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USGS2025

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research↗

USGS1998

Continuous hydrologic simulation of runoff for the Middle Fork and South Fork of the Beargrass Creek basin in Jefferson County, Kentucky

The Hydrological Simulation Pro-gram-FORTRAN (HSPF) was applied to an urban drainage basin in Jefferson County, Ky to integrate the large amounts of information being collected on water quantity and quality into an analytical framework that could be used as a management and planning tool. Hydrologic response units were developed using geographic data and a K-means analysis to characterize important hydrologic and physical factors in the basin. The Hydrological Simulation Program FORTRAN Expert System (HSPEXP) was used to calibrate the model parameters for the Middle Fork Beargrass Creek Basin for 3 years (June 1, 1991, to May 31, 1994) of 5-minute streamflow and precipitation time series, and 3 years of hourly pan-evaporation time series. The calibrated model parameters were applied to the South Fork Beargrass Creek Basin for confirmation. The model confirmation results indicated that the model simulated the system within acceptable tolerances. The coefficient of determination and coefficient of model-fit efficiency between simulated and observed daily flows were 0.91 and 0.82, respectively, for model calibration and 0.88 and 0.77, respectively, for model confirmation. The model is most sensitive to estimates of the area of effective impervious land in the basin; the spatial distribution of rain-fall; and the lower-zone evapotranspiration, lower-zone nominal storage, and infiltration-capacity parameters during recession and low-flow periods. The error contribution from these sources varies with season and antecedent conditions.

Kentucky↗

USGS2024

Radiogenic strontium- and uranium-isotope tracers of water-rock interactions and hydrothermal flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

Natural radiogenic isotopes (primarily 87 Sr/ 86 Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water-rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234 U/ 238 U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (<22 ng/g) and a wide range of 87 Sr/ 86 Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87 Sr/ 86 Sr compositions that bound the range of values observed in groundwater throughout the basin. Non-boiling springs on the west flank of the basin discharge water with low 87 Sr/ 86 Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87 Sr/ 86 Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87 Sr/ 86 Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87 Sr/ 86 Sr. Isotope data constrain basin-wide output of thermal water to 110–140 kg·s −1 . Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature-dependent water-rock reactions in one of the largest continental hydrothermal systems on Earth.

Wyoming↗

USGS2024

Federal lands greenhouse gas emissions and sequestration in the United States: Estimates for 2005–22

In 2016, the Secretary of the U.S. Department of the Interior requested that the U.S. Geological Survey (USGS) produce a publicly available and annually updated database of estimated greenhouse gas emissions associated with the extraction and use of fossil fuels from Federal lands. The first report in this series included emissions estimates from 2005 to 2014 and were reported for 29 States and two offshore areas. Native American and Tribal lands were not included in that analysis. This report recalculates those previous years (2005–14) with updated data and methods and extends the estimates to 2022. Nationwide emissions from fossil fuels produced on Federal lands in 2022 were 1,081.2 million metric tons of carbon dioxide equivalent (MMT CO 2 Eq.) for CO 2 , 33.4 MMT CO 2 Eq. for methane (CH 4 ), and 4.3 MMT CO 2 Eq. for nitrous oxide (N 2 O). Compared to 2005, the 2022 totals represent decreases in emissions for all three greenhouse gases (by 17 percent for CO 2 , 37 percent for CH 4 , and 30 percent for N 2 O). Emissions from fossil fuels produced on Federal lands represent, on average, 21.8 percent of U.S. emissions for CO 2 , 6.1 percent for CH 4 , and 1.3 percent for N 2 O over the 18 years included in this estimate. The trends and relative magnitudes of the greenhouse gas emissions estimated are roughly parallel to the Federal lands fossil fuel production volumes. In 2021, Federal lands of the conterminous United States stored 70,424 MMT CO 2 Eq. in terrestrial ecosystems. Soils stored most of the terrestrial ecosystem carbon (66 percent), followed by live vegetation (25 percent), deadwood (5 percent), and litter (4 percent). Carbon sequestration on Federal lands was highly variable over time, owing primarily to interannual variability in climate and weather, and variability in land use and land cover (LULC) change and disturbances, among these are wildfires and logging. Between 2005 and 2021, Federal lands sequestered an average of 83 MMT CO 2 Eq./yr. By subtracting the cumulative effects of LULC and disturbance-related CO 2 losses to the atmosphere from the total, we estimate that ecosystems at the national level sequestered CO 2 at an annual mean rate of 17 MMT CO 2 Eq./yr in a term called the net ecosystem exchange (NEE). This annual NEE sequestration value represents about 1.4 percent of average fossil fuel emissions over the same period. The USGS estimates presented in this report represent an accounting for the emissions resulting from fossil fuel extraction on Federal lands and the end-use combustion of those fuels, as well as for the sequestration of carbon in terrestrial ecosystems on Federal lands. A combined net CO 2 emissions estimate, which is the difference between the emitted and sequestered CO 2 from both the fossil fuel and ecosystems estimates, provides context for evaluating the greenhouse gas contributions of activities on these lands. The estimates included in this report can provide context for future energy decisions, as well as a basis to track change in the future.

