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A modular three-dimensional finite-difference fround-water flow model

This report presents a finite-difference model and its associated modular computer program. The model simulates flow in three dimensions. The report includes detailed explanations of physical and mathematical concepts on which the model is based and an explanation of how those concepts are incorporated in the modular structure of the computer program. The modular structure consists of a Main Program and a series of highly independent subroutines called 'modules.' The modules are grouped into 'packages.' Each package deals with a specific feature of the hydrologic system which is to be simulated, such as flow from rivers or flow into drains, or with a specific method of solving linear equations which describe the flow system, such as the Strongly Implicit Procedure or Slice-Successive Overrelaxation. The division of the program into modules permits the user to examine specific hydrologic features of the model independently. This also facilita development of additional capabilities because new packages can be added to the program without modifying the existing packages. The input and output systems of the computer program are also designed to permit maximum flexibility. Ground-water flow within the aquifer is simulated using a block-centered finite-difference approach. Layers can be simulated as confined, unconfined, or a combination of confined and unconfined. Flow associated with external stresses, such as wells, areal recharge, evapotranspiration, drains, and streams, can also be simulated. The finite-difference equations can be solved using either the Strongly Implicit Procedure or Slice-Successive Overrelaxation. The program is written in FORTRAN 77 and will run without modification on most computers that have a FORTRAN 77 compiler. For each program ,module, this report includes a narrative description, a flow chart, a list of variables, and a module listing.

Techniques of Water-Resources Investigations↗

The search for reliable aqueous solubility (Sw) and octanol-water partition coefficient (Kow) data for hydrophobic organic compounds; DDT and DDE as a case study

The accurate determination of an organic contaminant’s physico-chemical properties is essential for predicting its environmental impact and fate. Approximately 700 publications (1944–2001) were reviewed and all known aqueous solubilities (S w ) and octanol-water partition coefficients (K ow ) for the organochlorine pesticide, DDT, and its persistent metabolite, DDE were compiled and examined. Two problems are evident with the available database: 1) egregious errors in reporting data and references, and 2) poor data quality and/or inadequate documentation of procedures. The published literature (particularly the collative literature such as compilation articles and handbooks) is characterized by a preponderance of unnecessary data duplication. Numerous data and citation errors are also present in the literature. The percentage of original S w and K ow data in compilations has decreased with time, and in the most recent publications (1994–97) it composes only 6–26 percent of the reported data. The variability of original DDT/DDE S w and K ow data spans 2–4 orders of magnitude, and there is little indication that the uncertainty in these properties has declined over the last 5 decades. A criteria-based evaluation of DDT/DDE S w and K ow data sources shows that 95–100 percent of the database literature is of poor or unevaluatable quality. The accuracy and reliability of the vast majority of the data are unknown due to inadequate documentation of the methods of determination used by the authors. [For example, estimates of precision have been reported for only 20 percent of experimental S w data and 10 percent of experimental K ow data.] Computational methods for estimating these parameters have been increasingly substituted for direct or indirect experimental determination despite the fact that the data used for model development and validation may be of unknown reliability. Because of the prevalence of errors, the lack of methodological documentation, and unsatisfactory data quality, the reliability of the DDT/ DDE S w and K ow database is questionable. The nature and extent of the errors documented in this study are probably indicative of a more general problem in the literature of hydrophobic organic compounds. Under these circumstances, estimation of critical environmental parameters on the basis of S w and K ow (for example, bioconcentration factors, equilibrium partition coefficients) is inadvisable because it will likely lead to incorrect environmental risk assessments. The current state of the database indicates that much greater efforts are needed to: 1) halt the proliferation of erroneous data and references, 2) initiate a coordinated program to develop improved methods of property determination, 3) establish and maintain consistent reporting requirements for physico-chemical property data, and 4) create a mechanism for archiving reliable data for widespread use in the scientific/regulatory community.

