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At least 811 records · Page 45Linked to original sources

USGS2007

Chapter 7 Magmatic-hydrothermal fluid interaction and mineralization in alkali-syenite nodules from the Breccia Museo pyroclastic deposit, Naples, Italy

The Breccia Museo, a pyroclastic flow that crops out in the Campi Flegrei volcanic complex (Naples, Italy), contains alkali-syenite (trachyte) nodules with enrichment in Cl and incompatible elements (e.g., U, Zr, Th, and rare-earth elements). Zircon was dated at ≈52 ka, by U-Th isotope systematics using a SHRIMP. Scanning electron microscope and electron microprobe analysis of the constituent phases have documented the mineralogical and textural evolution of the nodules of feldspar and mafic accumulations on the magma chamber margins. Detailed electron microprobe data are given for alkali and plagioclase feldspar, salite to ferrosalite clinopyroxene, pargasite, ferrogargasite, magnesio-hastingsite hornblende amphibole, biotite mica, Cl-rich scapolite, and a member (probable davyne-type) of the cancrinite group. Detailed whole rock, major and minor element data are also presented for selected nodules. A wide variety of common and uncommon accessory minerals were identified such as zircon, baddeleyite, zirconolite, pollucite, sodalite, titanite, monazite, cheralite, apatite, titanomagnetite and its alteration products, scheelite, ferberite, uraninite/thorianite, uranpyrochlore, thorite, pyrite, chalcopyrite, and galena. Scanning electron microscope analysis of opened fluid inclusions identified halite, sylvite, anhydrite, tungstates, carbonates, silicates, sulfides, and phosphates; most are probably daughter minerals. Microthermometric determinations on secondary fluid inclusions hosted by alkali feldspar define a temperature regime dominated by hypersaline aqueous fluids. Fluid-inclusion temperature data and mineral-pair geothermometers for coexisting feldspars and hornblende and plagioclase were used to construct a pressure-temperature scenario for the development and evolution of the nodules. We have compared the environment of porphyry copper formation and the petrogenetic environment constructed for the studied nodules. The suite of ore minerals observed in the nodules supports a potential for mineralization, which is similar to that observed in the alkaline volcanic systems of southern Italy (Pantelleria, Pontine Archipelago, Mt. Somma-Vesuvius).

Campi Flegrei↗

USGS2023

Ediacaran-Ordovician magmatism and REE mineralization in the Wet Mountains, Colorado, USA: Implications for failed continental rifting

Structures associated with Ediacaran-Ordovician alkaline magmatism and the timing of rare earth element (REE) mineralization in the Wet Mountains, CO, were analyzed using field, geophysical, and U-Th-Pb isotope methods to interpret their tectonic setting in the context of previously proposed rift models. The Wet Mountains are known for thorium and REE mineralization associated with failed rift-related, Ediacaran-Ordovician alkaline intrusions and veins. Structural field data indicate that alkaline dikes and mineralized veins are controlled by a system of northwest-striking, high-angle faults and tension fractures formed in a 040°-directed extensional regime. Magnetic and surface expressions of Democrat Creek and McClure Mountain complexes show tectonic elongation toward ∼045°, consistent with NE-directed extension. Magnetic data also suggest the existence of a fourth, previously unrecognized mafic-ultramafic complex of inferred Cambrian age with a similar elongated orientation. Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) 208 Pb/ 232 Th analysis of low-uranium zircon from carbonatite dikes and in situ 206 Pb/ 238 U LA-ICP-MS analysis of monazite in mineralized dikes yielded 465 ± 18 Ma and 489 ± 33 Ma ages, respectively. These ages are consistent with the expected age based on slightly older, cross-cut syenite dikes and the hypothesized Ordovician end to failed rift-related magmatism. The Ediacaran-Ordovician age of alkaline magmatic rocks and the associated northeast-directed extension direction are similar to those of the along-strike, Ediacaran-Cambrian Southern Oklahoma Aulacogen. Therefore, the failed rift system in the Wet Mountains is interpreted to be a northwestern continuation of the Southern Oklahoma Aulacogen with carbonatite magmatism and thorium/REE mineralization representing late intrusive phases.

