists of approximately 900 m (∼2950 ft) of shallow-water limestone and dolostone that are in part silicified, laminated, oolitic, and pisolitic, and make up the lower member of the Jones Ridge Limestone. Conodonts, trilobites, archaeo-cyathids, and brachiopods indicate an age of Early Cambrian to early Early Ordovician (Tremadoc; Ibexian) and have Laurentian biogeographic affinities. Upper Ordovician bio-clastic limestone (the upper member of the Jones Ridge Limestone) unconformably overlies these strata. A roughly coeval, but somewhat deeper water, succession crops out near the Jones Ridge Limestone and consists of, in ascending order, the Funnel Creek Limestone, Adams Argillite, and Hillard Limestone. The Funnel Creek (15-400 m [50-1310 ft] thick) is mainly nonfossilif-erous, extensively silicified, commonly oolitic limestone and dolostone and is assumed to be Lower Cambrian in age. It is overlain by argillite, siltstone, cross-laminated quartzite, and oolitic to sandy limestone of the Adams Argillite (90-180 m [295-550 ft] thick). This unit contains the trace fossil Oldhamia and Lower Cambrian archaeocyathids and trilobites that have Siberian affinities. The Hillard (30-150 m [100-490 ft] thick) is chiefly limestone, with local ooids, edgewise and boulder conglomerate, and phosphatic horizons, and likely formed in a platform-margin setting. Trilobites and brachiopods from this unit are Early Cambrian to earliest Ordovician in age and have mainly Laurentian affinities. Slope and/or basinal rocks of the Road River Formation that are as old as Early Ordovician (early middle Arenig; Ibexian) unconformably overlie the Hillard Limestone. Abrupt facies transitions between the two Nation Arch area carbonate successions may reflect relatively steep paleoslopes and/or telescoping of facies by imbricate thrust faults. Carbonate strata of Cambrian–Ordovician age are also found north of the Nation Arch area in the Porcupine terrane. These rocks have been little studied, and their precise Stratigraphic succession and paleogeographic setting are uncertain. The few fossil collections indicate mainly Laurentian affinities and include Cambrian(?) trilobites and Lower and Middle Ordovician conodonts. Lower Paleozoic strata of the Porcupine terrane probably formed at or near the northwestern edge (present-day coordinates) of the Yukon stable block. Cambrian–Ordovician carbonate strata occur widely in northern Alaska (parts of the Arctic Alaska, York, and Seward terranes) and interior Alaska (Farewell terrane). These rocks share distinctive lithologic and faunal features and were deposited in a range of shallow-shelf to basinal environments. Carbonate platform successions in northern and interior Alaska include fossils of both Laurentian and Siberian biotic provinces and may have formed on a single crustal fragment that rifted away from the Siberian craton during the late Proterozoic. These Alaskan strata were most likely in faunal exchange with, but not physically attached to, the great American carbonate bank. Lower–Middle Ordovician carbonate and siliciclastic rocks are also found in the White Mountains, Livengood, and Ruby terranes of interior Alaska, the Alexander terrane in southeastern Alaska, and the Goodnews terrane in southwestern Alaska. These successions were likely not attached to Laurentia during their deposition, although some authors have proposed Laurentian origins for the White Mountains and Livengood terranes. Little detailed information is available on the resource potential of Cambrian–Ordovician successions in Alaska. Most have low porosity and are too thermally mature to be prospective for oil and gas, although a few units in east-central and northern Alaska may have some potential as petroleum source and reservoir rocks. Strata of this age have potential for metallic mineral resources; strata-bound Zn-Pb ± Ag occurrences are known in the Funnel Creek Limestone in east-central Alaska, as well as several units of possible Cambrian and/or Ordovician age in northern and interior Alaska.

