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Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas

Groundwater quality near an oil field in a stream-dominated recharge setting, California, USA

Alluvial valley aquifers are important sources of water supply in many areas but effects of co-located oil and gas development on these resources have not been widely reported, especially in settings where recharge is dominated by stream infiltration. Interpreting the presence of geochemical indicators in the context of hydrology, geology, and other factors provides a more complete understanding of the relations between groundwater and sources of oil-field fluids and aids in identifying risks associated with oil and gas development. Groundwater and Salinas River water samples were collected in an alluvial valley near the San Ardo Oil Field in Monterey County, California and analyzed for a wide range of dissolved chemical, gas, and isotopic constituents to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with fresh groundwater used for supply. Hydraulic gradients, age-dating tracers, and other geochemical indicators show that recharge from the Salinas River has the potential to dilute oil-field fluids that might migrate or seep into the aquifer. Groundwater and Salinas River water collected downgradient of the San Ardo Oil Field showed little or no evidence of mixing with oil-field fluids. Some samples within the oil field contained trace amounts of hydrocarbons or elevated temperatures, indicating that any potential effects from oil-field activities are minor or have been diluted by recharge from the Salinas River. The two samples with the most geochemical evidence of potential mixing with oil-field fluids (SP-18 and GW-17) were collected west of or along the Los Lobos fault, where naturally occurring hydrocarbons are near the land surface. Those samples are also near active or inactive oil-field wells, and so anthropogenic activities and pathways cannot be ruled out as a cause of trace detections of hydrocarbons and elevated temperatures in the aquifer.

California

Spatiotemporal variations in strain release and seismic rupture in multifault systems: An example from Panamint Valley, southeastern California

Geometrically complex, multifault ruptures have been observed in recent, damaging earthquakes in southeastern California, sparking renewed efforts to identify physical conditions that promote or inhibit fault discontinuity-spanning coseismic ruptures. The likelihood of ruptures propagating across fault discontinuities is thought to be partly controlled by fault geometries, rupture direction, and the history of strain release. However, these parameters vary in space and time over multiple earthquake cycles, making it difficult to forecast the likelihood that an earthquake on one fault will trigger rupture on a nearby fault. Here we use tectono-geomorphic mapping of a geometrically complex fault zone in Panamint Valley, southeastern California, to assess spatiotemporal variations of paleo-rupture patterns and geometries of fault discontinuities over multiple earthquake cycles. First, we identify ten generations of late Pleistocene to Holocene alluvium using geomorphic parameters and luminescence dating to constrain ages of alluvium and bracket late Holocene earthquake timing. Then, we quantify slip kinematics using high-resolution structure from motion digital surface models. We find the Panamint Valley transtensional relay (PVTR) hosted four late Holocene earthquakes, bracketed to ~5.8–3.4 ka, ~3.8–2.2 ka, ~2.4–0.6 ka, and ~0.64–0.16 ka, with ~0.6–1.1 m of slip per event, correlative to Mw ≈ 6.7–6.9 earthquakes. Additionally, we find similarities in earthquake timing on the Ash Hill, PVTR, and Panamint Valley faults and similarities in the slip magnitude and slip kinematics between the Ash Hill and PVTR faults, implying that the PVTR may co-rupture with nearby faults. Paleo-rupture patterns indicate that seismogenic strain transfer may occur through the PVTR, along different combinations of fault segments and jump distances, over multiple earthquake cycles. These data highlight the utility of tectono-geomorphic mapping in evaluating paleo-rupture patterns and suggest that the PVTR may act to propagate and/or arrest rupture between the Ash Hill and Panamint Valley faults.

