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Color-coded contour map of Mars M 25M RKN

NOTES ON BASE This map is based on data from the Mars Orbiter Laser Altimeter (MOLA) (Smith and others, 2001), an instrument on NASA's Mars Global Surveyor (MGS) spacecraft (Albee and others, 2001). The image used for the base of this map represents more than 600 million measurements gathered between 1999 and 2001, adjusted for consistency (Neumann and others, 2001, 2002) and converted to planetary radii. These have been converted to elevations above the areoid as determined from a martian gravity field solution GMM2 (Lemoine and others, 2001), truncated to degree and order 50, and oriented according to current standards (see below). The average accuracy of each point is originally ~100 meters in horizontal position, and ~1 meter in radius (Neumann, 2001). However, the total elevation uncertainty is at least +3 m due to the global error in the areoid (+1.8 meters according to Lemoine and others, 2001) and regional uncertainties in its shape (communication from Neumann, 2002). The measurements were converted into a digital elevation model (DEM) (communication from Neumann, 2002; Neumann and others, 2001; Smith and others, 2001) using Generic Mapping Tools software (Wessel and Smith, 1998), with a resolution of 0.015625 degrees per pixel or 64 pixels per degree. In projection, the pixels are 926.17 meters in size at the equator. PROJECTION The Mercator projection is used between latitudes +57°, with a central meridian at 0° and latitude equal to the nominal scale at 0°. The Polar Stereographic projection is used for the polar regions north of the +55° parallel and south of the –55° parallel with a central meridian set for both at 0°. The adopted equatorial radius is 3,396.19 km (Duxbury and others 2002; Seidelmann and others 2002). COORDINATE SYSTEM The MOLA data were initially referenced to an internally consistent inertial coordinate system, derived from tracking of the MGS spacecraft. By adopting appropriate values for the orientation of Mars as defined by the International Astronomical Union (IAU) and the International Association of Geodesy (IAG) (Seidelmann and others, 2002), these inertial coordinates were converted into the planet-fixed coordinates (longitude and latitude) used on this map. These values include the orientation of the north pole of Mars (including the effects of precession), the rotation rate of Mars, and a value for W0 of 176.630°, where W0 is the angle along the equator to the east, between the 0° meridian and the equator's intersection with the celestial equator at the standard epoch J2000.0 (Seidelmann and others, 2002). This value of W0 was chosen (Duxbury and others, 2002) in order to place the 0° meridian through the center of the small (~500 m) crater Airy-0, located in the crater Airy (de Vaucouleurs and others, 1973; Seidelmann and others, 2002). Longitude increases to the east, and latitude is planetocentric as allowed by IAU/IAG standards (Seidelmann and others, 2002) and in accordance with current NASA and USGS standards (Duxbury and others, 2002). A secondary grid (printed in red) has been added to the map as a reference to the west longitude/planetographic latitude system that is also allowed by IAU/IAG standards (Seidelmann and others, 2002) and has also been used for Mars. The figure adopted to compute this secondary grid is an oblate spheroid with an equatorial radius of 3,396.19 km and a polar radius of 3,376.2 km (Duxbury and others, 2002; Seidelmann and others, 2002). MAPPING TECHNIQUES To create the topographic base image, the original DEM produced by the MOLA team in Simple Cylindrical projection with a resolution of 64 pixels per degree was projected into the Mercator and Polar Stereographic pieces. A shaded relief was generated from each DEM with a sun angle of 30° from horizontal and a sun azimuth of 270°, as measured clockwise from north, and a vertical exaggeration of 100%. Illumination is from the west, which follows a long-standing USGS tradition for planetary maps. This allows for continuity in the shading between maps and quadrangles, and most closely resembles lighting conditions found on imagery. The DEM values were then mapped to a smooth global color look-up table. Note that the chosen color scheme simply represents elevation changes and is not intended to imply anything about surface characteristics (e.g., past or current presence of water or ice). These two files were then merged and scaled to 1:25 million for the Mercator portion and 1:15,196,708 for the two Polar Stereographic portions, with a resolution of 300 dots per inch. The projections have a common scale of 1:13,923,113 at +56° latitude. Contours were created from the DEM at a 1-kilometer interval. Contours for features with a diameter of 3 km or less (features too small for this map scale) were removed. The contours were then simplified by removing points along the contours spaced less than 1 km apart. NOMENCLATURE Names on this sheet are approved by the IAU and have been applied for features clearly visible at the scale of this map. For a complete list of the IAU-approved nomenclature for Mars, see the Gazetteer of Planetary Nomenclature at http://planetarynames.wr.usgs.gov/. Font color was chosen for readability. Names followed by an asterisk are provisionally approved. M 25M RKN: Abbreviation for Mars, 1:25,000,000 series, shaded relief (R), with color (K) and nomenclature (N) (Greeley and Batson, 1990).

