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At least 811 records · Page 45Linked to original sources
USGS2008

Occurrence of endocrine active compounds and biological responses in the Mississippi River— Study design and data, June through August 2006

Concern that selected chemicals in the environment may act as endocrine active compounds in aquatic ecosystems is widespread; however, few studies have examined the occurrence of endocrine active compounds and identified biological markers of endocrine disruption such as intersex occurrence in fish longitudinally in a river system. This report presents environmental data collected and analyzed by the U.S. Geological Survey, Minnesota Pollution Control Agency and St. Cloud State University as part of an integrated biological and chemical study of endocrine disruption in fish in the Mississippi River. Data were collected from water, bed sediment, and fish at 43 sites along the river from the headwaters at Lake Itasca to 14 miles downstream from Brownsville, Minnesota during June through August 2006. Twenty-four individual compounds were detected in water samples, with cholesterol, atrazine, N,N-diethyl-meta-toluamide, metolachlor, and hexahydrohexamethylcyclopentabenzopyran detected most frequently (in at least 10 percent of the samples). The number of compounds detected in water per site ranged from 0 to 8. Forty individual compounds were detected in bed-sediment samples. The most commonly detected compounds (in at least 50 percent of the samples) were indole, beta-sitosterol, cholesterol, beta-stigmastanol, 3-methyl-1H-indole, p-cresol, pyrene, phenol, fluoranthene, 3-beta coprostanol, benzo[a]pyrene, acetophenone, and 2,6-dimethylnaphthalene. The total number of detections in bed sediment (at a site) ranged from 3 to 31. The compounds NP1EO, NP2EO, and 4-nonylphenol were detected in greater than 10 percent of the samples. Most (80 percent) female fish collected had measurable concentrations of vitellogenin. Vitellogenin also was detected in 62, 63, and 33 percent of male carp, smallmouth bass, and redhorse, respectively. The one male walleye sample plasma sample analyzed had a vitellogenin detection. Vitellogenin concentrations were lower in male fish (not detected to 10.80 micrograms per milliliter) than female fish (0.04 to 248,079 micrograms per milliliter). Gonadosomatic Index values ranged from 0.02 to 7.49 percent among all male fish and were greater for male carp than for the other three species. No intersex (oocytes present in testes tissue) was found in any male fish sampled.

Minnesota, Wisconsin↗
USGS2016

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, July 2015

Previous investigations indicate that concentrations of chlorinated volatile organic compounds (CVOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision for the site. This report presents groundwater geochemical and selected CVOC data collected at Operable Unit 1 by the U.S. Geological Survey during July 6–8 and July 31, 2015 in support of long-term monitoring for natural attenuation. Water samples were collected from 13 wells, 9 piezometers, and 13 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents. Samples from all piezometers and four wells also were analyzed for CVOCs and dissolved gases, as were all samples from the passive-diffusion sampling sites. In 2015, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations all less than 1 milligram per liter; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2015, CVOC concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were equivalent to the concentrations measured in 2014. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2015 continued to be variable as in previous years, and often very high, and reductive dechlorination byproducts were detected in one of the three wells and in piezometers. Beneath the marsh adjacent to the southern plantation, CVOC concentrations measured in 2015 continued to vary spatially and temporally, and were high. The total CVOC concentration, at what have been historically the most contaminated passive-diffusion sampler sites (S-4 T, S-4B T, and S-5 T), continued elevated trends, as did one of the new sampler sites (S-9 T) installed in 2015. For the intermediate aquifer in 2015, concentrations of reductive dechlorination byproducts ethane and ethene and CVOCs were consistent with those measured in previous years.

Washington↗
USGS2010

Archive of side scan sonar and swath bathymetry data collected during USGS cruise 10CCT01 offshore of Cat Island, Gulf Islands National Seashore, Mississippi, March 2010

In March of 2010, the U.S. Geological Survey (USGS) conducted geophysical surveys east of Cat Island, Mississippi (fig. 1). The efforts were part of the USGS Gulf of Mexico Science Coordination partnership with the U.S. Army Corps of Engineers (USACE) to assist the Mississippi Coastal Improvements Program (MsCIP) and the Northern Gulf of Mexico (NGOM) Ecosystem Change and Hazards Susceptibility Project by mapping the shallow geological stratigraphic framework of the Mississippi Barrier Island Complex. These geophysical surveys will provide the data necessary for scientists to define, interpret, and provide baseline bathymetry and seafloor habitat for this area and to aid scientists in predicting future geomorpholocial changes of the islands with respect to climate change, storm impact, and sea-level rise. Furthermore, these data will provide information for barrier island restoration, particularly in Camille Cut, and provide protection for the historical Fort Massachusetts. For more information refer to http://ngom.usgs.gov/gomsc/mscip/index.html. This report serves as an archive of the processed swath bathymetry and side scan sonar data (SSS). Data products herein include gridded and interpolated surfaces, surface images, and x,y,z data products for both swath bathymetry and side scan sonar imagery. Additional files include trackline maps, navigation files, GIS files, Field Activity Collection System (FACS) logs, and formal FGDC metadata. Scanned images of the handwritten FACS logs and digital FACS logs are also provided as PDF files. Refer to the Acronyms page for expansion of acronyms and abbreviations used in this report or hold the cursor over an acronym for a pop-up explanation. The USGS St. Petersburg Coastal and Marine Science Center assigns a unique identifier to each cruise or field activity. For example, 10CCT01 tells us the data were collected in 2010 for the Coastal Change and Transport (CCT) study and the data were collected during the first field activity for that project in that calendar year. Refer to http://walrus.wr.usgs.gov/infobank/programs/html/definition/activity.html for a detailed description of the method used to assign the field activity ID. Data were collected using a 26-foot (ft) Glacier Bay Catamaran. Side scan sonar and interferometric swath bathymetry data were collected simultaneously along the tracklines. The side scan sonar towfish was towed off the port side just slightly behind the vessel, close to the seafloor. The interferometric swath transducer was sled-mounted on a rail attached between the catamaran hulls. During the survey the sled is secured into position. Navigation was acquired with a CodaOctopus Octopus F190 Precision Attitude and Positioning System and differentially corrected with OmniSTAR. See the digital FACS equipment log for details about the acquisition equipment used. Both raw datasets were stored digitally and processed using CARIS HIPS and SIPS software at the USGS St. Petersburg Coastal and Marine Science Center. For more information on processing refer to the Equipment and Processing page. Post-processing of the swath dataset revealed a motion artifact that is attributed to movement of the pole that the swath transducers are attached to in relation to the boat. The survey took place in the winter months, in which strong winds and rough waves contributed to a reduction in data quality. The rough seas contributed to both the movement of the pole and the very high noise base seen in the raw amplitude data of the side scan sonar. Chirp data were also collected during this survey and are archived separately.