California

Vegetation cover and composition in environments surrounding uranium mines in the Grand Canyon ecosystem, Northern Arizona

Mining uranium from breccia-pipe deposits in the greater Grand Canyon region has occurred since the mid-1900s. However, possible ecosystem contamination with harmful levels of radionuclides may have occurred due to mining activities in the 21st century. In response, a 20-year Federal moratorium on new mining claims in the Grand Canyon watershed was initiated in 2012, to allow time to evaluate the potential effects of uranium exploration and mining on human health, wildlife, and water resources. This moratorium, nor the 2023 designation of the “Baaj Nwaavjo I’tah Kukveni–Ancestral Footprints of the Grand Canyon National Monument,” precludes operation or development of mining claims predating 2012. Vegetation is a core ecosystem component that may be affected by uranium mining (for instance, through uptake and storage of radionuclides from the air or soil) or may act as a vector of exposure to wildlife, livestock, and humans (for instance, via their consumption of contaminated plant tissues). To provide baseline information about the plant communities associated with uranium mines in the Grand Canyon region, the U.S. Geological Survey surveyed an approximately 200-meter-wide buffer surrounding four breccia-pipe deposits, each in a unique stage of mine development, and at one reference area (a livestock water tank) that underwent ground disturbance but contains no mineral deposits. We sectioned the buffer zones into 0.65–4.52 hectare plots, within which we (1) inventoried all plant species, (2) measured percent cover of plant species, plant functional groups, and ground surface types (dark cyanobacteria, lichen, moss, bedrock, rock, embedded litter, duff, plant bases, and bare soil) using line-point intercept, and (3) measured length and frequency of gaps between perennial plant canopies using canopy gap intercept. We found that plant composition at the mines and the reference area differed from one another but were all characteristic of expected regional vegetation patterns. We provide this data summary as potential baseline information for future research and management efforts.

Arizona

Hydrogeologic investigation, framework, and conceptual flow model of the Antlers aquifer, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statute §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. Every 20 years, the Oklahoma Water Resources Board is required to update the hydrologic investigation on which the maximum annual yield determinations were based. The maximum annual yield allocated per acre of land is used to set the equal-proportionate share pumping rate. The maximum annual yield of 5,913,600 acre-feet per year and equal-proportionate-share of 2.1 acre-feet per acre per year currently (2025) in place for the Antlers aquifer were issued by the Oklahoma Water Resources Board on February 14, 1995. Because more than 20 years have elapsed since the 1995 final order for the Antlers aquifer was issued, the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, completed an in-depth hydrologic study that included a hydrogeologic framework and conceptual groundwater-flow model for the 1980–2022 study period. The results of an analysis of land use, long-term climate patterns, streamflow and base-flow patterns, historical groundwater use, as well as groundwater-level fluctuations across the Antlers aquifer are described. In addition, groundwater quality was analyzed for total dissolved solids concentrations and major ions for the Antlers aquifer. An updated hydrogeologic framework was developed that included refining the aquifer boundary in Oklahoma, the creation of new potentiometric surface and saturated thickness of fresh groundwater maps, one multiple-well aquifer test, slug tests, and an analysis of lithologic logs across the aquifer. A conceptual groundwater flow model and water budget were developed by incorporating estimates of recharge from precipitation, saturated-zone evapotranspiration, streambed seepage, lateral groundwater flows, vertical leakage, and withdrawals from groundwater wells.

