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Leachate plumes in ground water from Babylon and Islip landfills, Long Island, New York

Landfills operated by the Towns of Babylon and Islip in southwest and central Suffolk County contain urban refuse, incinerated garbage, and scavenger (cesspool) waste; some industrial refuse is deposited at the Babylon site. The Islip landfill was started in 1933, the Babylon landfill in 1947. The landfills are in contact with and discharge leachate into the highly permeable upper glacial aquifer (hydraulic conducitvity 190 to 500 ft/d [feet per day]). The aquifer is 74 feet thick at the Babylon landfill and 170 feet thick at the Islip landfill. The leachate-enriched water occupies the entire thickness of the aquifer beneath both landfills, but hydrologic boundaries retard downward migration of the plumes to deeper aquifers. The Babylon plume is 1,900 feet wide at the landfill and narrows to about 700 feet near its terminus 10,000 feet from the landfill. The Islip plume is 1,400 feet wide at the landfill and narrows to 500 feet near its terminus 5,000 feet from the landfill. Hydrochemical maps and sections show the distribution of the major chemical constituents of the plumes. The most highly leachate-enriched ground water obtained was from the Babylon site; it contained 860 mg/L (milligrams per liter) sodium, 110 mg/L potassium, 565 mg/L calcium, 100 mg/L magnesium, 2,700 mg/L bicarbonate, and 1,300 mg/L chloride. Sulfate was notably absent or in low concentration in most parts of both plumes. Nitrogen in plume water was mostly in the form NH4+, and concentrations as high as 90 mg/L were found; concentrations of nitrogen as N in the plume were less than 10 mg/L. As much as 440 mg/L iron and 190 mg/L manganese were found in the leachate-enriched water. Samples were also tested for arsenic, boron, cadmium, cobalt, chromium, copper, mercury, nickel, lead, selenium, strontium, and zinc. Boron was more or less ubiquitous and was found in concentrations as high as 2 mg/L. Organic carbon was found in concentrations as high as 2,250 mg/L in the most highly leachate-enriched water but attenuated rapidly to less than 20 mg/L. Dissolved-solids concentrations near the landfills were between 400 and 3,000 mg/L at Babylon and between 500 and 1,500 mg/L at Islip. Ground-water temperatures near the landfills exceed those in ambient water by as much as 7°C at Babylon and 16°C at Islip. Heat contributed by the landfills was mostly dissipated within 0.4 mi of the landfill, butat Islip, the warm leachate-enriched water extended 0.5 mi downgradient. The entrance of leachate into the less dense ground water as pulsations after rainfall may explain the presence of high leachate enrichment near the bottom of the aquifer. A comparison of the physical characteristics of leachate-enriched ground water with those of ambient water suggests that the downward movement of leachate results from its greater density. Simulation of the movement and dispersion of the Babylon plume with a mathematical dispersion model indicated the coefficient of longitudinal dispersion to be about 60 ft 2 /d (feet squared per day) and the ground-water velocity to be 1 ft/d. However, the velocity determined from the hydraulic gradient and public-supply wells in the area was 4 ft/d, which would cause a plume four times as long as that predicted by the mathmatical dispersion model. At the Islip site, the plume was one-third the length calculated on the basis of the age of the landfill. The shortness of the plumes has not been explained; it may be a result of the leachate's having been too dilute to form a plume during the early years of the landfills.

New York

An empirical Green’s function approach for isolating directivity effects in earthquake ground-motion amplitudes

In this study, we apply an empirical Green’s function (eGf) method within a ground‐motion modeling framework to mitigate trade‐offs between source, path, and site effects. Many physical processes contribute to spatial variations in observed ground motions, including earthquake radiation pattern, directivity, variable path attenuation, and site effects. Current nonergodic ground‐motion models use spatially varying coefficients for path and site effects, but they do not address trade‐offs with complex earthquake source effects. To quantify the influence of directivity on ground‐motion amplitudes, we use records from multiple smaller earthquakes with epicenters near that of a larger event. We use these small magnitude events as eGfs and estimate repeatable path and site effects at individual stations, assuming that the average adjustments are not controlled by directivity. We adjust residuals from the larger earthquake using the eGf terms, isolating effects related to the rupture. This method clearly enhances the observed broadband directivity observed in the 2022 M 5.1 and 2007 M 5.4 Alum Rock earthquake ground motions, reinforcing the conclusion that their ruptures were unilateral. For the 2004 M 6.0 Parkfield earthquake, we find a bilateral rupture model better fits the data because variations in rupture velocity, slip rate, and slip distribution seem to have a stronger effect on the ground motions than rupture direction alone. Applying eGf adjustments reduces the standard deviation of the rupture models over the three earthquakes by 32% on average and by up to 57% for the 2022 Alum Rock earthquake, confirming we have effectively removed repeatable effects related to the wave propagation path and site response. We propose a novel measure of the frequency‐dependent directivity amplification strength as the reduction in ground‐motion residual variability gained by fitting a directivity model; for the three earthquakes considered, this parameter varies between 25% and 75%, indicating that directivity can strongly influence ground motions and should be considered in ground‐motion modeling.

