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Methods to quantify seepage beneath Levee 30, Miami-Dade County, Florida

A two-dimensional, cross-sectional, finite-difference, ground-water flow model and a simple application of Darcy?s law were used to quantify ground-water flow (from a wetlands) beneath Levee 30 in Miami-Dade County, Florida. Geologic and geophysical data, vertical seepage data from the wetlands, canal discharge data, ground-water-level data, and surface-water-stage data collected during 1995 and 1996 were used as boundary conditions and calibration data for the ground-water flow model and as input for the analytical model. Vertical seepage data indicated that water from the wetlands infiltrated the subsurface, near Levee 30, at rates ranging from 0.033 to 0.266 foot per day when the gates at the control structures along Levee 30 canal were closed. During the same period, stage differences between the wetlands (Water Conservation Area 3B) and Levee 30 canal ranged from 0.11 to 1.27 feet. A layer of low-permeability limestone, located 7 to 10 feet below land surface, restricts vertical flow between the surface water in the wetlands and the ground water. Based on measured water-level data, ground-water flow appears to be generally horizontal, except in the direct vicinity of the canal. The increase in discharge rate along a 2-mile reach of the Levee 30 canal ranged from 9 to 30 cubic feet per second per mile and can be attributed primarily to ground-water inflow. Flow rates in Levee 30 canal were greatest when the gates at the control structures were open. The ground-water flow model data were compared with the measured ground-water heads and vertical seepage from the wetlands. Estimating the horizontal ground-water flow rate beneath Levee 30 was difficult owing to the uncertainty in the horizontal hydraulic conductivity of the main flow zone of the Biscayne aquifer. Measurements of ground-water flows into Levee 30 canal, a substantial component of the water budget, were also uncertain, which lessened the ability to validate the model results. Because of vertical flows near Levee 30 canal and a very low hydraulic gradient east of the canal, a simplified Darcian approach simulated with the ground-water flow model does not accurately estimate the horizontal ground-water flow rate. Horizontal ground-water flow rates simulated with the ground-water flow model (for a 60-foot-deep by 1-foot-wide section of the Biscayne aquifer) ranged from 150 to 450 cubic feet per day west of Levee 30 and from 15 to 170 cubic feet per day east of Levee 30 canal. Vertical seepage from the wetlands, within 500 feet of Levee 30, generally accounted for 10 to 15 percent of the total horizontal flow beneath the levee. Simulated horizontal ground-water flow was highest during the wet season and when the gates at the control structures were open.

Florida↗

Pesticide toxicity index for freshwater aquatic organisms

The U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program is designed to assess current water-quality conditions, changes in water quality over time, and the effects of natural and human factors on water quality for the Nation's streams and ground-water resources. For streams, one of the most difficult parts of the assessment is to link chemical conditions to effects on aquatic biota, particularly for pesticides, which tend to occur in streams as complex mixtures with strong seasonal patterns. A Pesticide Toxicity Index (PTI) was developed that combines pesticide exposure of aquatic biota (measured concentrations of pesticides in stream water) with toxicity estimates (standard endpoints from laboratory bioassays) to produce a single index value for a sample or site. The development of the PTI was limited to pesticide compounds routinely measured in NAWQA studies and to toxicity data readily available from existing databases. Qualifying toxicity data were found for one or more types of test organisms for 75 of the 83 pesticide compounds measured in NAWQA samples, but with a wide range of bioassays per compound (1 to 65). There were a total of 2,824 bioassays for the 75 compounds, including 287 48-hour EC50 values (concentration at which 50 percent of test organisms exhibit a nonlethal response) for freshwater cladocerans, 585 96-hour LC50 values (concentration lethal to 50 percent of test organisms) for freshwater benthic invertebrates, and 1,952 96-hour LC50 values for freshwater fish. The PTI for a particular sample is the sum of toxicity quotients (measured concentration divided by the median toxicity concentration from bioassays) for each detected pesticide. The PTI can be calculated for specific groups of pesticides and for specific taxonomic groups.While the PTI does not determine whether water in a sample is toxic, its values can be used to rank or compare the toxicity of samples or sites on a relative basis for use in further analysis or additional assessments. The PTI approach may be useful as a basis for comparing the potential significance of pesticides in different streams on a common basis, for evaluating relations between pesticide exposure and observed biological conditions, and for prioritizing where further studies are most needed.

