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At least 793 records · Page 44Linked to original sources

USGS2017

Coastal river plumes: Collisions and coalescence

Plumes of buoyant river water spread in the ocean from river mouths, and these plumes influence water quality, sediment dispersal, primary productivity, and circulation along the world’s coasts. Most investigations of river plumes have focused on large rivers in a coastal region, for which the physical spreading of the plume is assumed to be independent from the influence of other buoyant plumes. Here we provide new understanding of the spreading patterns of multiple plumes interacting along simplified coastal settings by investigating: (i) the relative likelihood of plume-to-plume interactions at different settings using geophysical scaling, (ii) the diversity of plume frontal collision types and the effects of these collisions on spreading patterns of plume waters using a two-dimensional hydrodynamic model, and (iii) the fundamental differences in plume spreading patterns between coasts with single and multiple rivers using a three-dimensional hydrodynamic model. Geophysical scaling suggests that coastal margins with numerous small rivers (watershed areas < 10,000 km 2 ), such as found along most active geologic coastal margins, were much more likely to have river plumes that collide and interact than coastal settings with large rivers (watershed areas > 100,000 km 2 ). When two plume fronts meet, several types of collision attributes were found, including refection, subduction and occlusion. We found that the relative differences in pre-collision plume densities and thicknesses strongly influenced the resulting collision types. The three-dimensional spreading of buoyant plumes was found to be influenced by the presence of additional rivers for all modeled scenarios, including those with and without Coriolis and wind. Combined, these results suggest that plume-to-plume interactions are common phenomena for coastal regions offshore of the world’s smaller rivers and for coastal settings with multiple river mouths in close proximity, and that the spreading and fate of river waters in these settings will be strongly influenced by these interactions. We conclude that new investigations are needed to characterize how plumes interact offshore of river mouths to better understand the transport and fate of terrestrial sources of pollution, nutrients and other materials in the ocean.

Progress in Oceanography↗

USGS2016

Sediment load and distribution in the lower Skagit River, Skagit County, Washington

The Skagit River delivers about 40 percent of all fluvial sediment that enters Puget Sound, influencing flood hazards in the Skagit lowlands, critically important estuarine habitat in the delta, and some of the most diverse and productive agriculture in western Washington. A total of 175 measurements of suspended-sediment load, made routinely from 1974 to 1993, and sporadically from 2006 to 2009, were used to develop and evaluate regression models of sediment transport (also known as “sediment-rating curves”) for estimating suspended-sediment load as a function of river discharge. Using a flow-range model and 75 years of daily discharge record (acquired from 1941 to 2015), the mean annual suspended-sediment load for the Skagit River near Mount Vernon, Washington, was estimated to be 2.5 teragrams (Tg, where 1 Tg = 1 million metric tons). The seasonal model indicates that 74 percent of the total annual suspended‑sediment load is delivered to Puget Sound during the winter storm season (from October through March), but also indicates that discharge is a poor surrogate for suspended‑sediment concentration (SSC) during the summer low-flow season. Sediment-rating curves developed for different time periods revealed that the regression model slope of the SSC-discharge relation increased 66 percent between the periods of 1974–76 and 2006–09 when suspended-sediment samples were collected, implying that changes in sediment supply, channel hydraulics, and (or) basin hydrology occurred between the two time intervals. In the relatively wet water year 2007 (October 1, 2006, through September 30, 2007), an automated sampler was used to collect daily samples of suspended sediment from which an annual load of 4.5 Tg was calculated, dominated by a single large flood event that contributed 1.8 Tg, or 40 percent of the total. In comparison, the annual load calculated for water year 2007 using the preferred flow-range model was 4.8 Tg (+6.7 percent), in close agreement with the measured value. Particle size affects sediment transport, fate and distribution across watersheds, and therefore is important for predicting how coastal environments, particularly deltas and beaches, will respond to changes in climate and sea-level. Particle-size analysis of winter storm samples indicated that about one-half of the suspended-sediment load consisted of fines (that is, silt- and clay-sized particles smaller than 0.0625 mm in diameter), and the remainder consisted of mostly fine- to medium-sized sand (0.0625–0.5 mm), whereas bedload during winter storm flows (about 1–3 percent of total sediment load) was predominantly composed of medium to coarse sand (0.25–1 mm). A continuous turbidity record from the Anacortes Water Treatment Plant (water years 1999–2013), used as a surrogate for the concentration of fines ( R 2 = 0.93, p = 4.2E-10, n = 17), confirms that about one-half of the mean annual suspended-sediment load is composed of fines. The distribution of flow through the delta distributaries (that is, the channels into which the main stem splits as it approaches the delta) is dynamic, with twice as much flow through the North Fork of the Skagit River relative to the South Fork during low-flow conditions, and close to equal flows in the two channels during high-flow conditions. Turbidity, monitored at several locations in the lower river in spring 2009, was essentially uniform among sites, indicating that fines are well mixed in the lower Skagit River system (defined as the Skagit River and all its distributaries downstream of the Mount Vernon streamgage). A strong relation ( R 2 = 0.95, p = 3.2E-14, n = 21; linear regression) between the concentration of fines and turbidity measured at various locations in summer 2009 indicates that turbidity is an effective surrogate for the concentration of fines, independent of location in the river, under naturally well-mixed fluvial conditions. This relation is especially useful for monitoring suspended sediment in western Washington rivers that are seasonally dominated by glacier meltwater because glacial melting typically produces suspended-sediment concentrations that are not well correlated with discharge. These results provide a comprehensive set of tools to estimate sediment delivery and delta responses of interest to scientists and resource managers including decision-makers examining options for flood hazard mitigation, estuary restoration, and climate change adaptation.