California

Alteration mapping in granitic gneiss using handheld geophysical and geochemical instruments: Implications for iron oxide-apatite and rare earth elements exploration

The Adirondack Mountains of New York, U.S.A. contain iron oxide-apatite (IOA) mineral deposits with variable concentrations of rare earth elements (REE). The IOA mineral deposits are typically hosted in the Lyon Mountain Granite Gneiss and are spatially correlated with extensive Na metasomatism (albitization) of the surrounding country rocks, although some mineral deposits also occur in metagabbro, paragneiss, and anorthosite hosts. The location of albitization zones is key to finding new IOA mineral deposits and better understanding the mineralization processes associated with their genesis. However, the Na alteration zones are generally not visibly identifiable in outcrop or hand specimens because the color and textural changes are subtle and are thus difficult to map. Here, we discuss the results from testing two spectroscopic techniques (handheld, field gamma-ray spectroscopy, and portable X-ray fluorescence (pXRF)) to characterize albitization zones surrounding IOA mineral deposits. The gamma-ray and pXRF spectrometers successfully distinguished the relative intensity of alteration in the Lyon Mountain Granite Gneiss based on the K abundance. The measured K content decreases towards the IOA mineral deposits, and the magnitude and width of the gradient are similar along the strike of each mineral deposit. Elevated Th and U values are present in host rocks adjacent to REE-bearing IOA mineral deposits. The pXRF and gamma-ray spectrometer K values are remarkably consistent with laboratory-based, whole-rock XRF compositional data and, therefore, useful for semi-quantitative analysis. Notably, albitization aureoles are consistent around REE-rich and REE-poor mineral deposits, suggesting that saline fluids are essential for the petrogenesis of IOA mineral deposits but may not be critical to REE mineralization. Ultimately, this study demonstrates the utility of handheld gamma-ray and pXRF spectrometry for identifying otherwise cryptic albitization gradients associated with IOA mineral deposits in granitic gneiss.

New York

The 2025 Puerto Rico and Virgin Islands U.S. National Seismic Hazard Model Update: Ground motion model selection and comparison

We evaluate, select, and describe the ground-motion models (GMMs) used in the 2025 update of the U.S. National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI). We identify the most appropriate models that align with GMM selection criteria for use in the PRVI region to improve the accuracy of seismic hazard assessments. The update incorporates globally applicable GMMs suited for the active crustal and subduction earthquakes in the region. We include region-specific adjustments to these GMMs derived from local site response analyses derived from ground motion records. The unadjusted and regionally-corrected GMMs are combined to create a robust model for predicting median ground motion. The model integrates epistemic uncertainty through a median ground motion logic tree that accounts for variations in magnitude and distance. This study compares the GMMs selected for the 2025 PRVI NSHM, including both as-provided and regionally adjusted NGA-West2 and NGA-Subduction models, with those used in the 2003 PRVI NSHM. We evaluate how changes in model selection, weighting, aleatory variability, and epistemic uncertainty influence seismic hazard estimates. Trends with distance, magnitude, and spectral period are analyzed to evaluate how the scaling behavior of the newer GMMs differs from that of earlier models. Relative to the GMMs used in the 2003 NSHM for this region, the 2025 models generally predict lower ground motions. Comparisons with additional GMMs indicate that the adjustments applied for PRVI are consistent with regional-specific modifications developed elsewhere globally. The increase in aleatory variability and epistemic uncertainty in the 2025 update results in a notable increase in hazard levels from these wider uncertainty bounds. These changes can result in as much as a 10%–20% variation in probabilistic ground motion at the 2% in 50 years exceedance level for hazard maps computed across the region for representative site classes and periods.