Mississippi↗
USGS2017

Groundwater-quality data in 12 GAMA study units: Results from the 2006–10 initial sampling period and the 2008–13 trend sampling period, California GAMA Priority Basin Project

The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey in cooperation with the California State Water Resources Control Board. From 2004 through 2012, the GAMA-PBP collected samples and assessed the quality of groundwater resources that supply public drinking water in 35 study units across the State. Selected sites in each study unit were sampled again approximately 3 years after initial sampling as part of an assessment of temporal trends in water quality by the GAMA-PBP. Twelve of the study units, initially sampled during 2006–11 (initial sampling period) and sampled a second time during 2008–13 (trend sampling period) to assess temporal trends, are the subject of this report. The initial sampling was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies in the 12 study units. In these study units, 550 sampling sites were selected by using a spatially distributed, randomized, grid-based method to provide spatially unbiased representation of the areas assessed (grid sites, also called “status sites”). After the initial sampling period, 76 of the previously sampled status sites (approximately 10 percent in each study unit) were randomly selected for trend sampling (“trend sites”). The 12 study units sampled both during the initial sampling and during the trend sampling period were distributed among 6 hydrogeologic provinces: Coastal (Northern and Southern), Transverse Ranges and Selected Peninsular Ranges, Klamath, Modoc Plateau and Cascades, and Sierra Nevada Hydrogeologic Provinces. For the purposes of this trend report, the six hydrogeologic provinces were grouped into two hydrogeologic regions based on location: Coastal and Mountain. The groundwater samples were analyzed for a number of synthetic organic constituents (volatile organic compounds, pesticides, and pesticide degradates), constituents of special interest (perchlorate and 1,2,3-trichloropropane), and natural inorganic constituents (nutrients, major and minor ions, and trace elements). Isotopic tracers (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) also were measured to help identify processes affecting groundwater quality and the sources and ages of the sampled groundwater. More than 200 constituents and water-quality indicators were measured during the trend sampling period. Quality-control samples (blanks, replicates, matrix-spikes, and surrogate compounds) were collected at about one-third of the trend sites, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. On the basis of detections in laboratory and field blank samples collected by GAMA-PBP study units, including the 12 study units presented here, reporting levels for some groundwater results were adjusted in this report. Differences between replicate samples were mostly within acceptable ranges, indicating low variability in analytical results. Matrix-spike recoveries were largely within the acceptable range (70 to 130 percent). This study did not attempt to evaluate the quality of water delivered to consumers. After withdrawal, groundwater used for drinking water typically is treated, disinfected, and blended with other waters to achieve acceptable water quality. The comparison benchmarks used in this report apply to treated water that is served to the consumer, not to untreated groundwater. To provide some context for the results, however, concentrations of constituents measured in these groundwater samples were compared with benchmarks established by the U.S. Environmental Protection Agency and the State of California. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most organic constituents that were detected in groundwater samples from the trend sites were found at concentrations less than health-based benchmarks. One volatile organic compound—perchloroethene—was detected at a concentration greater than the health-based benchmark in samples from one trend site during the initial and trend sampling periods. Chloroform was detected in at least 10 percent of the samples at trend sites in both sampling periods. Methyl tert -butyl ether was detected in samples from more than 10 percent of the trend sites during the initial sampling period. No pesticide or pesticide degradate was detected in greater than 10 percent of the samples from trend sites or at concentrations greater than their health-based benchmarks during either sampling period. Nutrients were not detected at concentrations greater than their health-based benchmarks during either sampling period. Most detections of major ions and trace elements in samples from trend sites were less than health-based benchmarks during both sampling periods. Arsenic and boron each were detected at concentrations greater than the health-based benchmark in samples from four trend sites during the initial and trend sampling periods. Molybdenum was detected in samples from four trend sites at concentrations greater than the health-based benchmark during both sampling periods. Samples from two of these trend sites had similar molybdenum concentrations, and two had substantially different concentrations during the initial and trend sampling periods. Uranium was detected at a concentration greater than the health-based benchmark only at two trend sites.

California↗
USGS2013

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June and October 2012

Previous investigations indicate that concentrations of chlorinated volatile organic compounds are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision for the site. This report presents groundwater geochemical and selected chlorinated volatile organic compound data collected at Operable Unit 1 by the U.S. Geological Survey during June and October 2012, in support of long-term monitoring for natural attenuation. Groundwater samples were collected from 13 wells and 9 piezometers, as well as from 10 shallow groundwater passive-diffusion sampling sites in the nearby marsh. Samples from all wells and piezometers were analyzed for oxidation-reduction (redox) sensitive constituents and dissolved gases. Samples from all piezometers also were analyzed for chlorinated volatile organic compounds, as were all samples from the passive-diffusion sampling sites. In 2012, concentrations of redox-sensitive constituents measured at all wells and piezometers were consistent with those measured in previous years, with dissolved oxygen concentrations all at 0.4 milligram per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. In the upper aquifer of the northern plantation in 2012, chlorinated volatile organic compound (CVOC) concentrations at all piezometers were similar to those measured in previous years, and concentrations of the reductive dechlorination byproducts ethane and ethene were slightly higher or the same as concentrations measured in 2011. In the upper aquifer of the southern plantation, CVOC concentrations measured in piezometers during 2012 continued to be extremely variable as in previous years, and often very high, and reductive dechlorination byproducts were detected in two of the four wells and in all piezometers. Beneath the marsh adjacent to the southern plantation, chloroethene concentrations measured in 2012 continued to vary spatially and temporarily, and also were very high. Additionally, CVOC concentrations measured in samplers deployed in access tubes were about two to four times less than those measured in the two samplers buried nearby, beneath the marsh stream. Total CVOC concentration, at what has been historically the most contaminated passive-diffusion sampler site (S-4), continued an increasing trend. For the intermediate aquifer in 2012, concentrations of reductive dechlorination byproducts ethane and ethene were consistent with those measured in previous years.

