USGS ScienceSearch

SEARCH · USGS Science

Results for “Canadian Journal of Fisheries and Aquatic Sciences”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

1,688 records · Page 44Linked to original sources

Stratigraphy, structure, and geomorphology of the central Appalachians across the North Mountain fault zone near Harrisonburg, Virginia, USA

This field trip focuses on the geology of the central Appalachian Valley and Ridge province near Harrisonburg, Virginia, USA. Recent geologic mapping utilizing 1-m resolution lidar data has revealed new insights into the Paleozoic stratigraphy, structural geology, and Neogene landscape evolution of the region. The detailed mapping reveals the presence of the Big Spring Station Member and multiple thrombolite zones in the Cambrian Conococheague Formation extending as far south as the Briery Branch 7.5 min quadrangle, providing insights into Late Cambrian sea-level fluctuations. Multiple outcrop exposures in the study area of this guidebook confirm recent work in Pennsylvania, USA, showing that the Ordovician Reedsville Shale overlies the Martinsburg Formation and that the two are distinct and mappable as separate formations rather than laterally equivalent units as previously interpreted. Our work extends the Silurian Williamsport Sandstone into Shenandoah County, Virginia, and describes its facies relationships with the Bloomsburg Formation along strike and across the Adams Run anticline. Mapping within the thick Devonian siliciclastic sequence reveals the presence of the Mahantango Formation on the western limb of Supin Lick syncline and illustrates its complex facies relationship with the Millboro Shale. In addition, we highlight new mapping criteria for the Brallier and Foreknobs Formations and demonstrate how the specific changes to the placement of the contact between them addresses previous challenges in their differentiation. We present cosmogenic burial ages of broad alluvial fan sediments in the Shenandoah Valley near Timberville and Briery Branch, Virginia, and erosion rates estimated for the Briery Branch stream basin. Both analyses provide new constraints on the timing of landscape evolution and karst development since the middle Pliocene. This field guide also highlights some significant structural features within the North Mountain fault zone, such as evidence of imbricated thrust sheets cut by cross-strike faults that have been exploited by Eocene igneous intrusions. Map-scale horses of Silurian and Ordovician rocks hold up ridges that are oblique to the regional strike. Deformation internal to one of these horse blocks is shown to be non-coaxial with respect to the main regional northwest directed transport.

Virginia

Application of acoustical methods for estimating water flow and constituent loads in Perdido Bay, Florida

Water flow and quality data were collected from December 1994 to September 1995 to evaluate variations in discharge, water quality, and chemical fluxes (loads) through Perdido Bay, Florida. Data were collected at a cross section parallel to the U.S. Highway 98 bridge. Discharges measured with an acoustic Doppler current profiler (ADCP) and computed from stage-area and velocity ratings varied roughly between + or - 10,000 cubic feet per second during a typical tidal cycle. Large reversals in flow direction occurred rapidly (less than 1 hour), and complete reversals (resulting in near peak net-upstream or downstream discharges) occurred within a few hours of slack water. Observations of simultaneous upstream and downstream flow (bidirectional flow) were quite common in the ADCP measurements, with opposing directions of flow occurring predominantly in vertical layers. Continuous (every 15 minutes) discharge data were computed for the period from August 18, 1995, to September 28, 1995, and filtered daily mean discharge values were computed for the period from August 19 to September 26, 1995. Data were not computed prior to August 18, 1995, either because of missing data or because the velocity rating was poorly defined (because of insufficient data) for the period prior to landfall of hurricane Erin (August 3, 1995). The results of the study indicate that acoustical techniques can yield useful estimates of continuous (instantaneous) discharge in Perdido Bay. Useful estimates of average daily net flow rates can also be obtained, but the accuracy of these estimates will be limited by small rating shifts that introduce bias into the instantaneous values that are used to compute the net flows. Instantaneous loads of total nitrogen ranged from -180 to 220 grams per second for the samples collected during the study, and instantaneous loads of total phosphorous ranged from -10 to 11 grams per second (negative loads indicate net upstream transport). The chloride concentrations from the water samples collected from Perdido Bay indicated a significant amount of mixing of saltwater and freshwater. Mixing effects could greatly reduce the accuracy of estimates of net loads of nutrients or other substances. The study results indicate that acoustical techniques can yield acceptable estimates of instantaneous loads in Perdido Bay. However, estimates of net loads should be interpreted with great caution and may have unacceptably large errors, especially when saltwater and freshwater concentrations differ greatly.