Puerto Rico, Virgin Islands

Water-quality study of a reach of the Merced River in Yosemite National Park and vicinity, California, April 1973 through September 1974

A 25-mile (40-kilometre) reach of the Merced River was studied to provide the National Park Service with water-quality data prior to the operation of a new sewage-treatment plant. Data were collected periodically at four Merced River and two inflow stations. Discharge varied seasonally with highest flow occurring at the time of spring snowmelt runoff. Lowest flow occurred during late summer, coinciding with high park visitor use and elevated water temperature. Water-quality variables investigated were discharge, temperature, major chemical constituents, selected trace metals, specific conductance, suspended sediment, turbidity, dissolved oxygen, pH, alkalinity, carbon dioxide, total organic carbon, nitrogen, phosphorus, algal growth potential, coliform bacteria, periphyton, and benthic invertebrates. Diel measurements were made at some stations to delineate daily fluctuations in selected water-quality variables. Results indicate that water in the reach of the Merced River studied was of good quality. The river had low concentrations of dissolved solids (8 to 41 milligrams per litre) and low alkalinity values (2 to 24 milligrams per litre of alkalinity as CaCO 3 ). Mean concentrations of nitrogen and phosphorus were highest in the Merced River at Rancheria Flat. Algal growth potential tests showed that phosphorus was limiting algal growth at Happy Isles Bridge, El Capitan Bridge, and South Fork Merced River, whereas nitrogen was limiting growth at Rancheria Flat. Input of excessive nitrogen and phosphorus concentrations in the Merced River during the summer low-flow period, and mixing with warm tributary inflow could cause excessive algal growth and production. The algal types found were diatoms, green algae, and blue-green algae. Biomass/chlorophyll a ratios in the Merced River were low (0.3 to 7.7). Benthic invertebrates consisted chiefly of Diptera, Ephemeroptera, and Plecoptera.

California

Methods to evaluate and improve the modeling of rupture directivity in assessment of seismic hazard

In recent years, there have been several advancements related to the modelling of near-source effects of earthquake rupture on strong ground shaking, leading to an improved characterization of ground motions and resulting seismic hazard. Some of these modifications have stemmed from physics-based numerical modelling of the earthquake rupture process, using physics-based dynamic rupture simulations. These contributions have led to a better understanding of how fault rupture characteristics, geometry, and the style of faulting can interact with the hypocenter-dependence on the path from source to site that may ultimately guide the development of seismic directivity models. Moving forward, the application of modern techniques can be used to incorporate these source characteristics and near-fault ground motion behavior that contribute to the azimuthally varying effects that result in rupture directivity. One example is the application of machine learning methods to support more automated integration of new predictor variables in model development and open more evaluation opportunities to access residuals. Here, we utilize several techniques to take advantage of the plethora of synthetic data and its ability to supplement preexisting trends observed in data. We showcase two examples of how models can be either developed, expanded upon, or constrained using artificial neural network model (ANNs). We evaluate the performance of the ANN with existing methods, comparing misfit, potential limitations, and ability to continue to improve upon these methods in the future. One approach uses a set of simulations with corresponding synthetic ground motions from the Southern California Earthquake Center (SCEC) CyberShake study to develop a ground motion model adapted to incorporate seismic directivity information using an ANN. This large database (TBs) enables us to train the model to capture magnitude, period, and distance variations and how these parameters relate to amplification from hypocenters located along finite-faults. In some cases, there is reduced misfit from better representing source features that aren’t included in base ground motion models that neglect hypocenter location (e.g. azimuthal variation, source-to-site terms). Another ANN method uses a shallow-layered neural network model to better fit a hypocenter-independent model. This method adjusts the median and aleatory variability to account for the averaged impact of various hypocenter distributions to fit the underlying directivity adjustment model. This method serves as a template to apply to other directivity models, improving computational efficiency and more readily enabling integration in hazard codes.

