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At least 793 records · Page 44Linked to original sources
USGS2000

Regoliths of the middle-Atlantic Piedmont and evolution of a polymorphic landscape

The regolith overlying the alumino-silicate rocks of the middle-Atlantic Piedmont Province consists primarily of saprolite with a thin veneer of diamictons of colluvial origin. Thickness and distribution of the saprolite is related to landform and lithology. For example, on uplands isovolumetric weathering of the Loch Raven Schist produces saprolite averaging 55 ft (17 m) thick. On Port Deposit Gneiss, saprolite beneath uplands averages 42 ft (13 m) in thickness. The saprolite results from the reaction of alumino-silicate rocks with through-flowing groundwater. Chemical weathering of the rock results in clay and resistate minerals, residual rock layers, corestones, and pinnacles. Surface erosion of saprolite with quartzite and metagraywacke residual layers may produce a 'washboard' topography. Surface erosion of a metagabbro saprolite containing corestones and pinnacles results in a surface with lag deposits of corestones and emergent pinnacles. The diamicton material comes from the underlying saprolite, weathered rock and bedrock. Generally, diamictons are thinner on uplands and upper slopes, and thicker at the base of slopes and in hollows and gathering areas of first-order streams. The saprolite and colluvium reflect response of geomorphic processes (chemical weathering, fluvial incision, and periglacial processes) to rock lithology and landscape. The modifications to the landscape have been driven by neotectonic crustal warping and alternating periglacial-humid temperate climates. Altogether these varied interactions have resulted in a Holocene polymorphic landscape.

Southeastern Geology↗
USGS1969

Distribution of oxygen and carbon isotopes in fossils of late cretaceous age, western interior region of North America

The oxygen isotope composition of both calcite and aragonite of the pelecypod Inoceramus is lighter than the composition of the aragonite of associated baculites and other cephalopods from the western interior region, the Gulf and Atlantic Coastal Plains, parts of Canada, and West Greenland. This difference cannot be explained by biotic and oceanographic factors or by postdepositional alteration of original isotopic compositions. Metabolic fractionation of oxygen isotopes by Inoceramus is strongly implied by the data and is not contradicted by what is known of the processes involved in the biologic deposition of shell carbonate. In addition, the oxygen isotope compositions of the inocerams and of some baculites are so light as to indicate temperatures greater than 30° C, which is too high for mollusks to tolerate. The unreasonable range of the indicated temperatures seems to be partly the result of metabolic fractionation of oxygen and partly the result of the Late Cretaceous sea in the western interior region having had a light oxygen isotope composition because of dilution with fresh water. The carbon isotope composition of the aragonite from Inoceramus is consistently heavier than that of the calcite in the same specimen by amounts ranging from 1 to 3 per mil. Metabolic fractionation of carbon isotopes within Inoceramus thus is indicated. The carbon isotope composition of the aragonite from baculites and other cephalopods is consistently lighter than that in either the aragonite or calcite in Inoceramus, indicating either that the cephalopods fractionated carbon isotopes from the dissolved carbonate in sea water differently than did inocerams or that the cephalopods utilized carbon of a different isotopic composition, probably from their food source, for their metabolic processes. While oxygen isotope data from the inocerams are not useful for paleotemperature interpretations, the oxygen isotope data from the baculites, if taken at face value, suggest either warmer temperatures for the western interior sea than around the periphery of Cretaceous North America, or water of oxygen isotope composition lighter than world oceans, or both. Data from British Columbia, southeastern Alaska, and West Greenland to the Gulf Coastal Plain do not indicate a well-developed latitudinal distribution of temperature in Late Cretaceous time. A general decline in temperatures during late Campanian and early Maestrichtian time is not evident. © 1969, The Geological Society of America, Inc.

Geological Society of America Bulletin↗
USGS2018

Subsurface controls on the development of the Cape Fear Slide Complex, central US Atlantic Margin

The Cape Fear Slide is one of the largest (>25 000 km 3 ) submarine slope failure complexes on the US Atlantic margin. Here we use a combination of new high-resolution multichannel seismic data (MCS) from the National Science Foundation Geodynamic Processes at Rifting and Subducting Margins (NSF GeoPRISMS) Community Seismic Experiment and legacy industry MCS to derive detailed stratigraphy of this slide and constrain the conditions that lead to slope instability. Limited outer-shelf and upper-slope accommodation space during the Neogene, combined with lowstand fluvial inputs and northwards Gulf Stream sediment transport, appears to have contributed to thick Miocene and Pliocene deposits that onlapped the lower slope. This resulted in burial of an upper-slope bypass zone developed from earlier erosional truncation of Paleogene strata. These deposits created a broad ramp that allowed accumulation of thick Quaternary strata across a low-gradient (<3.5°) upper slope. Upslope of one of the larger headwalls, undulating Quaternary strata appear to downlap onto a buried failure plane. Many of the nested headwalls of the upper-slope portion of slide complex are underlain by deformed strata, which may be the result of fluid migration associated with localized subsidence from salt migration. These new data and observations suggest that antecedent margin physiography, sediment loading and substrate fluid flow were key factors in preconditioning the Cape Fear slope for failure.

