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At least 793 records · Page 44Linked to original sources

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps and human health hazards associated with uranium exploration and mining, Red, White, and Fry Canyons, southeastern Utah, 2007

During May, June, and July 2007, 58 solid-phase samples were collected from abandoned uranium mine waste dumps, background sites, and adjacent streambeds in Red, White, and Fry Canyons in southeastern Utah. The objectives of this sampling program were to (1) assess the nonpoint-source chemical loading potential to ephemeral and perennial drainage basins from uranium waste dumps and (2) assess potential effects on human health due to recreational activities on and around uranium waste dumps on Bureau of Land Management property. Uranium waste-dump samples were collected using solid-phase sampling protocols. After collection, solid-phase samples were homogenized and extracted in the laboratory using a leaching procedure. Filtered (0.45 micron) water samples were obtained from the field leaching procedure and were analyzed for major and trace elements at the Inductively Coupled Plasma-Mass Spectrometry Metals Analysis Laboratory at the University of Utah. A subset of the solid-phase samples also were digested with strong acids and analyzed for major ions and trace elements at the U.S. Geological Survey Geologic Division Laboratory in Denver, Colorado. For the initial ranking of chemical loading potential for uranium waste dumps, results of leachate analyses were compared with existing aquatic-life and drinking-water-quality standards. To assess potential effects on human health, solid-phase digestion values for uranium were compared to soil screening levels (SSL) computed using the computer model RESRAD 6.5 for a probable concentration of radium. One or more chemical constituents exceeded aquatic life and drinking-water-quality standards in approximately 64 percent (29/45) of the leachate samples extracted from uranium waste dumps. Most of the uranium waste dump sites with elevated trace-element concentrations in leachates were located in Red Canyon. Approximately 69 percent (31/45) of the strong acid digestible soil concentration values were greater than a calculated SSL. Uranium waste dump sites with elevated leachate and total digestible concentrations may need to be further investigated to determine the most appropriate remediation method.

Utah↗

Assessment of nonpoint source chemical loading potential to watersheds containing uranium waste dumps associated with uranium exploration and mining, San Rafael Swell, Utah

During July and August of 2006, 117 solid-phase samples were collected from abandoned uranium waste dumps, geologic background sites, and adjacent streambeds in the San Rafael Swell, in southeastern Utah. The objective of this sampling program was to assess the nonpoint source chemical loading potential to ephemeral and perennial watersheds from uranium waste dumps on Bureau of Land Management property. Uranium waste dump samples were collected using solid-phase sampling protocols. After collection, solid-phase samples were homogenized and extracted in the laboratory using a field leaching procedure. Filtered (0.45 micron) water samples were obtained from the field leaching procedure and were analyzed for Ag, As, Ba, Be, Cd, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, U, V, and Zn at the Inductively Coupled Plasma-Mass Spectrometry Metals Analysis Laboratory at the University of Utah, Salt Lake City, Utah and for Hg at the U.S. Geological Survey National Water Quality Laboratory, Denver, Colorado. For the initial ranking of chemical loading potential of suspect uranium waste dumps, leachate analyses were compared with existing aquatic life and drinking-water-quality standards and the ratio of samples that exceeded standards to the total number of samples was determined for each element having a water-quality standard for aquatic life and drinking-water. Approximately 56 percent (48/85) of the leachate samples extracted from uranium waste dumps had one or more chemical constituents that exceeded aquatic life and drinking-water-quality standards. Most of the uranium waste dump sites with elevated trace-element concentrations in leachates were along Reds Canyon Road between Tomsich Butte and Family Butte. Twelve of the uranium waste dump sites with elevated trace-element concentrations in leachates contained three or more constituents that exceeded drinking-water-quality standards. Eighteen of the uranium waste dump sites had three or more constituents that exceeded trace-element concentrations for aquatic life water-quality standards. The proximity of the uranium waste dumps in the Tomsich Butte area near Muddy Creek, coupled with the elevated concentration of trace elements, increases the offsite impact potential to water resources. Future assessment and remediation priority of these areas may be done by using GIS-based risk-mapping techniques, such as Sensitive Catchment Integrated Mapping and Analysis Project.