Alaska↗

USGS2002

The Fish Canyon magma body, San Juan volcanic field, Colorado: Rejuvenation and eruption of an upper-crustal batholith

More than 5000 km 3 of nearly compositionally homogeneous crystal-rich dacite (∼68 wt % SiO 2 : ∼45% Pl + Kfs + Qtz + Hbl + Bt + Spn + Mag + Ilm + Ap + Zrn + Po) erupted from the Fish Canyon magma body during three phases: (1) the pre-caldera Pagosa Peak Dacite (an unusual poorly fragmented pyroclastic deposit, ∼200 km 3 ); (2) the syn-collapse Fish Canyon Tuff (one of the largest known ignimbrites, ∼5000 km 3 ); (3) the post-collapse Nutras Creek Dacite (a volumetrically minor lava). The late evolution of the Fish Canyon magma is characterized by rejuvenation of a near-solidus upper-crustal intrusive body (mainly crystal mush) of batholithic dimensions. The necessary thermal input was supplied by a shallow intrusion of more mafic magma represented at the surface by sparse andesitic enclaves in late-erupted Fish Canyon Tuff and by the post-caldera Huerto Andesite. The solidified margins of this intrusion are represented by holocrystalline xenoliths with Fish Canyon mineralogy and mineral chemistry and widely dispersed partially remelted polymineralic aggregates, but dehydration melting was not an important mechanism in the rejuvenation of the Fish Canyon magma. Underlying mafic magma may have evolved H 2 O–F–S–Cl-rich fluids that fluxed melting in the overlying crystal mush. Manifestations of the late up-temperature magma evolution are: (1) resorbed quartz, as well as feldspars displaying a wide spectrum of textures indicative of both resorption and growth, including Rapakivi textures and reverse growth zoning (An 27–28 to An 32–33 ) at the margins of many plagioclase phenocrysts; (2) high Sr, Ba, and Eu contents in the high-SiO 2 rhyolite matrix glass, which are inconsistent with extreme fractional crystallization of feldspar; (3) oscillatory and reverse growth zoning toward the margins of many euhedral hornblende phenocrysts (rimward increases from ∼5·5–6 to 7·7–8·5 wt % Al 2 O 3 ). Homogeneity in magma composition at the chamber-wide scale, contrasting with extreme textural and chemical complexities at the centimeter–millimeter scale, is consistent with a dynamic environment, wherein crystals with a variety of growth and resorption histories were juxtaposed shortly before eruption by convective currents.

Colorado↗

USGS1971

Geology of the Stroudsburg quadrangle and Adjacent areas, Pennsylvania--New Jersey

The Stroudsburg area is within the Valley and Ridge and Great Valley physiographic provinces, Northampton and Monroe Counties, Pennsylvania, and Warren County, New Jersey. The northeast-trending subparallel valleys and ridges resulted from erosion of folded heterogeneous sedimentary rocks. These are Middle Ordovician to Middle Devonian in age and are more than 17,000 feet thick. Deposition of a thick flysch sequence (Martinsburg Formation of Ordovician age) accompanied onset of Taconic orogenesis. It was followed by deposition of a thick molasse sequence of Silurian and Early Devonian age (continental and marginal-marine clastics--Shawangunk Formation and Bloomsburg Red Beds--overlain by predominantly marginal-marine and subtidal limestone, dolomite, shale, and sandstone--Poxono Island Formation through Oriskany Group). Basin deepening and gradual shallowing occurred during Esopus through Mahantango deposition, heralding the Acadian clastic wedge exposed north of the Stroudsburg area. Interpretation of sedimentary structures and regional stratigraphic relations suggest that the Silurian and Devonian rocks were deposited in the following environments: A1luviated coastal plain (meandering and braided streams), tidal flats (supratidal and intertidal), barrier zone, and neritic zone (upper and lower). The rock stratigraphic units have been grouped into four lithotectonic units, each having a different style of deformation. Folds produced in these rocks are disharmonic, and it is believed that each rock sequence is set off from units above and below by decollements, or zones of detachment. Movement was northwest into the Appalachian basin, primarily by gravitational sliding. The contact between the Shawangunk Formation of Silurian age and Martinsburg Formation of Ordovician age, is one zone of detachment as well as an angular unconformity. Deformational effects of the Middle to Late Ordovician Taconic orogeny are elusive, but it appears that the folds and most minor structures, including the prominent regional cleavage, were produced during the late Paleozoic Appalachian orogeny and are superimposed upon larger Taconic folds and faults. Field relations and microscopic study suggest that the regional cleavage in the Stroudsburg area is due to laminar flow of pelitic material along cleavage folia accompanied by mechanical reorientation of platy and elongate minerals and neocrystallization of mica, quartz, chlorite, and probably albite. Numerous lines of evidence point to the conclusion that cleavage developed after the rock was indurated and formed at, and Just below, conditions of low-grade metamorphism. Intensity of cleavage development increases to the southeast across the area. Second-generation slip cleavage, also believed to be Appalachian in age, formed by mechanical reorientation of minerals as well as by limited new mineral growth. The topography had a profound effect on the direction of movement of the Wisconsin glacier, as well as the manner of its retreat and the deposits that were formed. Till and stratified drift of Wisconsin age and till of Illinoian(?) age are common in the area. Wisconsin deglaciation occurred by northeastward retreat and by stagnation. A conspicuous terminal moraine marks the limit of Wisconsin ice movement. Lake Sciota was dammed between the retreating ice, the moraine, and the surrounding ridges north of Godfrey Ridge. Several deltas mark ice stand positions during the retreat of the ice. Lake-bottom and kame deposits are locally common in Cherry Valley. South of Kittatinny Mountain, on the other hand, melt water was freely discharged to the south. The wind and water gaps in the Stroudsburg area (including Delaware Water Gap and Wind Gap) are structurally controlled; specifically they are located where folds die out in short distances, where folding is locally more intense, or where resistant rocks dip steeply and have a narrow width of outcrop. This conclusion is contrary to