Geological Society of London Special Publications↗
USGS1973

Glauconites from New Jersey-Maryland coastal plain: Their K-Ar ages and application in stratigraphic studies

Glauconite samples from various stratigraphic levels in the northern Atlantic Coastal Plain were dated by the K-Ar method. Twenty-eight samples were collected from glauconite-bearing sands in four traverses across the outcrop belt of Upper Cretaceous–lower Tertiary formations from northern New Jersey to eastern Maryland, thus providing a framework on which to test the reliability of glauconite for dating in vertical sequences and within some formations along strike. Sample ages were determined paleontologically and radiogenically. The results show that most radiogenic determinations of glauconite followed a systematic pattern; the resultant ages were generally younger upward through the Stratigraphic section. In addition, consistent ages were obtained from many of the stratigraphic units along strike. A combination of paleontologically derived ages and the numerical radiogenic ages suggests that the stages of the Late Cretaceous are unequal rather than equal as some have proposed. For example, Campanian and Paleocene times are of significantly greater duration than the Maestrichtian. Several samples obtained across the Cretaceous-Tertiary boundary indicate that the age of the boundary is between 63.2 and 59.1 m.y., probably very near 61.1 m.y. Dates considered to be reliable were obtained from 25 of 28 samples. Two of the three discordant ages are ascribed to incomplete glauconitization of the pre-existing mineral phase and hence to mineral impurity. No adequate explanation for the third significantly younger age has been determined.

Delaware, Maryland, New Jersey, Pennsylvania↗
USGS2022

Pennsylvania and Landsat

The Commonwealth of Pennsylvania straddles an array of landscapes. From east to west, its 46,055 square miles connect the sea-level lowlands of the Atlantic seaboard with the rolling hills of the Midwest. It also acts as a bridge between regions from north to south, with the Appalachian Mountains swooping through its center from its northern border with New York to its southern borders with Maryland and West Virginia. The Declaration of Independence and U.S. Constitution were signed in the Commonwealth’s largest city, Philadelphia, and it was the second of the original 13 colonies to ratify the Constitution. The pivotal Civil War battle of Gettysburg took place in the southern part of Pennsylvania. Western Pennsylvania was an early hub for the coal, oil, and steel industries that fueled the Nation’s growth in the 20th century and still factor into Pennsylvania’s economy. The varied natural features of Pennsylvania have been an important proving ground for the value of satellite imagery from the USGS Landsat Program. Scientists began to lean on Landsat observations early in the program’s history to map the effect of invasive moths on Commonwealth forests. That activity continues to this day. Space-based imagery has also contributed to the study and management of land change from energy development, urban growth, and shifting land use patterns. The Landsat Program’s unparalleled 50-year archive of repeat Earth observations remains a critical public resource for Pennsylvania as environmental changes and land use patterns present new challenges to land managers and urban planners in the Keystone State.

Pennsylvania↗
USGS2003

Hydrogeology and Ground-Water Quality of Brunswick County, North Carolina

Brunswick County is the southernmost coastal county in North Carolina and lies in the southeastern part of the Coastal Plain physiographic province. In this report, geologic, hydrologic, and chemical data were used to investigate and delineate the hydrogeologic framework and ground-water quality of Brunswick County. The major aquifers and their associated confining units delineated in the Brunswick County study area include, from youngest to oldest, the surficial, Castle Hayne, Peedee, Black Creek, upper Cape Fear, and lower Cape Fear aquifers. All of these aquifers, with the exception of the Castle Hayne aquifer, are located throughout Brunswick County. The Castle Hayne aquifer extends across only the southeastern part of the county. Based on available data, the Castle Hayne and Peedee confining units are missing in some areas of Brunswick County, which allows direct hydraulic contact between the surficial aquifer and underlying Castle Hayne or Peedee aquifers. The confining units for the Black Creek, upper Cape Fear, and lower Cape Fear aquifers appear to be continuous throughout Brunswick County. In examining the conceptual hydrologic system for Brunswick County, a generalized water budget was developed to better understand the natural processes, including precipitation, evapotranspiration, and stream runoff, that influence ground-water recharge to the shallow aquifer system in the county. In the generalized water budget, an estimated 11 inches per year of the average annual precipitation of 55 inches per year in Brunswick County is estimated to infiltrate and recharge the shallow aquifer system. Of the 11 inches per year that recharges the shallow system, about 1 inch per year is estimated to recharge the deeper aquifer system. The surficial aquifer in Brunswick County is an important source of water for domestic supply and irrigation. The Castle Hayne aquifer is the most productive aquifer and serves as the principal ground-water source of municipal supply for the county. The upper part of the Peedee aquifer is an important source of ground-water supply for domestic and commercial use. Ground water in the lower part of the Peedee aquifer and the underlying aquifers is brackish and is not known to be used as a source of supply in Brunswick County. Most of the precipitation that recharges the surficial aquifer is discharged to local streams that drain into the Waccamaw River, Cape Fear River, and Atlantic Ocean. Recharge to the Castle Hayne aquifer occurs primarily from the surficial aquifer. Recharge to the Peedee aquifer occurs primarily from the surficial and Castle Hayne aquifers, with some upward leakage of water also occurring from the underlying Black Creek aquifer. Discharge from the Castle Hayne and Peedee aquifers occurs to local streams, the Cape Fear River, and the Atlantic Ocean. Evaluation of water-level data for the period January 1970 through May 2002 indicated no apparent long-term temporal trends in water levels in the surficial and Castle Hayne aquifers and in the upper part of the Peedee aquifer. The most significant water-level trends were noted for wells tapping the lower part of the Peedee aquifer and tapping the Black Creek aquifer where water levels have declined as much as 41 and 37 feet, respectively. These ground-water-level declines are attributed to regional ground-water pumping in areas outside of Brunswick County. Water-level data for Brunswick County wells tapping the upper Cape Fear and lower Cape Fear aquifers tend to fluctuate within a fairly uniform range with no apparent temporal trend noted. Analysis of vertical hydraulic gradients during this same period primarily indicate downward flow of ground water within and among the surficial, Castle Hayne, and Peedee aquifers. The vertical flow of ground water in the Black Creek aquifer is upward into the overlying Peedee aquifer. Upward flow also is noted for the upper and lower Cape Fear aquifers. Historic and recent analytic data were evaluated to better understand the sources of water contained in Brunswick County aquifers and the suitability of the water for consumption. Based on analytical results obtained for recent samples collected during this study, ground water from the surficial aquifer, Castle Hayne aquifer, and upper part of the Peedee aquifer appears to be generally suitable for drinking water. Although concentrations of iron and manganese commonly exceeded the drinking-water standards, the concern generally associated with the occurrence of these analytes in a water supply is one of aesthetics. In all samples, nitrate, nitrite, and sulfate were detected at concentrations less than drinkingwater standards. Based on historic analytical data, the brackish water in the lower part of the Peedee aquifer and in the Black Creek, upper Cape Fear, and lower Cape Fear aquifers is classified as a sodium-chloride type water. The presence of brackish water in these deeper systems combined with upward vertical gradients presents the potential for upward migration of brackish water into overlying aquifers, or upconing beneath areas of pumping. The current (2001) location of the boundary between freshwater and brackish water in Brunswick County aquifers is unknown.