Scientific Investigations Report↗

USGS2025

Airborne radiometric data map alteration of porphyry copper systems in the Elkhorn district, MT

The Elkhorn district in southwestern Montana is known for past production of high-grade base and precious metals from skarn and carbonate replacement deposits. The district also hosts a porphyry Cu-Mo deposit. A radiometric survey flown over the district and surrounds provides maps of surficial concentrations of potassium, thorium, and uranium. Handheld gamma ray spectrometer measurements on altered and unaltered rocks in the district and surrounding region provide a means to ground truth the airborne data. We demonstrate that the airborne and ground-based measurements show similar map patterns. We calculate ratios of the radioelement concentrations and present a potassium enhancement map that combines potassium and ratios of potassium to thorium and uranium. The results highlight the rocks previously mapped as having K-feldspar-biotite and quartz-sericite alteration assemblages in the Elkhorn district and map additional hydrothermal systems in the region, including known alteration in the Radersburg district. The data enhancement techniques can be used as a screening tool for mapping additional porphyry copper systems.

Montana↗

USGS1997

Chemical evolution and estimated flow velocity of water in the Trinity Aquifer, south-central Texas

Three permeable zones with varying lithology and water chemistry compose the Trinity aquifer, a principal source of water in the 5,500- square-mile study area in south-central Texas. The upper permeable zone locally yields small quantities of water to wells and was not included in this study. The middle permeable zone primarily is composed of limestone with minor amounts of dolostone. Terrigenous sand and marine limestone, with minor amounts of dolostone, are the principal lithologic units in the lower permeable zone. Dissolved solids concentrations range from 329 to 1,820 milligrams per liter in water samples from the middle permeable zone and from 518 to 3,030 milligrams per liter in water samples from the lower permeable zone. Principal hydrochemical facies in the middle permeable zone are calcium magnesium bicarbonate and calcium magnesium sulfate. Hydrochemical facies in ground-water samples from the lower permeable zone vary. Tritium concentrations as large as 5.3 tritium units in the southeastern part of the study area are indicative of relatively recent recharge. Results of a geochemical mass balance simulation along a flowpath in the middle permeable zone indicate a mass transfer of 4.25 millimoles per liter of dolomite dissolved, 5.74 millimoles per liter of gypsum dissolved, 0.46 millimole per liter of sodium chloride dissolved, 8.07 millimoles per liter of calcite precipitated, and 0.67 millimole per liter of calcium-for-sodium cation exchange between solid and aqueous phases. These results support dedolomitization as a principal chemical process in the middle permeable zone of the Trinity aquifer. Results of a simulation along a flowpath in the lower permeable zone indicate a mass transfer of 0.41 millimole per liter of dolomite dissolved, 0.001 millimole per liter of gypsum dissolved, 9.58 millimoles per liter of sodium chloride dissolved, 1.09 millimoles per liter of calcite precipitated, and 1.11 millimoles per liter of sodium-forcalcium cation exchange between solid and aqueous phases. Lower permeable zone processes indicate sodium chloride dissolution, dedolomitization, and cation exchange. Ground-water-flow velocities determined from adjusted carbon-14 ages, calculated using NETPATH, for selected flowpaths in the middle and lower permeable zones were about 1.7 feet per year and less than about 4.4 feet per year, respectively.