Utah↗

Recommendations for an orientation geochemical survey of the Avissawella quadrangle, Ceylon

In consultation with officers of the Geological Survey Department of Ceylon, Colombo, September 23 to October 6, 1970, recommendations have been drawn up for an orientation geochemical survey of the Avissawella quadrangle, Ceylon. The area of the quadrangle is particularly suited for this study because diverse geologic and geomorphic features are found within the quadrangle, and the three main agricultural crops of Ceylon (rice, rubber, and tea) are cultivated in the area of the quadrangle. The geology of the quadrangle is published. The recommendations propose the staged acquisition of basic data on field and laboratory techniques suitable for use in an area of heavy rainfall, deep weathering, varied topography, where the valleys are commonly planted in rice, and where geochemical methods have not been previously evaluated. Classic methods of semiquantitative colorimetric, spectrographic, and atomic absorption analysis are recommended to determine selected minor elements in the magnetic and non-magnetic fractions of concentrates from fluvial gravel and from silt and clay, and in the minus 80-meshfraction of silt and clay. It is recommended that the mineralcomposition of the non-magnetic fractions of the concentrates be estimated, and the presence of radioactive and flourescent mineral species be determined. It is recommended that suitable maps be prepared to show these chemical and mineralogical data. These maps will be compared with the geologic map of the Avissawella quadrangle, and with each other, to permit interpretation of the effects of geologic units, contacts, structures, and geomorphology on the distribution of detrital minerals and of minor elements in various sample media. The main purpose of the orientation survey is to determine which samplemedia and which methods of analysis are most effectivefor geochemical reconnaissance in Ceylon. Unsuitable media andmethods will not be used in work in other quadrangles. The role ofagriculture contamination and its effect on the results of geochemicalexploration would be determined. The spacing of samples would beevaluated to determine the optimum interval for reconnaissance inCeylon. Prospecting for gemstones could be conducted on a scientific basis if pathfinder minerals for precious gems can be identified in concentrates. Therefore, it is recommended that old records on gem-mining in the Avissawella area be plotted and compared with the distribution of minerals in concentrates from the Avissawella sample net. These data, in turn, would be interpreted with the geology and geomorphology of the quadrangle. Test pits would be sunk in unexplored areas indicated by the orientation survey, and the results evaluated for applicability to the exploration for gemstones. It is recommended that the results of the Avissawella orientation geochemical survey be thoroughly evaluated before further similar work is undertaken. If the appraisal of results is favorable, further work should then be undertaken in selected quadrangles using as simplified a total procedure as is consistent with the achievement of desired results.

Open-File Report↗

Applications of factor analysis in study of chemistry of groundwater quality, Mojave River Valley, California

Factor analysis is applied to results of chemical analyses of 103 water samples from wells in the Upper and Middle Mojave River valley, San Bernardino County, California. Chemical analyses showed that there are three principal chemical types of water, calcium bicarbonate, sodium sulfate, and sodium chloride, as well as many mixtures of the three. Data were studied by factor analysis to learn the relative importance of each principal ion in determining the variations among the samples, and to examine the possibility of chemical equilibrium between aqueous and solid phases in the aquifers. Most of the covariance in the system may be accounted for by variances of Ca +2 , Mg +2 , Na +1 , SO 4 −2 , and Cl −1 . There is almost identical loading on the constituents Na +1 and Cl −1 . The variance in chemical composition of the hydrochemical system is governed largely by sources of sodium chloride. None of the components is controlled by equilibrium between ions in the water and minerals in the aquifers. Concentrations of NO 3 −1 and F −1 vary independently of other constituents. Geographic distribution of statistical loadings of the principal constituents at individual wells does not reveal sources of the constituents, which must be deduced from geologic and hydrologic evidence. Factor analysis, however, furnished the critical information on chemical relationships basic to the deduction.