Washington↗

USGS2022

River floodplain abandonment and channel deepening coincide with the onset of clear-cut logging in a coastal California redwood forest

Changes in both land use and climate can alter the balance of transport capacity and sediment supply in rivers. Hence, the primary driver of recent incision or aggradation in alluvial channels is often unclear. The San Lorenzo River on the central coast of California is one location where both climate and land use—specifically, clear-cut forestry of coastal redwoods—could explain recent vertical incision and floodplain abandonment. At our field site on the San Lorenzo, we estimate the magnitude of recent incision using both the ratio of bankfull to critical Shields numbers ( τ bf * / τ c * "> 𝜏 ∗ 𝑏𝑓 / 𝜏 ∗ 𝑐 ) and the geomorphically effective discharge, calculated from historical gauge data. The Shields number ratio suggests that the normalized bankfull stress of the San Lorenzo River is in the upper 1–2% of West Coast rivers, and the effective discharge corresponds to flow depths ~2–4 m below current bankfull conditions. Radiocarbon ages from detrital charcoal in floodplain sediment reveal active floodplain deposition during the 1600s and possibly into the 1800s, constraining the timing of incision to the last few centuries. Multiple hanging tributaries above the mainstem San Lorenzo River, along with patterns in vegetation on terrace surfaces, corroborate our estimates of the magnitude and timing of incision. Taken together, our findings suggest that floodplain abandonment in this reach was mainly due to methods employed during logging that increased shear stress on the channel bed and reduced sediment storage capacity. We suggest that direct channel modifications in rivers can counterbalance increases in sediment delivery due to clear-cutting, resulting in channel incision rather than aggradation. Today, a young, lower surface appears to be forming adjacent to the San Lorenzo River, which we interpret as an incipient floodplain that is in equilibrium with modern sediment supply and transport capacity.

California↗

USGS2002

Subsurface controls on historical subsidence rates and associated wetland loss in southcentral Louisiana

Two regional releveling profiles and six tide gauges provide a basis for evaluating recent rates of delta plain subsidence in southcentral Louisiana . Analyses of these records demonstrate close correlations among highest historical rates of subsidence , rapid wetland losses, large volume hydrocarbon production, and probable reactivation of deep subsurface faults. Other researchers have demonstrated that the highest geological subsidence rates of the Mississippi delta plain (<3 mm/yr) correspond closely to the thickest Holocene sediments that fill the underlying incised valley. Within that geologic framework, highest historical subsidence rates (as much as 23 mm/yr) correspond to surface projections of the reactivated Lake Hatch and Golden Meadow fault zones and to individual oil and gas fields. The initial acceleration and subsequent decline in rates of wetland loss in southcentral Louisiana are attributed partly to increased and then possibly decreased rates of subsidence that were related to increased and then decreased rates of fluid production. Decreases in subsurface pore pressures associated with gas production were so large that the state of stress was altered and critically stressed faults were likely reactivated. Subsidence rates in coastal Louisiana associated with natural compaction and dewatering of Holocene deltaic sediments should decrease with time. Therefore historical rates of delta plain subsidence that accelerate and typically exceed geological subsidence rates are most likely influenced by anthropogenic activities, such as subsurface fluid extraction.

