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At least 793 records · Page 44Linked to original sources

USGS2012

Reconciling estimates of the contemporary North American carbon balance among terrestrial biosphere models, atmospheric inversions, and a new approach for estimating net ecosystem exchange from inventory-based data

We develop an approach for estimating net ecosystem exchange (NEE) using inventory-based information over North America (NA) for a recent 7-year period (ca. 2000–2006). The approach notably retains information on the spatial distribution of NEE, or the vertical exchange between land and atmosphere of all non-fossil fuel sources and sinks of CO 2 , while accounting for lateral transfers of forest and crop products as well as their eventual emissions. The total NEE estimate of a -327 ± 252 TgC yr -1 sink for NA was driven primarily by CO 2 uptake in the Forest Lands sector (-248 TgC yr -1 ), largely in the Northwest and Southeast regions of the US, and in the Crop Lands sector (-297 TgC yr -1 ), predominantly in the Midwest US states. These sinks are counteracted by the carbon source estimated for the Other Lands sector (+218 TgC yr -1 ), where much of the forest and crop products are assumed to be returned to the atmosphere (through livestock and human consumption). The ecosystems of Mexico are estimated to be a small net source (+18 TgC yr -1 ) due to land use change between 1993 and 2002. We compare these inventory-based estimates with results from a suite of terrestrial biosphere and atmospheric inversion models, where the mean continental-scale NEE estimate for each ensemble is -511 TgC yr -1 and -931 TgC yr -1 , respectively. In the modeling approaches, all sectors, including Other Lands, were generally estimated to be a carbon sink, driven in part by assumed CO 2 fertilization and/or lack of consideration of carbon sources from disturbances and product emissions. Additional fluxes not measured by the inventories, although highly uncertain, could add an additional -239 TgC yr -1 to the inventory-based NA sink estimate, thus suggesting some convergence with the modeling approaches.

Global Change Biology↗

USGS2019

Carbon accumulation and vertical accretion in a restored vs. historic salt marsh in southern Puget Sound, Washington, United States

Few comparisons exist between vertical accretion (VA) and carbon accumulation rates (CARs), in restored vs. historic (i.e., reference) marshes. Here we compare these processes in a formerly diked, sparsely vegetated, restored salt marsh (Six Gill Slough, SG), whose surface is subsided relative to the tidal frame, to an adjacent, relatively pristine, historic salt marsh (Animal Slough, AS). Six sediment cores were collected at both AS and SG ~six years after restoration. Cores were analyzed for bulk density, % loss of ignition, % organic carbon, and 210Pb. We found that sharp changes in bulk density in surface layers of SG cores were highly reliable markers for the onset of restoration. The mean VA since restoration at SG (0.79 (sd=0.29) cm yr-1) was ~twice that of AS (0.41 (sd=0.16) cm yr-1). In comparison, the VA at AS over 50 years was 0.30 (sd=0.09) cm yr-1. VA consisted almost entirely of inorganic sediment at SG whereas at AS it was ~55%. Mean CARs at SG were somewhat greater than at AS, but the difference was not significant due to high variability (SG: 81 - 210 g C m-2 yr-1; AS: 115 - 168 g C m-2 yr-1). The mean CAR at AS over the past 50 years was 118 (sd=23) g C m-2 yr-1. This study demonstrates that a sparsely vegetated, restored salt marsh can quickly begin to accumulate carbon and that historic and restored marshes can have similar CARs despite highly divergent formation processes.

Washington↗

USGS2024

Aridity drives the response of soil total and particulate organic carbon to drought in temperate grasslands and shrublands

The increasing prevalence of drought events in grasslands and shrublands worldwide potentially has impacts on soil organic carbon (SOC). We leveraged the International Drought Experiment to study how SOC, including particulate organic carbon (POC) and mineral-associated organic carbon (MAOC) concentrations, responds to extreme drought treatments (1-in-100-year) for 1 to 5 years at 19 sites worldwide. In more mesic areas (aridity index > 0.65), SOC and POC concentrations decreased by 7.9% (±3.9) and 15.9% (±6.2) with drought, respectively, but there were no impacts on MAOC concentrations. However, drought had no impact on SOC, POC, or MAOC concentrations in drylands (aridity index < 0.65). The response of SOC to drought varied along an aridity gradient, concomitant with interannual precipitation variability and standing SOC concentration gradients. These findings highlight the differing response magnitudes of POC and MAOC concentrations to drought and the key regulating role of aridity.

