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USGS2015

Geospatial compilation and digital map of centerpivot irrigated areas in the mid-Atlantic region, United States

To evaluate water availability within the Northern Atlantic Coastal Plain, the U.S. Geological Survey, in cooperation with the University of Delaware Agricultural Extension, created a dataset that maps the number of acres under center-pivot irrigation in the Northern Atlantic Coastal Plain study area. For this study, the extent of the Northern Atlantic Coastal Plain falls within areas of the States of New York, New Jersey, Delaware, Maryland, Virginia, and North Carolina. The irrigation dataset maps about 271,900 acres operated primarily under center-pivot irrigation in 57 counties. Manual digitizing was performed against aerial imagery in a process where operators used observable center-pivot irrigation signatures—such as irrigation arms, concentric wheel paths through cropped areas, and differential colors—to identify and map irrigated areas. The aerial imagery used for digitizing came from a variety of sources and seasons. The imagery contained a variety of spatial resolutions and included online imagery from the U.S. Department of Agriculture National Agricultural Imagery Program, Microsoft Bing Maps, and the Google Maps mapping service. The dates of the source images ranged from 2010 to 2012 for the U.S. Department of Agriculture imagery, whereas maps from the other mapping services were from 2013. Most of the irrigation in the study area is on the Delmarva Peninsula, where about 75 percent of the total acreage was delineated and where corn and soy bean are the main crops. The methods used to develop this dataset focused primarily on identifying center-pivot irrigation systems. In some instances (such as in in Suffolk County, New York), irrigated rectangular fields were observed through the aerial imagery, and these were included within the dataset. Other irrigation methods included subsurface drip and flood irrigation, which are commonly used on vegetable crops such as peppers and tomatoes and forage crops such as alfalfa in parts the western United States. Some fruit and nursery stock crops also use subsurface drip and flood irrigation. Drip irrigation is especially apparent in New Jersey where large plantings of truck crops are common. Subsurface drip and flood irrigation methods were not accounted for in this dataset. The U.S. Geological Survey collected these data to enhance the understanding of irrigation water demand and associated groundwater withdrawals for the Northern Atlantic Coastal Plain. The digitized acreage totals were compared with the irrigation estimates provided by the U.S. Department of Agriculture farm and ranch irrigation survey, which is the most comprehensive source of information on irrigation water use within the agricultural industry. This survey collects information on a wide range of topics, including the amount of water used, total acres irrigated, crop specific data, and even energy costs. The U.S. Department of Agriculture samples data for both entire States and individual counties.

Data Series↗
USGS2004

Water-use trends in the desert southwest: 1950-2000

The population of the Desert Southwest is among the fastest growing in the country. In this area, ground-water supplies have been developed, surface-water resources have been fully appropriated, and conservation and conjunctive water-use measures are being used to meet water-resource needs. Complex networks of water-distribution systems have been developed to deliver surface-water supplies, and interstate agreements, such as the Colorado River Compact of 1922, help manage the distribution of water among many States in the Western United States, including Arizona, California, Nevada, New Mexico, and Utah. The Colorado River, which lies on the borders of Arizona, California, and Nevada, plays an important role in supplying water to the Southwest. Water from the Colorado River is used to irrigate extensive farmland in the southern California deserts and is delivered to southern and central Arizona through the Central Arizona Project canal for domestic and agricultural uses. It is also the source of much of the water used for domestic purposes in southern Nevada. Estimated water-withdrawal and related data were compiled from various sources to identify trends in Arizona, California, Nevada, New Mexico, and Utah. More water is used for agriculture than domestic and industrial use in these five States. From 1950 to 2000, however, the percentage increase in withdrawal for domestic water use exceeded that for agricultural use. The estimated amount of water withdrawn for domestic, agricultural, and industrial purposes in Arizona, California, Nevada, New Mexico, and Utah increased 58 percent, from 39.6 to 62.8 million acre-feet, from 1950 to 2000. During this period withdrawals for domestic water use, which included self-supplied domestic and public supply (all deliveries to residential, commercial, and some industrial users), increased 410 percent from 2.0 million to 10.2 million acre-feet and the population in these five Southwestern States increased 250 percent. From 1965 to 2000, water withdrawals for agriculture, which were primarily for irrigation of crops and livestock uses, increased 14 percent in the five States, from 44.0 to 50.2 million acre-feet, while irrigated acreage increased 12 percent from 12.6 to 14.1 million acres. Water-use trends in the Southwest are dominated by water use in California where crop acreage is more than twice as large as the combined crop acreages in Arizona, Nevada, New Mexico, and Utah, and the population in 2000 was more than three times larger than the combined population of these States. Withdrawals for agriculture in California accounted for 62 percent of the water withdrawals for agriculture in the five States in 1950 and 68 percent in 2000. Water withdrawals for domestic-water use in California declined from 82 percent of the total domestic-water withdrawals in all five States in 1950 to 70 percent in 2000, indicating that the need for domestic withdrawals increased more in Arizona, Nevada, New Mexico, and Utah combined than in California. The population of California is larger than the combined population of Arizona, New Mexico, Nevada, and Utah, but the combined population of these smaller States grew faster than the population of California. From 1950 to 2000 the California population increased 220 percent, but the combined population of the four other States increased 390 percent. From 1960 to 2000, public supply per-capita use increased in Arizona, New Mexico, and California, and decreased in Nevada and Utah. Crop-application rates (water withdrawal for irrigation of crops divided by the irrigated crop acreage) from 1965 to 2000 ranged from 2.32 acre-feet per acre in Utah in 1975 to 6.21 acre-feet per acre in Arizona in 2000. More water is used per acre of irrigated land in Arizona than in the other four States. This could be due to several reasons, including differences in climate, conveyance losses, length of growing season, and type of crops grown. Trends in water withdrawals for industrial use are difficult to identify because of differences in data reporting from year to year. From 1950 to 2000, withdrawal for industrial use in the five States was generally less than 6 percent of the total withdrawal. Withdrawal for industrial use was less than 4 percent of the total withdrawal in Arizona, except in 1990; industrial withdrawal was less than 6 percent in California and less than 7 percent in Nevada, New Mexico, and Utah, except in 1980 when in Utah it was almost 12 percent of the total withdrawal. From 1950 to 2000, ground-water withdrawals increased 324 percent in Nevada, 147 percent in New Mexico, 208 percent in Utah, and 52 percent in California. Ground-water withdrawal decreased 15 percent in Arizona. For all five States, ground-water withdrawals increased 62 percent.