California

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota

Induced earthquakes are generally not tidally triggered in Oklahoma and Kansas

Human-induced earthquakes occur along critically stressed faults as injected wastewater simultaneously heightens fluid pressure and pushes faults to failure. We investigate the possibility that small stresses imposed by Earth tides could trigger earthquakes in the induced seismicity region of Oklahoma and Kansas from 2011 to 2018. We decluster a catalog consisting of ∼110,000 earthquakes using three methods (Reasenberg, nearest-neighbor distance, and phase-bin). We find no significant tidal earthquake triggering using Schuster's p -value test for the declustered catalogs as a whole. We search for localized triggering using discretized space-time cells and find ∼0–6% of cells have significant tidal triggering which is close to what is randomly expected (5%) and indicates there is an insignificant amount of tidal triggering for the full study region. One area that has significant p -values across multiple time windows, ∼2014–2016 is ∼15 km from a region of large wastewater injection volume. It is possible that localized tidal triggering occurs for this time and area because faults remain critically stressed and are particularly susceptible to slip under the small stress load from the semidiurnal tide. Possible explanations for the lack of tidal triggering in our broader study are that the pre-seismic stressing rate in the earthquake nucleation area is faster than the tidal stressing rate (∼3 kPa/day), faults are not close enough to critically stressed to be affected by tidal forcing, and that nucleation occurs over longer periods than the tides considered in this study (∼1, ∼14 days). Fluid injection could be the source of a higher pre-seismic stress rate.

Kansas, Oklahoma

From collision to subduction: Thermal-kinematic inversions constrain plate boundary structure and dip-slip activity in southwestern New Zealand

Constraints on three-dimensional fault system geometry and kinematics are required to understand both long-term tectonics and contemporary seismic hazard. In many cases, these parameters must be inferred from a combination of different data or analyses. Here, we invert low-temperature thermochronological data to quantitatively parameterize both the crustal-scale geometry and late Cenozoic dip-slip activity of the plate boundary system in southwest New Zealand. We find that the modern transpressive plate boundary system has accommodated the bulk of Australian-Pacific Plate convergence since establishment in the middle Miocene-early Pliocene. Shortening has occurred via (a) dextral-reverse slip on the moderate angle, listric central Alpine Fault décollement, and (b) reverse-slip on either the sharply curved, anti-listric northern Puysegur subduction interface or low-angle offshore thrust fault system that splays from the high-angle southern Alpine Fault at depth. We resolve late Cenozoic shortening rates on these structures that are indistinguishable, and interpret these to reflect the transfer of convergent deformation outboard of the predominantly strike-slip southern Alpine Fault. Our work helps elucidate the transition from strain localized oblique continental collision to strain partitioned subduction. We also provide an estimate of the across-strike width of the central-southern Alpine Fault section boundary at seismogenic depths. This is the first quantitative constraint on the geometry of a structural feature inferred to have arrested several major prehistoric earthquakes. This study furthers understanding of fault structure and dip-slip kinematics along the greatest sources of seismic hazard in and offshore of southwest New Zealand.

South Island

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 3 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 3, the subject of this scientific investigations map, has a mapped area of 185 km 2 and has water depths that range from about 30 meters (m) on the Stellwagen Bank crest to about 135 m in a basin east of South Ninety Bank, which lies off the eastern margin of Stellwagen Bank. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the southeastern part of Stellwagen Bank, on adjacent banks and basins in deeper water to the east, in the eastern part of Race Point Channel to the south of the bank, and on the northern slope of Cape Cod. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 309 stations were analyzed, including 279 sediment samples. The geologic substrate maps of quadrangle 3 show the distribution of 21 geologic substrates that represent a wide range of textures, such as rippled sand, immobile sand, immobile muddy sand, sand that partially veneers gravel, and boulder ridges. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 3. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that use the various substrates, and support seabed management in the region.

Quadrangle 3 of the Stellwagen Bank National Marin

Evaluation of submersible pressure transducers for streamflow monitoring in small streams