Science Advances↗

USGS1984

Major carbon-14 deficiency in modern snail shells from southern Nevada springs

Carbon-14 contents as low as 3.3 ± 0.2 percent modern (apparent age, 27,000 years) measured from the shells of snails Melanoides tuberculatus living in artesian springs in southern Nevada are attributed to fixation of dissolved HCO 3 - with which the shells are in carbon isotope equilibrium. Recognition of the existence of such extreme deficiencies is necessary so that erroneous ages are not attributed to freshwater biogenic carbonates.

Nevada↗

USGS2000

Isotopic studies of authigenic sulfides, silicates and carbonates, and calcite and pyrite veinlets in the Creede Formation, San Juan Mountains, Southwest Colorado

Sulfur isotope analysis of authigenic pyrite in the Creede Formation documents its precipitation by the reaction between iron in the volcaniclastic sediments and H 2 S formed through bacteriogenic reduction of sulfate added to the lake during and immediately following repeated volcanic eruptions during sedimentation. Pyrite veinlets in the underlying Snowshoe Mountain Tuff were formed by the percolation of H 2 S-bearing pore waters into fractures in the tuff. Conventional analyses of bulk samples of authigenic pyrite range from -20.4% to 34.5% essentially equivalent to the range of -30% to 40% determined using SHRIMP microprobe techniques. Conventional analyses of bulk samples of pyrite from veinlets in the Snowshow Mountain Tiff range from -3.5% to 17.6% much more limited than the ranges of -23% to 111% and -15.6% to 67.0% determined by SHRIMP and laser ablation microbeam techniques, respectively. The extreme range of δ 34 S for the veinlets is interpreted to be the result of continued fractionation of the already 34 S-depleted pore water. Oxygen isotope analysis of authigenic smectite, kaolinite, and K-feldspar together with fluid-inclusion temperatures and oxygen isotope analysis of calcite coexisting with kaolinite indicate that the smectites formed early during burial diagenesis, in accord with petrographic observations. The 40 Ar/ 39 Ar dating of K-feldspar, concorfance of K-feldspar, kaolinite, and calcite δ 18 O values, and fluid-inclusion temperatures in calcite, indicate that the sediments at core hole CCM-1 were subjected to a hydrothermal event at 17.6 Ma. The minerals formed oxygen-shifted meteoric waters with δ 18 O values of ~-9% Smecities at CCM-1 at least partially exchanged with these waters. Carbon and oxygen isotope analysis of authigenic calcites in the Creede Formation show that they formed over a wide range of temperatures from fluids having a wide range of isotopic composition, presumably over an extended period time. Some of the cements apparently formed very late from unexchanged meteoric water. Concretions and possibly some cements at CCM-1 appear to have exchanged with the 17.6 Ma oxygen-shifted hydrothermal fluids. Such exchange is consistent with evidence that lacustrine carbonates at CCM-1 exchanged with low 18 O waters, whereas those at CCM-2 underwent little, if any, exchange. The δ 13 C-δ 18 O values for calcite veinlets in the Creede Formation are similar to those for authegenic calcites. Fluid-inclusion temperatures and δ 18 O indicate that some were deposited during the 17.6 Ma hydrothermal event and others from unexchanged meteoric water at a later date. The isotope studies confirm that part of the model of Rye et al., proposing that the barites in the southern end of the Creede Mining District were formed by mixing of the Creede hydrotermal system with Lake Creede pore of lake waters. The silicate and carbonate isotope data indicate that the pores of the Creede Formation were occupied by at least three isotopically distinct water since the time of deposition. The original pore fluids were probably shifted to lower δ 18 O values during burial diagensis as a result of the hydrolysis of the volcanic glass to for smectites and other hydrous silicates. During or prior to a 17.6 Ma hydrothermal event in the vicinity of CCM-1, the Creede Formation was flushed with oxygen-shifted meteoric water, possibly related to the breaching of the east side of the caldera wall sometime between 20 and 22 Ma. Later, the Creede Formation was again flushed, this time with unexchanged meteoric water with δD-δ 18 O values of present-day waters, possibly during the incision of the Rio Grande drainage during uplifting of the southern Rocky Mountains beginning about 5 Ma.