Washington↗
USGS2021

Characterization of deep-sea coral and sponge communities in Greater Farallones National Marine Sanctuary: Point Arena South Essential Fish Habitat Conservation Area and New Amendment 28 Areas

This report summarizes samples collected during a remotely operated vehicle (ROV) cruise conducted in October 2019 on board E/V Nautilus. Areas sampled in Greater Farallones National Marine Sanctuary included areas proposed for fisheries management zoning in the Point Arena South (PAS) Essential Fish Habitat Conservation Area (EFH). Dive planning targeted habitats and biological communities of corals, sponges, and fishes in relation to the new, 2020 configuration of PAS EFH (hereafter referred to as PAS), which includes areas once closed to commercial bottom trawling and now opened to bottom trawling, once opened to bottom trawling and now closed, or that remain closed to commercial bottom trawling. Particular interest was given to enumerating deep-sea corals and sponges (DSCS) in these areas as they are long-lived, slow-growing species that are vulnerable to impacts from bottom trawling. Fish species were also enumerated. These data provide the most recent assessment and characterization for a portion of these areas before the final ruling on Amendment 28 went into effect on January 1, 2020 (50 C.F.R. part 660). A total of seven sponge specimens were collected on this mission, some of which could potentially be new species, such as the large yellow ‘plate’-shaped sponge and the ‘palm frond’ morphology of the predatory sponge Asbestopluma , documented on both dives. Six coral collections were made, including three types of red Swiftia sp. gorgonians (two had fan-shaped morphology and one had branched morphology) with different polyp colors. A high diversity of fishes, particularly groundfish, were documented across the entire PAS area. The findings from this cruise will be provided to NOAA’s National Marine Fisheries Service to help them identify biologically complex areas of the seafloor that are most sensitive to bottom trawling and aid in the ongoing management of this designated essential fish habitat conservation zone. Habitat data from these surveys will be used to confirm substrate prediction models that can be used to predict DSCS habitats where there is a dearth of visual observations.

California↗
USGS2015

Groundwater quality data in 15 GAMA study units: results from the 2006–10 Initial sampling and the 2009–13 resampling of wells, California GAMA Priority Basin Project

The Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) program was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). From May 2004 to March 2012, the GAMA-PBP collected samples from more than 2,300 wells in 35 study units across the State. Selected wells in each study unit were sampled again approximately 3 years after initial sampling as part of an assessment of temporal trends in water quality by the GAMA-PBP. This triennial (every 3 years) trend sampling of GAMA-PBP study units concluded in December 2013. Fifteen of the study units, initially sampled between January 2006 and June 2010 and sampled a second time between April 2009 and April 2013 to assess temporal trends, are the subject of this report. The initial sampling was designed to provide a spatially unbiased assessment of the quality of untreated groundwater used for public water supplies in the 15 study units. In these study units, 730 wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the areas assessed (grid wells, also called “status wells”). Approximately 3 years after the initial sampling, 93 of the previously sampled status wells (approximately 10 percent in each study unit) were randomly selected for trend sampling (“trend wells”). The 15 study units sampled for trends were distributed among 4 hydrogeologic provinces: Central Valley, Basin and Range, Desert, and Transverse and selected Peninsular Ranges. The total number of status wells sampled, along with those sampled again for trends, varied by study unit. In the Central Valley hydrogeologic province, the numbers of status wells and trend wells in each study unit were as follows: Kern County subbasin study unit—47 status wells, 5 trend wells Central Eastside San Joaquin Basin study unit—58 status wells, 6 trend wells Middle Sacramento Valley study unit—71 status wells, 8 trend wells Northern Sacramento Valley study unit—43 status wells, 4 trend wells Madera–Chowchilla study unit—30 status wells, 4 trend wells Western San Joaquin Valley study unit—39 status wells, 4 trend wells. The Basin and Range hydrogeologic province had only one study unit: Owens and Indian Wells Valleys study unit—53 status wells, 6 trend wells. In the Desert hydrogeologic province, the numbers of wells were as follows: Coachella Valley study unit—19 status wells 4 trend wells Colorado River study unit—20 status wells, 3 trend wells Antelope Valley study unit—56 status wells, 6 trend wells Mojave study unit—52 status wells, 7 trend wells Borrego Valley, Central Desert and Low-Use Basins of the Mojave and Sonoran Deserts study unit—49 status wells, 6 trend wells. In the Transverse and Selected Peninsular Ranges hydrogeologic province, the numbers of wells were as follows: Coastal Los Angeles Basin study unit—61 status wells, 8 trend wells Upper Santa Ana Watershed study unit—90 status wells, 16 trend wells Santa Clara River Valley study unit—42 status wells, 6 trend wells. The groundwater samples were analyzed for a number of synthetic organic constituents (volatile organic compounds, pesticides, and pesticide degradates), constituents of special interest (perchlorate, N -nitrosodimethylamine [NDMA], and 1,2,3-trichloropropane [1,2,3-TCP]), and naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements). Naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) also were measured to help identify processes affecting groundwater quality and the sources and ages of the sampled groundwater. More than 200 constituents and water-quality indicators were investigated. Quality-control samples (blanks, replicates, or samples for matrix spikes) were collected at 34 percent of the trend wells, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. On the basis of detections in laboratory and field blanks in samples from GAMA-PBP study units, including the study units presented here, some groundwater results were adjusted in this report. Differences between replicate samples were mostly within acceptable ranges, indicating acceptably low variability in analytical results. Median matrix-spike recoveries were within the acceptable range (70 to 130 percent) for 189 of the 224 compounds for which matrix spikes were analyzed (84 percent). This study did not attempt to evaluate the quality of water delivered to consumers. After withdrawal, groundwater used for drinking water typically is treated, disinfected, and blended with other waters to attain acceptable water quality. The benchmarks used in this report apply to treated water that is served to the consumer, not to untreated groundwater. To provide some context for the results, however, concentrations of constituents measured in these groundwater samples were compared with benchmarks established by the U.S. Environmental Protection Agency and California Department of Public Health. Comparisons between data collected for this study and benchmarks for drinking-water quality are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most constituents that were detected in groundwater samples from the trend wells were found at concentrations less than drinking-water benchmarks. Two volatile organic compounds (VOCs)—tetrachloroethene and trichloroethene—were detected in samples from one or more wells at concentrations greater than their health-based benchmarks, and three VOCs—chloroform, tetrachloroethene, and trichloroethene—were detected in at least 10 percent of the trend-well samples from the initial sampling period and the later trend sampling period. No pesticides were detected at concentrations near or greater than their health-based benchmarks. Three pesticide constituents—atrazine, deethylatrazine, and simazine—were detected in more than 10 percent of the trend-well samples in both sampling periods. Perchlorate, a constituent of special interest, was detected at a concentration greater than its health-based benchmark in samples from one trend well in the initial sampling and trend sampling periods, and in an additional trend well sample only in the trend sampling period. Most detections of nutrients, major and minor ions, and trace elements in samples from trend wells were less than health-based benchmarks in both sampling periods. Exceptions included nitrate, fluoride, arsenic, boron, molybdenum, strontium, and uranium; these were all detected at concentrations greater than their health-based benchmarks in at least one well sample in both sampling periods. Lead and vanadium were detected above their health-based benchmarks in one sample each collected in the initial sampling period only. The isotopic ratios of oxygen and hydrogen in water and the activities of tritium and carbon-14 generally changed little between sampling periods.