California↗

Chemical Data for Detailed Studies of Irrigation Drainage in the Salton Sea Area, California, 1995?2001

The primary purpose of this report is to present all chemical data from the Salton Sea area collected by the U.S. Geological Survey between 1995 and 2001. The data were collected primarily for the Department of the Interior's National Irrigation Water Quality Program (NIWQP). The report also contains a brief summary and citation to investigations done for the NIWQP between 1992 and 1995. The NIWQP began studies in the Salton Sea area in 1986 to evaluate effects on the environment from potential toxins, especially selenium, in irrigation-induced drainage. This data report is a companion to several reports published from the earlier studies and to interpretive publications that make use of historical and recent data from this area. Data reported herein are from five collection studies. Water, bottom material, and suspended sediment collected in 1995-96 from the New River, the lower Colorado River, and the All-American Canal were analyzed for elements, semi-volatile (extractable) organic compounds, and organochlorine compounds. Sufficient suspended sediment for chemical analyses was obtained by tangential-flow filtration. A grab sample of surficial bottom sediment collected from near the deepest part of the Salton Sea in 1996 was analyzed for 44 elements and organic and inorganic carbon. High selenium concentration confirmed the effective transfer (sequestration) of selenium into the bottom sediment. Similar grab samples were collected 2 years later (1998) from 11 locations in the Salton Sea and analyzed for elements, as before, and also for nutrients, organochlorine compounds, and polycyclic aromatic hydrocarbons. Nutrients were measured in bottom water, and water-column profiles were obtained for pH, conductance, temperature, and dissolved oxygen. Element and nutrient concentrations were obtained in 1999 from cores at 2 of the above 11 sites, in the north subbasin of the Salton Sea. The most-recent study reported herein was done in 2001 and contains element data on suspended material isolated by continuous-flow centrifugation on samples collected in transects extending out from the Whitewater, the Alamo, and the New Rivers into the Salton Sea. Chemical data on suspended sediment and bottom material from tributory rivers and the Salton Sea itself show that many insoluble constituents, including selenium and DDE, are concentrated in the fine-grained, organic- and carbonate-rich bottom sediment from deep areas near the center of the Salton Sea. Data also show that selenium and arsenic are markedly enriched in seston (plankton, partially-degraded algal detritus, and mineral matter that compose suspended particulates in the lake) collected just below the water surface in the Salton Sea. This result indicates that bio-concentration in primary producers in the water column provides an important pathway whereby high selenium residues accumulate in fish and fish-eating birds at the Salton Sea.

Scientific Investigations Report↗

Selected Physical, Chemical, and Biological Data for 30 Urbanizing Streams in the North Carolina Piedmont Ecoregion, 2002-2003

This report provides summarized physical, chemical, and biological data collected during a study of the effects of urbanization on stream ecosystems as part of the U.S. Geological Survey's National Water-Quality Assessment study. The purpose of this study was to examine differences in biological, chemical, and physical characteristics of streams across a gradient of urban intensity. Thirty sites were selected along an urbanization gradient that represents conditions in the North Carolina Piedmont ecoregion, including the cities of Raleigh, Durham, Cary, Greensboro, Winston-Salem, High Point, Asheboro, and Oxford. Data collected included streamflow variability, stream temperature, instream chemistry, instream aquatic habitat, and collections of the algal, macroinvertebrate, and fish communities. In addition, ancillary data describing land use, socioeconomic conditions, and urban infrastructure were compiled for each basin using a geographic information system analysis. All data were processed and summarized for analytical use and are presented in downloadable data tables, along with the methods of data collection and processing.

North Carolina↗

Gaining the necessary geologic, hydrologic, and geochemical understanding for additional brackish groundwater development, coastal San Diego, California, USA

Local water agencies and the United States Geological Survey are using a combination of techniques to better understand the scant freshwater resources and the much more abundant brackish resources in coastal San Diego, California, USA. Techniques include installation of multiple-depth monitoring well sites; geologic and paleontological analysis of drill cuttings; geophysical logging to identify formations and possible seawater intrusion; sampling of pore-water obtained from cores; analysis of chemical constituents including trace elements and isotopes; and use of scoping models including a three-dimensional geologic framework model, rainfall-runoff model, regional groundwater flow model, and coastal density-dependent groundwater flow model. Results show that most fresh groundwater was recharged during the last glacial period and that the coastal aquifer has had recurring intrusions of fresh and saline water. These intrusions disguise the source, flowpaths, and history of ground water near the coast. The flow system includes a freshwater lens resting on brackish water; a 100-meter-thick flowtube of freshwater discharging under brackish estuarine water and above highly saline water; and broad areas of fine-grained coastal sediment filled with fairly uniform brackish water. Stable isotopes of hydrogen and oxygen indicate the recharged water flows through many kilometers of fractured crystalline rock before entering the narrow coastal aquifer.