GSA Special Papers↗

USGS1994

Karstification without carbonic acid: Bedrock dissolution by gypsum- driven dedolomitization

Aggressive karstification can take place where dolomite and gypsum are in contact with the same aquifer. Gypsum dissolution drives the precipitation of calcite, thus consuming carbonate ions released by dolomite. Lake Banyoles, in northeastern Spain, is a karst lake supplied by sublacustrine springs, and karstic collapse is occurring in the immediate vicinity of the lake. Lake water is dominated by Mg-Ca and SO 4 -HCO 3 , and is supersaturated with calcite that is actively accumulating in lake sediments. Water chemistry, sulfur isotope composition, local stratigraphy, and mass-balance modelling suggest that the primary karst-forming process at at Lake Banyoles is dedolomitization of basement rocks driven by gypsum dissolution. Karstification takes place along the subsurface contact between the gypsiferous Beuda Formation and the dolomitic Perafita Formation. This process is here recognized for the first time to cause karstification on a large scale; this is significant because it proceeds without the addition of soil-generated carbonic acid. Gypsum-driven dedolomitization may be responsible for other karstic systems heretofore attributed to soil-generated carbonic acid.

Geology↗

USGS1997

Recognition of maximum flooding events in mixed siliciclastic-carbonate systems: Key to global chronostratigraphic correlation

The maximum flooding event within a depositional sequence is an important datum for correlation because it represents a virtually synchronous horizon. This event is typically recognized by a distinctive physical surface and/or a significant change in microfossil assemblages (relative fossil abundance peaks) in siliciclastic deposits from shoreline to continental slope environments in a passive margin setting. Recognition of maximum flooding events in mixed siliciclastic-carbonate sediments is more complicated because the entire section usually represents deposition in continental shelf environments with varying rates of biologic and carbonate productivity versus siliciclastic influx. Hence, this event cannot be consistently identified simply by relative fossil abundance peaks. Factors such as siliciclastic input, carbonate productivity, sediment accumulation rates, and paleoenvironmental conditions dramatically affect the relative abundances of microfossils. Failure to recognize these complications can lead to a sequence stratigraphic interpretation that substantially overestimates the number of depositional sequences of 1 to 10 m.y. duration.

Geology↗

USGS1998

Magnitude and significance of carbon burial in lakes, reservoirs, and peatlands

Globally, lakes are currently accumulating organic carbon (OC) at an estimated annual rate of about 42 Tgṁyr −1 . Most of the OC in all but the most oligotrophic of these lakes is autochthonous, produced by primary production in the lakes. The sediments of reservoirs accumulate an additional 160 Tg annually, and peatlands contribute 96 Tg annually. These three carbon pools collectively cover less than 2% of the Earth's surface and constitute a carbon sink of about 300 Tgṁyr −1 . Although the oceans cover 71% of the Earth's surface, they accumulate OC at a rate of only about 100 Tgṁyr −1 .

Geology↗

USGS2008

Devonian carbonate platform of eastern Nevada: Facies, surfaces, cycles, sequences, reefs, and cataclysmic Alamo Impact Breccia