California↗
USGS2015

Evaluation of fisher (Pekania pennanti) restoration in Olympic National Park and the Olympic Recovery Area: 2014 annual progress report

With the translocation and release of 90 fishers ( Pekania pennanti ) from British Columbia to Olympic National Park during 2008–2010, the National Park Service and Washington Department of Fish and Wildlife accomplished the first phase of fisher restoration in Washington State. Beginning in 2013, we initiated a new research project to determine the current status of fishers on Washington’s Olympic Peninsula 3–5 years after the releases and evaluate the short-term success of the restoration program. Objectives of the study are to determine the current distribution of fishers and proportion of the recovery area that is currently occupied by fishers, determine several genetic characteristics of the reintroduced population, and determine reproductive success of the founding animals through genetic studies. During 2014, we continued working with a broad coalition of cooperating agencies, tribes, and nongovernmental organizations (NGO) to collect data on fisher distribution and genetics using noninvasive sampling methods. The primary sampling frame consisted of 157 24-square-kilometer hexagons (hexes) distributed across all major land ownerships within the Olympic Peninsula target survey area. In 2014 we expanded the study by adding 58 more hexes to an expanded study area in response to incidental fisher observations outside of the target area obtained in 2013; 49 hexes were added south and 9 to the east of the target area. During 2014, federal, state, tribal and NGO biologists and volunteers established three baited motion-sensing camera stations, paired with hair snaring devices, in 80 hexes; 69 in the targeted area 11 in the expansion areas. Each paired camera/hair station was left in place for approximately 6 weeks, with three checks on 2-week intervals. We documented fisher presence in 5 of the 80 hexagons, and identified 5 different fishers through a combination of microsatellite DNA analyses and camera detections. All fisher detections were in the target area. These 5 individuals included 2 of the original founding population of 90, 1 of the 2 rescued and rehabilitated kits that were released in 2010, and 1 new recruit to the population (1 individual was not identified). Additionally, we identified more than 40 other species of wildlife at the baited camera stations. We also obtained eight incidental fisher observations through photographs and carcass retrieval. During 2015, we plan to sample 75 hexagons in the target area and 12 in the expansion area. We plan to sample all unsampled accessible hexes in the target area (26 hexes), and re-sample accessible hexes sampled in 2013 (49 hexes).

Washington↗
USGS2005

California GAMA program: ground-water quality data in the San Diego drainages hydrogeologic province, California, 2004

Because of concerns over ground-water quality, the California State Water Resources Control Board (SWRCB), in collaboration with the U.S. Geological Survey and Lawrence Livermore National Laboratory, has implemented the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. A primary objective of the program is to provide a current assessment of ground-water quality in areas where public supply wells are an important source of drinking water. The San Diego GAMA study unit was the first region of the state where an assessment of ground-water quality was implemented under the GAMA program. The San Diego GAMA study unit covers the entire San Diego Drainages hydrogeologic province, and is broken down into four distinct hydrogeologic study areas: the Temecula Valley study area, the Warner Valley study area, the Alluvial Basins study area, and the Hard Rock study area. A total of 58 ground-water samples were collected from public supply wells in the San Diego GAMA study unit: 19 wells were sampled in the Temecula Valley study area, 9 in the Warner Valley study area, 17 in the Alluvial Basins study area, and 13 in the Hard Rock study area. Over 350 chemical and microbial constituents and water-quality indicators were analyzed for in this study. However, only select wells were measured for all constituents and water-quality indicators. Results of analyses were calculated as detection frequencies by constituent classification and by individual constituents for the entire San Diego GAMA study unit and for the individual study areas. Additionally, concentrations of constituents that are routinely monitored were compared to maximum contaminant levels (MCL) and secondary maximum contaminant levels (SMCL). Concentrations of constituents classified as 'unregulated chemicals for which monitoring is required' (UCMR) were compared to the 'detection level for the purposes of reporting' (DLR). Eighteen of the 88 volatile organic compounds (VOCs) and gasoline oxygenates analyzed for were detected in ground-water samples. Twenty-eight wells sampled in the San Diego GAMA study had at least a single detection of VOCs or gasoline oxygenates. These constituents were most frequently detected in the Alluvial Basin study area (11 of 17 wells), and least frequently detected in the Warner Valley study area (one of nine wells). Trihalomethanes (THMs) were the most frequently detected class of VOCs (18 of 58 wells). The most frequently detected VOCs were chloroform (18 of 58 wells), bromodichloromethane (8 of 58 wells), and methyl tert-butyl ether (MTBE) (7 of 58 wells). Three VOCs were detected at concentrations greater than their MCLs. Tetrachloroethylene (PCE) and trichloroethylene (TCE) were detected in one well in the Hard Rock study area at concentrations of 9.75 and 7.27 micrograms per liter (?g/L), respectively; the MCL for these compounds is 5 ?g/L. MTBE was detected in one well in the Alluvial Basins study area at a concentration of 28.3 ?g/L; the MCL for MTBE is 13 ?g/L. Twenty-one of the 122 pesticides and pesticide degradates analyzed for were detected in ground-water samples. Pesticide or pesticide degradates were detected in 33 of 58 wells sampled, and were most frequently detected in the Temecula Valley study area wells (9 of 14 wells), and least frequently in the Warner Valley study area wells (3 of 9 wells). Herbicides were the most frequently detected class of pesticides (31 of 58 wells), and simazine was the most frequently detected compound (27 of 58 wells), followed by deethylatrazine (14 of 58 wells), prometon (10 of 58 wells), and atrazine (9 of 58 wells). None of the pesticides detected in ground-water samples had concentrations that exceeded MCLs. Eight waste-water indicator compounds were detected in ground-water samples. Twenty-one of 47 wells sampled for waste-water indicator compounds had at least a single detection. Waste-water indicator compounds were detected most frequently in the Allu