North Carolina↗
USGS2025

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States↗
USGS1963

Geology and ground-water conditions in southern Nassau and southeastern Queens Counties, Long Island, N.Y.

Test drilling, electrical logging, and water sampling of 'outpost' and other wells have revealed the existence of a deep confined body of salt water in the Magothy(?) formation beneath southwestern Nassau and southeastern Queens Counties, Long Island, N.Y. In connection with a test-drilling program, cooperatively sponsored by the U.S. Geological Survey, the Nassau County Department of Public Works, and the New York State Water Resources Commission (formerly Water Power and Control Commission), 13 wells ranging in depth from about 130 to 800 feet were drilled during 1952 and 1953 and screened at various depths in the Magothy(?) formation and Jameco gravel. On the basis of the preliminary geologic, hydrologic, and chemical data from these wells, a detailed investigation of ground-water conditions from the water table to the bedrock was begun in a 200-square-mile area in southern Nassau and southeastern Queens Counties. The Inain purposes of the investigation were to delineate the bodies of fresh and salty ground water in the project area, to relate their occurrence and movement to geologic and hydrologic conditions, to estimate the rate of encroachment, if any, of the salty water, and to evaluate the effectiveness of the existing network of outpost wells as detectors of salt-water encroachment. About a million people in the report area, residing mainly in southern Nassau County, are completely dependent on ground water as a source of supply. Fortunately, precipitation averages about 44 inches per year, of which approximately half is estimated to percolate into the ground-water reservoir. The ground water is contained in and moves through eight differentiated geologic units composed of unconsolidated gravel, sand, and clay, of Late Cretaceous, Pleistocene, and Recent age, having a maximum total thickness of about 1,700 feet. The underlying metamorphic and igneous crystalline basement rocks are of Precambrian age and are not water bearing. The water-yielding units from the surface down are (1) the upper Pleistocene deposits, (2) the principal artesian aquifer, composed of the Jameco gravel and Magothy(?) formation, and (3) the Lloyd sand member of the Raritar formation. The confining units are the '20-foot' clay, the Gardiners clay, and the clay member of the Raritan formation. The upper Pleistocene deposits contain an extensive unconfined body of fresh water. Fresh water under artesian conditions is contained in the principal artesian aquifer and the Lloyd sand member. The piezometric surface of the principal artesian aquifer is similar in shape to the south-ward-sloping water table; it ranges in altitude from about sea level to 55 feet above. The chemical quality of the fresh ground water in most of the area in all aquifers is good to excellent, and concentrations of dissolved solids and of chloride generally are below 100 ppm (parts per million) and 10 ppm, respectively. Analyses of water samples from selected wells show no progressive increase in concentration of chloride in most of the area. The data on quality of water have been used to delineate one major and several minor bodies of salty ground water. The wedgeshaped main confined salt-water body, in which the concentration of chloride reaches about 17,000 ppm, is in the Magothy(?) formation and Jameco gravel in extreme southwestern Nassau County and southeastern Queens County. The base of the salt-water wedge is about at the top of the clay member of the Raritan formation. Beneath the barrier beach in south-central and southeastern Nassau County a shallow extension of the main confined salt-water body contains as much as 4,000 ppm of chloride and is separated from the lower main salt-water body by fresh ground water. Shallow, thin bodies of unconfined salty ground water are common in the upper Pleistocene and Recent deposits adjacent to salty surface water in tidal creeks, bays, and the Atlantic

New York↗
USGS1997

Sr-isotopic evidence for leakage of pore water from clay-silt confining units to the Atlantic City 800-foot sand, Atlantic City, New Jersey

The evolution of water quality in confined aquifers in the New Jersey Coastal Plain may be affected by leakage of pore water from the adjacent confining units. We investigated the distribution and sources of solutes, particularly Sr, in pore water mechanically extracted from clay-silt core samples collected from depths of 552–840 ft (168–256 m) in the lower Miocene Kirkwood Formation at Atlantic City, New Jersey (Ocean Drilling Program Leg 150X). The sampled sediments consist of thin clay-silt stringers in the upper part of the Atlantic City 800-ft sand, a major aquifer, and the massive clay-silt units above and below it. The distribution of Sr and the ratio of 87 Sr to 86 Sr in the pore water and adjacent shell material were used to identify the possible sources of, and physical processes that may affect the distribution of, Sr in the pore water. Concentrations of Sr in 14 pore-water samples from the clay-silt unit above the aquifer and the clay-silt interbeds in the upper part of the aquifer ranged from 2.74 to 28.19 µM/L; those in the four pore-water samples from the clay-silt unit below the aquifer ranged from 0.52 to 7.30 µM/L. Concentrations of Sr in the samples varied with depth but correlated strongly with pore-water concentrations of Ca, Mg, Na, and SO4. Cation-exchange processes may be responsible, in part, for the lower concentrations of Sr, Ca, and Mg in pore water from the clay-silt unit below the aquifer than in that above the aquifer. 87 Sr/ 86 Sr values in 11 samples of aragonitic mollusk shells (bearing no visible evidence of recrystallization) collected from depths in the clay-silt unit similar to those from which the pore-water samples were collected ranged from 0.708468 to 0.708713 , and decreased (Sr in the shells was less radiogenic) with depth. This trend is consistent with the decrease in the 87 Sr/ 86 Sr value in seawater through time during the early Miocene. The 87 Sr/ 86 Sr values in 12 pore-water samples from the studied stratigraphic interval ranged from 0.708257 to 0.708527 and also decreased with depth. The Sr-isotope ratios in the pore water were lower than those in the shell material from nearby or adjacent sediments for all samples but one. Because the only known source of Sr with an isotope ratio this low is shell material from sediments deeper than the strata from which the pore-water samples were collected (including pre-Miocene stratigraphic units), the isotope ratio in the pore-water samples from the lower Miocene claysilt units may result from upward movement of pore water into lower Miocene strata through geologic time, which could create the observed difference in Sr isotope ratios between the pore water and shells.