Florida

The 3D Elevation Program—Supporting the economy of Massachusetts

Introduction Massachusetts extends from the mountains of the Appalachian system in the west of the State to the sandy beaches and rocky shorelines of the Atlantic coast in the east. Inland topographic data support a wide range of important activities, including geologic mapping, transportation planning, forest and wildlife management, quantifying ecological services, water supply protection, commonwealth-wide infrastructure planning, local site planning, and flood-plain management. Nearshore bathymetry can be used to support coastal portions of the Commonwealth by addressing the combined threats of ocean warming, strong storm surge, and rising sea levels. The maintenance and (or) expansion of Massachusetts ports (for instance, Boston, New Bedford) and Cape Cod sediment management depends upon the accurate mapping of bathymetry and the frequent influx of sediment and redeposition. Critical applications that address the broad range of requirements depend on light detection and ranging (lidar) data that provide a highly detailed three-dimensional (3D) model of the Earth’s surface and aboveground features. The 3D Elevation Program (3DEP) is managed by the U.S. Geological Survey (USGS) in partnership with Federal, State, Tribal, U.S. territorial, and local agencies to acquire consistent lidar coverage at quality level 2 or better to meet the many needs of the Nation and Massachusetts. The status of available and in-progress 3DEP baseline lidar data in Massachusetts is shown in figure 1. 3DEP baseline lidar data include quality level 2 or better, 1-meter or better digital elevation models, and lidar point clouds, and must meet the Lidar Base Specification version 1.2 ( https://www.usgs.gov/3dep/lidarspec ) or newer requirements. The National Enhanced Elevation Assessment identified user requirements and conservatively estimated that availability of lidar data would result in at least $1.23 million in new benefits annually to Massachusetts. The top 10 Massachusetts business uses for 3D elevation data, which are based on the estimated annual conservative benefits of 3DEP, are shown in table 2.

Massachusetts

Petrogenesis and mineralization potential of the Bradley Peak komatiitic basalts, Wyoming Province

The ca. 2.72 Ga Bradley Peak greenstone terrane in the Wyoming Province contains spinifex- and cumulate-textured komatiitic volcanic rocks that may host Ni-Cu-PGE sulfide mineralization. New whole rock geochemistry classifies these rocks as Al-undepleted komatiitic basalts derived from a parental melt with ~17 wt. % MgO. Isotopic data (Sm-Nd, Re-Os) and REE profiles suggest a plume source and possible assimilation of juvenile footwall volcanic rocks. Calculated sulfur concentrations at sulfide saturation and low-detection PGE geochemistry indicate these magmas did not saturate a sulfide liquid resulting in sulfide mineralization. Although the Bradley Peak komatiitic basalt flows are unlikely to host magmatic sulfide mineralization, they are likely the source of Au for regional orogenic gold deposits.

Wyoming

The Great Salt Lake (Utah, USA) acoustic and sedimentary archive of Wasatch Front earthquakes