Scientific Investigations Report↗
USGS2009

Chloride in Groundwater and Surface Water in Areas Underlain by the Glacial Aquifer System, Northern United States

A study of chloride in groundwater and surface water was conducted for the glacial aquifer system of the northern United States in forested, agricultural, and urban areas by analyzing data collected for the National Water-Quality Assessment Program from 1991 to 2004. Groundwater-quality data from a sampling of 1,329 wells in 19 states were analyzed. Chloride concentrations were greater than the secondary maximum contaminant level established by the U.S. Environmental Protection Agency of 250 milligrams per liter in 2.5 percent of samples from 797 shallow monitoring wells and in 1.7 percent of samples from 532 drinking-water supply wells. Water samples from shallow monitoring wells in urban areas had the largest concentration of chloride, followed by water samples from agricultural and forested areas (medians of 46, 12, and 2.9 milligrams per liter, respectively). An analysis of chloride:bromide ratios, by mass, and chloride concentrations compared to binary mixing curves for dilute groundwater, halite, sewage and animal waste, potassium chloride fertilizer, basin brines, seawater, and landfill leachate in samples from monitoring wells indicated multiple sources of chloride in samples from wells in urban areas and agricultural areas. Water from shallow monitoring wells in urban areas had the largest chloride:bromide ratio, and samples with chloride:bromide ratios greater than 1,000 and chloride concentrations greater than 100 milligrams per liter were dominated by halite; however, the samples commonly contained mixtures that indicated input from sewage or animal waste. Chloride:bromide ratios were significantly larger in samples from public-supply drinking-water wells than from private drinking-water wells, and ratios were significantly larger in all drinking-water wells in eastern and central regions of the glacial aquifer system than in west-central and western regions of the glacial aquifer system. Surface-water-quality data collected regularly during varying time periods from 1991-2004 from 100 basins dominated by forested, agricultural, or urban land in 15 states were analyzed to determine maximum measured chloride concentrations. Samples from 15 sites in east, central, and west-central areas, collected primarily in winter, had chloride concentrations higher than the U.S. Environmental Protection Agency recommended chronic criterion concentration for aquatic life of 230 milligrams per liter. Concentrations of chloride in base-flow samples were predictive of maximum measured chloride concentrations, indicating that inputs of chloride from groundwater and (or) point-source wastewater discharges increase the likelihood of samples exceeding the recommended chronic aquatic criterion. Multiple linear regression analyses showed that the density of major roads, potential evapotranspiration, and the percentage of annual runoff from saturated overland flow were significant factors in describing the range of maximum measured chloride concentrations in the basins studied. Chloride loads and yields were determined at 95 surface-water-monitoring stations in basins dominated by forested, agricultural, or urban land. Annual chloride yield was largest in the urban basins (median of 88 tons per square mile) and smallest in the forested basins (median of 6.4 tons per square mile). The median chloride yield in the agricultural basins was 15.4 tons per square mile. Multiple linear regression analyses showed that the density of highways (roads in U.S. highway system), the number of major wastewater discharges in the basin, potential evapotranspiration, and urban minus agricultural land area were significant factors in describing the range of average annual chloride yields. Upward trends in chloride loads were apparent in several urban basins for which additional long-term data were available. Increases in chloride loads over time may be related to a variety of factors, including increases in road area and consequent deicing, incr

Scientific Investigations Report↗
USGS2012

Groundwater quality in the Columbia Plateau, Snake River Plain, and Oahu basaltic-rock and basin-fill aquifers in the Northwestern United States and Hawaii, 1992-2010

