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USGS1980

Plan of study for the Northern Atlantic Coastal Plain Regional Aquifer System Analysis

Sediments of Cretaceous to Holocene age compose the Northern Atlantic Coastal Plain aquifer system in an area of 50,000 square miles in parts of New York, New Jersey, Delaware, Maryland, Virginia, and North Carolina. The aquifer system is a major source of water supply in the area. About 1.4 billion gallons is withdrawn from its aquifers each day. Increasing withdrawal of ground water has created or intensified several problems such as declining water levels, development of large cones of depression, saltwater intrusion, spreading of ground-water contamination, and land subsidence. The U.S. Geological Survey has begun a comprehensive study that will define the geology, hydrology, and geochemistry of the aquifer system. The effects of future utilization of the aquifer system will be determined and alternative plans for water withdrawal will be evaluated through computer simulation modeling. This report describes the objectives, organization, and work plans of the study, and describes the work to be accomplished in each U.S. Geological Survey District of the study area.

Delaware;Maryl;New Jersey;North Carolina;Virginia↗

USGS1994

Hydrology of, and water quality in, the open burning area and vicinity, Picatinny Arsenal, New Jersey, 1989-90

This report presents the results of a study to determine whether shallow ground water at Picatinny Arsenal Morris County, New Jersey, has been con- taminated as a result of operations at the open burning area, which is used for burning of waste explosives and materials contaminated with explosives. Results of previous investigations indicate that the soil in this area is contaminated with metals and organic compounds. Twenty-seven wells were sampled for analysis for inorganic constituents, nutrients, and explosive compounds. Selected wells also were sampled for analysis for base/neutral- and acid-extractable compounds, pesticides, volatile organic compounds, and dioxin and furan compounds. Surface-water and streambed- material samples were collected at three sites in Green Pond Brook. Water-level measurements indicate that ground-water flow generally is nearly horizontal and toward Green Pond Brook. The average velocity of the ground water is estimated to be 0.03 to 1.8 feet per day. Concentrations of iron and manganese in ground-water samples from the unconfined aquifer were consistently greater than U.S. Environmental Protection Agency secondary drinking-water regulations. Because similarly high concentrations of these constituents have been found in ground-water samples at the arsenal, they are not considered to be a consequence of activities at the open burning area. Contaminants from the open burning area appear to be contributing to elevated concentratons of lead, zinc, and explosive com- pounds found in the streambed material. Other trace element and polynuclear aromatic hydrocarbons probably are derived from both the open burning area and upstream sources. Volatile organic compounds were detected in surface-water samples at low concentrations, although most were found upstream from the open burning area. No inorganic or organic constituents were detected in ground-water or surface-water samples in concentrations that exceeded U.S. Environmental Protection Agency primary drinking-water regulations.

New Jersey↗

USGS2022

No evidence for tephra in Greenland from the historic eruption of Vesuvius in 79 CE: Implications for geochronology and paleoclimatology

Volcanic fallout in polar ice sheets provides important opportunities to date and correlate ice-core records as well as to investigate the environmental impacts of eruptions. Only the geochemical characterization of volcanic ash (tephra) embedded in the ice strata can confirm the source of the eruption, however, and is a requisite if historical eruption ages are to be used as valid chronological checks on annual ice layer counting. Here we report the investigation of ash particles in a Greenland ice core that are associated with a volcanic sulfuric acid layer previously attributed to the 79 CE eruption of Vesuvius. Major and trace element composition of the particles indicates that the tephra does not derive from Vesuvius but most likely originates from an unidentified eruption in the Aleutian arc. Using ash dispersal modeling, we find that only an eruption large enough to include stratospheric injection is likely to account for the sizable (24–85 µm ) ash particles observed in the Greenland ice at this time. Despite its likely explosivity, this event does not appear to have triggered significant climate perturbations, unlike some other large extratropical eruptions. In light of a recent re-evaluation of the Greenland ice-core chronologies, our findings further challenge the previous assignation of this volcanic event to 79 CE. We highlight the need for the revised Common Era ice-core chronology to be formally accepted by the wider ice-core and climate modeling communities in order to ensure robust age linkages to precisely dated historical and paleoclimate proxy records.

