SEARCH · USGS Science
Results for “Communications Earth and Environment”
Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa
This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.
Substrate Enhancement Pilot Project—Monitoring summary and evaluation, Kootenai River, Idaho, 2012–22
To assess changes in substrate conditions and the efficacy of artificially placed substrates at select sites on the Kootenai River near Bonners Ferry, Idaho, the U.S. Geological Survey, in cooperation with the Kootenai Tribe of Idaho, completed repeat bathymetric, velocimetric, and underwater videography surveys. Collectively, three project sites throughout the Kootenai River make up the Substrate Enhancement Pilot Project (SEPP), an effort intended to improve spawning and egg incubation viability at locations identified to be aquatic habitat limited for the endangered Kootenai River white sturgeon (Acipenser transmontanus). Following the placement of coarse substrates at each site, bathymetric, velocimetric, and underwater videography data were collected from 2012 to 2022 to assess the role of deposition and erosion on maintaining suitable white sturgeon spawning and incubation substrates. Minimal erosion and deposition occurred at all Substrate Enhancement Pilot Project sites, according to interannual and intra-annual net volumetric changes between bathymetric surveys. Depending on the timing of bathymetric surveys relative to the annual peak streamflow conditions, isolated locations of deposition or erosion were observed at each site and the potential for deposition or erosion was supported by measured mean depth-averaged velocities. This study concluded that variability of deposition and scour were common at each site throughout the monitoring period and may be attributed to fluctuations in streamflow. Repeat bathymetric, underwater videography, and velocity mapping surveys were used to verify the interstitial spaces and surfaces of substrates at each SEPP site remained free of fine sediments for intervals longer than a year but were susceptible to deposition between high streamflow events.
Concentrations and distribution of manmade organic compounds in the Lake Tahoe Basin, Nevada and California, 1997-99
The U.S. Geological Survey, in cooperation with the Tahoe Regional Planning Agency and the Lahontan Regional Water-Quality Control Board, sampled Lake Tahoe, major tributary streams to Lake Tahoe, and several other lakes in the Lake Tahoe Basin for manmade organic compounds during 1997-99. Gasoline components were found in all samples collected from Lake Tahoe during the summer boating season. Methyl tert -butyl ether (MTBE), benzene, toluene, ethylbenzene, and xylenes (BTEX) were the commonly detected compounds in these samples. Most samples from tributary streams and lakes with no motorized boating had no detectable concentrations of gasoline components. Motorized boating activity appears to be directly linked in space and time to the occurrence of these gasoline components. Other sources of gasoline components to Lake Tahoe, such as the atmosphere, surface runoff, and subsurface flow, are minor compared to the input by motorized boating. Water sampled from Lake Tahoe during mid-winter, when motorized boating activity is low, had no MTBE and only one sample had any detectable BTEX compounds. Soluble pesticides rarely were detected in water samples from the Lake Tahoe Basin. The only detectable concentrations of these compounds were in samples from Blackwood and Taylor Creeks collected during spring runoff. Concentrations found in these samples were low, in the 1 to 4 nanograms per liter range. Organochlorine compounds were detected in samples collected from semipermeable membrane devices (SPMD's) collected from Lake Tahoe, tributary streams, and Upper Angora Lake. In Lake Tahoe, SPMD samples collected offshore from urbanized areas contained the largest number and highest concentrations of organochlorine compounds. The most commonly detected organochlorine compounds were cis- and trans-chlordane, p , p' -DDE, and hexachlorobenzene. In tributary streams, SPMD samples collected during spring runoff generally had higher combined concentrations of organochlorine compounds than those collected during baseflow conditions. Upper Angora Lake had the fewest number of organochlorine compounds detected of all lake samples. Dioxins and furans were not detected in SPMD samples from two sites in Lake Tahoe or from two tributary streams. The number of polycyclic aromatic hydrocarbon (PAH) compounds and their combined concentrations generally were higher in samples from Lake Tahoe than those from tributary streams. Areas of high-motorized boating activity at Lake Tahoe had the largest number and highest concentrations of