Water-Resources Investigations Report↗

Statewide water-quality network for Massachusetts

A water-quality monitoring program is proposed that would provide data to meet multiple information needs of Massachusetts agencies and other users concerned with the condition of the State's water resources. The program was designed by the U.S. Geological Survey and the Massachusetts Department of Environmental Protection, Division of Watershed Management, with input from many organizations involved in water-quality monitoring in the State, and focuses on inland surface waters (streams and lakes). The proposed monitoring program consists of several components, or tiers, which are defined in terms of specific monitoring objectives, and is intended to complement the Massachusetts Watershed Initiative (MWI) basin assessments. Several components were developed using the Neponset River Basin in eastern Massachusetts as a pilot area, or otherwise make use of data from and sampling approaches used in that basin as part of a MWI pilot assessment in 1994. To guide development of the monitoring program, reviews were conducted of general principles of network design, including monitoring objectives and approaches, and of ongoing monitoring activities of Massachusetts State agencies.Network tiers described in this report are primarily (1) a statewide, basin-based assessment of existing surface-water-quality conditions, and (2) a fixed-station network for determining contaminant loads carried by major rivers. Other components, including (3) targeted programs for hot-spot monitoring and other objectives, and (4) compliance monitoring, also are discussed. Monitoring programs for the development of Total Maximum Daily Loads for specific water bodies, which would constitute another tier of the network, are being developed separately and are not described in this report. The basin-based assessment of existing conditions is designed to provide information on the status of surface waters with respect to State water-quality standards and designated uses in accordance with the reporting requirements [Section 305(b)] of the Clean Water Act (CWA). Geographic Information System (GIS)-based procedures were developed to inventory streams and lakes in a basin for these purposes. Several monitoring approaches for this tier and their associated resource requirements were investigated. Analysis of the Neponset Basin for this purpose demonstrated that the large number of sites needed in order for all the small streams in a basin to be sampled (about half of stream miles in the basin were headwater or first-order streams) pose substantial resource-based problems for a comprehensive assessment of existing conditions. The many lakes pose similar problems. Thus, a design is presented in which probabilistic monitoring of small streams is combined with deterministic or targeted monitoring of large streams and lakes to meet CWA requirements and to provide data for other information needs of Massachusetts regulatory agencies and MWI teams.The fixed-station network is designed to permit the determination of contaminant loads carried by the State's major rivers to sensitive inland and coastal receiving waters and across State boundaries. Sampling at 19 proposed sites in 17 of the 27 major basins in Massachusetts would provide information on contaminant loads from 67 percent of the total land area of the State; unsampled areas are primarily coastal areas drained by many small streams that would be impossible to sample within realistic resource limitations. Strategies for hot-spot monitoring, a targeted monitoring program focused on identifying contaminant sources, are described with reference to an analysis of the bacteria sampling program of the 1994 Neponset Basin assessment. Finally, major discharge sites permitted under the National Pollutant Discharge Elimination System (NPDES) were evaluated as a basis for ambient water-quality monitoring. The discharge sites are well distributed geographically among basins, but are primarily on large rivers (two-thirds or more

Water-Resources Investigations Report↗

Hydrogeology and ground-water quality of the county road a disposal site on the Bad River Indian Reservation, Ashland County, Wisconsin: 1997-98

The County Road A disposal site, located on the Bad River Indian Reservation, Ashland County, Wisconsin, contains papermill sludge generated by a former mill in the City of Ashland. Since the time of disposal (1968-1970) the site has been the subject of investigations by the U.S. Bureau of Indian Affairs, the U.S. Environmental Protection Agency, and private consultants. During 1997- 1998, an investigation was conducted by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the Natural Resources Department of the Bad River Indian Tribe, to evaluate the hydrogeology and groundwater quality of the disposal site, particularly with respect to the hydraulic connection between two ponds at the site and the shallow ground-waterflow system. Additional monitoring wells and well points were installed, and additional hydrogeologic, ground-water quality, and geophysical data were collected. The data from this and previous studies were integrated and interpreted.