Louisiana↗

USGS2015

Tracing the cycling and fate of the explosive 2,4,6-trinitrotoluene in coastal marine systems with a stable isotopic tracer, 15N-[TNT]

2,4,6-Trinitrotoluene (TNT) has been used as a military explosive for over a hundred years. Contamination concerns have arisen as a result of manufacturing and use on a large scale; however, despite decades of work addressing TNT contamination in the environment, its fate in marine ecosystems is not fully resolved. Here we examine the cycling and fate of TNT in the coastal marine systems by spiking a marine mesocosm containing seawater, sediments, and macrobiota with isotopically labeled TNT ( 15 N-[TNT]), simultaneously monitoring removal, transformation, mineralization, sorption, and biological uptake over a period of 16 days. TNT degradation was rapid, and we observed accumulation of reduced transformation products dissolved in the water column and in pore waters, sorbed to sediments and suspended particulate matter (SPM), and in the tissues of macrobiota. Bulk δ 15 N analysis of sediments, SPM, and tissues revealed large quantities of 15 N beyond that accounted for in identifiable derivatives. TNT-derived N was also found in the dissolved inorganic N (DIN) pool. Using multivariate statistical analysis and a 15 N mass balance approach, we identify the major transformation pathways of TNT, including the deamination of reduced TNT derivatives, potentially promoted by sorption to SPM and oxic surface sediments.

Environmental Science & Technology↗

USGS2017

Will fluctuations in salt marsh–mangrove dominance alter vulnerability of a subtropical wetland to sea‐level rise?

To avoid submergence during sea-level rise, coastal wetlands build soil surfaces vertically through accumulation of inorganic sediment and organic matter. At climatic boundaries where mangroves are expanding and replacing salt marsh, wetland capacity to respond to sea-level rise may change. To compare how well mangroves and salt marshes accommodate sea-level rise, we conducted a manipulative field experiment in a subtropical plant community in the subsiding Mississippi River Delta. Experimental plots were established in spatially equivalent positions along creek banks in monospecific stands of Spartina alterniflora (smooth cordgrass) or Avicennia germinans (black mangrove) and in mixed stands containing both species. To examine the effect of disturbance on elevation dynamics, vegetation in half of the plots was subjected to freezing (mangrove) or wrack burial (salt marsh), which caused shoot mortality. Vertical soil development was monitored for 6 years with the surface elevation table-marker horizon system. Comparison of land movement with relative sea-level rise showed that this plant community was experiencing an elevation deficit (i.e., sea level was rising faster than the wetland was building vertically) and was relying on elevation capital (i.e., relative position in the tidal frame) to survive. Although Avicennia plots had more elevation capital, suggesting longer survival, than Spartina or mixed plots, vegetation type had no effect on rates of accretion, vertical movement in root and sub-root zones, or net elevation change. Thus, these salt marsh and mangrove assemblages were accreting sediment and building vertically at equivalent rates. Small-scale disturbance of the plant canopy also had no effect on elevation trajectories—contrary to work in peat-forming wetlands showing elevation responses to changes in plant productivity. The findings indicate that in this deltaic setting with strong physical influences controlling elevation (sediment accretion, subsidence), mangrove replacement of salt marsh, with or without disturbance, will not necessarily alter vulnerability to sea-level rise.

Louisiana↗

USGS1982

Dynamic ice-wallow relief of northern Alaska's nearshore

Contour maps with 0.5-m depth interval were prepared for a small area seaward of Reindeer Island, a barrier island in the Beaufort Sea, Alaska, by repeated surveys with very accurate navigation and very close trackline spacing. The maps reveal numerous closed depressions and mounds about 50 to 100 m in diameter and 2 to 3 m in relief, presumably related to grounded ice floes common in the area year round. Some of the features were obliterated over the course of three seasons while new ones formed. Although the depressions resemble kettles, they are formed by very different mechanisms. We believe that these bedforms represent erosion and deposition caused by: a) intensified flow around stationary ice floes serving as obstacles and b) pulsating currents generated by vertical oscillations or rocking motions of grounded floes in a seaway. Because sediment transport occurs around the ice, not where it directly touches the sea floor, the depressions are much larger than the base of the acting floes. Ice-wallow bedforms, although not found everywhere, are characteristic of arctic nearshore regions with non-cohesive sediments, and most likely occur in other ice-stressed coastal environments in differing degrees. The bedforms studied here are highly active and must be considered in planning nearshore construction activities.