Climate of the Past↗

USGS2008

A Versatile Time-Lapse Camera System Developed by the Hawaiian Volcano Observatory for Use at Kilauea Volcano, Hawaii

Volcanoes can be difficult to study up close. Because it may be days, weeks, or even years between important events, direct observation is often impractical. In addition, volcanoes are often inaccessible due to their remote location and (or) harsh environmental conditions. An eruption adds another level of complexity to what already may be a difficult and dangerous situation. For these reasons, scientists at the U.S. Geological Survey (USGS) Hawaiian Volcano Observatory (HVO) have, for years, built camera systems to act as surrogate eyes. With the recent advances in digital-camera technology, these eyes are rapidly improving. One type of photographic monitoring involves the use of near-real-time network-enabled cameras installed at permanent sites (Hoblitt and others, in press). Time-lapse camera-systems, on the other hand, provide an inexpensive, easily transportable monitoring option that offers more versatility in site location. While time-lapse systems lack near-real-time capability, they provide higher image resolution and can be rapidly deployed in areas where the use of sophisticated telemetry required by the networked cameras systems is not practical. This report describes the latest generation (as of 2008) time-lapse camera system used by HVO for photograph acquisition in remote and hazardous sites on Kilauea Volcano.

Scientific Investigations Report↗

USGS2018

Comparability among four invertebrate sampling methods and two multimetric indexes, Fountain Creek Basin, Colorado, 2010–2012

The U.S. Geological Survey (USGS), in cooperation with Colorado Springs City Engineering and Colorado Springs Utilities, analyzed previously collected invertebrate data to determine the comparability among four sampling methods and two versions (2010 and 2017) of the Colorado Benthic Macroinvertebrate Multimetric Index (MMI). For this study, annual macroinvertebrate samples were collected concurrently (in space and time) at 15 USGS surface-water gaging stations in the Fountain Creek Basin from 2010 to 2012 using four sampling methods. The USGS monitoring project in the basin uses two of the methods and the Colorado Department of Public Health and Environment recommends the other two. These methods belong to two distinct sample types, one that targets single habitats and one that targets multiple habitats. The study results indicate that there are significant differences in MMI values obtained from the single-habitat and multihabitat sample types but methods from each program within each sample type produced comparable values. This study also determined that MMI values calculated by different versions of the Colorado Benthic Macroinvertebrate MMI are indistinguishable. This indicates that the Colorado Department of Public Health and Environment methods are comparable with the USGS monitoring project methods for single-habitat and multihabitat sample types. This report discusses the direct application of the study results to inform the revision of the existing USGS monitoring project in the Fountain Creek Basin.

Colorado↗

USGS2019

Summary of climatic, geographic, geologic, and available hydrologic data and identification of data gaps for the Black Bear Creek watershed of the Pawnee Nation Tribal Jurisdictional Area, Oklahoma

The Pawnee Nation is compiling a comprehensive water-management plan for the Pawnee Nation Tribal Jurisdictional Area in north-central Oklahoma. One of the first steps needed in preparing such a plan is a summary and analysis of available hydrologic data and reports that have been published for the area. In phase I of a three-phase, watershed-based approach to summary and analysis of water resources of the Pawnee Nation, the U.S. Geological Survey, in cooperation with the Pawnee Nation and Bureau of Indian Affairs, conducted a literature search and data analysis for the Black Bear Creek watershed within the Pawnee Nation Tribal Jurisdictional Area, referred to herein as the “Black Bear Creek study area.” This report summarizes the available data for the Black Bear Creek study area. Climatic, geographic, geologic, water-use, and hydrologic data from previously published reports or databases were collected and analyzed for this report. Because of the limited amount of groundwater-quality data for the study area, a field collection of groundwater levels and water samples was conducted. Sixteen wells were identified, and groundwater levels were measured at each well. Eight wells were sampled, and water properties, major ions, and nutrients were measured. Overall, there are few long-term monitoring stations to help determine trends of surface-water quality, groundwater quality, and groundwater levels across the study area. Establishing and maintaining long-term streamflow, surface-water-quality, groundwater-level, and groundwater-quality monitoring sites would greatly increase the understanding of the water resources in the Black Bear Creek study area. Additionally, water-use estimates would be greatly improved by metering groundwater withdrawals. Establishing hydrologic and water-quality trends and having improved estimates of water use can aid decision makers in the stewardship of the water resources in this area. This report can aid the Pawnee Nation in prioritization of future projects and serve as a background document for the development of a jurisdiction-wide comprehensive water-management plan.

