USGS Science⌕ Search

SEARCH · USGS Science

Results for “Studies in Natural Sciences”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 811 records · Page 45Linked to original sources

Determination of uranyl incorporation into biogenic manganese oxides using X-ray absorption spectroscopy and scattering

Βiogenic manganese oxides are common and an important source of reactive mineral surfaces in the environment that may be potentially enhanced in bioremediation cases to improve natural attenuation. Experiments were performed in which the uranyl ion, UO 2 2+ (U(VI)), at various concentrations was present during manganese oxide biogenesis. At all concentrations, there was strong uptake of U onto the oxides. Synchrotron-based extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) studies were carried out to determine the molecular-scale mechanism by which uranyl is incorporated into the oxide and how this incorporation affects the resulting manganese oxide structure and mineralogy. The EXAFS experiments show that at low concentrations (<0.3 mol % U, <1 μM U(VI) in solution), U(VI) is present as a strong bidentate surface complex. At high concentrations (>2 mol % U, >4 μM U(VI) in solution), the presence of U(VI) affects the stability and structure of the Mn oxide to form poorly ordered Mn oxide tunnel structures, similar to todorokite. EXAFS modeling shows that uranyl is present in these oxides predominantly in the tunnels of the Mn oxide structure in a tridentate complex. Observations by XRD corroborate these results. Structural incorporation may lead to more stable U(VI) sequestration that may be suitable for remediation uses. These observations, combined with the very high uptake capacity of the Mn oxides, imply that Mn-oxidizing bacteria may significantly influence dissolved U(VI) concentrations in impacted waters via sorption and incorporation into Mn oxide biominerals.

Environmental Science & Technology↗

PFReports: A program for systematic checking of annual peaks in NWISWeb

The accuracy, characterization, and completeness of the U.S. Geological Survey (USGS) peak-flow data drive the determination of flood-frequency estimates that are used daily to design water and transportation infrastructure, delineate flood-plain boundaries, and regulate development and utilization of lands throughout the Nation and are essential to understanding the implications of climate change on flooding. Indeed, this high-profile database reflects and highlights the quality of USGS water-data collection programs. Its extension and improvement are essential to efforts to strengthen USGS networks and science leadership and is worthy of the attention of Water Science Center (WSC) hydrographers. This document describes a computer program, PFReports, and its output that facilitates efficient and robust review and correction of data in the USGS Peak Flow File (PFF) hosted as part of NWISWeb (the USGS public Web interface to much of the data stored and managed within the National Water Information System or NWIS). Checks embedded in the program are recommended as part of a more comprehensive assessment of peak flow data that will eventually include examination of possible regional changes, seasonal changes, and decadal variations in magnitude, timing, and frequency. Just as important as the comprehensive assessment, cleaning up the database will increase the likelihood of improved WSC regional flood-frequency equations. As an example of the value of cleaning up the PFF, data for 26,921 sites in the PFF were obtained. Of those sites, 17,542 sites had peak streamflow values and daily values. For the 17,542 sites, 1,097 peaks were identified that were less than the daily value for the day on which the peak occurred. Of the 26,921 sites, 11,643 had peak streamflow values, concurrent daily values, and at least 10 peaks. At the 11,643 sites, 2,205 peaks were identified as potential outliers in a regression of peak streamflows on daily values. Previous efforts to identify problems with the PFF were time consuming, laborious, and often ineffective. This new suite of checks represents an effort to automate identification of specific problems without plotting or printing large amounts of data that may not have problems. In addition, the results of the checks of the peak flow files are delivered through the World Wide Web with links to individual reports so that WSCs can focus on specific problems in an organized and standardized fashion. Over the years, technical reviews, regional-flood studies, and user inquiries have identified many minor and some major problems in the PFF. However, the cumbersome nature of the PFF editor and a lack of analytical tools have hampered efforts at quality assurance/quality control (QA/QC) and subsequently to make needed revisions to the database. This document is organized to provide information regarding PFReports, especially those tests involving regression and to provide an overview of the review procedures for utilizing the output. It also may be used as a reference for the data qualification codes and abbreviations for the tests. Results of the checks for all peak flow files (March 2008) are available at http://nd.water.usgs.gov/internal/pfreports/.