New Jersey↗
USGS2008

Simulation of the Quantity, Variability, and Timing of Streamflow in the Dennys River Basin, Maine, by Use of a Precipitation-Runoff Watershed Model

The U.S. Geological Survey (USGS), in cooperation with the Maine Department of Marine Resources Bureau of Sea Run Fisheries and Habitat, began a study in 2004 to characterize the quantity, variability, and timing of streamflow in the Dennys River. The study included a synoptic summary of historical streamflow data at a long-term streamflow gage, collecting data from an additional four short-term streamflow gages, and the development and evaluation of a distributed-parameter watershed model for the Dennys River Basin. The watershed model used in this investigation was the USGS Precipitation-Runoff Modeling System (PRMS). The Geographic Information System (GIS) Weasel was used to delineate the Dennys River Basin and subbasins and derive parameters for their physical geographic features. Calibration of the models used in this investigation involved a four-step procedure in which model output was evaluated against four calibration data sets using computed objective functions for solar radiation, potential evapotranspiration, annual and seasonal water budgets, and daily streamflows. The calibration procedure involved thousands of model runs and was carried out using the USGS software application Luca (Let us calibrate). Luca uses the Shuffled Complex Evolution (SCE) global search algorithm to calibrate the model parameters. The SCE method reliably produces satisfactory solutions for large, complex optimization problems. The primary calibration effort went into the Dennys main stem watershed model. Calibrated parameter values obtained for the Dennys main stem model were transferred to the Cathance Stream model, and a similar four-step SCE calibration procedure was performed; this effort was undertaken to determine the potential to transfer modeling information to a nearby basin in the same region. The calibrated Dennys main stem watershed model performed with Nash-Sutcliffe efficiency (NSE) statistic values for the calibration period and evaluation period of 0.79 and 0.76, respectively. The Cathance Stream model had an NSE value of 0.68. The Dennys River Basin models make use of limited streamflow-gaging station data and provide information to characterize subbasin hydrology. The calibrated PRMS watershed models of the Dennys River Basin provide simulated daily streamflow time series from October 1, 1985, through September 30, 2006, for nearly any location within the basin. These models enable natural-resources managers to characterize the timing and quantity of water moving through the basin to support many endeavors including geochemical calculations, water-use assessment, Atlantic salmon population dynamics and migration modeling, habitat modeling and assessment, and other resource-management scenario evaluations. Characterizing streamflow contributions from subbasins in the basin and the relative amounts of surface- and ground-water contributions to streamflow throughout the basin will lead to a better understanding of water quantity and quality in the basin. Improved water-resources information will support Atlantic salmon protection efforts.

Scientific Investigations Report↗
USGS2010

An initial SPARROW model of land use and in-stream controls on total organic carbon in streams of the conterminous United States

Watersheds play many important roles in the carbon cycle: (1) they are a site for both terrestrial and aquatic carbon dioxide (CO2) removal through photosynthesis; (2) they transport living and decomposing organic carbon in streams and groundwater; and (3) they store organic carbon for widely varying lengths of time as a function of many biogeochemical factors. Using the U.S. Geological Survey (USGS) Spatially Referenced Regression on Watershed Attributes (SPARROW) model, along with long-term monitoring data on total organic carbon (TOC), this research quantitatively estimates the sources, transport, and fate of the long-term mean annual load of TOC in streams of the conterminous United States. The model simulations use surrogate measures of the major terrestrial and aquatic sources of organic carbon to estimate the long-term mean annual load of TOC in streams. The estimated carbon sources in the model are associated with four land uses (urban, cultivated, forest, and wetlands) and autochthonous fixation of carbon (stream photosynthesis). Stream photosynthesis is determined by reach-level application of an empirical model of stream chlorophyll based on total phosphorus concentration, and a mechanistic model of photosynthetic rate based on chlorophyll, average daily solar irradiance, water column light attenuation, and reach dimensions. It was found that the estimate of in-stream photosynthesis is a major contributor to the mean annual TOC load per unit of drainage area (that is, yield) in large streams, with a median share of about 60 percent of the total mean annual carbon load in streams with mean flows above 500 cubic feet per second. The interquartile range of the model predictions of TOC from in-stream photosynthesis is from 0.1 to 0.4 grams (g) carbon (C) per square meter (m-2) per day (day-1) for the approximately 62,000 stream reaches in the continental United States, which compares favorably with the reported literature range for net carbon fixation by phytoplankton in lakes and streams. The largest contributors per unit of drainage area to the mean annual stream TOC load among the terrestrial sources are, in descending order: wetlands, urban lands, mixed forests, agricultural lands, evergreen forests, and deciduous forests . It was found that the SPARROW model estimates of TOC contributions to streams associated with these land uses are also consistent with literature estimates. SPARROW model calibration results are used to simulate the delivery of TOC loads to the coastal areas of seven major regional drainages. It was found that stream photosynthesis is the largest source of the TOC yields ( about 50 percent) delivered to the coastal waters in two of the seven regional drainages (the Pacific Northwest and Mississippi-Atchafalaya-Red River basins ), whereas terrestrial sources are dominant (greater than 60 percent) in all other regions (North Atlantic, South Atlantic-Gulf, California, Texas-Gulf, and Great Lakes).