Oklahoma↗

USGS2023

Long-term water-quality constituent trends in the Little Arkansas River, south-central Kansas, 1995–2021

The Equus Beds aquifer and Cheney Reservoir are primary sources for the city of Wichita’s current (2023) water supply. The Equus Beds aquifer storage and recovery (ASR) project was developed by the city of Wichita in the early 1990s to meet future water demands using the Little Arkansas River as an artificial aquifer recharge water source during above-base-flow conditions. Little Arkansas River water is removed from the river at an ASR Facility intake structure, treated using National Primary Drinking Water Regulations as a guideline, and is infiltrated into the Equus Beds aquifer through recharge basins or injected into the aquifer through recharge wells for later use. The U.S. Geological Survey, in cooperation with the city of Wichita, completed this study to quantify and characterize Little Arkansas River water-quality data. Data in this report can be used to evaluate changing conditions, provide science-based information for decision making, and help meet regulatory requirements. Continuous (hourly) physicochemical properties were measured, and discrete water-quality samples were collected from three Little Arkansas River sites located along the easternmost extent of the Equus Beds aquifer during 1995 through 2021 over a range of streamflow conditions. The Little Arkansas River at Highway 50 near Halstead, Kansas, streamgage (U.S. Geological Survey station 07143672; hereafter referred to as the “Highway 50 site”) is located upstream from the other two sites, and the Little Arkansas River near Sedgwick, Kans., streamgage (U.S. Geological Survey station 07144100; hereafter referred to as the “Sedgwick site”) is located downstream from the other two sites; these two sites bracket most of the easternmost part of the Equus Beds aquifer. The Little Arkansas River upstream of ASR Facility near Sedgwick, Kans., streamgage (U.S. Geological Survey station 375350097262800; hereafter referred to as the “Upstream ASR site”) is located between the Highway 50 and Sedgwick sites, about 14.7 river miles (mi) downstream from the Highway 50 site, about 1.7 river mi upstream from the Sedgwick site, and immediately upstream from the ASR Facility intake structure. Surrogate models for water-quality constituents of interest (including bromide, dissolved organic carbon, 2-chloro-4-isopropylamino-6-amino- s -triazine [deethylatrazine], atrazine, and metolachlor) were updated or developed using continuously measured and concomitant discrete data. These surrogate models, along with previously developed regression models, were used to compute concentrations (at the Highway 50, Sedgwick, and Upstream ASR sites) and loads (at the Highway 50 and Sedgwick sites) during the study period. Federal criteria were used to evaluate water quality. Where applicable, water-quality data were compared to Federal national drinking-water regulations. Flow-normalized water-quality constituent trends were evaluated using Weighted Regressions on Time, Discharge, and Season (WRTDS) statistical models and water-quality trends were described using WRTDS bootstrap tests. Continuously computed primary ion concentrations were generally larger at the Highway 50 site compared to the Sedgwick site. During the study period, the Federal secondary maximum contaminant level (SMCL) for dissolved solids was exceeded 57 percent of the time at the Highway 50 site and 38 percent of the time at the Sedgwick site. Computed bromide concentrations were larger at the Highway 50 site and exceeded the city of Wichita treatment threshold about 70, 21, and 19 percent of the time at the Highway 50, Sedgwick, and Upstream ASR sites, respectively. Chloride concentrations exceeded the Federal SMCL about 16 percent of the time at the Highway 50 site and did not exceed the SMCL at the Sedgwick site. Continuous arsenic concentrations exceeded the Federal Maximum Contaminant Level (MCL) 9 to 15 percent of the time at the Sedgwick and Highway 50 sites, respectively, during the study. Atrazine concentrations exceeded the Federal MCL 10 percent of the time at the Highway 50 and Sedgwick sites and 14 percent of the time at the Upstream ASR site during the study; computed glyphosate concentrations at the Sedgwick site never exceeded the MCL during the study. Little Arkansas River flow-normalized primary ion concentrations during 1995 through 2021 generally had downward trends and decreases were generally larger at the Highway 50 site compared to the Sedgwick site. Dissolved solids and chloride concentrations decreased at the Highway 50 and Sedgwick sites. Bromide had no trend at the Highway 50 site and a downward trend at the Sedgwick site. Nitrate plus nitrite and total phosphorus concentrations had upward trends at the Highway 50 site but downward trends at the Sedgwick site, whereas total organic carbon had upward trends at both sites. Nitrate plus nitrite, total nitrogen, total phosphorus, and total organic carbon fluxes had upward trends at the Highway 50 and Sedgwick sites. Suspended-sediment concentrations had an upward trend at the Highway 50 site and had no trend at the Sedgwick site. Arsenic concentrations had downward trends at the Highway 50 and Sedgwick sites. About one-quarter to one-half of the Little Arkansas River loads, including nutrients and sediment, were transported during 1 percent of the time during the study. Because streamflows are highly sensitive to climatic variation and an increase of extreme precipitation events in the Great Plains is expected, similar disproportionately large pollutant loading events may increase into the future. Continuous measurement of physicochemical properties in near-real time allowed characterization of Little Arkansas River surface water during conditions and time scales that would not have been possible otherwise and served as a complement to discrete water-quality sampling. Continuation of this water-quality monitoring will provide data to characterize changing conditions in the Little Arkansas River and possibly identify new and changing trends. Information in this report allows the city of Wichita to make informed municipal water-supply decisions using past and present water-quality conditions and trends in the watershed.