Colorado↗

USGS1997

Strontium 87/strontium 86 as a tracer of mineral weathering reactions and calcium sources in an alpine/subalpine watershed, Loch Vale, Colorado

Sr isotopic ratios of atmospheric deposition, surface and subsurface water, and geologic materials were measured in an alpine/subalpine watershed to characterize weathering reactions and identify sources of dissolved Ca in stream water. Previous studies have noted an excess of Ca in stream water above that expected from stoichiometric weathering of the dominant bedrock minerals. Mixing calculations based on 87 Sr/ 86 Sr indicate that on an annual basis, 26 ± 7% of Ca export in streams is atmospherically derived, 23 ± 1% is from weathering of plagioclase, and the remainder is from weathering of calcite present in trace amounts in the bedrock. A potential source of error when applying Sr isotopes in catchment studies is determination of the 87 Sr/ 86 Sr of Sr released by mineral weathering, which is complicated by the wide range of mineral isotopic compositions, particularly in older rocks, and the variable rates at which the minerals weather. In this study, base-flow stream chemistry was used to represent the 87 Sr/ 86 Sr of Sr derived from mineral weathering because it effectively integrates the potentially variable isotopic composition of Sr released by weathering in the alpine environment.

Colorado↗

USGS2014

Rare chemical constituents of amelia (Virginia) pegmatite dikes, and their mineral sources

Students of Igneous phenomena have long since become familiar with the occurrence of rare minerals in pegmatitic bodies. The great local concentration of rare elements in pegmatite minerals provides a remarkably good opportunity for the Investigation of deep-seated rock constituents, for it is reasonable to suppose that these same elements are widely distributed in minute amounts through the parent rocks to which they are genetically related; but their concentration in pegmatite bodies affords a record of their presence that is lacking in other rocks. The unusual number of rare minerals of the Amelia, Virginia, pegmatites has long attracted attention, and the rare elements of the more abundant minerals which have been investigated in the laboratories of the United States Geological Survey afford an unusual opportunity to study the rare constituents of a pegmatite. This famous locality for rare minerals is situated 38 miles southwest of Richmond, just south of Appomattox River, on the Piedmont plateau.

Eos, Transactions, American Geophysical Union↗

USGS2017

Mineral supply for sustainable development requires resource governance

Successful delivery of the United Nations sustainable development goals and implementation of the Paris Agreement requires technologies that utilize a wide range of minerals in vast quantities. Metal recycling and technological change will contribute to sustaining supply, but mining must continue and grow for the foreseeable future to ensure that such minerals remain available to industry. New links are needed between existing institutional frameworks to oversee responsible sourcing of minerals, trajectories for mineral exploration, environmental practices, and consumer awareness of the effects of consumption. Here we present, through analysis of a comprehensive set of data and demand forecasts, an interdisciplinary perspective on how best to ensure ecologically viable continuity of global mineral supply over the coming decades.

Nature↗

USGS1991

Mineral remains of early life on Earth? On Mars?

The oldest sedimentary rocks on Earth, the 3.8‐Ga Isua Iron‐Formation in southwestern Greenland, are metamorphosed past the point where organic‐walled fossils would remain. Acid residues and thin sections of these rocks reveal ferric microstructures that have filamentous, hollow rod, and spherical shapes not characteristic of crystalline minerals. Instead, they resemble ferric‐coated remains of bacteria. Modern so‐called iron bacteria were therefore studied to enhance a search image for oxide minerals precipitated by early bacteria. Iron bacteria become coated with ferrihydrite, a metastable mineral that converts to hematite, which is stable under high temperatures. If these unusual morphotypes are mineral remains of microfossils, then life must have evolved somewhat earlier than 3.8 Ga, and may have involved the interaction of sediments and molecular oxygen in water, with iron as a catalyst. Timing is constrained by the early in fall of planetary materials that would have heated the planet's surface. Because there are no earlier sedimentary rocks to study on Earth, it may be necessary to expand the search elsewhere in the solar system for clues to any biotic precursors or other types of early life. Evidence from Mars shows geophysical and geochemical differentiation at a very early stage, which makes it an important candidate for such a search if sedimentation is an important process in life's origins. Not only does Mars have iron oxide‐rich soils, but its oldest regions have river channels where surface water and sediment may have been carried, and seepage areas where groundwater may have discharged. Mars may have had an atmosphere and liquid water in the crucial time frame of 3.9–4.0 Ga. A study of morphologies of iron oxide minerals collected in the southern highlands during a Mars sample return mission may therefore help to fill in important gaps in the history of Earth's earliest biosphere.