Open-File Report↗

Twenty-three years of vegetation change in a fly-ash leachate impacted meadow

1. Blag Slough, located in Indiana Dunes National Lakeshore, has received leachates from nearby fly-ash ponds for 13 years (1967-1980). We have monitored vegetation and sediment of Blag Slough since 1982, two years after the sealing of the fly-ash ponds and one year after the substrate was first exposed. The pH of the soil has increased one order of magnitude from 3.0 to 4.0 over the 23 years (1982-2005). If the pH further increases the solubility of many heavy metals will decrease, except for arsenic. We provide evidence that boron and zinc were bioaccumulating in the leaves of woody plants in 1984. The ratio of leaf concentration and soil concentration of aluminum suggests this element was not bioaccumulating in woody plants in 1984. 2. Soil concentrations of iron, aluminum, arsenic, and strontium were higher nearest the fly-ash ponds in 2005. The southwest corner of Blag Slough and middle position of transect X had the highest elevated levels of these metals and correlated with the occurrence of mixed spikerush association (dominated by Eleocharis olivacea). 3. Only a few exotic species occurred in the Blag Slough. Common reed (Phragmites australis) was among such species that occurred in three large clones. Other exotic species included dandelion (Taraxacum officinale), mullein (Verbascum thapsis), Jerusalem oak goosefoot (Chenopodium botrys), and sheep sorrel (Rumex acetosella). Ruderal species have occurred including thistle (Cirsium spp.), fire weed (Erechtites hieracifolium), and horseweed (Conyza canadensis). While occasional cattail (Typha) have been sampled and mapped in Blag Slough they have never persisted for very long. 4. Species richness leveled off between 1991 and 2005, except for Transect X that had a peak in 1986-7. After an extreme rainfall event in August 18, 1990, Transect V had an average water depth of 0.70 cm, W had 7.1 cm, and X had 26.90 cm. Richness in Transect X declined to a low level in 1990 and 1991 after the extreme flooding event because this transect had the deepest surface water. 5. Typical late successional vegetation associations developed since 1991 include blue joint grass (Calamagrostis canadensis) and buttonbush (Cephalanthus occidentalis), but large areas consist of disturbance-dependent mosaics of rush (Juncus effusus) and other species. The large expanses of woolly sedge (Scirpus cyperinus) that dominated in the 1980’s was replaced by rush. 6. Late-successional associations (Glyceria canadensis and Calamagrostis canadensis) were closer to the wetland edge compared to the other associations after the dewatering. This pattern occurred because wet meadow vegetation persisted at the wetland edge during the period of industrial flooding, but since then these associations expanded greatly into the north half of Blag Slough. 7. Richness, diversity, and floristic quality index (FQI) increased with time at the plot, association, association trajectories, and wetland levels; whereas mean conservatism scores (mean C), the basis of FQI calculation, decreased in time. The high C values, assigned to coastal plain disjunct species and shrubs by judgment of botanists based on their empirical xii experience including regional or state level plant conservation designations are largely responsible for the contradicted trend between FQI and C. Such contradiction highlights a problem with the subjective assignment of C values, and thus the inadequacy of application of FQI in these wetland systems. 8. Occurrence of interveinal clearing in winged sumac (Rhus copallina), late boneset (Eupatorium serotinum), and black dewberry (Rubus occidentalis) suggest a potential phytotoxicity by heavy metals. However, cause-effect relationship between the metals and the plants are yet to be investigated. Nevertheless, boron and zinc accumulation ratios in leaves of woody plants (Betula populifolia, Populus tremuloides, Rhus copallina, and Rubus sp.) in 1984 suggest that boron and zinc were bioaccumulating in those species. Known toxicity effects of aluminum suggest that plants with vein clearing may be experiencing toxic effects of aluminum despite leaf concentrations 58 to 193 ppm. 9. In a greenhouse experiment, rye (Secale cereale) and radish (Raphanus sativus) germinated poorly in the sediments from Blag Slough having high concentrations of heavy metals (ZN, Mn, B, and NH4+) compared to potting soil. However, rye and radish plants grown in Blag Slough soil had shorter shoots and roots, lower root and shoot mass, and lower root to shoot mass ratios compared to plants grown in potting soil. These results suggest some effect of the soil constituents on rye and radish growth. 10. Positive signs in the recovery of Blag Slough include the increase in soil pH, the increasing dominance of late successional grasses, and the establishment of wetland zonation relative to seasonal water depth. Some areas of Blag Slough near the fly-ash ponds that continue to have high concentrations of heavy metals continue to be devoid of vegetation or are dominated by early successional species such as green spikerush. Localized heavy metal concentrations, evidence for zinc and boron bioaccumulation in 1984, vein clearing that persists today, effects of soil on rye and racish growth, and slow succession in the southern portion of Blag Slough suggest further toxicity study is necessary to better assess the impacts on this wetland ecosystem and identify restoration actions.

Indiana↗

Biocrusts: The living skin of the Earth

Biological soil crusts (biocrusts) form a “living skin” at the soil surface in many low productivity ecosystems around the world including water- and cold-limited environments, and early successional seres (Belnap et al. 2003). They may be composed of any configuration of soil surface-dwelling cyanobacteria, eukaryotic algae, lichens, mosses or liverworts, and support assemblages of decomposers and a faunal food web (Belnap et al. 2003). These soil surface communities have global relevance, as it has been recently estimated that they cover about 12% of the terrestrial surface currently (Rodriguez-Caballero et al. 2018). Biocrust communities are perhaps an ideal subject for the journal Plant and Soil, because they are simultaneously plant-like, due to their dominance by autotrophs, yet biocrusts are also clearly a physical feature of the soil given that component organisms are enmeshed in, adherent to, or otherwise in direct contact with the soil surface. The activity of the organisms is what engineers the well-aggregated thin layer at the soil surface that we recognize as a biocrust (Belnap et al. 2003). The contributions of biocrusts to ecosystem function has fueled much research interest, initially in the observation of biocrusts’ soil aggregating and erosion-resisting nature, and later as a multifunctional, globally-relevant ecosystem element instrumental in: 1. building or otherwise altering soil nutrient stocks through N-fixation (Elbert et al. 2012), dust trapping (Reynolds et al. 2001) and nutrient cycling (Strauss et al. 2012), 2. influencing hydrological properties of soil such as the water balance (Chamizo et al. 2016), and 3. The thermal energy balance of the ecosystem (Coradeau et al. 2016, Rutherford et al. 2017).

Plant and Soil↗

Transport and concentration controls for chloride, strontium, potassium and lead in Uvas Creek, a small cobble-bed stream in Santa Clara County, California, U.S.A.: 1. Conceptual model