Devonian limestone and dolostone formations are superbly exposed in numerous mountain ranges of southeastern Nevada. The Devonian is as thick as 1500 m there and reveals continuous exposures of a classic, long-lived, shallow-water carbonate platform. This field guide provides excursions to Devonian outcrops easily reached from the settlement of Alamo, Nevada, ~100 mi (~160 km) north of Las Vegas. Emphasis is on carbonate-platform lithostratigraphy, but includes overviews of the conodont biochronology that is crucial for regional and global correlations. Field stops include traverses in several local ranges to study these formations and some of their equivalents, in ascending order: Lower Devonian Sevy Dolostone and cherty argillaceous unit, Lower and Middle Devonian Oxyoke Canyon Sandstone, Middle Devonian Simonson Dolostone and Fox Mountain Formation, Middle and Upper Devonian Guilmette Formation, and Upper Devonian West Range Limestone. Together, these formations are mainly composed of hundreds of partial to complete shallowing-upward Milankovitch-scale cycles and are grouped into sequences bounded by regionally significant surfaces. Dolomitization in the Sevy and Simonson appears to be linked to exposure surfaces and related underlying karst intervals. The less-altered Guilmette exhibits characteristic shallowing-upward limestone-to-dolostone cycles that contain typical carbonate-platform fossil- and ichnofossil-assemblages, displays stacked biostromes and bioherms of flourishing stromatoporoids and sparse corals, and is punctuated by channeled quartzose sandstones. The Guilmette also contains a completely exposed ~50-m-thick buildup that is constructed mainly of stromatoporoids, with an exposed and karstified crest. This buildup exemplifies such Devonian structures known from surface and hydrocarbon-bearing subsurface locations worldwide. Of special interest is the stratigraphically anomalous Alamo Breccia that represents the middle member of the Guilmette. This spectacular cataclysmic megabreccia, produced by the Alamo Impact Event, is as thick as 100 m and may be the best exposed proven bolide impact breccia on Earth. It contains widespread intervals generated by the seismic shock, ejecta curtain, tsunami surge, and runoff generated by a major marine impact. Newly interpreted crater-rim impact stratigraphy at Tempiute Mountain contains an even thicker stack of impact breccias that are interpreted as parautochthonous, injected, fallback, partial melt, resurge, and possibly post-Event crater fill.

Nevada↗

USGS2015

Sedimentology of SPICE (Steptoean positive carbon isotope excursion): A high-resolution trace fossil and microfabric analysis of the middle to late Cambrian Alum Shale Formation, southern Sweden

The Cambrian Alum Shale Formation in the Andrarum-3 core from Scania, southern Sweden, consists of black siliciclastic mudstone with minor carbonate intercalations. Four facies comprise three siliciclastic mudstones and one fine-grained carbonate. The facies reflect deposition along a transect from deep ramp to basin on a Cambrian shelf. The three mudstone facies contain abundant clay clasts and laterally variable siltstone laminae. Bed-load transport processes seem to have dominated deposition on this deep shelf. These sedimentary rocks record mainly event deposition, and only relatively few, thin laminae probably resulted from suspension settling. The Alum Shale Formation deep shelf did not show a bioturbation gradient, but fecal strings are common and Planolites burrows are rare in all mudstone facies. Evidence for biotic colonization indicates that this mudstone environment was not persistently anoxic, but rather was most likely intermittently dysoxic. The Alum Shale Formation in the Andrarum-3 core shows an overall decrease of grain size, preserved energy indicators, and carbonate content upsection interpreted to reflect a deepening upward. The succession can also be divided into four small-scale fining-upward cycles that represent deepening, and four overlying coarsening-upward cycles that represent upward shallowing.

Book chapter↗

USGS2010

Testing the limits of Paleozoic chronostratigraphic correlation via high-resolution (<500 k.y.) integrated conodont, graptolite, and carbon isotope (δ 13 C carb ) biochemostratigraphy across the Llandovery–Wenlock (Silurian) boundary: Is a unified Phanerozoic time scale achievable?