Water-Resources Investigations Report↗

Hydrogeology and ground-water quality of the northern part of the Town of Oyster Bay, Nassau County, New York, in 1980

This report presents geohydrologic and water quality data from the northern part of the Town of Oyster Bay, in the north-shore area of Long Island. The groundwater reservoir underlying the area consists of clay, silt, sand, and gravel layers that form six geohydrologic units; from bottom to top: the Lloyd aquifer, Raritan clay, Magothy aquifer, Port Washington aquifer, Port Washington confining unit, and the upper glacial aquifer. Crystalline bedrock underlies the Lloyd aquifer and forms the base of the groundwater system. The regional drought of 1962-67 caused groundwater levels to decline as much as 16 feet, but the water table altitude in 1980 equaled or exceeded predrought levels. Water levels measured in wells screened in the lower part of the Magothy aquifer and in the Lloyd aquifer throughout much of the area are still below those measured before the drought but are recovering. Groundwater in some areas contains nitrates, volatile organic compounds, and chloride in concentrations that exceed New York State drinking-water standards. Contamination is limited largely to the upper glacial aquifer and upper part of the Magothy aquifer. Saltwater has been reported in some wells along the shore but probably represents a natural condition rather than saltwater encroachment due to excessive pumping. (Author 's abstract)

Water-Resources Investigations Report↗

Numerical simulation of streamflow distribution, sediment transport, and sediment deposition along Long Beach Creek in Northeast Missouri

This report presents the results of a study conducted by the U.S. Geological Survey in cooperation with the Missouri Department of Conservation to describe the hydrology, sediment transport, and sediment deposition along a selected reach of Long Branch Creek in Macon County, Missouri. The study was designed to investigate spatial and temporal characteristics of sediment deposition in a remnant forested riparian area and compare these factors by magnitude of discharge events both within and outside the measured range of flood magnitudes. The two-dimensional finite-element numerical models RMA2-WES and SED2D-WES were used in conjunction with measured data to simulate streamflow and sediment transport/deposition characteristics during 2-, 5-, 10-, and 25-year recurrence interval floods. Spatial analysis of simulated sediment deposition results indicated that mean deposition in oxbows and secondary channels exceeded that of the remaining floodplain areas during the 2-, 5-, 10-, and 25-year recurrence interval floods. The simulated mass deposition per area for oxbows and secondary channels was 1.1 to 1.4 centimeters per square meter compared with 0.1 to 0.60 centimeters per square meter for the remaining floodplain. The temporal variability of total incremental floodplain deposition during a flood was found to be strongly tied to sediment inflow concentrations. Most floodplain deposition, therefore, occurred at the beginning of the streamflow events and corresponded to peaks in sediment discharge. Simulated total sediment deposition in oxbows and secondary channels increased in the 2-year through 10-year floods and decreased in the 25- year flood while remaining floodplain deposition was highest for the 25-year flood. Despite increases in sediment inflows from the 2-year through 25-year floods, the retention ratio of sediments (the ratio of floodplain deposition to inflow load) was greatest for the 5-year flood and least for the 25-year flood. The decrease in retention ratio at greater flows is likely the result of higher velocities on the floodplain, resulting in higher bed shear stress, greater suspension time of deposited material, and greater sediment transport through the system. Simulated sediment deposition was most sensitive to sediment inflow concentrations and modification of floodplain roughness—factors that can be controlled through management practices. The increase in floodplain sediment deposition resulting from a simulated increase in vegetation density (increase in floodplain roughness from a Manning's n of 0.11 to 0.12) was 142,000 kilograms, or 6.5 percent for a 10-year recurrence interval flood. This increase was comparable to total oxbow and secondary channel deposition mass in the simulations, but would result in a mean increase in floodplain deposition thickness of only 0.025 centimeter. The hydrodynamic model results show the importance of the secondary channels and meander cutoff channels in this system because these areas quickly bring floodwaters and sediment to areas not close to the main channel. The meander cutoff channels in the simulation also effectively decrease flow and velocities in some main channel sections thereby affecting sediment deposition in the vicinity of these features.