Open-File Report↗

A chemical and bio‐herbicide mixture increased exotic invaders, both targeted and non‐targeted, across a diversely invaded landscape after fire

Questions Invasive‐plant treatments often target a single or few species, but many landscapes are diversely invaded. Exotic annual grasses (EAGs) increase wildfires and degrade native perennial plant communities in cold‐desert rangelands, and herbicides are thus sprayed to inhibit EAG germination and establishment. We asked how EAG target and non‐target species responded to an herbicide mixture sprayed over a large, topographically diverse landscape after wildfire. We focused on how whole‐community and natural EAG‐pathogen treatment responses varied over years and physical properties of sites. Location Sagebrush steppe of southwest Idaho, USA. Methods We monitored plant cover and diversity in 41 pairs of plots located inside or outside areas (486 ha total) treated with a combined aerial broadcast spray of pre‐emergent herbicide (imazapic) and weed‐suppressive bacteria ( Pseudomonas fluorescens , “MB906”) to target EAGs after wildfires. Results EAG cover and exotic species richness were initially less in treated plots but increased to levels similar to or greater than those of untreated plots by the third post‐treatment year. The EAG pathogen Ustilago bullata was not directly affected by the treatment. The treatment increased exotic perennial forb cover in all plots and exotic annual forb cover in cooler/wetter plots but reduced exotic annual forb cover in warmer/drier plots. Cover of the invasive biennial grass Poa bulbosa decreased more across study years in untreated than treated plots. Among natives, the treatment reduced perennial grass cover and annual forb presence but led to marginal increases in perennial forb cover and, on soils with less gravel, increased shrub presence. Conclusions A treatment targeting a single plant functional group did not achieve lasting success in these diversely invaded communities. Spraying alone did not release native perennials sufficiently to counteract the simultaneous release of secondary invaders and the return of target invaders. Planting or seeding may also be needed to achieve management goals.

Idaho↗

India National Gas Hydrate Program Expedition-02: Operational and technical summary

The India National Gas Hydrate Program is being steered by the government of India's Ministry of Petroleum and Natural Gas (MoPNG) with participation of Directorate General of Hydrocarbons (DGH), Oil and Natural Gas Corporation Limited (ONGC), and the National Oil Companies and Research Institutes of India. The India National Gas Hydrate Program Expedition 01 (NGHP-01) established the presence of gas hydrate in the Krishna Godavari (KG) and Mahanadi Basins and in the offshore area of the Andaman Sea Basin. However, the gas hydrates discovered during NGHP-01 were mainly distributed as fracture-filling material in fine-grained clay-rich sediments. The India National Gas Hydrate Program Expedition 02 (NGHP-02) was carried out with an objective to discover gas hydrate in sand-rich sediment along the eastern offshore margin of India. ONGC planned and executed NGHP-02 on the behalf of the MoPNG. NGHP-02 started on March 3, 2015 and was completed on July 28, 2015 (total 147 days) using the Japanese scientific Drilling Vessel Chikyu (D/V Chikyu). During NGHP-02, 42 holes at 25 sites were drilled, cored, and/or surveyed with downhole logging tools. These sites were located in four areas along the eastern margin of India and formally named Area A (Mahanadi Basin, three sites), Area B (northern part of the KG-Basin, twelve sites), Area C (central part of the KG-Basin, six sites), and Area E (southern part to the KG-Basin, four sites). All 25 sites established during NGHP-02 were first drilled and logged with logging-while-drilling (LWD) tools and an additional 17 holes were then drilled and/or cored with conventional coring tools (HPCS/ESCS) or pressure coring tools (PCTB). Wireline logging was conducted in 10 holes and formation tests using a dual packer Modular Formation Dynamics Tester (MDT) tool were carried out in two holes. The onboard science team used the laboratory facilities on the D/V Chikyu to examine and analyse the physical properties, geochemistry, and sedimentology of all the cores collected during the expedition. Core samples were also analysed in additional post-expedition shore-based studies conducted in numerous domestic and international gas hydrate research laboratories. The NGHP-02 sediment cores were archived at the National Gas Hydrate Core Repository in Mumbai (India), which is associated with the ONGC Gas Hydrate Research and Technology Centre (GHRTC). The necessary data for characterizing the occurrence of gas hydrate, such as interstitial water chlorinities, core-derived gas chemistry, physical and sedimentological properties, thermal images of the recovered cores, pressure core and downhole measured logging data (LWD and/or conventional wireline log data), were obtained from most of the drill sites established during NGHP-02. Almost all the drill sites yielded evidence for the occurrence of gas hydrate; however, the inferred in situ concentration of gas hydrate varied substantially from site to site. For the most part, the interpretation of downhole logging data, core thermal images, interstitial water analyses, and pressure core images from the sites established during NGHP-02 indicate that the occurrence of concentrated gas hydrate is mostly associated with coarser grained (sand-rich) sediments. This paper presents the operational and technical summary of NGHP-02. NGHP-02 started on March 3, 2015 and was completed on July 28, 2015 (total 147 days) using the Japanese scientific Drilling Vessel Chikyu (D/V Chikyu). During NGHP-02, 42 holes at 25 sites were drilled, cored, and/or surveyed with downhole logging tools. These sites were located in four areas along the eastern margin of India and formally named Area A (Mahanadi Basin, three sites), Area B (northern part of the KG-Basin, twelve sites), Area C (central part of the KG-Basin, six sites), and Area E (southern part to the KG-Basin, four sites). All 25 sites established during NGHP-02 were first drilled and logged with logging-while-drilling (LWD) to

