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At least 793 records · Page 44Linked to original sources
USGS1982

Ground-water quality in east-central Idaho valleys

From May through November 1978, water quality, geologic, and hydrologic data were collected for 108 wells in the Lemhi, Pahsimeroi, Salman River (Stanley to Salmon), Big Lost River, and Little Lost River valleys in east-central Idaho. Data were assembled to define, on a reconnaissance level, water-quality conditions in major aquifers and to develop an understanding of factors that affected conditions in 1978 and could affect future ground-water quality. Water-quality characteristics determined include specific conductance, pH, water temperature, major dissolved cations, major dissolved anions, and coliform bacteria. Concentrations of hardness, nitrite plus nitrate, coliform bacteria, dissolved solids, sulfate, chloride, fluoride , iron, calcium, magnesium, sodium, potassium or bicarbonate exceed public drinking water regulation limits or were anomalously high in some water samples. Highly mineralized ground water probably is due to the natural composition of the aquifers and not to surface contamination. Concentrations of coliform bacteria that exceed public drinking water limits and anomalously high dissolved nitrite-plus-nitrite concentrations are from 15- to 20-year old irrigation wells in heavily irrigated or more densely populated areas of the valleys. Ground-water quality and quantity in most of the study area are sufficient to meet current (1978) population and economic demands. Ground water in all valleys is characterized by significant concentrations of calcium, magnesium, and bicarbonate plus carbonate ions. Variations in the general trend of ground-water composition (especially in the Lemhi Valley) probably are most directly related to variability in aquifer lithology and proximity of sampling site to source of recharge. (USGS)

Open-File Report↗
USGS1974

Analyses and economic potential of monazite in Liberia

Eleven monazite samples from Liberia, including seven from beach sands, were analyzed by the X-ray fluorescence method. The monazite samples, containing only one-half percent impurities, were obtained by use of a hot Clerici-solution procedure for purification which was devised by the author. The percentage of the rare-earth elements in Liberian monazite concentrates does not differ greatly from that of monazite sands elsewhere in the world. The average of the 11 samples shows less praseodymium and neodymium than Russian and American monazites, but more cerium. Liberian coastal sands apparently contain sufficient reserves of monazite (and other heavy minerals of commerce) to encourage mining. A feasibility study of production and marketing of monazite from Liberian beach sands is recommended.

Journal of Research of the U.S. Geological Survey↗
USGS2023

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin↗
USGS2012

Genesis of the Touissit-Bou Beker Mississippi Valley-type district (Morocco-Algeria) and its relation to the Africa-Europe collision

The Mississippi Valley-type deposits of the Touissit-Bou Beker district are hosted by a 25 m thick sequence of diagenetically and hydrothermally dolomitized carbonate platform rocks of Aalenian-Bajocian age. The sulfide mineralization consists principally of galena and sphalerite and occurs as open-space fillings of voids and moderate to massive replacement of the medium- to coarse-grained host dolostone. Five types of dolomite have been distinguished, two of which (D 1 and D 2 ) are of replacement origin, whereas HD 1 , HD 2 , HD 3 occurring as open-space filling are of hydrothermal affiliation. Main ore controls include stratigraphy and lithology, carbonate dissolution, paleogeography, faults or faulted rocks, and availability of organic matter. Fluid inclusion data, along with Na-Cl-Br leachate, indicate that the ore-forming fluids correspond to evolved NaCl-CaCl 2 -KCl-MgCl 2 basin-derived hot (100° ± 20°C) saline brines (>20 wt % NaCl equiv) that acquired their high salinities and Ca/Na ratios through evaporation of seawater, and subsequent dolomitization and fluid-rock interactions. Stable isotope data for replacement and hydrothermal dolomites are tightly clustered and overlapping, with δ 18 O and δ 13 C values from 20.5 to 21.2 and 0.2 to 0.7‰, respectively. Similarly, sulfides yield δ 34 S values between 11.2 and 1.9‰, whereas those corresponding to the nearby Triassic gypsum cluster yield around 14‰. Altogether, these isotopic compositions are consistent with a basinal-type fluid with reduced sulfur very likely being derived through thermochemical reduction of dissolved sulfate, resulting in metal precipitation, and carbon of mainly marine Aalenian-Bajocian carbonate origin with a minor biogenic component. 87 Sr/ 86 Sr values of replacement dolostone are similar to those of ore-related hydrothermal dolomites, ranging from 0.70746 to 0.70833 and from 0.70769 to 0.70828, respectively, and are different from those of the Visean rhyodacite (0.71849–0.72167). Lead isotope ratios ( 206 Pb/ 204 Pb = 18.319–18.390; 207 Pb/ 204 Pb = 15.620–15.680; 208 Pb/ 204 Pb = 38.452–38.650) of sulfides are consistent with Pb being derived from the Visean rhyodacite and associated volcaniclastic rocks. The intimate link between faults and mineralization suggests the strong possibility of brine flow along both ENE-trending regional-scale faults and NW-SW-trending local-scale faults. The data suggest that MVT mineralization was emplaced during the late Neogene-Quaternary (i.e., ca. 15–0 Ma), possibly as a result of subsurface gravity-driven fluid flow in response to the collision between the African and Eurasian plates.