Missouri↗

Characterization of geomorphic units in the alluvial valleys and channels of Gulf Coastal Plain rivers in Texas, with examples from the Brazos, Sabine, and Trinity Rivers, 2010

The U.S. Geological Survey, in cooperation with the Texas Water Development Board, described and characterized examples of geomorphic units within the channels and alluvial valleys of Texas Gulf Coastal Plain rivers using a geomorphic unit classification scale that differentiates geomorphic units on the basis of their location either outside or inside the river channel. The geomorphic properties of a river system determine the distribution and type of potential habitat both within and adjacent to the channel. This report characterizes the geomorphic units contained in the river channels and alluvial valleys of Texas Gulf Coastal Plain rivers in the context of the River Styles framework. This report is intended to help Texas Instream Flow Program practitioners, river managers, ecologists and biologists, and others interested in the geomorphology and the physical processes of the rivers of the Texas Gulf Coastal Plain (1) gain insights into how geomorphic units develop and adjust spatially and temporally, and (2) be able to recognize common geomorphic units from the examples cataloged in this report. Recent aerial imagery (high-resolution digital orthoimagery) collected in 2008 and 2009 were inspected by using geographic information system software to identify representative examples of the types of geomorphic units that occurred in the study area. Geomorphic units outside the channels of Texas Gulf Coastal Plain rivers are called \"valley geomorphic units\" in this report. Valley geomorphic units for the Texas Gulf Coastal Plain rivers described in this report are terraces, flood plains, crevasses and crevasse splays, flood-plain depressions, tie channels, tributaries, paleochannels, anabranches, distributaries, natural levees, neck cutoffs, oxbow lakes, and constructed channels. Channel geomorphic units occur in the river channel and are subject to frequent stresses associated with flowing water and sediment transport; they adjust (change) relatively quickly in response to short-term variations in flow. Channel geomorphic units described in this report are channel banks, benches and ledges, bank failures, point bars, cross-bar channels, channel bars, exposed bedrock, pools, runs, and crossovers.

Texas↗

Water quality of the Ogallala Formation, central High Plains aquifer within the North Plains Groundwater Conservation District, Texas Panhandle, 2012-13

In cooperation with the North Plains Groundwater Conservation District (NPGCD), the U.S. Geological Survey collected and analyzed water-quality samples at 30 groundwater monitor wells in the NPGCD in the Texas Panhandle. All of the wells were completed in the Ogallala Formation of the central High Plains aquifer. Samples from each well were collected during February–March 2012 and in March 2013. Depth to groundwater in feet below land surface was measured at each well before sampling to determine the water-quality sampling depths. Water-quality samples were analyzed for physical properties, major ions, nutrients, and trace metals, and 6 of the 30 samples were analyzed for pesticides. There was a strong relation between specific conductance and dissolved solids as evidenced by a coefficient of determination ( R 2 ) value of 0.98. The dissolved-solids concentration in water from five wells exceeded the secondary drinking-water standard of 500 milligrams per liter set by the U.S. Environmental Protection Agency. Water from 3 of these 5 wells was near the north central part of the NPGCD. Nitrate values exceeded the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter in 2 of the 30 wells. A sodium-adsorption ratio of 23.4 was measured in the sample collected from well Da-3589 in Dallam County, with the next largest sodium-adsorption ratio measured in the sample collected from well Da-3588 (12.5), also in Dallum County. The sodium-adsorption ratios measured in all other samples were less than 10. The groundwater was generally a mixed cation-bicarbonate plus carbonate type. Twenty-three trace elements were analyzed, and no concentrations exceeded the secondary drinking-water standard or maximum contaminant level set by the U.S. Environmental Protection Agency for water supplies. In 2012, 6 of the 30 wells were sampled for commonly used pesticides. Atrazine and its degradate 2-Chloro-4-isopropylamino-6-amino-s-triazine were detected in two samples. Tebuthiuron was detected in one sample at a detection level below the reporting level but above the long-term method detection level. There were no detections of the glyphosate, aminomethylphosphonic acid (AMPA), or glufosinate.

Texas↗

Continuous monitoring and Bayesian estimation of nutrient and sediment loads from Illinois watersheds, for water years 2016–2020

The State of Illinois is one of the leading contributors of nitrogen, phosphorus, and suspended sediment to the Mississippi River and the Gulf of Mexico. During water years 2016–20, the U.S. Geological Survey, in cooperation with the Illinois Environmental Protection Agency, operated continuous monitoring stations on eight major rivers in Illinois to better quantify nutrient and sediment loadings from the State of Illinois to the Mississippi River. This report estimates nitrate, phosphorus, and suspended-sediment loadings over that period, which can provide a benchmark against which to assess future changes in loading. In addition, this report develops a new method for incorporating the uncertainty created by gaps in continuous datasets based on Bayesian machine learning. Data gaps are a common problem in continuous monitoring, and gap filling is necessary to quantify loadings and the uncertainty in loadings, which is essential if these results are to provide a benchmark for future studies. The uncertainty estimates may also be useful in an operational context, and this report provides examples of how uncertainty can be used in monitoring-network design and potentially reducing monitoring costs.