Journal of Marine and Petroleum Geology↗

Ecological effects of pinyon-juniper removal in the Western United States—A synthesis of scientific research, January 2014–March 2021

Executive Summary Increasing density of pinyon ( Pinus spp. ) and juniper ( Juniperus spp. ) woodlands (hereinafter “pinyon-juniper”), as well as expansion of these woodlands into adjacent shrublands and grasslands, has altered ecosystem function and wildlife habitat across large areas of the interior western United States. Although there are many natural and human-caused drivers of woodland infilling and expansion, restoration of sagebrush ( Artemisia spp. ) habitat through removal of pinyon-juniper is considered an urgent management objective in many locations, particularly in support of sagebrush-dependent wildlife species of conservation concern. In December 2020, the Bureau of Land Management (BLM) established the Pinyon-Juniper Management Categorical Exclusion (PJCX) to expedite the regulatory process for pinyon-juniper removal projects on public lands, largely intended to benefit mule deer ( Odocoileus hemionus ) and greater sage-grouse ( Centrocercus urophasianus ) habitats. During final preparation of this report, the BLM discontinued use of the PJCX (as of November, 2022), but the pinyon-juniper tree removal techniques assessed in this report are commonly used and understanding their effects remains relevant to land use planning. To address areas of uncertainty relative to potential ecological effects of the PJCX, we conducted a review of the peer-reviewed science literature to better understand the likely responses of vegetation, environmental (for example, soils), and wildlife variables to specific tree removal techniques permitted by the PJCX. In brief, the PJCX permitted removal of trees by either manual cutting, mechanical cutting, or mastication; allowed certain methods to redistribute or remove resulting tree biomass after treatment; and prohibited broadcast burning, roadbuilding, removal of old-growth, and seeding of non-native species. Specifically, we conducted our review to address the following questions: How will PJCX removal techniques affect plant communities, soils, and abiotic resources? How do these pinyon-juniper removal techniques affect wildlife communities, including both woodland- and sagebrush-dependent species? What are the potential ecological implications of different pinyon-juniper removal treatment types and implementation strategies (for example, treatment sizes) over time? What are the most important gaps in our scientific understanding of how treatments might affect targeted ecosystems over space and time (for example, potential effects of climate change)? To answer these questions, we considered studies related to pinyon-juniper ecosystems, focusing on research that occurred over a large portion of the interior western United States that is the primary focus of the PJCX. We also focused on papers published from 2014 onward, to avoid excessive overlap with other recent reviews on pinyon-juniper management effects. Using strict criteria, including only considering research that tested responses for statistical significance, we identified 48 papers that primarily examined treatment effects on vegetation and other environmental variables (1,709 responses), and 11 papers that addressed effects on wildlife (132 responses). Responses to the PJCX-permitted treatments were summarized as either positive (that is, a significant increase), negative (that is, a significant decrease), or non-significant (that is, no significant difference). Responses were assigned to categories (for example, Native Annual Grass/Forb Abundance) and hierarchical treatment levels. We found that there were large proportions of non-significant responses among all categories combined, with roughly half or more of all responses non-significant (48 percent for wildlife, 60 percent for vegetation-environmental), comparable to other recent systematic reviews of pinyon-juniper treatment effects. However, we also found that when there were significant responses, some important trends potentially emerged. Important undesirable outcomes included far more positive than negative responses of exotic grass and forb abundance among nearly all treatment types. Cutting treatments were also more likely to decrease biocrust cover and microbial activity. Potentially beneficial outcomes included mostly positive responses among sagebrush obligate species, including more positive than negative responses for mule deer and sage-grouse. Some treatment types (for example, mastication) also resulted in more positive than negative responses for native grasses and forbs (although, non-significant responses were the majority). We also highlighted many limitations of this review, including how responses often come from few studies, and how some response-treatment category combinations lack adequate response data. Moreover, the existing research is often insufficient to address many key questions about treatment effects, largely owing to short time-scales and limited spatial extents of observations, which do not match the size of treatments being implemented by land managers, nor capture long-term, post-treatment ecological dynamics. We also identify a lack of research that addresses key interactions that could undermine restoration objectives, including potential effects of climate change and grazing on post-treatment environments. Thus, we emphasize the importance of integrating these factors into future pinyon-juniper treatment research, and we stress the need for use of monitoring programs and research studies that partake in data collection and analysis over long durations and broad spatial scales.