Kansas↗

USGS2025

Methods for peak-flow frequency analysis for streamgages in or near Montana, North Dakota, South Dakota, and Wyoming

The U.S. Geological Survey, in cooperation with the Montana Department of Natural Resources and Conservation, North Dakota Department of Water Resources, South Dakota Department of Transportation, and the Wyoming Water Development Office, has developed standard methods of peak-flow frequency analysis for studies in Montana, North Dakota, South Dakota, and Wyoming. These methods describe the implementation of national flood frequency guidelines described in Bulletin 17C ( https://doi.org/10.3133/tm4B5 ) for the four States and deviations from Bulletin 17C standard procedures to accommodate unusual hydrologic conditions. A U.S. Geological Survey data release accompanying this report ( https://doi.org/10.5066/P1WHRK8H ) provides example peak-flow frequency analyses for selected streamgages in the study area. The methods described in this report can be used to publish similar data releases for other streamgages in the study area.

Montana, North Dakota, South Dakota, Wyoming↗

USGS2000

Statistical identification of hydrochemical response units for hydrologic monitoring and modeling in Maryland

In support of Maryland's efforts to develop statewide water-quality management plans, a statistical analysis was performed to identify a set of representative and relatively homogeneous areas referred to as Hydrochemical Response Units (HRUs). The State intends to select representative areas within each hydrochemical response unit for monitoring and model development, and then apply the model to the entire unit. To identify hydrochemical response units, cluster analysis was applied to 1,136 digitally defined watershed units. Basin characteristics including land cover, soil type, slope, and geology were determined for each watershed unit and a clustering algorithm was applied to the data sets. A total of 11 hydrochemical response units were identified by the analysis. Major features that were important in distinguishing different areas of the state include: 1) upland and lowland Coastal Plain settings, 2) igneous, shale, and carbonate geology; and 3) urban land cover. The hydrochemical response units described in this report are considered to be an initial classification of watersheds in Maryland that can be refined as geographic data sets are improved and additional hydrologic data are collected.

Water-Resources Investigations Report↗

USGS1975

The potentiometric surface and water quality of the Floridan aquifer; in southwest Hillsborough County, Florida, 1952-74

Large ground-water withdrawals and a 10-year period of below- normal rainfall have caused the potentiometric surface of the Floridan aquifer to decline more than 10 feet (3 metres) in most of a 200- square-mile (520-square-kilometre) area of southwest Hillsborough County (fig. 1). The lowered ground-water levels and the consequent threat of salt-water intrusion concern farmers and residents who depend on ground water for irrigation and domestic purposes. Exten sive crop irrigation is continuing; small towns such as Ruskin, River- view, Sun City Center, and Apollo Beach are rapidly expanding; and new communities are being planned. In addition, there are plans to mine the extensive phosphate deposits a few miles east of this heavily- f armed area. All these activities require large supplies of fresh ground water. The Hillsborough County Commission cooperated with the U. S. Geological Survey to study changes of water levels and water quality in southwest Hillsborough County. The purpose of this report is to compare the position of the potentiometric surface in 1953 with that in 1973 and to show chloride and sulfate concentrations in ground water in 1974.