Oklahoma, Texas

Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

Washington

Site-specific amplifications in Northwestern Turkiye: A generic approach

In this study, we derive generic site amplification functions applicable to Northwestern Türkiye and follow guidance on site classifications established by the United States National Earthquake Hazards Reduction Program (NEHRP). We employ the one-dimensional (1-D) equivalent linear ground response analysis method and focus on recordings from a select suite of free-field strong motion (SM) stations. These particular SM stations are associated with a comprehensive geotechnical site conditions dataset comprising 76 shear-wave velocity profiles. Despite their varying resolutions and depths, this diversity allows for a more representative analysis across different site conditions, enhancing the robustness of our findings. For analyses, we utilize a robust set of global ground motion records, selected from both within and outside of Türkiye, to serve as strong and weak input bedrock motions. Site amplification is determined by propagating these bedrock records through 76 site-specific Afet ve Acil Durum Yönetimi Başkanlığı (AFAD) station profiles and calculating the spectral acceleration ratio between the ground surface and the input motion. Our analyses reveal substantial disparities between the amplification functions derived from 1-D site response analyses using strong and weak input motions. These disparities are central to our analysis and inform the subsequent comparison with site amplification functions reported in the literature. We compare the generic site amplification functions derived in this study with those reported in the literature for regions with similar geological and seismic conditions to Northwestern Türkiye. For example, site amplification functions for NEHRP Site Classes C and D have been documented for Greece and the United States utilizing frequency-dependent methods such as the quarter-wavelength approximation. Our findings reveal that the generic site amplification functions derived in this study exhibit differences in peak amplitudes and predominant frequencies compared to those in the literature, reflecting regional variations in geotechnical and seismic properties. This study represents an initial effort to formulate generic site amplification functions for Türkiye, with a particular emphasis on the Northwestern region. A thorough literature review indicated no prior studies have proposed such functions specifically for this area.

Northwestern Turkiye

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Medina County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018–20 within northern Medina County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in northern Medina County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic and hydrostratigraphic units (HSUs) in the study area. This study includes updates to the geology of the Kainer Formation (or its stratigraphic equivalent, the Fort Terrett Formation) with the addition of a burrowed unit between the basal nodular and dolomitic members. The hydrostratigraphy was also updated with the addition of HSU IIA for the upper part of the Devils River Limestone and the Seco Pass HSU for the burrowed member of the Kainer (or Fort Terrett) Formation. The Cretaceous age rocks (listed in ascending order) in the study area are part of the Trinity Group, Edwards Group and stratigraphically equivalent Devils River Limestone, Washita Group, Eagle Ford Group, Austin Group, and Taylor Group, with isolated areas where Late Cretaceous age igneous rocks have intruded. The groups and formations are composed primarily of relatively thick layers of clays, shales, and limestone. The igneous rocks are coarse-grained ultramafic in composition. Hydrostratigraphically, the rocks exposed in the study area (listed in descending order from land surface) are igneous, the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the upper part of the middle zone of the Trinity aquifer. The karstic carbonate Edwards and Trinity aquifers developed because of their original depositional history, primary and secondary porosity, diagenesis, fracturing, and faulting. These factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers.

Texas

Revisiting an enigma on California's north coast: The Mw6.5 Fickle Hill earthquake of 21 December 1954

Many earthquakes occur along the North Coast of California in the vicinity of the Mendocino Triple Junction (MTJ), where the Pacific, Gorda, and North American (NA) plates meet, and on the adjacent plate boundaries. The MTJ marks the nexus of the Mendocino and San Andreas faults with the Cascadia subduction zone (CSZ). Historically, most large earthquakes around the MTJ have been within the offshore Gorda plate and its subducted portion beneath the NA plate. North of the MTJ, active faults mapped in the NA plate are part of the CSZ fold‐and‐thrust belt. Although some events have been detected in the NA plate, no large historic events have been associated with mapped surface faults. The 21 December 1954 M w 6.5 earthquake in Humboldt County is one possible exception. Using published data from catalogs and articles, unpublished data from Berkeley’s archives, and S ‐ P times interpreted from two U.S. Coast and Geodetic Survey (USCGS) accelerometers, we determine a probability cloud for the earthquake’s hypocenter using NonLinLoc. The highest probability location lies beneath Fickle Hill just east of the city of Arcata, California, at 40.87° N, 124.03° W, and ∼11 km depth. Using P ‐wave polarities from Berkeley stations and the digitized waveforms from the accelerometers, we find that the focal mechanism most consistent with the data indicates thrust movement with strike, dip, and rake of 350°, 10°, and 90°, respectively, at a depth of 14 km. Given the depth uncertainties of both this event and the megathrust, this implies that the earthquake most likely took place on the subduction interface rather than on the mapped faults in the Mad River fault zone that trend 322° and dip to the northeast. The revisited intensity in the epicentral region also supports a location beneath Fickle Hill to the east of the city of Arcata, California.