The resolution and fidelity of global chronostratigraphic correlation are direct functions of the time period under consideration. By virtue of deep-ocean cores and astrochronology, the Cenozoic and Mesozoic time scales carry error bars of a few thousand years (k.y.) to a few hundred k.y. In contrast, most of the Paleozoic time scale carries error bars of plus or minus a few million years (m.y.), and chronostratigraphic control better than ??1 m.y. is considered "high resolution." The general lack of Paleozoic abyssal sediments and paucity of orbitally tuned Paleozoic data series combined with the relative incompleteness of the Paleozoic stratigraphic record have proven historically to be such an obstacle to intercontinental chronostratigraphic correlation that resolving the Paleozoic time scale to the level achieved during the Mesozoic and Cenozoic was viewed as impractical, impossible, or both. Here, we utilize integrated graptolite, conodont, and carbonate carbon isotope (??13Ccarb) data from three paleocontinents (Baltica, Avalonia, and Laurentia) to demonstrate chronostratigraphic control for upper Llando very through middle Wenlock (Telychian-Sheinwoodian, ~436-426 Ma) strata with a resolution of a few hundred k.y. The interval surrounding the base of the Wenlock Series can now be correlated globally with precision approaching 100 k.y., but some intervals (e.g., uppermost Telychian and upper Shein-woodian) are either yet to be studied in sufficient detail or do not show sufficient biologic speciation and/or extinction or carbon isotopic features to delineate such small time slices. Although producing such resolution during the Paleozoic presents an array of challenges unique to the era, we have begun to demonstrate that erecting a Paleozoic time scale comparable to that of younger eras is achievable. ?? 2010 Geological Society of America.

Geological Society of America Bulletin↗

USGS1995

Evidence of autumn nitrogen limitation and contribution of picoplankton to carbon fixation in Lake Tahoe

Water samples were collected from Lake Tahoe at midlake and nearshore stations at three depths (25, 50, and 75 m, corresponding to light intensities of approximately 10, 1, and 0.1% of surface light) in May and September. The water samples were evaluated to decide the following: (1) whether carbon fixation was N-limited and whether there were differences between picoplankton and larger phytoplankters and (2) the relative importance of picoplankton carbon fixation and related photosynthetic parameters. Evidence of N-limitation was observed only in September at the midlake station for the populations at 50 and 75 m, and to a lesser extent at the nearshore station at 75 m, but only for the nanoplankton fraction. The contribution of picoplankton to total carbon fixation ranged from 34 to 69% and did not increase with depth. Low values for I k , the photoadaptation parameter, for deep water populations (0.1% light level) in September, but not May, suggested that these populations were adapted to low light in the fall but not the spring.

California, Nevada↗

USGS2012

GFDL's ESM2 global coupled climate-carbon Earth System Models. Part I: physical formulation and baseline simulation characteristics

We describe the physical climate formulation and simulation characteristics of two new global coupled carbon-climate Earth System Models, ESM2M and ESM2G. These models demonstrate similar climate fidelity as the Geophysical Fluid Dynamics Laboratory's previous CM2.1 climate model while incorporating explicit and consistent carbon dynamics. The two models differ exclusively in the physical ocean component; ESM2M uses Modular Ocean Model version 4.1 with vertical pressure layers while ESM2G uses Generalized Ocean Layer Dynamics with a bulk mixed layer and interior isopycnal layers. Differences in the ocean mean state include the thermocline depth being relatively deep in ESM2M and relatively shallow in ESM2G compared to observations. The crucial role of ocean dynamics on climate variability is highlighted in the El Niño-Southern Oscillation being overly strong in ESM2M and overly weak ESM2G relative to observations. Thus, while ESM2G might better represent climate changes relating to: total heat content variability given its lack of long term drift, gyre circulation and ventilation in the North Pacific, tropical Atlantic and Indian Oceans, and depth structure in the overturning and abyssal flows, ESM2M might better represent climate changes relating to: surface circulation given its superior surface temperature, salinity and height patterns, tropical Pacific circulation and variability, and Southern Ocean dynamics. Our overall assessment is that neither model is fundamentally superior to the other, and that both models achieve sufficient fidelity to allow meaningful climate and earth system modeling applications. This affords us the ability to assess the role of ocean configuration on earth system interactions in the context of two state-of-the-art coupled carbon-climate models.