Open-File Report↗

USGS2011

Guidance manual for forensic analysis of perchlorate in groundwater using chlorine and oxygen isotopic analyses

Increased health concerns about perchlorate (ClO4-) during the past decade and subsequent regulatory considerations have generated appreciable interest in source identification. The key objective of the isotopic techniques described in this guidance manual is to provide evidence concerning the origin of ClO4- in soils and groundwater and, more specifically, whether that ClO4- is synthetic or natural. Chlorine and oxygen isotopic analyses of ClO4- provide the primary direct approach whereby different sources of ClO4- can be distinguished from each other. These techniques measure the relative abundances of the stable isotopes of chlorine (37Cl and 35Cl) and oxygen (18O, 17O, and 16O) in ClO4- using isotope-ratio mass spectrometry (IRMS). In addition, the relative abundance of the radioactive chlorine isotope 36Cl is measured using accelerator mass spectrometry (AMS). Taken together, these measurements provide four independent quantities that can be used to distinguish natural and synthetic ClO4- sources, to discriminate different types of natural ClO4-, and to detect ClO4- biodegradation in the environment. Other isotopic, chemical, and geochemical techniques that can be applied in conjunction with isotopic analyses of ClO4- to provide supporting data in forensic studies are also described. This guidance manual is intended to provide details of the methodology used to (1) collect ClO4- samples from the environment, particularly from groundwater, which is the main medium of interest for ClO4- source identification; (2) purify the collected ClO4- samples; (3) conduct oxygen (O) and chlorine (Cl) isotopic analyses on the purified samples; and (4) determine probable sources using the resulting isotope data. Current practices for groundwater sampling and quality assurance for sample collection, purification, and measurement of Cl and O isotopes in ClO4- are provided. A detailed case study of source evaluation in groundwater on Long Island is given along with the current literature on the subject of ClO4- source discrimination. ClO4- in the environment is derived from both synthetic and natural sources. Synthetic ClO4- salts, including ammonium perchlorate (NH4ClO4) and potassium perchlorate (KClO4), have been widely used as oxidants by the military and aerospace industry. A variety of commercial products also contain synthetic ClO4-,including fireworks, matches, air bags, chlorine bleach, safety flares, perchloric acid, and chlorate herbicides. Historical disposal practices by the military, aerospace industry, and chemical manufacturers have resulted in groundwater and drinking water contamination with ClO4- in the United States. Isolated contamination from fireworks, road flares, explosives, and perchloric acid has also been reported. However, ClO4- is also a naturally occurring anion. It is present with sodium nitrate (NaNO3) in surficial deposits in the Atacama Desert of Chile at an average concentration of around 0.1% (by mass) of the total soluble salt, and these deposits (sometimes referred to as “Chilean caliche”) were widely used in the United States during the first half of the 20th century as a source of inorganic nitrogen fertilizer. Natural ClO4- that is not associated with Chilean fertilizers has also recently been detected in the vadose zone, groundwaters, and mineral deposits collected from the arid southwestern United States, including 155,000 km2 of groundwater in the Southern High Plains (SHP) of Texas and New Mexico. In addition to synthetic sources, natural ClO4- from both Chilean fertilizers and indigenous sources represents a potentially large source of ClO4- in groundwater and drinking water in the United States.