This assessment of groundwater-quality conditions of the Columbia Plateau, Snake River Plain, and Oahu for the period 1992–2010 is part of the U.S. Geological Survey’s National Water Quality Assessment (NAWQA) program. It shows where, when, why, and how specific water-quality conditions occur in groundwater of the three study areas and yields science-based implications for assessing and managing the quality of these water resources. The primary aquifers in the Columbia Plateau, Snake River Plain, and Oahu are mostly composed of fractured basalt, which makes their hydrology and geochemistry similar. In spite of the hydrogeologic similarities, there are climatic differences that affect the agricultural practices overlying the aquifers, which in turn affect the groundwater quality. Understanding groundwater-quality conditions and the natural and human factors that control groundwater quality is important because of the implications to human health, the sustainability of rural agricultural economies, and the substantial costs associated with land and water management, conservation, and regulation. The principal regional aquifers of the Columbia Plateau, Snake River Plain, and Oahu are highly vulnerable to contamination by chemicals applied at the land surface; essentially, they are as vulnerable as many shallow surficial aquifers elsewhere. The permeable and largely unconfined character of principal aquifers in the Columbia Plateau, Snake River Plain, and Oahu allow water and chemicals to infiltrate to the water table despite depths to water commonly in the hundreds of feet. The aquifers are essentially unconfined over large areas, having few extensive clay layers to impede infiltration through permeable volcanic rock and alluvial sediments. Agriculture is intensive in all three study areas, and heavy irrigation has imposed large artificial flows of irrigation recharge that rival or exceed natural recharge rates. Fertilizers and pesticides applied at land surface are leached from soil and transported to deep water tables with the infiltrating irrigation recharge, resulting in a layer of degraded water quality overlying better quality regional groundwater beneath. This “irrigation-recharge layer” is best known on Oahu, where it has been studied since the 1960s; however, the extent of nitrate and pesticide contamination in the Columbia Plateau and Snake River Plain indicate that the same situation exists in those areas. Contamination from agricultural and urban activities is present not only at shallow depths in surficial materials of the three areas, but extends regionally in the deep, principal bedrock aquifers that are tapped for drinking water by domestic and public-supply wells. Naturally occurring constituents and nitrate concentrations above human-health benchmarks—Maximum Contaminant Levels (MCLs), and Health-Based Screening Levels (HBSLs)—were more common in the Columbia Plateau and the Snake River Plain than in Oahu. Concentrations of anthropogenic constituents (constituents related to human activities) above human-health benchmarks were more common in Oahu. Naturally occurring contaminants, such as arsenic and radon, may be present in groundwater at concentrations of potential concern for human health in relatively undeveloped settings that otherwise may not be perceived as susceptible to contamination. Even though the median depth to groundwater in Oahu is more than 300 feet, the common occurrence of anthropogenic compounds in groundwater indicates that Oahu has a high susceptibility to contamination. Nitrate concentrations in groundwater were above the national background concentrations of 1 milligram per liter (mg/L) in all three study areas. In the Columbia Plateau, nitrate exceeded the human-health benchmark of 10 mg/L in 20 percent of the wells sampled. In the Snake River Plain, nitrate exceeded the human-health benchmark of 10 mg/L in 3 percent of the wells sampled. Nitrate can persist in groundwater for years and even decades in the oxygen-rich groundwater of the Columbia Plateau and the Snake River Plain, so prudent groundwater protection measures are critical to protect drinking water resources by reducing nitrate leaching from the land surface. Nitrate logistic regression models indicated that areas with a high percentage of land in crops (such as potatoes or sugarcane) and soils with low amounts of organic matter are most likely to have elevated nitrate concentrations in the groundwater. Areas where agricultural activities were absent had much lower probabilities of detecting elevated nitrate concentrations. The Columbia Plateau had a much higher probability of having elevated nitrate concentrations, with most of the land area having greater than a 50 percent probability of elevated nitrate concentrations. Oahu and the Snake River Plain had a much lower probability of having elevated nitrate concentrations because of their lower percentage of agricultural land. Pesticides were detected at many sites in groundwater of the Columbia Plateau, Snake River Plain, and Oahu but generally at low concentrations below human-health benchmarks. Atrazine and its degradate (a compound produced from the breakdown of a parent pesticide), deethylatrazine, were the most commonly detected pesticides in groundwater sampled in the Columbia Plateau and Snake River Plain. Bromacil was the most commonly detected pesticide on Oahu. The other pesticides most commonly detected in the study areas include simazine, hexazinone, metribuzin, diuron, prometon, metolachlor, p,p’ -DDE, dieldrin, 2-4-D, and alachlor. DDE (a degradate of DDT) and dieldrin are still being detected in groundwater despite having been banned for more than 30 years. Codetection of multiple pesticides in water from a single well was common. The widespread occurrence of pesticides in groundwater in the study areas indicates that the groundwater is highly susceptible to pesticide contamination. Some pesticides were detected in groundwater samples from all three study areas, but other pesticides were detected only in samples from Oahu, or only in samples from the Columbia Plateau and Snake River Plain. This is because some pesticides (such as atrazine) are broad-spectrum pesticides that are used on many crops in many different areas of the United States. Other pesticides (such as simazine, metribuzin, and metolachlor) are used on row crops (such as potatoes, barley, and alfalfa) grown in the Columbia Plateau and Snake River Plain, but not on pineapple or sugarcane grown in Oahu. Atrazine logistic-regression models indicate that areas with a high percentage of land in crops (such as potatoes or sugarcane), a low percentage of fallow land, and highly permeable soils with low amounts of organic matter are most likely to have atrazine detected in the groundwater. Areas where agricultural activities were absent had much lower probabilities of atrazine being detected. The Snake River Plain had a much higher probability of atrazine detections, with more than 50 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu had a much lower probability of atrazine contamination, with only 24 percent of the land area having greater than a 50 percent probability of atrazine contamination. Oahu and the Columbia Plateau had some of the highest percentages of soil fumigant detections in groundwater in the United States. Soil fumigants are volatile organic compounds (VOCs) used as pesticides, which are applied to soils to reduce populations of plant parasitic nematodes (harmful rootworms), weeds, fungal pathogens, and other soil-borne microorganisms. They are used in Oahu and the Columbia Plateau on crops such as pineapple and potatoes. All three areas (Columbia Plateau, Snake River Plain, and Oahu) had fumigant concentrations exceeding human-health benchmarks for drinking water.

Hawai'i, Idaho, Nevada, Oregon, Utah, Washington, ↗
USGS2014

Effects of land use, stream habitat, and water quality on biological communities of wadeable streams in the Illinois River Basin of Arkansas, 2011 and 2012

The Illinois River Basin includes an area of diverse land use in northwestern Arkansas. Land-use data collected in 2006 indicate that most of the land in the basin is agricultural. The agricultural land is used primarily for production of poultry and cattle. Eighteen sites were selected from the list of candidate sites based on drainage area, land use, presence or absence of an upstream wastewater-treatment plant, water quality, and other information gathered during the reconnaissance. An important consideration in the process was to select sites along gradients of forest to urban land use and forest to agricultural land use. Water-quality samples were collected for analysis of nutrients, and a multiparameter field meter was used to measure water temperature, specific conductance, pH, and dissolved oxygen. Streamflow was measured immediately following the water-quality sampling. Macroalgae coverage was estimated and periphyton, macroinvertebrate, and fish communities were sampled at each site. Stream habitat also was assessed. Many types of land-use, water-quality, and habitat factors affected one or more aspects of the biological communities. Several macroinvertebrate and fish metrics changed in response to changes in percent forest; sites that would be considered most disturbed, based on these metrics, are sites with the highest percentages of urban land use in their associated basins. The presence of large mats of macroalgae was one of the most noticeable biological characteristics in several streams within the Illinois River Basin. The highest macroalgae percent cover values were recorded at four sites downstream from wastewater-treatment plants. Macroalgae percent cover was strongly correlated only with bed substrate size, canopy closure, and specific conductance. Periphyton metrics were most often and most strongly correlated with riparian shading, specific conductance, substrate turbidity, percent agriculture, poultry house density, and unpaved road density; some of these factors were strongly correlated with percent forest, percent urban, or percent agriculture. Total biovolume of periphyton was not strongly correlated with any of the land use, habitat, or water-quality factors assessed in the present study. Although algal growth typically increases with higher nutrient concentrations and less shading, the standing crop of periphyton on rocks can be reduced by herbivorous macroinvertebrates and fish, which may explain why total biovolume in Ozark streams was not strongly affected by water-quality (or other habitat) factors. A macroinvertebrate index and several macroinvertebrate metrics were adversely affected by increasing urban and agricultural land use and associated environmental factors. Factors most commonly affecting the index and metrics included factors associated with water quality, stream geometry, sediment, land-use percentages, and road density. In general, the macroinvertebrate index was higher (indicative of least disturbance) at sites with greater percentages of forest in their basins, lower percentages of urban land in their basins, and lower paved road density. Upstream wastewater-treatment plants affected several metrics. For example, three of the five lowest macroinvertebrate index scores, two of the five lowest percent predator values, and two of the five highest percent gatherer-collector values were at sites downstream from wastewater-treatment plants. The Ozark Highlands fish index of biotic integrity and several fish metrics were adversely affected by increasing urban and agricultural land use and associated factors. Factors affecting these metrics included factors associated with nutrients, sediment, and shading. In general, the fish index of biotic integrity was higher at sites with higher percentages of forest in their basins, lower percentages of urban land in their basins, higher unpaved road density, and lower paved and total road density. Upstream wastewater-treatment plants seemed to affect some fish community metrics substantially but had little effect on other metrics. For example, three of the five lowest relative abundances of lithophilic spawner minus stonerollers and four of the five highest stoneroller abundances were at sites downstream from wastewater-treatment plants. Interpretations of the results of the study described in this report are limited by a number of factors. These factors individually and collectively add to uncertainty and variability in the responses to various environmental stresses. Notwithstanding the limiting factors, the biological responses of macroalgae cover and periphyton, macroinvertebrate, and fish metrics to environmental variables provide multiple lines of evidence that biological communities of these streams are affected by recent and ongoing land-use practices. For several biological metrics there appears to be a threshold of about 40 to 50 percent forest where values of these metrics change in magnitude. However, the four sites with more than 50 percent forest in their basins were the four sites sampled in late May–early June of 2012 (rather than July–August of 2011). The relative influence of season and forest percentage on the biological communities at these sites is unknown.