Wisconsin↗

Surface-geophysical characterization of ground-water systems of the Caloosahatchee River basin, southern Florida

The Caloosahatchee River Basin, located in southwestern Florida, includes about 1,200 square miles of land. The Caloosahatchee River receives water from Lake Okeechobee, runoff from the watershed, and seepage from the underlying ground-water systems; the river loses water through drainage to the Gulf of Mexico and withdrawals for public-water supply and agricultural and natural needs. Water-use demands in the Caloosahatchee River Basin have increased dramatically, and the Caloosahatchee could be further stressed if river water is used to accommodate restoration of the Everglades. Water managers and planners need to know how much water will be used within the river basin and how much water is contributed by Lake Okeechobee, runoff, and ground water. In this study, marine seismic-reflection and ground-penetrating radar techniques were used as a means to evaluate the potential for flow between the river and ground-water systems. Seven test coreholes were drilled to calibrate lithostratigraphic units, their stratal geometries, and estimated hydraulic conductivities to surface-geophysical profiles. A continuous marine seismic-reflection survey was conducted over the entire length of the Caloosahatchee River and extending into San Carlos Bay. Lithostratigraphic units that intersect the river bottom and their characteristic stratal geometries were identified. Results show that subhorizontal reflections assigned to the Tamiami Formation intersect the river bottom between Moore Haven and about 9 miles westward. Oblique and sigmoidal progradational reflections assigned to the upper Peace River Formation probably crop out at the floor of the river in the Ortona area between the western side of Lake Hicpochee and La Belle. These reflections image a regional-scale progradational deltaic depositional system containing quartz sands with low to moderate estimated hydraulic conductivities. In an approximate 6-mile length of the river between La Belle and Franklin Lock, deeper karstic collapse structures are postulated. These structures influence the geometries of parallel reflections that intersect the river channel. Here, reflections assigned to the Buckingham Limestone Member of the Tamiami Formation (a confining unit) and reflections assigned to the clastic zone of the sandstone aquifer likely crop out at the river bottom. Beneath these shallow reflections, relatively higher amplitude parallel reflections of the carbonate zone of the sandstone aquifer are well displayed in the seismic-reflection profiles. In San Carlos Bay, oblique progradational reflections assigned to the upper Peace River Formation are shown beneath the bay. Almost everywhere beneath the river, a diffuse ground-water flow system is in contact with the channel bottom. Ground-penetrating radar profiles of an area about 2 miles north of the depositional axis of the deltaic depositional system in the Ortona area show that progradational clinoforms imaged on seismic reflection profiles in the Caloosahatchee River are present within about 17 feet of the ground surface. Ground-penetrating radar profiles show southward dipping, oblique progradational reflections assigned to the upper Peace River Formation that are terminated at their tops by a toplapping or erosional discontinuity. These clinoformal reflections image clean quartz sand that is probably characterized by moderate hydraulic conductivity. This sand could be mapped using ground-penetrating radar methods.

Water-Resources Investigations Report↗

Sediment deposition and trends and transport of phosphorus and other chemical constituents, Cheney Reservoir watershed, south-central Kansas

Sediment deposition, water-quality trends, and mass transport of phosphorus, nitrogen, selected trace elements, and selected pesticides within the Cheney Reservoir watershed in south-central Kansas were investigated using bathymetric survey data and reservoir bottom-sediment cores. Sediment loads in the reservoir were investigated by comparing 1964 topographic data to 1998 bathymetric survey data. Approximately 7,100 acre-feet of sediment deposition occurred in Cheney Reservoir from 1965 through 1998. As of 1998, sediment had filled 27 percent of the reservoir's inactive conservation storage pool, which is less than the design estimate of 34 percent. Mean annual sediment deposition was 209 acre-feet per year, or 0.22 acre-feet per year per square mile, and the mean annual sediment load was 453 million pounds per year. During the 3-year period from 1997 through 1999, 23 sediment cores were collected from the reservoir, and subsamples were analyzed for nutrients (phosphorus and nitrogen species), selected trace elements, and selected organic pesticides. Mean concentrations of total phosphorus in reservoir bottom sediment ranged from 94 milligrams per kilogram at the upstream end of the reservoir to 710 milligrams per kilogram farther downstream near the reservoir dam. The mean concentration for all sites was 480 milligrams per kilogram. Total phosphorus concentrations were greatest when more silt- and clay-sized particles were present. The implications are that if anoxic conditions (inadequate oxygen) occur near the dam, phosphorus could be released from the sediment and affect the drinking-water supply. Analysis of selected cores also indicates that total phosphorus concentrations in the reservoir sediment increased over time and were probably the result of nonpoint-source activities in the watershed, such as increased fertilizer use and livestock production. Mean annual phosphorus loading to Cheney Reservoir was estimated to be 226,000 pounds per year on the basis of calculations from deposited sediment in the reservoir. Mean total phosphorus concentration in the surface-water inflow to Cheney Reservoir was 0.76 milligram per liter, mean annual phosphorus yield of the watershed was estimated to be 0.38 pound per year per acre, and both are based on sediment deposition in the reservoir. A comparison of the Cheney Reservoir watershed to the Webster Reservoir, Tuttle Creek Lake, and Hillsdale Lake watersheds showed that phosphorus yields were smallest in the Webster Reservoir watershed where precipitation was less than in the other watersheds. Mean concentrations of total ammonia plus organic nitrogen in bottom sediment from Cheney Reservoir ranged from 1,200 to 2,400 milligrams per kilogram as nitrogen. A regression analysis between total ammonia plus organic nitrogen as nitrogen and sediment particle size showed a strong relation between the two variables and suggests, as with phosphorus, that total ammonia plus organic nitrogen as nitrogen adsorbs to the silt- and clay-sized particles that are transported to the deeper parts of the reservoir. An analysis of trends with depth of total ammonia plus organic nitrogen as nitrogen did not indicate a strong relation between the two variables despite the increase in fertilizer use in the watershed during the past 40 years. Selected cores were analyzed for trace elements. Concentrations of arsenic, chromium, copper, and nickel at many sites exceeded levels where adverse effects on aquatic organisms sometimes occur. Larger concentrations of these elements also occurred in sediment closer to the reservoir dam where there is a larger percentage of silt and clay in the bottom sediment than farther upstream. However, the lack of industrial or commercial land use in the watershed suggests that these concentrations may be the result of natural conditions. Organochlorine insecticides were detected in the reservoir-bottom sediment in Cheney Reservoir. DDT and its degradation products DDD and DD