Open-File Report↗

Sea-floor geology of a part of Mamala Bay, Hawai'i

We surveyed the sea-floor geology within a 200-km2 area of Mamala Bay, off Honolulu, Hawai'i, by collecting and analyzing sidescan sonar images, 3.5kHz profiles, video and still visual images, and box-core samples. The study area extends from 20-m water depth on the insular shelf to 600-m water depth in a southeast-trending trough. The sidescan images depict three principal types of seafloor material: low-backscatter natural sediment, high-backscatter drowned carbonate reef, and intermediate-backscatter dredged-material deposits. Cores indicate that the natural sediment is muddy sand, composed of carbonate reef and microfauna debris with some volcanic grains. Vague areal trends in composition are evident. The dredged material comprises poorly sorted, cobble- to clay-size mixtures of reef, volcanic, and man-made debris, up to 35 cm thick. Dredged-material deposits are not evident in the 3.5-kHz profiles. In the sidescan images they appear as isolated, circular to subcircular imprints, apparently formed by individual drops, around the periphery of their occurrence, but they overlap and coalesce to a nearly continuous, intermediate-backscatter blanket toward the center of three disposal sites investigated. We did not observe noticeable currents during our camera surveys, but there is abundant evidence of sediment reworking: symmetrical and asymmetrical ripples in the visual images, sand waves in the 3.5-kHz profiles and side-scan images, moats around the reefs in 3.5-kHz profiles, winnowed dredged material in the visual images, and burial of dredged material by natural sediment in cores. Most current indicators imply a westerly to northwesterly transport direction, along contours or upslope, although there are a few areas of easterly indicators. Internal waves probably drive the transport; their possible existence is implied by measured water-column density gradients.

Pacific Science↗

Soil aggregates as a source of dissolved organic carbon to streams: An experimental study on the effect of solution chemistry on water extractable carbon

Over the past two decades, headwater streams of the northern hemisphere have shown increased amounts of dissolved organic carbon (DOC), coinciding with decreased acid deposition. The exact nature of the mechanistic link between precipitation composition and stream water DOC is still widely debated in the literature. We hypothesize that soil aggregates are the main source of stream water DOC and that DOC release is greater in organic rich, riparian soils vs. hillslope soils. To test these hypotheses, we collected soils from two main landscape positions (hillslope and riparian zones) from the acid-impacted Sleepers River Research Watershed in northeastern Vermont. We performed aqueous soil extracts with solutions of different ionic strength (IS) and composition to simulate changes in soil solution. We monitored dynamic changes in soil particle size, aggregate architecture and composition, leachate DOC concentrations, dissolved organic matter (DOM) characteristics by fluorescence spectroscopy and trends in bioavailability. In low IS solutions, extractable DOC concentrations were significantly higher, particle size (by laser diffraction) was significantly smaller and organic material was separated from mineral particles in scanning electron microscope observations. Furthermore, higher DOC concentrations were found in Na + compared to Ca 2+ solutions of the same IS. These effects are attributed to aggregate dispersion due to expanding diffuse double layers in decreased IS solutions and to decreased bridging by divalent cations. Landscape position impacted quality but not quantity of released DOC. Overall, these results indicate that soil aggregates might be one important link between Critical Zone inputs (i.e., precipitation) and exports in streams.