PAH's. PAH compounds were detected in samples from SPMD's in four of six tributary streams during spring runoff, all tributary streams during baseflow conditions, and at all lake sites. The most commonly detected PAH's in tributary streams during spring runoff were phenanthrene, fluoranthene, pyrene, and chrysene, and during baseflow conditions were phenanthrene, 1-methylphenanthrene, diethylnaphthalene, and pyrene. Upper Truckee River, which has an urban area in its drainage basin, had the largest number and highest combined concentration of PAH's of all stream samples. Bottom-sediment from Lake Tahoe had detectable concentrations of p-cresol, a phenol, in all but one sample. A sample collected near Chambers Lodge contained phenol at an estimated concentration of 4 micrograms per kilogram (µg/kg). Bottom-sediment samples from tributary streams had no detectable concentrations of organochlorine or PAH compounds. Several compounds were detected in bottom sediment from Upper Angora Lake at high concentrations. These compounds and their concentrations were p , p' -DDD (10 µg/kg), p , p' -DDE (7.4 µg/kg), 2,6-dimethylnaphthalene (estimated at 190 µg/kg), pentachlorophenol (3,000 µg/kg), and p-cresol (4,400 µg/kg).
Precariously balanced rocks in northern New York and Vermont, U.S.A.: Ground-motion constraints and implications for fault sources
Precariously balanced rocks (PBRs) and other fragile geologic features have the potential to constrain the maximum intensity of earthquake ground shaking over millennia. Such constraints may be particularly useful in the eastern United States (U.S.), where few earthquake‐source faults are reliably identified, and moderate earthquakes can be felt at great distances due to low seismic attenuation. We describe five PBRs in northern New York and Vermont—a region of elevated seismic hazard associated with historical seismicity. These boulders appear to be among the most fragile PBRs in the region, based on reports from hobbyists. The PBRs are glacial erratics, best evidenced by glacial striations on bedrock pedestals. The pedestals themselves are locally high knobs, often situated on regionally high topography; this setting limits soil development and indicates that any outwash deposits were likely ephemeral. As a result, PBR ages can be reliably established by the retreat of the last continental ice sheet, ∼15–13 ka. To quantify the fragility of the PBRs, we surveyed them with ground‐based light detection and ranging and calculated geometric parameters from the point clouds, field observations, and seismic responses. Preliminary validation of the 2023 time‐independent U.S. National Seismic Hazard Model (NSHM) shows that the existence of PBRs is generally consistent with the median site‐specific hazard curves. Only the Blue Ridge Road site suggests a modest reduction in hazard. To visualize the ensemble of data, we mapped the minimum permissible distance to potential source faults around each PBR site as a function of source magnitude by using the ground‐motion models from the 2023 NSHM. Viewed in this manner, our data are consistent with potential M ∼6.5 earthquake‐source faults in many parts of the Lake Champlain Valley and northern Adirondack Mountains. Our work illustrates a potential pathway for better constraining earthquake‐source faults in regions of cryptic faults.
Reconnaissance basement geology and tectonics of North Zealandia
New rock dredge samples supply key information to establish the tectonic and geological framework of the northern two-thirds of the 95% submerged Zealandia continent. The R/V Investigator voyage IN2016T01 to the Fairway Ridge, Coral Sea, obtained poorly sorted poly-lithologic pebbly to cobbly sandstones, well sorted fine grained sandstones, mudstones, bioclastic limestones, and basaltic lavas. Post-cruise analytical work comprised petrography, whole rock geochemical and Sr and Nd isotopic analyses, and U-Pb zircon, Rb-Sr, and Ar-Ar geochronology. A Fairway Ridge cobbly sandstone has a ∼95 Ma (early Late Cretaceous) depositional age; two biotite granite cobbles are 111 ± 1 and 128 ± 1 Ma in age, and some volcanic pebbles are also likely Early Cretaceous. Fairway Ridge basalts have intraplate alkaline chemistry and are of Late Eocene age (∼40–36 Ma). By analogy with South Zealandia, we interpret strong positive continental magnetic anomalies of North Zealandia to mainly result from Late Cretaceous to Cenozoic intraplate basalts, many of them rift-related lavas. A new basement geological map of North Zealandia shows the position of the Mesozoic Gondwana magmatic arc axis (Median Batholith) and other major geological units. This study completes onland and offshore reconnaissance geological mapping of the entire 5 Mkm 2 Zealandia continent.