Stream sediments adsorb certain solutes from streams, thereby significantly changing the solute composition; but little is known about the details and rates of these adsorptive processes. To investigate such processes, a 24-hr. injection of a solution containing chloride, strontium, potassium, sodium and lead was made at the head of a 640-m reach of Uvas Creek in west-central Santa Clara County, California. Uvas Creek is a cobble-bed pool-and-riffle stream draining the eastern slopes of the Santa Cruz Mountains. By September 12, 1973, after a long dry season, Uvas Creek had a low (0.0215 m 3 s −1 average) flow which varied diurnally, from 0.018 to 0.025 m 3 s −1 . Because stream discharge varied while the injection rate was constant, the concentration of tracers (injected solutes), after mixing in the stream, varied inversely with discharge. Chloride, a nonreactive solute, served as a tracer of water movement. Analysis of extensive chloride concentration data at five sites below the injection point during and after the injection demonstrated that there was considerable underflow of water through the stream gravels; however, the extent of underflow varied greatly within the study reach. Pre-injection water, displaced by tracer-laden water percolating through the gravels, diluted tracers in the stream channel, giving the mistaken impression of groundwater inflow at some points. Accurate measurement of total discharge in such streams requires prolonged tracer injection unless a reach can be found where underflow is negligible. Strontium and potassium were adsorbed by the bed sediments to a moderate extent and lead was strongly adsorbed. A high proportion of these metals could be removed by adsorption from percolating underflow because of extensive and intimate contact with bed sediments. After channel clearing following injection cutoff, 51% of the added strontium and 96% of the lead remained in the study reach, whereas only 19% of the chloride remained. Packets of sized sediment, placed in the stream before the experiment and withdrawn during and after the injection, indicated that the strontium absorbed on the 0.42–0.50-mm size sediment appeared to achieve near equilibrium with dissolved strontium within less than 2 hr. whereas 3.4–4.0-mm grains had not reached that stage after 24 hr. The cation-exchange capacity (CEC) of the sediments shows a “bimodal” distribution with grain size. Largest values are in the finest sizes, lower values in the fine-to-medium sand-size range, intermediate values in the coarse- to very coarse-grained sand, and decreasing values with size above very coarse-grained sand. This considerable exchange capacity in coarse-sand to granule-size particles means that a streambed, that has not been infilled with fines to reduce permeability, can be highly reactive and accessible throughout a rather thick sediment layer and hence have a large and available reactive capacity. As stream discharge increases from low flow, the ratio of underflow to channel flow should decrease rapidly with resultant diminution in percent of solutes sorbed within a particular stream reach.

California↗

Gonadal abnormalities in frogs (Lithobates spp.) collected from managed wetlands in an agricultural region of Nebraska, USA

Nebraska's Rainwater Basin (RWB) provides important wetland habitat for North American migratory birds. Concern exists that pesticide and nutrient runoff from surrounding row-crops enters wetlands degrading water quality and adversely affecting birds and wildlife. Frogs may be especially vulnerable. Plains leopard (Lithobates blairi) metamorphs from RWB wetlands with varying concentrations of pesticides were evaluated for a suite of biomarkers of exposure to endocrine active chemicals. Froglets had ovarian dysgenesis, high rates of testicular oocytes, and female-biased sex ratios however, there was no clear statistical association between pesticide concentrations and biomarkers. Data interpretation was hindered because timing and duration of exposures were unknown and due to an incomplete understanding of L. blairi sexual development. Emphasis is on describing the complex developmental biology of closely-related leopard frogs, how this understanding can explain RWB L. blairi anomalies, and the need for sampling at the appropriate life stage.

Nebraska↗

The rocks of Gusev Crater as viewed by the Mini-TES instrument

The Miniature Thermal Emission Spectrometer (Mini-TES) on board the Mars Exploration Rover Spirit is part of a payload designed to investigate whether a lake once existed in Gusev Crater. Mini-TES has observed hundreds of rocks along the rover's traverse into the Columbia Hills, yielding information on their distribution, bulk mineralogy, and the potential role of water at the site. Although dust in various forms produces contributions to the spectra, we have established techniques for dealing with it. All of the rocks encountered on the plains traverse from the lander to the base of the Columbia Hills share common spectral features consistent with an olivine-rich basaltic rock known as Adirondack Class. Beginning at the base of the West Spur of the Columbia Hills and across its length, the rocks are spectrally distinct from the plains but can be grouped into a common type called Clovis Class. These rocks, some of which appear as in-place outcrop, are dominated by a component whose spectral character is consistent with unaltered basaltic glass despite evidence from other rover instruments for significant alteration. The northwest flank of Husband Hill is covered in float rocks known as Wishstone Class with spectral features that can be attributed uniquely to plagioclase feldspar, a phase that represents more than half of the bulk mineralogy. Rare exceptions are three classes of basaltic "exotics" found scattered across Husband Hill that may represent impact ejecta and/or float derived from local intrusions within the hills. The rare outcrops observed on Husband Hill display distinctive spectral characteristics. The outcrop called Peace shows a feature attributable to molecular bound water, and the outcrop that hosts the rock called Watchtower displays a dominant basaltic glass component. Despite evidence from the rover's payload for significant alteration of some of the rocks, no unambiguous detection of crystalline phyllosilicates or other secondary silicates has been observed by Mini-TES. The mineralogical results supplied by Mini-TES provide no clear evidence that a lake once existed in Gusev Crater. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

Predicting crappie recruitment in Ohio reservoirs with spawning stock size, larval density, and chlorophyll concentrations

Stock-recruit models typically use only spawning stock size as a predictor of recruitment to a fishery. In this paper, however, we used spawning stock size as well as larval density and key environmental variables to predict recruitment of white crappies Pomoxis annularis and black crappies P. nigromaculatus, a genus notorious for variable recruitment. We sampled adults and recruits from 11 Ohio reservoirs and larvae from 9 reservoirs during 1998-2001. We sampled chlorophyll as an index of reservoir productivity and obtained daily estimates of water elevation to determine the impact of hydrology on recruitment. Akaike's information criterion (AIC) revealed that Ricker and Beverton-Holt stock-recruit models that included chlorophyll best explained the variation in larval density and age-2 recruits. Specifically, spawning stock catch per effort (CPE) and chlorophyll explained 63-64% of the variation in larval density. In turn, larval density and chlorophyll explained 43-49% of the variation in age-2 recruit CPE. Finally, spawning stock CPE and chlorophyll were the best predictors of recruit CPE (i.e., 74-86%). Although larval density and recruitment increased with chlorophyll, neither was related to seasonal water elevation. Also, the AIC generally did not distinguish between Ricker and Beverton-Holt models. From these relationships, we concluded that crappie recruitment can be limited by spawning stock CPE and larval production when spawning stock sizes are low (i.e., CPE , 5 crappies/net-night). At higher levels of spawning stock sizes, spawning stock CPE and recruitment were less clearly related. To predict recruitment in Ohio reservoirs, managers should assess spawning stock CPE with trap nets and estimate chlorophyll concentrations. To increase crappie recruitment in reservoirs where recruitment is consistently poor, managers should use regulations to increase spawning stock size, which, in turn, should increase larval production and recruits to the fishery.