Vermont↗

Experimental tree mortality does not induce marsh transgression in a Chesapeake Bay low-lying coastal forest

Transgression into adjacent uplands is an important global response of coastal wetlands to accelerated rates of sea level rise. “Ghost forests” mark a signature characteristic of marsh transgression on the landscape, as changes in tidal inundation and salinity cause bordering upland tree mortality, increase light availability, and the emergence of tidal marsh species due to reduced competition. To investigate these mechanisms of the marsh migration process, we conducted a field experiment to simulate a natural disturbance event (e.g., storm-induced flooding) by inducing the death of established trees (coastal loblolly pine, Pinus taeda ) at the marsh-upland forest ecotone. After this simulated disturbance in 2014, we monitored changes in vegetation along an elevation gradient in control and treatment areas to determine if disturbance can lead to an ecosystem shift from forested upland to wetland vegetation. Light availability initially increased in the disturbed area, leading to an increase in biodiversity of vegetation with early successional grass and shrub species. However, over the course of this 5-year experiment, there was no increase in inundation in the disturbed areas relative to the control and pine trees recolonized becoming the dominant plant cover in the disturbed study areas. Thus, in the 5 years since the disturbance, there has been no overall shift in species composition toward more hydrophytic vegetation that would be indicative of marsh transgression with the removal of trees. These findings suggest that disturbance is necessary but not sufficient alone for transgression to occur. Unless hydrological characteristics suppress tree re-growth within a period of several years following disturbance, the regenerating trees will shade and outcompete any migrating wetland vegetation species. Our results suggest that complex interactions between disturbance, biotic resistance, and slope help determine the potential for marsh transgression.

Chesapeake Bay low-lying coastal forest↗

Cross-continental evaluation of landscape-scale drivers and their impacts to fluvial fishes: Understanding frequency and severity to improve fish conservation in Europe and the United States

Fluvial fishes are threatened globally from intensive human landscape stressors degrading aquatic ecosystems. However, impacts vary regionally, as stressors and natural environmental factors differ between ecoregions and continents. To date, a comparison of fish responses to landscape stressors over continents is lacking, limiting understanding of consistency of impacts and hampering efficiencies in conserving fishes over large regions. This study addresses these shortcomings through a novel, integrative assessment of fluvial fishes throughout Europe and the conterminous United States. Using large-scale datasets, including information on fish assemblages from more than 30,000 locations on both continents, we identified threshold responses of fishes summarized by functional traits to landscape stressors including agriculture, pasture, urban area, road crossings, and human population density. After summarizing stressors by catchment unit (local and network) and constraining analyses by stream size (creeks vs. rivers), we analyzed stressor frequency (number of significant thresholds) and stressor severity (value of identified thresholds) within ecoregions across Europe and the United States. We document hundreds of responses of fish metrics to multi-scale stressors in ecoregions across two continents, providing rich findings to aid in understanding and comparing threats to fishes across the study regions. Collectively, we found that lithophilic species and, as expected, intolerant species are most sensitive to stressors in both continents, while migratory and rheophilic species are similarly strongly affected in the United States. Also, urban land use and human population density were most frequently associated with declines in fish assemblages, underscoring the pervasiveness of these stressors in both continents. This study offers an unprecedented comparison of landscape stressor effects on fluvial fishes in a consistent and comparable manner, supporting conservation of freshwater habitats in both continents and worldwide.

Europe↗

Sea-floor geology of a part of Mamala Bay, Hawaii

We surveyed the sea-floor geology within a 200-km2 area of Mamala Bay, off Honolulu, Hawaii by collecting and analyzing sidescan sonar images, 3.5-kHz profiles, video and still visual images, and box-core samples. The study area extends from 20-m water depth on the insular shelf to 600-m water depth in a southeast-trending trough. The sidescan images depict three principal types of sea-floor material: low-backscatter natural sediment, high-backscatter drowned carbonate reef, and intermediate-backscatter dredged-material deposits. Cores indicate that the natural sediment is muddy sand, composed of carbonate reef and microfauna debris with some volcanic grains. Vague areal trends in composition are evident. The dredged material comprises poorly sorted, cobble- to clay-size mixtures of reef, volcanic, and man-made debris, up to 35 cm thick. Dredged-material deposits are not evident in the 3.5-kHz profiles. In the sidescan images they appear as isolated, circular to subcircular imprints, apparently formed by individual drops, around the periphery of their occurrence, but they overlap and coalesce to a nearly continuous, intermediate-backscatter blanket toward the center of three disposal sites investigated. We did not observe significant currents during our camera surveys, but there is abundant evidence of sediment reworking: symmetrical and asymmetrical ripples in the visual images, sand waves in the 3.5-kHz profiles and side-scan images, moats around the reefs in 3.5-kHz profiles, winnowed dredged material in the visual images, and burial of dredged material by natural sediment in cores. Most current indicators imply a westerly to northwesterly transport direction, along contours or up-slope, although there are a few areas of easterly indicators. Internal waves probably drive the transport; their possible existence is implied by measured water-column density gradients.