Archive of seismic-reflection data collected during USGS cruise Lake Mead 01007 in Lake Mead, Nevada and Arizona, 1-28 April, 2001
No abstract available.
Archive of seismic-reflection data collected during USGS cruise Lake Mead 99014 in Lake Mead - Nevada and Arizona, 14-25 May, 1999
No abstract available.
Case definitions for wildlife diseases
Welcome to the first manual of “Case Definitions for Wildlife Diseases,” a “living” electronic publication. The plan is to add and update this manual’s case definitions periodically as warranted; thus, this manual will never be completed, and readers should download the latest versions of specific chapters (that is, definitions) when available. Constructive suggestions from readers are welcome and will help guide adjustments as this project progresses. The purpose of this manual is to provide case definitions for selected diseases of importance to wildlife in Canada and the United States. Case definitions provide standard sets of criteria for classifying the degree of certainty of a particular diagnosis and help improve surveillance data quality and comparability. Better data and standardization allow for improved data sharing, which increases geographic and species surveillance coverage and permits more robust analyses. The definitions included in this manual have been developed by veterinary pathologists, epidemiologists, and wildlife biologists primarily from the U.S. Geological Survey National Wildlife Health Center (NWHC) and Canadian Wildlife Health Cooperative (CWHC). Pathologists from each organization reviewed and finalized the definitions. Each case definition has been peer reviewed by two scientific experts before publication. This manual begins with the case definition template. This generic template includes four sections: “Individual, Place, and Time Criteria for Diagnosis and Testing,” “Field Criteria for Diagnosis,” “Laboratory Criteria for Diagnosis,” and “Epidemiological Linkage Criteria for Diagnosis” and can be used to guide development of new case definitions. Information in each section is then combined to provide an overall case classification. Disease diagnoses are classified as “Confirmed,” “Presumptive,” or “Suspected;” and evidence of a pathogen or toxin is classified as “Exposed” or “Present/Detected.” Each subsequent chapter is then a case definition for a specific disease of wildlife, and infectious and non-infectious diseases are included.
USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis
Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.
Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project
This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.
A novel drive-point multilevel system to investigate PFAS and other contaminants of global concern in the hyporheic zone of a wastewater effluent dominated stream
Contaminants found in treated wastewater discharged to streams, including pharmaceuticals and per- and polyfluoroalkyl substances (PFAS), are of global concern due to their deleterious effects on aquatic ecosystems and potential impacts to human health. Hyporheic zones have strong potential for contaminant attenuation. Assessing this potential requires collection of physical and biogeochemical data within the hyporheic zone. This study tested the applicability of a novel drive-point multilevel system (DP-MLS) for quantifying head profiles and characterizing contaminant concentrations in the hyporheic zone of a temperate region effluent dominated stream (EDS). DP-MLS, each with 4 ports, were installed in the stream bed at two sites, DS-1 and DS-2, 0.2 and 4.7 km downstream of the effluent outfall, respectively. Head profiles were measured and groundwater collected for analysis of pharmaceuticals and PFAS temporally over two years. The DP-MLS withstood rapid changes in stage, ice formation, and floating debris. Vertical hydraulic gradients (VHG) were generally upward but varied in magnitude indicating heterogeneity in hydraulic conductivity and variability in flow conditions. Upward VHG were also about 2X larger at DS-1 than at DS-2. Contaminant concentration profiles consistently showed penetration of pharmaceuticals and PFAS to 1 m below the bed at DS-2 while there was less penetration, lower groundwater concentrations, and more temporal variability in concentrations at DS-1. Integration of the physical and chemical data suggests weaker upwelling conditions at DS-2 are more easily reversed during periods of high stream stage, which could facilitate migration of wastewater contaminants into the bed. However, further studies incorporating other transport processes and reach scale dynamics are required to fully characterize these exchanges. Overall, this study demonstrates the efficacy of these novel DP-MLSs for characterization of the hyporheic zone and provides new insights into the occurrence, composition, and persistence of wastewater derived contaminants in the hyporheic zone of a well-studied EDS.