Geomicrobiology Journal↗

USGS1990

A spectral reflectance study (0.4-2.5 μm) of selected playa evaporite mineral deposits and related geochemical processes

Playa evaporite mineral deposits show major compositional variations related to differences in lithology, hydrology, and groundwater geochemistry. The use of visible and near-infrared (VNIR) spectral reflectance measurements as a technique for investigating the mineralogy of playa efflorescent crusts is examined. Samples of efflorescent crust were collected from 4 playa: Bristol Dry Lake, Saline Valley, Teels Marsh, and Rhodes Marsh--all located in eastern California and western Nevada. Laboratory and field spectral analyses coupled with X-ray diffraction analyses of the crusts yielded the following observations: VNIR spectra of unweathered salt crusts can be used to infer the general chemistry of near-surface brines; VNIR spectra are very sensitive for detecting minor hydrate mineral phases contained in mixtures with anhydrous, spectrally featureless, minerals such as halite (NaCl) and thernardite (Na2So4); borate minerals exhibit particularly strong VNIR spectral features that permit small amounts of borate to be detected in efflorescent salt crusts; remote sensing spectral measurements of playa efflorescent crusts may have applications in global studies of playa brines and minerals.

Conference Paper↗

USGS2021

Mineral Mapping of the Battle Mountain District, Nevada, USA, Using AVIRIS-Classic and SpecTIR Inc. AisaFENIX 1K Imaging Spectrometer Datasets

Imaging spectroscopy (hyperspectral imaging) has been used to successfully map minerals at the outcrop, deposit, district, and regional scale. This contribution presents spectral-based mineral maps of the Battle Mountain mining district, Nevada, USA, generated using multi-scale airborne imaging and ground-based point spectrometers. Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and AisaFENIX 1K imaging spectrometer data were processed using Atmospheric and Topographic Correction (ATCOR-4) software with an empirical correction multiplier derived from field data. Data were used to generate spectral-based mineral maps with spatial resolutions of 13.5 and 1.8 m. A comparison of the various radiative transfer models used to convert radiance data to reflectance indicated that the ATCOR4 rugged model performed best for these datasets. These mineral maps were then used to spectrally characterize two potential porphyry mineral targets in the district.

Nevada↗

USGS2004

A hydrogeologic model of stratiform copper mineralization in the Midcontinent Rift System, Northern Michigan, USA

This paper presents a suite of two-dimensional mathematical models of basin-scale groundwater flow and heat transfer for the middle Proterozoic Midcontinent Rift System. The models were used to assess the hydrodynamic driving mechanisms responsible for main-stage stratiform copper mineralization of the basal Nonesuch Formation during the post-volcanic/pre-compressional phase of basin evolution. Results suggest that compaction of the basal aquifer (Copper Harbor Formation), in response to mechanical loading during deposition of the overlying Freda Sandstone, generated a pulse of marginward-directed, compaction-driven discharge of cupriferous brines from within the basal aquifer. The timing of this pulse is consistent with the radiometric dates for the timing of mineralization. Thinning of the basal aquifer near White Pine, Michigan, enhanced stratiform copper mineralization. Focused upward leakage of copper-laden brines into the lowermost facies of the pyrite-rich Nonesuch Formation resulted in copper sulfide mineralization in response to a change in oxidation state. Economic-grade mineralization within the White Pine ore district is a consequence of intense focusing of compaction-driven discharge, and corresponding amplification of leakage into the basal Nonesuch Formation, where the basal aquifer thins dramatically atop the Porcupine Mountains volcanic structure. Equilibrium geochemical modeling and mass-balance calculations support this conclusion. We also assessed whether topography and density-driven flow systems could have caused ore genesis at White Pine. Topography-driven flow associated with the Ottawan orogeny was discounted because it post-dates main-stage ore genesis and because recent seismic interpretations of basin inversion indicates that basin geometry would not be conductive to ore genesis. Density-driven flow systems did not produce focused discharge in the vicinity of the White Pine ore district.