Touissit-bou Beker District↗
USGS2009

Scientific communications: Re-Os sulfide (bornite, chalcopyrite, and pyrite) systematics of the carbonate-hosted copper deposits at ruby creek, southern brooks range, Alaska

New Re-Os data for chalcopyrite, bornite, and pyrite from the carbonate-hosted Cu deposit at Ruby Creek (Bornite), Alaska, show extremely high Re abundances (hundreds of ppb, low ppm) and contain essentially no common Os. The Re-Os data provide the first absolute ages of ore formation for the carbonate-hosted Ruby Creek Cu-(Co) deposit and demonstrate that the Re-Os systematics of pyrite, chalcopyrite, and bornite are unaffected by greenschist metamorphism. The Re-Os data show that the main phase of Cu mineralization pre dominantly occurred at 384 ?? 4.2 Ma, with an earlier phase possibly at ???400 Ma. The Re-Os data are consistent with the observed paragenetic sequence and coincide with zircon U-Pb ages from igneous rocks within the Ambler metallogenic belt, some of which are spatially and genetically associated with regional volcanogenic massive sulfide deposits. The latter may suggest a temporal link between regional magmatism and hydrothermal mineralization in the Ambler district. The utility of bornite and chalcopyrite, in addition to pyrite, contributes to a new understanding of Re-Os geochronology and permits a refinement of the genetic model for the Ruby Creek deposit. ?? 2009 Society of Economices Geologists, Inc.

Economic Geology↗
USGS1951

Ilmenite, magnetite, hematite, and copper in lavas of the Keweenawan series

The opaque minerals in ten lava flows of the Keweenawan series of Michigan were studied microscopically by the writer. The basaltic lavas , which range in thickness from 100 to 1,400 feet, contain ilmenite , magnetite , hematite , intergrowths of magnetite - ilmenite and ilmenite - hematite , copper sulfides, native copper , and pyrite. Variations of opaque iron minerals with thickness of flow are slight, but native copper predominates in the thinner flows and copper sulfides in the thickest. Pyrite occurs only in the thickest flow. Two groups of opaque minerals and their alteration products are distinguished. The earlier group includes magnetite , ilmenite , magnetite - ilmenite and ilmenite - hematite intergrowths, copper sulfides, and native copper . The later group includes hematite , native copper , chalcocite, pyrite, chlorite, and sphene. The second-generation minerals formed by the action of volatiles escaping from the lavas . The ratio of Ti to total Fe correlates with the degree of differentiation of the lavas , but the ratio of ferric to ferrous iron does not. The latter ratio was controlled primarily by the action of escaping volatiles.