California↗

Effects of urbanization on the chemical, physical, and biological characteristics of small Blackland Prairie streams in and near the Dallas-Fort Worth metropolitan area, Texas

In 2001, the U.S. Geological Survey National Water Quality Assessment Program began a series of studies in the contiguous United States to examine the effects of urbanization on the chemical, physical, and biological characteristics of streams. Small streams in the Texas Blackland Prairie level III ecoregion in and near the Dallas-Fort Worth metropolitan area were the focus of one of the studies. The principal objectives of the study, based on data collected in 2003-04 from 28 subbasins of the Trinity River Basin, were to (1) define a gradient of urbanization for small Blackland Prairie streams in the Trinity River Basin on the basis of a range of urban intensity indexes (UIIs) calculated using land-use/land-cover, infrastructure, and socioeconomic characteristics; (2) assess the relation between this gradient of urbanization and the chemical, physical, and biological characteristics of these streams; and (3) evaluate the type of relation (that is, linear or nonlinear, and whether there was a threshold response) of the chemical, physical, and biological characteristics of these streams to the gradient of urbanization. Of 94 water-chemistry variables and one measure of potential toxicity from a bioassay, the concentrations of two pesticides (diazinon and sima-zine) and one measure of potential toxicity (P450RGS assay) from compounds sequestered in semipermeable membrane devices were significantly positively correlated with the UII. No threshold responses to the UII for diazinon and simazine concentrations were observed over the entire range of the UII scores. The linear correlation for diazinon with the UII was significant, but the linear correlation for simazine with the UII was not. No statistically significant relations between the UII and concentrations of suspended sediment, total nitrogen, total phosphorous, or any major ions were indicated. Eleven of 59 physical variables from streamflow were significantly correlated with the UII. Temperature was not significantly correlated with the UII, and none of the physical habitat measurements were significantly correlated with the UII. Seven physical variables categorized as streamflow flashiness metrics were significantly positively correlated with the UII, two of which showed a linear but not a threshold response to the UII. Four flow-duration metrics were significantly negatively correlated with the UII, of which two showed a linear response to the UII, one showed a threshold response, and one showed neither. None of the fish metrics were significantly correlated with the UII in the Blackland Prairie streams. Two qualitative multi-habitat benthic macroinvertebrate metrics, predator richness and percentage filterer-collector richness, were significantly correlated with the UII; predator richness was negatively correlated with the UII, and percentage filterer-collector richness was positively correlated with the UII. No threshold response to the UII was observed for either metric, but both showed a significant linear response to the UII. Three richest targeted habitat (RTH) benthic macroinvertebrate metrics, Margalef's richness, predator richness, and omnivore richness were significantly negatively correlated with the UII. Margalef's richness was the only RTH metric that indicated a threshold response to the UII. The majority of unique taxa collected in the periphytic algae samples were diatoms. Six RTH periphytic algae metrics were correlated with the UII and five of the six showed no notable threshold response to the UII; but all five showed significant linear responses to the UII. Only the metric OT_VL_DP, which indicates the presence of algae that are tolerant of low dissolved oxygen conditions, showed a threshold response to the UII. Six depositional target habitat periphytic algae metrics were correlated with the UII, five of which showed no threshold response to the UII; three of the five showed significant linear responses to the UII, one showed a borderline significant

Texas↗

Selected ground water data in the Eola-Amity Hills area, northern Willamette Valley, Oregon

Occurrence, quality, and availability of ground water differ considerably from place to place in the Eola - Amity Hills area because of the highly diversified geologic and hydrologic conditions. A table relates the geologic situation to the availability of ground water for four areas-- Eola - Amity Hills , east and west valley plains, and Willamette River flood plain. Tables show well and spring records, drillers' logs, and chemical analyses of ground water . The final interpretive report will be published by the U.S. Geological Survey.