Michigan↗

USGS1962

Distribution and composition of sulfide minerals at Balmat, New York

In the Balmat area in northern New York , tabular deposits of sulfide minerals parallel the layering in folded, siliceous magnesian marbles of a metamorphic complex commonly referred to as the Precambrian Granville Series. Sphalerite, pyrite, and, locally, pyrrhotite and galena have replaced the carbonate minerals in parts of the marble units. The contacts between ore and marble are, in general, ill-defined; scattered grains of sulfides are present from several inches to hundreds of feet from the massive portions of ore. Access to the ore is provided through the Balmat No. 2 and No. 3 mines. The isotopic composition of lead from primary galena is uniform within an individual mine. The model age of this lead agrees with the age of the mineralization determined by other means - about a billion years. The isotopic composition of the leads in the marble is not uniform today, and calculations indicate that it was probably not uniform a billion years ago. Unless the lead in the ores is a uniform mixture of lead isotopes from an isotopically poorly mixed source, it is doubtful that the lead in the ores was derived from the surrounding marbles. Cobalt and nickel concentrations in pyrite from grains disseminated in the metasedimentary rocks away from the ore bodies are each greater than 200 ppm. Most samples of pyrite from the ore bodies at the No. 2 and No. 3 mines contain less than 50 ppm each of cobalt and nickel. Therefore the author believes it unlikely that the pyrite of the ores is genetically related to the pyrite in the metasedimentary rocks. Textural relationships suggest that pyrrhotite formed after most of the sphalerite, which in turn formed after most of the pyrite in the ore bodies. By use of the experimentally determined systems FeS-ZnS and FeS-FeS 2 , it is inferred from the amounts of iron in sphalerite and sulfur in pyrrhotite that the bulk of the sulfide minerals in the No. 2 mine formed above 320° C. The absolute temperature of formation of pyrrhotite indicated by the FeS-ZnS system is about 150° higher than that indicated by the FeS-FeS 2 system. The former system probably gives the more reliable estimate. The concentrations of individual minor elements in sphalerite and pyrite range considerably among specimens of the same sulfide mineral from the same level and ore body. An exception is cadmium in sphalerite which has a narrow concentration range around 1400 ppm in both the No. 2 and No. 3 mines. The ratio of the concentrations of minor elements between sphalerite-pyrite pairs varies considerably also. This variation probably indicates that exchange of minor elements between pyrite and sphalerite durin g the formation of the ores was very slow and incomplete.

New York↗

USGS1965

Stratigraphy and heavy minerals of the bays formation, Bays Mountain synclinorium, northeast Tennessee

The Bays Mountain synclinorium is in the Valley and Ridge province in northeast Tennessee , southwest of Kingsport and west of Greeneville. The more clastic part of the Bays formation lies in the east section of the synclinorium . The thickness of the Bays decreases from about 870 feet on the east to about 600 feet on the west. Presumably, the red beds and primary features of the Bays formation formed under deltaic conditions. A Camarocladia Zone near its base indicates a time-transgression of the Bays . The Bays is older at the base to the east than at its base to the west. The heavy minerals of the Bays were compared with those of the Cambrian and Precambrian(?) sediments, volcanic rocks, and accessory minerals of the crystalline complex which now comprise the Blue Ridge. The minerals identified include nearly all those in the Cambrian and Precambrian(?) sediments as well as additional minerals not found in these older sediments but that are in the crystalline complex. Such minerals indicate that at least a part of the crystalline complex was above sea level during the Middle Ordovician.

Tennessee↗

USGS1984

U-Th-Pb, Rb-Sr, and Ar-Ar mineral and whole-rock isotopic systematics in a metamorphosed granitic terrane, southeastern California