Water-Resources Investigations Report↗

Statistical summary of selected physical, chemical, and toxicity characteristics and estimates of annual constituent loads in urban stormwater, Maricopa County, Arizona

Stormwater and streamflow in Maricopa County were monitored to (1) describe the physical, chemical, and toxicity characteristics of stormwater from areas having different land uses, (2) describe the physical, chemical, and toxicity characteristics of streamflow from areas that receive urban stormwater, and (3) estimate constituent loads in stormwater. Urban stormwater and streamflow had similar ranges in most constituent concentrations. The mean concentration of dissolved solids in urban stormwater was lower than in streamflow from the Salt River and Indian Bend Wash. Urban stormwater, however, had a greater chemical oxygen demand and higher concentrations of most nutrients. Mean seasonal loads and mean annual loads of 11 constituents and volumes of runoff were estimated for municipalities in the metropolitan Phoenix area, Arizona, by adjusting regional regression equations of loads. This adjustment procedure uses the original regional regression equation and additional explanatory variables that were not included in the original equation. The adjusted equations had standard errors that ranged from 161 to 196 percent. The large standard errors of the prediction result from the large variability of the constituent concentration data used in the regression analysis. Adjustment procedures produced unsatisfactory results for nine of the regressions?suspended solids, dissolved solids, total phosphorus, dissolved phosphorus, total recoverable cadmium, total recoverable copper, total recoverable lead, total recoverable zinc, and storm runoff. These equations had no consistent direction of bias and no other additional explanatory variables correlated with the observed loads. A stepwise-multiple regression or a three-variable regression (total storm rainfall, drainage area, and impervious area) and local data were used to develop local regression equations for these nine constituents. These equations had standard errors from 15 to 183 percent.

Arizona↗

Calibration and validation of a two-dimensional hydrodynamic model of the Ohio River, Jefferson County, Kentucky

The quantification of current patterns is an essential component of a Water Quality Analysis Simulation Program (WASP) application in a riverine environment. The U.S. Geological Survey (USGS) provided a field validated two-dimensional Resource Management Associates-2 (RMA-2) hydrodynamic model capable of quantifying the steady-flowpatterns in the Ohio River extending from river mile 590 to 630 for the Ohio River Valley Water Sanitation Commission (ORSANCO) water-quality modeling efforts on that reach. Because of the hydrodynamic complexities induced by McAlpine Locks and Dam (Ohio River mile 607), the model was split into two segments: an upstream reach, which extended from the dam upstream to the upper terminus of the study reach at Ohio River mile 590; and a downstream reach, which extended from the dam downstream to a lower terminus at Ohio River mile 636. The model was calibrated to a low-flow hydraulic survey (approximately 35,000 cubic feet per second (ft 3 /s)) and verified with data collected during a high-flow survey (approximately 390,000 ft 3 /s). The model calibration and validation process included matching water-surface elevations at 10 locations and velocity profiles at 30 cross sections throughout the study reach. Based on the calibration and validation results, the model is a representative simulation of the Ohio River steady-flow patterns below discharges of approximately 400,000 ft 3 /s.