Conterminous United States↗
USGS2017

The role of deep-water sedimentary processes in shaping a continental margin: The Northwest Atlantic

The tectonic history of a margin dictates its general shape; however, its geomorphology is generally transformed by deep-sea sedimentary processes. The objective of this study is to show the influences of turbidity currents, contour currents and sediment mass failures on the geomorphology of the deep-water northwestern Atlantic margin (NWAM) between Blake Ridge and Hudson Trough, spanning about 32° of latitude and the shelf edge to the abyssal plain. This assessment is based on new multibeam echosounder data, global bathymetric models and sub-surface geophysical information. The deep-water NWAM is divided into four broad geomorphologic classifications based on their bathymetric shape: graded, above-grade, stepped and out-of-grade. These shapes were created as a function of the balance between sediment accumulation and removal that in turn were related to sedimentary processes and slope-accommodation. This descriptive method of classifying continental margins, while being non-interpretative, is more informative than the conventional continental shelf, slope and rise classification, and better facilitates interpretation concerning dominant sedimentary processes. Areas of the margin dominated by turbidity currents and slope by-pass developed graded slopes. If sediments did not by-pass the slope due to accommodation then an above grade or stepped slope resulted. Geostrophic currents created sedimentary bodies of a variety of forms and positions along the NWAM. Detached drifts form linear, above-grade slopes along their crests from the shelf edge to the deep basin. Plastered drifts formed stepped slope profiles. Sediment mass failure has had a variety of consequences on the margin morphology; large mass-failures created out-of-grade profiles, whereas smaller mass failures tended to remain on the slope and formed above-grade profiles at trough-mouth fans, or nearly graded profiles, such as offshore Cape Fear.

Marine Geology↗
USGS1992

Mid-Mesozoic (Mid-Jurassic to Early Cretaceous) evolution of the Georges Bank Basin, U.S. North Atlantic outer continental shelf: Sedimentology of the Conoco 145-1 well

The Conoco 145-1 exploratory well, located in the southeastern portion of the Georges Bank Basin, was drilled to a total depth of 4303 m below the sea floor. The oldest sedimentary rocks sampled are of Middle Jurassic age (Late Bathonian-Callovian). A dolomite-limestone-evaporite sequence dominates the section below 3917 m; limestone is the predominant lithology in the intervals of 3271-3774 m, 2274-3158 m, and 1548-1981 m. Siliciclastics dominate the remainder of the drilled section. Calcite tightly cements most of the rocks below 1548 m; dolomite, silica, siderite, and diagenetic clay cements are locally important. Restricted inner marine environments, representing lagoonal and tidal flat conditions, prevailed at the wellsite during much of the deposition recorded by the Callovian-Bathonian age Iroquois Formation. These environments gave way to a carbonate platform, which formed part of the > 5,000 km long Bahama-Grand Banks gigaplatform that lasted through the end of the Late Jurassic (encompassing the uppermost portion of the Iroquois Formation and the Scatarie Limestone and Bacarro Limestone Members of the Abenaki Formation). The absence of a skeletal-reef association and the dominance of muddy limestone fabrics are evidence that the 145-1 wellsite was located on the platform interior. Major periods of siticiclastic deposition interrupted carbonate deposition, and they are recorded by stratigraphic equivalents of the Mohican Formation, Misaine Shale Member of the Abenaki Formation, and the Mohawk and Mic Mac Formations. A series of sustained prograding delta systems, the earliest of which is preserved as the Missisauga Formation, buried the carbonate platform following its drowning in the Early Cretaceous (Berriasian-Valanginian). The sparser, primarily allochthonous lignite content and better-sorted, glauconite-bearing sands of the Missisauga strata at the 145-1 wellsite suggest that shallow marine or barrier-bar environments were more prevalent than the low delta-plain facies recorded farther shoreward at the COST G-1 wellsite.

Sedimentary Geology↗
USGS2006

Contaminant exposure and potential effects on terrestrial vertebrates residing in the National Capital Region network and Mid-Atlantic network