Economic Geology↗
USGS2024

Apatite and monazite geochemistry record magmatic and metasomatic processes in rare earth element mineralization at Mountain Pass, California

The largest rare earth element (REE) deposit in the United States is a carbonatite intrusion at Mountain Pass in the Mojave Desert, California. Despite a clear spatiotemporal association of alkaline silicate and carbonatite intrusions at Mountain Pass, a genetic model of their mutual formation has not been resolved. The Mountain Pass carbonatite has long been upheld as an example of a primary magmatic body, but recent work has suggested it could be fluid-derived. This study investigates the geochemistry of apatite and monazite grains from the alkaline silicate and carbonatite stocks and dikes of the Mountain Pass district, to elucidate the magmatic history of the intrusive suite and identify the role of fluids in rare earth element mineralization. Three apatite populations are identified in the alkaline silicate rocks. A primary magmatic apatite group supports intrusion of the stocks as separate pulses of magma derived from a spatially extensive metasomatized mantle source region. The second group implicates the role of a regional fluid that mobilized light rare earth elements from apatite grains. A minor group of inherited apatite cores, identified by low Sr and negative Eu anomalies, supports assimilation of crustal material in the formation of the intrusive suite. Analyses of monazite and apatite grains from the carbonatite orebody also reveal a mix of primary magmatic and metasomatic (fluid-related) minerals. Compositional similarities between primary phosphates in the carbonatite and alkaline silicate rocks support a genetic link between the intrusive suites. The presence of fluids regionally and within the carbonatite orebody indicates the Mountain Pass carbonatite should not be classified as a purely magmatic REE deposit.

Arizona, California, Nevada↗
USGS2007

Surficial sediment character of the New York-New Jersey offshore continental shelf region: A GIS compilation

Broad continental shelf regions such as the New York Bight are the product of a complex geologic history and dynamic oceanographic processes, dominated by the Holocene marine transgression (>100 m sea-level rise) following the end of the last Pleistocene ice advance ~ 20,000 years ago. The area of the U.S. Exclusive Economic Zone (U.S. EEZ) territory, extending 200 nautical miles seaward from the coast, is larger than the continental U.S. and contains submerged landforms that provide a variety of natural functions and societal benefits, such as: critical habitats for fisheries, ship navigation and homeland security, and engineering activities (i.e. oil and gas platforms, pipeline and cable routes, potential wind-energy-generation sites). Some parts of the continental margins, particularly inner-continental shelf regions, also contain unconsolidated hard-mineral deposits such as sand and gravel that are regarded as potential aggregate resources to meet or augment needs not met by onshore deposits (Williams, 1992). The present distribution of surficial sediment off the northeastern United States is shaped from the deposits left by the last glaciation and reflects the cumulative effects of sediment erosion, transport, sorting, and deposition by storm and tidal processes during the Holocene rise in sea level. As a result, the sediments on the sea floor represent both an historical record of former conditions and a guide to possible future sedimentary environments. The U.S. Geological Survey (USGS) through the Coastal and Marine Geology Program, in cooperation with the University of Colorado and other partners, has compiled extant sediment character and textural data as well as other geologic information on the sea floor from all regions around the U.S. into the usSEABED data system (Reid and others, 2005; Buczkowski and others, 2006; Reid and others, 2006). The usSEABED system, which contains information on sediment grain size and lithology for more than 340,500 stations within the U.S. EEZ. has been developed and populated with data as part of the USGS Marine Aggregate Resources and Processes and the National Benthic Habitats projects in order to provide the base-line data needed to update the current maps of offshore surficial geologic character and sediment distribution. The maps are also used to characterize benthic sea floor environments important for marine ecosystems. U.S. Geological Survey, Data Series 118 (Reid and others, 2005), of the usSEABED data release series, represents the combined efforts of the USGS and several other government agencies to provide a unified resource for accessing and preserving records of U.S. east coast sea floor geologic information and sediment texture data. For this present report, we have chosen to focus on the New York-New Jersey region, an area that has been intensely studied by the USGS for many years to address many complex issues. This report illustrates the uses of the usSEABED database for GIS applications, while offering additional insight into the resources and data available from the USGS and its collaborative institutions. This report is based on data contained in U.S. Geological Survey Data Series 118 (Reid and others, 2005) and shows an assortment of example GIS products that are possible using usSEABED. All data are intended to be GIS-ready and should not require any additional cleanup, formatting, or renaming of fields in order to use the data in a Geographic Information System. This project employs the Environmental Systems Research Institute's (ESRI) ArcView™ software. Many of these maps were made as part of the ongoing USGS study to assess marine aggregate resources offshore New York and New Jersey, but these maps can serve many other purposes. The marine science community, educators, students and others are encouraged to use these data to generate GIS products for their own purposes. The objectives of the Marine Aggregate Resources and Processes project are to produce a series of new geologic maps and reports of the sea floor that will provide scientific insights into the character and geologic development of U.S. continental margins and to use these maps and information to assess the potential availability of offshore sand and gravel resources. The mapping and aggregate resource assessments are being conducted on a national scale using the usSEABED data base as described in Williams and others (2003). Potential uses for these data include: (1) defining the geological variability of the sea floor in relation to benthic habitat diversity; (2) improving our understanding of the processes that control the distribution and transport of bottom sediments and benthic habitats; (3) locating aggregate resources for beach nourishment and industrial applications; and (4) providing a detailed geospatial framework for future marine science research, monitoring, and management activities. The initial assessments are in progress for the New York Bight and Louisiana offshore areas.