Data Series↗
USGS2012

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June 2011

Previous investigations indicate that concentrations of chlorinated volatile organic compounds are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington. Phytoremediation combined with ongoing natural attenuation processes was the preferred remedy selected by the U.S. Navy, as specified in the Record of Decision for the site. The U.S. Navy planted two hybrid poplar plantations on the landfill in spring 1999 to remove and to control the migration of chlorinated volatile organic compounds in shallow groundwater. The U.S. Geological Survey has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision. This report presents groundwater geochemical and selected volatile organic compound data collected at Operable Unit 1 by the U.S. Geological Survey during June 20-22, 2011, in support of long-term monitoring for natural attenuation. In 2011, groundwater samples were collected from 13 wells and 9 piezometers. Samples from all wells and piezometers were analyzed for redox sensitive constituents and dissolved gases, and samples from 5 of 13 wells and all piezometers also were analyzed for chlorinated volatile organic compounds. Concentrations of redox sensitive constituents measured in 2011 were consistent with previous years, with dissolved oxygen concentrations all at 0.4 milligram per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. The reductive declorination byproducts - methane, ethane, and ethene - were either not detected in samples collected from the upgradient wells in the landfill and the upper aquifer beneath the northern phytoremediation plantation or were detected at concentrations less than those measured in 2010. Chlorinated volatile organic compound concentrations in 2011 at most piezometers were similar to or slightly less than chlorinated volatile organic compound concentrations measured in previous years. For the upper aquifer beneath the southern phytoremediation plantation, chlorinated volatile organic compound concentrations in 2011 in groundwater from the piezometers were extremely high and continued to vary considerably over space and between years. At piezometer P1-9, the total chlorinated volatile organic compound concentrations increased from 9,500 micrograms per liter in 2010 to more than 44,000 micrograms per liter in 2011. Total chlorinated volatile organic compound concentrations decreased at piezometers P1-6, P1-7, and P1-10 compared to the concentrations measured in 2010. One or both of the reductive dechlorination byproducts ethane and ethene were detected at all piezometers and three of the four wells in the southern plantation. For the intermediate aquifer, concentrations of redox sensitive constituents and chlorinated volatile organic compounds in 2011 were consistent with concentrations measured in previous years, with the exception of notable decreases in sulfate and chloride concentrations at well MW1-28. Concentrations of the reductive dechlorination byproducts ethane and ethene decreased at wells MW1-25 and MW1-28 compared to previously measured concentrations.

Washington↗
USGS2006

Water-Quality Data, 1999-2005, and Ground-Water Level Data, 2004-2005, for McBaine Bottoms, Including the Eagle Bluffs Conservation Area, Columbia, Missouri

The U.S. Geological Survey, in cooperation with the city of Columbia, Missouri, and the Missouri Department of Conservation, collected ground-water quality data from June 1999 through August 2005, surface-water quality data from August 1999 through August 2003, and water-level data from February 2004 through August 2005 in McBaine Bottoms, southwest of Columbia. McBaine Bottoms, adjacent to the Missouri River, is the location of the municipal-supply well field for the city of Columbia, the city of Columbia wastewater-treatment wetlands, and the Missouri Department of Conservation Eagle Bluffs Conservation Area. This report presents water-quality data, which include water-quality analyses of samples collected from 36 water-quality sampling sites (31 were wells and 5 were surface-water sites), and ground-water level data, which include water-level measurements from more than 80 wells. Water samples were analyzed for physical properties, inorganic chemical constituents, nutrients, and dissolved iron. Selected samples were analyzed for trace elements, wastewater organic compounds, and pesticides. In samples from monitoring wells, chloride concentrations ranged from 2.41 to 259 mg/L (milligrams per liter), sodium concentrations ranged from 1.08 to 175 mg/L, and sulfate concentrations ranged from less than 0.2 to 271 mg/L (all concentrations were dissolved). Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 0.46 mg/L. Total phosphorous concentrations ranged from less than 0.04 to 1.68 mg/L, dissolved phosphorous concentrations ranged from less than 0.04 to 1.50 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 1.83 mg/L. Dissolved iron concentrations ranged from less than 6 to 42,900 g/L (micrograms per liter). Dissolved arsenic concentrations in samples from two monitoring wells ranged from 11 to 37 g/L. In samples from surface-water sampling sites, chloride concentrations ranged from 8.67 to 289 mg/L, sodium concentrations ranged from 6.18 to 219 mg/L, and sulfate concentrations ranged from 33.4 to 119 mg/L. All of the minimum concentrations were detected in samples from Perche Creek. Dissolved nitrite plus nitrate as nitrogen concentrations ranged from less than 0.05 to 1.53 mg/L. Total phosphorous concentrations ranged from 0.07 to 3.06 mg/L, dissolved phosphorous concentrations ranged from less than 0.05 to 2.88 mg/L, and dissolved orthophosphorous concentrations ranged from less than 0.01 to 2.86 mg/L. Most of the maximum concentrations were detected in samples from the city outflow. More than 35 wastewater organic compounds and pesticides were detected in samples from the city outflow. However, most concentrations were estimated or their presence verified, but not quantified. Water levels in monitoring wells ranged from 548.54 to 576.55 ft (feet) above the National Geodetic Vertical Datum of 1929 (NGVD 29). The difference in water levels from February 2004 to August 2005 ranged from 0.13 ft to 10.97 ft.