Florida↗

USGS1987

Ground-water-recharge rates in Nassau and Suffolk counties, New York

Groundwater is the sole source of freshwater in Nassau and Suffolk Counties on Long Island; therefore, the rate at which precipitation replenishes the groundwater system may affect future water supplies in some areas. Annual precipitation on Long Island averages 45 inches per year, but less than 23 inches , or 50%, recharges the ground-water system. (Recharge is precipitation that percolates to the ground-water system naturally; it does not include water from stormwater basins or injection wells.) The rate of recharge varies locally and ranges from 29% to 57% of precipitation, depending on land use, season, and amount of storm sewering in the area. Recharge was calculated by subtracting evapotranspiration and direct runoff values from known precipitation values. Evapotranspiration was calculated by the Thornwaite and Mather method, and direct runoff rates to streams were calculated from streamflow records and size of known storm-sewer service areas. This report includes maps that depict precipitation, evapotranspiration, and rates of natural recharge in Nassau and Suffolk Counties for use in future hydrologic studies on Long Island. (Author 's abstract)

Water-Resources Investigations Report↗

USGS1988

Selected reports that include computer programs produced by the US Geological Survey for simulation of ground-water flow and quality

A summary list of reports that document numerical models that simulate ground-water flow and quality is presented. The list documents the reference by giving a description of each model program, its numerical features, a qualitative expression of the number of past applications and where to obtain a copy. All reports included in the list have been published or developed by the U.S. Geological Survey and most contain listings of the computer programs. (Author 's abstract)

Water-Resources Investigations Report↗

USGS2024

U.S. Geological Survey Mississippi River Science Forum—Summary of data and science needs and next steps

The U.S. Geological Survey hosted a Mississippi River Science Forum with Federal agencies; Tribal, State, and local governments located in States that border the Mississippi River; academia; and other interested stakeholders. The purpose of the forum was to share current (2023) science; identify data gaps and areas of concern; and to prioritize next steps needed to advance the goals of improving water quality, restoring habitat and natural systems, improving navigation, eliminating aquatic invasive species, and building local resilience to natural disasters along the Mississippi River. The forum was a directive for the U.S. Geological Survey in the Consolidated Appropriations Act of 2022 (Public Law 117—103, 136 Stat. 49). Participants and stakeholders that attended the Mississippi River Science Forum indicated the following. A Mississippi River Science Committee could bring together the voices of all stakeholders, including Federal agencies; State, local, and Tribal governments; academia; nongovernmental organizations; business and industry; and other interested parties. This committee would also work with (but not replace) Mississippi River Basin entities already in place and establish effective communication to identify and address Basin-wide management needs and to develop holistic solutions for those needs. A Mississippi River science plan could expand on the science and data gaps identified by the Forum. This plan could guide data collection and help resource managers develop and implement restoration initiatives within the Basin, recognizing that addressing these needs will require substantial resources. The science committee, working with other entities in the basin, should develop data standards for the Mississippi River Basin that allow stakeholders to utilize comparable data to address their needs. These standards would include data findability, accessibility, interoperability, and reusability. This report highlights data gaps and areas of concern discussed during the forum, and it identifies needs to advance the goals of improving water quality, restoring habitat and natural systems, improving navigation, eliminating aquatic invasive species, and building local resilience to natural disasters with specific emphasis on data collection and measurement, and scientific investigation. The report also summarizes stakeholder input and feedback and outlines next steps identified by forum participants.

Open-File Report↗

USGS2012

Porphyry copper assessment of the Tibetan Plateau, China: Chapter F in Global mineral resource assessment

