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Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora

Assessment of groundwater quantity and quality contributions to Lake Huron

Lake Huron, one of the five Great Lakes, borders the United States and Canada, with Michigan as the only U.S. State on its shoreline. Like other freshwater lakes, it faces water-quality challenges from nutrients and chemicals applied across its drainage basin. Although past studies focused on surface-water sources, groundwater contributions remain less understood. To address this gap, the U.S. Geological Survey, as part of the Cooperative Science and Monitoring Initiative, classified drainage basins to Lake Huron into eight hydrogeologic zones based on bedrock rock type and glacial sediment transmissivity. Utilizing existing data and empirical field data, we quantified groundwater discharge and identified areas of concern for loading of chloride and nitrate to Lake Huron. Groundwater contributions, including indirect and shoreline discharge, ranged from 5.8 to 11.5 inches annually, totaling 1.9 cubic miles and 0.09 cubic mile, respectively. Hydrogeologic zones with higher glacial sediment transmissivity yielded greater indirect groundwater discharge. Chloride levels above the U.S. Environmental Protection Agency’s 250-mg/L recommendation were mainly in the Saginaw lowlands, whereas nitrate above the 10-mg/L standard was rare—found in only 11 wells. Together, the analysis of where groundwater discharge is occurring in the Lake Huron Basin and the identification of areas with potential groundwater-quality concerns can help prioritize areas that are critical to protecting the long-term health of Lake Huron.

Michigan

Potentiometric surface maps and groundwater-level hydrographs for confined aquifers of the New Jersey Coastal Plain, 2018

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection (NJDEP), prepared potentiometric surface maps for 10 confined aquifers of the New Jersey Coastal Plain physiographic province based on water-level measurements collected during late 2018 and early 2019 from 951 wells in New Jersey and parts of Pennsylvania and Delaware. Maps were prepared for the confined Cohansey aquifer, Rio Grande water-bearing zone, Atlantic City 800-foot sand, Piney Point aquifer, Vincentown aquifer, Wenonah-Mount Laurel aquifer, Englishtown aquifer system, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system. Potentiometric surface maps indicate regional cones of depression in the following aquifers and the counties in which they are centered: Atlantic City 800-foot sand in Atlantic County, the Piney Point aquifer in Cumberland County, the Wenonah-Mount Laurel aquifer and Englishtown aquifer system in Monmouth and Ocean Counties, the Wenonah-Mount Laurel aquifer in Camden and Gloucester County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Ocean County, and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy aquifer system in Camden County. Cones of depression with smaller areal extents were in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Atlantic City 800-foot sand centered in Cape May County, the Piney Point aquifer centered in Ocean County, the Wenonah-Mount Laurel aquifer in Salem and Burlington Counties, the Englishtown aquifer system in Camden County, the upper aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth County, and the middle aquifer of the Potomac-Raritan-Magothy aquifer system in Monmouth, Ocean, and Salem Counties. No cone of depression was interpreted in the Vincentown aquifer. Long-term hydrographs are presented for 75 wells spanning each of the 10 confined aquifers, and contain a mix of discrete water-level measurements and daily mean water levels based on continuously recorded 15-minute data. Changes of water levels during 2014–19, as indicated by the hydrographs, were compared with those of previous periods to assess any departures from historical data. During 2014–19, water levels were stable and fluctuated within similar ranges as previous periods in the following aquifers and locations: all wells in the confined Cohansey aquifer, the Rio Grande water-bearing zone, the Vincentown aquifer, the Englishtown aquifer system, the Piney Point aquifer wells in Burlington and Ocean Counties, six of eight wells in the Wenonah-Mount Laurel aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system except those within NJDEP Critical Area II. Increasing water levels in 2014–19, ongoing since historical periods, were indicated in the following aquifers and locations: Atlantic County wells in the Piney Point aquifer, all wells in the upper and lower aquifers of the Potomac-Raritan-Magothy aquifer system outside NJDEP Critical Areas, and all wells in the middle aquifer of the Potomac-Raritan-Magothy aquifer system within NJDEP Critical Area II. Water levels in the Atlantic City 800-foot sand also increased during 2014–19 in wells in Atlantic County and northern Cape May County closer to the center of the cone of depression in that aquifer, which is a response unique to this period and absent from previous periods. During 2013–19, continued decreasing water levels, ongoing since previous periods, were indicated by hydrographs of Atlantic City 800-foot sand wells in southern Cape May County, Piney Point aquifer wells in Cumberland County where the regional cone of depression is located, and two wells in the Wenonah-Mount Laurel aquifer—070478, which in 2014–19 departed from previous periods, and 330020, which continued a gradual decrease throughout its period of record.