Data Series↗
USGS2024

Control of introduced American bullfrogs and support of Chiricahua leopard frog conservation in southeast Arizona

1. This report summaries field surveys conducted during July 2023 through April 2024 to control introduced American bullfrogs ( Lithobates [ Rana ] catesbeianus ; hereafter bullfrog) and support Chiricahua leopard frog ( Lithobates [ Rana ] chiricahuensis ) conservation in southeast Arizona. We conducted 394 field surveys across 141 sites in Chiricahua leopard frog Recovery Units 1 and 2 during this survey period. 2. During these surveys, we detected bullfrogs at 36 sites and removed a total of 452 bullfrogs. Bullfrog reproduction was only observed during this survey period at sites on private property where we did not have landowner permission to remove bullfrogs. We found bullfrogs and Chiricahua leopard frogs co-occurring at only a single site (Chulo Tank). Only a single bullfrog was present at this site, and it was removed. 3. Within the Cobre Ridge/Recovery Unit 1 region, we detected Chiricahua leopard frogs at 15 sites, with reproductive activity confirmed at two sites. We performed or assisted with Chiricahua leopard frog translocations at five sites. We detected Chiricahua leopard frog overwinter survival at two sites in this region although moribund and dead frogs were observed at one of these two sites. 4. We did not detect Chiricahua leopard frog within our Canelo Hills Buffer Zone or stock tanks along the foothills of the San Rafael Valley. We detected Chiricahua leopard frogs at four sites on the Appleton-Whittell Research Ranch with reproduction documented at two sites. We also removed two adult bullfrogs from a single site. 5. We detected Chiricahua leopard frogs at 17 sites on the Las Cienegas National Conservation Area (LCNCA). While Chiricahua leopard frog reproduction was not confirmed during July–November of 2023, as of 24 April 2025 we detected Chiricahua leopard frog reproduction at three sites. We did detect a moribund Chiricahua leopard frog at Lower Empire Gulch in March 2024. No bullfrogs were detected on the LCNCA and a single adult bullfrog was removed from one site in the Elgin Buffer Zone. 6. We began bullfrog removal efforts at a new eradication site along the Babocomari River on the Babacomari Ranch. This planned four-year eradication project will remove a significant non-urban bullfrog source population that threatens existing Chiricahua leopard frog metapopulations.

Arizona↗
USGS2023

Evaluating the spatial and temporal distribution and ecology of Bighead and Silver Carp and native fishes of the lower Red River basin

We investigated the spatial and temporal distribution of Bighead Carp and Silver Carp (hereafter Carp) in the lower Red River basin of Arkansas. Our study objectives were: 1) determine the spatial and temporal extent of Bighead and Silver Carp in the Red River basin of Arkansas; 2) determine habitat associations of large river fish assemblages; and 3) summarize the demographics of Bighead and Silver Carp. We sampled 67 reaches in the lower Red River and its major tributaries for juvenile Carp and other small-bodied fishes (24 of the reaches were in the Arkansas portion of the Red River). We conducted repeated surveys in these reaches where the reaches were sampled 2-3 times over approximately 2 years representing 242 surveys (95 surveys in Arkansas). We completed adult Carp and native fish assemblage sampling across 61 reaches (22 reaches in Arkansas) where we also repeated surveys at these locations (245 total surveys, 100 surveys completed in Arkansas during the reporting period). We captured the most large-bodied fishes (including Carp) using gillnets and electrofishing, whereas fyke nets and seine hauls collected mainly smaller-bodied fishes. Hoop nets captured fewer fishes when compared to other gear types. We sampled 120,072 fishes, comprising 70 species and 41 genera, from the mainstem Red River in Arkansas. We used data associated with the entire catchment (including OK and TX data) to model the occupancy of adult fishes including both carp species. Carp tended to occupy reaches with the presence of slackwater habitat, that were deeper and narrower (lower habitat complexity), with higher discharge conditions, and were positively associated with chlorophyll-a concentrations. Adult and juvenile assemblage structure varied with reach scale attributes with notable differences among some taxonomically similar species. No carp under the age of 3 were sampled in the catchment. Bighead Carp and Silver Carp in the Red River catchment appear to live longer and grow larger than other populations. Silver Carp and Bighead Carp in the lower Red River had a theoretical maximum length (𝐿 ∞ ) of 920 and 1,348-mm TL, respectively. The oldest sampled Silver Carp and Bighead Carp were age 14 and 17, respectively. Bighead Carp growth was positively associated with warmer air temperatures and negatively associated with discharge variability. Similarly, Silver Carp growth was positively associated with warm air temperature and negatively associated with discharge variability. However, Silver Carp growth was also positively related to high discharge conditions and the variability of air temperature. Silver Carp annual mortality was relatively low and recruitment into the population appeared steady. It appears that Carp are likely coming from another catchment, have only limited or periodic successful reproduction in the study area, or spawn downriver in LA. Continued monitoring for reproductive success would be helpful. Moreover, if the goal is to greatly reduce or eliminate carp, then strategies that prevent further immigration before reproduction occurs or becomes more successful would be ideal. Targeted removal may then be useful for reducing numbers already in the catchment; however, there are also oxbow lakes that contain carp but appear only connected to the river during major floods (i.e., possible source locations).

Arkansas, Oklahoma, Texas↗
USGS2023

Evaluating the spatial and temporal distribution and ecology of Bighead and Silver Carp and native fishes of the lower Red River basin

We investigated the spatial and temporal distribution of Bighead Carp and Silver Carp (hereafter Carp) in the lower Red River basin of Arkansas. Our study objectives were: 1) determine the spatial and temporal extent of Bighead and Silver Carp in the Red River basin of Arkansas; 2) determine habitat associations of large river fish assemblages; and 3) summarize the demographics of Bighead and Silver Carp. We sampled 67 reaches in the lower Red River and its major tributaries for juvenile Carp and other small-bodied fishes (24 of the reaches were in the Arkansas portion of the Red River). We conducted repeated surveys in these reaches where the reaches were sampled 2-3 times over approximately 2 years representing 242 surveys (95 surveys in Arkansas). We completed adult Carp and native fish assemblage sampling across 61 reaches (22 reaches in Arkansas) where we also repeated surveys at these locations (245 total surveys, 100 surveys completed in Arkansas during the reporting period). We captured the most large-bodied fishes (including Carp) using gillnets and electrofishing, whereas fyke nets and seine hauls collected mainly smaller-bodied fishes. Hoop nets captured fewer fishes when compared to other gear types. We sampled 120,072 fishes, comprising 70 species and 41 genera, from the mainstem Red River in Arkansas. We used data associated with the entire catchment (including OK and TX data) to model the occupancy of adult fishes including both carp species. Carp tended to occupy reaches with the presence of slackwater habitat, that were deeper and narrower (lower habitat complexity), with higher discharge conditions, and were positively associated with chlorophyll-a concentrations. Adult and juvenile assemblage structure varied with reach scale attributes with notable differences among some taxonomically similar species. No carp under the age of 3 were sampled in the catchment. Bighead Carp and Silver Carp in the Red River catchment appear to live longer and grow larger than other populations. Silver Carp and Bighead Carp in the lower Red River had a theoretical maximum length (L_∞) of 920 and 1348-mm TL, respectively. The oldest sampled Silver Carp and Bighead Carp were age 14 and 17, respectively. Bighead Carp growth was positively associated with warmer air temperatures and negatively associated with discharge variability. Similarly, Silver Carp growth was positively associated with the warm air temperature and negatively associated with discharge variability. However, Silver Carp growth was also positively related to high discharge conditions and the variability of air temperature. Silver Carp annual mortality was relatively low and recruitment into the population appeared steady. It appears that Carp are likely coming from another catchment, have only limited or periodic successful reproduction in the study area, or spawn downriver in LA. Continued monitoring for reproductive success would be helpful. Moreover, if the goal is to greatly reduce or eliminate carp, then strategies to prevent further immigration would be ideal before reproduction occurs or becomes more successful. Targeted removal may then be useful for reducing numbers already in the catchment; however, there are also oxbow lakes that contain carp but appear only connected to the river during major floods (i.e., possible source locations).