Hawaii↗

Exposure and transport of alkaloids and phytoestrogens from soybeans to agricultural soils and streams in the Midwestern United States

Phytotoxins are naturally produced toxins with potencies similar/higher than many anthropogenic micropollutants. Nevertheless, little is known regarding their environmental fate and off-field transport to streams. To fill this research gap, a network of six basins in the Midwestern United States with substantial soybean production was selected for the study. Stream water ( n = 110), soybean plant tissues ( n = 8), and soil samples ( n = 16) were analyzed for 12 phytotoxins (5 alkaloids and 7 phytoestrogens) and 2 widely used herbicides (atrazine and metolachlor). Overall, at least 1 phytotoxin was detected in 82% of the samples, with as many as 11 phytotoxins detected in a single sample (median = 5), with a concentration range from below detection to 37 and 68 ng/L for alkaloids and phytoestrogens, respectively. In contrast, the herbicides were ubiquitously detected at substantially higher concentrations (atrazine: 99% and metolachlor: 83%; the concentrations range from below detection to 150 and 410 ng/L, respectively). There was an apparent seasonal pattern for phytotoxins, where occurrence prior to and during harvest season (September to November) and during the snow melt season (March) was higher than that in December–January. Runoff events increased phytotoxin and herbicide concentrations compared to those in base-flow conditions. Phytotoxin plant concentrations were orders of magnitude higher compared to those measured in soil and streams. These results demonstrate the potential exposure of aquatic and terrestrial organisms to soybean-derived phytotoxins.

Illinois, Indiana, Iowa, Minnesota, Missouri, Sout↗

Biodiversity influences plant productivity through niche–efficiency

The loss of biodiversity is threatening ecosystem productivity and services worldwide, spurring efforts to quantify its effects on the functioning of natural ecosystems. Previous research has focused on the positive role of biodiversity on resource acquisition (i.e., niche complementarity), but a lack of study on resource utilization efficiency, a link between resource and productivity, has rendered it difficult to quantify the biodiversity–ecosystem functioning relationship. Here we demonstrate that biodiversity loss reduces plant productivity, other things held constant, through theory, empirical evidence, and simulations under gradually relaxed assumptions. We developed a theoretical model named niche–efficiency to integrate niche complementarity and a heretofore-ignored mechanism of diminishing marginal productivity in quantifying the effects of biodiversity loss on plant productivity. Based on niche–efficiency, we created a relative productivity metric and a productivity impact index (PII) to assist in biological conservation and resource management. Relative productivity provides a standardized measure of the influence of biodiversity on individual productivity, and PII is a functionally based taxonomic index to assess individual species’ inherent value in maintaining current ecosystem productivity. Empirical evidence from the Alaska boreal forest suggests that every 1% reduction in overall plant diversity could render an average of 0.23% decline in individual tree productivity. Out of the 283 plant species of the region, we found that large woody plants generally have greater PII values than other species. This theoretical model would facilitate the integration of biological conservation in the international campaign against several pressing global issues involving energy use, climate change, and poverty.

Proceedings of the National Academy of Sciences of↗

Kinetics of the coesite to quartz transformation

The survival of coesite in ultrahigh-pressure (UHP) rocks has important implications for the exhumation of subducted crustal rocks. We have conducted experiments to study the mechanism and rate of the coesite→quartz transformation using polycrystalline coesite aggregates, fabricated by devitrifying silica glass cylinders containing 2850 H/10 6 Si at 1000°C and 3.6 GPa for 24 h. Conditions were adjusted following synthesis to transform the samples at 700–1000°C at pressures 190–410 MPa below the quartz–coesite equilibrium boundary. Reaction proceeds via grain-boundary nucleation and interface-controlled growth, with characteristic reaction textures remarkably similar to those seen in natural UHP rocks. We infer that the experimental reaction mechanism is identical to that in nature, a prerequisite for reliable extrapolation of the rate data. Growth rates obtained by direct measurement differ by up to two orders of magnitude from those estimated by fitting a rate equation to the transformation–time data. Fitting the rates to Turnbull's equation for growth therefore yields two distinct sets of parameters with similar activation energies (242 or 269 kJ/mol) but significantly different pre-exponential constants. Extrapolation based on either set of growth rates suggests that coesite should not be preserved on geologic time scales if it reaches the quartz stability field at temperatures above 375–400°C. The survival of coesite has previously been linked to its inclusion in strong phases, such as garnet, that can sustain a high internal pressure during decompression. Other factors that may play a crucial role in preservation are low fluid availability — possibly even less than that of our nominally “dry” experiments — and the development of transformation stress, which inhibits nucleation and growth. These issues are discussed in the context of our experiments as well as recent observations from natural rocks.