New Jersey

Status of water-quality conditions in the United States, 2010–20

Degradation of water quality can make water harmful or unusable for humans and ecosystems. Although many studies have assessed the effect of individual constituents or narrow suites of constituents on freshwater systems, no consistent, comprehensive assessment exists over the wide range of water-quality effects on water availability. Using published studies, data, and models completed at regional or national scales in the United States during 2010–20, this chapter moves towards a comprehensive assessment by summarizing how selected anthropogenic and geogenic water-quality constituents affect national-scale water availability for human and ecosystem needs. Several types of human health, agricultural, ecological, and beneficial-use standards or thresholds were used to provide context for categorizing surface-water and groundwater quality. Water availability for human and ecological use is limited by elevated concentrations of geogenic and anthropogenic constituents in surface and groundwater. Elevated concentrations of five geogenic constituents (arsenic, manganese, strontium, radium, and adjusted gross alpha) are common in groundwater and collectively affect the drinking water supply to over 30 million people. Surface water sourced drinking water supplies are impaired in about a third of assessed stream miles, most commonly because of non-mercury metals and salinity. Health-based violations at community water systems may disproportionately affect socially vulnerable communities. Ecological water uses are predominantly limited by nutrients, sediment, temperature, pathogens, salinity, and pesticides. Water availability for human and ecological use is adversely affected by human activities including human contaminant sources (for example, wastewater, agriculture), processes (for example, dredging, groundwater pumping), or permanent landscape modifications (for example, dams, urbanization). Primary contaminant sources vary spatially and include fertilizer and manure, atmospheric deposition, wastewater treatment plants, urban land, and a range of natural sources. Contaminants of emerging concern, contaminants without regulatory thresholds, and mixtures of geogenic and anthropogenic water contaminants also contribute to ecological degradation and human exposure.

conterminous United States

Tectonically driven integration of the 4.8 Ma Colorado River USA tracked with detrital sanidine and fish genetics

The development of the continental-scale Colorado River system, western USA, from 8 to 4.8 Ma, is revealed using 60-40 Ma detrital sanidine tracer grains and fish phylogeny. Here we show that precursor paleoriver segments became integrated north to south as traced by 60-40 Ma sand grains that were derived from the north and sequentially appeared in the 25-8 Ma Browns Park Formation of Utah, 7-6 Ma upper Bidahochi Formation of Arizona, and 4.8 Ma Bouse Formation of the lower Colorado River and proto Gulf of California. This timing is mimicked by molecular clock estimates of divergence times among fish lineages. River integration was a response to headwater uplifts in the Yellowstone hotspot track and Rocky Mountains. 40 Ar/ 39 Ar ages refine the timing for mantle-drips that caused subsidence, then uplift, of depositional basins that influenced the integration pathway and tempo. The ~ 3-million-year timescale suggests that multiscale mantle-driven uplift, rather than lake spillover, was the primary driver for integration of the proto-Colorado River through Grand Canyon.

Colorado River

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

Colorado

Characterization of stream water quality and groundwater levels in the Central Pine Barrens region, Suffolk County, New York, 2017–23