New Jersey, New York↗
USGS1992

Geochemistry and origin of the Bald Knob manganese deposit, North Carolina

Geochemical and textural evidence for the submarine hydrothermal origin of the Bald Knob Mn deposit, North Carolina, is preserved in a mineralogically diverse suite of rocks that have experienced amphibolite facies metamorphism. Manganese- and Mn-Fe-rich lithologies have high Mn/Fe ratios and low concentrations of Ni, Cu, Zn, U, Th, and rare earth elements that are similar to concentrations reported from other ancient manganiferous deposits and from crusts and sediments which are forming in hydrothermally active regions of the present sea floor. Manganese- and Ca-rich carbonate minerals, a variety of Mn-rich silicates (including tephroite, the Mn humite-group minerals, spessartine, rhodonite, and pyroxmangite), and the oxides galaxite and jacobsite form fine laminations that represent different bulk compositions. No chemical or textural evidence for replacement of Mn-poor by Mn-rich minerals was found and, in some samples, the same lithologic units are repeated on the scale of a thin section, consistent with a primary sedimentary origin for the layering. Chert, which is one of the country rocks at Bald Knob, and Mn- and Ca-rich carbonate rocks represent original sedimentary protoliths. More than one detrital component may be present in the Mn-rich layers. Biogenic detritus was the probable source of at least some of the siliceous material that allowed for the formation of the Mn-rich silicates. An aluminous detrital component, which probably was derived from a continental or andesitic source, is reflected in spessartine-rich layers. Minor Mn and Co sulfide mineralization (alabandite, cattierite, cobaltite) was contemporaneous with deposition of the Mn-rich sediments. The association of the manganiferous lithologies with chert and meta-igneous rocks (amphibolite) is consistent with deposition of the sediments in a rifting environment, such as a back-arc basin, or possibly, a midocean ridge.

Economic Geology↗
USGS1990

Geochemical hosts of solubilized radionuclides in uranium mill tailings

The solubilization and subsequent resorption of radionuclides by ore components or by reaction products during the milling of uranium ores may have both economic and environmental consequences. Particle-size redistribution of radium during milling has been demonstrated by previous investigators; however, the identification of sorbing components in the tailings has received little experimental attention. In this study, uranium-bearing sandstone ore was milled, on a laboratory scale, with sulfuric acid. At regular intervals, filtrate from this suspension was placed in contact with mixtures of quartz sand and various potential sorbents which occur as gangue in uranium ores; the potential sorbents included clay minerals, iron and aluminum oxides, feldspar, fluorspar, barite, jarosite, coal, and volcanic glass. After equilibration, the quartz sand-sorbent mixtures were separated from the filtrate and radioassayed by gamma-spectrometry to determine the quantities of 238 U, 230 Th, 226 Ra, and 210 Pb sorbed, and the radon emanation coefficients. Sorption of 238 U was low in all cases, with maximal sorptions of 1–2% by the bentonite- and coal-bearing samples. 230 Th sorption also was generally less than 1%; maximal sorption here was observed in the fluorspar-bearing sample and appears to be associated with the formation of gypsum during milling. 226 Ra and 210 Pb generally showed higher sorption than the other nuclides - more than 60% of the 26 Ra solubilized from the ore was sorbed on the barite-bearing sample. The mechanism (s) for this sorption by a wide variety of substrates is not yet understood. Radon emanation coefficients of the samples ranged from about 5 to 30%, with the coal-bearing samples clearly demonstrating an emanating power higher than any of the other materials.