North American Journal of Fisheries Management↗

Bottom currents and sediment transport in Long Island Sound: A modeling study

A high resolution (300-400 m grid spacing), process oriented modeling study was undertaken to elucidate the physical processes affecting the characteristics and distribution of sea-floor sedimentary environments in Long Island Sound. Simulations using idealized forcing and high-resolution bathymetry were performed using a three-dimensional circulation model ECOM (Blumberg and Mellor, 1987) and a stationary shallow water wave model HISWA (Holthuijsen et al., 1989). The relative contributions of tide-, density-, wind- and wave-driven bottom currents are assessed and related to observed characteristics of the sea-floor environments, and simple bedload sediment transport simulations are performed. The fine grid spacing allows features with scales of several kilometers to be resolved. The simulations clearly show physical processes that affect the observed sea-floor characteristics at both regional and local scales. Simulations of near-bottom tidal currents reveal a strong gradient in the funnel-shaped eastern part of the Sound, which parallels an observed gradient in sedimentary environments from erosion or nondeposition, through bedload transport and sediment sorting, to fine-grained deposition. A simulation of estuarine flow driven by the along-axis gradient in salinity shows generally westward bottom currents of 2-4 cm/s that are locally enhanced to 6-8 cm/s along the axial depression of the Sound. Bottom wind-driven currents flow downwind along the shallow margins of the basin, but flow against the wind in the deeper regions. These bottom flows (in opposition to the wind) are strongest in the axial depression and add to the estuarine flow when winds are from the west. The combination of enhanced bottom currents due to both estuarine circulation and the prevailing westerly winds provide an explanation for the relatively coarse sediments found along parts of the axial depression. Climatological simulations of wave-driven bottom currents show that frequent high-energy events occur along the shallow margins of the Sound, explaining the occurrence of relatively coarse sediments in these regions. Bedload sediment transport calculations show that the estuarine circulation coupled with the oscillatory tidal currents result in a net westward transport of sand in much of the eastern Sound. Local departures from this regional westward trend occur around topographic and shoreline irregularities, and there is strong predicted convergence of bedload transport over most of the large, linear sand ridges in the eastern Sound, providing a mechanism which prevents their decay. The strong correlation between the near-bottom current intensity based on the model results and the sediment response, as indicated by the distribution of sedimentary environments, provides a framework for predicting the long-term effects of anthropogenic activities.

New York↗

Transit losses and travel times for reservoir releases, upper Arkansas River Basin, Colorado

Factors influencing reservoir releases were analyzed for the upper reach of the Arkansas River in Colorado. The time of travel of releases from Twin Lakes Reservoir to Colorado Canal, a distance of 175 miles, ranges from 29 to 69 hours depending on the antecedent flow of the Arkansas River. Travel time of releases from Turquoise Lake is 42 hours more and travel time of releases from Clear Creek Reservoir is 12 hours less than for the Twin Lakes Reservoir to Colorado Canal reach. At the Colorado Canal, the streamflow hydrographs resulting from upstream reservoir releases are modified by channel and bank storage, inadvertent diversions, and evapotranspiration. During an average reservoir release of about 450 cubic feet per second for about 12 days, the released water arriving at the Colorado Canal is reduced by about 7 percent due to bank storage, by about 8 percent due to inadvertent diversions, and by about 1 percent due to evaporation. All release water in channel storage arrives at the Colorado Canal headgate during the release recession soon enough to be diverted and does not cause a loss. Transpiration losses due to bank storage are assumed to be negligible. This total average transportation Loss of 16 percent can vary from about 6 to 28 percent due to the antecedent river conditions, the amount and duration of the reservoir release, and the time of year the release occurs.

Colorado↗

Population Dynamics of Adult Lost River (Deltistes luxatus) and Shortnose (Chasmistes brevirostris) Suckers in Clear Lake Reservoir, California, 2006-08

We report results from ongoing research into the population dynamics of endangered Lost River and shortnose suckers in Clear Lake Reservoir, California. Results are included for sampling that occurred from fall 2006 to spring 2008. We summarize catches and passive integrated transponder tagging efforts from trammel net sampling in fall 2006 and fall 2007, and report on detections of tagged suckers on remote antennas in the primary spawning tributary, Willow Creek, in spring 2007 and spring 2008. Results from trammel net sampling were similar to previous years, although catches of suckers in fall 2006 were lower than in 2007 and past years. Lost River and shortnose suckers combined made up about 80 percent of the sucker catch in each year, and more than 2,000 new fish were tagged across the 2 years. Only a small number of the suckers captured in fall sampling were recaptures of previously tagged fish, reinforcing the importance of remote detections of fish for capture-recapture analysis. Detections of tagged suckers in Willow Creek were low in spring 2007, presumably because of low flows. Nonetheless, the proportions of tagged fish that were detected were reasonably high and capture-recapture analyses should be possible after another year of data collection. Run timing for Lost River and shortnose suckers was well described by first detections of individuals by antennas in Willow Creek, although we may not have installed the antennas early enough in 2008 to monitor the earliest portion of the Lost River sucker migration. The duration and magnitude of the spawning runs for both species were influenced by flows and water temperature. Flows in Willow Creek were much higher in 2008 than in 2007, and far more detections were recorded in 2008 and the migrations were more protracted. In both years and for both species, migrations began in early March at water temperatures between 5 and 6 deg C and peaks were related to periods of increasing water temperature. The sex ratio of Lost River suckers detected in Willow Creek was skewed toward males, despite consistently more females having been tagged in fall sampling. This pattern indicates that some tagged female Lost River suckers may be spawning elsewhere in the system, and we intend to investigate this possibility to verify or alter the representativeness of our spring monitoring. Length frequency analysis of fall trammel net catches showed that the populations of both species in Clear Lake Reservoir have undergone major demographic transitions during the last 15 years. In the mid-1990s, the populations were dominated by larger fish and showed little evidence of recent recruitment. These larger fish apparently disappeared in the late 1990s and early 2000s, and the populations are now dominated by fish that recruited into the adult populations in the late 1990s. The length frequencies from the last 4 years provide evidence of consistent recruitment into the Lost River sucker population, but provide no such evidence for the shortnose sucker population. Overall, annual growth rates for both species in Clear Lake were 2-4 times greater than growth rates for conspecifics in Upper Klamath Lake. However, little or no growth occurred for either species in Clear Lake between 2006 and 2007. Based on available evidence, we are unable to fully explain differences in growth rates between systems or among years within Clear Lake.