Timing of hydrothermal alteration and Au-Sb-W mineralization, Stibnite-Yellow Pine district, Idaho
The Stibnite-Yellow Pine district of central Idaho was mined from the early 1900s until the 1990s, extracting gold, antimony, tungsten, and mercury from veins and disseminated and replacement ores in mountainous terrain along the headwaters of the Salmon River. Mining during the two World Wars supplied critical antimony and tungsten to the war efforts. Recent exploration has delineated mineral resources of over 187 metric tons Au, 274 metric tons Ag, and 93,000 metric tons Sb. Mineralization is hosted in Cretaceous Idaho batholith granitic rocks and a sequence of Neoproterozoic to Paleozoic metasedimentary strata of carbonate and siliciclastic compositions. Historical studies outlined some of the complex paragenesis but debated the absolute age of mineralization. New petrographic and geochronologic work documents a sequence of five hydrothermal events in the Stibnite-Yellow Pine district. Event 1 is related to Cretaceous magmatic and hydrothermal activity and includes events ranging in age from 86 to 75 Ma, including sparse quartz-molybdenite veins dated at 86 Ma. Disseminated gold mineralization of event 2 is associated with sericitic alteration and sulfidation of igneous biotite and replacement of plagioclase by potassium feldspar, largely in granodiorite. Gold is present in zoned arsenian pyrite in both disseminated ores and in crosscutting carbonate-quartz veins containing pyrite and arsenopyrite. The large Yellow Pine deposit, localized at a dilatant bend in the Meadow Creek fault, hosts such disseminated and vein gold. Event 2 is interpreted as the major gold-forming event; 40 Ar/ 39 Ar ages of sericite and potassium feldspar alteration range, respectively, from 70 to 59 and 66 to 56 Ma. The long span is interpreted to reflect the age of gold mineralization and local overprinting by event 3. A narrower range from 66 to 61 Ma is interpreted to date the peak of gold mineralization and alteration. Event 3, tungsten mineralization with scheelite, is texturally later than event 2 gold and localized along the Meadow Creek structure. Event 3 scheelite has been dated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb methods at 57 Ma. Event 4, best developed in the West End area, includes gold-silver–bearing quartz-carbonate-pyrite veins and breccias with epithermal textures and potassium feldspar alteration envelopes. Adularia from event 4 yields 40 Ar/ 39 Ar plateau ages of 52 to 51 Ma. Event 5 antimony and mercury mineralization consists of stibnite veins and breccia cements at the Yellow Pine and Hangar Flat deposits as well as cinnabar veins and replacements at the peripheral Fern and Hermes deposits; it is constrained by an LA-ICP-MS U-Pb date on scheelite (ca. 47 Ma) intergrown with stibnite. Minor propylitic and argillic alteration is evident in 47 Ma igneous dikes, which do not contain economic mineralization. The Au-Sb-W ores in the Stibnite-Yellow Pine mining district formed over an extended time period from about 70 to 45 Ma in multiple pulses that were localized along the Meadow Creek fault zone. Each event corresponds to episodes of magmatism and/or hydrothermal activity in the region. Insignificant event 1 skarn and molybdenum mineralization is similar in age to the Thompson Creek porphyry molybdenum deposit in central Idaho. Event 2 gold mineralization occurred during a magmatic gap in central Idaho but was synchronous with magmatism in the Bitterroot lobe further north; event 2 is similar in age to orogenic gold-arsenic mineralization at the Beartrack mine in eastern Idaho. Event 3 scheelite mineralization coincides with tungsten mineralization at the Quartz Creek deposit, late magmatism in the Bitterroot lobe, and rapid exhumation of the Atlanta lobe of the Idaho batholith. Event 4 gold mineralization is coincident with the onset of regional Challis magmatism and extension. Event 5 antimony and mercury mineralization is time-equivalent to epithermal gold mineralization in the nearby Thunder Mountain volcanic field and the peak of Challis magmatism.