The area locally known as the “Central Pine Barrens” region, located in Suffolk County, New York, contains most of Long Island’s preserved and undeveloped land. This region overlays an aquifer system that provides potable groundwater for residents of Suffolk County. Between 2017 and 2023, the U.S. Geological Survey, in cooperation with the Central Pine Barrens Joint Planning & Policy Commission and the Town of Brookhaven, monitored groundwater levels and stream water quality in this region. Groundwater levels were measured monthly at five wells and continuously (15-minute intervals) at a sixth well. Water quality was monitored at five locations in the Carmans River and at two locations in the Peconic River, and samples were analyzed for major ions, trace elements, nutrients, pharmaceuticals, and pesticides. The major ion compositions at the sites were mainly sodium-chloride type waters, and compositions varied the most at the furthest upstream sites in both streams. Concentrations above aquatic-life criteria thresholds also occurred most frequently at the furthest upstream sites. The seasonal patterns of nutrient loads and concentrations varied between the Carmans and Peconic Rivers. Several organic compounds including pharmaceuticals, domestic use products, and pesticides were detected at low concentrations in both streams. Metformin was the most frequently detected pharmaceutical compound, and herbicides were the most frequently detected pesticide class. Water-quality conditions influenced by anthropogenic contributions are a result of current and historical land use, and these contributions include onsite wastewater disposal systems, commercial or domestic fertilizers and pesticides, and urban or industrial contaminants in road runoff. This study characterizes and improves understanding of the current hydrologic conditions in the Central Pine Barrens region and the study findings can help inform the development of plans to manage, protect, and restore water resources.

New York

Assessing locations susceptible to shallow landslide initiation during prolonged intense rainfall in the Lares, Utuado, and Naranjito municipalities of Puerto Rico

Hurricane Maria induced about 70 000 landslides throughout Puerto Rico, USA, including thousands each in three municipalities situated in Puerto Rico's rugged Cordillera Central range. By combining a nonlinear soil-depth model, presumed wettest-case pore pressures, and quasi-three-dimensional (3D) slope-stability analysis, we developed a landslide susceptibility map that has very good performance and continuous susceptibility zones having smooth, buffered boundaries. Our landslide susceptibility map enables assessment of potential ground-failure locations and their use as landslide sources in a companion assessment of inundation and debris-flow runout. The quasi-3D factor of safety, F 3 , showed strong inverse correlation to landslide density (high density at low F 3 ). Area under the curve (AUC) of true positive rate (TPR) versus false positive rate (FPR) indicated success of F 3 in identifying head-scarp points (AUC = 0.84) and source-area polygons (0.85 ≤ AUC ≤ 0.88). The susceptibility zones enclose specific percentages of observed landslides. Thus, zone boundaries use successive F 3 levels for increasing TPR of landslide head-scarp points, with zones bounded by F 3 at TPR = 0.75, very high; F 3 at TPR = 0.90, high; and the remainder moderate to low. The very high susceptibility zone, with 118 landslides km −2 , covered 23 % of the three municipalities. The high zone (51 landslides km −2 ) covered another 10 %.

Puerto Rice

The Great Lakes Geologic Mapping Coalition—Working collaboratively to understand the geology of the Great Lakes Region

Introduction The Great Lakes Geologic Mapping Coalition (GLGMC), commonly referred to as the “Coalition,” is a partnership between the U.S. Geological Survey (USGS), the U.S. States of Illinois, Indiana, Michigan, Minnesota, New York, Ohio, Pennsylvania, and Wisconsin and the Canadian province of Ontario. The member States receive funding for geologic mapping work from the USGS National Cooperative Geologic Mapping Program (NCGMP), whereas Ontario participates as a nonfunded partner. The mission of the GLGMC is to produce three-dimensional (3D) geologic maps that depict unconsolidated sediments and near-surface bedrock in the Great Lakes region of North America. Geologic maps are the basis of most earth science investigations and help support resource exploration (energy, minerals, groundwater), natural hazard mitigation, infrastructure development, and land-use planning, all of which can be used to advance economic development and strengthen national security in the Great Lakes region. During the last few million years, the Great Lakes region has experienced repeated glacial advances and retreats, leaving behind extensive sediments, abundant natural resources, and widespread effects on the underlying bedrock geology (Swezey and others, 2022). Linked by shared histories of past glaciations, industrial agriculture, and legacy automotive, coal, steel, and manufacturing industries, the GLGMC member States collaborate to improve the understanding of the 3D distribution of the sediments overlying the region’s bedrock (fig. 1). Developing a comprehensive subsurface 3D framework of this glaciated terrain can provide earth science data to policymakers at all levels. These insights facilitate informed decisions on the exploration, use, and protection of vital resources, such as critical minerals, industrial materials, and aquifers, thereby supporting economic prosperity and the well-being of the citizens of this region. Since its inception in 1998, the Coalition has completed more than 100 geologic mapping projects across the Great Lakes region. Each project aims to deliver geologic maps, 3D datasets, and other information that improves understanding of the geology of the Great Lakes region, with an emphasis on economic and water resources. Key deliverables include 3D geologic maps and models typically portraying sediment thickness, often derived from top-of-bedrock and borehole data. These products are developed through a combination of fieldwork, subsurface modeling, and the collection and analysis of rock and sediment cores. To support Coalition goals, member States collaborate with scientists working on related STATEMAP, EDMAP, and FEDMAP projects. Coalition scientists also engage with Tribal Nations in the Great Lakes region to ensure that Tribal interests pertaining to Coalition work are addressed. Through this collaboration, the Coalition unites the efforts of State, Federal, and Tribal Nation stakeholders to advance geologic data production and enhance understanding of the geologic resources of the Great Lakes region.