Open-File Report↗

Presence and potential significance of aromatic-ketone groups in aquatic humic substances

Aquatic humic- and fulvic-acid standards of the International Humic Substances Society were characterized, with emphasis on carbonyl-group nature and content, by carbon-13 nuclear-magnetic-resonance spectroscopy, proton nuclear-magnetic-resonance spectroscopy, and infrared spectroscopy. After comparing spectral results of underivatized humic and fulvic acids with spectral results of chemically modified derivatives, that allow improved observation of the carbonyl group, the data clearly indicated that aromatic ketone groups comprised the majority of the carbonyl-group content. About one ketone group per monocyclic aromatic ring was determined for both humic and fulvic acids. Aromatic-ketone groups were hypothesized to form by photolytic rearrangements and oxidation of phenolic ester and hydrocarbon precursors; these groups have potential significance regarding haloform formation in water, reactivity resulting from active hydrogen of the methyl and methylene adjacent to the ketone groups, and formation of hemiketal and lactol structures. Aromatic-ketone groups also may be the point of attachment between aliphatic and aromatic moieties of aquatic humic-substance structure.

Georgia↗

Nearly 400 million people are at higher risk of schistosomiasis because dams block the migration of snail-eating river prawns

Dams have long been associated with elevated burdens of human schistosomiasis, but how dams increase disease is not always clear, in part because dams have many ecological and socio-economic effects. A recent hypothesis argues that dams block reproduction of the migratory river prawns that eat the snail hosts of schistosomiasis. In the Senegal River Basin, there is evidence that prawn populations declined and schistosomiasis increased after completion of the Diama Dam. Restoring prawns to a water-access site upstream of the dam reduced snail density and reinfection rates in people. However, whether a similar cascade of effects (from dams to prawns to snails to human schistosomiasis) occurs elsewhere is unknown. Here, we examine large dams worldwide and identify where their catchments intersect with endemic schistosomiasis and the historical habitat ranges of large, migratory Macrobrachium spp. prawns. River prawn habitats are widespread, and we estimate that 277–385 million people live within schistosomiasis-endemic regions where river prawns are or were present (out of the 800 million people who are at risk of schistosomiasis). Using a published repository of schistosomiasis studies in sub-Saharan Africa, we compared infection before and after the construction of 14 large dams for people living in: (i) upstream catchments within historical habitats of native prawns, (ii) comparable undammed watersheds, and (iii) dammed catchments beyond the historical reach of migratory prawns. Damming was followed by greater increases in schistosomiasis within prawn habitats than outside prawn habitats. We estimate that one third to one half of the global population-at-risk of schistosomiasis could benefit from restoration of native prawns. Because dams block prawn migrations, our results suggest that prawn extirpation contributes to the sharp increase of schistosomiasis after damming, and points to prawn restoration as an ecological solution for reducing human disease.

Philosophical Transactions of the Royal Society B:↗

Determination of hydraulic properties in the vicinity of a landfill near Antioch, Illinois

A hydrogeologic investigation was conducted in and around a landfill near Antioch, Illinois, in December 1987. The investigation consisted, in part, of an aquifer test that was designed to determine the hydraulic connection between the hydrogeologic units in the area. The hydrogeologic units consist of a shallow, unconfined, sand and gravel aquifer of variable thickness that overlies an intermediate confining unit of variable thickness composed predominantly of till. Underlying the till is a deep, confined, sand and gravel aquifer that serves as the water supply for the village of Antioch. The aquifer test was conducted in the confined aquifer. Aquifer-test data were analyzed using the Hantush and Jacob method for a leaky confined aquifer with no storage in the confining unit. Calculated transmissivity of the confined aquifer ranged from 1.96x10^4 to 2.52x10^4 foot squared per day and storativity ranged from 2.10x10^-4 to 8.71x10^-4. Leakage through the confining unit ranged from 1.29x10^-4 to 7.84x10^-4 foot per day per foot, and hydraulic conductivity of the confining unit ranged from 3.22x10^-3 to 1.96x10^-2 foot per day. The Hantush method for analysis of a leaky confined aquifer with storage in the confining unit also was used to estimate aquifer and confining-unit properties. Transmissivity and storativity values calculated using the Hantush method are in good agreement with the values calculated from the Hantush and Jacob method. Properties of the confining unit were estimated using the ratio method of Neuman and Witherspoon. The estimated diffusivity of the confining unit ranged from 50.36 to 68.13 feet squared per day, A value for the vertical hydraulic conductivity of the confining unit calculated from data obtained using both the Hantush and the Neuman and Witherspoon methods was within the range of values calculated by the Hantush and Jacob method. The aquifer-test data clearly showed that the confining unit is hydraulically connected to the confined aquifer. The aquifer-test data also indicated that the unconfined aquifer becomes hydraulically connected to the deep sand and gravel aquifer within 24 hours after the start of pumping in the confined aquifer.

Water-Resources Investigations Report↗

Trophic structure of mesopelagic fishes in the Gulf of Mexico revealed by gut content and stable isotope analyses

Mesopelagic fishes represent an important component of the marine food web due to their global distributions, high abundances and ability to transport organic material throughout a large part of the water column. This study combined stable isotope (SIAs) and gut content analyses (GCAs) to characterize the trophic structure of mesopelagic fishes in the North-Central Gulf of Mexico. Additionally, this study examined whether mesopelagic fishes utilized chemosynthetic energy from cold seeps. Specimens were collected (9–25 August 2007) over three deep (>1,000 m) cold seeps at discrete depths (surface to 1,503 m) over the diurnal cycle. GCA classified 31 species (five families) of mesopelagic fishes into five feeding guilds: piscivores, large crustacean consumers, copepod consumers, generalists and mixed zooplanktivores. However, these guilds were less clearly defined based on stable isotope mixing model (MixSIAR) results, suggesting diets may be more mixed over longer time periods (weeks–months) and across co-occurring species. Copepods were likely important for the majority of mesopelagic fishes, consistent with GCA (this study) and previous literature. MixSIAR results also identified non-crustacean prey items, including salps and pteropods, as potentially important prey items for mesopelagic fishes, including those fishes not analysed in GCA ( Sternoptyx spp. and Melamphaidae). Salps and other soft-bodied species are often missed in GCAs. Mesopelagic fishes had δ 13 C results consistent with particulate organic matter serving as the baseline organic carbon source, fueling up to three trophic levels. Fishes that undergo diel vertical migration were depleted in 15 N relative to weak migrators, consistent with depth-specific isotope trends in sources and consumers, and assimilation of 15 N-depleted organic matter in surface waters. Linear correlations between fish size and δ 15 N values suggested ontogenetic changes in fish diets for several species. While there was no direct measure of mesopelagic fishes assimilating chemosynthetic material, detection of infrequent consumption of this food resource may be hindered by the assimilation of isotopically enriched photosynthetic organic matter. By utilizing multiple dietary metrics ( e.g . GCA, δ 13 C, δ 15 N, MixSIAR), this study better defined the trophic structure of mesopelagic fishes and allowed for insights on feeding, ultimately providing useful baseline information from which to track mesopelagic trophodynamics over time and space.