Arkansas↗
USGS2014

Water withdrawals, use, and trends in Florida, 2010

In 2010, the total amount of water withdrawn in Florida was estimated to be 14,988 million gallons per day (Mgal/d). Saline water accounted for 8,589 Mgal/d (57 percent) and freshwater accounted for 6,399 Mgal/d (43 percent). Groundwater accounted for 4,166 Mgal/d (65 percent) of freshwater withdrawals, and surface water accounted for the remaining 2,233 Mgal/d (35 percent). Surface water accounted for nearly all (99.9 percent) saline-water withdrawals. An additional 659 Mgal/d of reclaimed wastewater was used in Florida during 2010. Freshwater withdrawals were greatest in Palm Beach County (707 Mgal/d), and saline-water withdrawals were greatest in Hillsborough County (1,715 Mgal/d). Fresh groundwater provided drinking water (public supplied and self-supplied) for 17.33 million people (92 percent of Florida’s population), and fresh surface water provided drinking water for 1.47 million people (8 percent). The statewide public-supply gross per capita use for 2010 was 134 gallons per day, whereas the statewide public-supply domestic per capita use was 85 gallons per day. The majority of groundwater withdrawals (almost 62 percent) in 2010 were obtained from the Floridan aquifer system, which is present throughout most of the State. The majority of fresh surface-water withdrawals (56 percent) came from the southern Florida hydrologic unit subregion and is associated with Lake Okeechobee and the canals in the Everglades Agricultural Area of Glades, Hendry, and Palm Beach Counties, as well as the Caloosahatchee River and its tributaries in the agricultural areas of Collier, Glades, Hendry, and Lee Counties. Overall, agricultural irrigation accounted for 40 percent of the total freshwater withdrawals (ground and surface), followed by public supply with 35 percent. Public supply accounted for 48 percent of groundwater withdrawals, followed by agricultural self-supplied (34 percent), commercial-industrial-mining self-supplied (7 percent), recreational-landscape irrigation and domestic self-supplied (5 percent each), and power generation (less than 1 percent). Agricultural self-supplied accounted for 51 percent of fresh surface-water withdrawals, followed by power generation (25 percent), public supply (11 percent), recreational-landscape irrigation (9 percent), and commercial-industrial-mining self-supplied (4 percent). Power generation accounted for nearly all (99.8 percent) saline-water withdrawals. Of the 18.80 million people who resided in Florida during 2010, 41 percent (7.68 million people) resided in the South Florida Water Management District (SFWMD), 25 percent each resided in the Southwest Florida Water Management District (SWFWMD) and the St. Johns River Water Management District (SJRWMD) (4.73 and 4.70 million people, respectively), 7 percent (1.36 million people) resided in the Northwest Florida Water Management District (NWFWMD), and 2 percent (0.33 million people) resided in the Suwannee River Water Management District (SRWMD). The largest percentage of freshwater withdrawals was from the SFWMD (47 percent), followed by the SJRWMD (21 percent), SWFWMD (18 percent), NWFWMD (9 percent), and SRWMD (5 percent). Between 1950 and 2010, the population of Florida increased by 16.03 million (580 percent), and the total water withdrawals (fresh and saline) increased by 12,334 Mgal/d (465 percent). More recently, total freshwater withdrawals decreased by more than 1,792 Mgal/d (22 percent) between 2000 and 2010, while the population increased by 2.82 million (18 percent), and total freshwater withdrawals decreased by more than 474 Mgal/d (7 percent) between 2005 and 2010, while the population increased by 0.88 million (8 percent). The recent trend of decreases in freshwater withdrawals is a result of increased rainfall during this period, the development and use of alternative water sources, water conservation efforts, more conservative regulations and mandates, changes in economic conditions, and losses of irrigated lands. Fresh-water withdrawals for public supply, agricultural self-supplied use, and commercial-industrial-mining self-supplied use all decreased between 2000 and 2010 and between 2005 and 2010, whereas freshwater withdrawals for domestic self-supplied use, recreational-landscape irrigation use, and power generation use either remained the same or changed slightly during the decade. The use of highly mineralized groundwater (referred to as nonpotable water) as a source of drinking water has increased in Florida. Nonpotable water use for public supply has increased from nearly 2 Mgal/d in 1970 to about 165 Mgal/d in 2010. Nonpotable water is either blended or treated to meet drinking-water standards and is mostly used along the east and west coasts of central and southern Florida. The use of reclaimed wastewater increased from about 206 Mgal/d in 1986 to nearly 659 Mgal/d in 2010. More than three-quarters (79 percent) of reclaimed wastewater in 2010 was used to supplement potable-quality water withdrawals for urban irrigation, agricultural irrigation, and industrial use.