Illinois, Indiana, Michigan, Minnesota, New York,

Critical minerals in orogenic (gold) and Coeur d’Alene-type mineral systems of the United States

Orogenic and Coeur d’Alene-type mineral systems are produced by metamorphic devolatilization of thick volcanic or siliciclastic sedimentary rock sequences and the focused flow of hydrothermal fluids upwards along crustal-scale faults. Most orogenic systems are found along the Cordilleran orogen, stretching from California northwards into Alaska, whereas most Coeur d’Alene-type systems occur in the Proterozoic Belt Basin in Idaho and Montana. Although the deposit types in these systems are exploited for precious and base metals, potential exists for the production of critical minerals necessary for current (2025) societal needs in the United States. Publicly available geochemical data compiled for these mineral systems, coupled with mineralogical characteristics, indicate that several critical minerals could potentially be recovered from unmined resources and processed mine waste: arsenic, antimony, tellurium, cobalt, and tungsten from orogenic gold deposits and zinc, antimony, arsenic, and manganese from Coeur d’Alene-type systems. These critical minerals reside primarily in arsenopyrite (arsenic), scheelite (tungsten), siderite (manganese), sphalerite (zinc), tetrahedrite (antimony and arsenic), stibnite (antimony), and telluride (tellurium) minerals.

continental United States

Methods to evaluate and improve the modeling of rupture directivity in assessment of seismic hazard

In recent years, there have been several advancements related to the modelling of near-source effects of earthquake rupture on strong ground shaking, leading to an improved characterization of ground motions and resulting seismic hazard. Some of these modifications have stemmed from physics-based numerical modelling of the earthquake rupture process, using physics-based dynamic rupture simulations. These contributions have led to a better understanding of how fault rupture characteristics, geometry, and the style of faulting can interact with the hypocenter-dependence on the path from source to site that may ultimately guide the development of seismic directivity models. Moving forward, the application of modern techniques can be used to incorporate these source characteristics and near-fault ground motion behavior that contribute to the azimuthally varying effects that result in rupture directivity. One example is the application of machine learning methods to support more automated integration of new predictor variables in model development and open more evaluation opportunities to access residuals. Here, we utilize several techniques to take advantage of the plethora of synthetic data and its ability to supplement preexisting trends observed in data. We showcase two examples of how models can be either developed, expanded upon, or constrained using artificial neural network model (ANNs). We evaluate the performance of the ANN with existing methods, comparing misfit, potential limitations, and ability to continue to improve upon these methods in the future. One approach uses a set of simulations with corresponding synthetic ground motions from the Southern California Earthquake Center (SCEC) CyberShake study to develop a ground motion model adapted to incorporate seismic directivity information using an ANN. This large database (TBs) enables us to train the model to capture magnitude, period, and distance variations and how these parameters relate to amplification from hypocenters located along finite-faults. In some cases, there is reduced misfit from better representing source features that aren’t included in base ground motion models that neglect hypocenter location (e.g. azimuthal variation, source-to-site terms). Another ANN method uses a shallow-layered neural network model to better fit a hypocenter-independent model. This method adjusts the median and aleatory variability to account for the averaged impact of various hypocenter distributions to fit the underlying directivity adjustment model. This method serves as a template to apply to other directivity models, improving computational efficiency and more readily enabling integration in hazard codes.