Kentucky↗

Estimating monthly and annual streamflow statistics at ungaged sites in Idaho

Updated monthly and annual streamflow information for the many ungaged streams throughout Idaho is needed to assist planners and managers with issues regarding fish and wildlife, water rights, and other land and water uses. To provide this information, the U.S. Geological Survey used a multiple-regression analysis to develop equations for estimating daily mean discharge exceeded 80, 50, and 20 percent of the time each month (80-, 50-, and 20-percent monthly exceedances) and mean annual discharge values at ungaged sites. The analysis produced estimating equations that relate specific streamflow statistics to basin characteristics. The standard errors of estimate, in log 10 , of the final estimating equations ranged from a minimum of 0.072 (+18.1 to -15.3 percent) to a maximum of 0.498 (+214.8 to -68.2 percent). The estimating equations might not yield reliable results for sites with basin characteristic values outside of the range of values used to develop the equations. The equations also are not applicable for regulated streams or those that exhibit significant gains and (or) losses as a result of spring flow, seepage through permeable streambeds, or irrigation diversions. The equations generally were more reliable for estimating the high monthly streamflow statistics (20-percent exceedances) than for estimating the low streamflow statistics (80-percent exceedances) in each region and all streamflow statistics in regions where annual streamflow is relatively low.

Idaho;Montana;Nevada;Oregon;Utah;Washington;Wyomin↗

History and hydrologic effects of ground-water use in Kings, Queens, and western Nassau Counties, Long Island, New York, 1800's through 1997

Ground-water withdrawals from the aquifers underlying Kings and Queens Counties varied temporally and spatially during the 20th century and caused extreme changes in water levels. The resultant lowering of water levels during periods of heavy pumping caused saltwater intrusion in nearshore areas and the migration of contaminants from land surface into deep aquifers. The recovery of water levels in response to countywide curtailment of pumping has resulted in the flooding of underground structures. Combined withdrawals for public and industrial supply in Kings and Queens Counties were greatest during the 1930's--about 130 million gallons per day. During this period, a large cone of depression developed in the water table in Kings County; within this depression, water levels were about 45 feet lower than in 1903. All pumping for public supply was halted in Kings County in 1947, and in Jamaica (in Queens County) in 1974. Water levels in Kings County had recovered by 1974 and have remained similar to those of 1903 since then, except for minor localized drawdowns due to industrial-supply or dewatering withdrawals. A large cone of depression that had formed in southeastern Queens County before 1974 has now (1997) disappeared. The estimated combined withdrawal for public supply and industrial supply in Kings and Queens Counties in 1996 was only about 50 million gallons per day. The water-level recoveries in the water-table and confined aquifers generally have resulted in the dilution and dispersion of residual salty and nitrate-contaminated ground water. The majority of recently sampled wells indicate stable or decreasing chloride and nitrate concentrations in all aquifers since 1983. Organic contaminants remain in ground water in Kings, Queens, and Nassau Counties, however; the most commonly detected compounds in 1992-96 were tetrachloroethene, trichloroethene, chloroform, and total trihalomethanes. Water samples from monitoring wells in Kings County indicate a greater number of occurrences of these compounds in the upper glacial aquifer than in the Jameco-Magothy aquifer, whereas samples from public-supply wells in Queens County indicated a greater number of occurrences in the Jameco- Magothy aquifer than in the upper glacial aquifer. This distribution suggests that organic contaminants were not drawn into the deeper aquifers in Kings County before 1947, when their use was limited and deep withdrawals were greatest, and (or) that the longer period of waterlevel recovery in Kings County than in Queens has allowed greater degradation, dilution, and dispersion of any organic contaminants that might have entered the deep aquifers before the cessation of pumping in 1947.

New York↗

Hydrologic and salinity characteristics of Currituck Sound and selected tributaries in North Carolina and Virginia, 1998–99