Florida↗
USGS2018

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗
USGS2019

Spatial and Temporal Patterns of Best Management Practice Implementation in the Chesapeake Bay Watershed, 1985–2014

Efforts to restore water quality in Chesapeake Bay and its tributaries often include extensive Best Management Practice (BMP) implementation on agricultural and developed lands. These BMPs include a variety of methods to reduce nutrient and sediment loads, such as cover crops, conservation tillage, urban filtering systems, and other practices. Estimates of BMP implementation throughout the Chesapeake Bay watershed were provided for each year from 1985 through 2014 by the Chesapeake Bay Program (CBP). This dataset of BMP implementation is a compilation of actions reported by New York, Maryland, Pennsylvania, Delaware, West Virginia, Virginia, and the District of Columbia, and includes a wide array of management activities. Management actions vary among the jurisdictions and generally reflect the typical land use in each region. The amount of implementation also varies according to different priorities, reporting practices, and special programs within each jurisdiction. For example, extensive cover crop implementation was reported in Maryland whereas Pennsylvania, in general, has lower levels of BMP implementation reported on cropland. Pennsylvania and Maryland have higher levels of infiltration BMPs on developed land compared to those in Virginia. Conservation tillage BMPs accounted for the majority of reported agricultural BMP implementation in 1985. By 2014, however, a more diverse collection of agricultural BMPs was reported and conservation tillage BMPs accounted for a smaller proportion of overall reported agricultural BMP implementation. After the year 2000, land-use change BMPs, such as land retirement, pasture fencing, and forest buffers, were more commonly reported across the Chesapeake Bay watershed. Expected changes in nutrient and sediment loads in the Chesapeake Bay watershed due to BMP implementation were estimated by use of specially designed annual scenarios of the CBP Partnership Phase 5.3.2 Watershed Model. Nitrogen loads to streams were estimated to be reduced by 11 percent from 1985 to 2014 due to the implementation of BMPs. Compared with 1985, phosphorus loads were estimated to be 19 percent lower and sediment loads were estimated to be 23 percent lower by 2014 due to the effects of BMPs. Reductions in total nitrogen from 1985 to 2014 due to BMPs varied spatially across the watershed and were estimated to be as high as 42 percent in areas of the Eastern Shore of the Chesapeake Bay. Reductions in phosphorus and sediment also varied spatially, with the largest reductions occurring in the Potomac watershed upstream of Washington, D.C. and the Eastern Shore of Maryland, according to the CBP model results. Additional model scenarios were developed to estimate the effect of individual BMP types. The largest estimated reductions in total nitrogen loads on agricultural lands in 2014 were attributed to land retirement, animal waste management systems, and conservation tillage. The largest estimated reductions in total phosphorus loads on agricultural lands were attributed to animal waste management systems, pasture fencing, and phytase feed additives in 2014. The largest estimated reduction in total sediment loads on agricultural lands was attributed to conservation tillage, pasture fencing, and conservation plans. Dry ponds, wet ponds, and constructed wetlands were reported extensively throughout the watershed. These BMPs accounted for about half of the reduction in nitrogen loads from developed land to streams, half of the phosphorus reduction, and about a third of the sediment reduction.

Chesapeake Bay Watershed↗
USGS2020

Water withdrawals, uses, and trends in Florida, 2015

In 2015, the total amount of water withdrawn in Florida was estimated to be 15,319 million gallons per day (Mgal/d). Saline water accounted for 9,598 Mgal/d (63 percent) and freshwater accounted for 5,721 Mgal/d (37 percent) of the total. Groundwater accounted for 3,604 Mgal/d (63 percent) of freshwater withdrawals and surface water accounted for the remaining 2,117 Mgal/d (37 percent). Surface-water sources accounted for 9,401 Mgal/d (98 percent) of the saline-water withdrawals, and groundwater sources accounted for the remaining 198 Mgal/d (2 percent). The majority of groundwater withdrawals (almost 62 percent) in 2015 were from the Floridan aquifer system, which is used throughout most of the State while the majority of fresh surface-water withdrawals (52 percent) occurred in the Southern Florida Subregion, a hydrologic unit that includes Lake Okeechobee and canals in the Everglades Agricultural Area. Groundwater provided drinking water (public supplied and self-supplied) for 18.324 million people (92 percent of Florida’s population), and fresh surface water provided drinking water for 1.491 million people (8 percent). Overall, public supply accounted for 39 percent of the total freshwater withdrawals (ground and surface) and 53 percent of groundwater withdrawals, followed by agricultural self-supplied uses, which accounted for 37 percent of the total freshwater withdrawals and 28 percent of groundwater withdrawals. Other self-supplied groundwater withdrawals include commercial-industrial-mining self-supplied (8 percent), recreational-landscape irrigation and domestic self-supplied (5 percent each), and power generation (less than 1 percent). Agricultural self-supplied withdrawals accounted for 51 percent of fresh surface-water withdrawals, followed by power generation (19 percent), public supply (15 percent), recreational-landscape irrigation (10 percent), and commercial-industrial-mining self-supplied (5 percent). In 1975, agricultural water withdrawals accounted for 43 percent of the total freshwater withdrawals, followed by power generation (24 percent) and public supply (17 percent). By 2000, agricultural withdrawals increased to 48 percent of the total freshwater withdrawals, followed by public supply (30 percent). For 2015, agricultural self-supplied decreased to 37 percent of total freshwater withdrawals, and was surpassed by public supply at 39 percent. Over the 40-year period between 1975 and 2015, increases in freshwater withdrawals caused by large gains in population and the expansion of irrigated acreage were offset by decreases in water used for power generation and commercial-industrial-mining withdrawals. Since 2000, however, irrigated acreage has decreased statewide because of crop disease, storm damage, and urbanization. This decline, coupled with large gains in water conservation measures in the farming industry, has led to agricultural withdrawals in Florida being less than public-supply withdrawals for the first time since water-use data were first reported in 1965.