California

Utilization of stochastic ground motion simulations for scenario-based performance assessment of geo-structures

Probabilistic seismic performance assessments of engineered structures can be highly sensitive to the seismic input excitation and its variability. In the present study, the scenario-based performance assessment recommended by Federal Emergency Management Agency (FEMA) P-58 guidelines is adopted to estimate seismic fragility of concrete dams for various seismic hazard scenarios. Due to the scarcity of recorded ground motions and thereby their poor representation of uncertainties, stochastic ground motion simulation methods are utilized to obtain the required input excitations. Moreover, to understand the uncertainty in ground motion simulation models, two broadband stochastic simulation models are used to generate input excitations representing six seismic hazard scenarios defined by earthquake magnitude, source-to-site distance, and soil conditions. Optimal intensity measure parameters for each scenario are identified using a systematic procedure that considers criteria such as efficiency, practicality, proficiency, sufficiency, and hazard compatibility. Fragility curves and surfaces are derived using the cloud analysis technique, taking into account various damage measures and limit state functions. The study finds that the derived fragility curves are particularly sensitive to the selection of earthquake scenarios, the choice of records, and the methods used to calculate fragility curves, with less sensitivity observed to different engineering demand parameters. Given this sensitivity, particularly to ground motion selection, the study highlights the necessity of incorporating both model-to-model variability (epistemic uncertainty) and record-to-record variability (aleatory uncertainty), alongside the established material and modeling uncertainties, in the probabilistic seismic assessment.

Reliability Engineering and System Safety (RESS)

Earthquake stress drop, source spectra from laboratory experiments, and the apparent unsteadiness of frictional slip

Over a range of co-seismic total energy release, high sample rate slip, stress, and slip velocity measurements were made during frictional failure to determine seismic source properties. The near-field measurements were used to estimate stress drops using spectral approaches that are analogous to the standard seismological moment-corner determined Δσ and acceleration amplitude Δσ arms stress drops. Rapid frictional sliding produces slip velocity amplitude spectra that vary with frequency -1 so long as the energy dissipated by friction approaches the total energy release. Under these conditions Δσ and Δσ arms are similar in size. Since these are nearly direct measurements of fault slip velocity and because they produce flat acceleration spectra between the corner and an apparent fmax, friction in these experiments seems to produce dynamic acceleration and deceleration at all resolved frequencies. The physical origin of this unsteady motion is not known exactly but likely reflects rapid dynamic variations in fault strength or applied stress. On the other hand, when the total energy stored prior to failure is artificially made somewhat larger relative to that which can be dissipated by friction the velocity spectra vary with frequency -2 immediately below the corner. At these conditions Δσ and Δσ arms diverge. The excess stored energy is preferentially partitioned into radiated energy upon failure. Collectively the experiments imply that to produce unsteady, white noise accelerations that are observed for natural earthquakes, requires that at least 95% of the energy released does not escape the source region to be radiated to the far-field.

Bulletin of the Seismological Society of America

Light-dependent activity of deepwater sculpin (Myoxocephalus thompsonii) across substrates with and without predation risk

Light availability strongly influences predator–prey interactions in deepwater ecosystems, where visual constraints shape both foraging success and prey behavior. The behavioral response of deepwater sculpin ( Myoxocephalus thompsonii ) to siscowet lake trout ( Salvelinus namaycush siscowet ) was studied under ecologically relevant light intensities spanning several orders of magnitude typical of daytime downwelling light in the 20–100 m depth range of Lake Superior. Trials were conducted over varying substrates (gravel, sand, and black fabric). Deepwater sculpin showed a significant preference for gravel over sand and black fabric. In the absence of siscowet, sculpin movement frequency increased as light intensity decreased. Sculpin reaction distance to siscowet was influenced by both light and substrate. Reaction distance was shortest at low light intensities, peaked at intermediate light intensities (3.05 × 10⁹ to < 6.0 × 10⁹ photons m⁻2 s⁻1), and declined again at the highest light intensities tested. In the presence of siscowet, sculpin activity was suppressed at the upper end of the light range (≥ 6.0 × 10⁹ photons m⁻2 s⁻1). The greatest increase in movement occurred between 6.0 × 10⁹ and 3.05 × 10⁹ photons m⁻2 s⁻1, which corresponded to the range where siscowet prey capture declined, suggesting sculpin exploit this low-light window to move with reduced risk. Reduced activity in the presence of predators is common among cryptic species, and our findings suggest that sculpin restrict movement at higher light levels to avoid detection by siscowet.