Geology and mineral deposits of the Needle Mountains District, Southwestern Colorado
The Needle Mountains district is set in highly fractured Precambrian granitic rocks that have intruded and metamorphosed older Precambrian metasedimentary rocks. The Precambrian rocks are overlain by outliers of Paleozoic strata and intruded by a late Tertiary stock. Past mineral production reportedly was limited to silver and gold ores presumably taken from small fissure veins. Although the economic potential of the district has not been adequately explored, some evidence indicates potential for base metal deposits.
Characterization of the water resources of the Pamunkey River watershed in Virginia—A review of water science, management, and traditional ecological knowledge
In central Virginia, the Pamunkey Indian Tribe and Reservation are facing increasingly complex water resource issues related to quantity and quality. Documentation of surface-water, groundwater, water quality, land subsidence, sea-level rise, and river ecology issues in the Pamunkey River watershed and incorporation of traditional ecological knowledge into these research topics may improve understanding of the water resources broadly. This report summarizes the relevant traditional ecological knowledge and scientific literature to elucidate gaps in the total combined knowledge of a suite of water science topics concerning the Pamunkey River watershed. This suite of water science topics includes some of the issues that the Pamunkey Indian Tribe and Reservation are facing within the watershed: fragmentation of streams and management of streamflow, flooding, degrading water quality, groundwater extraction, relative sea-level rise, rapid changes in ecosystems, loss of ecological and biological diversity, and climate change. Gaps in total combined knowledge are pervasive throughout each of these water resource topics. Identifying these knowledge gaps can help inform future research and management strategies.
Using surficial geologic maps, vegetation, and monitoring to address erosion impacts from grazing in Channel Islands National Park, California
Employing a map-unit classification scheme based on geomorphic process and age, the U.S. Geological Survey (USGS) mapped Quaternary surficial deposits of the five islands comprising Channel Islands National Park (CHIS), California, as no such maps previously existed. Mapping was motivated through an agreement with the National Park Service (NPS) to aid natural resource assessments, including post-grazing disturbance recovery and identification of mass wasting and tectonic hazards. The resulting detailed (1:12,000 scale) maps portray areas of upland erosional transport processes and alluvial, fluvial, eolian, beach, marine terrace, mass wasting, and mixed depositional processes at a scale commensurate with the process signal on the landscape. Detailed, GPS-located observations of sedimentology, pedogenic development, landscape position, and geomorphology constrain map unit identification. In addition, map-unit boundary delineation was determined in a GIS using a variety of high-resolution (sub-meter) aerial imagery and lidar-based DEMs complemented by derivative raster products. The GIS geodatabase schema used is GeMS compliant. Resolvable map-unit widths are as small as 10-15 meter. Locational accuracy of unit boundaries is estimated to be as low as 10 m or better. Detailed mapping is at a scale allowing determination of geomorphic transport processes operating on the landscape and conveys geologic information to land managers at a resolution commensurate with park resources. Map unit ages are constrained by relative soil chronostratigraphy, vertebrate and invertebrate fossils, and materials collected for dating control using radiogenic, luminescence, and cosmogenic radionuclide techniques. Associated topical studies examined connections between geology, surface water, and vegetation distribution and restoration.