As the largest low-relief basin in the western United States, the Great Salt Lake offers an opportunity to explore acoustic and sedimentary archives of earthquake ruptures in a shallow terminal basin. Here, we use subbottom compressed high intensity radiated pulse (Chirp) profiles and sedimentary cores to address questions related to how Great Salt Lake sediments respond to surface rupture and earthquake shaking and whether the lake is sensitive to both Great Salt Lake fault (GSLF) and Wasatch fault zone (WFZ) earthquakes. Chirp profiles reveal laterally continuous seismic stratigraphy with vertically displaced strata, onlap surfaces, and growth stratigraphy produced by GSLF surface ruptures. We identify and date two ruptures on the Fremont Island section and three on the Antelope Island section; temporal overlap of these ruptures supports synchronous rupture of both sections. Combined with previous data, our results yield a record of four Holocene surface-rupturing (M W 6.9−7.3) earthquakes on the GSLF with a mean recurrence of ∼3.2 k.y. Sediment cores include ≤41-cm-thick, massive, homogeneous to normally graded disturbance beds that interrupt laminated bioclastic sediment. Disturbance bed correlations yield four lacustrine earthquake deposits since ca. 1.7 ka; the youngest possibly records the most recent GSLF surface rupture whereas older deposits were likely produced by WFZ earthquakes. Modeled historical earthquakes yield a Great Salt Lake sediment disturbance shaking threshold of MMI ∼VI, controlled in part by the lake-bottom expression of the GSLF scarp. Our integration of primary (fault-related) and secondary (shaking-related) earthquake evidence improves our understanding of sediment disturbance processes and the archival potential of low-relief lake basins.

Utah

Influence of new residential construction varying in housing density on bird species, human tolerance guilds, and communities

Human population growth and changing settlement patterns fuel the development of urban fringe lands worldwide, with implications for biodiversity. We conducted a 12-year study of birds in the fast-developing urban fringe lands of the central Puget Sound region, Washington, USA, to examine the effect of development configuration on birds. We hypothesized that lower-intensity conservation developments, compared to higher-intensity planned community developments, would benefit the overall bird community, as well as native forest birds (avoiders of human development) and avian generalist species (adapters to human development), but that higher-intensity planned community developments would benefit synanthropic species (exploiters of human development). We fit single-species and multi-species occupancy models to test these hypotheses. Consistent with our hypotheses, we found that a greater proportion of the overall community, avoiders, and adapters occupied lower-intensity conservation developments compared to higher-intensity planned community developments. However, we did not detect an effect of development type on the exploiter guild, and we found that species in the exploiter guild are variable in their response to the configuration of suburban developments. We also hypothesized that human tolerance guilds would be a useful predictor of individual species responses to development type. This hypothesis was somewhat supported: we found that, for avoiders, 87% of species in the guild had the same response to development type as the overall guild; for adapters, 63% had the same response as the overall guild, and for exploiters, only 44% had the same response as the overall guild. Our results indicate that the configuration of suburban developments can have a meaningful impact on bird communities, particularly on those species that are most sensitive to any level of development.

Washington

Technique for estimating magnitude and frequency of peak flows in Maryland

A convenient and reliable technique for estimating flood magnitudes is required for effective flood-plain management and for the efficient design of bridges, culverts, embankments, and flood-protection structures. Methods are presented for estimating peak-flow magnitudes of selected frequencies, ranging from 2 to 500 years, for all nontidal drainage basins in Maryland. The methods were developed by generalized least-squares regression techniques using data from 219 gaged basins in and near Maryland. The State is divided into five hydrologic regions: the Appalachian Plateaus and Allegheny Ridges region, the Blue Ridge and Great Valley region, the Piedmont region, the Western Coastal Plain region, and the Eastern Coastal Plain region. These regions correspond to the physiographic provinces of the State, with the exceptions that (1) the Coastal Plain Province is divided into two hydrologic regions, and (2) there is no distinct hydrologic region corresponding to the Valley and Ridge Province as it is divided into its constituent Allegheny Ridges and Great Valley subdivisions. Sets of equations for calculating peak discharges based on physical basin characteristics are provided for each of the regions. Based on the peak-flow equations, methods for estimating peak flows are presented for ungaged and gaged streams in Maryland. The methods and equations are supported by generalized least-squares analysis of basin and flood-frequency characteristics data from 219 drainage basins in and near Maryland. estimates for each of the five regions are calculated using combinations of the fol-lowing basin characteristics: drainage area, forest cover, basin relief, carbonate rock coverage, storage, and runoff-curve number. Drainage area contributes to the estimate in all five study regions. Carbonate rock coverage is used only in the Blue Ridge and Great Valley region. Storage and runoff-curve number are used solely in the Eastern Coastal Plain region. All other basin characteristics are used in two or more regions. Standard errors of estimate for the regression equations range from 19 to 31 percent in the Appalachian Plateaus and Allegheny Ridges region, 34 to 47 percent in the Blue Ridge and Great Valley region, 33 to 48 percent in the Piedmont region, 45 to 64 percent in the Western Coastal Plain region, and 36 to 42 percent in the Eastern Coastal Plain region.