Marine Ecology↗

Quantifying seepage using heat as a tracer in selected irrigation canals, Walker River Basin, Nevada, 2012 and 2013

The Walker River is an important source of water for western Nevada. The river provides water for agriculture and recharge to local aquifers used by several communities. Farmers began diverting water from the Walker River in the 1860s to support growing agricultural development. Over time, the reduced inflows into Walker Lake from upstream reservoirs and diversions have resulted in 170 feet of lake level decline and increased dissolved-solids concentrations to levels that threaten aquatic ecosystems, including survival of Lahonton cutthroat trout, a native species listed in the Endangered Species Act. Investigations of the water-budget components in the Walker River Basin have revealed uncertainty in the recharge to aquifers from irrigation canals. To address this need, the U.S. Geological Survey conducted an extensive field study from March 2012 through October 2013 to quantify seepage losses in selected canals in the Smith Valley, Mason Valley, and Walker Lake Valley irrigation areas. The seepage rates estimated for the 2012 and 2013 irrigation seasons in the Smith Valley transect sites (Saroni and Plymouth canals) ranged between 0.01 to 2.5 feet per day (ft/d) (0.01 to 0.68 cubic feet per second per mile [ ft 3 /s-mi ]). From 2012 to 2013, the average number of days the canals had flowing water decreased from 190 to 125 due to drier climate and lack of water available for diversion from the Walker River. The nearly 50-percent reductions in volumetric loss rates between 2012 and 2013 were associated with less than average diversions into canals from the Walker River and reductions in infiltration rates following routine canal maintenance. Models developed for the Saroni canal in 2012 were recalibrated in 2013 to evaluate changes in seepage as a result of siltation. Just prior to the 2012 irrigation season, nearly the entire length of the canal was cleared of vegetation and debris to improve flow conveyance. In 2013, following the first year of maintenance, a 90-percent reduction in seepage was observed at one of the transect sites. The removal of sediment-clogged layers during canal maintenance may have more profound effects on seepage rates beyond what was observed at the transect sites. The seepage rates for the Saroni canal in 2012 ranged from 0.02 to 1.6 ft/d (0.03 to 0.4 ft 3 /s-mi ). The total seepage loss in the Saroni canal for the 2012 and 2013 irrigation seasons was estimated to be 1,100 and 590 acre-feet (acre-ft), respectively. Seepage rates on the Plymouth canal in Smith Valley in 2012 were among the lowest, ranging from 0.01 to 0.2 ft/d (0.01 to 0.1 ft 3 /s-mi ). In 2013, the seepage rate on the Plymouth canal was similar to 2012; however, the volumetric loss was reduced by 50 percent due to the 50-percent reduction in number of canal flow days. Lower rates of seepage on the Plymouth canal for the 2012 and 2013 irrigation seasons were estimated to be 210 and 130 acre-ft, respectively. The seepage rates estimated for the 2012 and 2013 irrigation seasons in the Mason Valley transect sites (Fox, Mickey, and Campbell ditches) ranged from 0.1 to 3.3 ft/d (0.2 to 1.3 ft 3 /s-mi ). The influence of water-table declines on seepage was observed at the Mickey and Campbell ditches. In 2012, the estimated seepage on the Mickey ditch was 1.6 ft/d during a period when the water-table altitude was at or above the canal altitude. Following extensive declines in the water table, the hydraulic gradient increased between the canal and the shallow aquifer, thereby increasing the seepage rates to 3.2 ft/d in 2013. During the period of hydraulic disconnection, seepage rates increased to 9.5 ft/d during intermittent periods of canal flow. For the Mickey ditch, the seepage loss in 2013 was 1.5 times the rate estimated in 2012 despite the canal having 45 days less flow. Similarly, the Campbell ditch seepage loss increased slightly from 660 to 700 acre-ft, a factor of 1.1, with 49 days less flow. The seepage loss for the Fox ditch did not exhibit significant year to year variability. The annual seepage loss estimated for 2012 and 2013 in the Fox ditch was 2,100 and 2,200 acre-ft, respectively. The seepage rates estimated for the 2013 irrigation season in the Walker Lake Valley transect sites (Schurz Lateral Canals 1A and 2A, and Canal 2) ranged from 0.7 to 0.9 ft/d (0.4 to 1.3 ft 3 /s-mi ). In Walker Lake Valley, diversions into Lateral Canals 1A and 2A during the 2013 irrigation season were highly intermittent, a characteristic common of lateral diversions. The annual estimated seepage loss in Walker Lake Valley ranged between 50 and 725 acre-ft among the transect sites.

California, Nevada↗

Surface water of Muddy Boggy River basin in south-central Oklahoma

This report summarizes basic hydrologic data of the surface water resources of Muddy Boggy River basin, and by analysis and interpretation, presents certain streamflow characteristics at specified points in the basin. Muddy Boggy River has a drainage area of 2,429 square miles. The climate is moist subhumid and the annual precipitation averages about 39 inches. Gross annual lake evaporation averages 54 inches. The average annual discharge at the gaging stations for the period 1938-62 was 24,000 acre-feet for Chickasaw Creek near Stringtown; 72,000 acre-feet for McGee Creek near Stringtown; 671,800 acre-feet for Muddy Boggy Creek near Farris; and 358,200 acre-feet for Clear Boggy Creek near Caney. Flow-duration curves of daily discharge have been developed to show the percentage of time various rates of discharge have been equaled or exceeded. Procedures for determining the frequency of annual floods at any point in the basin are given. Low-flow frequency curves that define the recurrence intervals of 7, 14, 30, 60, and 120 day mean flows have been prepared for two gaging stations. Curves showing the relation of measured discharge at the low-flow partial-record stations to the daily mean discharge at a base gaging station are presented. Discharge measurements made in February 1963 at selected sites show the areal distribution of low flow. The storage requirements to supplement natural flows have been prepared for two gaging-stations sites. The chemical quality of surface water of Muddy Boggy River basin varies from place-to-place during base flow periods. Limestone and dolomite outcrops and oilfield brines affect water quality in some areas. Water of North Boggy Creek, McGee Creek, and their tributaries contains less than 100 ppm (parts per million) dissolved solids. Water of other streams in Muddy Boggy River basin has a higher dissolved-solids content, but the content does not exceed 500 ppm. Water of Muddy Boggy River basin is usable for domestic, irrigation, and most industrial purposes. Softening of water from some streams may be desirable, however.