Texas↗

USGS2026

Moment magnitude for small earthquakes in the Delaware basin of west Texas and southeast New Mexico, USA

The Delaware Basin region of west Texas and southeast New Mexico has become one of the most prolific regions of seismic activity in the continental United States due to widespread hydraulic fracturing and wastewater disposal injection. In response to the increased number of earthquakes in this region, rapid and accurate characterization of earthquake sources is necessary to understand the evolution of seismic activity and level of seismic hazard associated with these earthquakes. This study re-evaluates earthquake magnitudes, estimating moment magnitude (MW) for small earthquakes in the Delaware Basin using 1) moment-rate spectra derived from S-wave coda envelopes, and 2) a relative magnitude method that relies exclusively on the ratio of waveform amplitudes between highly correlated waveform pairs. The coda-envelope method produces accurate M W estimates for small earthquakes ( M 1.5 – 3) that are consistent with independent, waveform modeled moment magnitudes for events with M W > 3 . Using the relative amplitudes method to extend these M W magnitudes to many other events, we successfully provide relative moment magnitude ( M W,rel ) values for 81% of the Texas Seismological Network catalog in the Delaware Basin region, and 45% of the USGS Induced Seismicity Project’s catalog of events in southeast New Mexico. The adoption and integration of the calibrated M W,rel method with current magnitude estimation methods offers valuable insights into the relationships between local and moment magnitude and will contribute to improved characterization of widespread induced seismicity.

New Mexico, Texas↗

USGS2026

Suitability of ground-motion models for seismic hazard assessment in Puerto Rico and the U.S. Virgin Islands

We perform linear mixed-effects analyses with a ground-motion dataset to evaluate how well ground-motion models (GMMs) fit active crustal, subduction interface, and subduction intraslab earthquakes in Puerto Rico and the US Virgin Islands. Most of the GMMs reproduce the spatial variation in peak ground motions with earthquake magnitude and rupture distance but predict ground motions 0.3–1.0 natural log units (35%–270%) greater than observations. Two GMMs developed for Puerto Rico that are based on ground-motion records from mostly magnitude 4–5 earthquakes do not perform as well. We attribute the period-dependent overprediction in observed ground motions to differences between the observed site response and the linear site response in the GMMs. Consequently, we developed region-specific GMMs by adjusting the period-dependent linear site response coefficients and period-dependent constant coefficients to remove most of the bias between predicted ground motions and observations. For the analysis, we compile ground-motion records and process waveforms to build a dataset with 10,127 records at 72 stations from 849 magnitude 4.0–6.4 earthquakes between 1 January 2006 and 31 March 2024. The earthquakes include active crustal, subduction interface, and subduction intraslab events. We evaluate the GMMs using the time-averaged shear wave speed in the top 30 m ( ), which we compile from site surveys and proxy values computed from horizontal to vertical spectral ratios. Site terms exhibit strong consistency across GMMs and crustal and subduction earthquakes, indicating that the linear mixed-effects analysis successfully isolates the effects of local site response. The event terms show little spatial correlation and more substantial variability than in other regions, which we attribute to uncertainties in the earthquake magnitudes. This analysis guides the selection of the GMMs for the 2025 update of the National Seismic Hazard Model for Puerto Rico and the US Virgin Islands.

Puerto Rico, U.S. Virgin Islands↗

USGS2025

Lessons in business recovery following the 2023 Kahramanmaraş earthquake sequence, Türkiye informed by women entrepreneurs

On 6 February 2023, Southern Türkiye was hit by devastating earthquakes, directly affecting over 14 million people in 11 cities, causing more than 50,000 deaths and the destruction of more than 800,000 buildings. This article goes beyond the physical damage imposed by the catastrophe to discuss the effects of the earthquakes on the operations of women-owned businesses. The mixed-method study with entrepreneurs belonging to a women’s business association operating in a moderately disrupted part of the region explores their struggles and recovery expectations. Thirty-five questionnaires were analyzed to identify the reasons for business closure, challenges, and needs faced in the post-disaster period and their recovery strategies. In addition, 23 entrepreneurs participated in roundtable discussions to provide a broader context to their responses to survey topics as well as lessons learned. Across both the survey and roundtables, while many respondents reported minor physical damage to their building, they also experienced financial and personal challenges from disruption to equipment, infrastructure, services, supply chains, institutional decisions, employee well-being, and customer base. Many used their business resources and personal savings to assist employees and others in the community. The women entrepreneurs often felt their recovery needs were ignored by government and private relief organizations and encountered barriers to receiving assistance from public and private institutions. Organizing together as women in business, even informally, provided mutual support during the crisis and recovery periods and catalyzed their role in support of their communities. The results illuminate functional community recovery as a balance of recovery of built infrastructure functionality and recovery of the broader social and economic fabric of the community.

southern Turkey↗

USGS2026

Non-destructive sampling of larval amphibians shows tail tissues reflect whole-body methylmercury concentrations and trophic-related differences in bioaccumulation