The U.S. Geological Survey collaborated with the China Geological Survey to conduct a mineral-resource assessment of resources in porphyry copper deposits on the Tibetan Plateau in western China. This area hosts several very large porphyry deposits, exemplified by the Yulong and Qulong deposits, each containing at least 7,000,000 metric tons (t) of copper. However, large parts of the area are underexplored and are likely to contain undiscovered porphyry copper deposits. Three tracts were delineated as permissive for porphyry copper deposits on the Tibetan Plateau—the Yulong (Eocene and Oligocene), Dali (Eocene through Miocene), and Gangdese (Oligocene and Miocene) tracts. The tracts were defined based on mapped and inferred subsurface distributions of igneous rocks of specific age ranges in which the occurrence of porphyry copper deposits is possible. These tracts range in area from about 95,000 to about 240,000 square kilometers. Although maps of different scales were used in the assessment, the final tract boundaries are intended for use at a scale of 1:1,000,000. The deposits on the Tibetan Plateau all formed in a post-subduction environment, one newly recognized as permissive for the occurrence of porphyry copper deposits. Based on the grade, tonnage, and geologic characteristics of the known deposits, two tracts, Yulong and Gangdese, were evaluated using the general (Cu-Mo-Au) porphyry copper grade and tonnage model. The Dali tract was evaluated using the gold-rich (Cu-Au) submodel. Assessment participants estimated numbers of undiscovered deposits at different levels of confidence for each permissive tract. These estimates were then combined with the selected grade and tonnage models using Monte Carlo simulation to generate quantitative probabilistic estimates of undiscovered resources. Additional resources in extensions of deposits with identified resources were not specifically evaluated. Assessment results, presented in tables and graphs, show mean expected amounts of metal and rock in undiscovered deposits at different quantile levels, as well as the arithmetic mean for each tract. This assessment estimated a mean of 39 undiscovered porphyry copper deposits within the assessed permissive tracts on the Tibetan Plateau. This represents nearly four times the number of known deposits (11) already discovered. Predicted mean (arithmetic) resources that could be associated with the undiscovered deposits are about 145,000,000 t of copper and about 4,900 t of gold, as well as byproduct molybdenum and silver. Reliable reports of the identified resources in the 11 known deposits total about 27,000,000 t of copper and about 800 t of gold. Therefore, based on the assessments of undiscovered Tibetan Plateau resources in this report, about six times as much copper may occur in undiscovered porphyry copper deposits as has been identified to date.

Tibetan Plateau↗

USGS2019

Use of set blanks in reporting pesticide results at the U.S. Geological Survey National Water Quality Laboratory, 2001-15

Executive Summary Background .—Pesticide results from the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) are used for water-quality assessments by many agencies and organizations. The USGS is committed to providing data of the highest possible quality to the consumers of its data. A cooperator’s inquiries about specific pesticide detections in water revealed potential laboratory contamination issues for some results. Consequently, the USGS conducted an extensive evaluation of potential low-level contamination related to processing or analysis of water-quality samples at NWQL for 21 pesticide compounds of interest to the cooperator. This is the most comprehensive study of NWQL pesticide quality-control (QC) results to date. Purpose and scope .—The purpose of this study was to document protocols used by the NWQL to censor pesticide results and to determine the effects of laboratory contamination—as determined from detections in laboratory set blanks—on pesticide detections in groundwater and surface-water samples. More than 30,000 pesticide results from 113 selected batches of samples (2 percent or less of total batches) analyzed by the NWQL during the 15 years from 2001 to 2015 were reviewed. All laboratory results from the selected batches, including results from environmental (surface water and groundwater) and QC (set-blank, blind-blank, and blind-spike) samples, were evaluated. The study includes results for 21 pesticide compounds analyzed in groundwater and surface-water samples collected across the United States. Eleven pesticide compounds were analyzed by a gas chromatography/mass spectrometry method and 10 compounds by a liquid chromatography/mass spectrometry method. Objectives and methods .—The objectives of this study were to (1) determine the characteristics of laboratory contamination over time, (2) compare distributions of pesticide results in set blanks with distributions in environmental samples, (3) evaluate the potential for false-positive and false-negative reporting of results, and (4) evaluate the effects of reevaluating historical pesticide results using 2017 compound identification protocols on detections of pesticides in groundwater and surface-water samples. The 113 instrument batches selected for this study contained detections of one or more of the 21 pesticide compounds in set blanks or were among those batches with the highest pesticide detection frequencies in set blanks. As a result, the dataset for this study was targeted toward pesticides and batches with laboratory contamination. The objectives were addressed by statistically comparing environmental and set-blank results; computing moving averages of set-blank detection frequencies to identify periods of episodic contamination; and using summary statistics, tabular summaries, and graphical approaches, such as time-series plots and cumulative distribution functions. Results .— Objective 1 : Laboratory contamination, as determined by pesticide detections in set blanks, was found in 13 percent of set-blank results from the 113 targeted batches included in this study (as compared to 6 percent of set-blank results from all 7,620 batches analyzed during the study period). It is estimated that 92 percent of the laboratory contamination during the study period was episodic, meaning that it occurred during discrete periods of time. All 21 of the targeted pesticide compounds had periods of episodic contamination, with most episodes ranging in duration from about 1 to 8 months. The remaining 8 percent of laboratory contamination was random or from a known source (deterministic). Objective 2 : For some compounds, graphs of cumulative distribution functions of the entire distributions of set-blank and environmental samples overlap, suggesting that there is no difference in the distributions of the two types of samples. However, time-series graphs show that detections in set blanks often occur at different times (sometimes separated by years) than detections in environmental samples, indicating clear differences in those distributions, and indicating the importance of evaluating the timing of detections in all sample types. For most compounds detected in set-blank and environmental samples, detection frequencies were significantly greater in set blanks than in groundwater or surface-water samples ( p <0.05). There are several explanations for this finding, including that the 113 batches of samples chosen for this study targeted batches with detections in set blanks or that detections in set-blank samples were historically determined with less stringent identification criteria than for environmental samples (groundwater and surface-water samples). Objective 3 : The false-positive and false-negative rates from blind samples submitted during the study period by the USGS Quality Systems Branch generally were less than 1 and 5 percent, respectively, for the 21 pesticides. The only compound with a false-positive rate greater than 1 percent was flumetsulam (2.6 percent), indicating that there is a higher likelihood of flumetsulam being reported as a detection when it is not present in an environmental sample compared with the reporting of other compounds. Objective 4 : Altogether, for data in targeted batches, NWQL would have reported 0.1 percent of results from groundwater samples and 1.4 percent of results from surface-water samples differently if 2017 identification protocols were applied to historical pesticide results. In most of these cases, detections observed in historical results would change to nondetections. The small percentages of changes that would occur if historical data were reevaluated indicate that historical protocols used by the NWQL to identify detections in environmental samples were robust and produced results that are predominantly consistent with current [2017] practices. Conclusions .—The NWQL produces high-quality pesticide results at environmentally relevant concentrations. NWQL identification protocols and censoring practices are largely effective at minimizing the reporting of false-positive and false-negative results. Laboratory contamination, when it occurred, tended to occur in episodes; thus, evaluating the timing and magnitude of detections in set blanks relative to detections in environmental samples was determined to be an important consideration for analysis of environmental results. Because NWQL censoring practices do not address all types and occurrences of laboratory contamination, options for additional censoring practices are provided for data users with more specific or stringent data-quality objectives. The methods used to analyze the 21 compounds for this report can similarly be applied to all 173 pesticide compounds that were analyzed by the NWQL during the same time period. This study also has helped to identify potential improvements in reporting USGS data, such as conducting more frequent review of set-blank datasets.