Evaluation of nutrient, alkalinity, and acid-neutralizing capacity stabilities in water samples analyzed by the U.S. Geological Survey National Water Quality Laboratory, 2023–24
The U.S. Geological Survey evaluated the stability of water-sample chemical analysis of nutrient, alkalinity, and acid-neutralizing capacity constituents with respect to the duration between sample collection and laboratory analysis, also known as the sample holding time. A study began in the spring of 2023 to evaluate the sample stability, between 2 and 180 days after sample collection, of the chemical properties and chemical constituents of alkalinity as calcium carbonate, filtered; acid-neutralizing capacity as calcium carbonate, unfiltered; total ammonia as nitrogen, filtered; total ammonia plus organic nitrogen as nitrogen, filtered and unfiltered; nitrite as nitrogen, filtered; nitrate plus nitrite as nitrogen, filtered; total nitrogen, filtered and unfiltered; orthophosphate as phosphorous, filtered; and total phosphorus as phosphorus (filtered and unfiltered) in water. Both surface water and groundwater matrices were represented. Sample instability varied by observed property and matrix; therefore, providing general guidance for sample holding time is not possible based on matrices alone. No correlations between field measurements of sample characteristics and sample instability were observed. Although observations for some properties indicate sample stability that exceeds the recognized U.S. Geological Survey National Water Quality Laboratory method holding times, this is not necessarily the case for matrices and seasonal characteristics that were not investigated. Based on the limited number of six sample sources used in this study, some patterns emerge for the 12 observed properties studied. Five observed properties generally indicate stability for as many as 180 days after sampling (total nitrogen as nitrogen, both filtered and unfiltered; orthophosphate as phosphorus, filtered; and phosphorus as phosphorus, both filtered and unfiltered). Other observed properties indicate stability for as many as 180 days for some matrices, but not for others. Finally, some observed properties indicate instability well before 180 days.
A spatial analysis of the groundwater emergence flood hazard in Long Island, New York and near coastal areas surrounding Long Island Sound in New York, Connecticut, and Rhode Island
Long Island, New York and near coastal areas surrounding Long Island Sound are densely populated and, like other coastal areas, are susceptible to flooding from several potential sources, including stormwater from precipitation events, tidal flooding and storm surge, and groundwater inundation or groundwater emergence flooding. The latter refers to the intersection of a rising water table with land surface or critical infrastructure. Many studies of flood drivers either neglect or only briefly discuss how shallow groundwater conditions may contribute to or exacerbate flood conditions. As part of a comprehensive study of compound flood hazards in the near coastal areas surrounding Long Island and Long Island Sound, a spatial analysis was completed, in cooperation with the Environmental Protection Agency’s Long Island Sound Study, using available regional datasets to characterize the potential hazard for groundwater emergence flooding. The approximately 3,100 square mile study area was subdivided into 11,407 900-meter by 900-meter (approximately 3,000-feet by 3,000-feet) grid cells, for the purposes of integrating the spatial datasets to calculate and map the groundwater emergence flood hazard. The depth to the water table, hydrologic soil groups, and National Land Cover Database were harmonized to the common grid. A groundwater emergence flood hazard rank was calculated for each grid cell for current average conditions following a set of rules accounting for the depth to the water table and the percent of area within each cell with slow infiltrating soils. A higher sea level position scenario was also calculated for the Long Island part of the study area. The calculated groundwater emergence flood hazard rank was reviewed in concert with the National Land Cover Data Base to identify developed areas and associated infrastructure that may be at risk to groundwater emergence flooding. Study results indicate that the groundwater emergence flood hazard is highest in coastal areas and near surface water where the water table is close to ground surface. Inland areas away from surface water bodies are not likely to be exposed to groundwater emergence flooding. For Long Island, under a scenario with higher sea level position, a greater groundwater emergence flood hazard is calculated in some locations closer to the coast and where land is submerged. Away from the coast and surface-water drainage, the groundwater emergence flood hazard is similar between the current average sea level condition and a higher sea level position scenario.