Mercury (Hg), and specifically methylmercury (MeHg), is a contaminant of global concern to humans and wildlife, but there is still limited understanding of its effects on many taxa. Amphibians are closely associated with water, where Hg is converted to MeHg, and high concentrations of MeHg can reduce survival of amphibians in the wild. However, limited non-lethal proxies exist for estimating MeHg bioaccumulation in amphibian larvae, which could be used to reduce destructive sampling and allow sampling of imperiled species. We evaluated whether tail clips were indicative of whole-body MeHg concentrations of larval amphibians, whether dragonflies were an effective bioindicator of Hg concentrations of larval amphibians, and compared MeHg bioaccumulation in predatory caudate (salamanders, newts) and non-predatory anuran (frogs, toads) larvae. Tail-clip and whole-body MeHg concentrations were strongly correlated, especially for caudates. There was high variability among sites and species, but caudates had higher MeHg than anurans, and MeHg concentrations of caudates and anurans were strongly correlated. Dragonflies were a weak indicator of MeHg for anurans but strong indicators for larval caudates, likely because caudates and dragonflies are carnivorous and occupy similar trophic positions. Our study revealed that sampling tails can be an effective non-destructive index of whole-body MeHg for larval amphibians and demonstrates differences in MeHg bioaccumulation related to trophic position in larval amphibians and dragonflies. All post-embryo life stages for a broad suite of amphibian species can now be sampled non-lethally for MeHg, allowing for a broader examination of population-level effects and focus on imperiled species that cannot be sampled destructively.

conterminous United States↗

USGS2008

Late Jurassic igneous rocks in south-central Arizona and north-central Sonora: Magmatic accompaniment of crustal extension

In Middle Jurassic time, the region of south-central Arizona and north-central Sonora was part of a continental magmatic arc. In early Late Jurassic time, this magmatic arc gradually gave way to a extensional regime. Late Jurassic rifting was accompanied by magmatism, typically small in volume relative to the preceding arc phase, and with mildly alkaline compositions. These igneous rocks, the 158- to 146-Ma Ko Vaya Suite, make up much or most of the Comobabi, Artesa, Quijotoa, and Brownell Mountains and Sierra del Cobre. The bimodal Ko Vaya Suite constitutes volcanic to shallow plutonic complexes comprising chiefly trachyandesite and volcanic wacke; monzodiorite; rhyolite porphyry; distinctive, compositionally and texturally heterogeneous, quartzpoor granite (the Ko Vaya Granite); A-type perthite granite and quartz syenite; aphyric intrusive rhyolite; and locally abundant hematite veins. Alteration, particularly potassic alteration, is widespread. Minimally altered samples of granite and quartz syenite have the composition of trachyte or trachydacite and alkali rhyolite. The Ko Vaya Suite is nonconformably overlain by the latest Jurassic Sand Wells Formation, approximately correlative with the Glance Conglomerate, the basal unit of the Bisbee Group. The Ko Vaya Suite is in some ways analogous to the coeval Independence dike swarm of eastern California, but less diffuse. We infer that the Ko Vaya Suite represents especially intense or focused Late Jurassic extensional magmatism.

Arizona, Sonora↗

USGS1976

Hydrogeology of stratified drift in Farmington, Connecticut: Available data and future needs

The purpose of this report is twofold. The first is to update hydrogeologic information on the major stratified-drift deposits that underlie much of Farmington. The second is to outline data requirements for future ground-water evaluation and management. The scope of the report is limited to the stratified drift, as it is the only aquifer capable of sustaining large withdrawals for public or industrial supply. This aquifer is composed of interbedded layers of gravel, sand, silt and clay. Most of this material was deposited by glacial meltwaters, but locally the aquifer contains some unconsolidated deposits of nonglacial origin. The most extensive stratified-drift deposits are in the valleys of the Farmington and Pequabuck Rivers.(See plate B.) A few small areas of stratified drift near East Farmington Heights and Oakland Gardens are not discussed in this report as their potential for large-scale development is slight.