Data collected at three sites in Currituck Sound and three tributary sites between March 1, 1998, and February 28, 1999, were used to describe hydrologic and salinity characteristics of Currituck Sound. Water levels and salinity were measured at West Neck Creek at Pungo and at Albemarle and Chesapeake Canal near Princess Anne in Virginia, and at Coinjock, Bell Island, Poplar Branch, and Point Harbor in North Carolina. Flow velocity also was measured at the West Neck Creek and Coinjock sites. The maximum water-level range during the study period was observed near the lower midpoint of Currituck Sound at Poplar Branch. Generally, water levels at all sites were highest during March and April, and lowest during November and December. Winds from the south typically produced higher water levels in Currituck Sound, whereas winds from the north typically produced lower water levels. Although wind over Currituck Sound is associated with fluctuations in water level within the sound, other mechanisms, such as the effects of wind on Albemarle Sound and on other water bodies south of Currituck Sound, likely affect low-frequency water-level variations in Currituck Sound. Flow in West Neck Creek ranged from 313 cubic feet per second to the south to -227 cubic feet per second to the north (negative indicates flow to the north). Flow at the Coinjock site ranged from 15,300 cubic feet per second to the south to -11,700 cubic feet per second to the north. Flow was to the south 68 percent of the time at the West Neck Creek site and 44 percent of the time at the Coinjock site. Daily flow volumes were calculated as the sum of the instantaneous flow volumes. The West Neck Creek site had a cumulative flow volume to the south of 7.69 x 108 cubic feet for the period March 1, 1998, to February 28, 1999; the Coinjock site had a cumulative flow volume to the north of -1.33 x 1010 cubic feet for the same study period. Wind direction and speed influence flow at the West Neck Creek and Coinjock sites, whereas precipitation alone has little effect on flow at these sites. Flow at the West Neck Creek site is semidiurnal but is affected by wind direction and speed. Flow to the south (positive flow) was associated with wind speeds averaging more than 15 miles per hour from the northwest; flow to the north (negative flow) was associated with wind speeds averaging more than 15 miles per hour from the south and southwest. Flow at the Coinjock site reacted in a more unpredictable manner and was not affected by winds or tides in the same manner as West Neck Creek, with few tidal characteristics evident in the record. Throughout the study period, maximum salinity exceeded 3.5 parts per thousand at all sites; however, mean and median salinities were below 3.5 parts per thousand at all sites except the Point Harbor site (3.6 and 4.2 parts per thousand, respectively) at the southern end of the sound. Salinities were less than or equal to 3.5 parts per thousand nearly 100 percent of the time at the Bell Island and Poplar Branch sites in Currituck Sound and about 86 percent of the time at the Albemarle and Chesapeake Canal site north of the sound. Salinity at the West Neck Creek and Coinjock sites was less than or equal to 3.5 parts per thousand about 82 percent of the time. During this study, prevailing winds from the north were associated with flow to the south and tended to increase salinity at the West Neck Creek and the Albemarle and Chesapeake Canal sites. Conversely, these same winds tended to decrease salinity at the other sites. Prevailing winds from the south and southwest were associated with flow to the north and tended to increase salinity at the Poplar Branch and Point Harbor sites in Currituck Sound and at the Coinjock site, but these same winds tended to decrease salinity at the West Neck Creek and the Albemarle and Chesapeake Canal sites. The greatest variations in salinity were observed at the northernmost site, West Neck Creek, and thesouthernmost site, Point Harbor. The least variation in salinity was observed at the upper midpoint of the sound at the Bell Island site. Daily salt loads were computed for 364 days at the West Neck Creek site and 348 days at the Coinjock site from March 1, 1998, to February 28, 1999. The cumulative salt load at West Neck Creek was 28,170 tons to the south, and the cumulative salt load at the Coinjock site was -872,750 tons to the north. The cumulative salt load passing the West Neck Creek site during the study period would be 0.01 part per thousand if uniformly distributed throughout the sound (approximately 489,600 acre-feet in North Carolina). If the cumulative salt load passing the Coinjock site were uniformly distributed throughout the sound, the salinity in the sound would be 0.32 part per thousand. The net transport at the West Neck Creek and Coinjock sites indicates inflow of salt into the sound. A constant inflow of freshwater from tributaries and ground-water sources also occurs; however, the net flow volumes from these freshwater sources are not documented, and the significance of these freshwater inflows toward diluting the net import of salt into the sound is beyond the scope of this study.

North Carolina, Virginia↗

Hydrogeology and simulation of ground-water flow in the aquifers underlying Belvidere, Illinois