Illinois↗

Effects of sanitary sewers on ground-water levels and streams in Nassau and Suffolk Counties, New York; part 3: Development and application of southern Nassau County model

By 1990, sanitary sewers in Nassau County Sewage Disposal Districts 2 and 3 and Suffolk County Southwest Sewer District will discharge to the ocean 140 cu ft of water per second that would otherwise be returned to the groundwater system through septic tanks and similar systems. To evaluate the effects of this loss on groundwater levels and streamflow, the U.S. Geological Survey developed a groundwater flow model that couples a fine-scale subregional model to a regional model of a larger scale. The regional model generates flux boundary conditions for the subregional model, and the subregional model provides detail in the area of concern. Results indicate that the water table will decline by as much as 90% from conditions in the early 1970's. This report is one of a three-part series describing the predicted hydrologic effects of sewers in southern Nassau and southwestern Suffolk Counties.

New York↗

Hydrogeology and ground-water quality of Lannon-Sussex area, northeastern Waukesha County, Wisconsin

The Silurian dolomite aquifer in the Lannon-Sussex area of southeastern Wisconsin is overlain by glacial deposits, but is within 8 ft of the land surface over 15% of the study area. The proximity of the dolomite aquifer to the land surface makes it susceptible to contamination from man 's activities. Water from the aquifer was analyzed and several characteristics were monitored in a 30-sq-mi area of Waukesha County, including: water temperature, calcium, magnesium, potassium, strontium, alkalinity, chlorides, fluorides, sulfates, nitrites, nitrates, nitrogen, iron, manganese, hardness, and pH. The water is hard, commonly having a hardness of more than 350 mg/L as CaCO 3 , and high in iron, commonly containing more than 0.3 mg/L. However, nutrient concentrations are not high; nitrogen, greater than 8 mg/L; phosphorus, none detected; and potassium, greater than 4 mg/L. The chloride content of the water averages more than 50 mg/L indicating contamination probably from septic systems. The water quality varies over a time. High concentrations of chloride and, occasionally, of bacteria correlate with periods of groundwater recharge over a period of 17 months. Chloride concentrations were highest in water from wells where housing density is high. An attempt was made to relate water quality changes with depth to beds of cherty dolomite that are identified in geologic logs; it was postulated that these zones might be confining beds. Although the beds appear to extend over the area, no evidence was found that they are confining beds, other than reports of a few artesian wells. Water quality, indicated by chloride content, showed no significant relation to well bottom altitudes, casing bottom altitude, or well depth.

Wisconsin↗

Water-quality assessment of the Potomac River Basin: Analysis of available pesticide data, 1972-1990