Open-File Report↗

Assessment of soil-gas, soil, and water contamination at the former 19th Street landfill, Fort Gordon, Georgia, 2009-2010

Soil gas, soil, and water were assessed for organic and inorganic constituents at the former 19th Street landfill at Fort Gordon, Georgia, from February to September 2010. Passive soil-gas samplers were analyzed to evaluate organic constituents in the hyporheic zone and flood plain of a creek and soil gas within the estimated boundaries of the former landfill. Soil and water samples were analyzed to evaluate inorganic constituents in soil samples, and organic and inorganic constituents in the surface water of a creek adjacent to the landfill, respectively. This assessment was conducted to provide environmental constituent data to Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. The passive soil-gas samplers deployed in the water-saturated hyporheic zone and flood plain of the creek adjacent to the former landfill indicated the presence of total petroleum hydrocarbon (TPH) and octane above method detection levels in groundwater beneath the creek bed and flood plain at all 12 soil-gas sampler locations. The TPH concentrations ranged from 51.4 to 81.4 micrograms per liter. Octane concentrations ranged from 1.78 to 2.63 micrograms per liter. These detections do not clearly identify specific source areas in the former landfill; moreover, detections of TPH and octane in a soil-gas sampler installed at a seep on the western bank of the creek indicated the potential for these constituents to be derived from source areas outside the estimated boundaries of the former landfill. A passive soil-gas sampler survey was conducted in the former landfill from June 30 to July 5, 2010, and involved 56 soil-gas samplers that were analyzed for petroleum and halogenated compounds not classified as chemical agents or explosives. The TPH soil-gas mass exceeded 2.0 micrograms in 21 samplers. Most noticeable are the two sites with TPH detections which are located in and near the hyporheic zone and are likely to affect the creek. However, most TPH detections were located in and immediately adjacent to a debris field located within the former landfill and in areas where debris was not visible, including the northwestern and southeastern parts of the study area. Two of the four soil-gas samplers installed within a former military training area adjacent to the landfill also had TPH detections above the method detection level. Benzene, toluene, ethylbenzene, and xylene (as combined BTEX mass) were detected at 0.02 microgram or greater in three soil-gas samplers installed at the northwestern boundary and in five samplers installed in the southeastern part of the study area. There was no BTEX mass detected above the method detection level in samplers installed in the debris field. Toluene was the most frequently detected BTEX compound. Compounds indicative of diesel-range organics were detected above 0.04 microgram in 12 soil-gas samplers and had a distribution similar to that of TPH, including being detected in the debris field. Undecane was the most frequently detected diesel compound. Chloroform and naphthalene were detected in eight and two soil-gas samplers, respectively. Five soil-gas samplers deployed during September 2010 were analyzed for organic compounds classified as chemical agents and explosives, but none exceeded the method detection levels. Five composite soil samples collected from within the estimated boundaries of the former landfill were analyzed for 35 inorganic constituents, but none of the constituents detected exceeded regional screening levels for industrial soils. The sample collected in the debris field exceeded background levels for aluminum, barium, calcium, chromium, lead, nickel, potassium, sodium, and zinc. Three surface-water samples were collected in September 2010 from a stormwater outfall culvert that drains to the creek and from the open channel of the creek at upstream and downstream locations relative to the outfall. Toluene was detected at 0.661 mi