Journal of Climate↗

USGS2011

Rock formation characterization for CO2-EOR and carbon geosequestration; 3D seismic amplitude and coherency anomalies, Wellington Field, Kansas, USA

In this paper, we present a workflow for a Mississipian carbonates characterization case-study integrating post-stack seismic attributes, well-logs porosities, and seismic modeling to explore relating changes in small-scale "lithofacies" properties and/or sub-seismic resolution faulting to key amplitude and coherency 3D seismic attributes. The main objective of this study is to put emphasis on reservoir characterization that is both optimized for and subsequently benefiting from pilot tertiary CO2-EOR in preparation for future carbon geosequestration in a depleting reservoir and a deep saline aquifer. The extracted 3D seismic coherency attribute indicated anomalous features that can be interpreted as a lithofacies change or a sub-seismic resolution faulting. A 2D finite difference modeling has been undertaken to understand and potentially build discriminant attributes to map structural and/or lithofacies anomalies of interest especially when embarking upon CO2-EOR and/or carbon sequestration monitoring and management projects. ?? 2011 Society of Exploration Geophysicists.

SEG Technical Program Expanded Abstracts↗

USGS2022

Velocity modeling of supercritical pore fluids through porous media under reservoir conditions with applications for petroleum secondary migration and carbon sequestration plumes

Computational methods to characterize secondary migration in porous media traditionally rely on fluid transport equations with assumptions of time invariance, such as flowpath modeling of buoyancy vectors, statistical percolation algorithms, capillary pressure curves, or a form of Darcy’s Law which presumes instantaneous fluid transport. However, in petroleum systems modeling, the timeframe of secondary migration from source to reservoir is important to quantify in relation to other geologic factors such as timing of petroleum generation, fault movement, and seal formation. Additionally, quantifying migration velocities enables an estimation of the distance a plume of geologically sequestered carbon dioxide travels over time, as well as the identification of low-permeability strata appropriate for long-term containment. This study introduces a method to quantify transport velocities of supercritical fluids in low-permeability lithologies for a broad range of rock and fluid properties likely encountered in the sedimentary sequence. A time-dependent form of Darcy’s Law for pressure-driven viscous flow through homogeneous isotropic porous media was used to model flow velocities within a carrier bed. Thermodynamic equations of state were used to determine thermophysical properties of supercritical pore fluids under reservoir pressures ranging from 0–200 MPa (0–29,000 psi) to constrain the momentum equations. Three case studies were examined that (1) estimated fluid flow velocities of methane within the low-permeability Upper Jurassic Haynesville Formation, (2) defined permeability-based flow units to evaluate saline formations for long-term geologic carbon sequestration, and (3) calculated the migration distance of carbon dioxide plumes at the Decatur, Illinois injection and sequestration project.

SEG-AAPG Interpretation↗

USGS2002

The lacustrine carbon cycle as illuminated by the waters and sediments of two hydrologically distinct headwater lakes in north-central Minnesota, U.S.A

The accumulation rates of CaCO 3 and organic carbon (OC) in lake sediments are delicately balanced between production in the epilimnion and destruction in the hypolimnion. The cycling of these two forms of carbon makes a "carbon pump" that greatly affects the biogeochemical cycles of other elements. To further understand these biogeochemical dynamics, the lakes, streams, and wetlands of the Shingobee River headwater area of north-central Minnesota have been subjected to intensive hydrologic and biogeochemical studies. Williams Lake, situated close to the highest point in the regional flow system, is hydrologically closed, with no surface inlet or outlet, and ground water and precipitation as the only sources of water. Shingobee Lake, situated at the lowest point in the regional flow system, has the Shingobee River as an inlet and outlet. The surface waters of both lakes are oversaturated, and the bottom waters undersaturated, with respect to CaCO 3 during the summer. The small amount of CaCO 3 that is precipitated in the epilimnion of Williams Lake during the summer is dissolved in the undersaturated hypolimnion and sediments with the result that no CaCO 3 is incorporated into the profundal surface sediments. Because of the high phytoplankton productivity of Shingobee Lake, sufficient CaCO 3 is produced in the epilimnion that large amounts survive the corrosive hypolimnion and sediments, and an average of 46 wt. % accumulates in surface sediments. Another consequence of higher phytoplankton productivity in Shingobee Lake is that the hypolimnion becomes oxygen deficient within a month after overturn in both the spring and fall. Because of reducing conditions that develop in the hypolimnion of Shingobee Lake, high concentrations of dissolved Fe and Mn accumulate there during summer stratification. Precipitation of Fe and Mn oxyhydroxides during periods of fall and spring overturn results in high concentrations of Fe and Mn in surface sediments. In Williams Lake, high concentrations of Fe and Mn do not build up in the hypolimnion. The concentration of CaCO 3 is about 80 wt. % in lower Holocene sediments of both lakes. The lower Holocene sediments in both lakes also contain high concentrations of Fe and Mn, and the lower Holocene sediments of Shingobee are laminated. The waters of both lakes had identical values of δ 13 C and δ 18 O during the early Holocene, but the waters of Williams Lake "evolved" during the early Holocene, increasing about 10‰ in both δ 13 C and δ 18 O. Deposits of lacustrine marl occur as much as seven meters above the present elevation of Williams Lake, the highest of the two lakes. Taken together, these observations suggest that the lakes were once connected to form a larger lake called Lake Willobee with a hypolimnion that was anoxic, at least seasonally.