A study of available data for the period from 1972 to 1990 was conducted to characterize the occurrence and distribution of pesticides in surface water, bottom material, ground water, and fish tissue in the Potomac River Basin. The study was conducted by the Potomac River study unit of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. Existing data coverage was evaluated to guide future data-collection activities. Data from computer data bases and from published and unpublished reports were obtained from local, State, and Federal agencies in the four Potomac River Basin states and the District of Columbia. Data are available for all environmental media, but geographic and temporal coverage are limited. Clusters of data occur in the north-central parts of the basin, with numerous samples at discrete locations in the Shenandoah and Monocacy River Basins, along the mainstem Potomac River, in the Washington, D.C., area, and in streams along the Potomac Estuary. Much of the available surface-water and bottom-material data are from the earlier years of the period of interest, the ground-water data are from the middle years, and the fish-tissue data are distributed over much of the period. Overall, temporal coverage is not sufficient for analysis of trends. Comparisons between different sample media are possible in some areas of the Potomac River Basin, particularly in the northern end of the Great Valley. Residual concentrations of some pesticides have been found in surface water, bottom material, ground water, and fish tissue. Samples have been analyzed for a total of at least 69 pesticides and related compounds in surface water, bottom material, ground water, and fish tissue. Most concentrations of the pesticides analyzed during the period from 1972 to 1990 were less than or equal to reporting limits. For surface-water samples, 13 out of 41 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported in surface water included 2,4-D, atrazine, aldrin, chlordane, DDT and related compounds, dieldrin, endrin, lindane, prometone, prometryne, and simazine. For bottom material samples, 19 of 31 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported in bottom material included aldrin, chlordane, DDT and related compounds, diazinon, dieldrin, endosulfan, endrin, ethion, heptachlor, heptachlor epoxide, lindane, parathion, and toxaphene. In ground-water samples, 14 of 39 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported in ground water included 2,4-D, atrazine, chlordane, cyanazine, DDT and related compounds, diazinon, dieldrin, endosulfan, endrin, heptachlor epoxide, malathion, methyl parathion, simazine. For fish-tissue samples, 30 of the 37 pesticides and related compounds analyzed had concentrations equal to or greater than the reporting limits. Compounds reported included aldrin, chlorpyrifos, dacthal, dieldrin, endrin, HCB, heptachlor, heptachlor epoxide, methoxychlor, mirex, PCA, toxaphene, and those compounds related to chlordane, DDT, and lindane.

Maryland, Pennsylvania, Virginia, West Virginia↗

Management of conservation reserve program grasslands to meet wildlife habitat objectives

Numerous studies document environmental and social benefits of the Conservation Reserve Program (CRP). This report offers a synopsis of findings regarding effects of establishing CRP conservation practices on the quality and distribution of wildlife habitat in agricultural landscapes. On individual farms, year-round provision of wildlife habitat by the CRP may appear relatively insignificant. However, considered from multi-farm to National scales, such improvements in habitat and wildlife response have proven to be extensive and profound. Because CRP acres historically have been dominated by plantings of introduced and native grasses, this report focuses on issues pertaining to wildlife response to grass-dominated conservation practices. While the majority of CRP acres have been concentrated largely in the Great Plains and Corn Belt regions, 47 states (and Puerto Rico) have participated, resulting in measurable environmental benefits throughout the United States. Numerous investigations of habitat use by a wide range of wildlife species reveal that periodic management of CRP lands can enhance benefits through and beyond a typical 10 year general CRP contract. Over its 28-year existence, the CRP has evolved into an effective integration of conservation and agricultural policies targeting fragile and environmentally-valuable lands. Landowners with fields enrolled in the CRP often are the first to observe improvement in the landscape, greater numbers and kinds of wildlife, cleaner water and air, less erosion, and they have the satisfaction of seeing fragile lands serve better purposes. There is persistent concern that improvement seen in wildlife habitat and other environmental profits delivered by the CRP are ephemeral and last only as long as funding supports the existence of the program and its vegetative cover is properly managed. An involved American population will continue to expect governmental policies to enhance long-term protection of natural resources and public health. Recent investigations furnish evidence that the collective economic value of environmental benefits delivered by the CRP likely exceed program costs. The mounting significance placed on environmentally-responsible land management is based in part on public recognition that social, aesthetic, and recreational values enhance the traditional uses of agricultural land.

Scientific Investigations Report↗

Methods Used to Assess the Susceptibility to Contamination of Transient, Non-Community Public Ground-Water Supplies in Indiana