Earth and Planetary Science Letters↗

Sources of terrestrially-derived organic carbon in lower Mississippi River and Louisiana shelf sediments: Implications for differential sedimentation and transport at the coastal margin

In this study, we examined the temporal and spatial variability of terrestrial organic carbon sources in lower Mississippi River and Louisiana shelf sediments (during 11 cruises over a 22-month period) to further understand the sorting dynamics and selective transport of vascular plant materials within the primary dispersal system of the river. Bulk ??13C values in lower river sediments ranged from -21.90??? to -24.64??? (mean=-23.20??1.09???), these values were generally more depleted than those found in shelf sediments (-22.5??? to -21.2???). The ??8 (??8 = sum of vanillyl, syringyl and cinnamyl phenols produced from the oxidation of 100 mg of organic carbon) values in the lower river ranged from 0.71 to 3.74 (mean = 1.78??0.23). While there was no significant relationship between ??8 and river discharge (p>0.05), the highest value occurred during peak discharge in April 1999-which corresponded to the highest observed C/N value of 17.41. The ??8 values on the shelf ranged from 0.68 to 1.36 (mean = 0.54??0.30) and were significantly lower (p <0.05) than the average value for lower river sediments. The range of S/V (syringyl/vanillyl) and C/V (cinnamyl/vanillyl) ratios on the shelf, 0.11 to 0.95 and 0.01 to 0.08, respectively, were similar to that found in the lower river. These low C/V ratios are indicative a mixture of woody and non-woody carbon sources. Recent work by Goni et al. [Nature 389 (1997) 275; Geochim. Cosmochim. Acta 62 (1998) 3055], which did not include sampling transects within the primary dispersal system of the Mississippi River, showed a non-woody vascular plant signature on the Louisiana shelf. This suggests that riverine-derived woody tissues preferentially settle out of the water column, in the lower river and inner shelf, prior to the selective dispersal of C3 versus C4 non-woody materials in other regions the shelf and slope. This works further demonstrates the importance of differential settlement of particles, sampling location within the dispersal system, and river discharge, when examining biogeochemical cycles in river-dominated margins. ?? 2002 Elsevier Science B.V. All rights reserved.

Marine Chemistry↗

Rb-Sr, Sm-Nd, K-Ca, O, and H isotopic study of Cretaceous-Tertiary boundary sediments, Caravaca, Spain: evidence for an oceanic impact site

Isotopic ratios and trace element abundances were measured on samples of Ir-enriched clay at the Cretaceous-Tertiary boundary, and in carbonate and marl from 5 cm below and 3 cm above the boundary. Samples were leached with acetic acid to remove carbonate, and with hydrochloric acid. Leachates and residues were measured. The Sr, Nd, O and H isotopic compositions of the boundary clay residues are distinct from those of the stratigraphically neighboring materials. The data indicate that most of the clay material was derived from a terrestrial source with relatively low 87 Sr/ 86 Sr and high 143 Nd/ 144 Nd ratios. The δ 18 O data suggest that the detritus has been modified by submarine weathering. K-Ca and Rb-Sr systematics, as well as O isotope ratios of K-feldspar spherules within the boundary clay, suggest that they are predominantly authigenic and may have formed after the time of deposition. However, Sm-Nd and Rb-Sr isotopic data indicate that the spherules contain relict material that provides information on the nature of the original detritus. The isotopic evidence for foreign terrestrial detritus in the boundary clay, the low rare earth element concentrations and high Ni concentration, support the hypothesis of a terminal Cretaceous asteroidal impact that produced a global layer of fallout. The data are most easily explained if the impact site was on oceanic crust rather than continental crust, and if a substantial fraction of the fallout was derived from relatively deep within the lithosphere (>3 km). This would probably require a single large impactor.