Oregon↗

Water quality in the upper Anacostia River, Maryland: Continuous and discrete monitoring with simulations to estimate concentrations and yields, 2003-05

From 2003 through 2005, continuous and discrete waterquality data were collected at two stations on the Anacostia River in Maryland: Northeast Branch at Riverdale, Maryland (U.S. Geological Survey Station 01649500) and Northwest Branch near Hyattsville, Maryland (Station 01651000). Both stations are above the heads of tide for the river, and measurements approximately represent contributions of chemicals from the nontidal watersheds in the Anacostia River. This study was a cooperative effort between the U.S. Geological Survey, the Prince George’s County Department of Environmental Resources, the Maryland Department of the Environment, the U.S. Environmental Protection Agency, and George Mason University. Samples were collected for suspended sediment, nutrients, and trace metals; data were used to calculate loads of selected chemical parameters, and to evaluate the sources and transport processes of contaminants. Enrichment factors were calculated for some trace metals and used to interpret patterns of occurrence over different flow regimes. Some metals, such as cadmium, lead, and zinc, were slightly enriched as compared to global averages for shales; overall, median values of enrichment factors for all metals were approximately 15 to 35. Stepwise linear regression models were developed on log-transformed concentrations to estimate the concentrations of suspended sediment, total nitrogen, and total phosphorus from continuous data of discharge and turbidity. The use of multiple explanatory variables improved the predictions over traditional rating curves that use only streamflow as the explanatory variable, because other variables such as turbidity measure the hysteretic effects of fine-grained suspended sediment over storm hydrographs. Estimates of the concentrations of suspended sediment from continuous discharge and turbidity showed coefficients of determination for the predictions (multiple R2) of 0.95 and biases of less than 4 percent. Models to estimate the concentrations of total phosphorus and total nitrogen had lower values of multiple R2 than suspended sediment, but the estimated bias for all the models was similar. The models for total nitrogen and total phosphorus tended to under-predict high concentrations and to over-predict low concentrations as compared to measured values. Annual yields (loads per square area in kilograms per year per square kilometer) were estimated for suspended sediment, total nitrogen, and total phosphorus using the U.S. Geological Survey models ESTIMATOR and LOADEST. The model LOADEST used hourly time steps and allowed the use of turbidity, which is strongly correlated to concentrations of suspended sediment, as a predictor variable. Annual yields for total nitrogen and total phosphorus were slightly higher but similar to previous estimates for other watersheds of the Chesapeake Bay, but annual yields for suspended sediment were higher by an order of magnitude for the two Anacostia River stations. Annual yields of suspended sediment at the two Anacostia River stations ranged from 131,000 to 248,000 kilograms per year per square kilometer for 2004 and 2005. LOADEST estimates were similar to those determined with ESTIMATOR, but had reduced errors associated with the estimates.

Maryland↗

Progress report on the investigations of bauxite deposits in the eastern part of Kauai, Hawaii

Investigations of bauxite deposits on Kauai by the U. S. Geological Survey in cooperation with the State of Hawaii were begun July 1, 1959. The investigations, as planned, are to consist of two phases, each of two years duration. The geological investigations of the bauxite and associated rocks in the field and a considerable amount of chemical and mineralogical work in the laboratory are planned for completion during the first two years of the project. During this phase, a geologist and an assistant will be working on Kauai and geologists, mineralogists, and chemists will be analyzing and studying samples of the bauxite in laboratories of the Geological Survey at Beltsville, Maryland, and Washington, D. C. The work during the second phase of the investigations will be carried on at Beltsville and Washington and will consist of completion of chemical and mineralogical investigations, compilation of maps, analysis of field and laboratory data including determination of the size and quality of the bauxite deposits in the eastern part of Kauai, mineralogical research on bauxite samples, and preparation of a final geological report.