Cooperator Science Series↗
USGS2009

Riparian Land Use/Land Cover Data for Three Study Units in Group II of the Nutrient Enrichment Effects Topical Study of the National Water-Quality Assessment Program

This data set was developed as part of the National Water-Quality Assessment (NAWQA) Program, Nutrient Enrichment Effects Topical (NEET) study. This report is concerned with three of the eight NEET study units distributed across the United States: Ozark Plateaus, Upper Mississippi River Basin, and Upper Snake River Basin, collectively known as Group II of the NEET study. Ninety stream reaches were investigated during 2006-08 in these three study units. Stream segments, with lengths equal to the base-10 logarithm of the basin area, were delineated upstream from the stream reaches through the use of digital orthophoto quarter-quadrangle (DOQQ) imagery. The analysis area for each stream segment was defined by a streamside buffer extending laterally to 250 meters from the stream segment. Delineation of landuse and land-cover (LULC) map units within stream-segment buffers was completed using on-screen digitizing of riparian LULC classes interpreted from the DOQQ. LULC units were classified using a strategy consisting of nine classes. National Wetlands Inventory (NWI) data were used to aid in wetland classification. Longitudinal riparian transects (lines offset from the stream segments) were generated digitally, used to sample the LULC maps, and partitioned in accord with the intersected LULC map-unit types. These longitudinal samples yielded the relative linear extent and sequence of each LULC type within the riparian zone at the segment scale. The resulting areal and linear estimates of LULC extent filled in the spatial-scale gap between the 30-meter resolution of the 1990s National Land Cover Dataset and the reach-level habitat assessment data collected onsite routinely for NAWQA ecological sampling. The resulting data consisted of 12 geospatial data sets: LULC within 25 meters of the stream reach (polygon); LULC within 50 meters of the stream reach (polygon); LULC within 50 meters of the stream segment (polygon); LULC within 100 meters of the stream segment (polygon); LULC within 150 meters of the stream segment (polygon); LULC within 250 meters of the stream segment (polygon); frequency of gaps in woody vegetation at the reach scale (arc); stream reaches (arc); longitudinal LULC transect sample at the reach scale (arc); frequency of gaps in woody vegetation at the segment scale (arc); stream segments (arc); and longitudinal LULC transect sample at the segment scale (arc).

Data Series↗
USGS2005

Occurrence of selected pharmaceutical and non-pharmaceutical compounds, and stable hydrogen and oxygen isotope ratios, in a riverbank filtration study, Platte River, Nebraska, 2001 to 2003, Volume 1

Although studied extensively in recent years in Europe, the occurrence of endocrine disrupters and other organic wastewater compounds in the environment in the United States is not well documented. To better understand the efficiency of riverbank filtration with respect to endocrine disrupting compounds and to evaluate the use of riverbank filtration as an effective means of drinking-water treatment, a study was conducted during 2001-2003 by the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency and the City of Lincoln, at an established riverbank-filtration well field with horizontal collector wells and vertical wells. This study provides information that will be useful for (1) increased understanding of the processes and factors important in controlling the transport of endocrine disrupters, such as pesticides and pharmaceuticals during riverbank filtration, (2) better understanding of the physical and chemical processes that affect riverbank-filtration efficiency, and (3) managing the water resources of the eastern Platte River Basin. This report presents analytical methods and data collected during the study. Data are presented as generalized statistics and in figures showing temporal variations. Sites from which water-quality samples were collected for this study included wastewater sites (a cattle feedlot lagoon, a hog confinement lagoon, and wastewater-treatment plant effluent), surface-water sites (Platte River, Salt Creek, and Loup Power Canal), ground-water sites (one collector well and three vertical wells), and drinking-water sites (raw and finished). Field water-quality properties were measured in samples from these sites. Pharmaceutical compounds were detected often in the wastewater-treatment plant effluent. Surface and ground water showed low-level concentrations of pharmaceuticals. Finished drinking-water samples did not contain detectable concentrations of pharmaceuticals except for low levels of cotinine and caffeine. Antibiotics were found in some of the wastewater samples and twice in Salt Creek. Antibiotics were not detected in any samples from the Platte River or the well field. Surface-water samples were analyzed for total organic carbon and ground-water samples were analyzed for dissolved organic carbon. Samples from all sites were analyzed for major ions. Herbicides commonly detected in surface, ground, and drinking water included acetachlor, alachlor, atrazine, and metolachlor as well as degradates of these compounds. Most of the samples from wastewater sites were found to contain predominantly acetamide degradates. High concentrations of several organic wastewater indicator compounds were detected at the wastewater sites and in Salt Creek. Several organic wastewater indicator compounds were detected multiple times in samples from the Platte River. Bromoform, a by-product of disinfection in the treatment plant, was found in samples from the finished drinking water. Stable hydrogen isotope ratios show a range in seasonal variation of -73.6 per mill to -38.1 per mill relative to Vienna Standard Mean Ocean Water (VSMOW) reference water and -69.2 per mill to -46.5 per mill for surface water and ground water, respectively. Oxygen isotope ratios for surface-water samples varied between -9.86 per mill and -5.05 per mill. Stable oxygen isotope ratios of ground waters varied between -9.62 per mill and -5.81 per mill.