Journal of Sedimentary Petrology↗

USGS1998

Herbivore effects on plant species density at varying productivity levels

Artificially increasing primary productivity decreases plant species richness in many habitats; herbivory may affect this outcome, but it has rarely been directly addressed in fertilization studies. This experiment was conducted in two Louisiana coastal marshes to examine the effects of nutrient enrichment and sediment addition on herbaceous plant communities with and without vertebrate herbivory. After three growing seasons, fertilization increased community biomass in all plots, but decreased species density (the number of species per unit area) only in plots protected from herbivory. Herbivory alone did not alter species density at either site. At the brackish marsh, herbivory caused a shift in dominance in the fertilized plots from a species that is considered the competitive dominant, but is selectively eaten, to another less palatable species. At the fresh marsh, increased dead biomass in the absence of herbivory and in the fertilized plots probably contributed to the decrease in species density, perhaps by limiting germination of annuals. Our results support those of other fertilization studies in which plant species density decreases with increased biomass, but only in those plots protected from herbivory.

Louisiana↗

USGS2011

From ridge to reef—linking erosion and changing watersheds to impacts on the coral reef ecosystems of Hawai‘i and the Pacific Ocean

Coral reef ecosystems are threatened by unprecedented watershed changes in the United States and worldwide. These ecosystems sustain fishing and tourism industries essential to the economic survival of many communities. Sediment, nutrients, and pollutants from watersheds are increasingly transported to coastal waters, where these contaminants damage corals. Although pollution from watersheds is one of many factors threatening coral survival, it is one that local people can have a profound influence on. U.S. Geological Survey scientists are using mapping, monitoring, and computer modeling to better forecast the effects of watershed changes on reef health. Working with communities in Hawai‘i and on other U.S. islands in the Pacific, they are helping to provide the science needed to make informed decisions on watershed and coral reef management.

Hawai'i↗

USGS2013

Tracking and forecasting the Nation’s water quality - Priorities and strategies for 2013-2023

Water-quality issues facing the Nation are growing in number and complexity, and solutions are becoming more challenging and costly. Key factors that affect the quality of our drinking water supplies and ecosystem health include contaminants of human and natural origin in streams and groundwater; excess nutrients and sediment; alteration of natural streamflow; eutrophication of lakes, reservoirs, and coastal estuaries; and changes in surface and groundwater quality associated with changes in climate, land and water use, and management practices. Tracking and forecasting the Nation's water quality in the face of these and other pressing water-quality issues are important goals for 2013-2023, the third decade of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. In consultation with stakeholders and the National Research Council, a new strategic Science Plan has been developed that describes a strategy for building upon and enhancing assessment of the Nation's freshwater quality and aquatic ecosystems. The plan continues strategies that have been central to the NAWQA program's long-term success, but it also makes adjustments to the monitoring and modeling approaches NAWQA will use to address critical data and science information needs identified by stakeholders. This fact sheet describes surface-water and groundwater monitoring and modeling activities that will start in fiscal year 2013. It also provides examples of the types of data and information products planned for the next decade, including (1) restored monitoring for reliable and timely status and trend assessments, (2) maps and models that show the distribution of selected contaminants (such as atrazine, nitrate, and arsenic) in streams and aquifers, and (3) Web-based modeling tools that allow managers to evaluate how water quality may change in response to different scenarios of population growth, climate change, or land-use management.

Fact Sheet↗

USGS2012

Shipboard surveys track magnetic sources in marine sediments--geophysical studies of the Stono and North Edisto Inlets near Charleston, South Carolina