Hawaii↗

Dating methods

One of the greatest contributions of geochemistry to man's knowledge of the Earth and solar system has been the development and application of chemical and isotopic techniques used to measure the passage of time. Rates of geologic processes, rates of biological evolution, and contemporaneity of past events all depend on accurate ages of geologic materials. Many geochemical methods have been used to determine ages of rocks and minerals; the ages determined may record the time of mineral crystallization or recrystallization, the time of last heating beyond a given temperature (see Geothermometers ), or the time elapsed since exposure on the surface. The basic requirement for a chemical or isotopic geochronometer is some measurable parameter that changes as a function of time. Furthermore, for accurate ages to be determined, the parameter must have a known (and invariant) relationship with age or must be able to be calibrated.

Book chapter↗

Records of wells, water levels, and chemical quality of water in the lower Santiam River basin, middle Willamette Valley, Oregon

Basic water data on the lower Santiam River basin is preliminary to a comprehensive hydrologic study of this productive and intensely irrigated area where expanding population and industry increases the demand for water . Highest yielding wells are in shallow alluvial aquifers near the main streams; yields range from several hundred to more than a thousand gpm. Wells in lacustrine and older alluvial aquifers that underlie low, flat terraces have yields from a few tens to a few hundred gpm. Wells in the Salem Hills and in the Cascade Range foothills yield moderate to small quantities of water and tap a variety of geologic units. Tabulated material includes records of representative wells , drillers' logs, and chemical and spectrographic analyses of the ground water .

Oregon↗

Radiochemical and chemical constituents in water from selected wells south of the Idaho National Engineering and Environmental Laboratory, Idaho

The U.S. Geological Survey and the Bureau of Land Management, in cooperation with the U.S. Department of Energy, sampled water from five stock wells to monitor water quality of the Snake River Plain aquifer south of the Idaho National Engineering and Environmental Laboratory. The samples were analyzed for selected radiochemical and chemical constituents. The concentrations of strontium-90, transuranic elements, and cesium-137 in all samples were less than the reporting level. Concentrations of tritium in four samples and concentrations of gross alpha-and beta-particle radioactivity in all samples were greater than the reporting level. Most of the inorganic-constituent concentrations were greater than the minimum reporting levels. Concentrations of all 63 purgeable organic compounds analyzed for were less than the respective minimum reporting levels.

Open-File Report↗

Contribution to the study of the physico-chemical structure of Clais

The Cormeilles-en-Parisis hill shows one of the best geologic sections of the Paris region. The 80 meter high working face of the quarry exposes the complete section of the "Ludian" [the youngest beds of the Eocene] with its alternations of the marl and gypsum. Above is the sequence of supra-gypseous marls of the [lower oligocene] Sannosian stage, overlain by a very complex series of alternation brackish water and lacustrine layers, from blue marls to Brie limestone, up through the white Pantin marls, brown marls containing the pelecypod genus Cyrena and green marls. These strata overlain by the [Middle Oligocene] Stampian beds represented by the Fontainebleau sands and Ostrea-bearing marls.

Cormeilles-en-Parisis↗

Effects of controlled agricultural practices on water quality in the Minnesota sand-plain aquifer

Recent studies of Minnesota's sand plains indicate that ground-water chemistry is related to agricultural practices. Surficial sand-plain aquifers cover 8,000,000 acres of Minnesota and are a major source of water for domestic use, irrigation, and some municipal systems. The sand-plain aquifers consist of sand and gravel deposits that are from 20 to greater than 100 feet thick and are covered by a thin sandy loam that generally is less than 2 feet thick. Sand-plain aquifers are recharged by the downward percolation of precipitation through the soil root zone and the unsaturated zone in the sand to the water table. The water table is the upper surface of the zone of saturation and forms the top of the sand-plain aquifer. Sand-plain aquifers are susceptible to contamination by agricultural chemicals (fertilizers and pesticides), if downward-percolating recharge water contains these chemicals. The concentrations of nitrate, pesticides, and some other chemical constituents fluctuate seasonally and differ with depth below the water table (Anderson, 1989). Despite the availability of water-quality data for about 260 wells that were collected during previous studies in three U.S. Geological Survey (USGS) project areas in Minnesota, it is not known how concentrations of agricultural chemicals in ground water relate to the rate and timing of fertilizer and pesticide application or to the tillage practices used. Field-scale research is needed to determine the effects of different farming practices on the concentrations of nitrate, pesticides, and other agricultural chemicals in ground water in the unsaturated and saturated zones.