Connecticut↗

USGS2024

Forecasting storm-induced coastal flooding for 21st century sea-level rise scenarios in the Hawaiian, Mariana, and American Samoan Islands

Oceanographic, coastal engineering, ecologic, and geospatial data and tools were combined to evaluate the increased risks of storm-induced coastal flooding in the populated Hawaiian, Mariana, and American Samoan Islands as a result of climate change and sea-level rise. We followed a hybrid (dynamical and statistical) downscaling approach to map flooding due to waves and storm surge at 10-square meter resolution along all 1,870 kilometers of these islands’ coastlines for annual (1-year), 20-year, and 100-year return-interval storm events and +0.00 meter (m), +0.25 m, +0.50 m, +1.00 m, +1.50 m, +2.00 m, and +3.00 m sea-level rise scenarios. We quantified the coastal flood depths and extents using the latest climate forcing from Intergovernmental Panel for Climate Change’s Sixth Assessment Report Coupled Model Intercomparison Project. The data generated using these methods provide stakeholders and decision makers with a spatially explicit, rigorous valuation of how, where, and when climate change and sea-level rise increase coastal storm-induced flooding to help identify areas where management and (or) restoration could potentially help reduce the risk to, and increase the resiliency of, the coastal communities in the populated Hawaiian, Mariana, and American Samoan Islands.

Hawaii↗

USGS2025

Sources of water and salts for the Zuni Salt Lake in west-central New Mexico

The Zuni Salt Lake is located in a maar in west-central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. There have been several investigations suggesting different sources for the water and salt to the lake. Springs, seeps, and ephemeral streamflow have all been observed to contribute freshwater to the lake, and brackish to hypersaline seeps have been documented along the banks of the lake. This report summarizes the findings of a study that characterizes the lake’s hydrology, its water and salinity sources, and the hydrogeologic conceptual model. Regional groundwater levels indicate that each of the aquifers in the area have the potential to discharge groundwater to the lake. There is also evidence of vertical groundwater flow pathways at the maar that were likely created by the igneous intrusion that fractured the intersecting aquifers. A detailed water budget was constructed from continuous lake stage, precipitation, and evaporation data to estimate the groundwater inflow to the Zuni Salt Lake. It was determined that groundwater inflow to the lake is 441 ±94 acre-feet per year, which composes as much as 77 percent of the total inflows. The high sodium and chloride concentrations measured in two hypersaline samples collected near the lake indicate that the majority of the dissolved solids entering the lake are from a hypersaline groundwater source. The geochemical and isotopic compositions measured in the lake and surrounding features support the interpretation that hypersaline groundwater is the primary source of salts to the lake, which is likely sourced from the older (and deeper) Permian units. The hypersaline groundwater samples collected during this investigation have a unique aqueous chemistry relative to each of the mapped aquifers, and variability in groundwater compositions is interpreted to result from differences in minerology and residence time.

New Mexico↗

USGS2024

High resolution identification and quantification of diffuse deep groundwater discharge in mountain rivers using continuous boat-mounted helium measurements

Discharge of deeply sourced groundwater to streams is difficult to locate and quantify, particularly where both discrete and diffuse discharge points exist, but diffuse discharge is one of the primary controls on solute budgets in mountainous watersheds. The noble gas helium is a unique identifier of deep groundwater discharge because groundwater with long residence times is commonly enriched in helium. In this study, a portable mass spectrometer was used to measure longitudinal variation in dissolved helium concentrations in two mountainous rivers at high spatial resolution not feasible with traditional sampling techniques. Helium profiles were then simulated using a mass-balance model to quantify longitudinal variation in groundwater discharge to the receiving rivers. Results indicate helium concentrations were enriched by multiple orders of magnitude above atmospheric equilibrium in both rivers and that this persisted for up to 18 km below observed pulse inputs in the Colorado River. Helium mass-balance models match observed longitudinal patterns with the exception of sharp initial increases in helium observed in the rivers. Increased longitudinal groundwater discharge rates correspond to mapped geologic structures in both watersheds that likely transport deep geothermal water. Models show variable sensitivity to spatial assignment of input variables representing the groundwater source, illustrating the importance of collecting data from discrete groundwater discharges where possible. The methodology shows promise for field experiments designed to assess air–water exchange rates and to quantify total groundwater discharge from a combination of discrete and diffuse sources.