Report↗

USGS2006

Arsenic, Boron, and Fluoride Concentrations in Ground Water in and Near Diabase Intrusions, Newark Basin, Southeastern Pennsylvania

During an investigation in 2000 by the U.S. Environmental Protection Agency (USEPA) of possible contaminant releases from an industrial facility on Congo Road near Gilbertsville in Berks and Montgomery Counties, southeastern Pennsylvania, concentrations of arsenic and fluoride above USEPA drinking-water standards of 10 ?g/L and 4 mg/L, respectively, and of boron above the USEPA health advisory level of 600 ?g/L were measured in ground water in an area along the northwestern edge of the Newark Basin. In 2003, the USEPA requested technical assistance from the U.S. Geological Survey (USGS) to help identify sources of arsenic, boron, and fluoride in the ground water in the Congo Road area, which included possible anthropogenic releases and naturally occurring mineralization in the local bedrock aquifer, and to identify other areas in the Newark Basin of southeastern Pennsylvania with similarly elevated concentrations of these constituents. The USGS reviewed available data and collected additional ground-water samples in the Congo Road area and four similar hydrogeologic settings. The Newark Basin is the largest of the 13 major exposed Mesozoic rift basins that stretch from Nova Scotia to South Carolina. Rocks in the Newark Basin include Triassic through Jurassic-age sedimentary sequences of sandstones and shales that were intruded by diabase. Mineral deposits of hydrothermal origin are associated with alteration zones bordering intrusions of diabase and also occur as strata-bound replacement deposits of copper and zinc in sedimentary rocks. The USGS review of data available in 2003 showed that water from about 10 percent of wells throughout the Newark Basin of southeastern Pennsylvania had concentrations of arsenic greater than the USEPA maximum contaminant level (MCL) of 10 ?g/L; the highest reported arsenic concentration was at about 70 ?g/L. Few data on boron were available, and the highest reported boron concentration in well-water samples was 60 ?g/L in contrast to concentrations over 5,000 ?g/L in the Congo Road area. Although concentrations of fluoride up to 4 mg/L were reported for a few well-water samples collected throughout the Newark Basin, about 90 percent of the samples had concentrations of 0.5 mg/L or less. The USGS sampled 58 wells primarily in 5 areas in the Newark Basin, southeastern Pennsylvania, from February 2004 through April 2005 to identify other possible areas of elevated arsenic, boron, and fluoride and to characterize the geochemical environment associated with elevated concentrations of these constituents. Sampled wells included 12 monitor wells at an industrial facility near Congo Road, 45 private-supply wells in Berks, Montgomery, and Bucks Counties, and 1 private-supply well near Dillsburg, York County, an area where elevated fluoride in ground water had been reported in the adjacent Gettysburg Basin. Wells were sampled in transects from the diabase through the adjacent hornfels and into the unaltered shales of the Brunswick Group. Field measurements were made of pH, temperature, dissolved oxygen concentration, and specific conductance. Samples were analyzed in the laboratory for major ions, nutrients, total organic carbon, dissolved and total concentrations of selected trace elements, and boron isotopic composition. Generally, the ground water from the 46 private-supply wells had relatively neutral to alkaline pH (ranging from 6.1 to 9.1) and moderate concentrations of dissolved oxygen. Most water samples were of the calcium-bicarbonate type. Concentrations of arsenic up to 60 ?g/L, boron up to 3,950 ?g/L, and fluoride up to 0.70 mg/L were measured. Drinking-water standards or health advisories (for constituents that do not have standards established) were exceeded most frequently (about 20 percent of samples) for arsenic and boron and less frequently (6 percent or less of samples) for total iron, manganese, sulfate, nitrate, lead, molybdenum, and strontium. In water from 12 monitor