Maryland

Assessment of fresh groundwater discharge and saline surface-water intrusion at Operable Unit 2, North Chevalier Field Disposal Area (Site 11), Naval Air Station Pensacola, Florida, 2018–22

Site 11 is a former landfill at North Chevalier Field Disposal Area in Operable Unit 2 at Naval Air Station Pensacola, in northwest Florida. Site 11 is adjacent to Bayou Grande, a shallow, tidally influenced, saline estuary of the Pensacola Bay watershed. Federal and Florida regulators have expressed concern that contaminants detected in groundwater beneath the inland parts of Site 11 may discharge to Bayou Grande. In 2017, the Department of Defense, U.S. Navy, Naval Facilities Engineering Systems Command Southeast asked the U.S. Geological Survey to assess the occurrence of fresh groundwater discharge to Bayou Grande at Site 11 and to delineate to the extent practicable the location of groundwater discharge. Between 2018 and 2022, the U.S. Geological Survey used a multiple-lines-of-evidence approach that included a visual method and three physical methods based on the temperature difference between groundwater and surface water to assess groundwater discharge. One of the physically based methods also used the difference in specific conductance between fresh groundwater and brackish to saline surface water. Combined, the data indicate that fresh groundwater from across Site 11 discharges primarily along the shoreline of the northern and northeastern part of Site 11. The data also indicate that saline surface water from Bayou Grande intrudes tens of feet into the shallow aquifer beneath Site 11. The combined data indicate that the interface between fresh groundwater and saline surface water changes over space and time. Any new monitoring wells proposed for installation near the shoreline of Site 11 should include approaches to monitor the changes in the location of the freshwater/saltwater interface. Care would need to be taken to collect any groundwater samples at the correct season and tidal period to provide the highest probability of collecting a representative sample of Site 11 groundwater unaffected by saltwater.

Florida

Cultural benefits knowledge and social learning in Elwha River dam removal and ecosystem decision-making

In a retrospective case study of the seminal Elwha River dam removal in Washington State, USA, we explore pathways through which ecosystem services (ES) knowledge can inform environmental decision-making. We specifically investigate how knowledge of cultural benefits linked to the Elwha River ecosystem was made available. Through interviews and historical document review we identify diverse forms of cultural benefits knowledge (i.e., how individuals or groups know the contributions of an ecosystem to their identities, experiences, and capabilities), including both knowledge in the form of practices – embodied or enacted forms of knowledge, and knowledge in the form of products – quantitative or written documentation. Recognizing and learning from the diverse forms in which benefits knowledges are conveyed can support more accurate and equitable consideration of the diverse values, well-beings, and human-nature relationships linked to ecosystems. With this case study, we illuminate pathways for meaningful consideration of multiple knowledge forms, and the plural ecosystem values they convey, with relevance for environmental decision processes in the Puget Sound and beyond.

Washington

Evaluation of best management practices at an edge-of-field site in the Eagle Creek watershed, Ohio, 2012–20