Florida↗
USGS2025

Updating and recalibrating the integrated Santa Rosa Plain Hydrologic Model to assess stream depletion and to simulate future climate and management scenarios in Santa Rosa, Sonoma County, California

The Santa Rosa Plain Hydrologic Model (SRPHM) was developed and published in 2014 through a collaboration between the U.S. Geological Survey (USGS) and Sonoma Water to analyze the hydrologic system in the Santa Rosa Plain watershed, help meet the increasing demand for fresh water, and prepare for future uncertainties in water resources. The original model simulated hydrological conditions and water use from water years 1975 to 2010. Recently (2023), the USGS, in cooperation with Sonoma Water and the California State Water Resources Control Board, updated the SRPHM model to extend its simulation period to the end of the 2018 calendar year, incorporate new estimates of rural and agricultural water use, and use efficient input format for climate variables. The updated model was recalibrated, and evaluation of the new model calibration is included in this report. This report presents the results of comparing the hydraulic heads, streamflow, and groundwater budget simulated by the updated model with those generated by the original model and observed data. The main difference in the simulated budget between the original and updated SRPHM is the estimates of agricultural pumping, rural domestic pumping, and return flow generated from rural water use that was not simulated in the original model. The revised agricultural pumping is simulated using the agricultural package, which constrains pumping to available groundwater. The use of the agricultural package leads to a more realistic estimation of agricultural water use, with revised agricultural pumping being one-third less than that in the original model. The revised rural pumping is about half of the pumping in the original model because of using detailed parcel data to estimate population density in rural areas instead of coarse census tracts. Overall, average total inflows for water years 2006–10 simulated by the updated model were about 2 percent less than the original model, and the average total updated outflows were nearly 5 percent less than the original model. The updated model was then used to generate stream depletion maps, simulate climate change scenarios during 2019–99, and simulate water rights allocation using the Model for Decision Support in Integrated River Basin Management (MODSIM). The results from simulating eight future climate scenarios indicated either an increase in groundwater storage or no significant change in the next 80 years, along with an increase in recharge, an increase in actual evapotranspiration in six out of eight climate projections, and an increase in surface runoff. The increases in the simulated future groundwater storage, recharge, evapotranspiration, and runoff in most climate projections are mainly driven by the projected increase in precipitation in most of the future climate scenarios. The updated model also was used to test a pilot case study demonstrating water-resource allocation among different users with different water rights using the integrated MODSIM-Groundwater and Surface-Water Flow Model (GSFLOW) platform. The updated SRPHM serves as a valuable tool for analyzing historical and future hydrologic conditions in the Santa Rosa Plain watershed and preparing for future uncertainties.

California↗
USGS2003

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗
USGS1986

Occurrence of nitrate and herbicides in ground water in the upper Conestoga River basin, Pennsylvania : water-quality study of the Conestoga River headwaters, Pennsylvania

Nitrate-nitrogen and herbicide ground-water data is being collected by the u.s. Geological Survey as part of the nationwide Rural Clean Water Program designed to determine the effects of agricultural-management practices on water quality. Data collected from September 1982 to October 1983 · in the 188-square mile intensively farmed upper Conestoga River basin indicates high nitrate and detectable herbicide concentrations in ground water are closely associated with agricultural practices and carbonate geology. Maximum nitrate-nitrogen concentrations from 42 wells and one spring ranged from 37 to 40 milligrams per liter in the agricultural areas, and 12 to 19 milligrams per liter in the nonagricultural areas. Median concentrations of nitrate generally were three times higher in wells that penetrated carbonate rock than in wells that penetrated noncarbonate rocks. More than 40 percent of the wells in the carbonate and agricultural areas had dissolved-nitrate concentrations that exceeded 10 milligrams per liter as nitrogen, the criterion established by the U.S. Environmental Protection Agency as excessive for drinking water. Atrazine, simazine, alachlor, and metolachlor were found almost exclusively in the agricultural and carbonate areas. Water-quality data collected before and after installation of terraces, manure storage, and nutrient and herbicide management practices is valuable in determining the effectiveness of these agricultural practices, and will provide useful information to protect agricultural land, local water supplies, the Conestoga and Susquehanna Rivers and ultimately the Chesapeake Bay.

Pennsylvania↗
USGS1996

Instream investigations in the Beaver Creek Watershed in West Tennessee, 1991-95

The U.S. Geological Survey (USGS), in cooperation with the Tennessee Department of Agriculture, began a long-term scientific investigation in 1989 to evaluate the effect of agricultural activities on water quality and the effectiveness of agricultural best management practices in the Beaver Creek watershed, West Tennessee. In 1993 as a part of this study, the USGS, in cooperation with the Natural Resources Conservation Service, Shelby County Soil Conservation District, and the Tennessee Soybean Promotion Board, began an evaluation of the physical, chemical, biological and hydrological factors that affect water quality in streams and wetlands, and instream resource-management systems to treat agricultural nonpoint-source runoff and improve water quality. The purpose of this report is to present the results of three studies of stream and wetland investigations and a study on the transport of aldicarb from an agricultural field in the Beaver Creek watershed. A natural bottomland hardwood wetland and an artificially constructed wetland were evaluated as instream resource-management systems. These two studies showed that wetlands are an effective way to improve the quality of agricultural nonpoint-source runoff. The wetlands reduced concentrations and loads of suspended sediments, nutrients, and pesticides in the streams. A third paper documents the influence of riparian vegetation on the biological structure and water quality of a small stream draining an agricultural field. A comparison of the upper reach lined with herbaceous plants and the lower reach with mature woody vegetation showed a more stable biological community structure and Water- quality characteristics in the woody reach than in the herbaceous reach. The water-quality characteristics monitored were pH, temperature, dissolved oxygen, and specific conductance. The herbaceous reach had a greater diversity and abundance of organisms during spring and early summer, but the abundance dropped by approximately 85 percent during late summer. A fourth study describes the transport of aldicarb and its metabolites--aldicarb sulfoxide and aldicarb sulfone-in runoff at a small stream draining a cotton field. During 1991 to 1995, aldicarb and its metabolites were detected in runoff events. The highest concentrations occurred when aldicarb was applied to the field just hours before a rain storm. Aldicarb was not detectable in runoff a few weeks after application. The metabolites of aldicarb were detectable for 76 days after application. These studies demonstrate streambank vegetation and wetlands have a significant influence on stream water quality. The importance of weather conditions to herbicide application and runoff also is evident. This information can be used by resource managers to sustain and improve our Nation's streams for future generations.