Part of the mission of the National Park Service is to preserve the natural resources, processes, systems, and associated values of its units in an unimpaired condition. Environmental contamination and pollution processes are well recognized stressors addressed by its management policies and plans. A recent study indicates that contemporary terrestrial vertebrate ecotoxicological data are lacking for 59 of 126 Park Service units located in coastal watersheds exhibiting serious water quality problems or high vulnerability to pollution. Based upon these findings, a more in-depth evaluation of contaminant threats and ecotoxicological data gaps related to terrestrial vertebrates was undertaken at 23 Inventory and Monitoring National Park units in National Capital Region and Mid-Atlantic Networks. Ecotoxicological data were compiled for each park unit through literature searches and meetings with Park Service personnel. Information on contemporary and on persistent legacy pollutants in air, water, soil, and terrestrial vertebrates (amphibians, reptiles, birds and mammals) were evaluated. To identify contaminant threats in proximity to the 23 Park Service study units, data was gathered on National Priority List Superfund sites, Section 303(d) Impaired Waterbodies, the number and relative toxicity of current use pesticides and herbicides, Toxic Release Inventory sites and discharge of priority pollutants, and Fish Consumption Advisories. A metric was derived that described the quality and quantity of existing data for each park, and in combination with known contaminant threats, park units in need of additional study were identified. Results demonstrated that over half of the Park Service study units are near Toxic Release Inventory sites discharging dioxins, polychlorinated biphenyls, lead or mercury into air or water, and fish consumption advisories are in effect at or near 22 of the 23 study units. Pesticide and herbicide use at the park units is minimal, with the exception of those units with significant agricultural leases. Despite highly regulated use, many of the pesticides and herbicides applied are believed to be highly toxic to amphibians, and some of the compounds are also highly toxic to birds. Only 70 reports were found that describe terrestrial vertebrate ecotoxicology data on or near the study units. Of the greater than 75,000 compounds in commerce in the United States, existing terrestrial vertebrate exposure and effects data in the pr esent study were limited to 58 legacy organochlorine pesticides, polychlorinated biphenyls and individual congeners, insecticides and rodenticides, metals, and some contemporary compounds (e.g., polybrominated diphenyl ether flame retardants, and alkylphenol and ethoxylate surfactants). Based upon these and other findings, ecotoxicological monitoring and research investigations of terrestrial vertebrates are warranted at several National Parks. These include Shenandoah National Park, Richmond National Battlefield, Chesapeake & Ohio Canal National Historic Park, Valley Forge National Historic Park, Hopewell Furnace National Historic Site, Monocacy National Battlefield, and Harpers Ferry National Historic Park. The types of investigations vary according to the species present at these parks and potential contaminant threats, but should focus on contemporary use pesticides and herbicides, polychlorinated biphenyls, mercury, lead, and perhaps, emerging contaminants including antibiotics, flame retardants, pharmaceuticals, and surfactants. Other management recommendations include additional training for natural resource staff members in the area of ecotoxicology, inclusion of terrestrial vertebrate contaminant monitoring and the Contaminant Assessment Process (U.S. Geological Survey Biomonitoring of Environmental Status and Trends Project) into the National Park Service Vital Signs Program, development of protocols for hand ling and toxicological analysis of dead or seemingly affected wildlife, consideration of some alternative methods and compounds for pest management and weed control, and use of non-toxic fishing tackle by visitors.

Maryland, Pennsylvania, Virginia↗
USGS2018

Paleoclimate Records: Providing context and understanding of current Arctic change

At present, the Arctic Ocean is experiencing changes in ocean surface temperature and sea ice extent that are unprecedented in the era of satellite observations, which extend from the 1980s to the present (see sections 5c,d). To provide context for current changes, scientists turn to paleoclimate records to document and study anthropogenic influence and natural decadal and multidecadal climate variability in the Arctic system. Paleoceanographic records extend limited Arctic instrumental measurements back in time and are central to improving our understanding of climate dynamics and the predictive capability of climate models. By comparing paleoceanographic records with modern observations, scientists can place the rates and magnitudes of modern Arctic change in the context of those inferred from the geological record. Over geological time, paleoceanographic reconstructions using, for instance, marine sediment cores indicate that the Arctic has experienced huge sea ice fluctuations. These fluctuations range from nearly completely ice-free to totally ice-covered conditions. The appearance of ice-rafted debris and sea ice-dependent diatoms in Arctic marine sediments indicate that the first Arctic sea ice formed approxi-mately 47 million years ago (St. John 2008; Stickley et al. 2009; Fig. SB5.1), coincident with an interval of declining atmospheric carbon dioxide (CO2) concentration, global climate cooling, and expansion of Earths cryosphere during the middle Eocene. The development of year-round (i.e., perennial) sea ice in the central Arctic Ocean, similar to conditions that exist today, is evident in sediment records as early as 1418 million years ago (Darby 2008). These records suggest that transitions in sea ice cover occur over many millennia and often vary in concert with the waxing and waning of circum-Arctic land ice sheets, ice shelves, and long-term fluctuations in ocean and atmospheric temperature and atmospheric CO2 concentrations (Stein et al. 2012; Jakobsson et al. 2014). Over shorter time scales, shallow sediment records from Arctic Ocean continental shelves allow more detailed, higher-resolution (hundreds of years resolution) reconstructions of sea ice history extending through the Holocene (11 700 years ago to present), the most recent interglacial period. A notable feature of these records is an early Holocene sea ice minimum, corresponding to a thermal maximum (warm) period from 11 000 to 5000 years ago, when the Arctic may have been warmer and had less summertime sea ice than today (Kaufman et al. 2004). However, it is not clear that the Arctic was ice-free at any point during the Holocene (Polyak et al. 2010). High-resolution paleosea ice records from the western Arctic in the Chukchi and East Siberian Seas indicate that sea ice concentrations increased through the Holocene in concert with decreasing summer solar insolation (sunlight). Sea ice extent in this region also varied in response to the volume of Pacific water delivered via the Bering Strait into the Arctic Basin (Stein et al. 2017; Polyak et al. 2016). Records from the Fram Strait (Mller et al. 2012), Laptev Sea (Hrner et al. 2016), and Canadian Arctic Archipelago (Vare et al. 2009) also indicate a similar long-term expansion of sea ice and suggest sea ice extent in these regions is modulated by the varying influx of warm Atlantic water into the Arctic Basin (e.g., Werner et al. 2013). Taken together, available records support a circum-Arctic sea ice expansion during the late Holocene. A notably high-resolution summer sea ice history (<5-year resolution) has been established for the last 1450 years using a network of terrestrial records (tree ring , lake sediment, and ice core records) located around the margins of the Arctic Ocean (Kinnard et al. 2011). Results summarized in Fig. SB5.2 indicate a pronounced decline in summer sea ice extent beginning in the 20th century, with exceptionally low ice extent recorded since the mid-1990s, consistent with the satellite record (see section 5d). While several episodes of reduced and expanded sea ice extent occur in association with climate anomalies such as the Medieval Climate Warm Period (AD 8001300) and the Little Ice Age (AD 14501850), the magnitude and pace of the modern decline in sea ice is outside of the range of natural variability and unprecedented in the 1450-year reconstruction (Kinnard et al. 2011). A radiocarbon-dated driftwood record of the Ellesmere ice shelf in the Canadian High Arctic, the oldest landfast ice in the Northern Hemisphere, also demonstrates a substantial reduction in ice extents over the 20th century (England et al. 2017). A supporting sediment record indicates that inflowing Atlantic water in Fram Strait has warmed by 2C since 1900, driving break up and melt of sea ice (Spielhagen et al. 2011). Complementary mooring and satellite observations show the Atlantification of the eastern Arctic due to enhanced inflow of warm saline water through Fram Strait (Nilsen et al. 2016) and nutrient-rich Pacific water via the Bering has increased by more than 50% (Woodgate et al. 2012), further driving sea ice melt and warming seas. Similar high-resolution proxy records from Arctic regions also indicate that the modern rate of increasing annual surface air temperatures has not been observed over at least the last 2000 years (McKay and Kaufman 2014). Scientists conclude that broad-scale sea ice variations recorded in the paleo record were dominantly driven by changes in basin-scale changes in atmospheric circulation patterns, fluctuations in air temperature, strength of incoming solar radiation, and changes in the inflow of warm water via Pacific and Atlantic inflows (Polyak et al. 2010). There is general consensus that ice-free Arctic summers are likely before the end of the 21st century (e.g., Stroeve et al. 2007; Massonnet et al. 2012), while some climate model projections suggest ice-free Arctic summers as early as 2030 (Wang and Overland 2009). Paleoclimate studies and observational time series attribute the decline in sea ice extent and thickness over the last decade to both enhanced greenhouse warming and natural climate variability. While understanding the interplay of these factors is critical for future projections of Arctic sea ice and ecosystems, most observational time series records cover only a few decades. This highlights the need for additional paleoceanographic reconstructions across multiple spatial and temporal domains to better understand the drivers and implications of present and future Arctic Ocean change.