In 2010, the U.S. Geological Survey worked in partnership with the Great Lakes Restoration Initiative and the Natural Resources Conservation Service to identify farm fields in priority watersheds—watersheds critically important to Great Lake health. Intensive best management practices were implemented in five States to test the efficacy of best management practices, also referred to as agricultural conservation practices, to reduce sediment and nutrient runoff on agricultural fields. These fields were chosen as representatives of the priority watersheds because their farming practices and geographical conditions were common among farms in those watersheds. A farm site located near Findlay, Ohio, in the Eagle Creek watershed used two conservation practices, cover crop (Natural Resources Conservation Service practice standard 340) and variable rate technology (VRT; Natural Resources Conservation Service practice standard 590), which represent common practices in the Maumee priority watershed. This study monitored surface runoff and subsurface tile runoff at the Eagle Creek watershed site. The effects of cover crop and VRT nutrient application on sediment and nutrient runoff were assessed from October 2012 to September 2020. Cover crops were applied in fall of 2016, 2017, and 2018, coinciding with VRT applications. The following parameters were analyzed as part of the study: runoff discharge; peak discharge; and concentrations and loads of total phosphorus, particulate phosphorus, dissolved reactive phosphorus, and suspended sediment. High peak runoff events disproportionally affected nutrient concentrations and loads in runoff. A threshold of the 85th percentile of the peak discharge was chosen to assess the effect of cover crop and VRT nutrient application on nutrient mitigation at each gage. Runoff events below the 85th percentile were considered small, and runoff events over the 85th percentile were considered large. Concentrations from collected water-quality samples were used for the analysis; estimated concentrations were excluded from the statistical evaluation. All surface runoff parameters during small runoff events, except surface runoff volume, were significantly lower in the period with cover crops and VRT implementation. Contrarily, subsurface runoff parameters during small events were not statistically different between the periods with and without cover crops and VRT implementation. Surface and subsurface parameters during large events were also not statistically different between the periods with and without cover crops and VRT implementation. These results indicate cover crops and VRT may improve water quality during small runoff events, but additional best management practices that mitigate large runoff events may lead to greater water-quality improvement given the contribution of large events to overall losses.

Ohio

Geology and geochemistry of Jurassic plutonic rocks, Baboquivari Mountains, south-central Arizona

Among the plutons of the Jurassic magmatic arc segment in southern Arizona, northern Sonora, and southern California, two distinctive rock types dominate, occurring together in numerous mountain ranges: porphyritic, titanite-bearing hornblende-biotite granodiorite; and biotite leucogranite. These characteristic rocks are particularly well preserved and well exposed around Kitt Peak, in the Baboquivari Mountains, southern Arizona. The Middle to early Late Jurassic Kitt Peak Plutonic Suite (KPPS) comprises three units: Aguirre Peak Quartz Diorite (APQD;<170 Ma, >=165 Ma, U-Pb), chiefly hornblende mesodiorite; Kitt Peak Granodiorite (KPGD; 165 Ma), hornblende-biotite granodiorite and monzogranite; and Pavo Kug Granite (PKG; 159 Ma), equigranular biotite leucogranite. This range also hosts a fourth, regionally unusual, Jurassic plutonic unit: the Baboquivari Peak Perthite Granite, related to post-arc, Late Jurassic crustal extension. Binary variation diagrams, incompatible element patterns, and REE spectra indicate APQD and KPGD are consanguineous. APQD basaltic mesodiorite evidently approximates the parental magma for the APQD–KPGD series. More evolved rocks of this series evidently formed by combinations of fractional crystallization and mixing with or assimilation of crustal material. PKG is less directly related to APQD and KPGD than these two are to one another.

Arizona, Sonora

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California

Stream sediment geochemistry in mineral exploration: A review of fine-fraction, clay-fraction, bulk leach gold, heavy mineral concentrate and indicator mineral chemistry

Stream sediment surveys support early-stage reconnaissance mineral exploration and regional assessment programmes, enhanced by recent improvements in analytical method detection limits, continuously improving mineral chemistry, and new approaches to the interpretation of geochemical data. Sediment surveys may be used to predict catchment basin lithology, mineralization type based on pathfinder geochemistry, and geological features based on indicator mineral chemistry. Sediment surveys that target a finer-fraction sediment sample led to the discovery of the La Colosa gold deposit, Colombia. The Batu Hijau porphyry Cu–Au deposit in Indonesia was discovered based on an anomalous clay-sized fraction sample 12 km downstream. In an arid region with poorly developed drainages and minor topographic relief, the Ag-base-metal Navidad District in Argentina was discovered with clay-fraction sediment geochemistry. Heavy mineral concentrate (HMC) sediment surveys that include mineral chemistry determinations have led to global diamond discoveries. HMC surveys contributed to discovery of the Ring of Fire Ni–Cu–PGE and chromite district, Ontario, Canada. Discoveries and geochemical mapping can assist advancement of the application of stream sediment geochemistry in those global areas for which lithologies and deposits are exposed. Stream sediment surveys continue to be one of the most cost-effective geochemical methods for covering large areas for mineral exploration.