Compact streamgages requiring minimal infrastructure and equipped with submersible pressure transducers (PTs) are increasingly used to monitor small streams, yet disparate implementations obscure their accuracy under real-world conditions. This study isolated instrumentation-derived uncertainty in stage monitoring by co-locating various combinations of commercial vented and unvented PTs with seven U.S. Geological Survey (USGS) reference streamgages on small streams. Multi-year PT stage records from compact streamgages, collected and corrected following USGS protocols, were compared to concurrent reference observations. Vented PTs demonstrated an average measurement uncertainty of ±0.005 m and mean absolute percent error (MAPE) of ±0.2%. Unvented PTs exhibited higher uncertainty, averaging ±0.009 m and ±0.4% MAPE. Although both sensor types had stage errors up to ±0.3 m, 95% of vented PT and unvented PT observations were within 0.01 and 0.02 m of reference stage, respectively. Analysis of additional unvented PTs revealed stage errors of up to ±1.2% when using barometric sensors within 15 km of the in-water sensor. Propagation of stage error to discharge using reference rating models resulted in cumulative discharge MAPEs of ±4.5% for vented and ±5.5% for unvented PTs. These findings highlight PTs as practical alternatives to reference instrumentation when deployed with standardized procedures, potentially expanding access to reliable streamflow data.

conterminous United States

Multi-scale geophysical imaging of a hydrothermal system in Yellowstone National Park, USA

Little is known about the local plumbing systems that fuel Yellowstone’s famous hot springs, geysers and mud pots. A multi-method, multi-scale geophysical investigation was carried out in the Obsidian Pool Thermal Area (OPTA) to: (i) delineate the lateral extent of the hydrothermal area and associated surface features; (ii) estimate the dimensions of the upflow zone and identify its main controlling structures; (iii) assess fluids circulation pathways from depth to surface. Ground and airborne geophysical data were acquired to connect local and regional scales, from shallow to large depths. Maps of surface electrical resistivity show a strong correlation with hydrothermal features. At in-termediate depths, electrical resistivity permits delineating the upper limit of the upflow zone, while Poisson’s ratio highlights differences in subsurface fluid content. Combining these results with surface observations and topographic information, we speculate that differential mixing of hydrothermal and fresh water could explain the wide diversity of features observed at OPTA. Low electrical resistivity observed at large depths also suggest that a vast upflow zone, controlled by rhyolite flows and conjugate faults, underlies the OPTA. We speculate that hydrothermal fluids rise along fractures and reach the surface in topographic lows to form hydrothermal features. Our results show that synoptic, multi-scale geophysical measurements provide a roadmap for understanding where and how geologic heterogeneity, topography, fluid-gas separation, and the mixing of thermal and meteoric waters conspire to produce the wide variety of Yellowstone’s renowned hydrothermal features.

Wyoming

From landslide susceptibility to risk assessment in the conterminous U.S.

Understanding the spatial distribution of landslide prone-areas and what consequences they may have is important for risk management and land-use planning. In the United States, although landslides occur in every state, a comprehensive landslide risk assessment is still missing. Existing efforts, such as the Federal Emergency Management Agency (FEMA)’s National Risk Index, rely on aggregated products and coarse cartographic units, limiting their geomorphological and practical accuracy. In this study, we present a methodological advance for landslide risk assessment across large areas with incomplete and sparse data. We apply our procedures to the conterminous United States by integrating geomorphologically meaningful partitions and spatial and temporal probability data-driven models. Landslide susceptibility is estimated using a Generalized Additive Mixed Model incorporating a bias capture/correction scheme to account for inventory inaccuracies (reference Area Under the Curve = 0.75). The exceedance probabilities of landslide occurrence are defined for three temporal scenarios (2, 5, and 10 year). Then, we explore the associated potential economic consequences for human settlements and agricultural areas. The findings indicate that the spatial variability of risk is primarily controlled by exposure rather than by susceptibility/hazard alone. The mean risk increases by ∼170% from the 2-year to the 10-year scenario. Beyond its quantitative outcomes, this study offers a blueprint for continental or sub-continental scale landslide risk assessments, demonstrating both the opportunities and current limitations.

Engineering Geology

Abandonment of the Upper Devonian Greenland Gap Group and Scherr Formation and revision of the Upper Devonian Brallier and Foreknobs Formations in the central Valley and Ridge Province