Georgia↗

Recent surface movements in the Baldwin Hills, Los Angeles County, California

The Baldwin Hills are located in the northwest part of the densely populated Los Angeles basin. They comprise one of several groups of isolated hills that extend along the northwest-trending Newport-Inglewood zone of folds and faults, a structural lineament identified with a series of very productive oil fields. In addition to being the site of the Inglewood oil field, these hills are the site of surface deformation that has been monitored for over 35 years. This record of deformation, which includes differential subsidence, horizontal displacements, and surface rupturing, forms one of the best documented examples of oilfield-associated surface deformation yet recognized. The deformation is described in detail, analyzed as to cause(s), and finally attributed largely or essentially entirely to the exploitation of the spatially-associated Inglewood oil field. The Baldwin Hills are underlain by gently to moderately arched and conspicuously faulted Cenozoic sedimentary and volcanic rocks that overlie crystalline basement rocks at a depth of more than 10,000 feet. The Inglewood fault, a part of the northwest-trending Newport-Inglewood zone, diagonally transects the hills. Right-lateral displacements of 3,000-4,000 feet since middle or late Pliocene time and 1,500-2,000 feet during Quaternary time are indicated by offset structural and physio-graphic features; indications of vertical separations of up to about 200 feet during late Quaternary time occur locally. Evidence of continuing deformation includes recognized seismicity and regional elevation changes. The M5-5 1/2 Inglewood earthquake of 1920, the largest local earthquake of record, is believed to have originated immediately southeast of the Baldwin Hills; it was apparently unassociated with surficial fault displacements. Leveling in and around the west and central Los Angeles basin has shown that lowland stations have been consistently subsiding, whereas foothill stations commonly have been rising. Several seemingly persistent basins of differential subsidence and a zone of positive movement, roughly coincident with the Newport-Inglewood zone, have also been identified in the northwest part of the basin. A prominent, elliptically-shaped, northwest-trending subsidence bowl encompassing the northwest part of the Baldwin Hills, has been defined by repeated level circuits. Partial reconstruction of selected level circuits with respect to a common, relatively stable control point (Hollywood E-11), located on the edge of the subsidence bowl, has permitted evaluation of the subsidence since 1910 and 1911 at two points near the center of the bowl. Thus bench mark PBM 67 is estimated to have subsided approximately 4.324 feet between June 1910 and February 1963; and bench mark PBM 68 (the only bench mark within the subsidence bowl that was leveled prior to 1926 and has been repeatedly leveled since) subsided 3.846 feet between November 1911 and June 1962. Analysis of the available data indicates little if any elevation change at PBM 68 (or elsewhere throughout the Baldwin Hills-Inglewood area) associated with the Inglewood earthquake of 1920. Maximum subsidence of PBM 122 (which has remained very close to the center of subsidence since at . least 1950) between 1911 and 1963 is calculated to have been 5.67 feet. Horizontal displacements (with respect to a north-south base line about 3 miles east of the hills) of six triangulation points within the subsidence bowl have been measured for various periods between 1934 and 1963. Displacements have been generally toward the center of subsidence and almost precisely perpendicular to the immediately adjacent isobases of equal elevation change. Maximum movement has been recorded at triangulation point Baldwin Aux, which was displaced 2.21 feet between 1934 and 1961; horizontal displacements of three additional points ranged from 0.95 foot to 1.85 feet between 1936 and 1961. Displacements of 0.10-0.29 foot were recorded at all six monuments during the period 1961-1963. "Earth cracks" and surficial fault displacements were recognized in the Baldwin Hills at least as early as 1957. The cracks are relatively straight, generally continuous fractures confined to the structural block east of the Inglewood fault; they are concentrated in two areas centering on (1) the Baldwin Hills Reservoir and (2) the Stocker Street-LaBrea Avenue-Overhill Drive intersection. The cracks trend north to north-northeast and are nearly everywhere parallel to or coincident with minor faults and joints, and are generally orthogonal to radii emanating from the center of subsidence. Differential movement along the cracks has been almost entirely dip slip along steep to nearly vertical surfaces, and generally down-dropped toward the center of subsidence. Cumulative displacements have been as much as 6 or 7 inches. Rates of displacement have ranged widely, and the movement has generally occurred as creep or very small discrete jumps. A probable exception is the several inches of differential movement that is believed to have occurred along a crack through the floor of the Baldwin Hills Reservoir on or about December 14, 1963. The contemporary surface movements are attributable to one or more of the following phenomena: (1). exploitation of the Inglewood oil field; (2) changes in the ground-water regimen; (3) compaction of sedimentary materials in response to surface loading; (4) tectonic activity. The following considerations indicate that the differential subsidence is attributable largely or entirely to exploitation of the underlying Inglewood oil field: (1) the coincidence of the centers of the oil field, the producing structure, and the subsidence bowl; (2) the general correspondence between the pattern of subsidence and the outlines of the oil field; (3) the approximate coincidence between the initiation of production and the initiation of subsidence; (4) the generally linear relations between various measures of subsidence and liquid production from both the field as a whole and the exceptionally prolific Vickers zone in particular; (5) the sharp deceleration of subsidence in the eastern block of the field coincident with the initiation of full-scale water flooding there; (6) the many examples of oil fields In which both spatial and temporal associations between production and subsidence are recognized; (7) the many similarities of the subsidence-production relations in the Inglewood field to those in the Wilmington field, where the subsidence has been authoritatively attributed to oilfield operations; (8) the theoretical relation between subsidence or a tendency toward subsidence and increased effective pressure associated with underground fluid extraction. Consideration of six possible explanations for the increasing rather than decreasing or constant rate of subsidence with respect to reservoir fluid pressure decline suggests that measured or calculated down-hole reservoir fluid pressure decline is non-representative of average or real fluid pressure decline away from producing wells. The near-linear relations between net-liquid production and subsidence are explained through analogy with a tightly confined artesian system of infinite areal extent, where production must derive from liquid expansion and/or reservoir compaction. Test data from compaction studies in two other oil fields yield estimates of ultimate compaction of the Vickers zone resulting from a total loss of fluid pressure; these estimates range over an order of magnitude. The best estimate, based on these data and considerations of late Cenozoic history in the Baldwin Hills area, is about 10 feet. The centripetally-directed horizontal movements are considered attributable to exploitation of the Inglewood oil field on the basis of: (1) their well-defined symmetrical and geometrical association with the differential subsidence; (2) the similarities between these associations and those developed in and around other subsiding oil fields; and (3) the mechanical compatibility of these movements with subsidence induced by the extraction of subsurface materials. The earth cracks and surficial fault displacements are considered largely or entirely attributable to the exploitation of the Inglewood oil field on the basis of: (1) their spatial and temporal relations to both oil-field operations and the differential subsidence; (2) the similarities of these cracks and displacements to those generated in and around other oil fields and areas of subsurface materials extraction; and (3) surface strain patterns predicted from the measured vertical and horizontal surface movements. The cracks and displacements can i)e explained by an exploitation-based, elastic-rebound model which requires elastic compression of the sedimentary section in response to compaction-induced downdrag within those blocks around the periphery of the subsidence bowl. The measured displacements have been about one-quarter to one-half those predicted for a purely elastic system. Analysis of: (1) the history of ground-water extraction within and around the Baldwin Hills; and (2) subsidence associated with water-level declines in sediments comparable with those in the Baldwin Hills, indicate that the surface movements can be no more than incidentally attributed to changes in ground-water conditions. Similarly, analysis of the history of natural and artificial changes in surface loading indicate that these movements are generally unassociated with changes in surface loading conditions. Considerations of local geologic history and various tectonic associations indicate that it is very unlikely that the differential subsidence and horizontal movements are due to tectonic downwarping. There exists a far stronger prima facie argument for tectonic involvement in the earth cracking and associated fault displacements. This argument is disputed by; (1) the spatial and temporal relations of the earth cracks to, and their mechanical compatibility with, the nontectonic differential subsidence; (2) the absence of displacements on the Inglewood fault in conjunction with those along the conjugate earth cracks; (3) the probability that purely tectonic displaceMents would be characterized by oblique or strike slip; and (4) the absence of any clear temporal relation between crack growth and local seismicity, However, because as much as 10 percent of the local isobase gradient may be unexplained' by oil-field exploitation, a small fraction of this gradient, and thus the displacements among the southern group of cracks, may be attributable to tectonic activity. This fraction should have been insignificant in the presence of the strain pattern produced by nontectonic compaction of the underlying oil measures. Because nearly all of the observed and measured surface movements can be fully explained as the products of oil-field operations, yet can be no more than incidentally attributed to changes in ground-water conditions, surface loading, or tectonic activity, we conclude that these movements are attributable largely or essentially entirely to the exploitation of the Inglewood oil field.

California↗