The Safe Water Drinking Act of 1974 as amended in 1996 gave each State the responsibility of developing a Source-Water Assessment Plan (SWAP) that is designed to protect public-water supplies from contamination. Each SWAP must include three elements: (1) a delineation of the source-water protection area, (2) an inventory of potential sources of contaminants within the area, and (3) a determination of the susceptibility of the public-water supply to contamination from the inventoried sources. The Indiana Department of Environmental Management (IDEM) was responsible for preparing a SWAP for all public-water supplies in Indiana, including about 2,400 small public ground-water supplies that are designated transient, non-community (TNC) supplies. In cooperation with IDEM, the U.S. Geological Survey compiled information on conditions near the TNC supplies and helped IDEM complete source-water assessments for each TNC supply. The delineation of a source-water protection area (called the assessment area) for each TNC ground-water supply was defined by IDEM as a circular area enclosed by a 300-foot radius centered at the TNC supply well. Contaminants of concern (COCs) were defined by IDEM as any of the 90 contaminants for which the U.S. Environmental Protection Agency has established primary drinking-water standards. Two of these, nitrate as nitrogen and total coliform bacteria, are Indiana State-regulated contaminants for TNC water supplies. IDEM representatives identified potential point and nonpoint sources of COCs within the assessment area, and computer database retrievals were used to identify potential point sources of COCs in the area outside the assessment area. Two types of methods-subjective and subjective hybrid-were used in the SWAP to determine susceptibility to contamination. Subjective methods involve decisions based upon professional judgment, prior experience, and (or) the application of a fundamental understanding of processes without the collection and analysis of data for a specific condition. Subjective hybrid methods combine subjective methods with quantitative hydrologic analyses. The subjective methods included an inventory of potential sources and associated contaminants, and a qualitative description of the inherent susceptibility of the area around the TNC supply. The description relies on a classification of the hydrogeologic and geomorphic characteristics of the general area around the TNC supply in terms of its surficial geology, regional aquifer system, the occurrence of fine- and coarse-grained geologic materials above the screen of the TNC well, and the potential for infiltration of contaminants. The subjective hybrid method combined the results of a logistic regression analysis with a subjective analysis of susceptibility and a subjective set of definitions that classify the thickness of fine-grained geologic materials above the screen of a TNC well in terms of impedance to vertical flow. The logistic regression determined the probability of elevated concentrations of nitrate as nitrogen (greater than or equal to 3 milligrams per liter) in ground water associated with specific thicknesses of fine-grained geologic materials above the screen of a TNC well. In this report, fine-grained geologic materials are referred to as a geologic barrier that generally impedes vertical flow through an aquifer. A geologic barrier was defined to be thin for fine-grained materials between 0 and 45 feet thick, moderate for materials between 45 and 75 feet thick, and thick if the fine-grained materials were greater than 75 feet thick. A flow chart was used to determine the susceptibility rating for each TNC supply. The flow chart indicated a susceptibility rating using (1) concentrations of nitrate as nitrogen and total coliform bacteria reported from routine compliance monitoring of the TNC supply, (2) the presence or absence of potential sources of regulated contaminants (nitrate as nitrogen and coliform bac

Indiana↗

Inventory of ground-water resources in the Kabul Basin, Afghanistan

In 2004, the U.S. Geological Survey began working with engineers at the Afghanistan Geological Survey to provide hydrologic training and equipment and to apply these tools to build an inventory of water wells in the Kabul Basin of Afghanistan. An inventory of 148 wells now includes information on well location, depth, and access. Water-level and water-quality measurements have been made at most of these wells. A water-level elevation map has been constructed, and general directions of ground-water flow have been defined. Ground-water flow in the Kabul Basin is primarily through saturated alluvium and other basin-fill sediments. The water-table surface generally mirrors topography, and ground water generally flows in the directions of surface-water discharge. The quality of ground water in the Kabul Basin varies widely. In some areas, ground-water quality is excellent, with low concentrations of dissolved solids and no problematic constituents. In other areas, however, high concentrations of dissolved solids and the presence of some constituents at concentrations deemed harmful to humans and crops render untreated ground water marginal or unsuitable for public supply and/or agricultural use. Of particular concern are elevated concentrations of nitrate, boron, and dissolved solids, and an indication of fecal pollution in some parts of the basin. As Afghanistan emerges from years of conflict, as institutional capacities rejuvenate and grow, and as the need for wise water-management decisions continues, adequate data and a fuller understanding of the ground-water resource in the Kabul Basin will be imperative. The work described in this report represents only a modest beginning in what will be a long-term data-collection and interpretive effort.