Magnetic field data are traditionally used to analyze igneous and metamorphic rocks, but recent efforts have shown that magnetic sources within sediments may be detectable, suggesting new applications for high-resolution magnetic field surveys. Candidates for sedimentary sources include heavy mineral sand concentrations rich in magnetite or hematite, alteration-induced glauconite, or biogenic magnetite. Magnetic field surveys can be used to map the distributions of such sources with much denser and more widespread coverage than possible by sampling. These data can then provide constraints on the composition history of local sediments. Mapping such sediments requires the sensor to be relatively close to the source, and filtering approaches may be needed to distinguish signals from both system noise and deeper basement features. Marine geophysical surveys conducted in July, 2010, over the Stono and North Edisto River inlets and their riverine inputs south of Charleston, South Carolina, showed 10- to 40-m-wide, 1- to 6-nT magnetic anomalies associated with shallow, sand-covered seabed. These anomalies are distinct from system noise but are too narrow to represent basement features. The anomalies are present mostly in shallow areas where river sediments originating from upland areas enter the inlets. Surface grab samples from the North Edisto River contain trace amounts of heavy mineral sediments including hematite, maghemite, ilmenite, and magnetite, as well as garnet, epidote, zircon, and rutile. Previous stream sediment analyses show enhanced titanium over much of the Atlantic Coastal Plain. The combined data suggest that the anomalies are generated by titanium- and iron-rich heavy mineral sands ultimately originating from the Piedmont and Blue Ridge provinces, which are then reworked and concentrated by tidal currents.

South Carolina↗

USGS1975

Tectonic framework of petroliferous rocks in Alaska

Alaska, comprising 3.6 X 10 6 sq km (about 28 percent) of the land, shelf, and upper continental slope of the United States, has been estimated by the U.S. Geological Survey (1974) to contain about 25 percent of the Nation's petroleum resources. Some 11 billion barrels of petroleum liquids and 31 trillion cubic feet of natural gas have been announced as discovered to date. In northern Alaska, Paleozoic and Mesozoic shelf and slope deposits of the Brooks Range orogen were thrust relatively northward over the depressed south margin of the Paleozoic and Mesozoic Arctic platform, upon which a foredeep (the Colville geosyncline) developed in earliest Cretaceous time. Detritus from the Brooks Range filled the foredeep and pro-graded northwest and northeast to fill the Cretaceous and Tertiary North Chukchi and Umiat-Camden basins and form the Beaufort shelf. In southern Alaska, a series of arc-trench systems developed on oceanic rocks during the Jurassic and Cretaceous. Between the arcs and the metamorphic (continental) terranes of east-central and northern Alaska, large back-arc and arc-trench gap basins received thick volcanic and detrital deposits. These deposits were extensively deformed and disrupted by mid-Jurassic to Tertiary plutonism, Laramide oroclinal bending, wrench faulting, and arc-related compression. The Laramide events 'continentalized' the late Mesozoic back-arc basin deposits and welded them to the older continental terranes to the north and east. Subsequent sedimentation was localized and nonmarine except in onshore and offshore coastal basins, where thick mixed marine and nonmarine sections were deposited. The Aleutian arc and associated Queen Charlotte transform fault system have dominated structural and depositional patterns in southern Alaska since the early Cenozoic. The largest petroleum reserves in Alaska (the Prudhoe Bay and associated fields) and the best prospects for additional large discoveries are in northern Alaska, where an extensive terrane is underlain by Upper Paleozoic to Tertiary carbonate and shelf, slope and delta clastic deposits. The pre-Tertiary back-arc and arc-trench gap basins in southern and interior Alaska are too intensely deformed or too low in porosity (because of diagenetic mobilization of labile constituents) to offer more than modest local prospects. The Tertiary coastal basins do, however, offer large tracts of thick marine and nonmarine clastic rocks and in some areas many large folds to exploration. Such basins are known to be petroliferous on Bristol Bay and the Gulf of Alaska and to contain major accumulations of oil and gas at Cook Inlet, but they are relatively little explored.

Alaska↗

USGS2006

Geohydrology of the lower Apalachicola-Chattahoochee-Flint River basin, southwestern Georgia, northwestern Florida, and southeastern Alabama