The U.S. Geological Survey investigated the ground-water-flow system and distribution of contaminants in the vicinity of Belvidere, Illinois, during 1992?2000. The study included the compilation, collection, and analyses of hydrogeologic and water-quality data and simulation of the ground-water-flow system. Hydrogeologic data include lithologic, stratigraphic, geophysical, hydraulic-property, water-level, ground-water withdrawal, and streamflow data. Water-quality data include analyses of water samples primarily for volatile organic compounds (VOC?s) and selectively for tritium and inorganic constituents. Data were collected from about 250 wells and 21 surfacewater sites. These data were used (1) to describe the hydrogeologic framework of the ground-waterflow system, preferential pathways and directions of ground-water movement and contaminant distribution, ground-water/surface-water relations, and the water budget and (2) to develop and calibrate the ground-water-flow model. The glacial drift (sand and gravel with some clay) and Galena-Platteville (fractured dolomite) aquifers and the sandstone aquifers of the Cambrian-Ordovician aquifer system compose the ground-water-flow system underlying Belvidere and vicinity. The Glenwood confining unit separates the Galena-Platteville aquifer from the underlying sandstone aquifers. The Galena- Platteville aquifer and confining unit may be absent in parts of the Troy Bedrock Valley, about 1.5 miles west of Belvidere. Throughout the study area, the Kishwaukee River and its tributaries seem to be gaining flow from shallow ground-water discharge. Potentiometric levels in the glacial drift and Galena-Platteville aquifers range from about 900 feet above sea level in the upland areas to 740 feet along the Kishwaukee River. Estimated horizontal hydraulic conductivity of the glacial drift aquifer ranges from about 0.13 to 280 feet per day. The Galena-Platteville aquifer is a dual-porosity unit with the greatest percentage of flow through fractures and bedding-plane partings. Estimated horizontal hydraulic conductivity ranges from about 0.005 to 2,500 feet per day. Estimated horizontal hydraulic conductivity of the St. Peter aquifer (the uppermost sandstone aquifer of the Cambrian-Ordovician aquifer system ranges from about 4.7 to 17.5 feet per day. Volatile organic compounds have been detected in all aquifers underlying Belvidere. Trichloroethene and tetrachloroethene are the principal VOC?s detected at concentrations above regulatory levels, with the largest number of detections and highest concentrations in the glacial drift aquifer. VOC?s generally are not detected in the glacial drift aquifer farther than 1,000 feet from known or potential source areas (industrial or disposal sites), because most source areas are near the Kishwaukee River, where shallow ground water discharges. Across most of the study area, the Glenwood confining unit seems to restrict downward movement of VOC?s into the underlying St. Peter aquifer; in the immediate vicinity of Belvidere, downward movement also seems restricted by lateral movement toward the municipal wells through permeable intervals in the 2 Hydrogeology and Simulation of Ground-Water Flow in the Aquifers Underlying Belvidere, Illinois Galena-Platteville aquifer. Fractures and (or) unused wells that may penetrate the confining unit seem to provide local pathways for limited movement of VOC?s to the sandstone aquifers. At least two municipal wells seem to intercept the bedding-plane partings at about 525 and 485 feet above sea level. Water levels in the lower one-third of the Galena-Platteville aquifer rapidly respond to withdrawals at these wells. The ground-water-flow system underlying Belvidere was simulated to test the conceptual model of the system. The three-dimensional, steady-state model represents the glacial drift, Galena-Platteville, and sandstone aquifers sep

Water-Resources Investigations Report↗

Irrigation drainage studies of the Angostura Reclamation Unit and the Belle Fourche Reclamation Project, western South Dakota: Results of 1994 sampling and comparisons with 1988 data

The U.S. Department of the Interior started the National Irrigation Water Quality Program in 1985 to identify the nature and extent of irrigation-induced water-quality problems that might exist in the western U.S. The Angostura Reclamation Unit (ARU) and Belle Fourche Reclamation Project (BFRP) in western South Dakota were included as part of this program. The ARU and BFRP reconnaissance studies were initiated in 1988, during below-normal streamflow conditions in both study areas. Surface water, bottom sediment, and fish were resampled in 1994 at selected sites in both study areas during generally near-normal streamflow conditions to compare with 1988 study results. Concentrations of major ions in water for both the ARU and BFRP study areas are high relative to national baseline levels. Major-ion concentrations for both areas generally are lower for 1994 than for 1988, when low-flow conditions prevailed, but ionic proportions are similar between years. For ARU, dissolved-solids concentrations probably increase slightly downstream from Angostura Reservoir; however, the available data sets are insufficient to confidently discern effects of ARU operations on dissolved-solids loading. For BFRP, dissolved-solids concentrations are slightly higher at sites that are affected by irrigation drainage; again, however, the data are inconclusive to determine whether BFRP operations increase dissolved-solids loading. Most trace-element concentrations in water samples for both study areas are similar between 1988 and 1994, and do not show strong relations with discharge. ARU operations probably are not contributing discernible additional loads of trace elements to the Cheyenne River. For BFRP, concentrations of some trace elements are slightly higher at sites downstream from irrigation operations than at a site upstream from irrigation operations. BFRP operations might contribute to trace-element concentrations in the Belle Fourche River, but available data are insufficient to quantify increases. For both study areas, concentrations of several trace elements occasionally exceed National Irrigation Water Quality Program guidelines. Selenium routinely occurs in concentrations that could be problematic at sites upstream and downstream from both study areas. Elevated selenium concentrations at sites upstream from irrigation operations indicate that naturally occurring selenium concentrations are relatively high in and near the study areas. While ARU operations probably do not contribute discernible additional loads of selenium to the Cheyenne River, BFRP operations might contribute additional selenium loads to the Belle Fourche River. Concentrations of most trace elements in bottom sediment, except arsenic and selenium, are similar to typical concentrations for western U.S. soils for both study areas. Bottom-sediment arsenic and selenium (1988) concentrations in both study areas can reach levels that might be of concern; however, there is insufficient information to determine whether irrigation operations contribute to these elevated concentrations. Concentrations of most trace elements in fish in both study areas are less than values known to adversely affect fish or birds, although there are occasional exceedances of established criteria. However, selenium concentrations in fish samples routinely are within the National Irrigation Water Quality Program level of concern, and also commonly exceed the dietary guideline for avian consumers for both study areas. Selenium concentrations in fish samples generally are higher at sites downstream from irrigation operations. For BFRP, arsenic and mercury concentrations are elevated in fish samples from site B-18, which is influenced by mine tailings.