Scientific Investigations Report↗

USGS2016

Deposition, accumulation, and alteration of Cl−, NO3−, ClO4− and ClO3− salts in a hyper-arid polar environment: Mass balance and isotopic constraints

The salt fraction in permafrost soils/sediments of the McMurdo Dry Valleys (MDV) of Antarctica can be used as a proxy for cold desert geochemical processes and paleoclimate reconstruction. Previous analyses of the salt fraction in MDV permafrost soils have largely been conducted in coastal regions where permafrost soils are variably affected by aqueous processes and mixed inputs from marine and stratospheric sources. We expand upon this work by evaluating permafrost soil/sediments in University Valley, located in the ultraxerous zone where both liquid water transport and marine influences are minimal. We determined the abundances of Cl − , NO 3 − , ClO 4 − and ClO 3 − in dry and ice-cemented soil/sediments, snow and glacier ice, and also characterized Cl − and NO 3 − isotopically. The data are not consistent with salt deposition in a sublimation till, nor with nuclear weapon testing fall-out, and instead point to a dominantly stratospheric source and to varying degrees of post depositional transformation depending on the substrate, from minimal alteration in bare soils to significant alteration (photodegradation and/or volatilization) in snow and glacier ice. Ionic abundances in the dry permafrost layer indicate limited vertical transport under the current climate conditions, likely due to percolation of snowmelt. Subtle changes in ClO 4 − /NO 3 − ratios and NO 3 − isotopic composition with depth and location may reflect both transport related fractionation and depositional history. Low molar ratios of ClO 3 − /ClO 4 − in surface soils compared to deposition and other arid systems suggest significant post depositional loss of ClO 3 − , possibly due to reduction by iron minerals, which may have important implications for oxy-chlorine species on Mars. Salt accumulation varies with distance along the valley and apparent accumulation times based on multiple methods range from ∼10 to 30 kyr near the glacier to 70–200 kyr near the valley mouth. The relatively young age of the salts and relatively low and homogeneous anion concentrations in the ice-cemented sediments point to either a mechanism of recent salt removal, or to relatively modern permafrost soils (<1 million years). Together, our results show that near surface salts in University Valley serve as an end-member of stratospheric sources not subject to biological processes or extensive remobilization.

Geochimica et Cosmochimica Acta↗

USGS2024

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California↗

USGS1999

Connecting onshore and offshore near-surface geology: Delaware's sand inventory project

Beginning in 1988, the Delaware Geological Survey began a program to inventory on-land sand resources suitable for beach nourishment. The inventory included an assessment of the native beach textures using existing data and developing parameters of what would be considered suitable sand textures for Delaware's Atlantic beaches. An assessment of the economics of on-land sand resources was also conducted, and it was determined that the cost of the sand was competitive with offshore dredging costs. In addition, the sand resources were put into a geologic context for purposes of predicting which depositional environments and lithostratigraphic units were most likely to produce suitable sand resources. The results of the work identified several suitable on-land sand resource areas in the Omar and Beaverdam formations that were deposited in barrier-tidal delta and fluvial-estuarine environments, respectively. The identified on-land resources areas have not been utilized due to difficulties of truck transport and development pressures in the resource areas. The Delaware Geological Survey's participation in years 8, 9, and 10 of the Continental Margins Program was developed to extend the known resource areas onshore to offshore Delaware in order to determine potential offshore sand resources for beach nourishment. Years 8 and 9 involved primarily the collection of all available data on the offshore geology. These data included all seismic lines, surface grab samples, and cores. The data were filtered for those that had reliable locations and geologic information that could be used for geologic investigations. Year 10 completed the investigations onshore by construction of a geologic cross-section from data along the coast of Delaware from Cape Henlopen to Fenwick. This cross section identified the geologic units and potential sand resource bodies as found immediately along the coast. These units and resources are currently being extended offshore and tied to known and potential sand resources as part of the continuing cooperative effort between the Delaware Geological Survey and the Minerals Management Service's INTERMAR office as sand resources are identified in federal waters off Delaware. Offshore sand resources are found in the Pliocene Beaverdam Formation offshore where overlying Quaternary units have been stripped, in the tidal delta complexes of several Quaternary units likely equivalent to the onshore Omar Formation, and in late Pleistocene- and Holocene-age shoal complexes. Onshore lithostratigraphic units can be traced offshore and show another reason for continued geologic mapping both onshore and offshore.The Delaware Geological Survey's participation in years 8, 9, and 10 of the Continental Margins Program was developed to extend the known resource areas onshore to offshore Delaware in order to determine potential offshore sand resources for beach nourishment. Years 8 and 9 involved primarily the collection of all available data on the offshore geology. These data included all seismic lines, surface grab samples, and cores. The data were filtered for those that had reliable locations and geologic information that could be used for geologic investigations. Year 10 completed the investigations onshore by construction of a geologic cross-section from data along the coast of Delaware from cape Henlopen to Fenwick.