Hydrometallurgy↗
USGS1970

Uraninite-bearing contact metamorphic deposits, Heaths Peak, Carbon County, Wyoming

Deposits that contain uraninite and sulfide minerals at Heaths Peak, Carbon County, Wyo., display a zoned distribution of metals from the edge of granite into adjacent metamorphic rocks. The metallic minerals -- uraninite, molybdenite, pyrite, chalcopyrite, galena, pyrrhotite, and marcasite -- are concentrated on the undersides of metamorphosed roof pendants. At the Little Man mine, deposition was related to a small cupola projecting into the central part of an elongate pendant. The host rocks and the deposits are of Precambrian age.

Wyoming↗
USGS1984

Geophysical methods as mapping tools in a strata-bound gold deposit: Haile mine, South Carolina slate belt

Very low frequency electromagnetic, magnetic, and induced polarization methods. The very low frequency electromagnetic resistivity data show high resistivity zones that correlate with siliceous units known to host the gold. The magnetic data clearly identify the mafic and ultramafic dikes which cut metasediments and also fill faults that offset them. The induced polarization method allows examination of the mineralized metasediments in two dimensions by giving vertical sections of resistivity and percent frequency effect, parameters which correlate with silica and pyrite content, respectively. Lithologic units as well as ore zones can thus be mapped in this terrain which is deeply weathered and partially covered by coastal plain sediments.

Economic Geology↗
USGS1990

Geochemistry of vanadium in an epigenetic, sandstone-hosted vanadium-uranium deposit, Henry Basin, Utah

The epigenetic Tony M vanadium-uranium orebody in south-central Utah is hosted in fluvial sandstones of the Morrison Formation (Upper Jurassic). Although the deposit is mined for uranium, vanadium has a higher average abundance in the ore. Thus, the geochemistry of vanadium in the orebody was studied to characterize ore-forming processes within the inferred ground-water flow regime. Measurements of the relative amounts of V (super +3) and V (super +4) in ore minerals show that V (super +3) is more abundant. Thermodynamic calculations show that vanadium was more likely transported to the site of mineralization as V (super +4) . The ore formed as V (super +4) was reduced by hydrogen sulfide, followed by hydrolysis and precipitation of V (super +3) in oxide minerals (e.g., montroseitc or paramontroseite) or chlorite. Uranium was transported as uranyl ion (U (super +6) ), or some complex thereof, and reduced by hydrogen sulfide, forming coffinite. Detrital organic matter in the rocks served as the carbon source for sulfate-reducing bacteria. It was this bacteriogenic H 2 S that reduced the metals in the mineralization process.Possible sources for the V and U in this deposit have been identified previously. Vanadium most likely was derived from the dissolution of iron-titanium oxides, which liberated Fe as well as V. A zone of titanium-rich remnants is observed updip and up the hydrologic gradient from the deposit (M. Goldhaber and R. L. Reynolds, unpub. data). Uranium probably was derived from the overlying Brushy Basin Member of the Morrison Formation (Northrop, 1982). A preliminary age date for the deposit of 115 Ma (K. Ludwig, 1986, pers. commun.) indicates that the ore formed after deposition of the Brushy Basin Member.Previous studies have shown that the ore formed at the density-stratified interface between a basinal brine and dilute meteoric water. The mineralization processes described above occurred within the mixing zone between these two fluids. Stable isotope analyses of ore-stage dolomite show a progressively heavier carbon and oxygen isotope signature with increasing depth through an ore horizon, consistent with the two-solution interface model.