Bulletin American Meteorological Society↗
USGS1966

Hydrology of the Upper Capibaribe Basin, Pernambuco, Brazil - A reconnaissance in an Area of Crystalline Rocks

The upper Capibaribe basin is the western three-fourths, approximately, of the valley of the river that empties into the Atlantic Ocean at Recife, the capital of the State of Pernambuco, Brazil. It is the part of the drainage basin that is within the Drought Polygon of northeast Brazil, and it totals about 5,400 square kilometers. It receives relatively abundant precipitation in terms of the annual average, yet is regarded as hot subhumid to semiarid because the precipitation is uneven from year to year and place to place. The dependable water supply, therefore, is small. The basin has water, which could be put to better use than at present, but the opportunities for augmenting the usable supply are not great. The streams are intermittent and therefore cannot be expected to fill surface reservoirs and to keep them filled. The ground-water reservoirs have small capacity--quickly filled and quickly drained. A rough estimate based on the records for 1964 suggests that, of 4,700 million cubic meters of precipitation in the upper Capibaribe basin, 2,700 million cubic meters (57 percent) left the basin as runoff and 2,000 million cubic meters {43 percent) went into underground storage or was evaporated or transpired. The bedrock of the upper Capibaribe basin is composed of granite, gneiss, schist, and other varieties of crystalline rocks, which have only insignificant primary permeability. They are permeable mainly where fractured. The principal fracture zones, fortunately, are in the valleys, where water accumulates and can feed into them, but the volume of fractured rock is small in relation to the basin as a whole. A well in a large water-filled fracture zone may yield up to 20,000 liters per hour, but the average well yields less than one-fourth this amount, and some wells yield none. The saprolite, or weathered rock, is many meters thick at some places especially in the eastern half of the upper Capibaribe basin. It contains water locally, but ordinarily will yield only small quantities to wells. The alluvium probably is the most productive aquifer in the basin, but is limited to narrow bands along the rivers that generally are no more than a few hundred meters wide and 5 meters thick. The alluvium contains variable amounts of silty sand capable of yielding small to moderate quantities of water to wells. Wells driven or dug into the alluvium could solve many small water problems. The chemical quality of the water in the upper Capibaribe basin ranges from good to bad and generally presents a major problem that cannot be solved solely by applying geological criteria. Mineralized water is widespread in the area, both in streams and underground, and .the choice of aquifers is small. All known aquifers contain, at one place or another, water that is mineralized, leaving no alternative for a natural supply of good-quality water. Although much of the available water is unsatisfactory for human consumption, it is generally acceptable for animals and therefore meets one of the principal water needs. Some of the ground water could be made potable by diluting it with rainwater, which could be collected during rainy seasons and temporarily stored in cisterns or reservoirs.

Water Supply Paper↗
USGS2022

Mapping areas of groundwater susceptible to transient contamination events from rapid infiltration into shallow fractured-rock aquifers in agricultural regions of the conterminous United States