Scientific Investigations Report↗

Variations in Community Exposure and Sensitivity to Tsunami Hazards on the Open-Ocean and Strait of Juan de Fuca Coasts of Washington

Evidence of past events and modeling of potential future events suggest that tsunamis are significant threats to communities on the open-ocean and Strait of Juan de Fuca coasts of Washington. Although potential tsunami-inundation zones from a Cascadia Subduction Zone (CSZ) earthquake have been delineated, the amount and type of human development in tsunami-prone areas have not been documented. A vulnerability assessment using geographic-information-system tools was conducted to document variations in developed land, human populations, economic assets, and critical facilities relative to CSZ-related tsunami-inundation zones among communities on the open-ocean and Strait of Juan de Fuca coasts of Washington (including Clallam, Jefferson, Grays Harbor, and Pacific Counties). The tsunami-inundation zone in these counties contains 42,972 residents (24 percent of the total study-area population), 24,934 employees (33 percent of the total labor force), and 17,029 daily visitors to coastal Washington State Parks. The tsunami-inundation zone also contains 2,908 businesses that generate $4.6 billion in annual sales volume (31 and 40 percent of study-area totals, respectively) and tax parcels with a combined total value of $4.5 billion (25 percent of the study-area total). Although occupancy values are not known for each site, the tsunami-inundation zone also contains numerous dependent-population facilities (for example, schools and child-day-care centers), public venues (for example, religious organizations), and critical facilities (for example, police stations and public-work facilities). Racial diversity of residents in tsunami-prone areas is low?89 percent of residents are White and 8 percent are American Indian or Alaska Native. Nineteen percent of the residents in the tsunami-inundation zone are over 65 years in age, 30 percent of the residents live on unincorporated county lands, and 35 percent of the households are renter occupied. Employees in the tsunami-inundation zone are largely in businesses related to health care and social assistance, accommodation and food services, and retail trade, reflecting businesses that cater to a growing retiree and tourist population. Community vulnerability, described here by exposure (the amount of assets in tsunami-prone areas) and sensitivity (the relative percentage of assets in tsunami-prone areas) varies among 13 incorporated cities, 7 Indian reservations, and 4 counties. The City of Aberdeen has the highest relative community exposure to tsunamis, whereas the City of Long Beach has the highest relative community sensitivity. Levels of community exposure and sensitivity to tsunamis are found to be related to the amount and percentage, respectively, of a community?s land that is in a tsunami-inundation zone. This report will further the dialogue on societal risk to tsunami hazards in Washington and help risk managers to determine where additional risk-reduction strategies may be needed.

Scientific Investigations Report↗

Methods for Estimating Water Withdrawals for Mining in the United States, 2005

The mining water-use category includes groundwater and surface water that is withdrawn and used for nonfuels and fuels mining. Nonfuels mining includes the extraction of ores, stone, sand, and gravel. Fuels mining includes the extraction of coal, petroleum, and natural gas. Water is used for mineral extraction, quarrying, milling, and other operations directly associated with mining activities. For petroleum and natural gas extraction, water often is injected for secondary oil or gas recovery. Estimates of water withdrawals for mining are needed for water planning and management. This report documents methods used to estimate withdrawals of fresh and saline groundwater and surface water for mining during 2005 for each county and county equivalent in the United States, Puerto Rico, and the U.S. Virgin Islands. Fresh and saline groundwater and surface-water withdrawals during 2005 for nonfuels- and coal-mining operations in each county or county equivalent in the United States, Puerto Rico, and the U.S. Virgin Islands were estimated. Fresh and saline groundwater withdrawals for oil and gas operations in counties of six states also were estimated. Water withdrawals for nonfuels and coal mining were estimated by using mine-production data and water-use coefficients. Production data for nonfuels mining included the mine location and weight (in metric tons) of crude ore, rock, or mineral produced at each mine in the United States, Puerto Rico, and the U.S. Virgin Islands during 2004. Production data for coal mining included the weight, in metric tons, of coal produced in each county or county equivalent during 2004. Water-use coefficients for mined commodities were compiled from various sources including published reports and written communications from U.S. Geological Survey National Water-use Information Program (NWUIP) personnel in several states. Water withdrawals for oil and gas extraction were estimated for six States including California, Colorado, Louisiana, New Mexico, Texas, and Wyoming, by using data from State agencies that regulate oil and gas extraction. Total water withdrawals for mining in a county were estimated by summing estimated water withdrawals for nonfuels mining, coal mining, and oil and gas extraction. The results of this study were distributed to NWUIP personnel in each State during 2007. NWUIP personnel were required to submit estimated withdrawals for numerous categories of use in their States to a national compilation team for inclusion in a national report describing water use in the United States during 2005. NWUIP personnel had the option of submitting the estimates determined by using the methods described in this report, a modified version of these estimates, or their own set of estimates or reported data. Estimated withdrawals resulting from the methods described in this report may not be included in the national report; therefore the estimates are not presented herein in order to avoid potential inconsistencies with the national report. Water-use coefficients for specific minerals also are not presented to avoid potential disclosure of confidential production data provided by mining operations to the U.S. Geological Survey.