Minnesota↗

Sediment classification and the characterization, identification, and mapping of geologic substrates for the glaciated Gulf of Maine seabed and other terrains, providing a physical framework for ecological research and seabed management

A geologic substrate is a surface (or volume) of sediment or rock where physical, chemical, and biological processes occur, such as the movement and deposition of sediment, the formation of bedforms, and the attachment, burrowing, feeding, reproduction, and sheltering of organisms. Seabed mapping surveys in the Stellwagen Bank region off Boston, Massachusetts, from 1993 to 2004 have led to the development of a methodology for characterizing, identifying, and mapping geologic substrates. The resulting high-resolution interpretive maps (1:25,000) show the distribution of substrates in a glaciated terrain of banks and basins in water depths of 30 to 185 meters. Data sources used to characterize substrates are multibeam sonar bathymetric and backscatter imagery to document seabed topography and patterns of sediment and rock distribution, grain-size analyses of sediment samples to determine substrate composition, and video and photographic imagery of the seabed to aid in the interpretation of multibeam sonar imagery and to provide information on substrate layering and mobility, seabed structures, and sediments and nonsediment materials that cannot be physically sampled. Sediment composition is a major property of many seabed substrates. Sediment grains belong to a continuum of grain-diameter sizes previously classified into grades (for example, fine sand, medium sand) and into aggregates (mud, sand, gravel). The definition of grade and aggregate boundaries in a classification is arbitrary, and a useful classification is limited to as few classes as are needed to effectively organize and apply information. For the purpose of mapping substrates, sediment grades and aggregates were simplified and re-classified into eight composite grades based on grain-size content, mode of transport, and ecological role. Five composite grades are identified using grain-size analysis and three are identified using video and photographic imagery of the seabed. Naturally occurring sediments contain various amounts of the aggregates mud, sand, and gravel. The separation of naturally occurring sediments into sediment classes, based on grain-size analysis, requires that limits be set on the amount of mud, sand, and gravel each class contains. Fifteen previously identified basic sediment classes provided interpretive information on sediment transport by emphasizing gravel content (a low 0.01-weight-percent threshold) and on winnowing processes based on the sand-to-mud ratio. The present study recognizes 20 basic sediment classes that are combinations of aggregates in which the lower limits for recognition of mud and sand are 10 weight percent and of gravel, 25 weight percent. These sediment classes can be made more specific by listing their content of the composite grades fine-grained sand (3 and 4 phi), which is transported in suspension, and coarse-grained sand (0, 1, and 2 phi), which is transported as bedload. Additional sediment classes and nonsediment classes that cannot be sampled are recognized on the basis of visual analysis of seabed video and photographic imagery and include pebble, cobble, and boulder gravel, rock outcrops, and shell beds, among others. Substrates are not classified because their properties are too varied for a classification to be concise and useful. Rather, substrates are characterized and identified by sediment grain-size composition (the sediment class); the distribution, in millimeters, of grain diameters in the sediment; the presence of nonsediments (for example, rock outcrops); substrate mobility based on the presence of sediment ripples; substrate layering (for example, a partial veneer of sand on gravel); and seabed structures. These properties have interpretive value by providing information about sedimentary processes acting on a substrate and about its ecological function. A geologic substrate, when it is associated with one or more species, is an important element of a habitat. This methodology was developed to map a glaciated terrain characterized by geologic substrates that typify a wide range of erosional and depositional sedimentary environments, and it likely will be useful for mapping substrates in other terrains. Substrate maps provide the physical framework required for identifying sediment transport processes, validating sediment transport models, studying the ecology of species and communities, and managing marine resources and seabed usage.

Massachusetts↗