Geochemistry: Exploration, Environment, Analysis

U-Pb scheelite ages of tungsten and antimony mineralization in the Stibnite-Yellow Pine district, central Idaho

The Stibnite-Yellow Pine district contains the largest antimony resource in the United States, as well as significant gold, and is a historic producer of tungsten. Application of in situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) direct dating of scheelite from two Au-Sb-W ore deposits, Yellow Pine and Hangar Flats, yielded an older group of U-Pb ages in the range of 60.0 ± 2.8 to 57.0 ± 1.1 Ma and a younger U-Pb age for scheelite intergrown with stibnite of 47.4 ± 1.1 Ma. These in situ analyses were calibrated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb lower intercept ages of two coarsely crystalline scheelite samples that yielded ages of 57.52 ± 0.22 and 56.62 ± 0.16 Ma. Scheelite of the latter age is of sufficient quality to serve as a primary reference material for LA-ICP-MS scheelite U-Pb geochronology. The group of older U-Pb scheelite ages agrees with 40 Ar/ 39 Ar ages of 56.9 ± 1.2 to 56.38 ± 0.54 Ma on adularia from Yellow Pine and Hangar Flats, whereas the younger U-Pb scheelite age is similar to an 40 Ar/ 39 Ar age of 46.00 ± 0.40 Ma on adularia from an epithermal gold-silver deposit in the adjacent Thunder Mountain caldera. Our results indicate that the main stage of tungsten mineralization occurred at ca. 57 Ma, whereas the main stage of antimony mineralization occurred at ca. 47 Ma—thereby providing first-time age constraints for antimony and tungsten mineralization in the Stibnite-Yellow Pine district.

Idaho

Sensitivity of Alabama freshwater gastropod species to nickel exposure

Snails are effective bioindicators due to their prolific distribution, high level of endemism, and capacity to accumulate contaminants. Freshwater snails have unique ecological niches which are imperiled by land‐use change and the introduction of hazardous chemicals. To assess how environmental alterations affect gastropods, lab‐based studies are needed to characterize the toxicity of specific stressors. This can help guide policy decisions and remediation efforts. The aim of this research was to characterize acute toxicity of nickel (Ni) on endemic snails ( Somatogyrus georgianus [Walker, 1904], Elimia cahawbensis [Lea, 1861], and Elimia spp.) and measure the accumulation of Ni and mineral elements including calcium (Ca), magnesium, potassium, and sodium (Na). Snails were exposed to six concentrations (25–800 µg/L) of Ni for 96 h. Among the studied snail species, E. cahawbensis was the most sensitive to Ni, with the lowest lethal concentration where 50% of the organisms died (LC50) at 88.88 µg/L Ni after 96 h. The LC50 at 96 h for S. georgianus was 167.78 µg/L Ni, and 393.13 μg/L Ni for Elimia spp. Except for Elimia spp., mortality of the other two snail species corresponded to the whole‐body uptake of Ni. Nickel exposure also influenced Ca and Na uptake for Elimia spp. All three endemic species are potential candidate species for evaluating localized effects of human activities, and the present study provides a first step in characterizing how snails would be affected by environmental alterations. More research could further characterize potential effects of other human stressors on these endemic snail species. Future research into subindividual responses and routes of exposure can further elucidate variations in species sensitivity.

Alabama

Nanometer-scale relationships between sedimentary organic matter molecular composition, fluorescence, cathodoluminescence, and reflectance: The importance of oxygen content at low thermal maturities