Marine Georesources and Geotechnology↗

USGS2009

Concentration-discharge relationships reflect chemostatic characteristics of US catchments

Concentration-discharge relationships have been widely used as clues to the hydrochemical processes that control runoff chemistry. Here we examine concentration-discharge relationships for solutes produced primarily by mineral weathering in 59 geochemically diverse US catchments. We show that these catchments exhibit nearly chemostatic behaviour; their stream concentrations of weathering products such as Ca, Mg, Na, and Si typically vary by factors of only 3 to 20 while discharge varies by several orders of magnitude. Similar patterns are observed at the inter-annual time scale. This behaviour implies that solute concentrations in stream water are not determined by simple dilution of a fixed solute flux by a variable flux of water, and that rates of solute production and/or mobilization must be nearly proportional to water fluxes, both on storm and inter-annual timescales. We compared these catchments' concentration-discharge relationships to the predictions of several simple hydrological and geochemical models. Most of these models can be forced to approximately fit the observed concentration-discharge relationships, but often only by assuming unrealistic or internally inconsistent parameter values. We propose a new model that also fits the data and may be more robust. We suggest possible tests of the new model for future studies. The relative stability of concentration under widely varying discharge may help make aquatic environments habitable. It also implies that fluxes of weathering solutes in streams, and thus fluxes of alkalinity to the oceans, are determined primarily by water fluxes. Thus, hydrology may be a major driver of the ocean-alkalinity feedback regulating climate change. Copyright ?? 2009 John Wiley & Sons, Ltd.

Hydrological Processes↗

USGS2025

Comparison of creek and bay influences on salt marsh sediment budget and deposition patterns

The resilience of salt marshes with low organic production depends on their effective capture and retention of mineral sediment from adjacent waters. Little prior work has directly compared mechanisms of sediment import from wave-influenced marsh boundaries against those of tidal creeks. We used simultaneous deployment of net-deposition tiles and oceanographic sensors to identify the timing and magnitude of sediment import/export to, and redistribution within, a marsh in south San Francisco Bay. As the marsh has both an eroding bay-exposed scarp and a prominent tidal creek, we investigated the mechanisms and magnitudes of sediment import from the marsh-bay versus the marsh-creek interface. The strong daily sea breezes of the summer season produced most of the wave-driven erosion of the marsh scarp and controlled suspended sediment concentrations; the winter season had weaker winds punctuated by a few storms. A large seasonal difference in suspended sediment concentrations influenced both flood and ebb sediment fluxes to the marsh and led to much higher rates of import in the summer. Both bay-side and creek-side processes were important to total marsh sediment budget. Bay-side sediment contributions were more variable in time due to the bay-influenced environment, and creek-side contributions were overall larger, reflecting the large proportion of the marsh fed by creek water. Sediment was redistributed throughout the system, with erosion near the bay-edge, accretion near the creek-edge and slow import to the marsh interior. The marsh was net importing sediment in the summer and exporting in the winter from different rates of these processes; on an annual scale, the marsh was net importing despite rapid lateral marsh loss. These findings emphasize that a positive sediment budget does not imply a stable marsh and that both creek- and edge-side dynamics are important for marsh sedimentation and geomorphic trajectories. Further, we expand understandings of non-storm and seasonal controls on marsh sedimentation.