California, Idaho, Nevada, Oregon, Washington

Methods for estimating selected low-flow statistics at gaged and ungaged stream sites in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Conservation and Recreation, Office of Water Resources, computed selected at-site streamflow statistics at U.S. Geological Survey streamgages in and near Massachusetts and developed regional regression equations for estimating selected streamflows at ungaged stream sites in Massachusetts. Two sets of regional regression equations were developed: (1) the “mainland” equations, for mainland Massachusetts excluding the area covered by the second set, and (2) the “southeastern” equations, for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and for Cape Cod. The regression equations and at-site statistics may be used by Federal, State, and local water managers in addressing water-resources issues relevant in Massachusetts. Regional regression analyses for the mainland equations were developed to estimate the following 27 streamflow statistics: 99-, 98-, 95-, 90-, 85-, 80-, 75-, 70-, 60-, and 50-percent flow durations; monthly June, July, August, and September 90- and 50-percent flow durations; February, June, and August median of the monthly means; harmonic mean; and medians of the following annual low-flow frequency statistics: 7-day; 7-day, 2-year; 7-day, 10-year; 30-day, 2-year; and 30-day, 10-year. The analyses used 81 streamgages with minimal to no regulations in and near Massachusetts. The regression analyses determined that four basin characteristics—drainage area, combined hydrologic soils A and B, streamflow variability index, and annual mean temperature—were the only significant explanatory variables for the different mainland equations. Regional regression equations were developed for the Plymouth-Carver-Kingston-Duxbury aquifer area in southeastern Massachusetts and Cape Cod, because surface-water drainage areas and groundwater contributing areas do not always coincide in this area of the State. The regression analyses to estimate 10 flow durations from the 99th to 50th percentiles used 18 streamflow sites with some occasional minor regulations—because there are few unregulated streams in southeastern Massachusetts. The analyses determined that groundwater contributing area and storage (combined water bodies and wetlands) were the only significant explanatory variables in the southeastern equations.

Massachusetts

Methodology for inclusion of produced and stored carbon dioxide in the U.S. Geological Survey Federal lands greenhouse gas inventory

The U.S. Geological Survey (USGS) has developed two new carbon dioxide (CO2) emissions and sequestration accounting methods for use in future reports. The first method is a Federal lease-produced CO2 emissions calculation for an update of the report, “Federal Lands Greenhouse Gas Emissions and Sequestration in the United States.” The methodology to incorporate Federal lease CO2 production emissions into the updated report relies on CO2 sales royalty data from the Office of Natural Resources Revenue (ONRR). The end usage points for the gas include enhanced oil recovery with CO2 (CO2-EOR), food and beverage, and chemical production. CO2-EOR is the main end point for natural CO2 production in the United States; it accounted for 94% of usage in 2022 [1]. Federal lands emissions from this sector are estimated at 460 metric tons of CO2 in 2022, a very small amount relative to most other Federal lands emissions sector estimates. The second new method, planned for a separate report, is a calculation of the geologic storage of CO2 on Federal lands. The second method estimates the CO2 stored under Federal surface lands and documents Federal climate change mitigation efforts. Currently, there is no storage of CO2 at an industrial level on Federal lands, however multiple proposals and projects are planned. This method was developed on non-Federal lands datasets in an effort to prepare for when these activities on Federal lands will require accounting. National estimates for CO2 geologic storage using this method, but without a Federal lands filtering step, totaled 8.0 million metric tons (Mt) in 2022. The two methods described here are new benchmark methods in a collection of accounting procedures to document the current state of greenhouse gas emissions and their storage on Federal lands. These benchmarks can then be used to measure any subsequent changes in emissions from or carbon storage beneath Federal lands. While the magnitude of the values is currently non-existent to small, emissions mitigation goals established by decision makers indicate that these values will grow, and their documentation will take on greater value and use.

continental United States

The influence of pre-existing structures on geothermal springs: Inferences from potential field mapping in Surprise Valley, CA and other sites In the northwestern Great Basin