Water-Resources Investigations Report↗
USGS1997

Distribution of fish, benthic invertebrate, and algal communities in relation to physical and chemical conditions, Yakima River basin, Washington, 1990

Biological investigations were conducted in the Yakima River Basin, Washington, in conjunction with a pilot study for the U.S. Geological Survey's National Water-Quality Assessment Program. Ecological surveys were conducted at 25 sites in 1990 to (1) assess water-quality conditions based on fish, benthic invertebrate, and algal communities; (2) determine the hydrologic, habitat, and chemical factors that affect the distributions of these organisms; and (3) relate physical and chemical conditions to water quality. Results of these investigations showed that land uses and other associated human activities influenced the biological characteristics of streams and rivers and overall water-quality conditions. Fish communities of headwater streams in the Cascades and Eastern Cascades ecoregions of the Yakima River Basin were primarily composed of salmonids and sculpins, with cyprinids dominating in the rest of the basin. The most common of the 33 fish taxa collected were speckled dace, rainbow trout, and Paiute sculpin. The highest number of taxa (193) was found among the inverte- brates. Insects, particularly sensitive forms such as mayflies, stoneflies, and caddisflies (EPT--Ephemeroptera, Plecoptera, and Trichoptera fauna), formed the majority of the invertebrate communities of the Cascades and Eastern Cascades ecoregions. Diatoms dominated algal communities throughout the basin; 134 algal taxa were found on submerged rocks, but other stream microhabitats were not sampled as part of the study. Sensitive red algae and diatoms were predominant in the Cascades and Eastern Cascades ecoregions, whereas the abundance of eutrophic diatoms and green algae was large in the Columbia Basin ecoregion of the Yakima River Basin. Ordination of physical, chemical, and biological site characteristics indicated that elevation was the dominant factor accounting for the distribution of biota in the Yakima River Basin; agricultural intensity and stream size were of secondary importance. Ordination identified three site groups and three community types. Site groups consisted of (1) small streams of the Cascades and Eastern Cascades ecoregions, (2) small streams of the Columbia Basin ecoregions, and (3) large rivers of the Cascades and Columbia Basin ecoregions. The small streams of the Columbia Basin could be further subdivided into two groups--one where agricultural intensity was low and one where agricultural intensity was moderate to high. Dividing the basin into these three groups removed much of the influence of elevation and facilitated the analysis of land-use effects. Community types identified by ordination were (1) high elevation, cold-water communities associated with low agricultural intensity; (2) lower elevation, warm-water communities associated with low agricultural intensity, and (3) lower elevation, warm-water communities associated with moderate to high agricultural intensity. Multimetric community condition indices indicated that sites in the Cascades and Eastern Cascades site group were largely unimpaired. In contrast, all but two sites in the Columbia Basin site group were impaired, some severely. Agriculture (nutrients and pesticides) was the primary factor responsible for this impairment, and all impaired sites were characterized by multiple indicators of impairment. Three sites (Granger Drain, Moxee Drain, and Spring Creek) had high levels of impairment. Sites in the large-river site group were moderately to severely impaired downstream from the city of Yakima. High levels of impairment at large-river sites corresponded with high levels of pesticides in fish tissues and the occurrence of external anomalies.

Washington↗
USGS1997

Assessment of nutrients, suspended sediment, and pesticides in surface water of the upper Snake River basin, Idaho and western Wyoming, water years 1991-95

A water-quality investigation of the upper Snake River Basin began in 1991 as part of the U.S. Geological Survey's National Water- Quality Assessment Program. As part of the investigation, intensive monitoring was conducted during water years 1993 through 1995 to assess surface-water quality in the basin. Sampling and analysis focused on nutrients, suspended sediments, and pesticides because of nationwide interest in these constituents. Concentrations of nutrients and suspended sediment in water samples from 19 sites in the upper Snake River Basin, including nine on the main stem, were assessed. In general, concentrations of nutrients and suspended sediment were smaller in water from the 11 sites upstream from American Falls Reservoir than in water from the 8 sites downstream from the reservoir where effects from land-use activities are most pronounced. Median concentrations of dissolved nitrite plus nitrate as nitrogen at the 19 sites ranged from less than 0.05 to 1.60 milligrams per liter; total phosphorus as phosphorus, less than 0.01 to 0.11 milligrams per liter; and suspended sediment, 4 to 72 milligrams per liter. Concentrations of nutrients and suspended sediment in the main stem of the Snake River, in general, increased downstream. The largest concentrations in the main stem were in the middle reach of the Snake River between Milner Dam and the outlet of the upper Snake River Basin at King Hill. Significant differences (p<0.05) in nutrient and suspended sediment concentrations were noted among groups of sites categorized by the quantity of agricultural land in their upstream drainage basins. Water samples collected from sites in drainage basins where agricultural land constituted less than 10 percent of the land use contained significantly smaller concentrations of nutrients and suspended sediment than samples from sites in drainage basins where agricultural land constituted more than 10 percent of the land use. Significant differences in nutrient and suspended sediment concentrations were inconsistent among groups representing 10 to 19 percent, 20 to 29 percent, and greater than 29 percent agricultural land use. Seasonal concentrations of dissolved nitrite plus nitrate, total phosphorus, and suspended sediment were significantly different among most of the agricultural land-use groups. Concentrations of dissolved nitrite plus nitrate were largest during the nonirrigation season, October through March. Concentrations of total phosphorus and suspended sediment, in general, were largest during high streamflow, April through June. Nutrient and suspended sediment inputs to the middle Snake reach were from a variety of sources. During water year 1995, springs were the primary source of water and total nitrogen to the river and accounted for 66 and 60 percent of the total input, respectively. Isotope and water-table information indicated that the springs derived most of their nitrogen from agricultural activities along the margins of the Snake River. Aquacultural effluent was a major source of ammonia (82 percent), organic nitrogen (30 percent), and total phosphorus (35 percent). Tributary streams were a major source of organic nitrogen (28 percent) and suspended sediment (58 percent). In proportion to its discharge (less than 1 percent), the Twin Falls sewage-treatment plant was a major source of total phosphorus (13 percent). A comparison of discharge and loading in water year 1995 with estimates of instream transport showed a good correlation (relative difference of less than 15 percent) for discharge, total organic nitrogen, dissolved nitrite plus nitrate, total nitrogen, and total phosphorus. Estimates of dissolved ammonia and suspended sediment loads correlated poorly with instream transport; relative differences were about 79 and 61 percent, respectively. The pesticides EPTC, atrazine, desethylatrazine, metolachlor, and alachlor were the most commonly detected in the upper Snake River Basin and accounted for about 75 percent of all pesticide detections. All pesticides detected were at concentrations less than 1 microgram per liter and below water-quality criteria established by the U.S. Environmental Protection Agency. In samples collected from two small agriculturally dominated tributary basins, the largest number and concentrations of pesticides were detected in May and June following early growing season applications. At one of the sites, the pesticide atrazine and its metabolite desethylatrazine were detected throughout the year. On the basis of 37 samples collected basinwide in May and June 1994, total annual subbasin applications and instantaneous instream fluxes of EPTC and atrazine showed logarithmic relations with coefficients of determination (R2 values) of 0.55 and 0.62, respectively. At the time of sampling, the median daily flux of EPTC was about 0.0001 percent of the annual quantity applied, whereas the median daily flux of atrazine was between 0.001 and 0.01 percent.