Caravaca↗

Monitoring lava-dome growth during the 2004–2008 Mount St. Helens, Washington, eruption using oblique terrestrial photography

We present an analysis of lava dome growth during the 2004–2008 eruption of Mount St. Helens using oblique terrestrial images from a network of remotely placed cameras. This underutilized monitoring tool augmented more traditional monitoring techniques, and was used to provide a robust assessment of the nature, pace, and state of the eruption and to quantify the kinematics of dome growth. Eruption monitoring using terrestrial photography began with a single camera deployed at the mouth of the volcano's crater during the first year of activity. Analysis of those images indicates that the average lineal extrusion rate decayed approximately logarithmically from about 8 m/d to about 2 m/d (± 2 m/d) from November 2004 through December 2005, and suggests that the extrusion rate fluctuated on time scales of days to weeks. From May 2006 through September 2007, imagery from multiple cameras deployed around the volcano allowed determination of 3-dimensional motion across the dome complex. Analysis of the multi-camera imagery shows spatially differential, but remarkably steady to gradually slowing, motion, from about 1–2 m/d from May through October 2006, to about 0.2–1.0 m/d from May through September 2007. In contrast to the fluctuations in lineal extrusion rate documented during the first year of eruption, dome motion from May 2006 through September 2007 was monotonic (± 0.10 m/d) to gradually slowing on time scales of weeks to months. The ability to measure spatial and temporal rates of motion of the effusing lava dome from oblique terrestrial photographs provided a significant, and sometimes the sole, means of identifying and quantifying dome growth during the eruption, and it demonstrates the utility of using frequent, long-term terrestrial photography to monitor and study volcanic eruptions.

Washington↗

Establishment of Salsola tragus on aeolian sands: A Southern Colorado Plateau case study

Russian-thistle (Salsola tragus L.), is a nonnative, C4 photosynthesizing, annual plant that infests disturbed and natural areas in the arid U.S. Southwest. Land managers of natural areas may need to decide whether a S. tragus infestation is potentially harmful and whether it should be actively managed. One factor informing that decision is an understanding of the conditions under which this weed emerges and establishes and how those processes affect where and when infestations occur. We studied S. tragus establishment on aeolian (windblown) sandy soils at Petrified Forest National Park, AZ. Our sites were a previously disturbed sand sheet and a semistabilized sand dune. Measurements in plots on these sites over two growing seasons revealed a similar number of S. tragus seedlings emerging on both sites early in the 2015 growing season. As the season progressed, S. tragus cover (seedling survival and growth) was lower on the sand dune, except for a plot placed entirely on a coppice mound. In 2016, S. tragus seedling emergence and development of cover, measured on plots at both sites, was exceptionally low, as was summer rainfall. A growth chamber assay of seedling emergence from soil and litter samples collected at each site showed emergence was greatest from samples collected where S. tragus litter remained on the soil surface, and otherwise was infrequent. Our study suggests that S. tragus emergence and early establishment are sensitive to low precipitation and that soil-surface microtopography and grass and shrub cover may be determinants of the spatial pattern of infestation on sandy soils. As aeolian sands occur throughout drylands of the U.S. Southwest, deeper understanding of the conditions under which S. tragus seedlings emerge and establish can inform management of this invasive annual in those habitats.

Invasive Plant Science and Management↗

Museum records provide unique information about the distribution of the Yellow Lampmussel Lampsilis cariosa (Unionidae)

Natural history museum records may provide unique information on the distribution of species that can supplement survey data collected by resource managers. However, there can be challenges to using museum data for analyses, such as spurious geographic information, misidentifications, and incorrect labeling. Museum records have been centralized by open-source repositories with flags for coordinate precision and out-of-range specimens, providing some information about record uncertainty in general. Verification of uncertain museum records could increase confidence in distribution data and improve understanding of biodiversity patterns and range dynamics through time. The goal of this study was to determine if museum records provide unique information about the distribution of the Yellow Lampmussel Lampsilis cariosa (Say, 1817), an at-risk freshwater mussel species. We created a dichotomous key based on a hierarchy of conchological characteristics to verify the taxonomic identity of flagged L. cariosa specimens and assessed records occurring outside of the species’ expected range as compiled from primary literature. Fifty percent of flagged specimens were confirmed as L. cariosa . Of the invalid records, 56% were misidentifications, mainly of other Lampsilis species. Overall, museum collections (1800s–present) contributed 32 unique watersheds not represented by modern survey records (1980s–present, comprising 92 watersheds) including 13 unexpected watersheds in regions of New York and Vermont (USA) and Québec and Ontario (Canada). Our study provides a reproducible method for the reverification of freshwater mussel museum records and highlights how these records can provide unique contributions to our understanding of the geographic range of a rare, at-risk mussel species.

New York, Vermont↗