Current time-invariant groundwater vulnerability assessments may not capture intermittent contamination events in landscape areas that experience rapid infiltration following precipitation or snowmelt. Occurrences of rapid infiltration and intermittent degradation of groundwater quality are frequently reported in fractured-rock aquifers. This investigation identifies landscape areas underlain by fractured rock within the conterminous United States (CONUS) that may be susceptible to rapid infiltration and where groundwater is a principal source of water supply to the population. Our analysis shows that approximately 27 percent of the CONUS, corresponding to a population of approximately 150 million people, is both underlain by fractured rock and denoted as an area of significant groundwater use. The results of this survey identified shallow fractured-rock aquifers underlying glacial sediments in the upper Midwest and northeastern United States as areas that may be subject to rapid infiltration events. Additionally, aquifers associated with the early Mesozoic basins located in the northeastern and mid-Atlantic United States and bands of carbonate aquifers in the southeastern United States show high susceptibility to rapid infiltration. Index values used in this investigation indicate isolated areas in the western half of the United States also show high susceptibility to rapid infiltration. The isolated areas in Oklahoma, Texas, Arkansas, and southwestern Missouri correspond to karst regions of carbonate aquifers. The isolated areas showing high susceptibility to rapid infiltration and contamination from agricultural sources are locations where more detailed investigations of transient contamination events are warranted. This survey also addresses the potential for contaminant longevity in fractured-rock aquifers stemming from intermittent contamination events. Contaminants that can dissolve into the groundwater following infiltration may be introduced into fractures, and the dissolved constituents can diffuse from fractures into the porosity of the adjacent rock matrix. These constituents can then diffuse back into permeable fractures and adversely affect groundwater quality at downgradient locations over an extended time frame. Rock types with larger matrix porosities have the capacity to retain and then release larger quantities of dissolved constituents, resulting in longer residence times for dissolved groundwater contaminants. The magnitude of the dissolved contaminant concentration infiltrating to the water table will also dictate whether the contaminant concentration in the groundwater exceeds limits for human consumption over the duration of a contamination event. In general, sedimentary- and carbonate-rock aquifers have larger matrix porosities in comparison to igneous- and metamorphic-rock aquifers, and thus, they are more susceptible to longer contaminant residence times. Aquifers composed of sedimentary or carbonate rock constitute approximately 51 percent of the CONUS, and 19 percent of the CONUS is associated with sedimentary- or carbonate-rock aquifers that are of significance for groundwater use. Depending on the contaminants of concern and the concentration of the contaminants introduced into the groundwater from infiltrating water, it would be beneficial for investigations of susceptibility to rapid infiltration to also consider the potential for contaminant longevity. This investigation identifies areas of rapid infiltration into fractured rock using index values applied to the attributes (1) depth to the water table, (2) depth to bedrock, and (3) percentage of sand in soil, where larger index values indicate a greater susceptibility to rapid infiltration. These attributes are selected as the most likely factors that affect rapid infiltration to the water table. The combination of depth to water table and depth to bedrock highlight those aquifer settings that are characterized as shallow fractured-rock aquifers, where the water table may reside either in the bedrock or in overlying unconsolidated geologic materials. In addition, we consider the percentage of agricultural use as a land-use attribute when formulating an index of susceptibility to rapid infiltration and contamination. Agricultural areas are well recognized as nonpoint sources of contaminants that can affect groundwater quality because of seasonal amendments applied to the land surface. Rural agricultural areas are also characterized by septic tanks and leach fields for onsite treatment of wastewater, which may also be a source of contamination that may be introduced into the groundwater following precipitation or snowmelt events.

Conterminous United States↗
USGS2000

Hydrologic budget of the late Oligocene Lake Creede and the evolution of the upper Rio Grande drainage system

The filling history, hydrologic budget, and geomorphic development of ancient Lake Creede and its tributary basin are evaluated to determine the factors that controlled its character. The lake filled the Creede caldera that formed in the late Oligocene as a consequence of the eruption of the Snowshoe Mountain Tuff. The caldera's sedimentary fill accumlated to a depth of about 1.26 km and had a volume of about 89 km 3 . The highest lake level was ~3300 m (10,800 ft) present altitude before it drained eastward across a broad volcanic plateau as the ancestral Rio Grande. A tributary canyon several hundred meters deep was cut into hard rhyolite in the north wall of the caldera before the lake was more than half full; its presence demonstrates that ancient Lake Creede filled slowly and thus occupied a long-lived, closed basin. The slow filling rate is incompatible with the present water flux through the Creede caldera basin, because such a flow would fill the basin geologically instantaneously. This mismatch, together with the recognition that the Oligocene climate was similar to that of today, forces the reexamination of the hydrologic and geomorphic history of the caldera. That appraisal shows that the caldera cannot have resurged rapidly immediately after caldera collapse, and that ancient watershed must have been lass than half as large as the present upper Rio Grande basin. The ancient lake had a more or less constant surface area of about 200 km 2 that approximated a steady-state condition between inflow and evaporation. Although the lake level fluctuated with climatic variations, its surface elevation steadily climbed as sediment accumulated, accelerating as resurgance and dome growth usurped spacewithin the basin. It could have had one playa stage early in its development and another after the basin had nearly filled with sediment, but there is no direct evidence for either. At least the lower half of the sedimentary column (the part sampled by the scientific drilling) formed in an euxinic environment. This argues against a persistent early playa, although evaporative accumulation of brine was inevitable. When the rate of resurgance was rapid relative to sedimentary infilling, the lake would have been deep (i.e., bordered by bedrock rather than sedimentary fans). The geomorphic evolution of the Creede caldera and its watershed tracks a two-phase topographic history, the first the Oligocene through Miocene, and the second for Pliocene to the recent. In Oligocene time, the San Juan volcanic field was a hydrologically immature, gently undulating, and outward sloping, constructional volcanic plateau straddling the ancient Continental Divide. West of the Creede caldera, a dendritic drainage discharged northeastward into ancestral Cebolla Creek (a tributary of the ancestral Gunnison River) through an early stage of the Clear Creek graben in the vicinity of Spring Creek Pass. Miocene basalt choked, but did not reconstruct, the drainage. By the end of Miocene time a mature topography of moderate relief developed, exposing some of the higher ores in the Creede district to weathering. In the late Miocene-early Pliocene time the San Juan Mountains were uplifted and titled eastward; the ancestral Rio Grande was revitalized and cut deeply into the older terrain, excavating much of the accessible sediment from the moat of the Creede caldera and exposing successively lowe levels in the Creede district to oxidation. Simultaneously, the southeast end of the Clear Creek graben was reactivated and breached the southwest wall of the Creede caldera. The rejuvenated Rio Grande captured the formerly northeast-directed headwaters of ancestral Cebolla Creek, shifting more than 1000 km 2 from the Pacific-directed drainage to the Atlantic. The water budget for ancient Lake Creede was strictly limited by the early stages of the fist geomorphic cycle; the modern water budget is the product of the second cycle.

Colorado↗