Mesozoic structural domes are developed in an older Proterozoic crystalline basement of granitic to granodioritic foliate metaplutonic rocks in the Halloran Hills, southeastern California. Isotopic analyses of whole rocks and mineral separates from these rocks by U-Th-Pb, Rb-Sr, and Ar-Ar techniques yield a complex pattern of discordance that is the result of a fairly simple geologic history. Individual mineral isotopic systems have variably equilibrated with each other in response to Mesozoic regional metamorphism and locally to later heating during Mesozoic batholith emplacement. Discordant U-Th-Pb zircon data indicate that the granitic core rocks are 1,710 Ma and that one dioritic phase may be slightly older. Rb-Sr whole-rock model dates scatter about 1,700 Ma Rb-Sr amphibole–whole-rock and U-Th-Pb amphibole dates are also Proterozoic. Potassium feldspars retain a 207 Pb/ 206 Pb signature of their Proterozoic age. Ar-Ar amphibole spectra from the flank of the main dome reveal disturbed dates of 1,450 Ma to 1,100 Ma, and the dates become younger toward the structurally deeper core of the dome. All remaining isotopic determinations yield Mesozoic or younger dates for mineral–whole-rock systems. Rb-Sr whole-rock–apatite–feldspar–biotite analyses show nonequilibration of strontium isotopes, with resultant mineral pair dates from 4 foliate plutonic rocks ranging from 200 to 50 Ma. No single metamorphic age is indicated by the Rb-Sr data. Rb-Sr whole-rock–biotite dates are consistently younger than any other determinations and may be reduced by weathering or gain of nonradiogenic strontium from ground water. U-Pb sphene and apatite analyses from rocks that yield 1,710-Ma zircon dates are nearly concordant at 140 Ma. An amphibole from the structurally deepest rocks of the main dome that yield 140- to 150-Ma U-Pb sphene dates has an Ar-Ar plateau date of 144 Ma. The U-Pb sphene and Ar-Ar amphibole analyses are believed to be the best age estimate for the end of the highest-temperature phase of regional metamorphism. Th-Pb sphene and apatite dates and Ar-Ar biotite dates cluster at 90 ± 5 Ma as a consequence of regional cooling during Late Cretaceous time following extensive Mesozoic plutonism in the region at 97 to 90 Ma. We interpret the discordant mineral date patterns to have resulted from metamorphism of ∼1,700-Ma plutonic rocks during the Jurassic (≥ 140–50 Ma) and subsequent uplift and cooling to ∼200 °C at about 90 Ma. On the basis of this study, the isotope dating systems ranked in decreasing order of resistance to resetting are: U-Th-Pb zircon (concordia intercept) ≥ Rb-Sr whole rock ∼Rb-Sr amphibole ∼U-Th-Pb amphibole ∼Pb-Pb whole rock > Ar-Ar amphibole ≥ Rb-Sr sphene ≥ U-Pb sphene and apatite > Rb-Sr plagioclase-potassium feldspar-apatite > Th-Pb sphene and apatite ∼Ar-Ar biotite ∼U-Pb feldspars > Rb-Sr biotite.

California↗

USGS2011

To reactivate or not to reactivate: nature and varied behavior of structural inheritance in the Proterozoic basement of the Eastern Colorado mineral belt over 1.7 billion years of earth history

The eastern central Front Range of the Rocky Mountains in Colorado has long been a region of geologic interest because of Laramide-age hydrothermal polymetallic vein-related ores. The region is characterized by a well-exposed array of geologic structures associated with ductile and brittle deformation, which record crustal strain over 1.7 billion years of continental growth and evolution. The mineralized areas lie along a broad linear zone termed the Colorado Mineral Belt. This lineament has commonly been interpreted as following a fundamental boundary, such as a suture zone, in the North American Proterozoic crust that acted as a persistent zone of weakness localizing the emplacement of magmas and associated hydrothermal fluid flow. However, the details on the controls of the location, orientation, kinematics, density, permeability, and relative strength of various geological structures and their specific relationships to mineral deposit formation are not related to Proterozoic ancestry in a simple manner. The objectives of this field trip are to show key localities typical of the various types of structures present, show recently compiled and new data, offer alternative conceptual models, and foster dialogue. Topics to be discussed include: (1) structural history of the eastern Front Range; (2) characteristics, kinematics, orientations, and age of ductile and brittle structures and how they may or may not relate to one another and mineral deposit permeability; and (3) characteristics, localization, and evolution of the metal and non–metal-bearing hydrothermal systems in the eastern Colorado Mineral Belt.