The lower Apalachicola-Chattahoochee-Flint (ACF) River Basin contains about 4,600 square miles of karstic and fluvial plains and nearly 100,000 cubic miles of predominantly karst limestone connected hydraulically to the principal rivers and lakes in the Coastal Plain of southwestern Georgia, northwestern Florida, and southwestern Alabama. Sediments of late-middle Eocene to Holocene in hydraulic connection with lakes, streams, and land surface comprise the surficial aquifer system, upper semiconfining unit, Upper Floridan aquifer, and lower semiconfining unit and contribute to the exchange of ground water and surface water in the stream-lake-aquifer flow system. Karst processes, hydraulic properties, and stratigraphic relations limit ground-water and surface-water interaction to the following hydrologic units of the stream-lake-aquifer flow system: the surficial aquifer system, upper semiconfining unit, Upper Floridan aquifer, and lower confining unit. Geologic units corresponding to these hydrologic units are, in ascending order: Lisbon Formation; Clinchfield Sand; Ocala, Marianna, Suwannee, and Tampa Limestones; Hawthorn Group; undifferentiated overburden (residuum); and terrace and undifferentiated (surficial) deposits. Similarities in hydraulic properties and direct or indirect interaction with surface water allow grouping sediments within these geologic units into the aforementioned hydrologic units, which transcend time-stratigraphic classifications and define the geohydrologic framework for the lower ACF River Basin. The low water-transmitting properties of the lower confining unit, principally the Lisbon Formation, allow it to act as a nearly impermeable base to the stream-lake-aquifer flow system. Hydraulic connection of the surficial aquifer system with surface water and the Upper Floridan aquifer is direct where sandy deposits overlie the limestone, or indirect where fluvial deposits overlie clayey limestone residuum. The water level in perched zones within the surficial aquifer system fluctuates independently of water-level changes in the underlying aquifer, adjacent streams, or lakes. Where the surficial aquifer system is connected with surface water and the Upper Floridan aquifer, water-table fluctuations parallel those in adjacent streams or the underlying aquifer. More...

Alabama, Florida, Georgia↗

USGS2009

Latitudinal trends in Spartina alterniflora productivity and the response of coastal marshes to global change

Marshes worldwide are actively degrading in response to increased sea level rise rates and reduced sediment delivery, though the growth rate of vegetation plays a critical role in determining their stability. We have compiled 56 measurements of above-ground annual productivity for Spartina alterniflora, the dominant macrophyte in North American coastal wetlands. Our compilation indicates a significant latitudinal gradient in productivity, which we interpret to be determined primarily by temperature and/or the length of growing season. Simple linear regression yields a 27 g m-2 yr -1 increase in productivity with an increase of mean annual temperature by one degree C. If temperatures warm 2?4 C over the next century, then marsh productivity may increase by 10?40%, though physiological research suggests that increases in the north could potentially be offset by some decreases in the south. This increase in productivity is roughly equivalent to estimates of marsh lost due to future sea level change. If a warming-induced stimulation of vegetation growth will enhance vertical accretion and limit erosion, then the combined effects of global change may be to increase the total productivity and ecosystem services of tidal wetlands, at least in Northern latitudes.

Global Change Biology↗

USGS2014

Evaluating the effects of land use on headwater wetland amphibian assemblages in coastal Alabama

Anthropogenic land use is known to impact aquatic ecosystems in several ways, including increased frequency and intensity of floods, stream channel incision, sedimentation, and loss of microtopography. Amphibians are susceptible to changes in wetland and surrounding habitats. This study evaluated amphibian assemblages of fifteen headwater slope wetlands in coastal Alabama across a gradient of land uses. Amphibians were surveyed on a seasonal basis and land use was delineated within wetland watersheds and within a 200-m buffer surrounding each wetland. Amphibian presence/absence and land use data were used to develop species occupancy models. Both urban and agricultural land use were shown to influence amphibian occurrence. Species richness ranged from five to ten species across sites; however, five species only occurred in wetlands surrounded by forested lands. Many species were detected more frequently on these wetlands compared to wetlands surrounded by urban or mixed land uses. Occupancy models showed Acris gryllus was negatively associated with the amount of agriculture within a buffer around the wetland. Hyla squirella , Lithobates clamitans , and L. sphenocephalus were positively associated with agricultural land within a watershed. Anaxyrus terrestris and the non-native Eleutherodactylus planirostris were positively associated with the amount of impervious surface area within the wetland buffer.