Wisconsin

Effects of storm-water runoff on local ground-water quality, Clarksville, Tennessee

Storm-related water-quality data were collected at a drainage-well site and at a spring site in Clarksville, Tennessee, to define the effects of storm-water runoff on the quality of ground water in the area. A dye-trace test verified the direct hydraulic connection between the drainage well and Mobley Spring. Samples of storm run off and spring flow were collected at these sites for nine storms during the period February to October 1988. Water samples were collected also from Mobley Spring and two other springs and two observation wells in the area during dry-weather conditions to assess the general quality of ground water in an urban karst terrain. Evaluation of the effect of storm-water runoff on the quality of local ground water is complicated by the presence of other sources of contaminants in the area Concentrations and load for most major constituents were much smaller in storm-water runoff at the drainage well than in the discharge of Mobley Spring, indicating that much of the chemical constituent load discharged from the spring comes from sources other than the drainage well. However, for some of the minor constituents associated with roadway runoff (arsenic, copper, lead, organic carbon, and oil and grease), the drainage well contributed relatively large amounts of these constituents to local ground water during storms. The close correlation between concentrations of total organic carbon and concentrations of most trace metals at the drainage-well and Mobley Spring sites indicates that these constituents are transported together. Many trace metals were flushed early during each runoff event. Mean storm loads for copper, lead, zinc, and four nutrient species (total nitrogen, ammonia nitrogen, total phosphorus, and orthophosphorus) in storm-water runoff at the drainage-well site were lower than mean storm load predicted from an existing regression model. The overprediction by the model may be a result of the small size of the drainage area relative to the range of drainage areas used in the development of the models, or to the below-normal amounts of rainfall during the period of sampling for this investigation. Loads& in storm-water runoff for 22 constituents were extrapolated from sampled storms to total loads for the period February to October 1988. Calculated loads for trace metals for the period ranged from 0.030pound.s for cadmium to 12pound.s for strontium. Loads of the primary nutrients ranged from 0.97pounds for nitrite as nitrogen to 34pounds of organic nitrogen. Storm-water quality at the drainage-well and Mobley Spring sites was compared to background water quality of the local aquifer; as characterized by dry-weather samples from three springs and two observation wells in the Clarksville area. Concentrations of total-recoverable cadmium, chromium, copper, lead, and nickel were higher in many stormwater samples from both the drainage-well and Mobley Spring sites than in samples from any other site. In addition, concentrations of total organic carbon, methylene blue active substances, and total-recoverable oil and grease were generally higher in storm-water samples from the drainage-well site than in any ground-water sample. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total recoverable iron, manganese, and methylene blue active substances in storm samples from the drainage-well site exceeded the maximum contaminant levels listed in Tennessee’s drinking-water standards (1988) by as much as 2,500 and 5,500 colonies per 100 milliliters, and 2.7, 0.29, and 0.05 milligrams per liter, respectively. Densities of fecal coliform and fecal streptococcus bacteria and concentrations of total-recoverable iron, manganese, and lead in storm samples from Mobley Spring exceeded the maximum contaminant levels by as much as 500 and 4,500 colonies per 100 milliliters, and 18.7,0.65, and 0.02 milligrams per liter, respectively. For iron, manganese, and bacteria, these undesirable levels are not necessarily attributable to storm-water recharge, because concentrations of these constituents also exceeded drinking-water standards in one or more of the dry-weather samples from selected springs and observation wells in the area.