Scientific Investigations Report↗

Coastal and lower Elwha River, Washington, prior to dam removal--history, status, and defining characteristics: Chapter 1 in Coastal habitats of the Elwha River, Washington--biological and physical patterns and processes prior to dam removal

Characterizing the physical and biological characteristics of the lower Elwha River, its estuary, and adjacent nearshore habitats prior to dam removal is essential to monitor changes to these areas during and following the historic dam-removal project set to begin in September 2011. Based on the size of the two hydroelectric projects and the amount of sediment that will be released, the Elwha River in Washington State will be home to the largest river restoration through dam removal attempted in the United States. Built in 1912 and 1927, respectively, the Elwha and Glines Canyon Dams have altered key physical and biological characteristics of the Elwha River. Once abundant salmon populations, consisting of all five species of Pacific salmon, are restricted to the lower 7.8 river kilometers downstream of Elwha Dam and are currently in low numbers. Dam removal will reopen access to more than 140 km of mainstem, flood plain, and tributary habitat, most of which is protected within Olympic National Park. The high capture rate of river-borne sediments by the two reservoirs has changed the geomorphology of the riverbed downstream of the dams. Mobilization and downstream transport of these accumulated reservoir sediments during and following dam removal will significantly change downstream river reaches, the estuary complex, and the nearshore environment. To introduce the more detailed studies that follow in this report, we summarize many of the key aspects of the Elwha River ecosystem including a regional and historical context for this unprecedented project.

Washington↗

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of pesticides in water by graphitized carbon-based solid-phase extraction and high-performance liquid chromatography/mass spectrometry

In 1996, the U.S. Geological Survey National Water Quality Laboratory (NWQL) developed and implemented a graphitized carbon-based solid-phase extraction and high-performance liquid chromatographic analytical method to determine polar pesticide concentrations in surface- and ground-water samples. Subsequently, the NWQL developed a complementary analysis that uses high-performance liquid chromatography/mass spectrometry to detect, identify, and quantify polar pesticides and pesticide metabolites in filtered water at concentrations as low as 10 nanograms per liter. This new method was designed to improve sensitivity and selectivity over the prior method, and to reduce known interferences from natural organic matter. In this new method, pesticides are extracted from filtered water samples by useing a 0.5-gram graphitized carbon-based solid-phase extraction cartridge, eluted from the cartridge, and concentrations determined by using high-performance liquid chromatography with electrospray ionization-mass spectrometry. The upper concentration limit is 1.000 microgram per liter ( μ g /L) for most compounds. Single-operator method detection limits in organic-free water samples fortified with pesticides at a concentration of 0.025 μg/L ranged from 0.0019 to 0.022 μ g /L for all compounds in the method. The grand mean (mean of mean recoveries for individual compounds) recoveries in organic-free water samples ranged from 72 to 89 percent, fortified with pesticides at three concentrations between 0.025 and 0.5 μ g /L. Grand mean recoveries in ground- and surface-water samples ranged from 46 to 119 percent, also fortified with pesticides at three concentrations between 0.025 and 0.5 μ g /L. Long-term recoveries from reagent water spikes were used to demonstrate that 38 of 65 compounds can be reported without qualification of the quantitative result across the analytical range of the method. The remaining 27 are reported with qualified estimates of concentration because of greater variability of recovery.

Water-Resources Investigations Report↗

Chemical analyses of surface water in Illinois, 1958–74—Volume I, Des Plaines River basin and Lake Michigan

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency and its predecessor, the Stream Pollution Control Bureau of the Illinois Department of Public Health. The results for the period 1958 to 1974 are presented in tabular form and the history of sampling and analytical methods are summarized. Stream discharge data from records of the U.S. Geological Survey are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. The report is contained in three volumes. This volume (Volume I) includes Des Plaines River basin and Lake Michigan. (See also W78-10035 and W78-10036).

Illinois↗