Nebraska↗
USGS2011

Groundwater geochemical and selected volatile organic compound data, Operable Unit 1, Naval Undersea Warfare Center, Division Keyport, Washington, June 2009

Previous investigations indicate that natural attenuation and biodegradation of chlorinated volatile organic compounds (VOCs) are substantial in groundwater beneath the 9-acre former landfill at Operable Unit 1 (OU 1), Naval Undersea Warfare Center, Division Keyport, Washington. Phytoremediation combined with ongoing natural attenuation processes was the preferred remedy selected by the U.S. Navy, as specified in the Record of Decision for the site. The U.S. Navy planted two hybrid poplar plantations on the landfill in spring 1999 to remove and to control the migration of chlorinated VOCs in shallow groundwater. The U.S. Geological Survey (USGS) has continued to monitor groundwater geochemistry to ensure that conditions remain favorable for contaminant biodegradation as specified in the Record of Decision. This report presents groundwater geochemical and selected VOC data collected at OU 1 by the USGS during June 15-17, 2009, in support of long-term monitoring for natural attenuation. For 2009, groundwater samples were collected from 13 wells and 9 piezometers. Samples from all wells and piezometers were analyzed for redox sensitive constituents, and samples from 10 of 18 upper-aquifer wells and piezometers and 3 of 4 intermediate-aquifer wells also were analyzed for chlorinated VOCs. Concentrations of redox sensitive constituents measured in 2009 were consistent with previous years, with dissolved hydrogen (H2) concentrations ranging from less than 0.1 to 1.8 nanomolar (nM), dissolved oxygen concentrations all at 0.6 milligram per liter or less; little to no detectable nitrate; abundant dissolved manganese, iron, and methane; and commonly detected sulfide. The reductive declorination byproducts-methane, ethane, and ethene-were not detected in samples collected from the upgradient wells in the landfill or the upper aquifer beneath the northern phytoremediation plantation. Chlorinated VOC concentrations in 2009 at most piezometers were similar to or slightly less than chlorinated VOC concentrations measured in previous years. In 2009, concentrations of reductive dechlorination byproducts ethane and ethene were less than those measured in 2008 at most northern plantation wells and piezometers. For the upper aquifer beneath the southern phytoremediation plantation, chlorinated VOC concentrations in 2009 at the piezometers were extremely high and continued to vary considerably over space and between years. At piezometer P1-9, the total chlorinated VOC concentration increased from 25,000 micrograms per liter in 2008 to more than 172,000 micrograms per liter in 2009. At piezometer P1-7 in 2009, the concentrations of trichloroethene and cis-1,2-dichloroethene (cis-DCE) were the highest to date. The reductive dechlorination byproducts ethane and ethene were detected at all wells and piezometers in the southern plantation with the exception of piezometer P1-8, although the measured concentrations were not consistently high. For the intermediate aquifer, concentrations of redox sensitive constituents and VOCs in 2009 at wells MW1-25, MW1-28, and MW1-39 were consistent with concentrations measured in previous years. Concentrations of the reductive dechlorination byproducts ethane and ethene at wells MW1-25 and MW1-28 were equal to or greater than previously measured concentrations.

Washington↗
USGS2007

Concentrations of selected pharmaceuticals and antibiotics in south-central Pennsylvania waters, March through September 2006

This report presents environmental and quality-control data from analyses of 15 pharmaceutical and 31 antibiotic compounds in water samples from streams and wells in south-central Pennsylvania. The analyses are part of a study by the U.S. Geological Survey (USGS) in cooperation with the Pennsylvania Department of Environmental Protection (PADEP) to define concentrations of selected emerging contaminants in streams and well water in Pennsylvania. Sampling was conducted at 11 stream sites and at 6 wells in 9 counties of south-central Pennsylvania. Five of the streams received municipal wastewater and 6 of the streams received runoff from agricultural areas dominated by animal-feeding operations. For all 11 streams, samples were collected at locations upstream and downstream of the municipal effluents or animal-feeding operations. All six wells were in agricultural settings. A total of 120 environmental samples and 21 quality-control samples were analyzed for the study. Samples were collected at each site in March/April, May, July, and September 2006 to obtain information on changes in concentration that could be related to seasonal use of compounds. For streams, 13 pharmaceuticals and 11 antibiotics were detected at least 1 time. Detections included analytical results that were estimated or above the minimum reporting limits. Seventy-eight percent of all detections were analyzed in samples collected downstream from municipal-wastewater effluents. For streams receiving wastewater effluents, the pharmaceuticals caffeine and para-xanthine (a degradation product of caffeine) had the greatest concentrations, 4.75 μg/L (micrograms per liter) and 0.853 μg/L, respectively. Other pharmaceuticals and their respective maximum concentrations were carbamazepine (0.516 μg/L) and ibuprofen (0.277 μg/L). For streams receiving wastewater effluents, the antibiotic azithromycin had the greatest concentration (1.65 μg/L), followed by sulfamethoxazole (1.34 μg/L), ofloxacin (0.329 μg/L), and trimethoprim (0.256 μg/L). For streams receiving runoff from animal-feeding operations, the only pharmaceuticals detected were acetaminophen, caffeine, cotinine, diphenhydramine, and carbamazepine. The maximum concentration for pharmaceuticals was 0.053 μg/L. Three streams receiving runoff from animal-feeding operations had detections of one or more antibiotic compound--oxytetracycline, sulfadimethoxine, sulfamethoxazole, and tylosin. The maximum concentration for antibiotics was 0.157 μg/L. The average number of compounds (pharmaceuticals and antibiotics) detected in sites downstream from animal-feeding operations was three. The average number of compounds detected downstream from municipal-wastewater effluents was 13. For wells used to supply livestock, four compounds were detected--two pharmaceuticals (cotinine and diphenhydramine) and two antibiotics (tylosin and sulfamethoxazole). There were five detections in all the well samples. The maximum concentration detected in well water was for cotinine, estimated to be 0.024 μg/L. Seasonal occurrence of pharmaceutical and antibiotic compounds in stream water varied by compound and site type. At four stream sites, the same compounds were detected in all four seasonal samples. At other sites, pharmaceutical or antibiotic compounds were detected only one time in seasonal samples. Winter samples collected in streams receiving municipalwastewater effluent had the greatest number of compounds detected (21). Research analytical methods were used to determine concentrations for pharmaceuticals and antibiotics. To assist in evaluating the quality of the analyses, detailed information is presented on laboratory methodology and results from qualitycontrol samples. Quality-control data include results for nine blanks, nine duplicate environmental sample pairs, and three laboratory-spiked environmental samples as well as the recoveries of compounds in laboratory surrogates and laboratory reagent spikes.

Pennsylvania↗