South Dakota↗

Ground-water resources of the Clifton Park area, Saratoga County, New York

Ground water is the sole source of public water supply for Clifton Park, a growing suburban community north of Albany, New York. Increasing water demand, coupled with concerns over ground-water quantity and quality, led the Clifton Park Water Authority in 1995 to initiate a cooperative study with the U.S. Geological Survey to update and refine the understanding of ground-water resources in the area. Ground-water resources are largely associated with three aquifers in the eastern half of the area. These aquifers overlie or encompass the Colonie Channel, a north-south-oriented bedrock channel that is filled primarily with lacustrine glacial deposits. The three aquifers are: (1) an unconfined lacustrine sand aquifer, (2) the Colonie Channel aquifer, which is confined within the deepest parts of the channel and variably confined and unconfined within the shallower, peripheral channel areas, and (3) an unconfined alluvial aquifer beneath the Mohawk River flood plain, which represents the southern limit of the study area. The lacustrine sand aquifer has little potential for large-scale withdrawals because it is predominantly fine grained and is susceptible to contamination from human activities at land surface. Water from this aquifer can, however, recharge the underlying peripheral parts of the Colonie Channel aquifer where hydraulic connections are present. The Colonie Channel aquifer consists of thin sand and gravel and (or) shallow, fractured bedrock over much of the channel area; discontinuous deposits of thicker (more than 20 feet) sand and gravel are common in the peripheral channel areas. The deepest, or central, channel area of this aquifer is isolated from the overlying lacustrine sand aquifer by a continuous lacustrine silt and clay unit, which is the primary channel-fill deposit. The most productive areas of the Colonie Channel aquifer are typically the shallow peripheral areas, where conditions range from unconfined to confined. The most productive aquifer within the area is the alluvial aquifer, which is sustained to an unknown extent by induced infiltration of Mohawk River water. The chemical composition of ground water within the Clifton Park area varies widely in response to hydrogeologic setting, pumpage, and contamination from human activities. These chemical differences can be used to deduce ground-water flow paths within and between the unconfined and confined areas of the aquifer system. Six water types are defined; three are naturally occurring and three are the result of human activities. Precipitation that infiltrates the land surface is the sole source of recharge to the lacustrine sand aquifer; precipitation also recharges the alluvial aquifer and unconfined parts of the Colonie Channel aquifer. Ground-water withdrawals from confined or unconfined peripheral areas of the Colonie Channel aquifer induce flow from recharge areas, from the underlying bedrock, or from other confined aquifer areas. The rate of recharge to the confined central area of the Colonie Channel aquifer appears to be low. Potentiometric levels as much as 100 feet below water-table levels in the overlying lacustrine sand aquifer indicate two large depressions in the potentiometric surface; these depressions indicate that withdrawals from this aquifer have cumulatively exceeded the recharge rates. Localized recharge of the central channel area apparently occurs from two peripheral channel areas that are characterized by zones of elevated water levels and (or) by water chemistry that differs from those within the central channel area. Recharge from, or hydraulic connection with, adjoining segments of the Colonie Channel aquifer to the north and south is likely, but the potential for significant recharge is low because the aquifer is thin and poorly permeable.

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