Surprise Valley, located in the northwestern Great Basin, is an asymmetric extensional basin that marks a major tectonic transition between the relatively un-extended volcanic Modoc Plateau to the west, and the Basin and Range to the east that has undergone 10-15% extension. In addition, it sits just north of the Walker Lane which accommodates up to 20% of dextral slip associated with Pacific-North American plate interactions. Thermal springs issue from eight areas within Surprise Valley. Most of these occur within the basin and are not situated on the main basin forming range-front faults. As a result, efforts to resolve the structural setting of the valley’s hydrothermal system have relied on geophysics to characterize basin structure and geology. Extensive efforts to map the basin with ground and airborne magnetics have revealed a >35 km-long linear, intra-basin magnetic high, interpreted as a buried dike swarm. Geothermal springs on the eastern side of the valley, including Seifert hot springs, Leonards hot springs, and Surprise Valley hot springs (SVHS), are all situated along the magnetic high and occur at local breaks and bends in the anomaly, suggesting that fracture permeability is enhanced along the feature and particularly at these discontinuities. Recent studies, including drilling over the anomaly near SVHS that likely intersected dike material, as well as subsequent mapping and sampling of dikes outcropping along the anomaly on the playa surface south of SVHS, confirm (as previously inferred) that mafic intrusives are the principal source of the anomaly. Similar interpretations made in two other valleys (in southern Oregon and northwestern Nevada), where inferred intra-basin dikes appear to be spatially correlated with hot springs or prospective geothermal resource areas, suggest that the impact of pre-existing basement structure on hydrothermal activity may pertain more generally to other hydrothermal settings throughout the Great Basin. If so, efforts to map basement may enhance understanding structural controls on some geothermal systems. Furthermore, similarities across these disparate sites suggest that magmatism may play a much larger role in accommodating extension and influencing basin evolution across the western Great Basin than previously recognized.

Conference Paper

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Water quality of the Boca Raton canal system and effects of the Hillsboro Canal inflow, southeastern Florida, 1990-91

The City of Boca Raton in southeastern Palm Beach County, Florida, is an urban residential area that has sustained a constant population growth with subsequent increase in water use. The Boca Raton network of canals is controlled to provide for drainage of excess water, to maintain proper coastal ground-water levels to prevent saltwater intrusion, and to recharge the surficial aquifer system from which the city withdraws potable water. Most of the water supplied to the Boca Raton canal system and the surficial aquifer system, other than rainfall and runoff, is pumped from the Hillsboro Canal. The Biscayne aquifer, principal hydrogeologic unit of the surficial aquifer system, is highly permeable and there is a close relation between water levels in the canals and the aquifer. The amount of water supplied by seepage from the conservation areas is unknown. Because the Hillsboro Canal flows from Lake Okeechobee and Water Conservation Areas 1 and 2, which are places of more highly mineralized ground water and surface water, the canal is a possible source of contamination. Water samples were collected at 10 canal sites during wet and dry seasons and analyzed for major inorganic ions and related characteristics, nutrients, and trace elements. All concentrations were generally within or less than the drinking-water standards established by the Florida Department of Environmental Protection. The high concentrations of sodium and chloride that were detected in samples from the Boca Raton canal system are probably from the more mineralized water of the Hillsboro Canal. Other water-quality data, gathered from various sources from 1982 through 1991, did not indicate any significant changes nor trends. The data include pesticide and metal analyses of water samples and bottom sediments collected at four canal sites in the Boca Raton study area by the U.S. Geological Survey during 1982-84. The effects of the Hillsboro Canal on the water quality of the Boca Raton canal system are indicated by increased concentrations of sodium, chloride, dissolved solids, and total organic carbon. Concentrations of the constituents in the canal water generally decrease with distance from the Hillsboro Canal pumping station and are the result of dilution by receiving canal waters.