Tennessee

Characterization of selected biological, chemical, and physical conditions at fixed sites in the Upper Colorado River Basin, Colorado, 1995-98

Biological community samples were collected at 15 sites in the Upper Colorado River Basin (UCOL) in Colorado as part of the National Water-Quality Assessment (NAWQA) Program. Sites sampled in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, represented agriculture, mining, urban and recreation, and mixed land uses and background conditions. Nine measures of water quality, which include information on nutrients, specific conductance (a surrogate for salinity), trace elements in streambed sediment, pesticides in fish tissue, fish communities, and macroinvertebrate richness and composition and stream habitat were used for comparisons among sites within the two physiographic provinces. Sampling sites from three other NAWQA study units—the Rio Grande Valley, the South Platte River Basin, and the Upper Snake River Basin study units—were categorized on the basis of land use and stream size in order to develop a larger data set for comparison to sites in the UCOL. Three categories of land use—forested (includes mining, urban and recreation, and background), agriculture, and mixed—were used for comparison to the UCOL fixed sites. Results indicated that all sites other than the Colorado River below Baker Gulch (a background site) showed some water-quality characteristics to be significantly affected. Results indicated that the concentrations of cadmium and zinc in streambed sediment at mining land-use sites in the Southern Rocky Mountains physiographic province generally were orders of magnitude higher than streambed-sediment concentrations at the background site. Streambed-sediment concentrations at mining land-use sites in the UCOL were greater than the 75 th percentile of concentrations from sites in the three other NAWQA study units. Fish communities and habitat conditions were degraded at mining land-use sites compared to the background site. Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and the percentage of EPT were lower at mining land-use sites than at the background site and were less than the 50 th percentile of those for sites from the three other NAWQA study units. Nutrient concentrations at urban and recreation sites in the Southern Rocky Mountain physiographic province generally were greater than concentrations at the background site and generally were between the 25 th and 90 th percentile of concentrations for sites from the three other NAWQA study units. Habitat conditions and fish communities at urban and recreation sites were slightly degraded compared to the background site. EPT richness and the percentage of EPT were lower at urban and recreation sites than at the background site and were between the 25 th and 75 th percentile of those for sites from the three other NAWQA study units. The percentage of Chironomidae, which may be indicative of pollutant-tolerant organisms, was higher at urban and recreation sites than at the background site. Mixed land-use sites in the Southern Rocky Mountains physiographic province had similar nutrient concentrations and similar cadmium and zinc streambed-sediment concentrations. Fish-community degradation index values were very different among the three mixed land-use sites in the Southern Rocky Mountains physiographic province. Larger percentages of omnivores and anomalies such as lesions and deformities at two mixed land-use sites resulted in higher degradation values of the fish community. Agriculture land-use sites had higher concentrations of nutrients and selenium than the background site in the Colorado Plateau physiographic province. Concentrations of p,p '-DDE in fish tissue at agriculture sites were higher than the 75 th percentile of concentrations for sites from the three other NAWQA study units. Fish communities had degradation values near the 75 th percentile for agriculture sites. The percentage of EPT was low at agriculture sites when compared to the background site. Two mixed land-use sites in the Colorado Plateau physiographic province had similar concentrations of nutrients, selenium, and p,p '-DDE, and similar EPT richness and composition. These two sites were located downstream from agricultural and urban activities. Some water-quality measures at these two sites indicated degradation compared to a mixed land-use site upstream from most of the agriculture and urban activities in the Colorado Plateau physiographic province.

Colorado

Preliminary bedrock geologic map of the Port Henry quadrangle, Essex County, New York, and Addison County, Vermont