Idaho;Wyoming↗
USGS1998

Wet atmospheric deposition of pesticides in Minnesota, 1989-94

All of the rain samples during the growing season had detectable quantities of at least one pesticide, but most of the pesticides were only infrequently observed. The most frequently detected compounds were the herbicides alachlor, atrazine, cyanazine, and metolachlor, and in 1994, its first year of registration, acetochlor. Peak concentrations of most herbicides in rainfall occurred shortly after their application periods in the spring. Peak concentrations of most of the insecticides occurred later in the summer. The majority of the wet depositional flux of pesticides occurred between early May and October. The annual wet depositional flux of pesticides is 5 orders of magnitude less than is the "annual flux" normally applied on an agricultural field, although some of the pesticides in rain are deposited in areas far removed from agricultural fields. The annual variability in pesticide deposition can be explained by year-to-year differences in climate and pesticide use patterns. The one sampling site (Lamberton) that was in an area dominated by row crop agriculture showed a significantly greater annual flux than the other four sampling sites that were in areas of either urbanization or less intensive agricultural. Regional deposition, away from a local source, can be inferred from these four sites because they have annual pesticide fluxes that are very similar for any given year. The observation of agricultural pesticides (not registered for home and garden use) in rain and storm runoff in the urban area indicates their transport from areas of agricultural use. Urban areas may be the best locations for assessing changes in regional use and deposition of agricultural pesticides. The pesticide fluxes in the streams out of the small three watersheds was compared to the pesticide flux into the watersheds in rain. The data indicate that flux into the watersheds from the rain is generally much greater than the flux from the watersheds in the streams. Therefore, a large fraction of the pesticides deposited in rain is retained within the watersheds. For the urban area, this is on the order of 98 percent for the four most commonly observed herbicides in rain and runoff.

Minnesota↗
USGS1998

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma — Nutrients, bacteria, organic carbon, and suspended sediment in surface water, 1993-95

Nutrient, bacteria, organic carbon, and suspended- sediment samples were collected from 1993-95 at 43 surface-water-quality sampling sites within the Ozark Plateaus National Water- Quality Assessment Program study unit. Most surface-water-quality sites have small or medium drainage basins, near-homogenous land uses (primarily agricultural or forest), and are located predominantly in the Springfield and Salem Plateaus. The water-quality data were analyzed using selected descriptive and statistical methods to determine factors affecting occurrence in streams in the study unit. Nitrogen and phosphorus fertilizer use increased in the Ozark Plateaus study unit for the period 1965-85, but the application rates are well below the national median. Fertilizer use differed substantially among the major river basins and physiographic areas in the study unit. Livestock and poultry waste is a major source of nutrient loading in parts of the study unit. The quantity of nitrogen and phosphorus from livestock and poultry wastes differed substantially among the river basins of the study unit's sampling network. Eighty six municipal sewage-treatment plants in the study unit have effluents of 0.5 million gallons per day or more (for the years 1985-91). Statistically significant differences existed in surface-water quality that can be attributed to land use, physiography, and drainage basin size. Dissolved nitrite plus nitrate, total phosphorus, fecal coliform bacteria, and dissolved organic carbon concentrations generally were larger at sites associated with agricultural basins than at sites associated with forested basins. A large difference in dissolved nitrite plus nitrate concentrations occurred between streams draining basins with agricultural land use in the Springfield and Salem Plateaus. Streams draining both small and medium agricultural basins in the Springfield Plateau had much larger concentrations than their counterparts in the Salem Plateau. Drainage basin size was not a significant factor in affecting total phosphorus, fecal coliform bacteria, or dissolved organic carbon concentrations. Suspended-sediment concentrations generally were small and indicative of the clear water in streams in the Ozark Plateaus. A comparison of the dissolved nitrite plus nitrate, total phosphorus, and fecal coliform data collected at the fixed and synoptic sites indicates that generally the data for streams draining basins of similar physiography, land-use setting, and drainage basin size group together. Many of the variations are most likely the result of differences in percent agricultural land use between the sites being compared or are discharge related. The relation of dissolved nitrite plus nitrate, total phosphorus, and fecal coliform concentration to percent agricultural land use has a strong positive 2 Water-Quality Assessment-Nutrients, Bacteria, Organic Carbon, and Suspended Sediment in Surface Water, 1993-95 correlation, with percent agricultural land use accounting for between 42 and 60 percent of the variation in the observed concentrations.

Arkansas, Kansas, Missouri, Oklahoma↗
USGS2000

Occurrence of pesticides in five rivers of the Mississippi Embayment Study Unit, 1996-98

The occurrence and temporal distribution of more than 80 pesticides and pesticide metabolites were determined in five rivers of the Mississippi Embayment National Water-Quality Assessment study unit from February 1996 through January 1998. More than 230 samples were collected and analyzed during the 2-year study. The five rivers sampled included three rivers with small, primarily agricultural watersheds; one river with a small urban watershed in Memphis, Tennessee; and one large river with mixed land use (row-crop agriculture, pasture, forest, and urban). Pesticides, usually herbicides, were frequently detected in water samples from every river. Insecticides were frequently detected (chlorpyrifos and diazinon in all samples) only in the river that drains the urban watershed. The occurrence of pesticides in surface water varied among the agricultural watersheds as well as between the agricultural and urban watersheds. The pesticides detected in the rivers that drain the agricultural watersheds were related to the major crop types cultivated in the watershed?corn is mostly grown in the northern part of the study unit, whereas cotton and rice are mostly grown in the southern part. The occurrence of pesticides in the Yazoo River, which drains the mixed land-use watershed, was similar to pesticide occurrence in the rivers that drain smaller agricultural watersheds, although concentrations were lower in the Yazoo River. Likewise, simazine, which was detected in all urban stream samples, was also detected in all Yazoo River samples, but in lower concentrations. The aquatic-life criteria for diazinon and chlorpyrifos was exceeded in 24 of 25 and 12 of 25 urban river samples, respectively, but only once or twice in agricultural and mixed-use watershed samples. Atrazine exceeded the aquatic-life criterion in about 20 percent of the samples from each river, particularly in the spring following pesticide application.

Water-Resources Investigations Report↗