Alabama↗

USGS2020

Degradation of RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) in contrasting coastal marine habitats: Subtidal non-vegetated (sand), subtidal vegetated (silt/eel grass), and intertidal marsh

Hundreds of explosive-contaminated marine sites exist globally, many of which contain the common munitions constituent hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Quantitative information about RDX transformation in coastal ecosystems is essential for management of many of these sites. Isotopically labelled RDX containing 15 N in all 3 nitro groups was used to track the fate of RDX in three coastal ecosystem types. Flow-through mesocosms representing subtidal vegetated (silt/eel grass), subtidal non-vegetated (sand) and intertidal marsh ecosystems were continuously loaded with isotopically labelled RDX for 16–17 days. Sediment, pore-water and overlying surface water were analyzed to determine the distribution of RDX, nitroso-triazine transformation products (NXs) and nitrogen containing complete mineralization products, including ammonium, nitrate+nitrite, nitrous oxide and nitrogen gas. The marsh, silt, and sand ecotypes transformed 94%, 90% and 76% of supplied RDX, respectively. Total dissolved NXs accounted for 2%–4% of the transformed 15 N-RDX. The majority of RDX transformation in the water column was by mineralization to inorganic N (dissolved and evaded; 64%–78% of transformed 15 N-RDX). RDX was mineralized primarily to N 2 O (62–74% of transformed 15 N-RDX) and secondarily to N 2 (1–2% of transformed 15 N-RDX) which exchanged with the atmosphere. Transformation of RDX was favored in carbon-rich lower redox potential sediments of the silt and marsh mesocosms where anaerobic processes of iron and sulfate reduction were most prevalent. RDX was most persistent in the carbon-poor sand mesocosm. Partitioning of 15 N derived from RDX onto sediment and suspended particulates was negligible in the overall mass balance of RDX transformation (2%–3% of transformed 15 N-RDX). The fraction of 15 N derived from RDX that was sorbed or assimilated in sediment was largest in the marsh mesocosm (most organic carbon), and smallest in the sand mesocosm (largest grain size and least organic carbon). Sediment redox conditions and available organic carbon stores affect the fate of RDX in different coastal marine habitats.

Connecticut, New York↗

USGS2014

Sediment data collected in 2010 from Cat Island, Mississippi

Scientists from the U.S. Geological Survey, St. Petersburg Coastal and Marine Science Center, in collaboration with the U.S. Army Corps of Engineers, conducted geophysical and sedimentological surveys in 2010 around Cat Island, Mississippi, which is the westernmost island in the Mississippi-Alabama barrier island chain. The objective of the study was to understand the geologic evolution of Cat Island relative to other barrier islands in the northern Gulf of Mexico by identifying relationships between the geologic history, present day morphology, and sediment distribution. This data series serves as an archive of terrestrial and marine sediment vibracores collected August 4-6 and October 20-22, 2010, respectively. Geographic information system data products include marine and terrestrial core locations and 2007 shoreline data. Additional files include marine and terrestrial core description logs, core photos, results of sediment grain-size analyses, optically stimulated luminescence dating and carbon-14 dating locations and results, Field Activity Collection System logs, and formal Federal Geographic Data Committee metadata.

Mississippi↗

USGS2018

A Holocene record of ocean productivity and upwelling from the northern California continental slope

The Holocene upwelling history of the northern California continental slope is examined using the high-resolution record of TN062-O550 (40.9°N, 124.6°W, 550 m water depth). This 7-m-long marine sediment core spans the last ∼7500 years, and we use it to test the hypothesis that marine productivity in the California Current System (CCS) driven by coastal upwelling has co-varied with Holocene millennial-scale warm intervals. A combination of biogenic sediment concentrations (opal, total organic C, and total N), stable isotopes (organic matter δ 13 C and bulk sedimentary δ 15 N), and key microfossil indicators of upwelling were used to test this hypothesis. The record of biogenic accumulation in TN062-O550 shows considerable Holocene variability despite being located within 50 km of the mouth of the Eel River, which is one of the largest sources of terrigenous sediment to the Northeast Pacific Ocean margin. A key time interval beginning at ∼2900 calibrated years before present (cal yr BP) indicates the onset of modern upwelling in the CCS, and this period also corresponds to the most intense period of upwelling in the last 7500 years. When these results are placed into a regional CCS context during the Holocene, it was found that the timing of upwelling intensification at TN062-O550 corresponds closely to that seen at nearby ODP Site 1019, as well as in the Santa Barbara Basin of southern California. Other CCS records with less refined age control show similar results, which suggest late Holocene upwelling intensification may be synchronous throughout the CCS. Based on the strong correspondence between the alkenone sea surface temperature record at ODP Site 1019 and the onset of late Holocene upwelling in northern California, we suggest that CCS warming may be conducive to upwelling intensification, though future changes are unclear as the mechanisms forcing SST variability may differ.

California↗