Florida

Exploration for blind geothermal systems in the eastern Great Basin of Utah: An update on the “Lund North” INGENIOUS detailed study site

Existing geothermal production in Utah is commonly collocated with surficial expressions of geothermal heat including active hot springs and hot spring deposits. However, geothermal potential across the Great Basin region is thought to be much higher for hidden or blind geothermal systems. Accordingly, exploration techniques that can locate geothermal resources that lack surface thermal features could support future development of these systems. The goal of the INGENIOUS project is to reduce exploration risk and discover new, economically viable hidden geothermal systems in the Great Basin region. This paper summarizes the efforts and preliminary results of blind geothermal resource prospecting in Utah as part of the larger INGENIOUS project. The Lund North site in the Basin and Range province of southwest Utah was designated as the fourth detailed study site for the project. The site was initially identified from the preliminary Play Fairway Analysis (PFA) geothermal favorability map, which is based on various data elements, and the identification of favorable structural settings across Utah. This site contains existing legacy data including a thermal gradient borehole with a heat-flow value exceeding 220 mW/m 2 . New data collected at this site include terrestrial gravity, magnetotellurics, transient electromagnetics, fluid geochemistry, geologic mapping, UAV-based lidar, paleomagnetism, aeromagnetic surveys, and a shallow temperature survey. Preliminary data and model interpretations corroborate the presence of a large, east-dipping, northeast-southwest-trending normal fault on the edge of a typical Basin and Range graben. Quaternary fault mapping refined by high-resolution lidar surveys suggests a complex step over fault geometry. Utilizing multi-disciplinary datasets for further site assessment at Lund North will facilitate the development of a local-scale PFA and geothermal conceptual model. This new data will be used to site successive thermal gradient drilling to verify heat flow with temperatures at depth at the Lund North site and further investigate the existence of a local geothermal system.

Utah

Assessment of the interconnection between Tampa Bay and the Floridan aquifer system: Historical groundwater data compilation and analysis, 1976–2022

The U.S. Geological Survey used existing data collected after the last major navigational channel modification in the mid-1980s to investigate groundwater levels and chloride concentrations in wells in the Floridan aquifer system and other aquifers beneath and near Tampa Bay. Tampa Bay is located on the west-central coast of Florida and provides access for commercial shipping. In 2021, the U.S. Army Corps of Engineers began to investigate alternatives to improve the efficiency of the deep-draft navigation channels within Tampa Bay, reduce costs, improve safety, and analyze the implications of modifying navigational channels. The Floridan aquifer system underlies Tampa Bay and is the primary source of public water supply in the region. Modifications to the channels have the potential to expose the Floridan aquifer system to the saltwater in Tampa Bay, with the potential to increase salinity in wells in the region. Other factors affecting the groundwater levels and the location of the freshwater/saltwater interface were also examined, including changes in sea level, groundwater extraction, and variations in climate. Groundwater levels and well-construction reports were used to identify whether different aquifer units are well-connected. Twelve wells had available data before and after the last major channel modifications, which took place in the 1980s, with six datasets of chloride concentration available in areas along the northern and eastern coastline of Tampa Bay, which is nearest to historical dredging activities. Of these six, Kendall’s τ and p -values indicated increasing trends in chloride concentration for three datasets (TR 11-2, TR 10-2, 51), no trend in chloride concentration for two datasets (TR 9-3, 50), and a decreasing trend in chloride concentration for one dataset (TR 9-1). The upward trends in chloride concentration observed for TR 10-2 and 51 are likely the result of changes in local groundwater withdrawals. Well TR 11-2 had a gradual increasing trend in chloride concentration, fresh groundwater throughout the period of record, and a 3- to 4-foot increase in hydraulic head during the period of record, possibly caused by the construction and control of the Tampa Bypass Canal, resulting in changes to the regional potentiometric surface.