Economic Geology↗
USGS2012

Sulfur, carbon, hydrogen, and oxygen isotope geochemistry of the Idaho cobalt belt

Cobalt-copper ± gold deposits of the Idaho cobalt belt, including the deposits of the Blackbird district, have been analyzed for their sulfur, carbon, hydrogen, and oxygen isotope compositions to improve the understanding of ore formation. Previous genetic hypotheses have ranged widely, linking the ores to the sedimentary or diagenetic history of the host Mesoproterozoic sedimentary rocks, to Mesoproterozoic or Cretaceous magmatism, or to metamorphic shearing. The δ 34 S values are nearly uniform throughout the Blackbird dis- trict, with a mean value for cobaltite (CoAsS, the main cobalt mineral) of 8.0 ± 0.4‰ ( n = 19). The data suggest that (1) sulfur was derived at least partly from sedimentary sources, (2) redox reactions involving sulfur were probably unimportant for ore deposition, and (3) the sulfur was probably transported to sites of ore for- mation as H 2 S. Hydrogen and oxygen isotope compositions of the ore-forming fluid, which are calculated from analyses of biotite-rich wall rocks and tourmaline, do not uniquely identify the source of the fluid; plausible sources include formation waters, metamorphic waters, and mixtures of magmatic and isotopically heavy meteoric waters. The calculated compositions are a poor match for the modified seawaters that form vol- canogenic massive sulfide (VMS) deposits. Carbon and oxygen isotope compositions of siderite, a mineral that is widespread, although sparse, at Blackbird, suggest formation from mixtures of sedimentary organic carbon and magmatic-metamorphic carbon. The isotopic compositions of calcite in alkaline dike rocks of uncertain age are consistent with a magmatic origin. Several lines of evidence suggest that siderite postdated the emplacement of cobalt and copper, so its significance for the ore-forming event is uncertain. From the stable isotope perspective, the mineral deposits of the Idaho cobalt belt contrast with typical VMS and sedimentary exhalative deposits. They show characteristics of deposit types that form in deeper environments and could be related to metamorphic processes or magmatic processes, although the isotopic evidence for magmatic components is relatively weak.

Idaho↗
USGS1950

Geochemistry of ground water

The science of geochemistry is the study of the chemical composition of and actual or possible chemical changes in the crust of the earth. The subdivision of geochemistry concerned with ground water includes study of the nature and amounts of dissolved mineral matter in ground waters, the chemical and geologic changes that influence the kinds and amounts of substances carried in solution, and the chemical relationships between dissolved mineral matter in waters and minerals that make up the rocks in which the waters occur. As . thus defined, the field of geochemistry of ground water is very large. Although much work has been done in geochemistry in general, and in some phases of the geochemistry of ground water, the field remains to a large extent unexplored.

Economic Geology↗
USGS2004

A geologic framework for mineralization in the western Brooks Range

The Brooks Range is a 950-km-long north-vergent fold and thrust belt, which was formed during Mesozoic convergence of the continental Arctic Alaska terrane and the oceanic Angayucham terrane and was further shortened and uplifted in Tertiary time. The Arctic Alaska terrane consists of parautochthonous rocks and the Endicott Mountains and De Long Mountains subterranes. The Endicott Mountains allochthon of the western Brooks Range is the setting for many sulfide and barite occurrences, such as the supergiant Red Dog zinc-lead mine. Mineralization is sediment hosted and most commonly is present in black shale and carbonate turbidites of the Mississippian Kuna Formation. The reconstructed Kuna basin is a 200 by +600 km feature that represents the culmination of a remarkable chain of events that includes three fluvial-deltaic and two or more orogenic cycles, Middle Devonian to Mississippian episodes of extension and igneous activity, and the emergence of a seaward Lower Proterozoic landmass that may have constituted a barrier to marine circulation. Mississippian extension and related horst-and-graben architecture in the western Brooks Range is manifested in part by strong facies variability between coeval units of allochthons and structural plates. Shallow marine to possibly nonmarine arkose, platform to shelf carbonate, slope-to-basin shale, chert and carbonate turbidites, and submarine volcanic rocks are all represented in Mississippian time. The structural setting of Mississippian sedimentation, volcanism, and mineralization in the Kuna basin may be comparable to documented Devono-Mississippian extensional sags or half-grabens in the subsurface north of the Brooks Range. Climate, terrestrial ecosystems, multiple fluvial-deltaic aquifers, and structural architecture affected the liberation, movement, and redeposition of metals in ways that are incompletely understood.