Colorado, Utah↗

USGS2024

Status and understanding of groundwater quality in the Mojave Basin Domestic-Supply Aquifer study unit, 2018—California GAMA Priority Basin Project

Groundwater quality in the western part of the Mojave Desert in San Bernardino County, California, was investigated in 2018 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The Mojave Basin Domestic-Supply Aquifer study unit (MOBS) region was divided into two study areas—floodplain and regional—to assess differences between the two major aquifers used for drinking water supply in the area. This assessment characterized the quality of ambient groundwater and not the quality of treated drinking water. The study included three components: (1) a status assessment, which characterized the quality of groundwater resources used for domestic drinking-water supply in the floodplain and regional study areas; (2) a brief understanding assessment, which evaluated factors that could potentially affect the quality of groundwater used by domestic wells in the region; and (3) a comparative assessment between the groundwater resources used by domestic wells and public-supply wells in the two study areas. The domestic-well assessment was based on data collected by the U.S. Geological Survey from 48 domestic wells in January–May 2018. The public-supply assessment was based on data for samples from 322 public-supply wells in 2008–18, either collected by the U.S. Geological Survey or compiled from the California State Water Resources Control Boards Division of Drinking Water publicly available database. Concentrations of water-quality constituents in ambient groundwater were compared to regulatory and non-regulatory benchmarks typically used by the State of California and Federal agencies as health-based or aesthetic standards for public drinking water. Relative concentrations, defined as the measured concentration divided by the benchmark concentration, were classified as high (greater than 1.0), moderate (greater than 0.5 for inorganic constituents or 0.1 for organic and special-interest constituents, and not high), or low (concentrations lower than moderate). The floodplain and regional study areas were divided into 15 and 35 grid cells, respectively, and grid-based methods were used to compute the areal proportions of the two study areas with high, moderate, or low relative concentrations of individual constituents and classes of constituents. For the domestic-supply assessment, one or more inorganic constituents with health-based benchmarks were detected at high relative concentrations in 58 percent of the regional study area and 13 percent of the floodplain study area. The inorganic constituents with health-based benchmarks detected at high relative concentrations in the regional study area were arsenic, chromium and hexavalent chromium, fluoride, adjusted gross alpha particle activity, uranium, molybdenum, strontium, and nitrate; only arsenic was detected at high relative concentrations in the floodplain study area. One or more inorganic constituents with secondary maximum contaminant level benchmarks were detected at high concentrations in 15 and 6.7 percent of the regional and floodplain study areas, respectively. The constituents detected at high relative concentrations in the regional study area were total dissolved solids, chloride, sulfate, and iron; only total dissolved solids and sulfate were detected at high relative concentrations in the floodplain study area. Organic constituents were not detected at moderate or high relative concentrations in either the regional or floodplain study areas. Volatile organic compounds were detected at low relative concentrations in 21 and 27 percent of the regional and floodplain study areas, respectively, and pesticides were detected at low relative concentrations in 9.1 and 20 percent of the regional and floodplain study areas, respectively. The only individual organic constituent detected in more than 10 percent of either study area was the trihalomethane trichloromethane. Total coliform bacteria were detected in 15 and 27 percent of the grid wells in the regional and floodplain study areas, respectively. The greater prevalence of high relative concentrations of many inorganic constituents in the regional study area compared to the floodplain area likely indicates the greater diversity of geologic material at depth in aquifer material and generally finer-grained alluvium compared to the floodplain study area combined with generally older groundwater that has had more contact time with aquifer materials. In general, trace element concentrations (1) increased with increasing groundwater age, (2) increased with distance from recharge sources in the mountains, and (3) increased with closer proximity to some types of geological units. In general, groundwater from domestic wells in the floodplain study area is young, with most samples containing a component of modern groundwater based on tritium and unadjusted carbon-14 activities, whereas groundwater from domestic wells in the regional study area generally is old, with most samples having unadjusted carbon-14 ages of 5,000–40,000 years. Public-supply wells in MOBS generally were deeper than domestic wells and presumably are in contact with older, more weathered alluvium that may have more mobile trace elements, such as arsenic or uranium. However, only 26 percent of the public-supply regional study area had high relative concentrations of inorganic constituents, compared to 58 percent for the domestic regional study area. The percentages of the public-supply and domestic floodplain study areas with high relative concentrations of inorganic constituents were 11 and 13 percent, respectively. The ages of groundwater used by public-supply and domestic wells in each study area were similar, which was not expected given the greater depth of the public-supply wells. Three potential factors may contribute to these results: (1) greater spatial footprint of domestic well network, which may result in domestic wells pumping groundwater from fractured bedrock or mineralized areas not used by public-supply wells; (2) greater pumping rates in public-supply wells, resulting in more water being withdrawn from coarse-grained, heterogeneous alluvium than finer-grained layers, which may have higher concentrations of (or more mobile) inorganic constituents; and (3) a greater degree of well management with public-supply wells, which may include pausing use of or decommissioning wells if treating or blending water is not feasible to lower constituent concentrations.

California↗

USGS2000

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee↗

USGS2024

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

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