Florida

Geological context and significance of the clay-sulfate transition region in Mount Sharp, Gale crater, Mars: An integrated assessment based on orbiter and rover data

On Mars, phyllosilicate (“clay”) minerals are often associated with older terrains, and sulfate minerals are associated with younger terrains, and this dichotomy is taken as evidence that Mars’ surface dried up over time. Therefore, in situ investigation of the Mount Sharp strata in Gale crater, which record a shift from dominantly clay-bearing to sulfate-bearing minerals, as seen in visible−near-infrared orbital reflectance spectra, is a key science objective for the Mars Science Laboratory (MSL) Curiosity rover mission. Here, we present regional (orbiter-based) and in situ (rover-based) evidence for a low-angle erosional unconformity that separates the lacustrine and marginal lacustrine deposits of the Carolyn Shoemaker formation from the dominantly eolian deposits of the lower Mirador formation within the orbitally defined clay-sulfate transition region. The up-section record of wetter (Carolyn Shoemaker formation) to drier (lower Mirador formation) depositional conditions is accompanied by distinct changes in diagenesis. Clay minerals occur preferentially within the Carolyn Shoemaker formation and are absent within the lower members of the Mirador formation. At and above the proposed unconformity, strata are characterized by an increase in diagenetic nodules enriched in X-ray amorphous Mg-sulfate. Early clay formation in the Carolyn Shoemaker formation may have created a hydraulic barrier such that later migrating magnesium- and sulfur-rich fluids accumulated preferentially within the lower members of the Mirador formation. The proposed unconformity may have also acted as a fluid conduit to further promote Mg-sulfate nodule formation at the Carolyn Shoemaker−Mirador formation boundary. These results confirm an association of the clay-sulfate transition with the drying of depositional environments, but they also suggest that at least some orbital sulfate signatures within the region are not time-congruent with the environmental signals extracted from primary sedimentology. Our findings highlight that complex interactions among primary depositional environment, erosion, and diagenesis contribute to the transition in clay-sulfate orbital signatures observed in the stratigraphy of Mount Sharp.

GSA Bulletin

Using stable oxygen isotope dual-inlet isotope-ratio mass spectrometry to elucidate uranium transport and mixed 230Th/U calcite formation ages at the seminal Devils Hole, Nevada, natural laboratory

Rationale Vein calcite in Devils Hole has been precipitating continuously in oxygen-isotope equilibrium at a constant temperature for over 500 000 years, providing an unmatched δ 18 O paleoclimate time series. A substantial issue is that coeval calcite (based on matching δ 18 O values) has uranium-series ages differing by 12 000 years. Methods An unparalleled high-accuracy δ 18 O chronology series from continuously submerged calcite was used to correct the published uranium-series ages of non-continuously formed calcite in two cores, cyclically exposed by water-table decline during glacial–interglacial transitions. This method relies on the premise that the δ 18 O values of coevally precipitated calcite are identical, allowing matching calcite δ 18 O values to establish formation ages. Results Exposed calcite can have apparent ages that are 12 000 years too young due to unrecognized uranium mobility and resulting mixed ages identified in over 50 mixed uranium-series ages from previous studies. Secondary uranium in fluids, sourced from the formation or dissolution of porous carbonate deposits (folia) with high uranium-238 ( 238 U) concentrations, has migrated up to 10 mm into vein calcite. Conclusions The continuously submerged Devils Hole δ 18 O chronology is not explained by orbital forcing. Rather, this chronology represents a regional climate record in the southern Great Basin of sea-surface-temperature (SST) variations off California, variations that preceded the last and penultimate deglaciations by 5000 to approximately 10 000 years. Temporal discrepancies between the continuously submerged Devils Hole chronology and other regional δ 18 O records (e.g., the Leviathan chronology) can be explained by unrecognized cryptic, pernicious uranium mobility, leading to model estimations that may be thousands of years younger than actual ages. Consequently, paleo-moisture availability, water-table, and groundwater recharge models based on these mixed uranium-series ages are too young by as much as 12 000 years. The potential for post-formation uranium addition in subaerial cores and speleothems underscores the need for caution in uranium-series dating, highlighting δ 18 O time-series comparisons as a method for identifying mixed ages.

Nevada