Molecular characterization of sedimentary organic matter (SOM), termed macerals, is a common goal when seeking to understand petroleum generation as well as other geologic processes in deep time. However, unambiguous measurement of discrete macerals is challenging due to the small size of organic particles in sedimentary rocks, the proximity of different organic matter types to one another, mineral-organic matter interactions, and maceral mixing that occurs during SOM isolation prior to ex situ analysis. The recent advent of infrared spectrometers capable of nanometer-scale resolution and the application of these technologies to geologic samples has enabled advances in rapid, in situ molecular characterization of SOM allowing for insights into paleoenvironmental processes, such as organic matter productivity and preservation, among others. Here we employ one such technology, optical photothermal infrared (OPTIR) spectroscopy, to map SOM functional group distributions at 500-nm resolution in a sample from the Lower Cretaceous Sunniland Limestone of the South Florida Basin. Examined fields of view include occurrences of amorphous organic matter (AOM), inertinite, micrinite, solid bitumen, telalginite, and vitrinite. OPTIR data from these macerals are compared against traditional organic petrographic data from the same organic grains including fluorescence intensity and white light reflectance as well as against cathodoluminescence response, an emerging organic petrographic approach. Maceral oxygen content (using carbonyl functional group abundance as a proxy) is observed to vary widely between maceral types but correlates strongly with fluorescence and cathodoluminescence intensity as well as against reflectance. These findings highlight the important role that oxygen content plays in determining the optical properties of SOM and further demonstrate the ability of OPTIR to discriminate subtle molecular differences between SOM types.

Organic Geochemistry

Case study of deep learning image segmentation for the purposes of rapid 2D petrographic analysis in volcanic rocks

Automation using deep learning methods is a useful alternative to manual methods of petrographic segmentation, but often requires user familiarity with coding and/or algorithms. We examine the Dragonfly TM program's deep learning tools for application by users with a variety of skill levels as a method for petrographic image segmentation. An image processing methodology, bimodal image stacking, was created for low-input-data, high-efficacy training of models which can then be applied to varied samples. Using backscatter electron images we show that the resulting model segmentations agree with manual segmentation total and modal crystallinity values within 5%, and calculated plagioclase crystal size distribution (CSD) values within 2σ, despite limitations in discriminating mafic phases. Model creation and training takes <24 hours, 1–3 hours of which are supervised, and the resultant model can then be applied to new uncharacterized samples in <15 minutes per image. This allows for non-experts to create and utilize deep learning models to segment images of variable brightness and texture, at low user-time cost and resulting in size and shape data which are within uncertainty of manual segmentation. While some limitations are noted (for example, sieve-textured phases may need manual correction, and different minerals with similar BSE intensity may not be resolved as separate phases), this methodology can be utilized for general application of models to wide ranges of volcanic crystalline and bubble textures, and to create a library of models for rapid petrological analysis during volcanic eruptions.

Alaska

Using gridded seismicity to forecast the long-term spatial distribution of earthquakes for the 2025 Puerto Rico and U.S. Virgin Islands National Seismic Hazard Model

Gridded (or background) seismicity models are a critical component of probabilistic seismic hazard assessments, accounting for off‐fault and smaller‐magnitude earthquakes. They are typically developed by declustering and spatially smoothing an earthquake catalog to estimate a long‐term seismicity rate that can be used to forecast future earthquakes. Here, we present new gridded seismicity models for use in the 2025 National Seismic Hazard Model (NSHM) for Puerto Rico and the U.S. Virgin Islands (PRVI). The previous PRVI NSHM was released in 2003, and our new models incorporate updates to both data and methodology. We utilize an updated earthquake catalog based on improved Puerto Rico Seismic Network data with newly characterized completeness epochs. The catalog is divided into crustal, subduction interface, and intraslab seismicity using new methods and Slab2 subduction zone geometries. To forecast the long‐term spatial distribution of earthquakes, we use an updated methodology developed for the 2023 U.S. 50‐state NSHM, considering three declustering methods and two spatial smoothing methods based on 2D Gaussian kernels. To adapt it for the complex seismotectonics of the region, we also adopt probabilistic methods to account for events with unknown depths and uncertainties in tectonic classification, and develop a new method for spatial scaling to counteract the effects of spatial variability in network coverage while maintaining the use of smaller events. Finally, we test the performance of these spatial models in forecasting the location of M w ≥ 5earthquakes in the region. Our updated methodology improves the representation of epistemic uncertainty relative to the 2003 model, and our results demonstrate the effectiveness of the new measures we have introduced to address heterogeneities in network detection and systematically evaluate forecast performance.

Puerto Rico, U.S. Virgin Islands