Introduction The bedrock geology of the 7.5-minute Port Henry quadrangle consists of deformed and metamorphosed Mesoproterozoic gneisses of the Adirondack Highlands unconformably overlain by weakly deformed lower Paleozoic sedimentary rocks of the Champlain Valley. The Mesoproterozoic rocks occur on the eastern edge of the Adirondack Highlands and represent an extension of the Grenville Province of Laurentia. Mesoproterozoic paragneiss, marble, and amphibolite hosted the emplacement of an anorthosite-mangerite-charnockite-granite (AMCG) suite, now exposed mostly as orthogneiss, at approximately 1.18–1.15 Ga (giga-annum). In the Port Henry quadrangle, the AMCG metaigneous rocks (Yhg, Ygb, Yanw) intruded older, mostly metasedimentary rocks of the Grenville Complex during the middle to late Shawinigan orogeny (~1,160–1,150 Ma [mega-annum]). All rocks were subsequently metamorphosed to upper amphibolite to granulite facies conditions during the 1,080–1,050 Ma Ottawan orogeny. New mapping reveals four periods of deformation: (1) D1 produced rarely preserved isoclinal folds in the paragneiss and marble and predates AMCG magmatism. (2) Subsequent D2 deformation produced the dominant gneissic fabric preserved in the rock, recumbent folding, and deformed all the Proterozoic units in the map area. Syn- to late-D2 felsic magmatism resulted in the regionally extensive Lyon Mountain Granite Gneiss, which hosts numerous magnetite ore bodies. (3) Mylonitic extensional shear zones and core complex formation marked the beginning of D3 deformation. Protracted D3 deformation resulted in F3 upright folding, dome and basin formation, pegmatite intrusion, reactivation of the S2 foliation, partial melting, metamorphism, metasomatism, iron-ore remobilization, and intrusion of magnetite-bearing pegmatite both as layer-parallel sills and crosscutting dikes. (4) D4 created northeast- and northwest-trending local high-grade ductile shear zones and boudinage, northwest-trending regional kilometer (km)-wide ductile shear zones, and crosscutting granitic pegmatite dikes. The development of the late-stage regional shear zones (D4) was likely due to the continuation of extensional doming and uplift from upper amphibolite facies conditions at the end of the Ottawan orogeny. The majority of iron-ore deposits in the Port Henry and adjacent Witherbee quadrangles are in the hanging wall of these extensional shear zones. In the Port Henry quadrangle, the km-wide Cheney Mountain shear zone is the result of D4 deformation. Kilometer-scale lineaments readily observed in lidar data are Ediacaran mafic dikes and Phanerozoic brittle faults. The Paleozoic rocks are part of the Early Cambrian to Late Ordovician carbonate bank on the ancient margin of Laurentia. The approximately 1-km-thick Cambrian to Ordovician stratigraphy records a transition from synrift clastics to passive-margin peritidal carbonate buildups to gradually deeper-water subtidal- to shelf-carbonates during foreland basin development associated with the Taconic orogeny. The Paleozoic rocks are weakly folded and block faulted. Large areas of the Champlain Valley are covered by undifferentiated glacial deposits, some of which contain mapped landslides. The map also shows waste rock piles and tailings from historical mining operations. This study was undertaken to improve our understanding of the bedrock geology in the Adirondack Highlands, establish a modern framework for 1:24,000-scale bedrock geologic mapping in the Adirondacks, provide a context for historical iron mines in the eastern Adirondacks, and update the stratigraphy of the Champlain Valley in New York and Vermont. This Open-File Report includes a bedrock geologic map; a description of map units; a correlation of map units; and a geographic information system database that includes bedrock geologic units, faults, outcrops, and structural geologic information.

New York, Vermont

AAPG Energy and Minerals Division Tight Oil and Gas Committee Activities and Commodity Report for 2021-2022: Tuscaloosa Marine Shale, Gulf Coast basin, Louisiana and Mississippi

The Upper Cretaceous Tuscaloosa marine shale (TMS) potential production area encompasses 20.4 million acres across central Louisiana (LA), southern Mississippi (MS), southwestern Alabama (AL), and a small southwestern section of the Florida panhandle (Hackley et al., 2018). It remains a minor and largely undeveloped unconventional shale oil play with production from the TMS confined along the east-west LA-MS State boundary (Fig. 1). The mean undiscovered, technically recoverable resources in the TMS are estimated at 1.5 billion barrels of oil and 4.6 trillion cubic feet of gas (Hackley et al., 2018). Geochemical analyses of source rock solvent extracts and oil samples indicate that, in the play area, the TMS is the primary source of shale oil produced from the TMS as well as of accumulated oils in the underlying conventional reservoirs of the lower Tuscaloosa (Hackley et al., 2020). The API gravity of TMS oils ranges from approximately 34 to 46 degrees (Hackley et al., 2020; Croke et al., 2020).

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