Minnesota↗

USGS2024

Surface area of montmorillonite from the dynamic sorption of nitrogen and carbon dioxide

Surface area determinations were made on a montmorillonite with various cations emplaced on the exchangeable sites, utilizing nitrogen and carbon dioxide as adsorbates at 77 ° K and 195 ° K, respectively, in a dynamic system. From the fraction of a Mississippi montmorillonite less than about 1 μ in size, samples were prepared by replacing the original exchangeable cations with Li + , Na + , K + , Rb + , Cs + , Mg ++ , Ca ++ , Ba ++ , and NH 4 + , forming a series of homoionic montmorillonite species. Surface areas from 3-point B.E.T. plots (half-hour adsorption points), with nitrogen as the adsorbate, ranged from 61 m 2 /g for Li-montmorillonite to 138 m 2 /g for Cs-montmorillonite, thus reflecting a certain degree of nitrogen penetration between layers. Complete penetration should theoretically result in a surface area of over 300 m 2 /g for this clay with a nitrogen monolayer between each pair of platelets. The experimental data indicate that the extent of penetration is time-dependent and is also a function of the interlayer forces as governed by the size and charge of the replaceable cation. This finding negates the generally accepted concept that nitrogen at 77 ° K does not penetrate the layers and provides a measure only of the external surface of expandable clay minerals. A further measure of the variation of interlayer forces is provided by the adsorption of carbon dioxide at 195 ° K. Surface area values ranged from 99 m 2 /g for Li-montmorillonite to 315 m 2 /g for Csmontmorillonite. Although the carbon dioxide molecule is larger than the nitrogen molecule, its greater penetration apparently is a result of its being kinetically more energetic (with a larger diffusion coefficient) at its higher adsorption temperature. Similar differences have been found with both adsorbates in the study of microporous substances, such as coal, where activated diffusion is of considerable significance.

Clays and Clay Minerals↗

USGS2024

Surface area of vermiculite with nitrogen and carbon dioxide as adsorbates

Surface-area studies were made on several homoionic vermiculites with both nitrogen and carbon dioxide as adsorbates. These studies show that only very slight penetration occurs between individual vermiculite platelets. This is in contrast to an earlier investigation of montmorillonite where it was found that the degree of penetration between layers is quite high, particularly for carbon dioxide, and is governed by the size and charge of the interlayer cation. The inability of these adsorbates to penetrate substantially between vermiculite platelets is due primarily to this mineral's high surface-charge density. The extent of penetration of nitrogen and carbon dioxide at the edges of vermiculite platelets, though slight, is influenced by the coordinated water retained within the sample at a given degassing temperature. Forces between layers are weakened with increasing water content, which permits slightly greater penetration by adsorbate gases. Thus, the surface area of vermiculite, as determined by gas adsorption, is larger than the calculated external surface area based upon particle size and shape considerations. In addition, "extra" surface is provided by the lifting and scrolling of terminal platelets. These morphological features are shown in scanning electron micrographs of a naturally occuring vermiculite.

Clays and Clay Minerals↗