California↗

USGS2003

Integrating soils and geomorphology in mountains - An example from the Front Range of Colorado

Soil distribution in high mountains reflects the impact of several soil-forming factors. Soil geomorphologists use key pedological properties to estimate ages of Quaternary deposits of various depositional environments, estimate long-term stability and instability of landscapes, and make inferences on past climatic change. Once the influence of the soil-forming factors is known, soils can be used to help interpret some aspects of landscape evolution that otherwise might go undetected. The Front Range of Colorado rises from the plains of the Colorado Piedmont at about 1700 m past a widespread, dissected Tertiary erosion surface between 2300 and 2800 m up to an alpine Continental Divide at 3600 to over 4000 m. Pleistocene valley glaciers reached the western edge of the erosion surface. Parent rocks are broadly uniform (granitic and gneissic). Climate varies from 46 cm mean annual precipitation (MAP) and 11 ??C mean annual temperature (MAT) in the plains to 102 cm and -4 ??C, respectively, near the range crest. Vegetation follows climate with grassland in the plains, forest in the mountains, and tundra above 3450 m. Soils reflect the bioclimatic transect from plains to divide: A/Bw or Bt/Bk or K (grassland) to A/E/Bw or Bt/C (forest) to A/Bw/C (tundra). Corresponding soil pH values decrease from 8 to less than 5 with increasing elevation. The pedogenic clay minerals dominant in each major vegetation zone are: smectite (grassland), vermiculite (forest), and 1.0-1.8 nm mixed-layer clays (tundra). Within the lower forested zone, the topographic factor (aspect) results in more leached, colder soils, with relatively thin O horizons, well-expressed E horizons and Bt horizons (Alfisols) on N-facing slopes, whereas soils with thicker A horizons, less developed or no E horizons, and Bw or Bt horizons (Mollisols) are more common on S-facing slopes. The topographic factor in the tundra results in soil patterns as a consequence of wind-redistributed snow and the amount of time it lingers on the landscape. An important parent material factor is airborne dust, which results in fine-grained surface horizons and, if infiltrated, contributes to clay accumulation in some Bt horizons. The time factor is evaluated by soil chronosequence studies of Quaternary deposits in tundra, upper forest, and plains grassland. Few soils in the study area are >10,000 years old in the tundra, >100,000 years old in the forest, and >2 million years old in the grassland. Stages of granite weathering vary with distance from the Continental Divide and the best developed is grus near the sedimentary/granitic rock contact just west of the mountain front. Grus takes a minimum of 100,000 years to form. Some of the relations indicated by the soil map patterns are: (1) parts of the erosion surface have been stable for 100,000 years or more; (2) development of grus near the mountain front could be due in part to pre-Pennsylvanian weathering; (3) a few soil properties reflect Quaternary paleoclimate; and (4) a correlation between soil development in the canyons and stream incision rates. ?? 2003 Elsevier Science B.V. All rights reserved.

Geomorphology↗

USGS2019

Tracing the cycling and fate of the munition, Hexahydro-1,3,5-trinitro-1,3,5-triazine in a simulated sandy coastal marine habitat with a stable isotopic tracer, 15N-[RDX]

Coastal marine habitats become contaminated with the munitions constituent, Hexahydro-1,3,5-trinitro-1,3,5-trazine (RDX), via military training, weapon testing and leakage of unexploded ordnance. This study used 15 N labeled RDX in simulated aquarium-scale coastal marine habitat containing seawater, sediment, and biota to track removal pathways from surface water including sorption onto particulates, degradation to nitroso-triazines and mineralization to dissolved inorganic nitrogen (DIN). The two aquaria received continuous RDX inputs to maintain a steady state concentration (0.4 mg L −1 ) over 21 days. Time series RDX and nitroso-triazine concentrations in dissolved (surface and porewater) and sorbed phases (sediment and suspended particulates) were analyzed. Distributions of DIN species (ammonium, nitrate + nitrite and dissolved N 2 ) in sediments and overlying water were also measured along with geochemical variables in the aquaria. Partitioning of RDX and RDX-derived breakdown products onto surface sediment represented 13% of the total added 15 N as RDX ( 15 N-[RDX]) equivalents after 21 days. Measured nitroso-triazines in the aquaria accounted for 6–13% of total added 15 N-[RDX]. 15 N-labeled DIN was found both in the oxic surface water and hypoxic porewaters, showing that RDX mineralization accounted for 34% of the 15 N-[RDX] added to the aquaria over 21 days. Labeled ammonium ( 15 NH 4 + , found in sediment and overlying water) and nitrate + nitrite ( 15 NO X , found in overlying water only) together represented 10% of the total added 15 N-[RDX]. The production of 15 N labeled N 2 ( 15 N 2 ), accounted for the largest individual sink during the transformation of the total added 15 N-[RDX] (25%). Hypoxic sediment was the most favorable zone for production of N 2 , most of which diffused through porous sediments into the water column and escaped to the atmosphere.