Scientific Investigations Report↗

USGS2025

Monitoring recreation on federally managed lands and waters—Visitation estimation

Federally managed public lands and waters attract millions of visitors each year, generating significant economic benefits for surrounding communities. Accurate visitation data are crucial for guiding policy decisions and managing resources effectively. This report explores the methods employed by agencies to collect and use data on recreational visitation to Federal lands and waters. Visitation estimation practices across seven agencies are reviewed, revealing similarities such as the use of automated counters for on-site data collection, alongside differences in reporting frequencies, visit definitions, and public access to data. Emerging technologies, including social media, mobile device activity, and community science, are also evaluated for their potential to improve visitation estimation. Although these technologies offer promising opportunities, they come with challenges such as data biases, the need for calibration, costs, and privacy concerns. The report concludes with opportunities to enhance data collection, coordination, and accessibility, ensuring more efficient resource management and informed decision making.

Scientific Investigations Report↗

USGS1956

Oxidation potential and state of some vanadium ores and the relation of woody material to their deposition

Oxidation potential studies with a multiple pH-potential recorder designed and constructed for this purpose demonstrated that some uranium-vanadium ores in the Colorado Plateau were in a reduced state when deposited. Any oxidation which took place occurred after deposition. Experimental and theoretical reducing studies on fresh wood, wood degraded by burial for 450 years, and lignite, indicate that such ores may have been deposited by reduction of oxidized vanadium solutions by woody material. A vanadium (III) mineral, V 2 O(OH) 4 , was prepared synthetically by reduction of a vanadium (V) solution with wood. This is the only reported synthesis of any reduced vanadium mineral by any method. It was shown that the origin of almost all vanadium deposits currently of commercial importance involves life processes and products.

Utah↗

USGS1976

Guidelines for collection and field analysis of ground-water samples for selected unstable constituents

The unstable nature of many chemical and physical constituents in ground water requires special collection procedures and field analysis immediately after collection. This report describes the techniques and equipment commonly used m the collection and field analysis of samples for pH, temperature, carbonate, bicarbonate, specific conductance, Eh, and dissolved oxygen.

Techniques of Water-Resources Investigations↗