Alaska↗
USGS1990

International strategic minerals inventory summary report; tin

The International Strategic Minerals Inventory tin inventory contains records for 56 major tin deposits and districts in 21 countries. These countries accounted for 98 percent of the 10 million metric tons of tin produced in the period 1934-87. Tin is a good alloying metal and is generally nontoxic, and its chief uses are as tinplate for tin cans and as solder in electronics. The 56 locations consist of 39 lode deposits and 17 placers and contain almost 7.5 million metric tons of tin in identified economic resources (R1E) and another 1.5 million metric tons of tin in other resource categories. Most of these resources are in major deposits that have been known for over a hundred years. Lode deposits account for 44 percent of the R1E and 87 percent of the resources in other categories. Placer deposits make up the remainder. Low-income and middle-income countries, including Bolivia and Brazil and countries along the Southeast Asian Tin Belt such as Malaysia, Thailand, and Indonesia account for 91 percent of the R1E resources of tin and for 61 percent of resources in other categories. The United States has less than 0.05 percent of the world's tin R1E in major deposits. Available data suggest that the Soviet Union may have about 4 percent of resources in this category. The industrial market economy countries of the United States, Japan, Federal Republic of Germany, and the United Kingdom are major consumers of tin, whereas the major tin-producing countries generally consume little tin. The Soviet Union and China are both major producers and consumers of tin. At the end of World War II, the four largest tin-producing countries (Bolivia, the Belgian Congo (Zaire), Nigeria, and Malaysia) produced over 80 percent of the world's tin. In 1986, the portion of production from the four largest producers (Malaysia, Brazil, Soviet Union, Indonesia) declined to about 55 percent, while the price of tin rose from about $1,500 to $18,000 per metric ton. In response to tin shortages during World War II, the United States began stockpiling refined tin metal from approximately 1946 to 1953 to ensure a strategic supply in the event of another war. Since World War II, there have been six International Tin Agreements to maintain price and supply stability between tin producers and consumers. Artificially high prices set by the tin-producing members and a tin glut brought on by independent producers like Brazil caused the collapse of the world tin market in late 1985; the International Tin Council exhausted its credit to support the market price. By the year 2025, Bolivia's underground lode mines will likely have insignificant production, as will those in the United Kingdom. Tin mines in the Southeast Asian Tin Belt will still be active. Brazil, which has risen from the eighth-ranked tin-producing country in 1982 to the largest producer in 1988, will likely be a major influence on world tin production well into the 21st century. The future mining activity of deposits presently inactive in Australia is impossible to predict.

Circular↗
USGS1987

Prospects for heavy crude oil development

The problems of utilizing heavy crude oil and natural bitumens centre on their high viscosity which makes them difficult to produce, store, transport, and refine. These factors are reflected in costs. World reserves are substantial, however, perhaps as much as 7 trillion† barrels estimated to represent 0·9 trillion barrels of recoverable oil. Nearly 2·1 trillion barrels of heavy crude oil, more than 50% of the world's total reserve, are located in Venezuela largely in the Orinoco Oil Belt. About 75% of the natural bitumen, 2·6 trillion barrels, is located in Canada in the Athabasca, Cold Lake, and Peace River areas of Alberta. Most of the estimated undiscovered heavy crude oil in the world, approximately 630 billion barrels, is outside the US and Canada. Data required to determine the cost of finding natural bitumen and heavy oil are roughly the same as for other mineral commodities. Similarly for recovery costs. The variables are so extensive that dollar amounts have little meaning without qualification. Recovery depends on depth below surface. Near-surface deposits are recovered by mechanical mining. Deeper deposits must be won by thermal means. Transportation by pipeline is feasible only if the viscosity is lowered by partial upgrading, heating, or by the use of diluents. Part of the high cost of refining results from the major investment required for the large installations that are needed for economic rates of production.

Energy Exploration & Exploitation↗