Science of the Total Environment↗

USGS1983

Anaerobic oxalate degradation: Widespread natural occurrence in aquatic sediments

Significant concentrations of oxalate (dissolved plus particulate) were present in sediments taken from a diversity of aquatic environments, ranging from 0.1 to 0.7 mmol/liter of sediment. These included pelagic and littoral sediments from two freshwater lakes (Searsville Lake, Calif., and Lake Tahoe, Calif.), a hypersaline, meromictic, alkaline lake (Big Soda Lake, Nev.), and a South San Francisco Bay mud flat and salt marsh. The oxalate concentration of several plant species which are potential detrital inputs to these aquatic sediments ranged from 0.1 to 5.0% (wt/wt). In experiments with litter bags, the oxalate content of Myriophyllum sp. samples buried in freshwater littoral sediments decreased to 7% of the original value in 175 days. This suggests that plant detritus is a potential source of the oxalate within these sediments. [ 14 C]oxalic acid was anaerobically degraded to 14 CO 2 in all sediment types tested, with higher rates evident in littoral sediments than in the pelagic sediments of the lakes studied. The turnover time of the added [ 14 C]oxalate was less than 1 day in Searsville Lake littoral sediments. The total sediment oxalate concentration did not vary significantly between littoral and pelagic sediments and therefore did not appear to be controlling the rate of oxalate degradation. However, depth profiles of [ 14 C]oxalate mineralization and dissolved oxalate concentration were closely correlated in freshwater littoral sediments; both were greatest in the surface sediments (0 to 5 cm) and decreased with depth. The dissolved oxalate concentration (9.1 μmol/liter of sediment) was only 3% of the total extractable oxalate (277 μmol/liter of sediment) at the sediment surface. These results suggest that anaerobic oxalate degradation is a widespread phenomenon in aquatic sediments and may be limited by the dissolved oxalate concentration within these sediments.

California, Nevada↗

USGS2023

Anthropogenic influence on groundwater geochemistry in Horn Creek Watershed near the Orphan Mine in Grand Canyon National Park, Arizona, USA

Breccia pipe deposits of the Grand Canyon region contain ore grade copper and uranium. Horn Creek is located near the Orphan Mine mineralized breccia pipe deposit and groundwater emerging from the bedrock in the headwaters of Horn Creek has the highest uranium concentrations in the region. Uranium decreases an order of magnitude between the groundwater at the top of the watershed and the groundwater emerging from the alluvial material lower in the watershed. Horn Creek water has low sulfur and uranium isotopic ratios which may suggest interaction with sulfide and uranium minerals found in mineralized breccia pipe deposits. Per- and polyfluoroalkyl substances (PFBA and PFBS) were found in low concentrations in groundwater from the bedrock and may be related to mining process materials or other anthropogenic activities. PHREEQC modeling suggests that water that is elevated in uranium emerging from the bedrock in the upper watershed may mix with other groundwater and atmospheric precipitation infiltrated into the alluvial material in the lower watershed. Tritium is elevated in Horn Creek groundwaters suggesting a component of modern water, some of which may have interacted with Orphan Mine workings. Additional studies could build on this understanding of chemistry changes in waters of Horn Creek to provide more direct evidence of contribution of water moving through the Orphan Mine.

Arizona↗

USGS2025

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California↗