This study revises the lithostratigraphic framework of the Upper Devonian interval traditionally assigned to the Greenland Gap Group across the central Appalachian Valley and Ridge Province. The work aims to modernize and standardize lithostratigraphic nomenclature, establish a new reference section and demonstrate how the revised stratigraphy improves edge-matching of 1:24,000 scale geologic maps and supports compilation mapping at scales of 1:100,000 and larger. The revision eliminates the names Greenland Gap Group, Scherr Formation and the Minnehaha Springs Member of the Scherr Formation; reassigns all strata previously designated as Scherr Formation by Dennison (1970) to the upper Brallier Formation; and abandons the basal Mallow Member of the Foreknobs Formation, placing its strata within the upper Brallier as originally defined by Butts (1918). The contact between the Brallier and Foreknobs formations is placed at the base of the first mappable, ridge-forming package of fine- to coarse-grained, cross-bedded, sandstone beds, often containing rounded quartz pebbles with minor interbeds of shale and siltstone. This contact may be gradational in places but, even in absence of good exposure, can usually be distinguished topographically in recently produced lidar-derived imagery as having elevated relief due to the presence of more resistant, compositionally mature coarse-grained sandstone-rich strata. Applying this criterion for mapping the contact between the Brallier and Foreknobs formations has resulted in reconciliation of mismatches of geologic contacts along several 7.5-minute quadrangle boundaries in the states of Virginia, West Virginia, Maryland and Pennsylvania. A new reference section at Baker, West Virginia showcases the contacts between the Harrell Shale, Brallier Formation, Foreknobs Formation and Hampshire Formation. A digital outcrop model of the reference section is provided for future preservation.

Maryland, Pennsylvania, Virginia, West Virginia

Groundwater, surface-water, and water-chemistry data, Black Mesa area, northeastern Arizona—2019–2021

The Navajo (N) aquifer is an extensive aquifer and the primary source of groundwater in the 5,400-square-mile Black Mesa area in northeastern Arizona. Water availability is an important issue in the Black Mesa area because of the arid climate, past industrial water use, and continued water requirements for municipal use by a growing population. Precipitation in the area typically ranges from less than 6 to more than 16 inches per year, depending on location. The U.S. Geological Survey water-monitoring program in the Black Mesa area began in 1971 and provides information about the long-term effects of groundwater withdrawals from the N aquifer for industrial and municipal uses. This report presents the results of data collected as part of the monitoring program in the Black Mesa area from calendar years 2020–2021 and, additionally, uses streamflow statistics from November and December 2019. The monitoring program includes measurements of (1) groundwater withdrawals (pumping), (2) groundwater levels, (3) spring discharge, (4) surface-water discharge, and (5) groundwater chemistry. In calendar year 2020, total groundwater withdrawals were estimated to be 2,680 acre-feet (acre-ft), and, in 2021, total withdrawals were estimated to be 2,570 acre-ft. Total withdrawals during 2021 were about 65 percent less than total withdrawals in 2005 because the Peabody Western Coal Company discontinued its use of water to transport coal in a coal slurry pipeline after 2005 and ceased mining operations in 2019. Owing to Navajo Nation and Hopi Reservation access restrictions during the Coronavirus pandemic, water levels were not collected from municipal wells in 2020 or 2021. Water levels measured in 2021 from wells completed in the unconfined areas of the N aquifer within the Black Mesa area showed a decline in 7 of 13 wells when compared with water levels from the prestress period (prior to 1965). The changes in water levels across all 13 wells ranged from +8.4 feet (ft) to −42.4 ft, and the median change was −0.4 ft. Water levels also showed decline in 11 of 12 wells measured in the confined area of the aquifer when compared to the prestress period. The median change for the confined area of the aquifer was −25.9 ft, with changes across all 12 wells ranging from +17.3 ft to −133.7 ft. Spring flow was measured at four springs between 2020 and 2021. Flow fluctuated during the period of record for Burro Spring and Pasture Canyon Spring, but a decreasing trend was statistically significant (p<0.05) at Moenkopi School Spring and Unnamed Spring near Dennehotso, Arizona. Discharge at Burro Spring has remained relatively constant since it was first measured in the 1980s, and discharge at Pasture Canyon Spring has fluctuated for the period of record. Continuous records of surface-water discharge in the Black Mesa area were collected from streamflow-gaging stations at the following sites: Moenkopi Wash at Moenkopi 09401260 (1976–2021), Dinnebito Wash near Sand Springs 09401110 (1993–2020), Polacca Wash near Second Mesa 09400568 (1994–2020), and Pasture Canyon Springs 09401265 (2004–2021). Median winter flows (November through February) of each winter were used as an estimate of the amount of groundwater discharge at the above-named sites. For the period of record, the median winter flows have generally remained constant at Polacca Wash and Pasture Canyon Springs, whereas a decreasing trend was observed at Moenkopi Wash and Dinnebito Wash. In 2020 and 2021, water samples were collected from a total of four springs in the Black Mesa area and analyzed for selected chemical constituents. Results from the four springs were compared with previous analyses from the same springs. Dissolved solids, chloride, and sulfate concentrations increased at Moenkopi School Spring during the more than 30 years of record at that site. Concentrations of dissolved solids and sulfate at Pasture Canyon Spring have not varied significantly (p>0.05) since the early 1980s, and there is no increasing or decreasing trend in those data. However, concentrations of chloride from Pasture Canyon Spring show a diminishing trend. Concentrations of dissolved solids, chloride, and sulfate at Unnamed Spring near Dennehotso have varied for the period of record, but there is no statistical trend in the data. Concentrations of dissolved solids at Burro Spring have varied for the period of record, but there is no statistical trend in the data. However, concentrations of chloride and sulfate from Burro Spring show a trend towards lower concentrations.