Colorado↗

USGS1993

Factors influencing the composition of detrital heavy mineral suites in Holocene sands of the Apure River drainage basin, Venezuela

Heavy mineral assemblages in rivers in the Apure River drainage basin of Venezuela and Colombia closely reflect the nature of the source regions, which lie in the Andean orogenic terranes to the west and northwest. The Caribbean Mountains, largely composed of greenschist-facies pelites, phyllites, carbonates, and metavolcanics, supply assemblages dominated by epidote and calcic amphibole. Minor amounts of the high-pressure index minerals glaucophane and lawsonite indicate the presence of blueschistfacies rocks, reflecting the origin of the Caribbean Mountains by subduction-related tectonism. The northern Mérida Andes, which comprise basement gneisses and granites overlain by unmetamorphosed to low-grade metamorphosed clastics, supply two types of assemblage reflecting these two lithological types: garnet-sillimanite-staurolite-amphibole suites from the basement rocks, and epidote-amphibole suites from the overlying cover sequence. The southern Mérida Andes supply stable heavy mineral suites reflecting recycling from the extensive unmetamorphosed sandstones that occur at outcrop. By considering suites from different physiographical provinces, the effects of short-term alluvial storage in the Llanos on heavy mineral assemblages have been evaluated. Weathering during alluvial storage appears to be effective in modifying the apatite-tourmaline ratio, which shows a steady, marked decline with distance from the mountain front, resulting from the removal of apatite during weathering. Clinopyroxene and garnet may also show evidence of loss through weathering, although the trends are poorly constrained statistically. Epidote and amphibole proportions remain essentially constant, possibly through a balance between loss through weathering and continual resupply from the breakdown of rock fragments. In general, the heavy mineral assemblages are less affected than the bulk mineralogy by alluvial storage on the Llanos.

Special Paper of the Geological Society of America↗

USGS2022

Spectral reflectance properties (0.4-2.5 μm) of secondary Fe-oxide, Fe-hydroxide, and Fe-sulphate-hydrate minerals associated with sulphide-bearing mine wastes

Diffuse reflectance spectra of 15 mineral species commonly associated with sulphide-bearing mine wastes show diagnostic absorption bands related to electronic processes involving ferric and/or ferrous iron, and to vibrational processes involving water and hydroxyl. Many of these absorption bands are relatively broad and overlapping; however, spectral analysis methods, including continuum removal and derivative analysis, permit most of the minerals to be distinguished. Key spectral differences between the minerals are illustrated in a series of plots showing major absorption band centres and other spectral feature positions. Because secondary iron minerals are sensitive indicators of pH, Eh, relative humidity, and other environmental conditions, spectral mapping of mineral distributions promises to have important application to mine waste remediation studies.

Geochemistry: Exploration, Environment, Analysis↗

USGS2000

Self-ordering and complexity in epizonal mineral deposits

Epizonal base and precious metal deposits makeup a range of familiar deposit styles including porphyry copper-gold, epithermal veins and stockworks, carbonate-replacement deposits, and polymetallic volcanic rock-hosted (VHMS) deposits. They occur along convergent plate margins and are invariably associated directly with active faults and volcanism. They are complex in form, variable in their characteristics at all scales, and highly localized in the earth’s crust. More than a century of detailed research has provided an extensive base of observational data characterizing these deposits, from their regional setting to the fluid and isotope chemistry of mineral deposition. This has led to a broad understanding of the large-scale hydrothermal systems within which they form. Low salinity vapor, released by magma crystallization and dispersed into vigorously convecting groundwater systems, is recognized as a principal source of metals and the gases that control redox conditions within systems. The temperature and pressure of the ambient fluid anywhere within these systems is close to its vapor-liquid phase boundary, and mineral deposition is a consequence of short timescale perturbations generated by localized release of crustal stress. However, a review of occurrence data raises questions about ore formation that are not addressed by traditional genetic models. For example, what are the origins of banding in epithermal veins, and what controls the frequency of oscillatory lamination? What controls where the phenomenon of mineralization occurs, and why are some porphyry deposits, for example, so much larger than others? The distinctive, self-organized characteristics of epizonal deposits are shown to be the result of repetitive coupling of fracture dilation consequent on brittle failure, phase separation (“boiling”), and heat transfer between fluid and host rock. Process coupling substantially increases solute concentrations and triggers fast, far-from-equilibrium depositional processes. Since these coupled processes lead to localized transient changes in fluid characteristics, paragenetic, isotope, and fluid inclusion data relate to conditions at the site of deposition and only indirectly to the characteristics of the larger-scale hydrothermal system and its longer-term behavior. The metal concentrations (i.e. grade) of deposits and their internal variation is directly related to the geometry of the fracture array at the deposit scale, whereas finer-scale oscillatory fabrics in ores may be a result of molecular scale processes. Giant deposits are relatively rare and develop where efficient metal deposition is spatially focused by repetitive brittle failure in active fault arrays. Some brief case histories are provided for epithermal, replacement, and porphyry mineralization. These highlight how rock competency contrasts and feedback between processes, rather than any single component of a hydrothermal system, govern the size of individual deposits. In turn, the recognition of the probabilistic nature of mineralization provides a firmer foundation through which exploration investment and risk management decisions can be made.

Annual Review of Earth and Planetary Sciences↗

USGS2013

Blood mineral concentrations in manatees ( Trichechus manatus latirostris and Trichechus manatus manatus )

Limited information is available regarding the role of minerals and heavy metals in the morbidity and mortality of manatees. Whole-blood and serum mineral concentrations were evaluated in apparently healthy, free-ranging Florida ( Trichechus manatus latirostris , n = 31) and Belize ( Trichechus manatus manatus , n = 14) manatees. Toxicologic statuses of the animals and of their environment had not been previously determined. Mean mineral whole-blood (WB) and serum values in Florida (FL) and Belize (BZ) manatees were determined, and evaluated for differences with respect to geographic location, relative age, and sex. Mean WB and serum silver, boron, cobalt, magnesium, molybdenum, and WB cadmium concentrations were significantly higher in BZ versus FL manatees ( P ≤ 0.05). Mean WB aluminum, calcium, manganese, sodium, phosphorus, vanadium, and serum zinc concentrations were significantly lower in BZ versus FL manatees. Adult manatees had significant and higher mean WB aluminum, manganese, sodium, antimony, vanadium, and serum manganese and zinc concentrations compared to juvenile animals. Significant and lower mean WB and serum silver, boron, cobalt, and serum copper and strontium concentrations were present in adults compared to juveniles ( P ≤ 0.05). Females had significant and higher mean WB nickel and serum barium compared to males ( P ≤ 0.05). Mean WB arsenic and zinc, and mean serum iron, magnesium, and zinc concentrations fell within toxic ranges reported for domestic species. Results reveal manatee blood mineral concentrations differ with location, age, and sex. Influence from diet, sediment, water, and anthropogenic sources on manatee mineral concentration warrant further investigation.

Journal of Zoo and Wildlife Medicine↗

USGS2007

Effects of mother lode-type gold mineralization on 187Os/188Os and platinum group element concentrations in peridotite: Alleghany District, California

Osmium isotope compositions and concentrations of Re, platinum group elements (PGE), and Au were determined for host peridotites (serpentinites and barzburgites) and hydrothermally altered ultramafic wall rocks associated with Mother Lode-type hydrothermal gold-quartz vein mineralization in the Alleghany district, California. The host peridotites have Os isotope compositions and Re, PGE, and Au abundances typical of the upper mantle at their presumed formation age during the late Proterozoic or early Paleozoic. The hydrothermally altered rocks have highly variable initial Os isotope compositions with ??os, values (% deviation of 187OS/188OS from the chondritic average calculated for the approx. 120 Ma time of mineralization) ranging from -1.4 to -8.3. The lowest Os isotope compositions are consistent with Re depletion of a chondritic source (e.g., the upper mantle) at ca. 1.6 Ga. Most of the altered samples are enriched in Au and have depleted and fractionated abundances of Re and PGE relative to their precursor peridotites. Geoehemical characteristics of the altered samples suggest that Re and some PGE were variably removed from the ultramafic rocks during the mineralization event. In addition to Re, the Pt and Pd abundances of the most intensely altered rocks appear to have been most affected by mineralization. The 187Os-depleted isotopic compositions of some altered rocks are interpreted to be a result of preferential 187Os loss via destruction of Re-rich phases during the event. For these rocks, Os evidently is not a useful tracer of the mineralizing fluids. The results do, however, provide evidence for differential mobility of these elements, and mobility of 187Os relative to the initial bulk Os isotope composition during hydrothermal metasomatic alteration of ultramafic rocks. ?? 2007 Society of Economic Geologists, Inc.

Economic Geology↗