Arizona

Structural analysis of brittle-plastic shear zones in the Sangre de Cristo Range, southern Colorado USA: Superposition of Rio Grande rift extension on Laramide contraction

The Sangre de Cristo Range in southern Colorado exposes some of the deepest Cenozoic structural levels in the Rocky Mountain region, including mylonitic shear zones associated with both the Laramide orogeny and Rio Grande rift. We investigated the relation between Laramide contraction and Rio Grande rift extension with detailed geologic mapping, kinematic analysis, and geochronometry in a 50 km 2 area centered on the Independence Mine shear zone (IMSZ). The 15−100-m-thick IMSZ is one of several shallowly to moderately (∼45° ± 20°) W-SW−dipping brittle-plastic shear zones along the western flank of the range. These shear zones display microstructural evidence of initiation as top-NE contractional mylonite zones, consistent with regional Laramide kinematics, which have been pervasively overprinted by shear fabrics indicating top-SW extensional reactivation. Both top-NE and top-SW shear fabrics involve cataclasis and quartz dislocation creep, although top-SW shear is more commonly localized along phyllosilicate-lined shear bands. Shear zones are hosted predominately within Proterozoic gneiss, and contain abundant chlorite and white mica derived from alteration of hornblende and feldspar, which indicates that weakening driven by fluid reactions played an important role in localizing strain. Extensional overprinting appears to be most pervasive along more steeply dipping portions of shear zones and where secondary phyllosilicates form an interconnected weak phase, which suggests that reactivation was primarily controlled by geometry and rheological contrasts inherited from contraction. One top-SW shear zone adjacent to the IMSZ cuts a late Oligocene gabbro stock, and monazite grains synkinematic with top-SW shear in the IMSZ yielded late Oligocene to Early Miocene U-Th-Pb dates that correspond with initiation of the Rio Grande rift. Reactivation of weak reverse faults may represent an important structural control during initial extension in the middle crust, prior to slip along the high-angle Sangre de Cristo normal fault system.

Colorado

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Methods for estimating the magnitude and frequency of peak discharges of rural, unregulated streams in Virginia

Methods are presented for estimating the peak discharges of rural, unregulated streams in Virginia. A Pearson Type III distribution is fitted to the logarithms of the unregulated annual peak-discharge records from 363 stream-gaging stations in Virginia to estimate the peak discharge at these stations for recurrence intervals of 2 to 500 years. Peak-discharge characteristics for 284 unregulated stations are divided into eight regions based on physiographic province, and regressed on basin characteristics, including drainage area, main channel length, main channel slope, mean basin elevation, percentage of forest cover, mean annual precipitation, and maximum rainfall intensity. Regression equations for each region are computed by use of the generalized least-squares method, which accounts for spatial and temporal correlation between nearby gaging stations. This regression technique weights the significance of each station to the regional equation based on the length of records collected at each cation, the correlation between annual peak discharges among the stations, and the standard deviation of the annual peak discharge for each station. Drainage area proved to be the only significant explanatory variable in four regions, while other regions have as many as three significant variables. Standard errors of the regression equations range from 30 to 80 percent. Alternate equations using drainage area only are provided for the five regions with more than one significant explanatory variable. Methods and sample computations are provided to estimate peak discharges at gaged and engaged sites in Virginia for recurrence intervals of 2, 5, 10, 25, 50, 100, 200, and 500 years, and to adjust the regression estimates for sites on gaged streams where nearby gaging-station records are available.

Virginia